CN105479890A - Water-based polyurethane wall cloth capable of being printed with water-based ink and preparation method of water-based polyurethane wall cloth - Google Patents

Water-based polyurethane wall cloth capable of being printed with water-based ink and preparation method of water-based polyurethane wall cloth Download PDF

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Publication number
CN105479890A
CN105479890A CN201510955535.9A CN201510955535A CN105479890A CN 105479890 A CN105479890 A CN 105479890A CN 201510955535 A CN201510955535 A CN 201510955535A CN 105479890 A CN105479890 A CN 105479890A
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CN
China
Prior art keywords
layer
water
woven fabrics
wall cloth
aqueous polyurethane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510955535.9A
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Chinese (zh)
Inventor
夏汉忠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kunshan Hua Fu New Material Ltd Co
Original Assignee
Kunshan Hua Fu New Material Ltd Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kunshan Hua Fu New Material Ltd Co filed Critical Kunshan Hua Fu New Material Ltd Co
Priority to CN201510955535.9A priority Critical patent/CN105479890A/en
Publication of CN105479890A publication Critical patent/CN105479890A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/40Layered products comprising a layer of synthetic resin comprising polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42Intermediate, backcoat, or covering layers
    • B41M5/44Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0866Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0871Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having an ornamental or specially shaped visible surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/022 layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/02Coating on the layer surface on fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/10Fibres of continuous length
    • B32B2305/20Fibres of continuous length in the form of a non-woven mat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/758Odour absorbent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2375/00Polyureas; Polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels
    • B32B2607/02Wall papers, wall coverings

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Paper (AREA)

Abstract

The invention discloses a water-based polyurethane wall cloth capable of being printed with water-based ink and a preparation method of the water-based polyurethane wall cloth. The water-based polyurethane wall cloth is of a two-layer structure, a non-woven fabric PU layer is adopted as one layer, and a water-based ink adsorption layer is adopted as the other layer; the non-woven fabric PU layer is prepared from a non-woven fabric and water-based PU distributed in the non-woven fabric. According to the water-based polyurethane wall cloth capable of being printed with the water-based ink and the preparation method of the water-based polyurethane wall cloth, the non-woven fabric PU layer is obtained by immersing the non-woven fabric into the water-based PU, one side face of the non-woven fabric PU layer is coated with modified water-based polyurethane resin to obtain the water-based ink adsorption layer which serves as a printable layer, and different patterns can be individually printed or customized to meet the different requirements of different crowds. Meanwhile, the wall cloth and the preparation process thereof are all poisonless and tasteless, and compared with traditional wallpaper, the obtained wall cloth is good in performance, long in service life, very environmentally friendly and capable of being applied to furniture attaching, interior decoration and advertisements and has the wide application prospect.

Description

Aqueous polyurethane wall paper of printable water color ink and preparation method thereof
Technical field
The present invention relates to a kind of wall paper, aqueous polyurethane wall paper particularly relating to printable water color ink and preparation method thereof.
Background technology
Wallpaper, also referred to as wallpaper, wall paper, it is a kind of house decorative material for papering metope, because have the advantages that other house decorative materials multiple such as color is various, pattern enriches, easy construction, affordable are incomparable, be widely used in the interior decoration etc. in house, office, hotel, hotel.When family's interior decoration, due to the particularity that wallpaper has, the color of its finishing and style become the keynote of whole family, and the variation of wallpaper to meet in home decoration the principle of " with light packs repair, decorations of resetting " completely, therefore, is deeply subject to liking of consumers in general.Because people are to the requirement of house ornamentation also fashion individual character increasingly, wallpaper is more and more subject to many youthful high praises.
Current widely used wallpaper, its production technology generally adopts at base stock surface coating PVC paste resin, then drying (gel), cooling, make semi-finished product, then directly print with multicolour press, or first print embossing again, with wallpaper surface obtain color various enrich pattern.First, base stock generally with commercial wood pulp and inorganic filler processing, then is formed after melmac impregnation, and melamine Diazolidinyl Urea, the health of formaldehyde serious harm people.Secondly, the main component of coating is PVC, adjacent benzene class plasticizer, auxiliary agent, titanium dioxide and calcium carbonate etc., and wherein, adjacent benzene class plasticizer belongs to the Environmental Hormone affecting reproduction and growth, have a great impact developmental male reproductive system, the threat wherein suffered by child is higher than adult.In addition, generally adopt oil-based ink when embossing, and the main component of oil-based ink being TOL, MEK, DMF etc., there is VOC and remains in such technique, and VOC is residual also has tremendous influence to health.
As can be seen here, existing wallpaper is in production and manufacture process, owing to there being participating in of number of chemical harmful and noxious substance, cause wallpaper still can discharge various poisonous and harmful substance in use, especially formaldehyde, adjacent benzene class plasticizer and VOC, cause serious threat to environment and the healthy and safe of human body.
Summary of the invention
In order to overcome above-mentioned defect; the invention provides aqueous polyurethane wall paper of a kind of printable water color ink and preparation method thereof, not only can personalize pattern, and nonpoisonous and tasteless; very environmental protection, can be applicable to interior decoration simultaneously, attaches furniture and make house ads etc.
The present invention in order to the technical scheme solving its technical problem and adopt is: a kind of aqueous polyurethane wall paper of printable water color ink, and this aqueous polyurethane wall paper is double-layer structure, and wherein one deck is non-woven fabrics PU layer, and another layer is aqueous ink sorptive layer; Described non-woven fabrics PU layer comprises non-woven fabrics and is distributed in the water-based PU in this non-woven fabrics.
As a further improvement on the present invention, the thickness of described non-woven fabrics PU layer is: 0.2-0.6mm, and the thickness of described aqueous ink sorptive layer is 0.02-0.05mm.
As a further improvement on the present invention, described aqueous ink sorptive layer is the waterborne polyurethane resin of modification.
The present invention also provides a kind of aqueous polyurethane wall paper preparation method of printable water color ink, comprises the following steps:
1. prepare a non-woven fabrics, this non-woven fabrics is impregnated in water-based PU, dry after taking out, namely obtain the non-woven fabrics PU layer of point aqueous polyurethane in non-woven fabrics;
2. on one of them side of described non-woven fabrics PU layer, coating can adsorb the aqueous polyurethane solution of the modification of water color ink, namely on described non-woven fabrics PU layer, obtain aqueous ink sorptive layer after drying, namely obtain the aqueous polyurethane wall paper finished product of printable water color ink.
As a further improvement on the present invention, described step 2. in, the coated weight of the aqueous polyurethane solution of described modification is 50-150g/m 2.
The invention has the beneficial effects as follows: aqueous polyurethane wall paper of this printable water color ink and preparation method thereof adopts in non-woven fabrics impregnation water-based PU and obtains non-woven fabrics PU layer, and then obtain aqueous ink sorptive layer at the waterborne polyurethane resin of this non-woven fabrics PU layer one side coating modification, this aqueous ink sorptive layer is printable layer, personalizedly can print or customize different patterns, meeting the demand that different crowd is different.This wall paper and preparation process thereof are all nonpoisonous and tasteless simultaneously, and it is good that traditional wallpaper performance not only compared by the wall paper obtained, long service life, and very environmental protection, can be used for attaching furniture, and interior decoration and house ads, be with a wide range of applications.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
By reference to the accompanying drawings, make the following instructions:
1---non-woven fabrics PU layer 2---aqueous ink sorptive layer
11---non-woven fabrics 12---water-based PU
Detailed description of the invention
By reference to the accompanying drawings, elaborate to the present invention, but protection scope of the present invention is not limited to following embodiment, the simple equivalence namely in every case done with the present patent application the scope of the claims and description changes and modifies, and all still belongs within patent covering scope of the present invention.
Embodiment 1:
An aqueous polyurethane wall paper preparation method for printable water color ink, comprises the following steps:
1. prepare a non-woven fabrics 11, this non-woven fabrics is impregnated in water-based PU, dry after taking out, namely obtain the non-woven fabrics PU layer 1 of point aqueous polyurethane in non-woven fabrics;
2. on one of them side of described non-woven fabrics PU layer 1, coating can adsorb the modified aqueous polyurethane solution of water color ink, and coated weight is 50g/m 2, namely on described non-woven fabrics PU layer 1, obtain aqueous ink sorptive layer 2 after drying, namely obtain the aqueous polyurethane wall paper finished product of printable water color ink.
Shown in Figure 1, the aqueous polyurethane wall paper of this printable water color ink is double-layer structure, and wherein one deck is non-woven fabrics PU layer 1, and another layer is aqueous ink sorptive layer 2; The water-based PU12 that described non-woven fabrics PU layer comprises non-woven fabrics 11 and is distributed in this non-woven fabrics.
Wherein, described aqueous ink sorptive layer is the waterborne polyurethane resin of modification; The thickness of described non-woven fabrics PU layer is: 0.2mm, and the thickness of described aqueous ink sorptive layer is 0.02mm.
Embodiment 2:
An aqueous polyurethane wall paper preparation method for printable water color ink, comprises the following steps:
1. prepare a non-woven fabrics 11, this non-woven fabrics is impregnated in water-based PU, dry after taking out, namely obtain the non-woven fabrics PU layer 1 of point aqueous polyurethane in non-woven fabrics;
2. on one of them side of described non-woven fabrics PU layer 1, coating can adsorb the modified aqueous polyurethane solution of water color ink, and coated weight is 150g/m 2, namely on described non-woven fabrics PU layer 1, obtain aqueous ink sorptive layer 2 after drying, namely obtain the aqueous polyurethane wall paper finished product of printable water color ink.
Shown in Figure 1, the aqueous polyurethane wall paper of this printable water color ink is double-layer structure, and wherein one deck is non-woven fabrics PU layer 1, and another layer is aqueous ink sorptive layer 2; The water-based PU12 that described non-woven fabrics PU layer comprises non-woven fabrics 11 and is distributed in this non-woven fabrics.
Wherein, described aqueous ink sorptive layer is the waterborne polyurethane resin of modification; The thickness of described non-woven fabrics PU layer is: 0.4mm, and the thickness of described aqueous ink sorptive layer is 0.05mm.
Embodiment 3:
An aqueous polyurethane wall paper preparation method for printable water color ink, comprises the following steps:
1. prepare a non-woven fabrics 11, this non-woven fabrics is impregnated in water-based PU, dry after taking out, namely obtain the non-woven fabrics PU layer 1 of point aqueous polyurethane in non-woven fabrics;
2. on one of them side of described non-woven fabrics PU layer 1, coating can adsorb the modified aqueous polyurethane solution of water color ink, and coated weight is 100g/m 2, namely on described non-woven fabrics PU layer 1, obtain aqueous ink sorptive layer 2 after drying, namely obtain the aqueous polyurethane wall paper finished product of printable water color ink.
Shown in Figure 1, the aqueous polyurethane wall paper of this printable water color ink is double-layer structure, and wherein one deck is non-woven fabrics PU layer 1, and another layer is aqueous ink sorptive layer 2; The water-based PU12 that described non-woven fabrics PU layer comprises non-woven fabrics 11 and is distributed in this non-woven fabrics.
Wherein, described aqueous ink sorptive layer is the waterborne polyurethane resin of modification; The thickness of described non-woven fabrics PU layer is: 0.6mm, and the thickness of described aqueous ink sorptive layer is 0.035mm.

Claims (5)

1. an aqueous polyurethane wall paper for printable water color ink, is characterized in that: this aqueous polyurethane wall paper is double-layer structure, and wherein one deck is non-woven fabrics PU layer (1), and another layer is aqueous ink sorptive layer (2); Described non-woven fabrics PU layer comprises non-woven fabrics (11) and is distributed in the water-based PU (12) in this non-woven fabrics.
2. the aqueous polyurethane wall paper of printable water color ink according to claim 1, is characterized in that: the thickness of described non-woven fabrics PU layer is: 0.2-0.6mm, and the thickness of described aqueous ink sorptive layer is 0.02-0.05mm.
3. the aqueous polyurethane wall paper of printable water color ink according to claim 2, is characterized in that: described aqueous ink sorptive layer is the waterborne polyurethane resin of modification.
4. an aqueous polyurethane wall paper preparation method for printable water color ink as claimed any one in claims 1 to 3, is characterized in that, comprise the following steps:
1. prepare a non-woven fabrics (11), this non-woven fabrics is impregnated in water-based PU, dry after taking out, namely obtain the non-woven fabrics PU layer (1) of point aqueous polyurethane in non-woven fabrics;
2. on one of them side of described non-woven fabrics PU layer (1), coating can adsorb the aqueous polyurethane solution of the modification of water color ink, namely described non-woven fabrics PU layer (1) upper acquisition aqueous ink sorptive layer (2) after drying, namely obtain the aqueous polyurethane wall paper finished product of printable water color ink.
5. the aqueous polyurethane wall paper preparation method of printable water color ink according to claim 4, is characterized in that: described step 2. in, the coated weight of the aqueous polyurethane solution of described modification is 50-150g/m 2.
CN201510955535.9A 2015-12-18 2015-12-18 Water-based polyurethane wall cloth capable of being printed with water-based ink and preparation method of water-based polyurethane wall cloth Pending CN105479890A (en)

Priority Applications (1)

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CN201510955535.9A CN105479890A (en) 2015-12-18 2015-12-18 Water-based polyurethane wall cloth capable of being printed with water-based ink and preparation method of water-based polyurethane wall cloth

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106758548A (en) * 2017-01-05 2017-05-31 汪良 A kind of novel environment friendly facing paper and preparation method thereof
WO2020005264A1 (en) * 2018-06-29 2020-01-02 Hewlett-Packard Development Company, L.P. Printable fabrics

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080188152A1 (en) * 2007-02-02 2008-08-07 Chiu-Shiung Tsai Moisture-vapor- permeable and water-resistant fiber
CN103993486A (en) * 2014-05-26 2014-08-20 合肥市科天化工有限公司 Method for preparing waterborne polyurethane wall leather
CN205238749U (en) * 2015-12-18 2016-05-18 昆山华富新材料股份有限公司 Printable water -based ink's waterborne polyurethane wall paper

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080188152A1 (en) * 2007-02-02 2008-08-07 Chiu-Shiung Tsai Moisture-vapor- permeable and water-resistant fiber
CN103993486A (en) * 2014-05-26 2014-08-20 合肥市科天化工有限公司 Method for preparing waterborne polyurethane wall leather
CN205238749U (en) * 2015-12-18 2016-05-18 昆山华富新材料股份有限公司 Printable water -based ink's waterborne polyurethane wall paper

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106758548A (en) * 2017-01-05 2017-05-31 汪良 A kind of novel environment friendly facing paper and preparation method thereof
WO2020005264A1 (en) * 2018-06-29 2020-01-02 Hewlett-Packard Development Company, L.P. Printable fabrics

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Application publication date: 20160413

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