CN106192575A - A kind of anti-theft security paper - Google Patents

A kind of anti-theft security paper Download PDF

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Publication number
CN106192575A
CN106192575A CN201510317264.4A CN201510317264A CN106192575A CN 106192575 A CN106192575 A CN 106192575A CN 201510317264 A CN201510317264 A CN 201510317264A CN 106192575 A CN106192575 A CN 106192575A
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China
Prior art keywords
amorphous
theft security
security paper
fiber
paper
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Chinese (zh)
Inventor
陈征
王诚
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BEIJING HOWLET TECHNOLOGIES Co.,Ltd.
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Beijing Heng Wei Science And Technology Ltd
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Abstract

The present invention relates to a kind of anti-theft security paper, this anti-theft security paper implants the amorphous naked fiber with large Barkhusen effect, a diameter of 10-50 micron of wherein said amorphous naked fiber, preferably 20-30 micron;The a length of 2-10mm of described amorphous naked fiber, or 3-8mm, or 3-5mm.

Description

A kind of anti-theft security paper
Technical field
The application relates to a kind of anti-theft security paper, and the method preparing this anti-theft security paper.
Background technology
Information is as a kind of resource, its universality, sharing, appreciation, handlability and multiple-effect By property so that it is the mankind are had to the meaning of particular importance.According to the definition of International Organization for Standardization, The implication of Information Security is primarily referred to as the integrity of information, availability, confidentiality and reliability, protects Protecting the basic goal of information security is exactly to make internal information not by the prestige of the factor such as internal, outside, natural The side of body.Information security is the problem that any country all must attach great importance to, and is a country that can not be ignored Security strategy.Hostile force or illegal organization use various means to steal politics, military affairs, economy, section The secret information of the aspect such as learn a skill, how government, army and company ensure information security becomes urgency The problem that need to solve.Nowadays have a lot of concerning security matters or important paper document in the case of with no authorized Being not allow to take security areas out of, this needs to protect these secrecy paper, it is desirable to having people Attempt illegally to carry secrecy paper when leaving security areas, can with perception also by special detection means Report to the police.
Prior art uses the mode implanting amorphous band in paper to protect secrecy paper.Non- Crystal zone material has large Barkhusen effect, it may be assumed that domain wall generation saltatory is not in magnetic history for material Reversible displacement process, can be detected by instrument.Amorphous band is put in alternating magnetic field, when After magnetic field reaches the switch yard of material, the magnetic domain generation instantaneous variation of material, instrument can sense one Individual distinctive electromagnetic signal.In actual applications, detection equipment is placed on the exit of security areas, When implanting the paper entrance detection region of amorphous band when there being people to carry, detecting instrument will detect One electromagnetic signal, reports to the police immediately.Due to preparation technology, prepare width and be less than 1 millimeter Amorphous band difficulty is very big, and in order to offset the impact of demagnetizing field, amorphous band must keep certain length Degree, just can have large Barkhusen effect.The amorphous with large Barkhusen effect used on market Band, a length of 32 millimeters of standard, the shortest can being only capable of reaches 28 millimeters.Prior art is by length Spending 32 millimeters, the sheet metal strip location that width is 1 millimeter is implanted in paper, and amorphous band is easy to by people Finding, and then destroy it, the warning function of modern this anti-theft security paper lost efficacy.
Accordingly, it would be desirable to a kind of, there is the higher antitheft and anti-theft security paper of anti-damage ability.
Summary of the invention
By the present invention in that the amorphous fiber having prepared a diameter of 10-50 micron with melt czochralski method, and And find, when this amorphous fiber has the high length-diameter ratio higher than 100, can have big Barkhausen Effect, implants the amorphous fiber of this high length-diameter ratio in paper, just obtains one and have higher antitheft Anti-theft security paper with anti-damage ability.
Therefore, the present invention comprises herein below:
1. 1 kinds of anti-theft security paper of embodiment, implant in this anti-theft security paper and have big Barkhausen The amorphous naked fiber of effect, a diameter of 10-50 micron of wherein said amorphous naked fiber;Described amorphous is fine The a length of 2-10mm of dimension.
The anti-theft security paper of embodiment 2. embodiment 1, wherein said amorphous naked fiber is antitheft at this Content in safety paper is 5-15m/m2, or 1 meter to 2 meters of every A4 paper.
The anti-theft security paper of embodiment 3. embodiment 4, wherein said amorphous naked fiber is by molten Prepared by body czochralski method.
Anti-theft security paper any one of embodiment 4. aforementioned embodiments, wherein said anti-theft security Paper is prepared by using amorphous naked fiber to be implanted directly in the middle of paper.
Anti-theft security paper any one of embodiment 5. aforementioned embodiments, wherein amorphous naked fiber contains Have:
A) Co, one or more elements in Fe, Mn, Ni;
B) Si, one or more elements in B, C;With
C) optional rare earth or magnesium-yttrium-transition metal.
Anti-theft security paper any one of embodiment 6. aforementioned embodiments, wherein said amorphous fiber It is distributed in described anti-theft security paper in the way of the distribution of full version, location distribution or a combination thereof.
Anti-theft security paper any one of embodiment 7. aforementioned embodiments, wherein said amorphous fiber Arrange in described anti-theft security paper in the way of ordered arrangement, lack of alignment or a combination thereof.
Anti-theft security paper any one of embodiment 8. aforementioned embodiments, wherein amorphous fiber contains Have:
The Fe of 1-15wt%;
The Si of 2-12wt%;
Total amount is the one in B, Nb, Cu, Mn, Mo, Ni, Cr and Al of 2-25wt% Or it is multiple;And
The Co of surplus.
Anti-theft security paper any one of embodiment 9. aforementioned embodiments, the naked fibre of wherein said amorphous A diameter of 20-30 micron of dimension;The a length of 3-8mm of described amorphous fiber.
Anti-theft security paper any one of embodiment 10. aforementioned embodiments, wherein said amorphous is naked A diameter of 20-30 micron of fiber;The a length of 3-5mm of described amorphous fiber.
Accompanying drawing explanation
In order to be illustrated more clearly that the technical scheme of the embodiment of the present invention, below by the accompanying drawing to embodiment It is briefly described, it should be apparent that, the accompanying drawing in describing below merely relates to some realities of the present invention Execute example, rather than limitation of the present invention.
(31 induction coil 32 foundry alloy bar 33 copper wheels 34 are female to be closed Fig. 1: melt czochralski method schematic diagram Gold apparatus for feeding).
Fig. 2: amorphous naked fiber electromicroscopic photograph.
Fig. 3: amorphous fiber large Barkhusen effect curve.
Fig. 4: containing the anti-theft security paper schematic diagram of unordered full version distribution amorphous fiber.
Fig. 5: containing the anti-theft security paper schematic diagram of the most completely version distribution amorphous fiber.
Fig. 6: containing the anti-theft security paper schematic diagram of unordered location distribution amorphous fiber.
Fig. 7: containing the anti-theft security paper schematic diagram of location distribution amorphous fiber in order.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below in conjunction with this The accompanying drawing of inventive embodiments, is clearly and completely described the technical scheme of the embodiment of the present invention. Obviously, described embodiment is a part of embodiment of the present invention rather than whole embodiments. Based on described embodiments of the invention, those of ordinary skill in the art are without creative work The every other embodiment obtained under premise, broadly falls into the scope of protection of the invention.
Definition:
In this application, term " large Barkhusen effect " refers to what amorphous band or fiber were had A kind of characteristic, i.e. the movement of this material domain wall generation saltatory in magnetic history or reversion, this mistake Journey can be detected by instrument.When actual detection, amorphous band or fiber are put into alternation In magnetic field, after magnetic field reaches the switch yard of material, the magnetic domain generation instantaneous variation of material, detector Device just can sense a distinctive electromagnetic signal.In some embodiments, wherein generate Electromagnetic signal is pulse signal or higher hamonic wave.In the present invention, amorphous fiber has large Barkhusen effect, As it is shown on figure 3, under the excitation of alternating magnetic field, when reaching a switching magnetic field value, magnetic induction is strong Degree can jump, thus generates an electromagnetic signal, such as: pulse signal or higher hamonic wave.When Detecting instrument will be reported to the police when detecting the electromagnetic signal that amorphous fiber produces.
In this application, term " melt czochralski method " refers to be made by the steps amorphous fiber Method:
In the present invention, amorphous naked fiber uses melt czochralski method to prepare, (as shown in Figure 3) specific as follows:
First the foundry alloy rod with required composition is provided;
2. the mode utilizing sensing heating or LASER HEATING melts foundry alloy so that foundry alloy upper end is formed One stable weld pool;
3. upwards fed foundry alloy by machinery, utilize the portion that guider is connected with foundry alloy simultaneously Foundry alloy is cooled down by position, prevents the part beyond foundry alloy top from melting;
4. the foundry alloy of fusing is cut by the copper wheel of the high speed rotating using edge to be taper, obtains Amorphous naked fiber.
As it is shown in figure 1, Fig. 1 describes the concrete grammar preparing amorphous naked fiber of the present invention.At Fig. 1 In, reference has a following implication:
31: induction coil
32: foundry alloy bar
33: copper wheel
34: foundry alloy apparatus for feeding.
Fig. 2 is an example of the amorphous naked fiber prepared by the process described above.
In this application, term " amorphous fiber " or " amorphous naked fiber " have people in the art The implication that member is generally understood.It is said that in general, it refers to a kind of alloy fiber, it contains multiple alloy Element, such as Co, Fe, Mn, Ni, Si, B, C and transition metal etc..
The size range of the amorphous fiber in the present invention is: 10-50 micron;A length of 2-10 millimeter.
In a kind of specific embodiment, the present invention provides a kind of anti-theft security paper, this anti-theft security Paper implants the amorphous naked fiber with large Barkhusen effect, wherein said amorphous naked fiber straight Footpath is 10-50 micron, preferably 20-30 micron;The a length of 2-10mm of described amorphous fiber, or 3-8mm, or 3-5mm.The inventors found that the size of amorphous fiber is relatively low, such as diameter Time in 10-50 micrometer range, as long as the draw ratio of amorphous fiber is higher than 50, especially higher than 100 Time, this amorphous fiber still has large Barkhusen effect.Therefore, if the length of amorphous fiber is spent Low, then it is difficult to detect.And in common paper, if amorphous fiber length is long, amorphous is fine Tie up excessive with the difference of paper pulp fiber, often paper technology is had a negative impact.
In one embodiment, in the anti-theft security paper of the present invention, described amorphous naked fiber is at this Content in anti-theft security paper is 15-30m/m2, or content be every A4 paper be 1 meter to 2 meters. Content at amorphous fiber is higher than 15m/m2(such as, in every A4 paper, the content of amorphous fiber is 1 When rice is above) time, detection equipment in the market can arrive with higher accuracy detection.But, If content is the highest, then the cost of anti-theft security paper can be greatly improved, it is therefore preferred that amorphous Fiber content in this anti-theft security paper is less than or equal to 30m/m2(such as, at every A4 paper The content of middle amorphous fiber is less than 2 meters).In one embodiment, described amorphous fiber is prevented at this The content stolen in safety paper is 3-30m/m2, such as in every A4 paper, the content of amorphous fiber is 0.2 meter To 2 meters.3 to less than 15m/m2Content range in, although commercially available detection equipment may not allowed Easily detect, but, in this case it is still possible to detected by the parameter of regulation detection equipment.
In one embodiment, in the anti-theft security paper of the present invention, described amorphous fiber is to pass through Prepared by melt czochralski method.The amorphous fiber without clad is also referred to as amorphous naked fiber.As above institute Stating, amorphous naked fiber described herein is prepared by " melt czochralski method ", described method Comprise the following steps: first the foundry alloy rod with required composition is provided;2. utilize sensing heating or The mode of LASER HEATING melts foundry alloy so that foundry alloy upper end forms a stable weld pool;3. by Machinery upwards feeds foundry alloy, and mother is closed by the position simultaneously utilizing guider to be connected with foundry alloy Gold cools down, and prevents the part beyond foundry alloy top from melting;4. using edge is the high speed of taper The foundry alloy of fusing is cut by the copper wheel rotated, and obtains amorphous naked fiber.The chip side of the present invention It can be 10-50 micron that method can obtain the amorphous naked fiber that diameter is the least, such as this diameter, or 20-30 micron.This fiber is very suitable for preparing the anti-theft security paper of the present invention.The method is in the company of production Continuous long amorphous fiber aspect is restricted.
In some embodiments, the anti-theft security paper of the present invention is by using amorphous naked fiber directly to plant Enter and prepare in the middle of paper.In this way, can prepare there is the amorphous fiber of ordered arrangement Anti-theft security paper.
For the material of amorphous fiber, it is not particularly limited, as long as the mesh of the present invention can be reached ?.In some embodiments, described amorphous naked fiber contains:
A) Co, one or more elements in Fe, Mn, Ni;
B) Si, one or more elements in B, C;With
C) optional rare earth or magnesium-yttrium-transition metal.
In the amorphous fiber of this composition, component a) is the component with ferromagnetic material, and component b) is Non-metallic alloying elements.Component c) is optional, and the different proportioning of addO-on therapy makes it possible to material The switch yard position producing large Barkhusen effect is subjected to displacement.
Some preferred embodiment in, amorphous fiber contains: the Fe of 1-15 weight %;2-12 weight The Si of amount %;Total amount be 2-25 weight % selected from B, Nb, Cu, Mn, Mo, Ni, Cr and Al In one or more;And Co.Some preferred embodiment in, amorphous fiber contains: 1-15 The Fe of weight %;The Si of 2-12 weight %;Total amount be 2-25 weight % selected from B, Nb, Cu, Mn, One or more in Mo, Ni, Cr and Al;And the Co of surplus.There is the amorphous of this composition Fiber is preferred in the present invention, because its material source is extensive, it is easy to preparation.
For the anti-theft security paper of the present invention, wherein said amorphous fiber distribution model in paper Enclosing and do not limit, in a particular embodiment, described amorphous fiber can be distributed with full version, position The mode of distribution or a combination thereof is distributed in described anti-theft security paper.Full version distribution refers to that amorphous fiber divides The scope of cloth is throughout whole paper.Location distribution refers to that scope that amorphous fiber is distributed is in certain of paper In fixed range, the most only in the marginal portion of paper, or a corner.
For the anti-theft security paper of the present invention, wherein said amorphous fiber arrangement side in paper Formula does not has concrete restriction.In some embodiments, described amorphous fiber in anti-theft security paper with The mode of ordered arrangement, lack of alignment or a combination thereof arranges in described anti-theft security paper.
In the present invention amorphous fiber with unordered full version distribution or the most completely version distribution or the distribution of unordered location or Location is distributed in the example in the middle of paper as shown in Fig. 4, Fig. 5, Fig. 6, Fig. 7 in order.
Embodiment
The raw material used in embodiments of the invention is all conventional, can buy from the market, or Can be prepared by conventional method in the lab.
Detection method:
The detection equipment used in embodiments of the invention is electromagnetism (EM) label detection equipment, such as: The electromagnetic tag detection door that first news U.S. money produces.
The principle of detection can be described as follows:
Detection equipment contains sender unit and signal receiving device.Sender unit be by Induction coil applies an alternating current or the mode of alternating voltage, produces excitation field district, excitation Magnetic field is the magnetic field of an alternation.Signal receiving device is an induction coil.When amorphous fiber enters During excitation field district, owing to it has large Barkhusen effect, under the excitation of alternating magnetic field, in it Portion's domain structure can occur Rapid Variable Design, the electricity generated in the induction coil in signal receiving device Magnetic field impulse signal or higher hamonic wave.When signal receiving device detects electromagnetic pulse signal or higher hamonic wave Time, illustrate that target detection thing occurs in detection region.
Embodiment 1
The preparation of amorphous naked fiber, melt czochralski method
Below with reference to the accompanying drawings 1, introduce the preparation method of the amorphous naked fiber of the present invention.
First providing Co base foundry alloy rod, the fusing point of this alloy bar is 970 DEG C, a diameter of 7mm, becomes It is divided into Co71.8Fe4.9Nb0.8Si7.5B15
The mode utilizing sensing heating melts foundry alloy, is heated to 1200 degree so that foundry alloy upper end shape Become a stable weld pool;
Machinery as shown in Figure 2 upwards feeds foundry alloy with the speed of 2mm/ second, utilizes simultaneously and leads Foundry alloy is cooled down by the position being connected with foundry alloy to device, prevents the portion beyond foundry alloy top Fractional melting;
The foundry alloy of fusing is cut by the copper wheel of the high speed rotating using edge to be taper, obtains non- Brilliant naked fiber.
The diameter of the continuous print amorphous naked fiber 20 ± 2 microns of embodiment 1 preparation.
The continuous print amorphous naked fiber of acquisition is cut into a length of 0.5 millimeter, 1 millimeter, 2 millimeters, 5 Millimeter, 10 millimeters and 15 millimeters standby.
Embodiment 2
Have different by the amorphous fiber of preparation in embodiment 1 is implanted directly into preparation in the middle of paper The paper of amorphous fiber content, wherein, amorphous fiber total length distribution in paper is respectively 0.5m/A4 paper, 0.75m/A4 paper, 1m/A4 paper, 2m/A4 paper.To preparation containing amorphous fiber Paper test, result is following, and (the most each result is the system obtaining 1000 paper duplicate detection Meter result, when recall rate refers to the detection zone that paper is put into detecting instrument, it is secondary that detecting instrument is reported to the police Number):
As can be seen from the above results, in embodiment 1, the glass fluxing technique amorphous fiber of preparation has Large Barkhusen effect.In the case of the length of amorphous fiber is less than or equal to 1mm, instrument is to this The recall rate of kind of anti-theft security paper is less than 56%, but in the length of the amorphous fiber situation higher than 2mm Under, instrument is higher than 79%, especially at amorphous fiber in A4 paper to the recall rate of anti-theft security paper When total length is more than 1m, recall rate has reached more than 98%.
The above is only the exemplary embodiment of the present invention, not for the protection limiting the present invention Scope, protection scope of the present invention is determined by appended claim.
This application claims in the Chinese patent application the 201510156031.0th that on April 3rd, 2015 submits Number priority, quote in full above-mentioned Chinese patent application disclosure at this using as the application's A part.

Claims (10)

1. an anti-theft security paper, implants in this anti-theft security paper and has the non-of large Barkhusen effect Brilliant naked fiber, a diameter of 10-50 micron of wherein said amorphous naked fiber;The length of described amorphous naked fiber Degree is 2-10mm.
2. the anti-theft security paper of claim 1, wherein said amorphous naked fiber is in this anti-theft security paper Content be 3-30m/m2
3. the anti-theft security paper of claim 4, wherein said amorphous naked fiber is by melt czochralski method Preparation.
Anti-theft security paper any one of the most aforementioned claim, wherein said anti-theft security paper is by adopting It is implanted directly in the middle of paper with amorphous naked fiber and prepares.
Anti-theft security paper any one of the most aforementioned claim, wherein amorphous naked fiber contains:
A) Co, one or more elements in Fe, Mn, Ni;
B) Si, one or more elements in B, C;With
C) optional rare earth or magnesium-yttrium-transition metal.
Anti-theft security paper any one of the most aforementioned claim, wherein said amorphous naked fiber is with full version The mode of distribution, location distribution or a combination thereof is distributed in described anti-theft security paper.
Anti-theft security paper any one of the most aforementioned claim, wherein said amorphous naked fiber is with in order The mode of arrangement, lack of alignment or a combination thereof arranges in described anti-theft security paper.
Anti-theft security paper any one of the most aforementioned claim, wherein amorphous naked fiber contains:
The Fe of 1-15wt%;
The Si of 2-12wt%;
Total amount is the one in B, Nb, Cu, Mn, Mo, Ni, Cr and Al of 2-25wt% Or it is multiple;And
The Co of surplus.
Anti-theft security paper any one of the most aforementioned claim, the diameter of wherein said amorphous naked fiber For 20-30 micron;The a length of 3-8mm of described amorphous naked fiber.
Anti-theft security paper any one of the most aforementioned claim, the diameter of wherein said amorphous naked fiber For 20-30 micron;The a length of 3-5mm of described amorphous naked fiber.
CN201510317264.4A 2015-04-03 2015-06-11 A kind of anti-theft security paper Pending CN106192575A (en)

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CN201510156031 2015-04-03

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CN201510317262.5A Pending CN106192549A (en) 2015-04-03 2015-06-11 An anti-theft security paper
CN202311174605.8A Pending CN117166284A (en) 2015-04-03 2015-06-11 Antitheft safety paper
CN201520399245.6U Expired - Lifetime CN205617157U (en) 2015-04-03 2015-06-11 Theftproof safety paper
CN201510317263.XA Pending CN106192574A (en) 2015-04-03 2015-06-11 A kind of anti-theft security paper
CN201510317264.4A Pending CN106192575A (en) 2015-04-03 2015-06-11 A kind of anti-theft security paper
CN201520399262.XU Expired - Lifetime CN205907547U (en) 2015-04-03 2015-06-11 Theftproof safety paper
CN201520399257.9U Expired - Lifetime CN205907549U (en) 2015-04-03 2015-06-11 Theftproof safety paper

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CN202311174605.8A Pending CN117166284A (en) 2015-04-03 2015-06-11 Antitheft safety paper
CN201520399245.6U Expired - Lifetime CN205617157U (en) 2015-04-03 2015-06-11 Theftproof safety paper
CN201510317263.XA Pending CN106192574A (en) 2015-04-03 2015-06-11 A kind of anti-theft security paper

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Publication number Priority date Publication date Assignee Title
CN106192549A (en) * 2015-04-03 2016-12-07 北京恒维科技有限公司 An anti-theft security paper
CN107100035A (en) * 2017-06-14 2017-08-29 盛世龙图(北京)物联技术有限公司 A kind of recognizable and antitheft safety paper
CN113077708B (en) * 2020-01-03 2024-08-23 北京恒维科技有限公司 Anti-counterfeiting label with double matrixes and anti-counterfeiting method
CN113699470A (en) * 2020-05-20 2021-11-26 日照恒维新材料科技有限公司 Amorphous fiber and preparation method thereof
TWI749843B (en) * 2020-11-03 2021-12-11 南亞塑膠工業股份有限公司 Security paper

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CN106192549A (en) 2016-12-07
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CN205907547U (en) 2017-01-25
CN205907549U (en) 2017-01-25
CN117166284A (en) 2023-12-05

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Application publication date: 20161207

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