CN106189608A - Water-soluble flame retardant and application thereof - Google Patents
Water-soluble flame retardant and application thereof Download PDFInfo
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- CN106189608A CN106189608A CN201610534034.8A CN201610534034A CN106189608A CN 106189608 A CN106189608 A CN 106189608A CN 201610534034 A CN201610534034 A CN 201610534034A CN 106189608 A CN106189608 A CN 106189608A
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- Prior art keywords
- water
- flame retardant
- soluble
- agent
- emulsion
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 41
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 239000000839 emulsion Substances 0.000 claims abstract description 22
- 230000000149 penetrating effect Effects 0.000 claims abstract description 19
- 239000002562 thickening agent Substances 0.000 claims abstract description 15
- 239000012796 inorganic flame retardant Substances 0.000 claims abstract description 12
- 239000011230 binding agent Substances 0.000 claims abstract description 9
- 229920002521 macromolecule Polymers 0.000 claims abstract description 9
- 239000002023 wood Substances 0.000 claims abstract description 5
- 239000000835 fiber Substances 0.000 claims abstract description 4
- 239000000470 constituent Substances 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical group [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 235000019353 potassium silicate Nutrition 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 239000004254 Ammonium phosphate Substances 0.000 claims description 3
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 claims description 3
- 239000002174 Styrene-butadiene Substances 0.000 claims description 3
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 3
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 3
- 239000007767 bonding agent Substances 0.000 claims description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 3
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 3
- 229920003063 hydroxymethyl cellulose Polymers 0.000 claims description 3
- 229940031574 hydroxymethyl cellulose Drugs 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011115 styrene butadiene Substances 0.000 claims description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 3
- 229920003169 water-soluble polymer Polymers 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 235000010338 boric acid Nutrition 0.000 claims description 2
- 210000000481 breast Anatomy 0.000 claims description 2
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 235000011007 phosphoric acid Nutrition 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 230000008719 thickening Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 10
- 238000000034 method Methods 0.000 abstract description 7
- 230000008569 process Effects 0.000 abstract description 6
- 238000004078 waterproofing Methods 0.000 abstract description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- -1 phosphate ester Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- KHSLHYAUZSPBIU-UHFFFAOYSA-M benzododecinium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 KHSLHYAUZSPBIU-UHFFFAOYSA-M 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- UDHMTPILEWBIQI-UHFFFAOYSA-N butyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OCCCC)=CC=CC2=C1 UDHMTPILEWBIQI-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- NOLXQSVNNIIHMV-UHFFFAOYSA-L disodium;2,2-diethyl-3-hexyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCC(C([O-])=O)(S(O)(=O)=O)C(CC)(CC)C([O-])=O NOLXQSVNNIIHMV-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09D109/06—Copolymers with styrene
- C09D109/08—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/30—Fireproofing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Forests & Forestry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses a kind of water-soluble flame retardant and application thereof, by weight calculating, be made up of following component: water-soluble inorganic flame retardant 4 30%, aqueous inorganic binding agent 10 40%, the sub-macromolecule emulsion of moisture content 10 30%, thickening agent 1 3%, penetrating agent 1 3%, constituent content sum is 100%.And water-soluble flame retardant is in wood and/or the application of fiber surface.The water-soluble flame retardant of the present invention has flame retardant effect, can be greatly improved disaster relief flameproof effect, and can solve the problem that the durability after material surface process and water proofing property.
Description
Technical field
The present invention relates to a kind of water-soluble flame retardant and application thereof.
Background technology
Wood materials and fibrous material be all and inflammable monomer, based on China's cloud, expensive, valley district ethnic groups
Now live board house, the former residence board house of colony of resident family of inhabitation village does not mostly carry out flame treatment, the simultaneously guest of the existing top grade of China
Shop, with the metope fitted up, curtain and carpet, does not the most possess certain fire protecting performance, and once flashing not only causes certain warp
Ji loss, brings serious harm to affect also to the life security of inhabitation passenger, therefore ensures the security of the lives and property of people
Product become in the urgent need to.
Fire retardant, also known as incombustible agent or fireproof agent；It is additive flame retardant and reactive flame retardant according to application mode.Add
Type fire retardant mainly includes inorganic combustion inhibitor (water solublity and water-insoluble), halogenated flame retardant (organochlorine and organic bromide),
Phosphorus flame retardant (red phosphorus, phosphate ester etc.).Reactive flame retardant mostly is the organic halogen containing reactivity worth group and the monomer of organophosphor.
As polymer plastic material flame-retardant as inflammable in PP, PA, PE, PS, ABS, EVA and PET, PBT etc. currently mainly have
Machine and inorganic, halogen and non-halogen.Having halogen system, nitrogen system and phosphorus system as organic, inorganic mainly have tri-chlorination two antimony, magnesium hydroxide, hydrogen
Aluminium oxide, silicon system etc..Organic fire-retardant is oil-soluble agent because of the overwhelming majority, will produce a large amount of toxic gas and dense smoke during burning,
Typically it is not suitable for the application at timber and textile fabric.Though existing inorganic combustion inhibitor has certain flame retardant effect, but makees
For applying in processing at chemical fibre timber, not only equipment investment is expensive, and the fire retardant processed as combustible material surface, it is waterproof
Poor with durability.
Summary of the invention
For solving above-mentioned technical problem, it is an object of the invention to provide a kind of water-soluble flame retardant and application thereof, this
Bright water-soluble flame retardant has flame retardant effect, can be greatly improved disaster relief flameproof effect, and can solve the problem that material surface processes
After durability and water proofing property.
The technical scheme used is:
A kind of water-soluble flame retardant, by weight calculating, is made up of following component:
Water-soluble inorganic flame retardant 4-30%,
Aqueous inorganic binding agent 10-40%,
Moisture content macromolecule emulsion 10-30%,
Thickening agent 1-3%,
Penetrating agent 1-3%,
Constituent content sum is 100%.
The water-soluble inorganic flame retardant of the present invention, when decomposes goes out phosphide, Metaphosphoric acid and water, heat expands (carbonization),
Heat insulation (air), reduces ignition point, to reach flame retardant effect.As preferably, described water-soluble inorganic flame retardant be phosphoric acid hydrogen,
One or more in ammonium, water-soluble poly ammonium phosphate, phosphoric acid, boric acid, ammonium chloride, Firebrake ZB, Metaphosphoric acid, Borax.
Water-soluble inorganic bonding agent of the present invention, bonding force is strong, and high temperature resistant (1500-1600 DEG C), there is again dirt-resisting dustproof
The functions such as ageing-resistant fire prevention.As preferably, described water-soluble inorganic bonding agent is in waterglass (i.e. sodium silicate), the molten acid of silicon
One or more.
The water soluble polymer emulsion of the present invention has certain bonding force, and the transparent protection of dried material surface is thin
Film, has certain water proofing property simultaneously.As preferably, described water soluble polymer emulsion is pure-acrylic emulsion, acid pure third breast
One in liquid, styrene-butadiene emulsion, butyronitrile emulsion, soluble polyurethane, water solublity cyclochloride resin, water solublity styrene-acrylic emulsion or one
Above.
The thickening agent of the present invention is for regulating the mobility of water-soluble flame retardant.As preferably, described thickening agent is poly-
One or one in acrylate thickening agent, hydroxymethyl cellulose, hydroxyethyl cellulose, polyvinyl alcohol (PVA), thickening agent 4050
More than Zhong.
The penetrating agent of the present invention is for accelerating the water-soluble flame retardant infiltration to material inner layer, to reach to strengthen fire-retardant effect
Really.As preferably, described penetrating agent is that (i.e. sodium diethylhexyl sulfosuccinate, also known as quickly penetrating agent for penetrant t
T), bromo geramine (i.e. dodecyl dimethyl benzyl ammonium bromide), penetrating agent JFC (i.e. fatty alcohol-polyoxyethylene ether), penetrating agent
One or more in BX (i.e. sodium butylnaphthalenesulfonate).
Time prepared by the present invention, by conventional component mixing and stirring.
The water-soluble flame retardant of the present invention is in wood and/or the application of fiber surface.I.e. at wood materials and/or fibrous material
The process on surface, as sprayed its surface applications.
The beneficial effects of the present invention is:
The present invention selects one group of water solublity, the fire-retardant liquor of water white transparency, have do not fire, nontoxic, corrosion-free, pollution-free, easy
Infiltration, can be retained in inflammable dielectric surface after natural drying, meets fire high temperature and complex chemical reaction can occur, and its product has
Significantly fire-retardant fireproof effect, make material can only " carbonization " and can not burn thus substantially increase disaster relief flameproof effect.
The present invention now can live board house, colony of resident family based on China's cloud, inhabitation village expensive, valley district ethnic groups
Former residence board house transform, to reach flame treatment.Simultaneously the hotel of the existing top grade of China with the metope fitted up, curtain and
Carpet can use the present invention to carry out surface process, reaches flame retardant effect.
The present invention has preferable durability and water proofing property, and film forming is transparent higher, thus raw material substantially can be kept at place
Keep the shape after reason, keep true qualities.
Detailed description of the invention
Below by specific embodiment, the present invention is described in detail, but the purposes of these exemplary embodiments and
Purpose is only used for enumerating the present invention, and not the real protection scope to the present invention constitutes any type of any restriction, more non-general
Protection scope of the present invention is confined to this.
It addition, unless stated otherwise, below percentage ratio used by component be all weight percentage.
Embodiment 1:
A kind of water-soluble flame retardant, is made up of following component:
Water-soluble inorganic flame retardant 29%,
Aqueous inorganic binding agent 40%,
The sub-macromolecule emulsion of moisture content 29%,
Thickening agent 1%,
Penetrating agent 1%.
Described water-soluble inorganic flame retardant is water-soluble poly ammonium phosphate；
Described aqueous inorganic binding agent is waterglass；
The sub-macromolecule emulsion of described moisture content is pure-acrylic emulsion；
Described thickening agent is hydroxymethyl cellulose；
Described penetrating agent is penetrating agent JFC.
During preparation, by conventional component mixing and stirring.
Embodiment 2
With reference to embodiment 1, the water-soluble flame retardant of the present embodiment, it is made up of following component: water-soluble inorganic flame retardant
30%,
Aqueous inorganic binding agent 36%,
The sub-macromolecule emulsion of moisture content 30%,
Thickening agent 2%,
Penetrating agent 2%.
Described water-soluble inorganic flame retardant is phosphoric acid hydrogen；
Described aqueous inorganic binding agent is waterglass；
The sub-macromolecule emulsion of described moisture content is styrene-butadiene emulsion；
Described thickening agent is polyvinyl alcohol；
Described penetrating agent is penetrating agent BX.
Embodiment 3
With reference to embodiment 1, the water-soluble flame retardant of the present embodiment, it is made up of following component: water-soluble inorganic flame retardant
28%,
Aqueous inorganic binding agent 38%,
The sub-macromolecule emulsion of moisture content 28%,
Thickening agent 3%,
Penetrating agent 3%.
Described water-soluble inorganic flame retardant is Firebrake ZB；
Described aqueous inorganic binding agent is the molten acid of silicon；
The sub-macromolecule emulsion of described moisture content is water solublity cyclochloride resin；
Described thickening agent is polyacrylate；
Described penetrating agent is penetrant t.
The water-soluble flame retardant that embodiment 1-3 prepares is compared with like product, sees table 1
Table 1
From table 1 it is known that
(1) present invention fire-retardant liquor constructing operation is simple, and film forming is transparent higher, thus raw material substantially can be kept to exist
Keep the shape after process, keep true qualities.
(2) product all uses more as anti-flaming dope the most both at home and abroad, and to raw sheet material complex treatment process, equipment is held high
Expensive.
(3) there is no the practicable techniques processed on combustible surface that can look at present both at home and abroad.
Based on China's cloud, the former residence board house that expensive, board house, colony of resident family are now lived in valley district ethnic groups inhabitation village
Sample is transformed, and then carries out repeated combustion test, durability and waterproof test, it was found that sample is substantially difficult to
Burning, the most durable have fire resistance, and water resistance is preferable simultaneously.
Should be appreciated that the purposes of these embodiments is merely to illustrate the present invention and is not intended to limit the protection model of the present invention
Enclose.Additionally, it will also be appreciated that after the technology contents having read the present invention, the present invention can be made respectively by those skilled in the art
Planting change, amendment and/or modification, all these equivalent form of value falls within the guarantor that the application appended claims is limited equally
Within the scope of protecting.
Claims (7)
1. a water-soluble flame retardant, it is characterised in that by weight calculating, be made up of following component:
Water-soluble inorganic flame retardant 4-30%,
Aqueous inorganic binding agent 10-40%,
Moisture content macromolecule emulsion 10-30%,
Thickening agent 1-3%,
Penetrating agent 1-3%,
Constituent content sum is 100%.
Water-soluble flame retardant the most according to claim 1, it is characterised in that described water-soluble inorganic flame retardant is phosphoric acid
One or more in hydrogen, ammonium, water-soluble poly ammonium phosphate, phosphoric acid, boric acid, ammonium chloride, Firebrake ZB, Metaphosphoric acid, Borax.
Water-soluble flame retardant the most according to claim 1, it is characterised in that described water-soluble inorganic bonding agent is water glass
One or more in the molten acid of glass, silicon.
Water-soluble flame retardant the most according to claim 1, it is characterised in that described water soluble polymer emulsion is pure third breast
Liquid, acid pure-acrylic emulsion, styrene-butadiene emulsion, butyronitrile emulsion, soluble polyurethane, water solublity cyclochloride resin, water solublity styrene-acrylic emulsion
In one or more.
Water-soluble flame retardant the most according to claim 1, it is characterised in that described thickening agent is polyacrylate thickening
One or more in agent, hydroxymethyl cellulose, hydroxyethyl cellulose, polyvinyl alcohol, thickening agent 4050.
Water-soluble flame retardant the most according to claim 1, it is characterised in that described penetrating agent is penetrant t, new clean that
Go out, one or more in penetrating agent JFC, penetrating agent BX.
7. the arbitrary described water-soluble flame retardant of claim 1-6 is in wood and/or the application of fiber surface.
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| CN201610534034.8A CN106189608A (en) | 2016-07-07 | 2016-07-07 | Water-soluble flame retardant and application thereof |
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| CN201610534034.8A CN106189608A (en) | 2016-07-07 | 2016-07-07 | Water-soluble flame retardant and application thereof |
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| CN106671225A (en) * | 2016-12-17 | 2017-05-17 | 浦北县建业胶合板有限责任公司 | Flame retardant plywood and preparation method thereof |
| CN107030819A (en) * | 2017-05-03 | 2017-08-11 | 贵港市鑫宏木业有限公司 | A kind of fire retardant and its application for glued board |
| CN107879708A (en) * | 2017-10-20 | 2018-04-06 | 北京电线电缆总厂保定有限责任公司 | Extrusion type insulating cement and preparation method thereof and a kind of mineral insulated cable |
| CN111020869A (en) * | 2019-12-27 | 2020-04-17 | 泉州飞鹰无纺布有限责任公司 | Method for preparing flame-retardant non-woven fabric by using waste materials |
| CN112207927A (en) * | 2020-10-15 | 2021-01-12 | 桃江县鑫龙阳光木业胶板厂(普通合伙) | Organic phosphate wood modifier and preparation method thereof |
| CN112549225A (en) * | 2020-11-28 | 2021-03-26 | 无锡市森泰木制品有限公司 | Wood processing method |
| CN113061417A (en) * | 2021-04-29 | 2021-07-02 | 贵州八六三科技有限公司 | Halogen-free environment-friendly flame retardant liquid |
| CN114450331A (en) * | 2019-10-08 | 2022-05-06 | 爱克发-格法特公司 | Flame-retardant film |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106671225A (en) * | 2016-12-17 | 2017-05-17 | 浦北县建业胶合板有限责任公司 | Flame retardant plywood and preparation method thereof |
| CN107030819A (en) * | 2017-05-03 | 2017-08-11 | 贵港市鑫宏木业有限公司 | A kind of fire retardant and its application for glued board |
| CN107879708A (en) * | 2017-10-20 | 2018-04-06 | 北京电线电缆总厂保定有限责任公司 | Extrusion type insulating cement and preparation method thereof and a kind of mineral insulated cable |
| CN107879708B (en) * | 2017-10-20 | 2020-11-10 | 北京电线电缆总厂保定有限责任公司 | Extrusion type insulating glue, preparation method thereof and mineral insulated cable |
| CN114450331A (en) * | 2019-10-08 | 2022-05-06 | 爱克发-格法特公司 | Flame-retardant film |
| CN111020869A (en) * | 2019-12-27 | 2020-04-17 | 泉州飞鹰无纺布有限责任公司 | Method for preparing flame-retardant non-woven fabric by using waste materials |
| CN112207927A (en) * | 2020-10-15 | 2021-01-12 | 桃江县鑫龙阳光木业胶板厂(普通合伙) | Organic phosphate wood modifier and preparation method thereof |
| CN112549225A (en) * | 2020-11-28 | 2021-03-26 | 无锡市森泰木制品有限公司 | Wood processing method |
| CN113061417A (en) * | 2021-04-29 | 2021-07-02 | 贵州八六三科技有限公司 | Halogen-free environment-friendly flame retardant liquid |
| CN114507462A (en) * | 2022-02-25 | 2022-05-17 | 海鹰空天材料研究院(苏州)有限责任公司 | Fireproof flame-retardant coating and preparation method thereof |
| CN115779328A (en) * | 2022-11-23 | 2023-03-14 | 应急管理部天津消防研究所 | High-viscosity water-based environment-friendly efficient fire extinguishing agent, preparation method thereof and fire extinguishing device |
| CN115779328B (en) * | 2022-11-23 | 2024-03-01 | 应急管理部天津消防研究所 | High-viscosity water-based environment-friendly high-efficiency fire extinguishing agent, preparation method thereof and fire extinguishing device |
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