CN1054384C - 烯烃聚合物的制备方法 - Google Patents

烯烃聚合物的制备方法 Download PDF

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Publication number
CN1054384C
CN1054384C CN93120452A CN93120452A CN1054384C CN 1054384 C CN1054384 C CN 1054384C CN 93120452 A CN93120452 A CN 93120452A CN 93120452 A CN93120452 A CN 93120452A CN 1054384 C CN1054384 C CN 1054384C
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Prior art keywords
catalyst component
carbon atom
polymerization
electron donor
alkyl
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Expired - Lifetime
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CN93120452A
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Chinese (zh)
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CN1090854A (zh
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扇泽雅明
木冈护
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Mitsui Chemicals Inc
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Mitsui Chemicals Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/645—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/642 - C08F4/643
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/658—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in a single group of groups C08F4/653 - C08F4/657
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN93120452A 1992-12-04 1993-12-04 烯烃聚合物的制备方法 Expired - Lifetime CN1054384C (zh)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP32569792 1992-12-04
JP325698/92 1992-12-04
JP32569892 1992-12-04
JP325698/1992 1992-12-04
JP325697/92 1992-12-04
JP325697/1992 1992-12-04

Publications (2)

Publication Number Publication Date
CN1090854A CN1090854A (zh) 1994-08-17
CN1054384C true CN1054384C (zh) 2000-07-12

Family

ID=26571918

Family Applications (1)

Application Number Title Priority Date Filing Date
CN93120452A Expired - Lifetime CN1054384C (zh) 1992-12-04 1993-12-04 烯烃聚合物的制备方法

Country Status (7)

Country Link
US (1) US5844046A (2)
EP (1) EP0601496B2 (2)
KR (1) KR0137119B1 (2)
CN (1) CN1054384C (2)
CA (1) CA2110606C (2)
DE (1) DE69309864T3 (2)
TW (1) TW300235B (2)

Families Citing this family (69)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3304462B2 (ja) † 1993-01-04 2002-07-22 住友化学工業株式会社 エチレン−プロピレンブロック共重合体の製造方法
US6686433B1 (en) 1994-02-04 2004-02-03 Exxonmobil Chemical Patents Inc. Dual donor catalyst system for the polymerization of olefins
ATE166074T1 (de) * 1994-02-04 1998-05-15 Exxon Chemical Patents Inc Zweidonokatalysatorsystem zur olefinpolymerisation
US6635734B2 (en) * 1994-04-26 2003-10-21 Fina Technology, Inc. Catalyst system to produce highly crystalline polypropylene
FR2728181B1 (fr) 1994-12-16 1997-01-31 Appryl Snc Composante catalytique pour la polymerisation des olefines, son procede de fabrication, et procede de polymerisation des olefines en presence de ladite composante catalytique
CN1089106C (zh) * 1995-01-09 2002-08-14 黄庆源 合成树脂粘合剂的连续化生产方法及其设施
USH1722H (en) * 1995-05-05 1998-04-07 Goode; Mark Gregory Process for producing polypropylene impact block copolymers
KR960041206A (ko) * 1995-05-26 1996-12-19 이현태 폴리프로필렌의 제조방법
CN1067693C (zh) * 1995-09-27 2001-06-27 中国科学院化学研究所 低等规度聚丙烯催化剂体系及其制备方法
FI104080B1 (fi) * 1996-05-15 1999-11-15 Borealis As Olefiinien polymerointiin tarkoitettu stereospesifinen katalyyttisysteemi ja monivaiheiset polymerointiprosessit, joissa tätä systeemiä käytetään
US6403708B2 (en) * 1996-05-27 2002-06-11 Mitsui Chemicals Inc Crystalline polypropylenes, process for preparing thereof, polypropylene compositions, and thermoformed products
US6057407A (en) * 1997-01-08 2000-05-02 Bp Amoco Corporation High melt flow propylene polymer produced by gas-phase polymerization
KR100334167B1 (ko) * 1997-05-08 2002-11-22 삼성종합화학주식회사 알파-올레핀중합방법
KR100334165B1 (ko) 1998-04-17 2002-11-27 삼성종합화학주식회사 에틸렌 중합 및 에틸렌/α-올레핀 공중합용 담지촉매의 제조방법
KR100334164B1 (ko) 1998-04-17 2002-09-25 삼성종합화학주식회사 에틸렌 중합 및 에틸렌/α-올레핀 공중합용 TI/V 담지촉매의제조방법
CN1138794C (zh) * 1998-05-14 2004-02-18 埃克森美孚化学专利公司 采用电子供体混合物形成的聚合物材料
US6087459A (en) * 1998-05-14 2000-07-11 Exxon Chemical Patents Inc. Polymeric materials formed using blends of electron donors
KR100705475B1 (ko) 1998-12-30 2007-12-20 삼성토탈 주식회사 올레핀 중합 및 공중합용 촉매
KR100546499B1 (ko) 1999-05-27 2006-01-26 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
KR100524293B1 (ko) 1999-05-27 2005-10-26 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
US6800580B1 (en) 1999-10-23 2004-10-05 Samsung General Chemicals Co., Ltd. Method for producing an improved catalyst for homo-and co-polymerization of olefin
KR100361224B1 (ko) 1999-12-01 2002-11-29 삼성종합화학주식회사 에틸렌 중합 및 공중합용 촉매의 제조방법
KR100351386B1 (ko) 2000-04-24 2002-09-05 삼성종합화학주식회사 초고분자량 폴리에틸렌 제조용 촉매 및 이를 이용한초고분자량 폴리에틸렌 제조방법
DE60134611D1 (de) * 2000-04-24 2008-08-14 Toho Titanium Co Ltd Feste katalysatorkomponente und katalysaor für die olefinpolymerisation
KR100353960B1 (ko) 2000-05-31 2002-09-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체의 제조방법
KR100359932B1 (ko) 2000-06-15 2002-11-07 삼성종합화학주식회사 에틸렌 중합 및 공중합용 촉매
KR100387734B1 (ko) 2000-06-17 2003-06-18 삼성종합화학주식회사 올레핀 중합용 촉매 및 중합방법
KR100389476B1 (ko) 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체 제조방법
KR100389475B1 (ko) 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합 또는 공중합용 촉매의 제조 방법
KR100389477B1 (ko) 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체 제조방법
KR100389962B1 (ko) 2000-11-10 2003-07-02 삼성종합화학주식회사 에틸렌 중합 또는 공중합용 촉매의 제조 방법
KR100421551B1 (ko) 2000-12-16 2004-03-09 삼성아토피나주식회사 올레핀 전중합 촉매 및 이를 이용한 올레핀 중합방법
US6566294B2 (en) 2000-12-21 2003-05-20 Exxonmobil Chemical Patents Inc. Multi-donor catalyst system for the polymerization of olefins
WO2002051882A1 (en) 2000-12-22 2002-07-04 Samsung General Chemicals Co., Ltd. Chelate catalyst for olefin polymerization and olefin polymerization method using the same
CN1220789C (zh) 2000-12-22 2005-09-28 三星综合化学株式会社 阻燃聚丙烯树脂组合物
KR100421553B1 (ko) 2000-12-27 2004-03-09 삼성아토피나주식회사 알파 올레핀 중합 방법
KR100530794B1 (ko) 2001-06-21 2005-11-23 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
KR100496776B1 (ko) 2001-06-21 2005-06-22 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
KR100530795B1 (ko) * 2001-12-26 2005-11-23 삼성토탈 주식회사 에틸렌 중합 및 공중합 방법
CA2470531C (en) * 2002-01-03 2010-04-13 Bp Corporation North America Inc. Gas phase olefin polymerizations using dual donor catalyst systems
US7141635B2 (en) * 2002-06-14 2006-11-28 Union Carbide Chemicals And Plastics Tech Catalyst composition and polymerization process using mixtures of selectivity control agents
DE602004024994D1 (de) * 2003-06-24 2010-02-25 Union Carbide Chem Plastic Katalysatorzusammensetzung und Polymerisationsverfahren mit einer Mischung von Silane Elektrondonoren
CN1856513A (zh) * 2003-09-23 2006-11-01 联合碳化化学及塑料技术公司 含有混合sca的催化剂组合物和丙烯聚合法
JP2007505983A (ja) * 2003-09-23 2007-03-15 ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション 混合された選択性制御剤を有する触媒組成物、及びプロピレン重合方法
KR101109270B1 (ko) * 2003-09-23 2012-01-30 다우 글로벌 테크놀로지스 엘엘씨 디카르복실산 에스테르 내부 공여체를 갖는 자가 제한 촉매조성물 및 프로필렌 중합 방법
US7491670B2 (en) 2003-09-23 2009-02-17 Dow Global Technologies Inc. Self limiting catalyst composition and propylene polymerization process
PL379383A1 (pl) * 2003-09-23 2006-09-04 Dow Global Technologies Inc. Kompozycja katalityczna z estrem kwasu monokarboksylowego jako donorem wewnętrznym oraz sposób polimeryzacji propylenu
US6800703B1 (en) * 2003-10-15 2004-10-05 Equistar Chemicals, Lp Method for preparing propylene polymers having broad molecular weight distribution
US7135531B2 (en) * 2004-01-28 2006-11-14 Basf Catalysts Llc Spherical catalyst for olefin polymerization
US7351778B2 (en) * 2004-04-30 2008-04-01 China Petroleum & Chemical Corporation Catalyst component for olefin polymerization and catalyst comprising the same
KR100640275B1 (ko) 2004-10-14 2006-11-01 대한유화공업 주식회사 에틸렌 중합 및/또는 에틸렌 공중합용 고체 촉매의 제조방법
CN100491458C (zh) 2006-04-20 2009-05-27 中国石油化工股份有限公司 高性能聚丙烯组合物的制备方法
WO2009029487A1 (en) * 2007-08-24 2009-03-05 Dow Global Technologies, Inc. Self-limiting catalyst system with controlled aluminum rto sca ratio and method
US8003559B2 (en) * 2008-05-13 2011-08-23 Basf Corporation Internal donor for olefin polymerization catalysts
US7638585B2 (en) 2008-05-13 2009-12-29 Basf Catalysts, Llc Catalyst flow
US8003558B2 (en) * 2008-07-29 2011-08-23 Basf Corporation Internal donor for olefin polymerization catalysts
CN102186889B (zh) 2008-08-21 2013-11-06 陶氏环球技术有限责任公司 具有混合的选择性控制剂的催化剂组合物和使用它的聚合反应方法
ES2472668T3 (es) 2009-08-21 2014-07-02 China Petroleum & Chemical Corporation Componente de catalizador para la polimerizaci�n de etileno, preparación del mismo y catalizador que comprende el componente de catalizador
KR101798500B1 (ko) 2010-01-22 2017-11-16 차이나 페트로리움 앤드 케미컬 코포레이션 고 용융강도를 가지는 프로필렌 단일중합체 및 이의 제조 방법
CN102134291B (zh) * 2010-01-22 2013-12-04 中国石油化工股份有限公司 一种高熔体强度聚丙烯的制备方法
JP5984173B2 (ja) 2012-09-24 2016-09-06 インディアン オイル コーポレーション リミテッド オレフィン重合用の触媒を調製するプロセス
CN104610475B (zh) * 2013-11-05 2017-07-28 中国石油化工股份有限公司 一种用于烯烃聚合反应的催化剂
US10759883B2 (en) 2015-08-07 2020-09-01 Sabin Global Technologies B.V. Process for the polymerization of olefins
CN108174605B (zh) * 2015-08-07 2021-03-26 Sabic环球技术有限责任公司 用于烯烃聚合的方法
US10696756B2 (en) 2015-08-07 2020-06-30 Sabic Global Technologies B.V. Process for the polymerization of olefins
CN106565870B (zh) * 2015-10-12 2019-07-05 中国科学院化学研究所 烯烃聚合催化剂及其制备方法和烯烃聚合催化剂体系及其应用以及聚烯烃树脂的制备方法
US11427660B2 (en) 2016-08-17 2022-08-30 Formosa Plastics Corporation, Usa Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same
SG11202008074SA (en) * 2018-04-20 2020-11-27 Toho Titanium Co Ltd Olefin polymer and method for producing olefin polymer
US20250109218A1 (en) 2023-09-29 2025-04-03 Formosa Plastics Corporation, U.S.A. Method for preparing catalyst component for polymerization of polyolefin without the use of internal electron donors

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0385765A2 (en) * 1989-03-02 1990-09-05 Mitsui Petrochemical Industries, Ltd. Process for polymerizing olefins and catalyst for polymerizing olefins

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5883016A (ja) † 1981-11-13 1983-05-18 Mitsui Petrochem Ind Ltd プロピレンブロツク共重合体の製法
JPS61215613A (ja) † 1985-03-22 1986-09-25 Mitsubishi Petrochem Co Ltd プロピレン共重合体の製造法
KR920000173B1 (ko) * 1986-10-09 1992-01-09 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 저결정성 프로필렌계 랜덤 공중합체 조성물, 그 제조방법 및 폴리프로필렌 복합 적층체
EP0357394B1 (en) † 1988-08-31 1995-08-02 Mitsubishi Chemical Corporation Process for producing propylene block copolymer
JPH072799B2 (ja) * 1988-12-16 1995-01-18 住友化学工業株式会社 高立体規則性ａ―オレフィン重合体の製造方法
JPH0426313A (ja) † 1990-05-21 1992-01-29 Sumitomo Electric Ind Ltd 電線貫通部の電線引込み方法
JP3044668B2 (ja) † 1990-09-27 2000-05-22 三菱化学株式会社 プロピレンブロック共重合体の製造法
US5218052A (en) † 1991-02-04 1993-06-08 Amoco Corporation Olefin polymerization and copolymerization process
JP3089713B2 (ja) * 1991-07-04 2000-09-18 住友化学工業株式会社 エチレン−プロピレンブロック共重合体の製造方法
JP3304462B2 (ja) * 1993-01-04 2002-07-22 住友化学工業株式会社 エチレン−プロピレンブロック共重合体の製造方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0385765A2 (en) * 1989-03-02 1990-09-05 Mitsui Petrochemical Industries, Ltd. Process for polymerizing olefins and catalyst for polymerizing olefins

Also Published As

Publication number Publication date
CA2110606A1 (en) 1994-06-05
DE69309864D1 (de) 1997-05-22
KR0137119B1 (ko) 1998-04-27
EP0601496B1 (en) 1997-04-16
CA2110606C (en) 1999-06-01
DE69309864T2 (de) 1997-09-11
EP0601496A1 (en) 1994-06-15
EP0601496B2 (en) 2001-06-27
TW300235B (2) 1997-03-11
US5844046A (en) 1998-12-01
KR940014456A (ko) 1994-07-18
CN1090854A (zh) 1994-08-17
DE69309864T3 (de) 2001-11-22

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