CN105294167A - Staining fluid for zirconia pre-burned false tooth - Google Patents

Staining fluid for zirconia pre-burned false tooth Download PDF

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Publication number
CN105294167A
CN105294167A CN201510893415.0A CN201510893415A CN105294167A CN 105294167 A CN105294167 A CN 105294167A CN 201510893415 A CN201510893415 A CN 201510893415A CN 105294167 A CN105294167 A CN 105294167A
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Prior art keywords
staining fluid
zirconium white
tinting material
color
artificial tooth
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CN105294167B (en
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陈志杰
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Qinhuangdao Zekeni Ceramic Technology Co Ltd
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Qinhuangdao Zekeni Ceramic Technology Co Ltd
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Abstract

The invention relates to staining fluid for a zirconia pre-burned false tooth. The staining fluid consists of the following raw materials in parts by weight: 1000 parts of deionized water, 9.6 to 57 parts of iron chloride, 4.2 to 46.2 parts of erbium nitrate and 0.6 to 24 parts of praseodymium nitrate. The staining fluid has excellent permeation rate, the staining fluid can permeate for 0.8mm in 5 seconds in a single direction, for 1.2mm in 10 seconds in a single direction and for 1.5mm in 20 seconds in a single direction, the permeation speed is high, the stained pre-burned false tooth is integrally uniform in color; moreover, the light transmittance is similar to that of a natural color. Besides, the satisfaction on the requirement of vita 16 colors, four effect colors of A5, B5, C5 and G1 (gingival porcelain color) can also be achieved by the staining color, the production demand of a technician is satisfied, and the blank of the effect color in the industry can be filled. The staining fluid has the characteristics of short time, good staining effect and low cost, and is capable of completing the staining in ten seconds and suitable for the production of false tooth companies.

Description

A kind of zirconium white pre-burning artificial tooth staining fluid
Technical field
The present invention relates to a kind of staining fluid, be specifically related to a kind of full porcelain artificial tooth especially zirconium white pre-burning artificial tooth staining fluid.
Background technology
At present, in Prosthodontics, color and light transmission are the important indicators affecting dummy and tooth objectivity.Use dental CAD/CAM fabrication techniques all-ceramic prosthesis, for the automatization processing of dummy and the making of high strength all-ceramic crown bridge open up a new way.Uncoloured zirconium white pre-burning artificial tooth color many in white to ivory white, although can the color of simulating nature tooth to a certain extent, the clinical requirement to dummy color can not be met.Only have and carry out painted to zirconium white, zirconium white intrinsic colour and light transmission are adjusted to the color and transparence of intending repairing tooth close, the demand of client could be met.The dye technology of current zirconium white pre-burning artificial tooth mainly contains powder dyeing and liquid dip method two kinds, interior dye method is that directly in powder, Direct Uniform adds coloring oxide, and outer dye method is that dentistry presintering base substrate permeates the staining fluid containing painted thing by soak and brushing etc.
Although there is the staining fluid of the multiple zirconium white pre-burning artificial tooth for full porcelain artificial tooth in the market, but ubiquity dyeing time length, complicated component, the defect that cost is high, and existing Vita16 look staining fluid can not meet the demand of daily production, in view of this need to invent the full porcelain artificial tooth zirconium white pre-burning artificial tooth staining fluid that a kind of dyeing time is short, cost is low, Color is good.
Summary of the invention
The object of the invention is to the defect overcoming prior art, provide a kind of dyeing time short, penetrating power is strong, zirconium white pre-burning artificial tooth staining fluid that Color is good.
To achieve these goals, the technical scheme taked of the present invention is as follows:
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000 parts;
Nitrate tinting material 9.6-57 part;
Hydrochloride tinting material 0.4-36.6 part.
Further improve as the present invention, described nitrate tinting material comprises Erbium trinitrate and praseodymium nitrate.
Further improve as the present invention, described Erbium trinitrate is 4.2-46.2 part, and described praseodymium nitrate is 0.6-24 part.
Further improve as the present invention, described hydrochloride is iron(ic) chloride.
The present inventor finds only to need can meet Vita16 look demand by the adjustment of three kinds of composition components after large quantifier elimination, and without the need to increasing any additive, while Color is good, shorten the time of dip-dye, this point discovery be not easy to expect with non-obvious, obtain technical scheme of the present invention by arranging further.
Compared with staining fluid of the prior art, staining fluid provided by the present invention possesses excellent infiltration rate, 5 seconds one direction infiltration 0.8mm, 10 seconds one direction infiltration 1.2mm, 20 seconds one direction infiltration 1.5mm, seepage velocity is fast, and after the dyeing of pre-burning artificial tooth, integral color is even, and transmittance is similar to natural colour.
Staining fluid provided by the invention, except meeting Vita16 look demand, can also dye A5, B5, C5, G1 (gum porcelain look) four kinds of effect looks, compensate for technician's Production requirement and the blank having filled up effect look in industry.
Staining fluid dyeing time provided by the present invention is short, and Color is good, and cost is low, is applicable to industrial production.
Embodiment
Below in conjunction with embodiment, detailed further describing is carried out to the present invention.
Embodiment 1
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 16g;
Praseodymium nitrate tinting material 3.2g;
Iron(ic) chloride tinting material 8.1g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned A1 staining fluid 10 seconds, to dry artificial tooth 10 minutes with infrared(ray)lamp, under 1480 DEG C of-1530 DEG C of conditions, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display A1 color.
Embodiment 2
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 23.1g;
Praseodymium nitrate tinting material 4.9g;
Iron(ic) chloride tinting material 10.7g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned A2 staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display A2 color.
Embodiment 3
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 2.7g;
Praseodymium nitrate tinting material 22.8g;
Iron(ic) chloride tinting material 16.5g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in sub above-mentioned staining fluid 10 seconds, dry, under 1500 DEG C of conditions, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display A3 color.
Embodiment 4
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 13.22g;
Praseodymium nitrate tinting material 6.3g;
Iron(ic) chloride tinting material 18.31g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display A3.5 color.
Embodiment 5
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 20g;
Praseodymium nitrate tinting material 8.5g;
Iron(ic) chloride tinting material 12.8g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display A4 color.
Embodiment 6
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 4g;
Praseodymium nitrate tinting material 4.1g;
Iron(ic) chloride tinting material 6.9g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display B1 color.
Embodiment 7
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 10g;
Praseodymium nitrate tinting material 2g;
Iron(ic) chloride tinting material 9.4g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display B2 color.
Embodiment 8
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 10g;
Praseodymium nitrate tinting material 10g;
Iron(ic) chloride tinting material 13.87g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display B3 color.
Embodiment 9
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 5g;
Praseodymium nitrate tinting material 2g;
Iron(ic) chloride tinting material 14.12g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display B4 color.
Embodiment 10
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 2.1g;
Praseodymium nitrate tinting material 2.7g;
Iron(ic) chloride tinting material 4.9g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display C1 color.
Embodiment 11
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 6.7g;
Praseodymium nitrate tinting material 3g;
Iron(ic) chloride tinting material 8.1g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display C2 color.
Embodiment 12
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 2.4g;
Praseodymium nitrate tinting material 10g;
Iron(ic) chloride tinting material 11.22g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display C3 color.
Embodiment 13
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 5.9g;
Praseodymium nitrate tinting material 12g;
Iron(ic) chloride tinting material 14.89g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display C4 color.
Embodiment 14
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g:
Erbium trinitrate tinting material 15.1g;
Praseodymium nitrate tinting material 4g;
Iron(ic) chloride tinting material 4.4g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display D2 color.
Embodiment 15
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 14.21g;
Praseodymium nitrate tinting material 8g;
Iron(ic) chloride tinting material 8.6g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display D3 color.
Embodiment 16
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 2.32g;
Praseodymium nitrate tinting material 5g;
Iron(ic) chloride tinting material 12.9g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display D4 color.
Embodiment 17
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 20g;
Praseodymium nitrate tinting material 6g;
Iron(ic) chloride tinting material 16.6g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display A5 color.
Embodiment 18
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 3.9g;
Praseodymium nitrate tinting material 7.1g;
Iron(ic) chloride tinting material 16.7g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display B5 color.
Embodiment 19
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 7.2g;
Praseodymium nitrate tinting material 12g;
Iron(ic) chloride tinting material 16.01g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display C5 color.
Embodiment 20
A kind of zirconium white pre-burning artificial tooth staining fluid, it is made up of the raw material of following weight part:
Deionized water 1000g;
Erbium trinitrate tinting material 20.12g;
Praseodymium nitrate tinting material 0.312g;
Iron(ic) chloride tinting material 0.2g.
Concocting method is as follows:
Be placed on electronic balance by 500 milliliters of volumetric glass beakers, electronic balance resets, and adds above-mentioned each tinting material successively, pours beaker into graduated cylinder amount 500 ml distilled water, then carry out being stirred well to all tinting materials and melt completely and get final product by formula.
Zirconium white pre-burning artificial tooth to be soaked in above-mentioned staining fluid 10 seconds, dry, under 1480-1530 DEG C of condition, sinter 5 hours, obtain painted after dental prosthesis, zirconium white display G1 color is gum porcelain look.
It is grey that above-mentioned A, B, C, D tetra-series represent palm fibre, Huang, ash and palm fibre respectively, the color of G1 to be peach be gum.Label 1 to 4 for color bit by bit lightness deepen, saturation ratio increases.
The above embodiment is only the preferred embodiments of the present invention, and and the feasible enforcement of non-invention exhaustive.For persons skilled in the art, to any apparent change done by it under the prerequisite not deviating from the principle of the invention and spirit, all should be contemplated as falling with within claims of the present invention.

Claims (4)

1. a zirconium white pre-burning artificial tooth staining fluid, is characterized in that, it is made up of the raw material of following weight part:
Deionized water 1000 parts;
Nitrate tinting material 9.6-57 part;
Hydrochloride tinting material 0.4-36.6 part.
2. a kind of zirconium white pre-burning artificial tooth staining fluid according to claim 1, it is characterized in that, described nitrate tinting material comprises Erbium trinitrate and praseodymium nitrate.
3. a kind of zirconium white pre-burning artificial tooth staining fluid according to claim 2, it is characterized in that, described Erbium trinitrate is 4.2-46.2 part, and described praseodymium nitrate is 0.6-24 part.
4. a kind of zirconium white pre-burning artificial tooth staining fluid according to claim 1, it is characterized in that, described hydrochloride is iron(ic) chloride.
CN201510893415.0A 2015-12-09 2015-12-09 A kind of zirconium oxide pre-burning artificial tooth dyeing liquor Active CN105294167B (en)

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Cited By (5)

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CN109608233A (en) * 2019-01-30 2019-04-12 成都贝施美医疗科技股份有限公司 A technique for improving dental zirconia ceramic permeability
CN109771064A (en) * 2019-02-27 2019-05-21 深圳市翔通光电技术有限公司 The artificial tooth and preparation method thereof that a kind of intensity, permeability and color successively change
CN109987969A (en) * 2019-04-29 2019-07-09 成都贝施美生物科技有限公司 A kind of rapid soaking zirconium oxide artificial tooth dyeing liquor
CN112830779A (en) * 2021-03-19 2021-05-25 杭州西湖生物材料有限公司 Colored transparent zirconia ceramic bracket and powder injection molding process thereof
CN114538959A (en) * 2022-03-21 2022-05-27 南京市口腔医院 Dyeing formula of VITA3D-MASTER colorimetric system and dyeing method of zirconia false tooth

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Cited By (8)

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Publication number Priority date Publication date Assignee Title
CN109608233A (en) * 2019-01-30 2019-04-12 成都贝施美医疗科技股份有限公司 A technique for improving dental zirconia ceramic permeability
CN109771064A (en) * 2019-02-27 2019-05-21 深圳市翔通光电技术有限公司 The artificial tooth and preparation method thereof that a kind of intensity, permeability and color successively change
CN109987969A (en) * 2019-04-29 2019-07-09 成都贝施美生物科技有限公司 A kind of rapid soaking zirconium oxide artificial tooth dyeing liquor
CN109987969B (en) * 2019-04-29 2021-07-06 成都贝施美生物科技有限公司 A rapid immersion zirconia denture staining solution
CN112830779A (en) * 2021-03-19 2021-05-25 杭州西湖生物材料有限公司 Colored transparent zirconia ceramic bracket and powder injection molding process thereof
CN112830779B (en) * 2021-03-19 2023-10-27 杭州西湖生物材料有限公司 Colored transparent zirconia ceramic bracket and powder injection molding process thereof
CN114538959A (en) * 2022-03-21 2022-05-27 南京市口腔医院 Dyeing formula of VITA3D-MASTER colorimetric system and dyeing method of zirconia false tooth
CN114538959B (en) * 2022-03-21 2023-08-11 南京市口腔医院 Dyeing formula of VITA3D-MASTER colorimetric system and dyeing method of zirconia false tooth

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