CN105802477B - A kind of environment-friendly water-based paint and preparation method thereof - Google Patents
A kind of environment-friendly water-based paint and preparation method thereof Download PDFInfo
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- CN105802477B CN105802477B CN201610371124.XA CN201610371124A CN105802477B CN 105802477 B CN105802477 B CN 105802477B CN 201610371124 A CN201610371124 A CN 201610371124A CN 105802477 B CN105802477 B CN 105802477B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 239000003973 paint Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 241001122767 Theaceae Species 0.000 claims abstract description 36
- 239000000843 powder Substances 0.000 claims abstract description 36
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000000835 fiber Substances 0.000 claims abstract description 25
- 229920002472 Starch Polymers 0.000 claims abstract description 16
- 235000019698 starch Nutrition 0.000 claims abstract description 16
- 239000008107 starch Substances 0.000 claims abstract description 16
- 229920003009 polyurethane dispersion Polymers 0.000 claims abstract description 14
- 239000000049 pigment Substances 0.000 claims abstract description 13
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 125000005396 acrylic acid ester group Chemical group 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 13
- 239000002134 carbon nanofiber Substances 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 10
- 230000004048 modification Effects 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- 239000007822 coupling agent Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000004806 packaging method and process Methods 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- -1 is stirred 12 h Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000012467 final product Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 239000002121 nanofiber Substances 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 210000000481 breast Anatomy 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229940093430 polyethylene glycol 1500 Drugs 0.000 description 2
- IQXJCCZJOIKIAD-UHFFFAOYSA-N 1-(2-methoxyethoxy)hexadecane Chemical compound CCCCCCCCCCCCCCCCOCCOC IQXJCCZJOIKIAD-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000004923 Acrylic lacquer Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229950009789 cetomacrogol 1000 Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 208000021760 high fever Diseases 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention belongs to coating preparation field, and in particular to a kind of environment-friendly water-based paint and preparation method thereof.Its raw material composition is calculated as by weight, 50 60 parts of aqueous polyurethane dispersion, 15 20 parts of acrylic acid ester emulsion, 20 35 parts of pure water, 58 parts of auxiliary agent, 10 15 parts of modified carbon nano tube fiber, 57 parts of hydroxypropul starch, modified 35 parts of tea stalk powder, 5 10 parts of water dispersible pigment.The present invention adds the wearability of water paint by adding modified carbon nano tube fiber；The addition of hydroxypropul starch so that water paint has certain anti-flammability；The addition of modified tea stalk powder, is conducive to increase the adhesive force of water paint；Obtained water paint environmental protection, filming performance, wearability are good, there is preferable glossiness, are suitable for Christmas ball japanning.
Description
Technical field
The invention belongs to coating preparation field, and in particular to a kind of environment-friendly water-based paint and preparation method thereof.
Background technology
Christmas ball is usually used polystyrene resin and is fabricated to sphere for primary raw material, and then sphere is baked again
Paint, colouring, are allowed to that various colors are presented.During existing Christmas ball baking vanish, finishing coat is using acrylic lacquer, by third
Olefin(e) acid resin and various volatile organic solvents composition, have air certain pollution, and highly inflammable.Priming paint then be alcohol
Sour varnish, is made of alkyd resin and organic solvent, and water body and air can be polluted；And inflammable, its steam and air
Explosive mixture is easily formed, meets high fever, naked light, strong oxidizer easily causes burning.
Although traditional water paint environmental protection, filming performance is poor, gloss difference, wears no resistance, and defoaming is difficult.
The content of the invention
It is an object of the invention to the deficiency for existing water paint, there is provided a kind of environment-friendly water-based paint and preparation method thereof.
The water paint filming performance, wearability are good, there is preferable glossiness, are suitable for Christmas ball japanning.
To achieve the above object, the present invention adopts the following technical scheme that：
A kind of environment-friendly water-based paint, its raw material composition are calculated as by weight, 50-60 parts of aqueous polyurethane dispersion, acrylic acid
15-20 parts of ester lotion, 30-35 parts of pure water, 5-8 parts of auxiliary agent, 10-15 parts of modified carbon nano tube fiber, 5-7 parts of hydroxypropul starch, change
3-5 parts of tea stalk powder of property, 5-10 parts of water dispersible pigment.
Preferably, environment-friendly water-based its raw material of paint composition is calculated as by weight, 58 parts of aqueous polyurethane dispersion, acrylate
17 parts of lotion, 35 parts of pure water, 8 parts of auxiliary agent, 13 parts of modified carbon nano tube fiber, 6 parts of hydroxypropul starch, modified 4 parts of tea stalk powder, moisture
Dissipate 7 parts of property pigment.
The preparation method of the modified carbon nano tube fiber is：The cetomacrogol 1000-1500 of 0.4-0.6 g is dissolved in
In 40-50 ml pure water, ultrasonic disperse 15-20 min, make its dispersion liquid that is uniformly dispersed to obtain；0.3- is then added in dispersion liquid
0.5 g carbon nano-fibers, are stirred 12 h, polyethylene glycol is substantially adhered to carbon nano-fiber surface, and obtained carbon modified is received
Rice fiber.
The preparation method of the modification tea stalk powder is：Dry tea stalk powder is added in high-speed mixer, 80-90 DEG C
Under be stirred, add the coupling agent of tea stalk powder weight 1-2%, stir 5-6min, up to the tea stalk powder after activating.
A kind of method for preparing environment-friendly water-based paint as described above, concretely comprises the following steps：
1）Aqueous polyurethane dispersion, acrylic acid ester emulsion and portion of pure water are put into mixer, mixing speed is
500-700r/min, stirs 10-15min；
2）Under 500-700r/min states, auxiliary agent, hydroxypropul starch are added, stirs 12-15min；
3）Then proceed to add modified carbon nano tube fiber, modified tea stalk powder and water dispersible pigment, in 1200-1500r/
Min disperses 20-30min；
4）Remaining pure water is eventually adding, 10-15min is stirred with 500-700r/min；Then censorship, packaging.
A kind of application of environment-friendly water-based paint as described above：For Christmas ball japanning.
The beneficial effects of the present invention are：
1）The present invention adds the wearability of water paint by adding modified carbon nano tube fiber；The addition of hydroxypropul starch,
So that water paint has certain anti-flammability；The addition of modified tea stalk powder, is conducive to increase the adhesive force of water paint, adsorbs air
In formaldehyde；Obtained water paint environmental protection, filming performance, wearability are good, have preferable glossiness, are suitable on Christmas ball
Paint；
2）Using the one-dimentional structure, physics and chemical property of carbon nano-fiber uniqueness, make itself and hydroxypropul starch, modified tea
Obstruct powder, aqueous polyurethane dispersion and acrylic acid ester emulsion collective effect, produce synergistic function；Environment protecting is prominent,
Strong adhesive force on Christmas ball, wear-resisting, decorative effect is good.
Embodiment
In order to make content of the present invention easily facilitate understanding, with reference to embodiment to of the present invention
Technical solution is described further, but the present invention is not limited only to this.
Embodiment 1
A kind of environment-friendly water-based paint, its raw material composition are calculated as by weight, 50 parts of aqueous polyurethane dispersion, acrylate breast
20 parts of liquid, 30 parts of pure water, 8 parts of auxiliary agent, 10 parts of modified carbon nano tube fiber, 7 parts of hydroxypropul starch, modified 3 parts of tea stalk powder, moisture dissipate
10 parts of pigment of property.
The preparation method of the modified carbon nano tube fiber is：The cetomacrogol 1000 of 0.5 g is dissolved in 45 ml pure water
In, 17 min of ultrasonic disperse, makes its dispersion liquid that is uniformly dispersed to obtain；0.4 g carbon nano-fibers are then added in dispersion liquid, are stirred
12 h are mixed, polyethylene glycol is substantially adhered to carbon nano-fiber surface, modified carbon nano tube fiber is made.
The preparation method of the modification tea stalk powder is：Dry tea stalk powder is added in high-speed mixer, at 85 DEG C
It is stirred, adds the coupling agent of tea stalk powder weight 1%, stir 5min, up to the tea stalk powder after activation.
A kind of method for preparing environment-friendly water-based paint as described above, concretely comprises the following steps：
1）Aqueous polyurethane dispersion, acrylic acid ester emulsion and portion of pure water are put into mixer, mixing speed is
600r/min, stirs 12min；
2）Under 700r/min states, auxiliary agent, hydroxypropul starch are added, stirs 14min；
3）Then proceed to add modified carbon nano tube fiber, modified tea stalk powder and water dispersible pigment, disperse in 1200r/min
30min；
4）Remaining pure water is eventually adding, 13min is stirred with 600r/min；Then censorship, packaging.
A kind of application of environment-friendly water-based paint as described above：For Christmas ball japanning.
Embodiment 2
A kind of environment-friendly water-based paint, its raw material composition are calculated as by weight, 58 parts of aqueous polyurethane dispersion, acrylate breast
17 parts of liquid, 35 parts of pure water, 8 parts of auxiliary agent, 13 parts of modified carbon nano tube fiber, 6 parts of hydroxypropul starch, modified 4 parts of tea stalk powder, moisture dissipate
7 parts of pigment of property.
The preparation method of the modified carbon nano tube fiber is：The polyethylene glycol 1500 of 0.4 g is dissolved in 50 ml pure water
In, 20 min of ultrasonic disperse, makes its dispersion liquid that is uniformly dispersed to obtain；0.3 g carbon nano-fibers are then added in dispersion liquid, are stirred
12 h are mixed, polyethylene glycol is substantially adhered to carbon nano-fiber surface, modified carbon nano tube fiber is made.
The preparation method of the modification tea stalk powder is：Dry tea stalk powder is added in high-speed mixer, at 90 DEG C
It is stirred, adds the coupling agent of tea stalk powder weight 1%, stir 6min, up to the tea stalk powder after activation.
A kind of method for preparing environment-friendly water-based paint as described above, concretely comprises the following steps：
1）Aqueous polyurethane dispersion, acrylic acid ester emulsion and portion of pure water are put into mixer, mixing speed is
500r/min, stirs 15min；
2）Under 500r/min states, auxiliary agent, hydroxypropul starch are added, stirs 15min；
3）Then proceed to add modified carbon nano tube fiber, modified tea stalk powder and water dispersible pigment, disperse in 1500r/min
20min；
4）Remaining pure water is eventually adding, 10min is stirred with 700r/min；Then censorship, packaging.
A kind of application of environment-friendly water-based paint as described above：For Christmas ball japanning.
Embodiment 3
A kind of environment-friendly water-based paint, its raw material composition are calculated as by weight, 60 parts of aqueous polyurethane dispersion, acrylate breast
15 parts of liquid, 35 parts of pure water, 5 parts of auxiliary agent, 15 parts of modified carbon nano tube fiber, 5 parts of hydroxypropul starch, modified 5 parts of tea stalk powder, moisture dissipate
5 parts of pigment of property.
The preparation method of the modified carbon nano tube fiber is：The polyethylene glycol 1500 of 0.6 g is dissolved in 50 ml pure water
In, 20 min of ultrasonic disperse, makes its dispersion liquid that is uniformly dispersed to obtain；0.5 g carbon nano-fibers are then added in dispersion liquid, are stirred
12 h are mixed, polyethylene glycol is substantially adhered to carbon nano-fiber surface, modified carbon nano tube fiber is made.
The preparation method of the modification tea stalk powder is：Dry tea stalk powder is added in high-speed mixer, at 80 DEG C
It is stirred, adds the coupling agent of tea stalk powder weight 2%, stir 6min, up to the tea stalk powder after activation.
A kind of method for preparing environment-friendly water-based paint as described above, concretely comprises the following steps：
1）Aqueous polyurethane dispersion, acrylic acid ester emulsion and portion of pure water are put into mixer, mixing speed is
700r/min, stirs 10-15min；
2）Under 700r/min states, auxiliary agent, hydroxypropul starch are added, stirs 12min；
3）Then proceed to add modified carbon nano tube fiber, modified tea stalk powder and water dispersible pigment, disperse in 1500r/min
20min；
4）Remaining pure water is eventually adding, 10min is stirred with 700r/min；Then censorship, packaging.
A kind of application of environment-friendly water-based paint as described above：For Christmas ball japanning.
The foregoing is merely presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with
Modification, should all belong to the covering scope of the present invention.
Claims (2)
- A kind of 1. preparation method of environment-friendly water-based paint on Christmas ball, it is characterised in that：Its original of the environment-friendly water-based paint Material composition is calculated as by weight, and 50-60 parts of aqueous polyurethane dispersion, 15-20 parts of acrylic acid ester emulsion, 30-35 parts of pure water, help 5-8 parts of agent, 10-15 parts of modified carbon nano tube fiber, 5-7 parts of hydroxypropul starch, modified 3-5 parts of tea stalk powder, water dispersible pigment 5- 10 parts；The preparation method of the modified carbon nano tube fiber is：The cetomacrogol 1000-1500 of 0.4-0.6 g is dissolved in 40-50 In ml pure water, ultrasonic disperse 15-20 min, make its dispersion liquid that is uniformly dispersed to obtain；0.3-0.5 g carbon is then added in dispersion liquid Nanofiber, is stirred 12 h, polyethylene glycol is substantially adhered to carbon nano-fiber surface, and modified carbon nano tube fiber is made；The preparation method of the modification tea stalk powder is：Dry tea stalk powder is added in high-speed mixer, at 80-90 DEG C into Row stirring, adds the coupling agent of tea stalk powder weight 1-2%, stirs 5-6min, the tea stalk powder activate to obtain the final product after；Its preparation method concretely comprises the following steps：1）Aqueous polyurethane dispersion, acrylic acid ester emulsion and portion of pure water are put into mixer, mixing speed 500- 700r/min, stirs 10-15min；2）Under 500-700r/min states, auxiliary agent, hydroxypropul starch are added, stirs 12-15min；3）Then proceed to add modified carbon nano tube fiber, modified tea stalk powder and water dispersible pigment, at 1200-1500r/min points Dissipate 20-30min；4）Remaining pure water is eventually adding, 10-15min is stirred with 500-700r/min；Then censorship, packaging.
- 2. the preparation method of the environment-friendly water-based paint according to claim 1 on Christmas ball, it is characterised in that：Described Environment-friendly water-based its raw material of paint composition is calculated as by weight, 58 parts of aqueous polyurethane dispersion, 17 parts of acrylic acid ester emulsion, pure water 35 Part, 8 parts of auxiliary agent, 13 parts of modified carbon nano tube fiber, 6 parts of hydroxypropul starch, modified 4 parts of tea stalk powder, 7 parts of water dispersible pigment.
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| CN201610371124.XA CN105802477B (en) | 2016-05-31 | 2016-05-31 | A kind of environment-friendly water-based paint and preparation method thereof |
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| CN105802477B true CN105802477B (en) | 2018-05-04 |
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| CN106280951B (en) * | 2016-08-25 | 2017-10-03 | 阜阳富瑞雪化工科技有限公司 | A kind of high-quality furniture water paint |
| CN106243964A (en) * | 2016-08-25 | 2016-12-21 | 阜阳富瑞雪化工科技有限公司 | A kind of furniture water paint with refreshment effect |
| CN106833344A (en) * | 2016-12-13 | 2017-06-13 | 苏州赛斯德工程设备有限公司 | A kind of water nano anticorrosive paint and preparation method thereof |
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| CN109096900A (en) * | 2018-07-20 | 2018-12-28 | 张军 | A kind of environment-friendly water-based woodcare paint |
| CN109666352A (en) * | 2018-11-22 | 2019-04-23 | 河北晨阳工贸集团有限公司 | A kind of water paint and preparation method thereof for door and window |
| CN110982321A (en) * | 2019-12-02 | 2020-04-10 | 中山市恒美油墨涂料有限公司 | A water-based two-component automotive interior paint |
| CN111100215A (en) * | 2019-12-30 | 2020-05-05 | 河南新孚望新材料科技有限公司 | Preparation method of hydroxypropyl high amylose starch for water-based paint |
| CN111393929A (en) * | 2020-04-01 | 2020-07-10 | 郑州熙虎科技有限公司 | Environment-friendly water-based paint for historic building |
| CN112343262A (en) * | 2020-07-14 | 2021-02-09 | 青岛悦浪建筑技术有限责任公司 | Self-repairing waterproof coiled material connecting part structure and interface waterproof adhesive coating for connection of self-repairing waterproof coiled material connecting part structure |
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| CN104130640A (en) * | 2014-08-28 | 2014-11-05 | 漳州鑫展旺化工有限公司 | Ultralong-weathering baking varnish and preparation method thereof |
| CN104403540A (en) * | 2014-12-10 | 2015-03-11 | 成都拜迪新材料有限公司 | High-gloss aqueous modified polyurethane finish coat and preparation method thereof |
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| CN105802477A (en) | 2016-07-27 |
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