CN106751155A - A kind of fire-retardant athletic floor - Google Patents
A kind of fire-retardant athletic floor Download PDFInfo
- Publication number
- CN106751155A CN106751155A CN201611083195.6A CN201611083195A CN106751155A CN 106751155 A CN106751155 A CN 106751155A CN 201611083195 A CN201611083195 A CN 201611083195A CN 106751155 A CN106751155 A CN 106751155A
- Authority
- CN
- China
- Prior art keywords
- parts
- retardant
- fire
- athletic
- floor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000386 athletic effect Effects 0.000 title claims abstract description 32
- 239000003063 flame retardant Substances 0.000 title claims abstract description 29
- 239000000843 powder Substances 0.000 claims abstract description 37
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 17
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 17
- 239000010445 mica Substances 0.000 claims abstract description 17
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 239000003381 stabilizer Substances 0.000 claims abstract description 15
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical class [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 14
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 11
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 11
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 claims description 8
- 239000003822 epoxy resin Substances 0.000 claims description 8
- 229920000647 polyepoxide Polymers 0.000 claims description 8
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- 239000004250 tert-Butylhydroquinone Substances 0.000 claims description 4
- 235000019281 tert-butylhydroquinone Nutrition 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 claims description 2
- 239000010426 asphalt Substances 0.000 claims description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 2
- 238000002347 injection Methods 0.000 claims description 2
- 239000007924 injection Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000005453 pelletization Methods 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 238000007670 refining Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- -1 hydrogen Aluminum oxide Chemical class 0.000 claims 2
- 235000010388 propyl gallate Nutrition 0.000 claims 2
- 239000000473 propyl gallate Substances 0.000 claims 2
- 229940075579 propyl gallate Drugs 0.000 claims 2
- 240000006927 Foeniculum vulgare Species 0.000 claims 1
- 235000004204 Foeniculum vulgare Nutrition 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 239000004411 aluminium Substances 0.000 claims 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 5
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000002861 polymer material Substances 0.000 abstract description 2
- 229920001596 poly (chlorostyrenes) Polymers 0.000 description 6
- 150000001336 alkenes Chemical class 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 229940024545 aluminum hydroxide Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019282 butylated hydroxyanisole Nutrition 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical group Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to technical field of polymer materials, specifically on a kind of fire-retardant athletic floor, the floor includes that the raw material of following weight portion is made：37 parts of modified aluminium hydroxide, 100 150 parts of polyvinyl chloride, 13 parts of stabilizer, 0.5 1 parts of antioxidant, 70 90 parts of mica powder, 15 30 parts of rubber powder.The method of the invention uses small rubber powder, can be filled into the cavity of other components formation, so that the floor produced is entirely capable of reaching the use requirement of athletic floor, there is good elasticity simultaneously, it is also that product surface has minimum shrinkage factor, the product also has very excellent flame-retarding characteristic, safety and environmental protection.
Description
Technical field
The present invention relates to technical field of polymer materials, specifically on a kind of fire-retardant athletic floor.
Background technology
At present, PVC plastic flooring material is international formal including the optimal of all ball game places including basketball
Selection, may be used to lay the rooms such as internationally recognized shuttlecock, table tennis, vollyball, handball by the PVC athletic floors of certification
Interior competition area.The type athletic floor have it is certain it is fire-retardant, moistureproof, anti-skidding, the coefficient of expansion is extremely low, anti-chemical contamination, anti-
Electrostatic, termite-proof characteristic, it is removed in addition, movement is more convenient, daily especially to safeguard, is had a wide range of applications.It is existing
Common plasticses athletic floor facestock can not meet the requirement growing to its performance, therefore, to existing floor need
Further to improve, improve its physical properties.
The content of the invention
It is an object of the invention to provide a kind of fire-retardant athletic floor, with elasticity it is good, durable, fire-retardant the characteristics of.
A kind of fire-retardant athletic floor, the floor includes that the raw material of following weight portion is made：Modified aluminium hydroxide 3-7 parts,
Polyvinyl chloride 100-150 parts, stabilizer 1-3 parts, antioxidant 0.5-1 parts, mica powder 60-90 parts, rubber powder 15-30 parts.It is described
Modified aluminium hydroxide is according to mass ratio 1 by titanate coupling agent and micron aluminium-hydroxide powder:100 formula is added, then high
Speed stirring is obtained.
Preferably, the fire-retardant athletic floor, the floor includes that the raw material of following weight portion is made：Modified aluminium hydroxide
3-5 parts, polyvinyl chloride 120-150 parts, stabilizer 1-2 parts, antioxidant 0.5-0.8 parts, mica powder 70-85 parts, rubber powder 15-25
Part.
Preferably, the fire-retardant athletic floor, also including epoxy resin 10-20 parts.
Preferably, the fire-retardant athletic floor, is made up of the raw material of following weight portion：Modified aluminium hydroxide 4-7 parts, polychlorostyrene
Ethene 130-140 parts, stabilizer 2.5-3 parts, antioxidant 0.8-1 parts, mica powder 80-85 parts, rubber powder 20-25 parts, asphalt mixtures modified by epoxy resin
Fat 15-20 parts.
Preferably, the fire-retardant athletic floor, is made up of the raw material of following weight portion：5 parts of modified aluminium hydroxide, polychlorostyrene second
135 parts of alkene, 2.5 parts of stabilizer, 0.9 part of antioxidant, 80 parts of mica powder, 25 parts of rubber powder, 18 parts of epoxy resin.
Preferably, the mica Powder Particle Size is 150-300 mesh.
Preferably, the rubber Powder Particle Size is 100-130 mesh.
Preferably, the stabilizer is vinyl trichlorosilane, VTES and vinyl trimethoxy
One or more in silane.
Preferably, the antioxidant is butylated hydroxy anisole (BHA), dibutyl hydroxy toluene (BHT), gallic acid third
One or more in ester (PG) and TBHQ (TBHQ).
Present invention also offers the preparation method of the fire-retardant athletic floor, comprise the following steps：
（1）Raw material is taken by proportioning and be well mixed；
（2）It is stirred in the material input homogenizer that will be mixed, is 1000-1200 revs/min of high-speed stirred with speed
Time 100-150s, then switch to 650 revs/min of stirring at low speed 60-80s, then it is transferred in banbury, refined at 150-160 DEG C
Modeling 150-200s；
（3）By after refining modeling treatment, being transferred in double screw extruder, extruding pelletization, eventually pass injection and obtain product.
Beneficial effect of the present invention：
Compared with prior art, the method for the invention uses small rubber powder, can be filled into the cavity of other components formation
It is interior, so that the floor produced is entirely capable of reaching the use requirement of athletic floor, while having good elasticity, also make product
Surface has minimum shrinkage factor, and the product also has very excellent flame-retarding characteristic, safety and environmental protection.
Specific embodiment
With reference to embodiment, the present invention is further described.
Embodiment 1
A kind of fire-retardant athletic floor, the floor includes that the raw material of following weight portion is made：3 parts of modified aluminium hydroxide, polychlorostyrene second
100 parts of alkene, 1.5 parts of stabilizer, 0.5 part of antioxidant, 60 parts of mica powder, 15 parts of rubber powder.
Embodiment 2
A kind of fire-retardant athletic floor, the floor includes that the raw material of following weight portion is made：7 parts of modified aluminium hydroxide, polychlorostyrene second
125 parts of alkene, 2 parts of stabilizer, 0.8 part of antioxidant, 85 parts of mica powder, 20 parts of rubber powder.
Embodiment 3
A kind of fire-retardant athletic floor, the floor includes that the raw material of following weight portion is made：4 parts of modified aluminium hydroxide, polychlorostyrene second
120 parts of alkene, 1 part of stabilizer, 0.8 part of antioxidant, 85 parts of mica powder, 15 parts of rubber powder.
Embodiment 4
A kind of fire-retardant athletic floor, the floor includes that the raw material of following weight portion is made：5 parts of modified aluminium hydroxide, polychlorostyrene second
100 parts of alkene, 1 part of stabilizer, 0.5 part of antioxidant, 90 parts of mica powder, 15 parts of rubber powder.
Embodiment 5
A kind of fire-retardant athletic floor, is made up of the raw material of following weight portion：It is 6 parts of modified aluminium hydroxide, 135 parts of polyvinyl chloride, steady
Determine 2.5 parts of agent, 0.9 part of antioxidant, 80 parts of mica powder, 25 parts of rubber powder, 18 parts of epoxy resin.
Embodiment 6
A kind of fire-retardant athletic floor, is made up of the raw material of following weight portion：It is 5 parts of modified aluminium hydroxide, 140 parts of polyvinyl chloride, steady
Determine 3 parts of agent, 1 part of antioxidant, 85 parts of mica powder, 25 parts of rubber powder, 15 parts of epoxy resin.
Although reference be made herein to invention has been described for explanatory embodiment of the invention, when above-described embodiment is only this
Invention preferably one of implementation method, embodiments of the present invention are simultaneously not restricted to the described embodiments, it should be appreciated that this area
Technical staff can be designed that a lot of other modification and implementation methods, and these modifications and implementation method will fall in disclosure
Spirit and spirit within.
Claims (10)
1. a kind of fire-retardant athletic floor, it is characterised in that the floor includes that the raw material of following weight portion is made：Modified hydroxide
Aluminium 3-7 parts, polyvinyl chloride 100-150 parts, stabilizer 1-3 parts, antioxidant 0.5-1 parts, mica powder 60-90 parts, rubber powder 15-30
Part.
2. fire-retardant athletic floor according to claim 1, it is characterised in that the floor includes the raw material system of following weight portion
Into：Modified aluminium hydroxide 3-5 parts, polyvinyl chloride 120-150 parts, stabilizer 1-2 parts, antioxidant 0.5-0.8 parts, mica powder 70-
85 parts, rubber powder 15-25 parts.
3. fire-retardant athletic floor according to claim 1, it is characterised in that also including epoxy resin 10-20 parts.
4. fire-retardant athletic floor according to claim 3, it is characterised in that be made up of the raw material of following weight portion：Modified hydrogen
Aluminum oxide 4-7 parts, polyvinyl chloride 130-140 parts, stabilizer 2.5-3 parts, antioxidant 0.8-1 parts, mica powder 80-85 parts, rubber
Powder 20-25 parts, epoxy resin 15-20 parts.
5. fire-retardant athletic floor according to claim 4, it is characterised in that be made up of the raw material of following weight portion：Modified hydrogen
5 parts of aluminum oxide, 135 parts of polyvinyl chloride, 2.5 parts of stabilizer, 0.9 part of antioxidant, 80 parts of mica powder, 25 parts of rubber powder, asphalt mixtures modified by epoxy resin
18 parts of fat.
6. according to any fire-retardant athletic floors of claim 1-5, it is characterised in that：The mica Powder Particle Size is 150-300
Mesh.
7. according to any fire-retardant athletic floors of claim 1-5, it is characterised in that：The rubber Powder Particle Size is 100-130
Mesh.
8. according to any fire-retardant athletic floors of claim 1-5, it is characterised in that：The stabilizer is vinyl trichlorine silicon
One or more in alkane, VTES and vinyltrimethoxy silane.
9. according to any fire-retardant athletic floors of claim 1-5, it is characterised in that：The antioxidant is butylhydroxy fennel
It is a kind of or many in ether (BHA), dibutyl hydroxy toluene (BHT), propylgallate (PG) and TBHQ (TBHQ)
Kind.
10. as described in claim 1-5 is any fire-retardant athletic floor preparation method, it is characterised in that comprise the following steps：
（1）Raw material is taken by proportioning and be well mixed；
（2）It is stirred in the material input homogenizer that will be mixed, is 1000-1200 revs/min of high-speed stirred with speed
Time 100-150s, then switch to 650 revs/min of stirring at low speed 60-80s, then it is transferred in banbury, refined at 150-160 DEG C
Modeling 150-200s；
（3）By after refining modeling treatment, being transferred in double screw extruder, extruding pelletization, eventually pass injection and obtain product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611083195.6A CN106751155A (en) | 2016-11-30 | 2016-11-30 | A kind of fire-retardant athletic floor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611083195.6A CN106751155A (en) | 2016-11-30 | 2016-11-30 | A kind of fire-retardant athletic floor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106751155A true CN106751155A (en) | 2017-05-31 |
Family
ID=58898230
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611083195.6A Pending CN106751155A (en) | 2016-11-30 | 2016-11-30 | A kind of fire-retardant athletic floor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106751155A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109370111A (en) * | 2018-10-25 | 2019-02-22 | 申彦芳 | A kind of preparation method of high-strength fire-retardant plastic floor material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101538393A (en) * | 2009-04-23 | 2009-09-23 | 福建思嘉环保材料科技有限公司 | High-elastic wearproof athletic floor material and preparation method thereof |
| CN103146094A (en) * | 2011-12-07 | 2013-06-12 | 滁州格美特科技有限公司 | Modified plastic, and preparation method and application thereof |
| CN104927245A (en) * | 2015-06-30 | 2015-09-23 | 青岛宇星智能科技开发有限公司 | Outdoor wearproof floor |
| CN104945776A (en) * | 2015-06-30 | 2015-09-30 | 青岛精石通精密机械制造有限公司 | Outdoor sports floorboard |
-
2016
- 2016-11-30 CN CN201611083195.6A patent/CN106751155A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101538393A (en) * | 2009-04-23 | 2009-09-23 | 福建思嘉环保材料科技有限公司 | High-elastic wearproof athletic floor material and preparation method thereof |
| CN103146094A (en) * | 2011-12-07 | 2013-06-12 | 滁州格美特科技有限公司 | Modified plastic, and preparation method and application thereof |
| CN104927245A (en) * | 2015-06-30 | 2015-09-23 | 青岛宇星智能科技开发有限公司 | Outdoor wearproof floor |
| CN104945776A (en) * | 2015-06-30 | 2015-09-30 | 青岛精石通精密机械制造有限公司 | Outdoor sports floorboard |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109370111A (en) * | 2018-10-25 | 2019-02-22 | 申彦芳 | A kind of preparation method of high-strength fire-retardant plastic floor material |
| CN109370111B (en) * | 2018-10-25 | 2021-04-02 | 东阳市茂盛塑胶有限公司 | Preparation method of high-strength fireproof plastic floor material |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |
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| RJ01 | Rejection of invention patent application after publication |