CN106589293A - Inflaming-retardant polyurethane leather-carving flexible package composition - Google Patents

Inflaming-retardant polyurethane leather-carving flexible package composition Download PDF

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CN106589293A
CN106589293A CN201611265661.2A CN201611265661A CN106589293A CN 106589293 A CN106589293 A CN 106589293A CN 201611265661 A CN201611265661 A CN 201611265661A CN 106589293 A CN106589293 A CN 106589293A
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flame
parts
component
retardant
leather carving
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CN106589293B (en
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殷玉鹏
徐军
郭勇生
崔玉志
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Shandong Inov Polyurethane Co Ltd
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Shandong Inov Polyurethane Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6688—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271—Hydroxyamines
    • C08G18/3275—Hydroxyamines containing two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271—Hydroxyamines
    • C08G18/3278—Hydroxyamines containing at least three hydroxy groups
    • C08G18/3281—Hydroxyamines containing at least three hydroxy groups containing three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4829—Polyethers containing at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6552—Compounds of group C08G18/63
    • C08G18/6558—Compounds of group C08G18/63 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/657—Compounds of group C08G18/63 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of C08G18/3225 or C08G18/3271 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

本发明涉及一种阻燃聚氨酯皮雕软包组合物，属于高分子材料技术领域。所述的组合物由A组分和B组分组成，以重量份数计，A组份由以下原料制成：高活性聚醚多元醇50～85份，结构型阻燃聚合物多元醇10～30份，高活性聚合物多元醇10～30份，交联剂0.1～2份，泡沫稳定剂0.1～2份，发泡剂1.5～5份，催化剂0.1～2份，阻燃剂0.1～10份；B组份为100份的改性异氰酸酯。本发明的阻燃聚氨酯皮雕软包组合物通过将结构阻燃聚合物多元醇引入到配方体系中，制备得到的聚氨酯材料皮雕软包具有优良的阻燃性能，能够满足室内家具装饰的功能化需求，且其制备方法简单、易实施。The invention relates to a flame-retardant polyurethane leather carving soft bag composition, which belongs to the technical field of polymer materials. The composition is composed of component A and component B. In parts by weight, component A is made of the following raw materials: 50-85 parts of high-activity polyether polyol, 10 parts of structural flame-retardant polymer polyol ～30 parts, high active polymer polyol 10～30 parts, crosslinking agent 0.1～2 parts, foam stabilizer 0.1～2 parts, blowing agent 1.5～5 parts, catalyst 0.1～2 parts, flame retardant 0.1～2 parts 10 parts; B component is 100 parts of modified isocyanate. The flame retardant polyurethane leather carving soft bag composition of the present invention introduces the structural flame retardant polymer polyol into the formula system, and the prepared polyurethane material leather carving soft bag has excellent flame retardancy and can meet the function of indoor furniture decoration needs, and its preparation method is simple and easy to implement.

Description

阻燃聚氨酯皮雕软包组合物Flame-retardant polyurethane leather carving soft bag composition

技术领域technical field

本发明涉及一种阻燃聚氨酯皮雕软包组合物，属于高分子材料技术领域。The invention relates to a flame-retardant polyurethane leather carving soft bag composition, which belongs to the technical field of polymer materials.

背景技术Background technique

随着生活水平的提高，人们对居住环境也越来越注重，每一个家庭的装潢中都要用到背景墙这一块，比如床头背景墙、电视背景墙、沙发背景墙、餐厅背景墙等等，且人们对于背景墙中用到的皮雕软包制品的要求也是越来越高，其中就包括具有阻燃、吸音、隔音、防潮、防霉、抗菌、防水、防油、防尘、防污、防静电、防撞等功能。作为室内家具装饰用的皮雕软包，最为重要的是对于阻燃性能的要求，市场需求在这一方面也存在一定的空缺。With the improvement of living standards, people pay more and more attention to the living environment. Every family decoration must use the background wall, such as bedside background wall, TV background wall, sofa background wall, restaurant background wall, etc. etc., and people's requirements for the leather carving soft package products used in the background wall are getting higher and higher, including flame-retardant, sound-absorbing, sound-proof, moisture-proof, mildew-proof, antibacterial, waterproof, oil-proof, dust-proof, Anti-fouling, anti-static, anti-collision and other functions. As the leather carving soft bag for indoor furniture decoration, the most important thing is the requirement for flame retardancy, and there is a certain gap in market demand in this respect.

发明内容Contents of the invention

本发明的目的是提供一种阻燃聚氨酯皮雕软包组合物，具有阻燃性能优良、制备方法简单的特点。The object of the present invention is to provide a flame-retardant polyurethane leather carving soft bag composition, which has the characteristics of excellent flame-retardant performance and simple preparation method.

本发明所述的阻燃聚氨酯皮雕软包组合物由A组分和B组分组成，其中：The flame retardant polyurethane leather carving soft package composition of the present invention is composed of A component and B component, wherein:

以重量份数计，A组份由以下原料制成：In parts by weight, component A is made from the following raw materials:

以重量份数计，B组份由以下原料制成：In parts by weight, component B is made from the following raw materials:

改性异氰酸酯 100份。Modified isocyanate 100 parts.

其中：in:

所述高活性聚醚多元醇是以丙三醇、三乙醇胺或三羟甲基丙烷中的任意一种或者多种为起始剂，用氧化乙烯封端的聚氧化丙烯三元醇，其伯羟基含量≥75％，数均分子量为4000～8000；The highly reactive polyether polyol is a polyoxypropylene trihydric alcohol terminated with ethylene oxide using any one or more of glycerol, triethanolamine or trimethylolpropane as an initiator, and its primary hydroxyl group Content ≥ 75%, number average molecular weight 4000-8000;

所述结构型阻燃聚合物多元醇是由三聚氰胺和双氰胺利用甲醛进行缩合反应、聚醚多元醇接枝的方法而合成的结构型阻燃聚合物多元醇，其固体质量分数为28％，粒径为90～300nm，粘度2450mPa·s；The structural flame-retardant polymer polyol is a structural flame-retardant polymer polyol synthesized by melamine and dicyandiamide using formaldehyde for condensation reaction and polyether polyol grafting, and its solid mass fraction is 28%. , the particle size is 90-300nm, the viscosity is 2450mPa·s;

所述高活性聚合物多元醇为江苏长华聚氨酯科技有限公司生产的CHP-H28、CHP-H30、CHP-H45中的一种或者多种；The highly active polymer polyol is one or more of CHP-H28, CHP-H30, and CHP-H45 produced by Jiangsu Changhua Polyurethane Technology Co., Ltd.;

所述交联剂为二乙醇胺、三乙醇胺中的一种或两种。The crosslinking agent is one or both of diethanolamine and triethanolamine.

所述泡沫稳定剂为德美世创化工有限公司生产的AK-7705、AK-7706中的一种或两种。The foam stabilizer is one or both of AK-7705 and AK-7706 produced by Demei Shichuang Chemical Co., Ltd.

所述发泡剂为水。The blowing agent is water.

所述催化剂为美国气体化工产品公司生产的Dabco BL-22、Dabco BLV、Dabco R-8020中的一种或多种。The catalyst is one or more of Dabco BL-22, Dabco BLV, and Dabco R-8020 produced by American Gas Chemical Products Company.

所述改性异氰酸酯为山东一诺威聚氨酯股份有限公司生产的DG5411、DG5412、DG5413中的一种或多种。The modified isocyanate is one or more of DG5411, DG5412, and DG5413 produced by Shandong Yinuowei Polyurethane Co., Ltd.

所述阻燃剂为常用的高效水溶性阻燃剂，优选DMMP。The flame retardant is a commonly used high-efficiency water-soluble flame retardant, preferably DMMP.

所述阻燃聚氨酯皮雕软包组合物的使用方法包括以下步骤：The using method of described flame-retardant polyurethane leather carving soft bag composition comprises the following steps:

(1)将配方量的高活性聚醚多元醇、结构阻燃聚合物多元醇、高活性聚合物多元醇加入到反应釜中进行搅拌，然后加入交联剂、催化剂、发泡剂、泡沫稳定剂、阻燃剂，在常温下物理搅拌2～3h，得到A组分；(1) Add high-activity polyether polyol, structural flame-retardant polymer polyol, and high-activity polymer polyol into the reaction kettle for stirring, then add crosslinking agent, catalyst, foaming agent, foam stabilizer agent, flame retardant, and physically stirred at room temperature for 2 to 3 hours to obtain component A;

(2)室温下将A组分和B组分按100:20～70的重量配比混匀，然后将其注入铝制皮雕软包模具中，过1-9min常温熟化脱模即可加工成制品。(2) At room temperature, mix component A and component B according to the weight ratio of 100:20~70, then pour it into the aluminum leather carving soft package mold, after 1-9min aging at room temperature and demoulding, it can be processed into products.

本发明的有益效果如下：The beneficial effects of the present invention are as follows:

本发明的阻燃聚氨酯皮雕软包组合物通过将结构阻燃聚合物多元醇引入到配方体系中，制备得到的聚氨酯材料皮雕软包具有优良的阻燃性能，能够满足室内家具装饰的功能化需求，且其制备方法简单、易实施。The flame retardant polyurethane leather carving soft bag composition of the present invention introduces the structural flame retardant polymer polyol into the formula system, and the prepared polyurethane material leather carving soft bag has excellent flame retardancy and can meet the function of indoor furniture decoration needs, and its preparation method is simple and easy to implement.

具体实施方式detailed description

以下结合实施例对本发明做进一步描述。The present invention is further described below in conjunction with embodiment.

实施例1Example 1

A组分：将50kg高活性聚醚多元醇、30kg结构阻燃聚合物多元醇、25kg高活性聚合物多元醇CHP-H28加入到反应釜中进行搅拌，然后依次加入1.2kg二乙醇胺、1.2kg AK-7705、2.5kg水、1.3kg Dabco BL-22、2.0kg DMMP，常温下物理搅拌2.0h，取样进行检测，满足各项检测指标，即得A组分的合格产品，从反应釜中放料装桶入库。Component A: Add 50kg of high-activity polyether polyol, 30kg of structural flame-retardant polymer polyol, and 25kg of high-activity polymer polyol CHP-H28 into the reactor for stirring, then add 1.2kg of diethanolamine, 1.2kg of AK-7705, 2.5kg of water, 1.3kg of Dabco BL-22, 2.0kg of DMMP, physically stirred at room temperature for 2.0h, sampling for testing, to meet the test indicators, that is, the qualified product of component A, put it from the reaction kettle The material is loaded into barrels and put into storage.

B组分：DG5411Component B: DG5411

使用时，室温下将A组分和B组分按100:50的重量配比进行机械混匀，然后注入铝制皮雕软包模具中，经过1min常温熟化脱模即可加工成制品。When in use, mechanically mix components A and B at a weight ratio of 100:50 at room temperature, then inject them into an aluminum leather carving soft package mold, and process them into finished products after 1 minute of aging at room temperature and demoulding.

实施例2Example 2

将70kg高活性聚醚多元醇、15kg结构阻燃聚合物多元醇、20kg高活性聚合物多元醇CHP-H28加入到反应釜中进行搅拌，然后依次加入1.2kg三乙醇胺、1.2kg AK-7706、3.0kg水、1.3kg Dabco BLV、2.0kg DMMP，常温下物理搅拌4.0h，取样进行检测，满足各项检测指标，即得A组分的合格产品，从反应釜中放料装桶入库；Add 70kg of highly active polyether polyol, 15kg of structural flame-retardant polymer polyol, and 20kg of highly active polymer polyol CHP-H28 into the reactor for stirring, then add 1.2kg of triethanolamine, 1.2kg of AK-7706, 3.0kg of water, 1.3kg of Dabco BLV, and 2.0kg of DMMP were physically stirred at room temperature for 4.0 hours, and samples were taken for inspection. If all inspection indicators were met, the qualified product of component A was obtained, and the material was discharged from the reactor and put into storage;

B组分：DG5412Component B: DG5412

使用时，室温下将A组分和B组分按100:30的重量配比进行机械混匀，然后注入铝制皮雕软包模具中，经过3min常温熟化脱模即可加工成制品。When in use, mechanically mix components A and B at a weight ratio of 100:30 at room temperature, then inject them into an aluminum leather carving soft package mold, and process them into finished products after 3 minutes of aging at room temperature and demoulding.

实施例3Example 3

分别称量：高活性聚醚多元醇80公斤，结构阻燃聚合物多元醇45公斤，高活性聚合物多元醇CHP-H28为15公斤，交联剂二乙醇胺1.8公斤，泡沫稳定剂AK-7705为1.6公斤，水4.0公斤，催化剂Dabco R-8020为1.5公斤，DMMP为4.0公斤。Weigh respectively: 80 kg of high-activity polyether polyol, 45 kg of structural flame-retardant polymer polyol, 15 kg of high-activity polymer polyol CHP-H28, 1.8 kg of crosslinking agent diethanolamine, and foam stabilizer AK-7705 1.6 kg of water, 4.0 kg of water, 1.5 kg of catalyst Dabco R-8020, and 4.0 kg of DMMP.

A组分：将80kg高活性聚醚多元醇、45kg结构阻燃聚合物多元醇、15kg高活性聚合物多元醇CHP-H28加入到反应釜中进行搅拌，然后依次加入1.8kg二乙醇胺、1.6kg AK-7705、4.0kg水、1.5kg Dabco R-8020、4.0kg DMMP，常温下物理搅拌3.5h，取样进行检测，满足各项检测指标，即得A组分的合格产品，从反应釜中放料装桶入库；Component A: Add 80kg of high-activity polyether polyol, 45kg of structural flame-retardant polymer polyol, and 15kg of high-activity polymer polyol CHP-H28 into the reactor for stirring, then add 1.8kg of diethanolamine, 1.6kg of AK-7705, 4.0kg water, 1.5kg Dabco R-8020, 4.0kg DMMP, physical stirring at room temperature for 3.5h, sampling for testing, meet all testing indicators, that is, the qualified product of component A, put it from the reaction kettle Material loading into barrels;

B组分料：DG5413B component material: DG5413

使用时，室温下将A组分和B组分按100:60的重量配比进行机械混匀，然后注入铝制皮雕软包模具中，经过9min常温熟化脱模即可加工成制品。When in use, mechanically mix components A and B at a weight ratio of 100:60 at room temperature, then inject them into an aluminum leather carving soft package mold, and process them into products after 9 minutes of aging at room temperature and demoulding.

Claims (7)

1.一种阻燃聚氨酯皮雕软包组合物，其特征在于：由A组分和B组分组成，其中：1. A flame-retardant polyurethane leather carving soft bag composition, characterized in that: it consists of A component and B component, wherein: 以重量份数计，A组份由以下原料制成：In parts by weight, component A is made from the following raw materials: 其中，所述高活性聚醚多元醇是以丙三醇、三乙醇胺或三羟甲基丙烷中的任意一种或者多种为起始剂，用氧化乙烯封端的聚氧化丙烯三元醇，其伯羟基含量≥75％，数均分子量为4000～8000；Wherein, the highly reactive polyether polyol is a polyoxypropylene trihydric alcohol terminated with ethylene oxide, using any one or more of glycerol, triethanolamine or trimethylolpropane as an initiator. Primary hydroxyl content ≥ 75%, number average molecular weight 4000-8000; 所述结构型阻燃聚合物多元醇是由三聚氰胺和双氰胺利用甲醛进行缩合反应、聚醚多元醇接枝的方法而合成的结构型阻燃聚合物多元醇，其固体质量分数为28wt％，粒径为90～300nm，粘度2450mPa·s；The structural flame-retardant polymer polyol is a structural flame-retardant polymer polyol synthesized by melamine and dicyandiamide using formaldehyde for condensation reaction and polyether polyol grafting, and its solid mass fraction is 28wt% , the particle size is 90-300nm, the viscosity is 2450mPa·s; 所述高活性聚合物多元醇为江苏长华聚氨酯科技有限公司生产的CHP-H28、CHP-H30、CHP-H45中的一种或者多种；The highly active polymer polyol is one or more of CHP-H28, CHP-H30, and CHP-H45 produced by Jiangsu Changhua Polyurethane Technology Co., Ltd.; 以重量份数计，B组份由以下原料制成：In parts by weight, component B is made from the following raw materials: 改性异氰酸酯 100份。Modified isocyanate 100 parts. 2.根据权利要求1所述的阻燃聚氨酯皮雕软包组合物，其特征在于：交联剂为二乙醇胺、三乙醇胺中的一种或两种。2. The flame retardant polyurethane leather carving soft bag composition according to claim 1, characterized in that: the crosslinking agent is one or both of diethanolamine and triethanolamine. 3.根据权利要求1所述的阻燃聚氨酯皮雕软包组合物，其特征在于：泡沫稳定剂为德美世创化工有限公司生产的AK-7705、AK-7706中的一种或两种。3. The flame retardant polyurethane leather carving soft bag composition according to claim 1, characterized in that: the foam stabilizer is one or both of AK-7705 and AK-7706 produced by Demei Shichuang Chemical Co., Ltd. 4.根据权利要求1所述的阻燃聚氨酯皮雕软包组合物，其特征在于：发泡剂为水。4. The flame-retardant polyurethane leather carving soft bag composition according to claim 1, characterized in that: the foaming agent is water. 5.根据权利要求1所述的阻燃聚氨酯皮雕软包组合物，其特征在于：催化剂为美国气体化工产品公司生产的Dabco BL-22、Dabco BLV、Dabco R-8020中的一种或多种。5. The flame retardant polyurethane leather carving soft bag composition according to claim 1, characterized in that: the catalyst is one or more of Dabco BL-22, Dabco BLV, and Dabco R-8020 produced by American Gas Chemical Products Company kind. 6.根据权利要求1所述的阻燃聚氨酯皮雕软包组合物，其特征在于：改性异氰酸酯为山东一诺威聚氨酯股份有限公司生产的DG5411、DG5412、DG5413中的一种或多种。6. The flame-retardant polyurethane leather carving soft bag composition according to claim 1, wherein the modified isocyanate is one or more of DG5411, DG5412, and DG5413 produced by Shandong Yinuowei Polyurethane Co., Ltd. 7.根据权利要求1所述的阻燃聚氨酯皮雕软包组合物，其特征在于：使用方法包括以下步骤：7. The flame-retardant polyurethane leather carving soft package composition according to claim 1, wherein the method of use comprises the following steps: (1)将配方量的高活性聚醚多元醇、结构阻燃聚合物多元醇、高活性聚合物多元醇加入到反应釜中进行搅拌，然后加入交联剂、催化剂、发泡剂、泡沫稳定剂、阻燃剂，在常温下物理搅拌2～3h，得到A组分；(1) Add high-activity polyether polyol, structural flame-retardant polymer polyol, and high-activity polymer polyol into the reaction kettle for stirring, then add crosslinking agent, catalyst, foaming agent, foam stabilizer agent, flame retardant, and physically stirred at room temperature for 2 to 3 hours to obtain component A; (2)室温下将A组分和B组分按100:20～70的重量配比混匀，然后将其注入铝制皮雕软包模具中，过1-9min常温熟化脱模即可加工成制品。(2) At room temperature, mix component A and component B according to the weight ratio of 100:20~70, then pour it into the aluminum leather carving soft package mold, after 1-9min aging at room temperature and demoulding, it can be processed into products.
CN201611265661.2A 2016-12-31 2016-12-31 Flame retardant polyurethane leather carving soft package composition Expired - Fee Related CN106589293B (en)

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