CN105504694A - High-strength flame-retardant nano-composite material - Google Patents
High-strength flame-retardant nano-composite material Download PDFInfo
- Publication number
- CN105504694A CN105504694A CN201511009079.5A CN201511009079A CN105504694A CN 105504694 A CN105504694 A CN 105504694A CN 201511009079 A CN201511009079 A CN 201511009079A CN 105504694 A CN105504694 A CN 105504694A
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- CN
- China
- Prior art keywords
- parts
- nano
- composite material
- strength
- flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000463 material Substances 0.000 title claims abstract description 19
- 239000002114 nanocomposite Substances 0.000 title claims abstract description 14
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 5
- 239000003063 flame retardant Substances 0.000 title abstract description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 16
- -1 diphenylmethane ester Chemical class 0.000 claims abstract description 14
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 8
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 8
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 8
- 239000010425 asbestos Substances 0.000 claims abstract description 8
- 239000003365 glass fiber Substances 0.000 claims abstract description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 229910052895 riebeckite Inorganic materials 0.000 claims abstract description 8
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 14
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 14
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 claims description 7
- 239000004593 Epoxy Substances 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 7
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 claims description 7
- 229920003986 novolac Polymers 0.000 claims description 7
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 7
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 239000004809 Teflon Substances 0.000 abstract 1
- 229920006362 Teflon® Polymers 0.000 abstract 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-M decanoate Chemical compound CCCCCCCCCC([O-])=O GHVNFZFCNZKVNT-UHFFFAOYSA-M 0.000 abstract 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 abstract 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 abstract 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 abstract 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 abstract 1
- 239000004843 novolac epoxy resin Substances 0.000 abstract 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 230000000979 retarding effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/04—Epoxynovolacs
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high-strength flame-retardant nano-composite material. The high-strength flame-retardant nano-composite material is prepared from the following raw materials in pars by weight: 11-14 parts of diphenylmethane ester diisochlorate, 4-6 parts of stannous caprate, 6-8 parts of polytetramethylene glycol, 12-16 parts of nano-titanium dioxide, 10-14 parts of nano-silicon dioxide, 12-15 parts of glass fiber, 22-26 parts of novolac epoxy resin, 11-15 parts of hydroxypropyl methyl cellulose, 7-9 parts of Teflon, 8-13 parts of carboxylic acrylonitrile butadiene rubber, 6-9 parts of aluminium hydroxide, 5-7 parts of asbestos. The high-strength flame-retardant nano-composite material has the advantages of high strength, high wear resistance, high oxidation resistance, corrosion resistance, fire-proofness and flame retardancy.
Description
Technical field
The present invention relates to technical field of composite materials, particularly relate to a kind of high-strength anti-flaming nano composite material.
Background technology
Matrix material refers to the material combined by different way by two or more different substances, it can play the advantage of various material, overcome the defect of single-material, expand the range of application of material, due to matrix material have lightweight, intensity is high, machine-shaping is convenient, excellent spring, the feature such as resistance to chemical attack and good weatherability, progressively replace timber and metal alloy, be widely used in aerospace, automobile, electric, the field such as building, body-building apparatus, obtain develop rapidly especially in recent years.Existing matrix material loss of properties on aging, flame retardant resistance has much room for improvement, and governs the development of field of compound material.
Summary of the invention
For solving above-mentioned Problems existing, the invention provides a kind of intensity high, wear resistance is good, and resistance of oxidation is good, corrosion-resistant, the high-strength anti-flaming nano composite material of fire protection flame retarding.
The technical scheme that the present invention solves the problems of the technologies described above employing is: a kind of high-strength anti-flaming nano composite material, is made up of the raw material of following mass fraction:
Ditan two different chlorate 11-14 part, capric acid sub-tin 4-6 part, polytetramethylene glycol 6-8 part, nano titanium oxide 12-16 part, nano silicon 10-14 part, glass fibre 12-15 part, novolac epoxy 22-26 part, Vltra tears 11-15 part, tetrafluoroethylene 7-9 part, carboxy nitrile rubber 8-13 part, aluminium hydroxide 6-9 part, asbestos 5-7 part.
Above-mentioned high-strength anti-flaming nano composite material, be made up of the raw material of following mass fraction:
The different chlorate of ditan two 13 parts, sub-5 parts, the tin of capric acid, polytetramethylene glycol 7 parts, nano titanium oxide 14 parts, nano silicon 12 parts, 14 parts, glass fibre, novolac epoxy 24 parts, Vltra tears 13 parts, tetrafluoroethylene 8 parts, carboxy nitrile rubber 11 parts, 7 parts, aluminium hydroxide, 6 parts, asbestos.
The beneficial effect that technical solution problem of the present invention is brought is: intensity of the present invention is high, and wear resistance is good, and resistance of oxidation is good, corrosion-resistant, fire protection flame retarding.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further details.
Embodiment 1
A kind of high-strength anti-flaming nano composite material, be made up of the raw material of following mass fraction:
The different chlorate of ditan two 11 parts, sub-4 parts, the tin of capric acid, polytetramethylene glycol 6 parts, nano titanium oxide 12 parts, nano silicon 10 parts, 12 parts, glass fibre, novolac epoxy 22 parts, Vltra tears 11 parts, tetrafluoroethylene 7 parts, carboxy nitrile rubber 8 parts, 6 parts, aluminium hydroxide, 5 parts, asbestos.
Embodiment 2
A kind of high-strength anti-flaming nano composite material, be made up of the raw material of following mass fraction:
The different chlorate of ditan two 13 parts, sub-5 parts, the tin of capric acid, polytetramethylene glycol 7 parts, nano titanium oxide 14 parts, nano silicon 12 parts, 14 parts, glass fibre, novolac epoxy 24 parts, Vltra tears 13 parts, tetrafluoroethylene 8 parts, carboxy nitrile rubber 11 parts, 7 parts, aluminium hydroxide, 6 parts, asbestos.
Embodiment 3
A kind of high-strength anti-flaming nano composite material, be made up of the raw material of following mass fraction:
The different chlorate of ditan two 14 parts, sub-6 parts, the tin of capric acid, polytetramethylene glycol 8 parts, nano titanium oxide 16 parts, nano silicon 14 parts, 15 parts, glass fibre, novolac epoxy 26 parts, Vltra tears 15 parts, tetrafluoroethylene 9 parts, carboxy nitrile rubber 13 parts, 9 parts, aluminium hydroxide, 7 parts, asbestos.
Although above-mentioned, the specific embodiment of the present invention is described; but not limiting the scope of the invention; one of ordinary skill in the art should be understood that; on the basis of technical scheme of the present invention, those skilled in the art do not need to pay various amendment or distortion that creative work can make still within protection scope of the present invention.
Claims (2)
1. a high-strength anti-flaming nano composite material, is characterized in that: be made up of the raw material of following mass fraction:
Ditan two different chlorate 11-14 part, capric acid sub-tin 4-6 part, polytetramethylene glycol 6-8 part, nano titanium oxide 12-16 part, nano silicon 10-14 part, glass fibre 12-15 part, novolac epoxy 22-26 part, Vltra tears 11-15 part, tetrafluoroethylene 7-9 part, carboxy nitrile rubber 8-13 part, aluminium hydroxide 6-9 part, asbestos 5-7 part.
2. high-strength anti-flaming nano composite material according to claim 1, is characterized in that: be made up of the raw material of following mass fraction:
The different chlorate of ditan two 13 parts, sub-5 parts, the tin of capric acid, polytetramethylene glycol 7 parts, nano titanium oxide 14 parts, nano silicon 12 parts, 14 parts, glass fibre, novolac epoxy 24 parts, Vltra tears 13 parts, tetrafluoroethylene 8 parts, carboxy nitrile rubber 11 parts, 7 parts, aluminium hydroxide, 6 parts, asbestos.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511009079.5A CN105504694A (en) | 2015-12-30 | 2015-12-30 | High-strength flame-retardant nano-composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511009079.5A CN105504694A (en) | 2015-12-30 | 2015-12-30 | High-strength flame-retardant nano-composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105504694A true CN105504694A (en) | 2016-04-20 |
Family
ID=55713019
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511009079.5A Pending CN105504694A (en) | 2015-12-30 | 2015-12-30 | High-strength flame-retardant nano-composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105504694A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106832781A (en) * | 2017-02-17 | 2017-06-13 | 南通苏源化纤有限公司 | Novel nano high fire-retardance thermosetting resin based composites |
-
2015
- 2015-12-30 CN CN201511009079.5A patent/CN105504694A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106832781A (en) * | 2017-02-17 | 2017-06-13 | 南通苏源化纤有限公司 | Novel nano high fire-retardance thermosetting resin based composites |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160420 |
|
| WD01 | Invention patent application deemed withdrawn after publication |