CN105908496A - Process for preparing anti-ultraviolet finishing liquid for wool-cotton fabric - Google Patents
Process for preparing anti-ultraviolet finishing liquid for wool-cotton fabric Download PDFInfo
- Publication number
- CN105908496A CN105908496A CN201610329267.4A CN201610329267A CN105908496A CN 105908496 A CN105908496 A CN 105908496A CN 201610329267 A CN201610329267 A CN 201610329267A CN 105908496 A CN105908496 A CN 105908496A
- Authority
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- Prior art keywords
- liquid
- wool
- ionic liquid
- ultraviolet finishing
- butyl
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- Pending
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- 239000007788 liquid Substances 0.000 title claims abstract description 58
- 239000004744 fabric Substances 0.000 title claims abstract description 34
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- 229920000742 Cotton Polymers 0.000 title abstract description 8
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000002608 ionic liquid Substances 0.000 claims abstract description 26
- 210000002268 wool Anatomy 0.000 claims abstract description 18
- 102000011782 Keratins Human genes 0.000 claims abstract description 16
- 108010076876 Keratins Proteins 0.000 claims abstract description 16
- 238000013329 compounding Methods 0.000 claims abstract description 6
- 241000283898 Ovis Species 0.000 claims description 19
- 150000002500 ions Chemical class 0.000 claims description 19
- 239000000243 solution Substances 0.000 claims description 18
- 240000000902 Diospyros discolor Species 0.000 claims description 17
- 235000003115 Diospyros discolor Nutrition 0.000 claims description 17
- 235000007474 pcego de ndia Nutrition 0.000 claims description 17
- -1 phosphine hydrogen phosphonium ion Chemical class 0.000 claims description 13
- KAIPKTYOBMEXRR-UHFFFAOYSA-N 1-butyl-3-methyl-2h-imidazole Chemical compound CCCCN1CN(C)C=C1 KAIPKTYOBMEXRR-UHFFFAOYSA-N 0.000 claims description 10
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 10
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical group [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims description 6
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 5
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 5
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 5
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 4
- 239000000284 extract Substances 0.000 claims description 4
- 239000000376 reactant Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 150000002460 imidazoles Chemical class 0.000 claims 2
- 238000000034 method Methods 0.000 abstract description 6
- 238000004090 dissolution Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 3
- 150000001413 amino acids Chemical class 0.000 abstract description 2
- 125000002091 cationic group Chemical group 0.000 abstract description 2
- 239000000835 fiber Substances 0.000 abstract description 2
- 230000002427 irreversible effect Effects 0.000 abstract description 2
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 238000002835 absorbance Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- QIVBCDIJIAJPQS-VIFPVBQESA-N L-tryptophane Chemical compound C1=CC=C2C(C[C@H](N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-VIFPVBQESA-N 0.000 description 1
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- QIVBCDIJIAJPQS-UHFFFAOYSA-N Tryptophan Natural products C1=CC=C2C(CC(N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004546 feltproofing Methods 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical group 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/285—Phosphines; Phosphine oxides; Phosphine sulfides; Phosphinic or phosphinous acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/45—Shrinking resistance, anti-felting properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a process for preparing an anti-ultraviolet finishing liquid for a wool-cotton fabric. The process comprises the steps of compounding an ionic liquid, extracting wool keratin, regulating a pH value and the like. Hydrophilic groups of the cationic fraction in a phosphoric ionic liquid used in the process for preparing an anti-ultraviolet finishing liquid for a wool-cotton fabric cause irreversible changes in the fabric, including dissolving part of scale layers and removing edges and corners from scales to expose more active sites on the surface of the wool. In addition, an imidazole ionic liquid has an effect of dissolving to the wool. The two ionic liquids are compounded to cause fast dissolution of the wool, thereby generating a wool keratin solution in which unsaturated amino acids react with cotton fibers to increase the absorptivity of the fabric to ultraviolet rays. Moreover, the ionic liquid is able to dissolve the scales on the surfaces of wool fibers during finishing, thus being conducive to optimizing the shrink-proofing and anti-pilling properties of the wool-cotton fabric.
Description
Technical field
The present invention relates to after-finishing of textile products liquid technical field, be specifically related to a kind of velvet apple fabric anti-ultraviolet finishing liquid
Production technology.
Background technology
Wool keratin contains substantial amounts of unsaturated double-bond with the tryptophan in keratin solution and tyrosine, can cause valency
The transition of electronics, thus increase the yarn absorbance to ultraviolet.Therefore, wool keratin solution is usually used in the anti-of cotton fabric
During ultraviolet performance optimization processes.In wool keratin dressing liquid of the prior art, many employings are swelling containing reducing agent and Pilus Caprae seu Ovis
The acidity of agent or alkaline solution extract keratin, and conventional reducing agent has TGA, sodium pyrosulfite, and conventional Pilus Caprae seu Ovis is molten
Swollen dose is carbamide, zinc chloride, lithium chloride etc..Wool fiber in fabric has absorption in various degree and makees above-mentioned metal ion
With, therefore need substantial amounts of water that fabric is carried out, to reduce the content of metal ion in fabric during washing after arrangement.Change
The technical scheme entered uses ion liquid dissolving Pilus Caprae seu Ovis to extract keratin.CN 105399809 A discloses a kind of Pilus Caprae seu Ovis angle
The extracting method of albumen, wherein uses keratin at compounding ion liquid dissolving Pilus Caprae seu Ovis extraction.But in above-mentioned document not
The solution obtained by ion liquid dissolving keratin directly prepares dressing liquid.
Summary of the invention
It is an object of the invention to overcome defect present in prior art, it is provided that a kind of velvet apple fabric anti-ultraviolet finishing
The production technology of liquid, is directly used in extraction keratin by the ionic liquid to wool scale with dissolution, utilizes ionic liquid
The feature of body stable performance, directly prepares the anti-ultraviolet finishing liquid of velvet apple fabric.
For realizing above-mentioned technique effect, the technical scheme is that the life of a kind of velvet apple fabric anti-ultraviolet finishing liquid
Production. art, it is characterised in that comprise the following steps:
S1: compounding ionic liquid, by imidazole type ion liquid with hypophosphorous acidization three (propyl group alcohol) phosphine hydrogen phosphonium ion liquid according to weight
Amount is than (3～4): the ratio mixing of 1, obtains ionic liquid hybrid solution；
S2: wool keratin extracts, and is immersed in by Pilus Caprae seu Ovis in S1 gained ionic liquid hybrid solution, heated under vacuum to 60
～80 DEG C, insulated and stirred to Pilus Caprae seu Ovis is completely dissolved as ecru liquid；
S3: regulation acid-base value, mixes S2 gained reactant liquor with deionized water, adds pH value regulator, regulate mixed solution pH
Value, to 8～9, prepares velvet apple fabric anti-ultraviolet finishing liquid.
Preferably technical scheme is that described imidazole type ion liquid is 1-butyl-3-Methylimidazole. bromide and 1-butyl-3-
At least one in methyl imidazolium tetrafluoroborate.
Preferably technical scheme is that described imidazole type ion liquid is by 1-butyl-3-Methylimidazole. bromide and 1-butyl-3-
Methyl imidazolium tetrafluoroborate mixes, and in imidazole type ion liquid, the weight ratio of 1-butyl-3-Methylimidazole. bromide is 30
～40%.
Preferably technical scheme is that in S2, the weight ratio of Pilus Caprae seu Ovis and ionic liquid hybrid solution is 1:(10～15).
Preferably technical scheme is, in S3, the addition of deionized water is (60 with the weight ratio of S2 gained ecru liquid
～100): 1.
Preferably technical scheme is that pH value regulator is sodium bicarbonate or disodium hydrogen phosphate.
Advantages of the present invention and having the beneficial effects that:
The hydrophilic radical of the phosphonium ion liquid cationic part in the present invention makes fabric that irreversible change to occur, and dissolves squama
A part in lamella and eliminate scale corner angle, exposes more wool surfaces avtive spot, and imidazole type ion liquid pair
Pilus Caprae seu Ovis has dissolution, by compounding for the above two ionic liquid rapid solution that can promote Pilus Caprae seu Ovis, prepares wool keratin molten
Liquid, the unsaturated aminoacid in wool keratin solution reacts with cotton fiber, can increase the fabric absorbance to ultraviolet, with
Time, ionic liquid physical ability is dissolved the scale of wool surface, is hence helped to optimize felt proofing and the anti-pilling of velvet apple fabric
Energy.
Detailed description of the invention
Below in conjunction with embodiment, the detailed description of the invention of the present invention is further described.Following example are only used for more
Add and clearly demonstrate technical scheme, and can not limit the scope of the invention with this.
Embodiment 1
For realizing above-mentioned technique effect, in embodiment 1, the production technology of velvet apple fabric anti-ultraviolet finishing liquid comprises the following steps:
S1: compounding ionic liquid, by imidazole type ion liquid with hypophosphorous acidization three (propyl group alcohol) phosphine hydrogen phosphonium ion liquid according to weight
The amount ratio mixing than 3:1, obtains ionic liquid hybrid solution；
S2: wool keratin extracts, and is immersed in by Pilus Caprae seu Ovis in S1 gained ionic liquid hybrid solution, heated under vacuum to 60
DEG C, insulated and stirred to Pilus Caprae seu Ovis is completely dissolved as ecru liquid；
S3: regulation acid-base value, mixes S2 gained reactant liquor with deionized water, adds pH value regulator, regulate mixed solution pH
Value, to 8, prepares velvet apple fabric anti-ultraviolet finishing liquid.
Imidazole type ion liquid is 1-butyl-3-Methylimidazole. bromide.
In S2, the weight ratio of Pilus Caprae seu Ovis and ionic liquid hybrid solution is 1:10.
In S3, the addition of deionized water is 60:1 with the weight ratio of S2 gained ecru liquid.
PH value regulator is sodium bicarbonate.
Embodiment 2
Embodiment 2 is with the difference of embodiment 1:
In S1, imidazole type ion liquid mixes according to the ratio of weight ratio 4:1 with hypophosphorous acidization three (propyl group alcohol) phosphine hydrogen phosphonium ion liquid
Close；
S2 intermediate ion liquid hybrid solution heated under vacuum is to 80 DEG C；
S3 regulates mixed solution pH value to 9；
Imidazole type ion liquid is 1-butyl-3-methyl imidazolium tetrafluoroborate.
In S2, the weight ratio of Pilus Caprae seu Ovis and ionic liquid hybrid solution is 1:15.
In S3, the addition of deionized water is 100:1 with the weight ratio of S2 gained ecru liquid.
PH value regulator is disodium hydrogen phosphate.
Embodiment 3
Embodiment 3 is with the difference of embodiment 1:
In S1, imidazole type ion liquid mixes according to the ratio of weight ratio 7:2 with hypophosphorous acidization three (propyl group alcohol) phosphine hydrogen phosphonium ion liquid
Close；
S2 intermediate ion liquid hybrid solution heated under vacuum is to 70 DEG C；
S3 regulates mixed solution pH value to 8.5；
Imidazole type ion liquid is by 1-butyl-3-Methylimidazole. bromide and the mixing of 1-butyl-3-methyl imidazolium tetrafluoroborate
Becoming, in imidazole type ion liquid, the weight ratio of 1-butyl-3-Methylimidazole. bromide is 30%.
In S2, the weight ratio of Pilus Caprae seu Ovis and ionic liquid hybrid solution is 2:5.
In S3, the addition of deionized water is (60～100) with the weight ratio of S2 gained ecru liquid: 1.
PH value regulator is sodium bicarbonate.
Embodiment 4
Embodiment is with the difference of embodiment 3, and in imidazole type ion liquid, the weight ratio of 1-butyl-3-Methylimidazole. bromide is
40%。
Comparative example
Not containing hypophosphorous acidization three (propyl group alcohol) phosphine hydrogen phosphonium ion liquid in comparative example, other technological parameters are with embodiment 1.
Comparative example Pilus Caprae seu Ovis dissolution velocity is the slowest.
The dressing liquid that the velvet apple fabric of 20 mao of 80 cotton is respectively adopted embodiment 1-4 and comparative example is carried out Final finishing process,
Fabric anti pilling index after embodiment 1-4 processes all reaches 4 grades, and comparative example fabric anti pilling index is 3 grades；Embodiment 3 and 4
UPF value 50+ before fabric uvioresistant index washing after arrangement, UPF value 50+ after washing 20 times, after embodiment 1 and 2 arranges
UPF value 50+ before the washing of fabric uvioresistant index, UPF value 40+ after washing 20 times, the fabric uvioresistant after comparative example arrangement
UPF value 40+ before linear index washing.
It addition, use disodium hydrogen phosphate to increase as pH value regulator, the viscosity of dressing liquid, therefore, pH value regulator is excellent
Elect sodium bicarbonate as.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For Yuan, on the premise of without departing from the technology of the present invention principle, it is also possible to make some improvements and modifications, these improvements and modifications
Also should be regarded as protection scope of the present invention.
Claims (6)
1. the production technology of a velvet apple fabric anti-ultraviolet finishing liquid, it is characterised in that comprise the following steps:
S1: compounding ionic liquid, by imidazole type ion liquid with hypophosphorous acidization three (propyl group alcohol) phosphine hydrogen phosphonium ion liquid according to weight
Amount is than (3～4): the ratio mixing of 1, obtains ionic liquid hybrid solution；
S2: wool keratin extracts, and is immersed in by Pilus Caprae seu Ovis in S1 gained ionic liquid hybrid solution, heated under vacuum to 60
～80 DEG C, insulated and stirred to Pilus Caprae seu Ovis is completely dissolved as ecru liquid；
S3: regulation acid-base value, mixes S2 gained reactant liquor with deionized water, adds pH value regulator, regulate mixed solution pH
Value, to 8～9, prepares velvet apple fabric anti-ultraviolet finishing liquid.
The production technology of velvet apple fabric anti-ultraviolet finishing liquid the most according to claim 1, it is characterised in that described imidazoles
Type ionic liquid is at least one in 1-butyl-3-Methylimidazole. bromide and 1-butyl-3-methyl imidazolium tetrafluoroborate.
The production technology of velvet apple fabric anti-ultraviolet finishing liquid the most according to claim 2, it is characterised in that described imidazoles
Type ionic liquid is mixed by 1-butyl-3-Methylimidazole. bromide and 1-butyl-3-methyl imidazolium tetrafluoroborate, imidazole type
In ionic liquid, the weight ratio of 1-butyl-3-Methylimidazole. bromide is 30～40%.
The production technology of velvet apple fabric anti-ultraviolet finishing liquid the most according to claim 1, it is characterised in that Pilus Caprae seu Ovis in S2
It is 1:(10～15 with the weight ratio of ionic liquid hybrid solution).
The production technology of velvet apple fabric anti-ultraviolet finishing liquid the most according to claim 1, it is characterised in that S3 goes from
The addition of sub-water is (60～100) with the weight ratio of S2 gained ecru liquid: 1.
The production technology of velvet apple fabric anti-ultraviolet finishing liquid the most according to claim 1, it is characterised in that pH value regulates
Agent is sodium bicarbonate or disodium hydrogen phosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610329267.4A CN105908496A (en) | 2016-05-18 | 2016-05-18 | Process for preparing anti-ultraviolet finishing liquid for wool-cotton fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610329267.4A CN105908496A (en) | 2016-05-18 | 2016-05-18 | Process for preparing anti-ultraviolet finishing liquid for wool-cotton fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105908496A true CN105908496A (en) | 2016-08-31 |
Family
ID=56748234
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610329267.4A Pending CN105908496A (en) | 2016-05-18 | 2016-05-18 | Process for preparing anti-ultraviolet finishing liquid for wool-cotton fabric |
Country Status (1)
| Country | Link |
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| CN (1) | CN105908496A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107541928A (en) * | 2017-08-11 | 2018-01-05 | 嘉兴学院 | Ultraviolet irradiation based on keratin oligopeptides, polypeptide or keratin macromolecular is used for nursing and the felt-proofing finishing method of wool fabric |
| CN110106706A (en) * | 2019-05-23 | 2019-08-09 | 叶盛 | A kind of preparation method of modified protein UV resistance finishing agent |
-
2016
- 2016-05-18 CN CN201610329267.4A patent/CN105908496A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107541928A (en) * | 2017-08-11 | 2018-01-05 | 嘉兴学院 | Ultraviolet irradiation based on keratin oligopeptides, polypeptide or keratin macromolecular is used for nursing and the felt-proofing finishing method of wool fabric |
| CN110106706A (en) * | 2019-05-23 | 2019-08-09 | 叶盛 | A kind of preparation method of modified protein UV resistance finishing agent |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160831 |