CN106220811B - A kind of non-reactive flexible polyurethane foams flame plastering agent and its preparation method and application - Google Patents
A kind of non-reactive flexible polyurethane foams flame plastering agent and its preparation method and application Download PDFInfo
- Publication number
- CN106220811B CN106220811B CN201610719012.9A CN201610719012A CN106220811B CN 106220811 B CN106220811 B CN 106220811B CN 201610719012 A CN201610719012 A CN 201610719012A CN 106220811 B CN106220811 B CN 106220811B
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- China
- Prior art keywords
- flame
- polyurethane foams
- flexible polyurethane
- plastering agent
- foam
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 61
- 229920005830 Polyurethane Foam Polymers 0.000 title claims abstract description 45
- 239000011496 polyurethane foam Substances 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000006260 foam Substances 0.000 claims abstract description 60
- 239000000203 mixture Substances 0.000 claims abstract description 25
- 239000012948 isocyanate Substances 0.000 claims abstract description 24
- 238000010030 laminating Methods 0.000 claims abstract description 21
- -1 aromatic isocyanate Chemical class 0.000 claims abstract description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920005906 polyester polyol Polymers 0.000 claims abstract description 12
- 150000002009 diols Chemical class 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims abstract description 8
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 16
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 13
- 150000002513 isocyanates Chemical class 0.000 claims description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 6
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 4
- 239000004088 foaming agent Substances 0.000 claims description 4
- 230000000640 hydroxylating effect Effects 0.000 claims description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
- 150000005846 sugar alcohols Polymers 0.000 claims description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims description 3
- GTACSIONMHMRPD-UHFFFAOYSA-N 2-[4-[2-(benzenesulfonamido)ethylsulfanyl]-2,6-difluorophenoxy]acetamide Chemical compound C1=C(F)C(OCC(=O)N)=C(F)C=C1SCCNS(=O)(=O)C1=CC=CC=C1 GTACSIONMHMRPD-UHFFFAOYSA-N 0.000 claims description 2
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 claims description 2
- 101710130081 Aspergillopepsin-1 Proteins 0.000 claims description 2
- 102100031007 Cytosolic non-specific dipeptidase Human genes 0.000 claims description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 2
- 150000008065 acid anhydrides Chemical class 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 229940051250 hexylene glycol Drugs 0.000 claims description 2
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 claims 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 claims 1
- 125000004185 ester group Chemical group 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 14
- 238000009472 formulation Methods 0.000 abstract description 5
- 230000008569 process Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 230000004044 response Effects 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 15
- 239000002585 base Substances 0.000 description 7
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical group C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 238000005187 foaming Methods 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000001514 detection method Methods 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 150000008301 phosphite esters Chemical class 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 2
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- YSAANLSYLSUVHB-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]ethanol Chemical compound CN(C)CCOCCO YSAANLSYLSUVHB-UHFFFAOYSA-N 0.000 description 1
- ANHAEBWRQNIPEV-UHFFFAOYSA-N 2-chloroethyl dihydrogen phosphate Chemical compound OP(O)(=O)OCCCl ANHAEBWRQNIPEV-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- HHDUMDVQUCBCEY-UHFFFAOYSA-N 4-[10,15,20-tris(4-carboxyphenyl)-21,23-dihydroporphyrin-5-yl]benzoic acid Chemical compound OC(=O)c1ccc(cc1)-c1c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc([nH]2)c(-c2ccc(cc2)C(O)=O)c2ccc(n2)c(-c2ccc(cc2)C(O)=O)c2ccc1[nH]2 HHDUMDVQUCBCEY-UHFFFAOYSA-N 0.000 description 1
- 101000575029 Bacillus subtilis (strain 168) 50S ribosomal protein L11 Proteins 0.000 description 1
- 102100035793 CD83 antigen Human genes 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 101000946856 Homo sapiens CD83 antigen Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- BCAARMUWIRURQS-UHFFFAOYSA-N dicalcium;oxocalcium;silicate Chemical compound [Ca+2].[Ca+2].[Ca]=O.[O-][Si]([O-])([O-])[O-] BCAARMUWIRURQS-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 229940035423 ethyl ether Drugs 0.000 description 1
- 235000021050 feed intake Nutrition 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- WHZWVUKPJBNTAK-UHFFFAOYSA-N hydroxy dihydrogen phosphite Chemical compound OOP(O)O WHZWVUKPJBNTAK-UHFFFAOYSA-N 0.000 description 1
- GTTBQSNGUYHPNK-UHFFFAOYSA-N hydroxymethylphosphonic acid Chemical compound OCP(O)(O)=O GTTBQSNGUYHPNK-UHFFFAOYSA-N 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000002984 plastic foam Substances 0.000 description 1
- 229920001992 poloxamer 407 Polymers 0.000 description 1
- 229920001583 poly(oxyethylated polyols) Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
- C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/664—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/282—Alkanols, cycloalkanols or arylalkanols including terpenealcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3206—Polyhydroxy compounds aliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6603—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6607—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Medicinal Preparation (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
The present invention relates to a kind of non-reactive flexible polyurethane foams flame plastering agent and its preparation method and application.The plastering agent is made up of low molecular weight diols, benzoic anhydride polyester polyol, monohydric alcohol and the crosslinked reaction of aromatic isocyanate, and the percentage by weight of each raw material is：1 50% low molecular weight diols；20 60% benzoic anhydride polyester polyols；1 30% monohydric alcohol；30 70% aromatic isocyanates；The flame plastering agent is used to prepare and is used for the flexible polyurethane foams that flame is fitted, its consumption is the 1 10% of foam gross weight, what is prepared is used for the flexible polyurethane foams that flame is fitted, relatively other response type flame plastering agents, while with equal laminating effect, the tolerance that also improves foam formulation, the stability for improving foam fabrication process and the performance for improving final foamed product.
Description
Technical field
The present invention relates to a kind of non-reactive flexible polyurethane foams flame plastering agent and its preparation method and application, tool
Body be related to the flame plastering agent be made and its prepare be used for flame fit flexible polyurethane foams in use, the fire
Flame plastering agent is compared with traditional flame plastering agent, because it is non-reactive flame plastering agent, it is being prepared flame laminating use
The smaller influence to process and the influence to final foaming properties are shown during flexible polyurethane foams.
Background technology
Flexible polyurethane foams are widely used to every field, such as furniture, automobile, aircraft.In substantial amounts of application,
Need by laminating, to form a kind of compound between polyurethane foam and base material (such as timber, fabric, metal or plastic material)
Material.A kind of method is to lead to foam and fabric to fit for additional alite paste, and another method is to lead to foam and base material
Cross flame hot-melting resolidification and fit, do not use extra additive.Here, generally by flame interaction by polyurethane foam
Surface hot melt be changed into stickum, then substrate layer is closed.It is changed into solid after waiting stickum cooling again, and obtains
Very lasting combination between polyurethane foam and base material.This method is initially appropriate only for the polyurethane of polyester type, because
It can not be cured sufficiently after the cooling period for the polyurethane of polyether type, and generally there is excessively poor adhesive force.Therefore polyethers is worked as
When polyurethane foam is used for flame laminating, additional flame plastering agent is generally needed to strengthen the adhesive force of foam and base material.
US3131105 describes the method for preparing polyurethane foam laminating thing, wherein the coating comprising combustible material is applied
The surface of polyurethane foam is added to, the coating is then lighted, makes surface melting, then other surface material layers are applied under stress
To plastic foam surface.This method does not disclose and additive is added into foam；US3142650 and 3142651 describe by containing
Hydroxyl phosphite ester such as three (polypropylene glycol) phosphite ester starting prepares polyurethane.Do not disclose and prepared based on polyurethane foam
Flame laminating thing；US3205105 and US3205120 describe the preparation of the flame laminating thing of polyetherurethane foam.Pass through
The a small amount of low molecular weight polyols of addition, the day selected from polyoxyalkylene polyol, phosphorous sour hydroxyaliphatic ester and hydroxyl
Right oil compounds increase adhesive force, but critical defect is that foam will investigate whole formula in preparation process, while also easily going out
The series of problems such as existing foam closed pore, contraction, Huang Xin；US3497416 describes the flame laminating thing of polyetherurethane foam
Prepare.It is different by adding DPG or dibutylene glycol and excessive fragrant adoption in the foam to improve Foam machining process
The plastering agent that polyisocyanate reactant is obtained is realized.But the easy closed pore of foam is still had using the plastering agent, it is necessary to extra addition again
Pore-creating agent such as dimethylformamide；US4060439 describes polyetherurethane foam by adding the two of 2-8 carbon atom
The glycol of the dialkanol amine and some short chains of the triol of alcohol or 3-10 carbon atom and 2-10 carbon atom, triol increase patch
With joint efforts, the addition of these materials, the formula border for preparing foam is very narrow, it is difficult to balance the cracking and closed pore of foam.
CN201010273111 describes polyetherurethane foam by adding phosphorous hydroxy-containing compounds such as two (polyethylene glycol oxide)
The Pluronic F-127 ether of hydroxymethylphosphonate, three (DPG) phosphite esters and glycerine or bisphenol-A reduces discharge, improves
Initial adhesive force etc., but the problems such as equally exist unstable Foam machining process, easy closed pore, yellow core.
In the scheme of above-mentioned all prior arts, although obtaining ether-based foam by adding each flame plastering agent
Improved laminating ability, but it can be found that above-mentioned each flame plastering agent contains reactive group such as hydroxyl or isocyanates
Base, due to their reactivity, makes to change the original structure of foam in the progress for preparing foam, be degrading prepare into
Journey, while making the performance of foam occur big change, there is closed pore, Huang Xin in such as foam.
The content of the invention
For the above-mentioned problems in the prior art, it is an object of the invention to provide a kind of non-reactive flexibel polyurethane
Foam flame plastering agent and its preparation method and application, the common defects existed compared to above-mentioned all kinds of flame plastering agents-anti-
Ying Xing, flame plastering agent of the invention is used in the flexible polyurethane foams that flame is fitted because it is non-reacted preparing,
Foam original formulation need not be changed, and prepare process and foaming properties to foam does not influence substantially.
Described a kind of non-reactive flexible polyurethane foams flame plastering agent, it is characterised in that by following weight percent
Than for component composition：1-49% low molecular weight diols；20-60% benzoic anhydride polyester polyols；1-30% monohydric alcohols；30-
70% aromatic isocyanate.
Described a kind of non-reactive flexible polyurethane foams flame plastering agent, it is characterised in that low molecular weight diols are
One or more of mixtures in ethylene glycol, diethylene glycol, propane diols, DPG, butanediol, hexylene glycol, pentanediol.
A kind of described non-reactive flexible polyurethane foams flame plastering agent, it is characterised in that benzoic anhydride polyester polyol
For containing the aromatic series composition based on phthalic acid and its derivative, the average functionality of the benzoic anhydride polyester polyol is
1.8-2.5, average hydroxyl value is 50-400mgKOH/g, hydroxyl value " refer to that per unit weight material contains and can be reacted with isocyanates
The concentration of hydroxyl, commercially produced product is such as：Si Taipan (Nanjing) Chemical Co., Ltd.：STEPANOL PS-3152, STEPANOL
PS-2402, STEPANOL PS-2002, STEPANOL PS-1752, STEPANOL PS-1552 etc..
Described a kind of non-reactive flexible polyurethane foams flame plastering agent, it is characterised in that the phthalic anhydride polyester is more
First alcohol contains hydroxylating composition, its hydroxylating composition be ethylene glycol, propane diols, butanediol, diethylene glycol, DPG, glycerine,
One or more of mixtures in trimethylolpropane.
A kind of described non-reactive flexible polyurethane foams flame plastering agent, it is characterised in that monohydric alcohol be methanol,
One or more of mixtures in ethanol, isopropanol, n-butanol, isobutanol, amylalcohol, isooctanol.
A kind of described non-reactive flexible polyurethane foams flame plastering agent, it is characterised in that aromatic isocyanate
For toluene di-isocyanate(TDI), '-diphenylmethane diisocyanate or both mixture.
Described non-reactive flexible polyurethane foams flame plastering agent, it is characterised in that by low molecular weight diols, benzene
Acid anhydride PEPA, monohydric alcohol and the crosslinked reaction of aromatic isocyanate are made, and NCO and hydroxyl are fitted in flame
Weight percentage in agent is respectively less than 0.5%, the detection of isocyanate content be by using excess toluene-di-n-butylamine with
Isocyanates reacts, then is obtained with the di-n-butylamine of hydrogen chloride overtitration；The detection of hydroxy radical content be by hydroxyl with it is molten
Phthalic anhydride of the solution in pyridine carries out esterification, and excessive phthalic anhydride is titrated with standard solution of sodium hydroxide
To obtain, the composition principle and the ripe prior art of synthesis condition system the art of flame plastering agent of the invention, it is closed
It is to react to form carbamate and carry out using hydroxyl and isocyanates into principle, the synthesis condition does not have strict limitation,
Can having, without catalyst under conditions of carry out；Also it can be carried out in normal pressure, negative pressure or environment with pressure；Reaction temperature is preferred
10-120 degree.
Described non-reactive flexible polyurethane foams are preparing the soft poly- ammonia for flame laminating with flame plastering agent
Application in ester foam.
Described application, it is characterised in that non-reactive flexible polyurethane foams are that foam is total with the consumption of flame plastering agent
The 1-10% of weight, prepares the flexible polyurethane foams fitted for flame and also includes isocyanates, polyalcohol, phosphor-containing flame-proof
Agent, foaming agent, foam stabilizer and catalyst；Polyalcohol is PPOX-polyoxyethylated polyols, it is however preferred to have 2-5's
Degree of functionality and the PPG that number-average molecular weight is 1000-5000, commercially produced product is such as：Shanghai Gaoqiao petrochemical corporation (complex)：
GEP-560S, Jin Hua Chemical Group Co., Ltd JH-3030, CNOOC and Shell Petrochemicals Co., Ltd SC-5602 etc.；Institute
The isocyanates stated is diphenyl methane 4,4 '-diisocyanate, toluene di-isocyanate(TDI) or two ability mixtures；The phosphorous resistance
Combustion agent is liquid organic phosphorus compound, preferably diethylene glycol double (two-chloro isopropyl phosphate) (WSFR-504L), the tert-butyl groups
Change triphenyl (WSFR-HF-4), triethyl phosphate (TEP), three (the chloro- 2- propyl group of 1-) phosphates (TCPP) and three (2-
Chloroethyl) phosphate (TCEP), dimethylmethane phosphonate ester (DMMP) or one kind in dimethylpropane phosphonate ester (DMPP) or
Several mixtures；Foaming agent is water, dichloromethane, formic acid or pentane；Catalyst is triethylene diamine, stannous octoate, double diformazans
Amido ethylether, dimethylaminoethanol or dimethyl amino ethoxy ethanol, commercially produced product is such as：US Air gasification chemical product
Dabco 33LV, Dabco BL11, the Dabco T9 of Co., Ltd；Foam stabilizer is polyethergpolysiloxane condensation polymer, business
Change product such as：B8110, B8123, B8232 of Degussa (China) Co., Ltd；Mai Tu new and high technologies Materials Co., Ltd of the U.S.
L-580, L-618 etc..
By using above-mentioned technology, compared with prior art, beneficial effects of the present invention are as follows：
1) present invention by by low molecular weight diols, benzoic anhydride polyester polyol, monohydric alcohol by with aromatic isocyanate
Cross-linking reaction, synthesis is substantially free of the non-reactive flame plastering agent of NCO (- NCO) and hydroxyl (- OH), and with the fire
Flame plastering agent prepares the flexible polyurethane foams fitted for flame, is fitted on an equal basis effect with previous reaction type flame plastering agent
While, the tolerance that improves foam formulation, the stability for improving foam fabrication process and improve final foamed product
Performance；
2) the flame plastering agent that the present invention is obtained is preparing the flexible polyurethane foams for flame laminating, and its consumption is limited
It is set to the 1-10% of foam gross weight, when consumption is less than 1%, flame laminating effect can not reach requirement；When consumption is big
When 10%, the other performance to foam has a negative impact.
The described preparation method for the flexible polyurethane foams that flame is fitted that is used for is the ripe prior art in this area, can
Carried out by one-step method or prepolymer method, the representative formula of the one-step synthesis method is as shown in table 1.
The one-step method representative formula of table 1 is as follows：Foam density 25KG/M3
| Raw material | Consumption (in parts by weight) |
| PPG GEP-560S | 100 |
| Phosphonium flame retardant (WSFR-504L) | 12 |
| Flame plastering agent | 5 |
| Foam stabilizer L-580 | 1.0 |
| Catalyst Dabco 33LV | 0.2 |
| Dabco T9 | 0.25 |
| Foaming agent water | 4.5 |
| Isocyanates TDI | 57.5 |
| TDI indexes | 110 |
Its preparation procedure is as follows:
Prepare what a 400mm*400mm*400mm chest in advance as foaming mould.The polyethers that first upper table is arranged
Polyalcohol, phosphonium flame retardant, flame plastering agent, catalyst, foam stabilizer and water are weighed into a plastic containers by weight, with turn
Speed reaches that 3000 revs/min of agitator is quickly mixed 1 minute, is well mixed material.It will in advance weigh again and be placed on another appearance
Isocyanate compound TDI in device is added in above-mentioned compound, after 1000 revs/min quickly mix 10 seconds, is quickly fallen
Enter and foamed in the foaming mould got ready in advance, while counting record compound from mould is poured into time during frothy gel and bubble
Whether punching phenomenon is had when foam rises to highest order.After the completion of foaming, then at room temperature place 24 hours after, meter record foam whether have
Shrinkage phenomenon, and other performance.Foam is cut into 4cm*15cm*1cm foam strip, (such as polyester-cotton blend is knitted with base material through flame fusing
Thing) the obtained foam flame laminating thing of laminating.
Prepared by foam flame laminating thing laboratory is summarized as follows：
First foam batten and base material are horizontally fixed on two ceramics respectively, by the foam of foam batten downwards, water
The flame regulated in advance that flat, constant speed (10cm/s) is produced by using natural gas range, makes foam batten all by flame, table
Face is slightly melted, and is quickly pasted into the ceramics for being fixed with fabric substrate, then two ceramics of light pressure is after 1 hour, determines it and peels off (patch
Close) intensity.
(laminating) strength testing method is peeled off according to ISO 8067,07/1995, with 100mm/min peeling rate, test stripping
From intensity, unit (N), the measure of foam rebound performance GB/T6670-2008 flexible polyurethane foam rebound performances, foam
Collapse the measure (collapsing method) of performance GB/T10807-2006 flexible foam polymeric material hardness.
Embodiment
Following embodiments are used to further describe the explanation present invention, and they are not to be construed as the limit to the scope of the present invention
System.
Embodiment 1-5 is the preparation of non-reactive flexible polyurethane foams flame plastering agent of the present invention.
Low molecular weight diols, benzoic anhydride polyester polyol are added in four mouthfuls of reaction bulbs, vacuumizes, stir, and be warming up to 90
DEG C, it is dehydrated 30 minutes, turns off vacuum, be passed through nitrogen, cools to 70 DEG C of dropwise addition aromatic isocyanates, 70 DEG C of insulations after dripping off
1 hour, then the monohydric alcohol for the amount of skipping over is added dropwise, 70 DEG C of insulations 1 hour or so again after dripping off, sampling detection isocyanate content, when
When content is less than 0.1%, reaction terminates, and removal low volatility materials are vacuumized again, obtains flame plastering agent of the present invention, enters one
Step knot surveys the technical indicators such as hydroxyl value, the viscosity of product.Feed intake formula and experimental data be shown in Table 2.
The flame plastering agent of table 2 is prepared with when experimental data
Embodiment 4-11 is to be formulated flame plastering agent of the present invention and non-invention flame plastering agent carrying out foam system by table 1
Standby and performance detection, as shown in table 3, wherein comparing embodiment (13) is prepared and property its result for the foam of non-flame enrichment flame plastering agent
Energy.
The preparation of the flame laminating polyurethane foam of table 3 and performance
Note：P-430 is three (dipropylene glycol) phosphite esters in table 3
PS-3152 is the benzoic anhydride polyester polyol of Si Taipan companies, and hydroxyl value is：300-330mgKOH/g
Result, which is prepared, from the foam of table 3 shows that preparation and performance of the flame plastering agent of the present invention on foam there are not influence substantially,
And routinely qualified foam can not be made in foaming formulation to non-invention flame plastering agent.
Comparing embodiment 14-15 is adjusted by foam formulation, with foam and performance made from non-invention flame plastering agent,
As a result it is as shown in table 4.
Foam and performance made from the non-invention flame plastering agent of table 4
Note:Pore-creating agent Y-8331 is South Korea's SKC Products in table 4, for promoting foamed open cell
By above-described embodiment 7, embodiment 8, embodiment 9, embodiment 10, embodiment 11, comparing embodiment 13, compare implementation
After foam made from example 14, comparing embodiment 15 fits thing through sample preparation into flame, (laminating) intensity such as table 5 below is peeled off in test.
The peel strength (N/50mm) of flame laminating thing made from each embodiment of table 5
Table 5 is shown, is pasted added with flame plastering agent of the present invention with adding flame prepared by existing response type flame plastering agent
Its peel strength of compound is essentially the same, and is not added with the then peel strength very little of flame plastering agent.
Claims (8)
1. a kind of non-reactive flexible polyurethane foams flame plastering agent, it is characterised in that by the component of following percentage by weight
Crosslinked reaction is made：1-49% low molecular weight diols；20-60% benzoic anhydride polyester polyols；1-30% monohydric alcohols；30-78% virtues
Fragrant race's isocyanates, low molecular weight diols are ethylene glycol, diethylene glycol, propane diols, DPG, butanediol, hexylene glycol, penta 2
One or more of mixtures in alcohol.
2. a kind of non-reactive flexible polyurethane foams flame plastering agent according to claim 1, it is characterised in that benzene
Acid anhydride PEPA be containing the aromatic series composition based on phthalic acid and its derivative, the benzoic anhydride polyester polyol it is flat
Equal degree of functionality is 1.8-2.5, and average hydroxyl value is 50-400mgKOH/g.
3. a kind of non-reactive flexible polyurethane foams flame plastering agent according to claim 1, it is characterised in that institute
State benzoic anhydride polyester polyol and contain hydroxylating composition, its hydroxylating composition is ethylene glycol, propane diols, butanediol, diethylene glycol, two
One or more of mixtures in propane diols, glycerine, trimethylolpropane.
4. a kind of non-reactive flexible polyurethane foams flame plastering agent according to claim 1, it is characterised in that one
First alcohol is one or more of mixtures in methanol, ethanol, isopropanol, n-butanol, isobutanol, amylalcohol, isooctanol.
5. a kind of non-reactive flexible polyurethane foams flame plastering agent according to claim 1, it is characterised in that virtue
Fragrant race's isocyanates is toluene di-isocyanate(TDI), '-diphenylmethane diisocyanate or both mixture.
6. it is a kind of according to any described non-reactive flexible polyurethane foams flame plastering agents of claim 1-5, its feature
It is to be made up of low molecular weight diols, benzoic anhydride polyester polyol, monohydric alcohol and the crosslinked reaction of aromatic isocyanate, isocyanic acid
The weight percentage of ester group and hydroxyl in flame plastering agent is respectively less than 0.5%.
7. a kind of non-reactive flexible polyurethane foams flame plastering agent according to claim 1 is used to prepare flame patch
Share the application of flexible polyurethane foams.
8. application according to claim 7, it is characterised in that non-reactive flexible polyurethane foams flame plastering agent
Consumption is the 1-10% of flame laminating flexible polyurethane foams gross weight, the flame laminating of preparation with flexible polyurethane foams also
Include isocyanates, polyalcohol, phosphonium flame retardant, foaming agent, foam stabilizer and catalyst.
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