CN105962007A - Chemical prepared from kaolinite and capable of reducing pesticide residues of fruits and vegetables and using method of chemical - Google Patents
Chemical prepared from kaolinite and capable of reducing pesticide residues of fruits and vegetables and using method of chemical Download PDFInfo
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Abstract
Description
技术领域 technical field
本发明涉及农业,具体涉及用白石脂制备降低果蔬农残的药物及其使用方法,属生物医药技术领域。 The invention relates to agriculture, in particular to a medicine for reducing pesticide residues in fruits and vegetables prepared by using white stone fat and its application method, belonging to the technical field of biomedicine.
技术背景 technical background
农作物的病害如防治不及时造成农作物品质降低,产量下降,严重者甚至绝收,给农业生产带来巨大的损失。农药是农作物种植过程中重要的生产资料之一。在增加产量、减少病害的发生,农药都起着十分重要的作用。但许多农药又是有害物质,在生产和使用中带来了环境污染和农药残留问题。农作物种植过程中,农药的大量使用,造成农残超标,食物中毒事件频繁发生。随着科技发展和生活水平提高,人们对食品安全的要求越来越高。吃上绿色健康食品,已经成为国民共同的呼声。 If the diseases of crops are not prevented and controlled in time, the quality of crops will be reduced, the yield will be reduced, and in severe cases, the harvest will even be lost, which will bring huge losses to agricultural production. Pesticides are one of the important means of production in the process of crop cultivation. Pesticides play a very important role in increasing yield and reducing the occurrence of diseases. However, many pesticides are harmful substances, causing environmental pollution and pesticide residue problems in production and use. In the process of planting crops, a large number of pesticides are used, resulting in excessive pesticide residues and frequent occurrence of food poisoning incidents. With the development of science and technology and the improvement of living standards, people have higher and higher requirements for food safety. Eating green and healthy food has become the common voice of the people.
白石脂为常用中药,具有养肺气,厚肠,补骨髓,疗五脏惊悸不足,心下烦,止腹痛下水,小肠湃,热溏便脓血,女子崩中漏下赤自沃,排痈疽疮痔等功效。经过多次试验我们发现白石脂制成液体后,喷施于农作物后有较好的降低农残作用。 Baishizhi is a commonly used traditional Chinese medicine. It has the functions of nourishing lung qi, thickening intestines, nourishing bone marrow, treating insufficiency of five viscera and palpitations, restlessness in the heart, relieving abdominal pain and water discharge, small intestine pain, hot loose stools with pus and blood, women's metrorrhagia, bleeding from redness, and expelling carbuncles. Sore hemorrhoids and other effects. After many experiments, we found that the white stone resin has a better effect of reducing pesticide residues after it is made into a liquid and sprayed on crops.
发明内容 Contents of the invention
本发明的目的是为了提供一种用白石脂制备降低果蔬农残的药物,对内吸和触杀两大类农药均可大大降低果蔬农药残留量,提高食品的安全性。且用量少,费用低。 The purpose of the present invention is to provide a medicine for reducing pesticide residues in fruits and vegetables prepared by white stone fat, which can greatly reduce pesticide residues in fruits and vegetables for systemic and contact pesticides, and improve food safety. And the dosage is less, and the cost is low.
本发明的目的通过以下技术方案实现: The object of the present invention is achieved through the following technical solutions:
用白石脂制备降低果蔬农残的药物,其特征在于:用白石脂为有效成分制备。 The medicine for reducing pesticide residues in fruits and vegetables is prepared by using white stone resin, which is characterized in that it is prepared by using white stone resin as an active ingredient.
本发明所述的用白石脂制备降低果蔬农残的药物,其特征在于:制成液体加碱性化合物调pH值至大于8。 The medicine for reducing pesticide residues in fruits and vegetables prepared by using white stone fat according to the present invention is characterized in that it is made into a liquid and added with an alkaline compound to adjust the pH value to be greater than 8.
本发明所述的用白石脂制备降低果蔬农残的药物,其特征在于:碱性化合物是氢氧化钠,碳酸钠、碳酸氢钠、碳酸钾、氨等。 The medicine for reducing pesticide residues in fruits and vegetables prepared by using white stone fat according to the present invention is characterized in that: the basic compound is sodium hydroxide, sodium carbonate, sodium bicarbonate, potassium carbonate, ammonia and the like.
本发明所述的用白石脂制备降低果蔬农残的药物,其特征在于:制成液体,按重量百分比计白石脂的含量是8 -20%。 The preparation of the medicament for reducing pesticide residues in fruits and vegetables by using white stone fat according to the invention is characterized in that it is made into a liquid, and the white stone fat content is 8-20% by weight percentage.
本发明所述的用白石脂制备降低果蔬农残的药物的使用方法,其特征在于:使用浓度为水︰药物=100—800︰1,对施用了农药的果蔬,在果蔬采摘或收割前10小时以上喷施,使植物全株充分接触本发明的药液。 The method for using white stone fat to prepare medicines for reducing pesticide residues in fruits and vegetables according to the present invention is characterized in that: the use concentration is water: medicine = 100-800: 1, and the fruits and vegetables to which pesticides have been applied should be prepared 10 days before picking or harvesting the fruits and vegetables. Spray for more than 1 hour, make the whole plant fully contact the liquid medicine of the present invention.
本发明所述的用白石脂制备降低果蔬农残的药物的使用方法,其特征在于:使用浓度为水︰药物=500︰1,对施用了农药的果蔬,在果蔬采摘或收割前24小时以上喷施,使植物全株充分接触本发明的药液。 The method for using white stone fat to prepare medicines for reducing pesticide residues in fruits and vegetables according to the present invention is characterized in that: the use concentration is water: medicine = 500: 1, and the fruits and vegetables to which pesticides have been applied should be harvested more than 24 hours before the fruits and vegetables are picked or harvested. Spray to make the whole plant fully contact with the liquid medicine of the present invention.
本发明所述果蔬,指水果和蔬菜。 Fruits and vegetables in the present invention refer to fruits and vegetables.
至此完成了本发明。 The present invention has been completed thus far.
农药有内吸和触杀两大类。内吸性农药内吸性杀虫、杀菌剂施药后4—5小时便有80%的有效成分能通过植株的根、茎、叶等的吸收进入到组织内部,从而将取食的病菌害虫致死。触杀性农药植株不内吸,药剂接触虫体使害虫致死。 There are two types of pesticides, systemic and contact. 4-5 hours after the application of systemic pesticides, systemic insecticides and fungicides, 80% of the active ingredients can enter the tissue through the absorption of the roots, stems, leaves, etc. of the plant, so that the pathogens and pests that eat lethal. Plants do not absorb contact pesticides systemically, and the pesticides contact the insects to kill the pests.
我们针对不同的果蔬类植物,不同的农药,进行了本发明的降低农残的药物使用方法试验,包括真对内吸和触杀两大类农药施药后使用本发明的时机、使用浓度、使用方法等。经过反复多次的试验,结果使用本发明的药物10小时以后,采摘收割,洗涤后,对内吸和触杀两大类农药均去除率均为80%以上。大大降低了果蔬农药残留量,提高食品的安全性。 For different fruit and vegetable plants and different pesticides, we have carried out the test of the drug application method for reducing pesticide residues of the present invention, including the timing of using the present invention, the concentration of use, and the use of two types of pesticides for systemic and contact killing. method etc. After repeated tests, the results show that after 10 hours of using the medicine of the present invention, after picking and harvesting, after washing, the removal rates of both systemic and contact pesticides are more than 80%. It greatly reduces the amount of pesticide residues in fruits and vegetables and improves the safety of food.
具体实施方式 detailed description
用白石脂制备降低果蔬农残的药物,其特征在于:用白石脂为有效成分制备。 The medicine for reducing pesticide residues in fruits and vegetables is prepared by using white stone resin, which is characterized in that it is prepared by using white stone resin as an active ingredient.
本发明所述的用白石脂制备降低果蔬农残的药物,其特征在于:制成液体加碱性化合物调pH值至大于8。 The medicine for reducing pesticide residues in fruits and vegetables prepared by using white stone fat according to the present invention is characterized in that it is made into a liquid and added with an alkaline compound to adjust the pH value to be greater than 8.
本发明所述的用白石脂制备降低果蔬农残的药物,其特征在于:碱性化合物是氢氧化钠,碳酸钠、碳酸氢钠、碳酸钾、氨等。 The medicine for reducing pesticide residues in fruits and vegetables prepared by using white stone fat according to the present invention is characterized in that: the basic compound is sodium hydroxide, sodium carbonate, sodium bicarbonate, potassium carbonate, ammonia and the like.
本发明所述的用白石脂制备降低果蔬农残的药物,其特征在于:制成液体,按重量百分比计白石脂的含量是8 -20%。 The preparation of the medicament for reducing pesticide residues in fruits and vegetables by using white stone fat according to the invention is characterized in that it is made into a liquid, and the white stone fat content is 8-20% by weight percentage.
本发明所述用白石脂制备降低果蔬农残的药物的使用方法,其特征在于:使用浓度为水︰药物=100—800︰1,对施用了农药的果蔬,在果蔬采摘或收割前10小时以上喷施,使植物全株充分接触本发明的药液。 The use method of the present invention for preparing medicines for reducing pesticide residues in fruits and vegetables with white stone fat is characterized in that: the use concentration is water: medicine = 100-800: 1, and the fruits and vegetables that have been applied with pesticides should be harvested 10 hours before the fruits and vegetables are picked or harvested. More than spraying, the whole plant is fully contacted with the liquid medicine of the present invention.
本发明所述一种降低果蔬农残的药物的使用方法,其特征在于:使用浓度为水︰药物=500︰1,对施用了农药的果蔬,在果蔬采摘或收割前24小时以上喷施,使植物全株充分接触本发明的药液。 A method for using a drug for reducing pesticide residues in fruits and vegetables according to the present invention is characterized in that: the concentration of use is water: drug = 500: 1, and the fruits and vegetables that have been applied with pesticides are sprayed more than 24 hours before the fruits and vegetables are picked or harvested. The whole plant is fully exposed to the medicinal solution of the present invention.
实施例1:Example 1:
取白石脂20kg,加水至100kg,搅拌均匀,用胶体磨充分分散制得降低果蔬农残的乳剂。 Take 20kg of white stone fat, add water to 100kg, stir evenly, and fully disperse with a colloid mill to prepare an emulsion for reducing pesticide residues in fruits and vegetables.
在黄瓜霜霉病发病时,施用了百菌清水乳剂(800倍稀释液),每7天1次,连续喷洒3次。采摘黄瓜前12小时,将黄瓜地块一分为二,一块使用降低果蔬农残的药物液体(200倍液)处理,喷雾器喷至每颗黄瓜全株充分接触本发明的药液。另一块使用清水处理,喷雾器喷至每颗黄瓜全株充分接触清水。收后水洗,百菌清的残留量分别为:使用降低果蔬农残的药物液体(200倍液)处理的为0.37mg/kg,使用清水处理的为2.06mg/kg。与使用清水处理的相比较,使用本发明处理的黄瓜百菌清残留降低了81.7%。 When cucumber downy mildew occurs, chlorothalonil aqueous emulsion (800 times dilution) is applied, once every 7 days, and sprayed 3 times in a row. 12 hours before picking cucumbers, the cucumber plots were divided into two, and one piece was treated with a medicinal liquid (200 times liquid) for reducing pesticide residues in fruits and vegetables, and the sprayer was sprayed until the whole plant of each cucumber was fully exposed to the medicinal liquid of the present invention. The other piece is treated with clean water, and sprayed with a sprayer until the whole plant of each cucumber is fully exposed to clean water. After washing with water after harvesting, the residual amounts of chlorothalonil are: 0.37 mg/kg for those treated with the drug liquid (200 times liquid) for reducing pesticide residues in fruits and vegetables, and 2.06 mg/kg for those treated with clean water. Compared with the treatment with clear water, the residual chlorothalonil of cucumbers treated with the present invention is reduced by 81.7%.
实施例2:Example 2:
取白石脂8kg,加水至100kg,搅拌均匀,用胶体磨充分分散,边搅拌边加入碳酸钠,至pH值为8,得降低果蔬农残的乳剂。 Take 8 kg of white stone fat, add water to 100 kg, stir evenly, fully disperse with a colloid mill, add sodium carbonate while stirring, until the pH value is 8, and obtain an emulsion that reduces pesticide residues in fruits and vegetables.
在黄瓜霜霉病发病时,施用了百菌清水乳剂(800倍液),每7天1次,连续喷洒3次。采摘黄瓜前15小时,将黄瓜地块一分为二,一块使用降低果蔬农残的药物液体(500倍液)处理,喷雾器喷至每颗黄瓜全株充分接触本发明的药液。另一块使用清水处理,喷雾器喷至每颗黄瓜全株充分接触清水。收后水洗,分别化验百菌清的残留量,结果分别为:使用降低果蔬农残的药物液体(500倍液)处理的为0.29mg/kg,使用清水处理的为1.98mg/kg。与使用清水处理的相比较,使用本发明处理的黄瓜百菌清残留降低了85.4%。 When cucumber downy mildew occurs, chlorothalonil aqueous emulsion (800 times liquid) is applied, once every 7 days, and sprayed continuously for 3 times. Fifteen hours before picking cucumbers, the cucumber plots were divided into two, and one piece was treated with a medicinal liquid (500 times liquid) for reducing pesticide residues in fruits and vegetables, and the sprayer was sprayed until the whole plant of each cucumber was fully exposed to the medicinal liquid of the present invention. The other piece is treated with clean water, and sprayed with a sprayer until the whole plant of each cucumber is fully exposed to clean water. After harvesting, wash with water, and test the residual amount of chlorothalonil respectively. The results are: 0.29 mg/kg for the drug liquid (500 times liquid) for reducing pesticide residues in fruits and vegetables, and 1.98 mg/kg for the water. Compared with the treatment with clear water, the residual chlorothalonil of cucumbers treated with the present invention is reduced by 85.4%.
实施例3:Example 3:
取白石脂10kg,加水至100kg,搅拌均匀,用胶体磨充分分散,边搅拌边加入氢氧化钠,至pH值为11,得降低果蔬农残的乳剂。 Take 10kg of white stone fat, add water to 100kg, stir evenly, fully disperse with a colloid mill, add sodium hydroxide while stirring, until the pH value is 11, and obtain an emulsion that reduces pesticide residues in fruits and vegetables.
在小白菜发生菜蚜虫时,施用了倍硫磷(50%乳油50毫升,对水30千克喷雾),采收前20小时,将小白菜地块一分为二,一块使用降低果蔬农残的药物液体(300倍液)处理,喷雾器喷至每颗小白菜全株充分接触本发明的药液。另一块使用清水处理,喷雾器喷至每颗小白菜全株充分接触清水。收后水洗,分别化验倍硫磷的残留量,结果分别为:使用降低果蔬农残的药物液体(300倍液)处理的为0.01mg/kg,使用清水处理的为0.11mg/kg。与使用清水处理的相比较,使用本发明处理的小白菜倍硫磷残留降低了90.9%。 When cabbage aphids occurred in pakchoi, fenthion (50 ml of 50% emulsifiable concentrate, sprayed on 30 kg of water) was applied. 20 hours before harvest, the pakchoi plot was divided into two, and one was used to reduce fruit and vegetable pesticide residues. Medicinal liquid (300 times liquid) is processed, and sprayer is sprayed until the whole plant of every pakchoi is fully contacted with medicinal liquid of the present invention. The other piece is treated with clear water, and the sprayer is sprayed until the whole plant of each pakchoi is fully exposed to clear water. After harvesting, wash with water, and test the residual amount of fenthion respectively. The results are: 0.01 mg/kg treated with the drug liquid (300 times liquid) for reducing pesticide residues in fruits and vegetables, and 0.11 mg/kg treated with clean water. Compared with the treatment with clear water, the fenthion residue in pakchoi treated with the present invention is reduced by 90.9%.
实施例4:Example 4:
取白石脂15kg,加水至100kg,搅拌均匀,用胶体磨充分分散,边搅拌边加入碳酸氢钠,至pH值为11,得降低果蔬农残的乳剂。 Take 15kg of white stone fat, add water to 100kg, stir evenly, fully disperse with a colloid mill, add sodium bicarbonate while stirring, until the pH value is 11, and obtain an emulsion that reduces pesticide residues in fruits and vegetables.
防治油菜温室白粉虱时,施用敌敌畏,用80%乳油1000倍稀释液喷雾,每隔7天喷药1次,连喷3次,采收前72小时,将油菜地块一分为二,一块使用降低果蔬农残的药物液体(100倍液)处理,喷雾器喷至每颗油菜全株充分接触本发明的药液。另一块使用清水处理,喷雾器喷至每颗油菜全株充分接触清水。收后水洗,分别化验敌敌畏的残留量,结果分别为:使用降低果蔬农残的药物液体(100倍液)处理的为0.03mg/kg,使用清水处理的为0.24mg/kg。与使用清水处理的相比较,使用本发明处理的油菜敌敌畏残留降低了87.5%。 When controlling rape greenhouse whitefly, apply dichlorvos, spray with 1000 times dilution of 80% emulsifiable oil, spray once every 7 days, and spray 3 times in a row. 72 hours before harvesting, divide the rape plot into two, one piece Treat with a medicinal liquid (100 times liquid) for reducing pesticide residues in fruits and vegetables, and spray until each rapeseed whole plant is fully exposed to the medicinal liquid of the present invention. The other piece is treated with clear water, and the sprayer is sprayed until the whole plant of each rapeseed is fully exposed to clear water. After harvesting, wash with water, and test the residual amount of dichlorvos respectively. The results are: 0.03 mg/kg treated with the drug liquid (100 times liquid) for reducing pesticide residues in fruits and vegetables, and 0.24 mg/kg treated with clean water. Compared with the treatment with clean water, the residue of dichlorvos in rapeseed treated with the present invention is reduced by 87.5%.
实施例5:Example 5:
取白石脂18kg,加水至100kg,边搅拌边加入碳酸钾,至pH值为9,得防治植物病害的乳剂。 Get 18kg of white stone fat, add water to 100kg, add potassium carbonate while stirring, until the pH value is 9, the emulsion for preventing and controlling plant diseases is obtained.
防治菜花小菜蛾时,用毒死蜱原液1000倍稀释液喷雾1次,采收前72小时,将菜花地块一分为二,一块使用降低果蔬农残的药物液体(800倍液)处理,喷雾器喷至每颗菜花全株充分接触本发明的药液。另一块使用清水处理,喷雾器喷至每颗菜花全株充分接触清水。收后水洗,分别化验毒死蜱的残留量,结果分别为:使用降低果蔬农残的药物液体(800倍液)处理的为0.3mg/kg,使用清水处理的为1.7mg/kg。与使用清水处理的相比较,使用本发明处理的菜花毒死蜱残留降低了82.3%。 When controlling cauliflower diamondback moth, spray once with 1000 times dilution of chlorpyrifos stock solution. 72 hours before harvesting, divide the cauliflower plot into two, and treat one piece with the drug liquid (800 times solution) for reducing pesticide residues in fruits and vegetables, and spray it with a sprayer. Until every cauliflower whole plant fully contacts the medicinal liquid of the present invention. The other piece is treated with clean water, and the sprayer is sprayed until the whole cauliflower plant is fully exposed to clean water. After harvesting, wash with water, and test the residual amount of chlorpyrifos respectively. The results are: 0.3 mg/kg treated with the drug liquid (800 times liquid) for reducing pesticide residues in fruits and vegetables, and 1.7 mg/kg treated with clean water. Compared with the treatment with clear water, the residue of chlorpyrifos in cauliflower treated with the present invention is reduced by 82.3%.
最后所应说明的是,以上实施例仅用以说明本发明的技术方案而非限制,尽管参照实施例对本发明进行了详细说明,本领域的普通技术人员应当理解,可以对发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的精神和范围,其均应涵盖在本发明的权利要求范围当中。 Finally, it should be noted that the above examples are only used to illustrate the technical solutions of the present invention without limitation, although the present invention has been described in detail with reference to the examples, those of ordinary skill in the art should understand that the technical solutions of the invention can be carried out Modifications or equivalent replacements without departing from the spirit and scope of the technical solution of the present invention shall be covered by the claims of the present invention.
蒙脱石是一大族类矿物,经过反复多次的试验研究,我们还发现,不同的蒙脱石制备的药物降低果蔬农残的效果不同,选择方法将另案申请专利。 Montmorillonite is a large family of minerals. After repeated experiments and studies, we also found that the drugs prepared from different montmorillonites have different effects on reducing pesticide residues in fruits and vegetables. The selection method will be applied for a separate patent.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1316282A (en) * | 2000-04-06 | 2001-10-10 | 湖南省植物保护研究所 | Degradating agent for residual agricultural chemicals |
| CN105360284A (en) * | 2015-11-24 | 2016-03-02 | 邱德文 | Biological source fruit and vegetable fresh keeping agent, and preparation method and application thereof |
| CN105473007A (en) * | 2014-07-29 | 2016-04-06 | 韩微科研 | Fruit and vegetable washing machine |
-
2016
- 2016-05-12 CN CN201610310229.4A patent/CN105962007A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1316282A (en) * | 2000-04-06 | 2001-10-10 | 湖南省植物保护研究所 | Degradating agent for residual agricultural chemicals |
| CN105473007A (en) * | 2014-07-29 | 2016-04-06 | 韩微科研 | Fruit and vegetable washing machine |
| CN105360284A (en) * | 2015-11-24 | 2016-03-02 | 邱德文 | Biological source fruit and vegetable fresh keeping agent, and preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 叶定江主编: "《中药炮制学词典》", 30 June 2005, 上海科学技术出版社 * |
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Application publication date: 20160928 |