CN105507017A - Production method of dynamic waterproof deeply-embossed synthetic leather - Google Patents

Production method of dynamic waterproof deeply-embossed synthetic leather Download PDF

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Publication number
CN105507017A
CN105507017A CN201610064580.XA CN201610064580A CN105507017A CN 105507017 A CN105507017 A CN 105507017A CN 201610064580 A CN201610064580 A CN 201610064580A CN 105507017 A CN105507017 A CN 105507017A
Authority
CN
China
Prior art keywords
water
synthetic leather
fluorine element
sprinkling agent
dynamic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610064580.XA
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Chinese (zh)
Inventor
朱巨波
苏德业
林小芳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anan (China) Co Ltd
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Anan (China) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anan (China) Co Ltd filed Critical Anan (China) Co Ltd
Priority to CN201610064580.XA priority Critical patent/CN105507017A/en
Publication of CN105507017A publication Critical patent/CN105507017A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/142Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0011Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00Macromolecular materials of the coating layers
    • D06N2203/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/044Fluoropolymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/12Permeability or impermeability properties
    • D06N2209/126Permeability to liquids, absorption
    • D06N2209/128Non-permeable

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

The invention relates to the field of dynamic waterproof shoe materials, in particular to a production method of dynamic waterproof deeply-embossed synthetic leather. The production method is characterized in that a water-repellent perfluorocarbon water-based water sprinkling agent permeates the whole dry-wet process structure of synthetic leather, so that no-net cloth in the synthetic leather and the perfluorocarbon water-based water sprinkling agent form a fluorine protective film which cannot be sensed by naked eyes to realize dynamic water repellency of the deeply-embossed shoe leather. The deeply-embossed synthetic leather produced by the production method can achieve the dynamic 15,000-time effect, the whole technological process is simple, the operation is convenient and easy to control, and the production method is very suitable for production.

Description

The production method of the dark embossing synthetic leather of a kind of dynamic water-proof
Technical field
The present invention relates to dynamic water-proof footwear material field, the production method of the dark embossing synthetic leather of especially a kind of dynamic water-proof.
Background technology
Being in great demand in the market to the outdoor sports shoe material of anti-siphon, spill resistant and dynamic water-proof three types.When spill resistant refers to that there is water on its surface, synthetic leather positive and negative, it is as the globule on lotus leaf, does not permeate the phenomenon of leather the inside.Anti-siphon refers to wide 1cm, the synthetic leather of long 20cm, and synthetic leather bottom vertical inserts below mercurochrome liquid level 1cm place, leaves standstill after 2 hours, how much defines with mercurochrome pole-climbing amount.Dynamic water-proof refers to that synthetic leather is clipped on anti-siphon tester table, and the leather back side contacts with water, normal temperature folding 1.5 ten thousand times, sees that just whether leather has the globule to infiltrate.
Anti-siphon and spill resistant just can reach the effect required by it at wet processing, but for folding exigent dynamic water-proof footwear material itself, dark lines embossed product will destroy dry method top layer in embossing process, even there is the risk destroying wet method surface layer, now its dynamic water-proof effect will become very poor, cannot meet the requirement of sport footwear material for dynamic water-proof; But dark lines embossing footwear leather is dark liking by outdoor and mountain-climbing fan again, so, solve dark embossed product dynamic water-proof material and to be necessary research topic.
Summary of the invention
Technical problem to be solved by this invention is the production method changing conventional motion footwear material synthetic leather, provides the production method of the dark embossing synthetic leather of a kind of dynamic water-proof.
For solving the problems of the technologies described above; this production method, by the fluorine element eight carbon water-based water-sprinkling agent with WATER REPELLENCY being penetrated in whole dry, the wet method structure of synthetic leather, makes forming one deck naked eyes without the plain eight carbon water-based water-sprinkling agent of screen cloth and fluorine and be not aware of the dynamic water-proof that the plain diaphragm of fluorine removes from office to realize dark lines embossing footwear in synthetic leather.
The production method of the dark embossing synthetic leather of a kind of dynamic water-proof of the present invention comprises the steps:
1) the selected and processing of base material: select 24 hours hydrolysis space base materials, through the semi-finished product synthetic leather that the production of wet method embossing bass, dry method surfacing process, the dark embossed technology of post processing are made;
2) preparation of water-sprinkling agent solution: select the eight carbon water-based water-sprinkling agent 7 parts of fluorine element according to volume constituents proportioning, slowly inject the water of 93 parts, forms the fluorine element eight carbon water-based water-sprinkling agent aqueous solution of 7%, stirs;
3) the fluorine element eight carbon water-based water-sprinkling agent aqueous solution be stirred is injected the impregnating groove of impregnation machine;
4) by step 1) in semi-finished product synthetic leather impregnation board by deflector roll immerse step 3) in be equipped with fluorine element the eight carbon water-based water-sprinkling agent aqueous solution impregnating groove in, base material is soaked completely, and to reach water absorption be 100g/ square metre, so that the eight carbon water-based water-sprinkling agent of fluorine element can be evenly distributed in the base material selected, one deck fluorine element diaphragm is jointly formed with nonwoven fabric, polyurethane resin, fluorine element diaphragm can be not damaged normal temperature folding 15000 times, thus reach dynamic water-proof 15000 effects;
5) through step 4) base material that soaks is by temperature 150-160 DEG C of oven for drying, and drying time 5-6 minute, reaches fluorine element eight carbon water-based water-sprinkling agent solidification and improves dynamic water-proof effect;
6) cooling meat.
Good effect of the present invention:
The production method of the dark embossing synthetic leather of a kind of dynamic water-proof of the present invention, the dark embossing synthetic leather produced by the method can meet the requirement of anti-siphon, spill resistant and dynamic water-proof simultaneously, especially dynamic water-proof aspect achieves dynamic water-proof 15000 effects, whole technological process is simple, easy to operate easy control, is highly suitable for producing.
Detailed description of the invention
The production method of the dark embossing synthetic leather of a kind of dynamic water-proof of the present invention comprises the steps:
1) the selected and processing of base material: select 24 hours hydrolysis space base materials, through the semi-finished product synthetic leather that the production of wet method embossing bass, dry method surfacing process, the dark embossed technology of post processing are made;
2) preparation of water-sprinkling agent solution: select the eight carbon water-based water-sprinkling agent 7 parts of fluorine element according to volume constituents proportioning, slowly inject the water of 93 parts, forms the fluorine element eight carbon water-based water-sprinkling agent aqueous solution of 7%, stirs;
3) the fluorine element eight carbon water-based water-sprinkling agent aqueous solution be stirred is injected the impregnating groove of impregnation machine;
4) by step 1) in semi-finished product synthetic leather impregnation board by deflector roll immerse step 3) in be equipped with fluorine element the eight carbon water-based water-sprinkling agent aqueous solution impregnating groove in, base material is soaked completely, and to reach water absorption be 100g/ square metre, so that the eight carbon water-based water-sprinkling agent of fluorine element can be evenly distributed in the base material selected, one deck fluorine element diaphragm is jointly formed with nonwoven fabric, polyurethane resin, fluorine element diaphragm can be not damaged normal temperature folding 15000 times, thus reach dynamic water-proof 15000 effects;
5) through step 4) base material that soaks is by temperature 150-160 DEG C of oven for drying, and drying time 5-6 minute, reaches fluorine element eight carbon water-based water-sprinkling agent solidification and improves dynamic water-proof effect; Cooling meat.

Claims (1)

1. a production method for the dark embossing synthetic leather of dynamic water-proof, is characterized in that: comprise the steps:
1) the selected and processing of base material: select 24 hours hydrolysis space base materials, through the semi-finished product synthetic leather that the production of wet method embossing bass, dry method surfacing process, the dark embossed technology of post processing are made;
2) preparation of water-sprinkling agent solution: select the eight carbon water-based water-sprinkling agent 7 parts of fluorine element according to volume constituents proportioning, slowly inject the water of 93 parts, forms the fluorine element eight carbon water-based water-sprinkling agent aqueous solution of 7%, stirs;
3) the fluorine element eight carbon water-based water-sprinkling agent aqueous solution be stirred is injected the impregnating groove of impregnation machine;
4) by step 1) in semi-finished product synthetic leather impregnation board by deflector roll immerse step 3) in be equipped with fluorine element the eight carbon water-based water-sprinkling agent aqueous solution impregnating groove in, base material is soaked completely, and to reach water absorption be 100g/ square metre, so that the eight carbon water-based water-sprinkling agent of fluorine element can be evenly distributed in the base material selected, one deck fluorine element diaphragm is jointly formed with nonwoven fabric, polyurethane resin, fluorine element diaphragm can be not damaged normal temperature folding 15000 times, thus reach dynamic water-proof 15000 effects;
5) through step 4) base material that soaks is by temperature 150-160 DEG C of oven for drying, and drying time 5-6 minute, reaches fluorine element eight carbon water-based water-sprinkling agent solidification and improves dynamic water-proof effect;
6) cooling meat.
CN201610064580.XA 2016-02-01 2016-02-01 Production method of dynamic waterproof deeply-embossed synthetic leather Pending CN105507017A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610064580.XA CN105507017A (en) 2016-02-01 2016-02-01 Production method of dynamic waterproof deeply-embossed synthetic leather

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610064580.XA CN105507017A (en) 2016-02-01 2016-02-01 Production method of dynamic waterproof deeply-embossed synthetic leather

Publications (1)

Publication Number Publication Date
CN105507017A true CN105507017A (en) 2016-04-20

Family

ID=55715297

Family Applications (1)

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CN201610064580.XA Pending CN105507017A (en) 2016-02-01 2016-02-01 Production method of dynamic waterproof deeply-embossed synthetic leather

Country Status (1)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1554822A (en) * 2003-12-26 2004-12-15 长沙中园科技有限公司 Water-proof, cold-proof and moisture permeable polyurethane coating cloth and its producing process
CN1814906A (en) * 2005-02-03 2006-08-09 三芳化学工业股份有限公司 Artificial leather with high water repellency and its manufacturing method
CN101886343A (en) * 2010-06-30 2010-11-17 安徽安利合成革股份有限公司 Method for manufacturing acid-proof, alkali-proof, hydrolysis-resistant and high-peel-strength polyurethane space leather
CN102650103A (en) * 2012-05-23 2012-08-29 安徽安利合成革股份有限公司 Preparation method for polyurethane synthetic leather with water repellent performance
CN102797166A (en) * 2012-09-05 2012-11-28 上海华峰超纤材料股份有限公司 Water-repellent oil-repellent superfine fiber synthetic leather and preparation method thereof
CN104420331A (en) * 2013-08-20 2015-03-18 上海华峰超纤材料股份有限公司 Environmental-protective waterproof oilproof microfiber synthetic leather and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1554822A (en) * 2003-12-26 2004-12-15 长沙中园科技有限公司 Water-proof, cold-proof and moisture permeable polyurethane coating cloth and its producing process
CN1814906A (en) * 2005-02-03 2006-08-09 三芳化学工业股份有限公司 Artificial leather with high water repellency and its manufacturing method
CN101886343A (en) * 2010-06-30 2010-11-17 安徽安利合成革股份有限公司 Method for manufacturing acid-proof, alkali-proof, hydrolysis-resistant and high-peel-strength polyurethane space leather
CN102650103A (en) * 2012-05-23 2012-08-29 安徽安利合成革股份有限公司 Preparation method for polyurethane synthetic leather with water repellent performance
CN102797166A (en) * 2012-09-05 2012-11-28 上海华峰超纤材料股份有限公司 Water-repellent oil-repellent superfine fiber synthetic leather and preparation method thereof
CN104420331A (en) * 2013-08-20 2015-03-18 上海华峰超纤材料股份有限公司 Environmental-protective waterproof oilproof microfiber synthetic leather and preparation method thereof

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Application publication date: 20160420

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