CN105908287A - Method for preparing novel efficient antibacterial fiber - Google Patents

Method for preparing novel efficient antibacterial fiber Download PDF

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Publication number
CN105908287A
CN105908287A CN201610451140.XA CN201610451140A CN105908287A CN 105908287 A CN105908287 A CN 105908287A CN 201610451140 A CN201610451140 A CN 201610451140A CN 105908287 A CN105908287 A CN 105908287A
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Prior art keywords
oil
fibre
antibacterial
fiber
oils
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CN201610451140.XA
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Chinese (zh)
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金利芬
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Priority to CN201610451140.XA priority Critical patent/CN105908287A/en
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Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F11/00Chemical after-treatment of artificial filaments or the like during manufacture
    • D01F11/04Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers
    • D01F11/08Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/096Humidity control, or oiling, of filaments, threads or the like, leaving the spinnerettes
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/253Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F11/00Chemical after-treatment of artificial filaments or the like during manufacture
    • D01F11/02Chemical after-treatment of artificial filaments or the like during manufacture of cellulose, cellulose derivatives, or proteins
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F11/00Chemical after-treatment of artificial filaments or the like during manufacture
    • D01F11/04Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers
    • D01F11/06Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Artificial Filaments (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a method for preparing a novel efficient antibacterial fiber. An antibacterial agent and spinning oil are mixed well according a specified ratio, the fiber passes through the mixed antibacterial oil agent in the forming process, the surface of the fiber is wrapped by a layer of antibacterial oil agent, and the novel efficient antibacterial fiber is prepared. The antibacterial oil agent is directly fed in multiple modes in the processing and moving processes of the fiber and evenly smeared to the surface of the fiber, environment friendliness and zero pollution are achieved, no process is added, the production cost and the labor cost are reduced, a good antibacterial effect is achieved, and good economic benefits are achieved.

Description

A kind of new and effective anti-bacterial fibre preparation method
Technical field
The present invention relates to field of textile industry, particularly relate to the preparation method of a kind of anti-bacterial fibre.
Background technology
Current anti-bacterial fibre anti-microbial property is more weak, particularly with other fiber blends such as cotton, viscoses or mixed knit The anti-bacterial fibre used, when other fiber content superelevation 60wt% such as cottons, fabric is almost without antibacterial effect. Fabrics as many in natural fiber content such as the cottons that people are liked, especially underwear, trousers, socks, home textile etc., The content of its natural fiber almost reaches to 80wt%.Current anti-bacterial fibre is extremely difficult to good antibacterial effect; The woven component ratio of such as regular sock is 80wt% cotton, 20wt% existing anti-bacterial fibre spandex covered yarn, The antibacterial effect of its foot fungus (Candida albicans) is almost 0.Therefore, the antibacterial green wood of good anti-bacterial effect Material becomes current research and development focus.
But current anti-bacterial fibre technique is all to implant fibrous inside by the way of blended, or the side of plating Formula plating last layer is silver-colored, or the mode of dyeing sticks to fiber surface.But these process energy consumptions are lost the most too Greatly, the marketing of antimicrobial technology it is unfavorable for.
Summary of the invention
It is an object of the invention to overcome above-mentioned the deficiencies in the prior art, disclose a kind of new and effective antibacterial fibre Dimension preparation method, antibacterial mixes according to the specified ratio with spinning oil, warp during fiberizing Crossing this antibacterial oil preparation mixed, fiber surface has just wrapped up one layer of antibacterial oil preparation, just prepares a kind of novel height Effect anti-bacterial fibre, the present invention can fiber during working motion by the way of different on antibacterial oil preparation, And uniform application is at fiber surface, environmental protection is pollution-free, without increasing technique, reduces into product cost with artificial Cost, has good antibacterial effect, has good economic benefit.
In order to achieve the above object, the technical scheme is that the preparation of a kind of new and effective anti-bacterial fibre Method, antibacterial is to oil by the way of spinning or tow oil during working motion, makes antibacterial Uniform application is at fiber surface.
Arrange further, the mode of oil agent spins on oil before being, drawing-off oils, add bullet oils, wind oil, Debatching oils, and can an independent link oil, it is possible to oiled by multiple links;
Arrange further, the main component of antibacterial as can be preferably silver ion, copper ion, zinc ion, Deng metallic element class, it is also possible to for quaternary ammonium salt, it is also possible to for polysaccharide, it is also possible to resist for organic or inorganic Microbial inoculum, or the complex of above-mentioned several main component.
Arranging further, in oil agent technique, antibacterial can individually oil, it is also possible to oil preparation or other Auxiliary agent is deployed to oil together;
Arrange further, oil mass on antibacterial, can be at the fibre weight ratio of 0.0001wt%-50wt%.
Arrange further, described fiber, comprise polyester fiber, polypropylene fibre, Fypro, gather Independent or compound chemical fibre and the fibres such as vinyl fiber, PET-PE composite fibre, PP-PE composite fibre The regenerated fibers such as cellulose fiber;Fibre morphology can be long filament or short-term, and fibre section shape can be circle Shape, flat, the most compound, cross, the special-shaped character such as W, CC.
Beneficial effects of the present invention: the present invention be fiber during working motion in several ways on anti- Bacterium oil preparation, and uniform application is at fiber surface, environmental protection is pollution-free, without increasing technique, reduces into and produces into Basis and cost of labor, have good antibacterial effect, have good economic benefit.
Accompanying drawing illustrates:
Fig. 1 is the schematic diagram that fiber oils in spinning process;
Fig. 2 is that tow oils through oil nozzle in the course of processing, oil tanker oils, on the mode antibacterial of oil groove Oil schematic diagram.
In figure: fiber 1, oil nozzle 2, winding 3, oil tanker 4.
Detailed description of the invention
Below by embodiment and combine accompanying drawing, technical scheme is further described in detail.
A kind of new and effective anti-bacterial fibre preparation method, as shown in Figure 1 and Figure 2: described fiber 1 is to add Antibacterial in the mode that labour movement oils through oil nozzle 2 during moving, oil tanker 4 oils, uniform application is at fiber Surface, preparation process environmental protection of the present invention is pollution-free, without increasing technique, reduces into product cost and manually becomes This, have good antibacterial effect, have good economic benefit.
The mode of oil agent spins on oil before being, drawing-off oils, add bullet oils, wind oil, debatching oils, Can an independent link oil, it is possible to oiled by multiple links;
The main component of antibacterial as can be preferably silver ion, copper ion, zinc ion, etc. metallic element Class, it is also possible to for quaternary ammonium salt, it is also possible to for polysaccharide, it is also possible to for organic or inorganic antibacterial, or It it is the complex of above-mentioned several main component.
In oil agent technique, antibacterial can individually oil, it is also possible to together with deployed with oil preparation or other auxiliary agents Oil;
Oil mass on antibacterial, can be at the fibre weight ratio of 0.0001wt%-50wt%.
Described fiber, comprises polyester fiber, polypropylene fibre, Fypro, polyethylene fibre, PET-PE The regeneration fibre such as chemical fibre that composite fibre, PP-PE composite fibre etc. are independent or compound and cellulose fibre Dimension;Fibre morphology can be long filament or short-term, and fibre section shape can be circular, flat, multiple side by side The abnormity character such as conjunction, cross, W, CC.
Embodiment 1
Chemical fibre in the present embodiment is PFY, and oiling method is that Fig. 1 fiber resists at spinning process Microbial inoculum oils.
The part by weight weighing silver-series antibacterial agent and front spin oil preparation and water is: 5:1:4, reconciles into miscible oil, Oiling with oil nozzle and be connected, other are constant with conventional spinning technique.Thus it is made for antibacterial polyester fibre. The antimicrobial levels of this fiber is 0.1wt%.Fibre section is flat.
Single jersey is made by large circle machine with this anti-bacterial fibre, after washing 100 times, this golden yellow Portugal of single jersey bacteriostasis rate Grape coccus > 99%, colibacillus > 99%, Candida albicans > 95%, anti-microbial property far surpasses GB/T20944.3 mark Accurate.
Embodiment 2
Chemical fibre in the present embodiment is polypropylene, and oiling method is that Fig. 1 fiber is at spinning process antibacterial Oil.
Keep existing oil circuit and spinning oil constant.A row is added again above or below existing oil nozzle oils Oil nozzle oils, and oils at the oil nozzle newly the added inner direct silver-series antibacterial agent that oils, and upper speed oil is adjusted to spinning oil The half of agent;Or it is that 1:1 oils in the oil ratio of inner silver-series antibacterial agent and water of the oil nozzle newly added, on Speed oil is adjusted to as spinning oil speed.Other are constant with conventional spinning technique.Thus it is made for Antibacterial polypropylene fiber.The antimicrobial levels of this fiber is 0.05wt%.Fibre section is the most compound.
Single jersey is made by large circle machine with this anti-bacterial fibre, after washing 100 times, this golden yellow Portugal of single jersey bacteriostasis rate Grape coccus > 99%, colibacillus > 99%, Candida albicans > 97%, anti-microbial property far surpasses GB/T20944.3 mark Accurate.
Embodiment 3
Chemical fibre in the present embodiment is PET-PE long filament, and oiling method is that Fig. 1 fiber is at spinning process Antibacterial oils.
Weigh chitosan or chitin (polysaccharide) antibacterial with the part by weight spinning oil preparation and water be: 2:1:7, Reconciling into miscible oil, oiling with oil nozzle is connected, and other are constant with conventional spinning technique.Thus make Antibacterial ES fiber, the antimicrobial levels of this ES fiber is 0.005wt%.Fibre section is skin-core structure.
Non-woven fabrics is made by hot blast with this antibacterial ES fiber, white by medical antibacterial standard GB15979 mono-hour Color reads coccus sterilizing rate > 99.9%.
Embodiment 4
Chemical fibre in the present embodiment is that polyester DTY adds elater, and oiling method is that Fig. 2 fiber is in drawing-off Front oil through the oil tanker antibacterial that oils.
First before drawing of fiber, add one group of oil tanker to oil, weigh silver ion be main multicomponent complex antimicrobials with The part by weight of water is: 1:1, reconciles into miscible oil, and the pipeline oiled with oil tanker is connected, and oil tanker oils Rotating speed is 35 turns/min, and other are constant with conventional DTY texturing craft.Thus it is made for antibacterial polyester DTY Adding elater, this antimicrobial levels adding elater is 0.025wt%.Fibre section is typical circular.
It is made spandex covered yarn with this anti-bacterial fibre, then is made quilted stockings with this wrap yarn, after washing 50 times, should Quilted stockings bacteriostasis rate staphylococcus aureus > 99%, colibacillus > 97%, Candida albicans > 97%, anti-microbial property is remote Super FZ/T73023-2006AAA superlative degree standard.
Embodiment 5
Chemical fibre in the present embodiment is that chinlon DTY adds elater, and oiling method is that Fig. 1 fiber is at spray webbing The while that process and Fig. 2 fiber being before drawing-off, antibacterial oils.
The part by weight weighing silver-series antibacterial agent and front spin oil preparation and water is: 2:1:7, reconciles into miscible oil, Oiling with oil nozzle and be connected, other are constant with spinning spinning technique before routine.After drawing-off adds bullet, then weigh silver Series antibacterial agent with after spin oil preparation part by weight and be: 1:1, reconcile into miscible oil, be directly added into elasticizer oil tanker In oiling, the oil tanker rotating speed that oils is original 2 times, and other are constant with conventional texturing craft, thus make Antibacterial DTY has been become to add elater.This antimicrobial levels adding elater is 0.3wt%.Fibre section is W word abnormity.
It is made spandex covered yarn with this anti-bacterial fibre, then is made quilted stockings with this wrap yarn, after washing 50 times, should Quilted stockings bacteriostasis rate staphylococcus aureus > 99%, colibacillus > 99%, Candida albicans > 98%, anti-microbial property is remote Super FZ/T73023-2006 AAA superlative degree standard.
Embodiment 6
Chemical fibre in the present embodiment is DTY color spinning, and oiling method is that Fig. 1 fiber is at spinning process The while of with Fig. 2 fiber after drawing, antibacterial oils.
The part by weight weighing zinc series antibacterial agent and front spin oil preparation and water is: 8:1:1, reconciles into miscible oil, Oiling with oil nozzle and be connected, other are constant with conventional color spinning fore-spinning.After drawing-off adds bullet, then weigh Zinc series antibacterial agent with after spin oil preparation part by weight and be: 2:1, reconcile into miscible oil, be directly added into elasticizer oil In wheel oils, the oil tanker rotating speed that oils is original 3 times, and other are constant, thus with conventional texturing craft It is made for antibacterial DTY color spinning.The antimicrobial levels of this color spinning is 0.5wt%.Fibre section is that cross is different Shape.
It is made screen cloth with this anti-bacterial fibre, after washing 50 times, this screen cloth bacteriostasis rate staphylococcus aureus > 99%, Colibacillus > 99%, Candida albicans > 98%, anti-microbial property far surpasses FZ/T73023-2006 AAA superlative degree mark Accurate.
Embodiment 7
Chemical fibre in the present embodiment is DTY color silk, and oiling method is that Fig. 2 fiber passes through after drawing The oil tanker antibacterial that oils oils.
After DTY has contaminated color, unwinding process or be processed into other products unwinding winding process (as cladding Silk) add one group of oil tanker on equipment and oil, the part by weight weighing the antibacterial of quaternary ammonium salt and water is: 1:1, Reconciling into miscible oil, during addition oil tanker oils, the rotating speed that oil tanker oils is 30 turns/min, and other unwind volume Winding technologe is constant.Thus it is made for antibacterial DTY color silk.The antimicrobial levels of this color spinning is 0.01wt%.
It is made spandex covered yarn with this anti-bacterial fibre, then is made seamless underwear with this wrap yarn, after washing 50 times, This quilted stockings bacteriostasis rate staphylococcus aureus > 99%, colibacillus > 99%, Candida albicans > 99%, anti-microbial property Remote super FZ/T73023-2006 AAA superlative degree standard.
Embodiment 8
Chemical fibre in the present embodiment is chinlon/spandex cladding wire, and oiling method is that Fig. 2 fiber is at winding Oil through the oil tanker antibacterial that oils.
After processing chinlon/spandex cladding wire, unwinding winding process equipment adds one group of oil tanker and oils, weigh The part by weight of the antibacterial and water of quaternary ammonium salt is: 1:1, reconciles into miscible oil, during addition oil tanker oils, The rotating speed that oil tanker oils is 10 turns/min, and other unwinding winding process are constant.Thus be made for antibacterial nylon/ Polyurethane covered yarn.The antimicrobial levels of this color spinning is 0.01wt%.
Silk stocking are made with this antibacterial nylon/polyurethane covered yarn, after washing 20 times, this golden yellow Portugal of silk stocking bacteriostasis rate Grape coccus > 99%, colibacillus > 99%, Candida albicans > 99%, anti-microbial property far surpasses FZ/T73023-2006 AA。
Embodiment 9
Cellulose fibre in the present embodiment is viscose, oiling method be Fig. 2 fiber in drawing-off through oil tanker The antibacterial that oils oils.
After viscose shapes, winding process equipment adds one group of oil tanker and oils, weigh the antibacterial of silver system, Being directly added into during oil tanker oils, the rotating speed that oil tanker oils is 40 turns/min, and other winding process are constant.So Just it is made for antibacterial viscose.The antimicrobial levels of this viscose is 0.06wt%.
With this viscose spun yarn, then make elastic polyurethane fiber fabric, then underwear is made in cutting, after washing 50 times, This underwear bacteriostasis rate staphylococcus aureus > 99%, colibacillus > 99%, Candida albicans > 99%, anti-microbial property The AAA level that remote super FZ/T73023-2006 specifies.
Ultimate principle and the principal character of the present invention, and advantages of the present invention have more than been shown and described.This The technical staff of industry is also aware that, the present invention is not limited by above-mentioned case study on implementation, above-mentioned case study on implementation and saying The principle that the present invention is simply described described in bright book, under connect meter category premise without departing from the present invention, this Invention also has various changes and modifications, and these changes and improvements both fall within scope of the claimed invention. Claimed scope is defined by appending claims and equivalent thereof.

Claims (5)

1. a new and effective anti-bacterial fibre preparation method, it is characterized in that: described fiber (1) be oil (2) through oil nozzle during working motion, oil tanker oil (4) mode on antibacterial, uniform application at fiber surface, after be wound (3).
A kind of new and effective anti-bacterial fibre preparation method, it is characterized in that: the mode of oil agent spins on oil before being, drawing-off oils, add bullet oils, wind oil, debatching oils, can an independent link oil, it is possible to oiled by multiple links.
A kind of new and effective anti-bacterial fibre preparation method, it is characterised in that: in oil agent technique, antibacterial can individually oil, it is also possible to oils together with deployed with oil preparation or other auxiliary agents.
A kind of new and effective anti-bacterial fibre preparation method, it is characterised in that: oil mass on antibacterial, can be at the fibre weight ratio of 0.0001wt%-50wt%.
5. a new and effective anti-bacterial fibre preparation method, it is characterized in that: described fiber 1, comprise the regenerated fibers such as independent or compound chemical fibre and cellulose fibre such as polyester fiber, polypropylene fibre, Fypro, polyethylene fibre, PET-PE composite fibre, PP-PE composite fibre;Fibre morphology can be long filament or short-term, and fibre section shape can be circular, flat, the most compound, cross, the special-shaped character such as W, CC.
CN201610451140.XA 2016-06-21 2016-06-21 Method for preparing novel efficient antibacterial fiber Pending CN105908287A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107385533A (en) * 2017-08-29 2017-11-24 德清县利通绢纺塑化有限公司 Thin,tough silk bourette silk weaves multi-functional spinning-drawing machine
CN108950769A (en) * 2018-07-16 2018-12-07 叶剑 A kind of production method of antibacterial polyester low stretch yarn
CN111172737A (en) * 2020-02-28 2020-05-19 浙江康洁丝新材料科技有限公司 Plasma modified grafted antibacterial deodorizing fiber and preparation method and application thereof
CN112853541A (en) * 2019-11-28 2021-05-28 凯泰特种纤维科技有限公司 Composite fiber and preparation method thereof
CN115262216A (en) * 2022-08-29 2022-11-01 赛得利(福建)纤维有限公司 Preparation method of high-whiteness antibacterial viscose fiber

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107385533A (en) * 2017-08-29 2017-11-24 德清县利通绢纺塑化有限公司 Thin,tough silk bourette silk weaves multi-functional spinning-drawing machine
CN108950769A (en) * 2018-07-16 2018-12-07 叶剑 A kind of production method of antibacterial polyester low stretch yarn
CN108950769B (en) * 2018-07-16 2021-04-06 杭州中丽化纤有限公司 Production method of antibacterial polyester low stretch yarn
CN112921462A (en) * 2018-07-16 2021-06-08 叶剑 Production method of improved antibacterial polyester low stretch yarn
CN112853541A (en) * 2019-11-28 2021-05-28 凯泰特种纤维科技有限公司 Composite fiber and preparation method thereof
CN111172737A (en) * 2020-02-28 2020-05-19 浙江康洁丝新材料科技有限公司 Plasma modified grafted antibacterial deodorizing fiber and preparation method and application thereof
CN115262216A (en) * 2022-08-29 2022-11-01 赛得利(福建)纤维有限公司 Preparation method of high-whiteness antibacterial viscose fiber
CN115262216B (en) * 2022-08-29 2024-03-19 赛得利(福建)纤维有限公司 Preparation method of high-whiteness antibacterial viscose fiber

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Application publication date: 20160831