CN106777535B - Alkali-activated recycled concrete mix proportion design method and system - Google Patents
Alkali-activated recycled concrete mix proportion design method and system Download PDFInfo
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Abstract
Description
技术领域technical field
本发明涉及到混凝土制备领域,特别是涉及到一种碱激发再生混凝土配合比设计方法及系统。The invention relates to the field of concrete preparation, in particular to a method and a system for designing the mixing ratio of alkali-excited recycled concrete.
背景技术Background technique
混凝土,是指由胶凝材料将骨料胶结成整体的工程复合材料的统称。通常讲的混凝土一词是指用水泥作胶凝材料,砂、石作骨料;与水(可含外加剂和掺合料)按一定比例配合,经搅拌而得的水泥混凝土,也称普通混凝土,它广泛应用于土木工程。再生混凝土,是指将废弃的混凝土块经过破碎、清洗、分级后,按一定比例与级配混合,部分或全部代替砂石等天然骨料(主要是粗骨料),再加入水泥、水等配而成的新混凝土。再生混凝土按骨料的组合形式可以有以下几种情况:骨料全部为再生集料;粗骨料为再生骨料、细骨料为天然砂;粗骨料为天然碎石或卵石、细骨料为再生骨料;再生骨料替代部分粗骨料或细骨料。Concrete is a general term for engineering composite materials in which aggregates are cemented into a whole by cementitious materials. The term concrete usually refers to cement concrete as cementing material, sand and stone as aggregate; it is mixed with water (may contain admixtures and admixtures) in a certain proportion, and the cement concrete obtained by stirring is also called ordinary concrete. Concrete, which is widely used in civil engineering. Recycled concrete means that after crushing, cleaning and grading waste concrete blocks, they are mixed with the gradation in a certain proportion, partially or completely replacing natural aggregates such as sand and gravel (mainly coarse aggregates), and then adding cement, water, etc. Made of new concrete. According to the combination of aggregates, recycled concrete can be in the following situations: all aggregates are recycled aggregates; coarse aggregates are recycled aggregates, and fine aggregates are natural sand; The raw material is regenerated aggregate; regenerated aggregate replaces part of coarse aggregate or fine aggregate.
随着混凝土技术的不断发展,人们对于混凝土这一建筑材料认识不断加深,考虑可持续发展设计理念以及对生态环境的保护的观念日益加深。但由于目前传统波特兰水泥的大量应用不仅消耗着大量的自然资源,同时在制备过程中以及后期使用会排放出大量的气体。根据最新研究,全球范围内每年仅水泥产业就产生1.8Gt的排放量,大约占了人类生产过程中排放总量的5-7%。数据表明,每吨水泥会产生0.8t的排放量。因此,利用工业废渣和来自建筑废弃物的再生骨料制备的再生混凝土具有重要意义。再生混凝土,是指将废弃的混凝土块经过破碎、清洗、分级后,按一定比例与级配混合,部分或全部代替砂石等天然骨料(主要是粗骨料),再加入水泥、水等配而成的新混凝土。再生混凝土按骨料的组合形式可以有以下几种情况:骨料全部为再生集料;粗骨料为再生骨料、细骨料为天然砂;粗骨料为天然碎石或卵石、细骨料为再生骨料;再生骨料替代部分粗骨料或细骨料。与传统的波特兰水泥混凝土相比,碱激发再生混凝土既可以有效解决大量建筑废弃物的处理问题,又能实现对废弃物的再生利用从而节约自然资源,兼顾生态与环保效益。此外,该种混凝土利用碱激发胶凝材料取代传统的水泥胶材,能够大幅度降低混凝土制备过程中由于使用水泥胶凝材料带来的碳排放,因而进一步体现了“绿色发展”的思想。With the continuous development of concrete technology, people's understanding of concrete as a building material is deepening, and the concept of considering sustainable development design concepts and the protection of ecological environment is deepening. However, due to the current large-scale application of traditional Portland cement, it not only consumes a large amount of natural resources, but also emits a large amount of gas during the preparation process and later use. According to the latest research, the cement industry alone produces 1.8Gt of emissions every year worldwide, accounting for about 5-7% of the total emissions from human production. The data shows that every ton of cement will produce 0.8t of emissions. Therefore, recycled concrete prepared from industrial waste residue and recycled aggregate from construction waste is of great significance. Recycled concrete means that after crushing, cleaning and grading waste concrete blocks, they are mixed with the gradation in a certain proportion, partially or completely replacing natural aggregates such as sand and gravel (mainly coarse aggregates), and then adding cement, water, etc. Made of new concrete. According to the combination of aggregates, recycled concrete can be in the following situations: all aggregates are recycled aggregates; coarse aggregates are recycled aggregates, and fine aggregates are natural sand; The raw material is regenerated aggregate; regenerated aggregate replaces part of coarse aggregate or fine aggregate. Compared with traditional Portland cement concrete, alkali-activated recycled concrete can not only effectively solve the problem of processing a large amount of construction waste, but also realize the recycling of waste to save natural resources and take into account ecological and environmental benefits. In addition, this kind of concrete uses alkali-excited cementitious materials to replace traditional cement cement materials, which can greatly reduce the carbon emissions caused by the use of cement cementitious materials in the process of concrete preparation, thus further embodying the idea of "green development".
目前为止,尽管各国学者对于碱激发混凝土的研究已经取得了诸多成果,也提出了不少配合比设计方法,但以完全的再生粗骨料替代天然骨料制备碱激发混凝土的报道至今仍比较少见。现有的配合比设计方案,存在无法兼顾最终产品强度与耐久性能的问题,或者只是简单的将混凝土密度设定为一恒定值进行配合比的计算。另外ObadaKayali指出,推广碱激发混凝土的工程应用当务之急在于提出一套适宜的、简单实用的配合比设计方法。So far, although scholars from all over the world have achieved many achievements in the research on alkali-excited concrete and proposed many mixing ratio design methods, reports on the preparation of alkali-excited concrete with completely recycled coarse aggregate instead of natural aggregate are still relatively rare. . The existing mix ratio design scheme has the problem of not taking into account the strength and durability of the final product, or simply setting the concrete density to a constant value to calculate the mix ratio. In addition, Obada Kayali pointed out that the most urgent task to promote the engineering application of alkali-induced concrete is to propose a suitable, simple and practical mix proportion design method.
发明内容SUMMARY OF THE INVENTION
本发明的主要目的为提供一种碱激发再生混凝土配合比设计方法及系统,根据混凝土各组分之间的实际关系进行计算,适用范围更广,得到准确的配合比。The main purpose of the present invention is to provide a method and system for designing the mix ratio of alkali-excited recycled concrete, which is calculated according to the actual relationship between the various components of the concrete, has a wider application range, and obtains an accurate mix ratio.
本发明提出了一种碱激发再生混凝土配合比设计方法,包括以下步骤:The present invention provides a method for designing the mix proportion of alkali-excited recycled concrete, which includes the following steps:
根据应用场景的性能要求,确定目标碱激发再生混凝土的目标抗压强度fcu,k,并选定适合的碱胶比A/B和强度标准差σk;According to the performance requirements of the application scenario, determine the target compressive strength f cu,k of the target alkali-excited recycled concrete, and select the appropriate alkali-binder ratio A/B and strength standard deviation σ k ;
根据fcu,0≥fcu,k+1.645σk,得到fcu,0具体数值,其中fcu,0为碱激发再生混凝土的试配强度;According to f cu,0 ≥f cu,k +1.645σ k , the specific value of f cu, 0 is obtained, where f cu,0 is the trial strength of alkali-excited recycled concrete;
根据碱胶比A/B,得到对应的回归系数αa、αb和胶砂28d抗压强度fb取值,再根据碱胶比A/B、试配强度fcu,0、回归系数αa、αb和胶砂28d抗压强度fb,计算得到水固比W/GPS;According to the alkali-binder ratio A/B, the corresponding regression coefficients α a , α b and the 28d compressive strength f b of the mortar are obtained, and then according to the alkali-binder ratio A/B, trial strength f cu,0 , regression coefficient α a , α b and the 28d compressive strength f b of the mortar, the water-solid ratio W/GPS is calculated;
根据碱胶比A/B、水固比W/GPS、浆骨质量比和砂率使用浆骨质量比法计算得到碱激发再生混凝土中各组分的含量。The content of each component in the alkali-excited recycled concrete was calculated according to the alkali-binder ratio A/B, water-solid ratio W/GPS, pulp-bone mass ratio and sand ratio using the pulp-bone mass ratio method.
进一步地,所述根据具体应用场景的性能要求,确定碱激发再生混凝土的目标抗压强度fcu,k,并选定适合的碱胶比A/B和强度标准差σ步骤之前,包括:Further, before the steps of determining the target compressive strength f cu,k of the alkali-excited recycled concrete according to the performance requirements of specific application scenarios, and selecting a suitable alkali-to-binder ratio A/B and strength standard deviation σ, the steps include:
根据公式计算得到碱激发再生混凝土不同的抗压强度fcu对应的强度标准差σ,并将抗压强度fcu数值和与其对应的强度标准差σ一一对应存储为标准差数据库。According to the formula The strength standard deviation σ corresponding to different compressive strength f cu of alkali-excited recycled concrete is calculated, and the compressive strength f cu value and its corresponding strength standard deviation σ are stored as a standard deviation database in one-to-one correspondence.
进一步地,所述根据具体应用场景的性能要求,确定碱激发再生混凝土的目标抗压强度fcu,k,并选定适合的碱胶比A/B和强度标准差σk步骤,包括:Further, according to the performance requirements of specific application scenarios, the steps of determining the target compressive strength f cu,k of the alkali-excited recycled concrete, and selecting a suitable alkali-to-binder ratio A/B and strength standard deviation σ k include:
将目标抗压强度fcu,k和标准差数据库中抗压强度fcu数据进行匹配,找到目标抗压强度fcu,k数值对应的目标强度标准差σk数值。Match the target compressive strength f cu, k with the compressive strength f cu data in the standard deviation database, and find the target strength standard deviation σ k value corresponding to the target compressive strength f cu,k value.
进一步地,所述根据碱胶比A/B,得到对应的回归系数αa、αb和胶砂28d抗压强度fb取值,再根据碱胶比A/B、试配强度fcu,0、回归系数αa、αb和胶砂28d抗压强度fb,计算得到水固比W/GPS,包括:Further, according to the alkali to glue ratio A/B, obtain the corresponding regression coefficients α a , α b and the compressive strength f b of the mortar 28d value, then according to the alkali glue ratio A/B, the trial strength f cu, 0 , the regression coefficients α a , α b and the 28d compressive strength f b of the mortar, the water-solid ratio W/GPS is calculated, including:
通过公式计算得到水固比W/GPS。by formula Calculate the water-solid ratio W/GPS.
进一步地,所述根据碱胶比A/B、水固比W/GPS、浆骨质量比和砂率使用浆骨质量比法计算得到碱激发再生混凝土中各组分的含量步骤,包括:Further, the step of calculating the content of each component in the alkali-excited recycled concrete according to the alkali-binder ratio A/B, the water-solid ratio W/GPS, the pulp-bone mass ratio and the sand ratio using the pulp-bone mass ratio method, comprising:
使用以下关系等式进行计算,It is calculated using the following relational equation,
胶凝组分用量*碱胶比=碱溶液*碱固体质量分数;The amount of gelling components * alkali to glue ratio = alkali solution * alkali solid mass fraction;
碱溶液*(1-碱固体质量分数)+额外水=(胶凝组分用量+碱溶液*碱固体质量分数)*水固比;Alkaline solution*(1-alkali solid mass fraction)+additional water=(amount of gelling component+alkali solution*alkali solid mass fraction)*water-solid ratio;
(胶凝组分用量+碱溶液+额外水)*浆骨质量比=再生粗骨料+细骨料;(amount of gelling component + alkali solution + additional water) * pulp-bone mass ratio = regenerated coarse aggregate + fine aggregate;
细骨料=(再生粗骨料+细骨料)*砂率;Fine aggregate = (recycled coarse aggregate + fine aggregate) * sand rate;
再生粗骨料=(再生粗骨料+细骨料)-细骨料;Regenerated coarse aggregate = (regenerated coarse aggregate + fine aggregate) - fine aggregate;
矿粉用量=胶凝组分用量*90%;The amount of mineral powder = the amount of gelling components * 90%;
粉煤灰用量=胶凝组分用量-矿粉用量。The amount of fly ash = the amount of cementitious components - the amount of mineral powder.
本发明还提出了一种碱激发再生混凝土配合比设计系统,包括:The present invention also proposes an alkali-excited recycled concrete mix ratio design system, including:
目标参数单元,用于根据应用场景的性能要求,确定目标碱激发再生混凝土的目标抗压强度fcu,k,并选定适合的碱胶比A/B和强度标准差σk;The target parameter unit is used to determine the target compressive strength f cu,k of the target alkali-excited recycled concrete according to the performance requirements of the application scenario, and select a suitable alkali-to-binder ratio A/B and strength standard deviation σ k ;
试配强度计算单元,用于根据fcu,0≥fcu,k+1.645σk,得到fcu,0具体数值,其中fcu,0为碱激发再生混凝土的试配强度;Trial strength calculation unit, used to obtain the specific value of f cu, 0 according to f cu,0 ≥f cu,k +1.645σ k , where f cu,0 is the trial strength of alkali-excited recycled concrete;
水固比计算单元,用于根据碱胶比A/B,得到对应的回归系数αa、αb和胶砂28d抗压强度fb取值,再根据碱胶比A/B、试配强度fcu,0、回归系数αa、αb和胶砂28d抗压强度fb,计算得到水固比W/GPS;The water-solid ratio calculation unit is used to obtain the corresponding regression coefficients α a , α b and the 28d compressive strength f b of the mortar according to the alkali-binder ratio A/B, and then according to the alkali-binder ratio A/B, trial strength f cu,0 , regression coefficients α a , α b and 28d compressive strength f b of mortar, the water-solid ratio W/GPS is calculated;
配合比计算单元,用于根据碱胶比A/B、水固比W/GPS、浆骨质量比和砂率使用浆骨质量比法计算得到碱激发再生混凝土中各组分的含量。The mixing ratio calculation unit is used to calculate the content of each component in the alkali-excited recycled concrete according to the alkali-binder ratio A/B, the water-solid ratio W/GPS, the pulp-bone mass ratio and the sand ratio using the pulp-bone mass ratio method.
进一步地,还包括有标准差数据库建立单元,用于根据公式计算得到碱激发再生混凝土不同的抗压强度fcu对应的强度标准差σ,并将抗压强度fcu数值和与其对应的强度标准差σ一一对应存储为标准差数据库。Further, it also includes a standard deviation database establishment unit, for according to the formula The strength standard deviation σ corresponding to different compressive strength f cu of alkali-excited recycled concrete is calculated, and the compressive strength f cu value and its corresponding strength standard deviation σ are stored as a standard deviation database in one-to-one correspondence.
进一步地,所述目标参数单元,包括有目标参数模块,用于将目标抗压强度fcu,k和标准差数据库中抗压强度fcu数据进行匹配,找到目标抗压强度fcu,k数值对应的目标强度标准差σk数值。Further, the target parameter unit includes a target parameter module, which is used to match the target compressive strength f cu,k with the compressive strength f cu data in the standard deviation database, and find the target compressive strength f cu, k value. Corresponding target intensity standard deviation σ k value.
进一步地,所述水固比计算单元,包括有水固比W/GPS计算模块,用于通过公式计算得到水固比W/GPS。Further, the water-solid ratio calculation unit includes a water-solid ratio W/GPS calculation module for passing the formula Calculate the water-solid ratio W/GPS.
进一步地,所述配合比计算单元包括有配合比计算模块,用于使用以下关系等式进行计算:Further, the mixing ratio calculation unit includes a mixing ratio calculation module for calculating using the following relational equation:
胶凝组分用量*碱胶比=碱溶液*碱固体质量分数;The amount of gelling components * alkali to glue ratio = alkali solution * alkali solid mass fraction;
碱溶液*(1-碱固体质量分数)+额外水=(胶凝组分用量+碱溶液*碱固体质量分数)*水固比;Alkaline solution*(1-alkali solid mass fraction)+additional water=(amount of gelling component+alkali solution*alkali solid mass fraction)*water-solid ratio;
(胶凝组分用量+碱溶液+额外水)*浆骨质量比=再生粗骨料+细骨料;(amount of gelling component + alkali solution + additional water) * pulp-bone mass ratio = regenerated coarse aggregate + fine aggregate;
细骨料=(再生粗骨料+细骨料)*砂率;Fine aggregate = (recycled coarse aggregate + fine aggregate) * sand rate;
再生粗骨料=(再生粗骨料+细骨料)-细骨料;Regenerated coarse aggregate = (regenerated coarse aggregate + fine aggregate) - fine aggregate;
矿粉用量=胶凝组分用量*90%;The amount of mineral powder = the amount of gelling components * 90%;
粉煤灰用量=胶凝组分用量-矿粉用量。The amount of fly ash = the amount of cementitious components - the amount of mineral powder.
本发明的有益效果是:使用建筑废弃物等再生骨料代替天然骨料的碱激发混凝土,不仅扩大了碱激发混凝土的使用范围,还有充分使得废物资源的再利用,有利于环境保护;通过利用水固比得到适用碱激发再生混凝土的计算模型,并建立了不同碱胶比下对应的回归系数及28d胶砂抗压强度,最终采用浆骨质量比法计算得满足碱激发再生混凝土强度的各组分含量,最终得到碱激发再生混凝土配合比设计方法,根据混凝土各组分之间的实际质量关系进行计算,得到配合比更加准确,其适用范围更广。The beneficial effects of the invention are as follows: the alkali-excited concrete using recycled aggregates such as construction waste instead of natural aggregates not only expands the use range of the alkali-excited concrete, but also fully recycles waste resources, which is beneficial to environmental protection; The water-solid ratio was used to obtain a calculation model suitable for alkali-excited recycled concrete, and the corresponding regression coefficients and 28d compressive strength of mortar under different alkali-binder ratios were established. According to the content of each component, the design method of alkali excited recycled concrete mix ratio is finally obtained. Calculated according to the actual quality relationship between the various components of concrete, the obtained mix ratio is more accurate and has a wider application range.
附图说明Description of drawings
图1是本发明一种碱激发再生混凝土配合比设计方法一实施例的方法流程图;Fig. 1 is a method flow diagram of an embodiment of a method for designing an alkali-excited recycled concrete mix ratio of the present invention;
图2是本发明一种碱激发再生混凝土配合比设计方法另一实施例的方法流程图;Fig. 2 is a method flow chart of another embodiment of the alkali-excited recycled concrete mix proportion design method of the present invention;
图3是本发明一种碱激发再生混凝土配合比设计系统一实施例的结构框图。3 is a structural block diagram of an embodiment of an alkali-excited recycled concrete mix ratio design system of the present invention.
本发明目的的实现、功能特点及优点将结合实施例,参照附图做进一步说明。The realization, functional characteristics and advantages of the present invention will be further described with reference to the accompanying drawings in conjunction with the embodiments.
具体实施方式Detailed ways
应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。It should be understood that the specific embodiments described herein are only used to explain the present invention, but not to limit the present invention.
下面详细描述本发明的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,仅用于解释本发明,而不能解释为对本发明的限制。The following describes in detail the embodiments of the present invention, examples of which are illustrated in the accompanying drawings, wherein the same or similar reference numerals refer to the same or similar elements or elements having the same or similar functions throughout. The embodiments described below with reference to the accompanying drawings are exemplary and are only used to explain the present invention, but not to be construed as a limitation of the present invention.
本技术领域技术人员可以理解,除非另外定义,这里使用的所有术语(包括技术术语和科学术语),具有与本发明所属领域中的普通技术人员的一般理解相同的意义。还应该理解的是,诸如通用字典中定义的那些术语,应该被理解为具有与现有技术的上下文中的意义一致的意义,并且除非像这里一样被特定定义,否则不会用理想化或过于正式的含义来解释。It will be understood by those skilled in the art that, unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. It should also be understood that terms, such as those defined in a general dictionary, should be understood to have meanings consistent with their meanings in the context of the prior art and, unless specifically defined as herein, should not be interpreted in idealistic or overly formal meaning to explain.
参照图1,提出本发明一实施例,一种碱激发再生混凝土配合比设计方法,包括以下步骤:Referring to FIG. 1, an embodiment of the present invention is proposed, a method for designing the mix ratio of alkali-excited recycled concrete, including the following steps:
S2、根据应用场景的性能要求,确定目标碱激发再生混凝土的目标抗压强度fcu,k,并选定适合的碱胶比A/B和强度标准差σk。S2. According to the performance requirements of the application scenario, determine the target compressive strength f cu,k of the target alkali-excited recycled concrete, and select a suitable alkali-binder ratio A/B and strength standard deviation σ k .
S3、根据fcu,0≥fcu,k+1.645σk,得到fcu,0具体数值,其中fcu,0为碱激发再生混凝土的试配强度。S3. According to f cu,0 ≥f cu,k +1.645σ k , the specific value of f cu, 0 is obtained, where f cu,0 is the trial strength of the alkali-excited recycled concrete.
S4、根据碱胶比A/B,得到对应的回归系数αa、αb和胶砂28d抗压强度fb取值,再根据碱胶比A/B、试配强度fcu,0、回归系数αa、αb和胶砂28d抗压强度fb,计算得到水固比W/GPS。S4. According to the alkali-binder ratio A/B, the corresponding regression coefficients α a , α b and the 28d compressive strength f b of the mortar are obtained, and then according to the alkali-binder ratio A/B, trial strength f cu,0 , regression The coefficients α a , α b and the 28d compressive strength f b of the mortar can be calculated to obtain the water-solid ratio W/GPS.
S5、根据碱胶比A/B、水固比W/GPS、浆骨质量比和砂率使用浆骨质量比法计算得到碱激发再生混凝土中各组分的含量。S5. Calculate the content of each component in the alkali-excited recycled concrete according to the alkali-binder ratio A/B, the water-solid ratio W/GPS, the pulp-bone mass ratio and the sand ratio using the pulp-bone mass ratio method.
参考图2,在本发明另一实施例,在步骤S2之前还包括有步骤S1,具体为:Referring to FIG. 2, in another embodiment of the present invention, step S1 is further included before step S2, specifically:
S1、根据公式计算得到碱激发再生混凝土不同的抗压强度fcu对应的强度标准差σ,并将抗压强度fcu数值和与其对应的强度标准差σ一一对应存储为标准差数据库。S1, according to the formula The strength standard deviation σ corresponding to different compressive strength f cu of alkali-excited recycled concrete is calculated, and the compressive strength f cu value and its corresponding strength standard deviation σ are stored as a standard deviation database in one-to-one correspondence.
如上所述的步骤S1,通过上述的强度标准差σ计算公式计算得到不同抗压强度fcu对应的强度标准差σ,并按照表1中强度标准差σ与抗压强度fcu一一对应的形式记录成数据表格,上述的标准差数据库5在本实施例中为表1,表1如下所示。In step S1 as described above, the strength standard deviation σ corresponding to different compressive strengths f cu is obtained by calculating the above-mentioned strength standard deviation σ calculation formula, and according to the one-to-one correspondence between the strength standard deviation σ and the compressive strength f cu in Table 1 The form is recorded as a data table, the above-mentioned
表1碱激发再生混凝土抗压强度标准差σTable 1 Standard deviation σ of compressive strength of alkali-excited recycled concrete
如上所述的步骤S2,在根据实际应用场景确定好混凝土的目标抗压强度fcu,k之后,根据强度指标及普通混凝土配合比设计方法JGJ55-2011《普通混凝土配合比设计规程》的要求确定碱胶比A/B;另外将目标抗压强度fcu,k与表1中抗压强度fcu数据对比,找到与目标抗压强度fcu,k数值相同或相近的抗压强度fcu,并选择适合范围的强度标准差σ数值作为强度标准差σk的数值,以进行下一步的计算。具体的,根据此表1结果,当碱激发再生混凝土强度标准值位于45Mpa至65Mpa范围内时,其强度标准差可直接取4.0Mpa.也就是说不是查表。当位于此范围,强度标准差直接取4.0。当碱激发再生混凝土强度标准值不位于此范围时,也可通过适配获得其强度标准差。In step S2 as described above, after determining the target compressive strength f cu,k of concrete according to the actual application scenario, it is determined according to the strength index and the requirements of the ordinary concrete mix proportion design method JGJ55-2011 "Ordinary Concrete Mix Proportion Design Regulations" Alkali-binder ratio A/B; in addition, compare the target compressive strength f cu,k with the compressive strength f cu in Table 1, and find the compressive strength f cu with the same or similar value as the target compressive strength f cu ,k , And select the value of the intensity standard deviation σ in a suitable range as the value of the intensity standard deviation σ k for the next step of calculation. Specifically, according to the results in Table 1, when the standard strength value of alkali-excited recycled concrete is in the range of 45Mpa to 65Mpa, the standard deviation of its strength can be directly taken as 4.0Mpa. That is to say, it is not a table lookup. When in this range, the intensity standard deviation is directly taken as 4.0. When the standard value of alkali-excited recycled concrete strength is not within this range, its strength standard deviation can also be obtained by fitting.
如上所述的步骤S4,具体通过公式计算得到水固比W/GPS。其中回归系数可以根据碱胶比A/B查表2得到,表2如下:Step S4 as described above, specifically through the formula Calculate the water-solid ratio W/GPS. The regression coefficient can be obtained by looking up Table 2 according to the alkali to glue ratio A/B. Table 2 is as follows:
表2不同碱胶比下回归系数的取值Table 2 Values of regression coefficients under different alkali-gel ratios
如上所述的步骤S5,根据碱胶比A/B、水固比W/GPS、浆骨质量比和砂率使用浆骨质量比法计算得到碱激发再生混凝土中各组分的含量步骤,包括:The above step S5, according to the alkali-binder ratio A/B, the water-solid ratio W/GPS, the pulp-bone mass ratio and the sand ratio, use the pulp-bone mass ratio method to calculate the content steps of each component in the alkali-excited recycled concrete, including :
使用以下关系等式进行计算:Calculated using the following relational equation:
胶凝组分用量*碱胶比=碱溶液*碱固体质量分数;The amount of gelling components * alkali to glue ratio = alkali solution * alkali solid mass fraction;
碱溶液*(1-碱固体质量分数)+额外水=(胶凝组分用量+碱溶液*碱固体质量分数)*水固比;Alkaline solution*(1-alkali solid mass fraction)+additional water=(amount of gelling component+alkali solution*alkali solid mass fraction)*water-solid ratio;
(胶凝组分用量+碱溶液+额外水)*浆骨质量比=再生粗骨料+细骨料;(amount of gelling component + alkali solution + additional water) * pulp-bone mass ratio = regenerated coarse aggregate + fine aggregate;
细骨料=(再生粗骨料+细骨料)*砂率;Fine aggregate = (recycled coarse aggregate + fine aggregate) * sand rate;
再生粗骨料=(再生粗骨料+细骨料)-细骨料;Regenerated coarse aggregate = (regenerated coarse aggregate + fine aggregate) - fine aggregate;
矿粉用量=胶凝组分用量*90%;The amount of mineral powder = the amount of gelling components * 90%;
粉煤灰用量=胶凝组分用量-矿粉用量。The amount of fly ash = the amount of cementitious components - the amount of mineral powder.
表3试验范围内碱激发胶材28d胶砂抗压强度Table 3 Compressive strength of 28d mortar of alkali-excited rubber material within the test range
其中,碱溶液、碱胶比、碱固体质量分数、水固比、浆骨质量比和砂率为已知参数,其余胶凝组分用量、额外水、再生粗骨料、细骨料、矿粉用量和粉煤灰用量为未知参数。通过各个已知参数代入可计算得出我们需要的额外水、再生粗骨料、细骨料、矿粉用量和粉煤灰用量等混凝土组分的含量,进而得到碱激发混凝土的配合比。(上述28d是指28天)Among them, the alkali solution, alkali-binder ratio, alkali solid mass fraction, water-solid ratio, pulp-bone mass ratio and sand ratio are known parameters, and the remaining cementitious components dosage, additional water, recycled coarse aggregate, fine aggregate, mineral The amount of powder and the amount of fly ash are unknown parameters. By substituting each known parameter, the content of concrete components such as additional water, recycled coarse aggregate, fine aggregate, mineral powder amount and fly ash amount that we need can be calculated, and then the mix ratio of alkali-activated concrete can be obtained. (The above 28d refers to 28 days)
最后根据所得配合比进行碱激发再生混凝土配制,标准条件下养护至28天,测试得到其抗压强度平均值,和目标抗压强度对比,看是否满足目标强度要求,如满足,则选用该配合比;如不满足,则调整浆骨比和/或砂率具体数值再进行计算,直到得到适合的碱激发再生混凝土配合比。Finally, according to the obtained mixing ratio, the alkali-excited recycled concrete is prepared, and cured for 28 days under standard conditions. The average compressive strength of the test is obtained, and the average compressive strength is compared with the target compressive strength to see if it meets the target strength requirements. If it is not satisfied, adjust the concrete value of the slurry-bone ratio and/or the sand ratio and then calculate until a suitable mix ratio of alkali-excited recycled concrete is obtained.
本方法是在胶凝材料以矿粉为主导,内掺10%粉煤灰条件下根据各组分关系,因此利用该方法得到的碱激发再生混凝土配合比,其胶凝原材料中粉煤灰同样要保持10%的掺量,最终得到满足强度要求的碱激发再生混凝土配合比。This method is based on the relationship of each component under the condition that the cementitious material is dominated by mineral powder and mixed with 10% fly ash. Therefore, the mix ratio of the alkali-excited recycled concrete obtained by this method is the same as the fly ash in the cementitious raw material. To keep 10% of the content, finally get the alkali excited recycled concrete mix ratio that meets the strength requirements.
具体的案例如下:The specific cases are as follows:
将本发明提出的配合比设计方法对碱激发再生混凝土进行设计,要求:目标抗压强度达到fcu,k=50MPa,施工和易性良好。具体设计步骤如下:The mixing ratio design method proposed in the present invention is designed for alkali excited recycled concrete, and it is required that the target compressive strength reaches f cu,k =50MPa, and the construction workability is good. The specific design steps are as follows:
(1)首先初步确定碱胶比。根据强度指标及普通混凝土配合比设计方法JGJ55-2011《普通混凝土配合比设计规程》的要求,目标抗压强度等综合性能初步选择碱胶比A/B=0.24。(1) First determine the ratio of alkali to glue. According to the requirements of strength index and ordinary concrete mix proportion design method JGJ55-2011 "Ordinary concrete mix proportion design regulations", the target compressive strength and other comprehensive properties are preliminarily selected as alkali-binder ratio A/B=0.24.
(2)根据碱胶比A/B,可以得到相应回归系数,即能明确抗压强度与水固比关系式。碱胶比A/B=0.24,查表2可得,对应的回归系数为αa=0.2227,αb=-1.5245。此外,根据表3可以得到碱胶比为0.24条件下,胶砂28d抗压强度fb=58.2MPa。(2) According to the ratio of alkali to glue A/B, the corresponding regression coefficient can be obtained, that is, the relationship between compressive strength and water-solid ratio can be clearly defined. The alkali to glue ratio A/B=0.24, which can be obtained from Table 2, and the corresponding regression coefficients are α a =0.2227, α b =-1.5245. In addition, according to Table 3, it can be obtained that under the condition that the ratio of alkali to glue is 0.24, the compressive strength f b =58.2MPa of the mortar 28d.
(3)根据配制目标,目标抗压强度fcu,k=50MPa,根据表1结果,当目标强度位于45Mpa~65Mpa时,目标强度标准差取值可取σk=4.0Mpa,并由此得到混凝土的试配强度fcu,0=fcu,k+1.645σ=50+1.645*4.0=56.58MPa。(3) According to the preparation target, the target compressive strength fcu,k = 50MPa, according to the results in Table 1, when the target strength is between 45Mpa and 65Mpa, the standard deviation of the target strength can be taken as σ k = 4.0Mpa, and the concrete is obtained from this The trial strength f cu,0 =f cu,k +1.645σ=50+1.645*4.0=56.58MPa.
并将fcu,0,fb,αa、αb具体数值代入式并求解,可以得到水固比W/GPS=0.352。Substitute the specific values of f cu,0 , f b , α a , α b into the formula And solve it, we can get the water-solid ratio W/GPS=0.352.
(4)查表3取胶凝组分用量=600+66=666kg/m3为基准值,通过前期预实验,再根据碱激发再生混凝土的工作性能和强度要求选择砂率为0.45,浆骨质量比0.99,计算各组分的含量,具体计算过程如下,(4) Look up Table 3 and take the amount of cementitious component = 600 + 66 = 666 kg/ m3 as the reference value, through the preliminary experiment, and then select the sand ratio of 0.45 according to the working performance and strength requirements of alkali-induced recycled concrete, and the mortar bone The mass ratio is 0.99, and the content of each component is calculated. The specific calculation process is as follows:
第一步,计算水玻璃含量,胶凝组分用量*碱胶比=碱溶液*碱固体质量分数,本试验选择模数为1.95的水玻璃,其中Na2O质量分数为14.26%,S iO2质量分数为26.92%,故此水玻璃的碱固体质量分数取41.18%,代入可得:The first step is to calculate the water glass content, the amount of gelling components * alkali to glue ratio = alkali solution * alkali solid mass fraction, this test selects water glass with a modulus of 1.95, in which the mass fraction of Na 2 O is 14.26%, and the mass fraction of SiO 2 The mass fraction is 26.92%, so the alkali solid mass fraction of water glass is 41.18%, which can be substituted into:
666*0.24=碱溶液*0.412,666*0.24=alkali solution*0.412,
计算得到碱溶液(水玻璃)=387.96kg/m3。Alkali solution (water glass) = 387.96 kg/m 3 by calculation.
第二步,计算额外水含量,碱溶液*(1-碱固体质量分数)+额外水=(胶凝组分用量+碱溶液*碱固体质量分数)*水固比,代入已知组分具体数值得:The second step is to calculate the additional water content, alkali solution*(1-base solid mass fraction)+additional water=(amount of gelling component+alkali solution*base solid mass fraction)*water-solid ratio, and substituting the known component specific The number is worth:
387.96*(1-0.412)+额外水=(666+387.96*0.412)*0.352,387.96*(1-0.412)+extra water=(666+387.96*0.412)*0.352,
计算得到额外水=62.57kg/m。Calculated extra water = 62.57 kg/m.
第三步,计算细骨料和再生粗骨料总合,(胶凝组分用量+碱溶液+额外水)*浆骨质量比=再生粗骨料+细骨料,代入相关组分具体数值:The third step is to calculate the sum of fine aggregate and recycled coarse aggregate, (amount of gelling component + alkaline solution + additional water) * pulp-bone mass ratio = recycled coarse aggregate + fine aggregate, and substitute the specific values of the relevant components :
(666+387.96+62.57)*0.99=再生粗骨料+细骨料,由此算出再生骨料+细骨料总=1127.81kg/m3。(666+387.96+62.57)*0.99=recycled coarse aggregate+fine aggregate, from this, regenerated aggregate+fine aggregate total=1127.81 kg/m 3 .
第四步,计算细骨料,细骨料=(再生粗骨料+细骨料)*砂率;细骨料=1127.81*0.45=507.51kg/m3,其中细骨料为天然砂。The fourth step is to calculate the fine aggregate, fine aggregate=(regenerated coarse aggregate+fine aggregate)*sand rate; fine aggregate=1127.81*0.45=507.51kg/m 3 , wherein the fine aggregate is natural sand.
第五步,计算再生粗骨料,再生粗骨料=(再生粗骨料+细骨料)-细骨料,代入相关组分具体数值,计算得到再生粗骨料=1127.81-507.51=620.30kg/m3。The fifth step, calculate the regenerated coarse aggregate, regenerated coarse aggregate = (regenerated coarse aggregate + fine aggregate) - fine aggregate, substitute the specific values of the relevant components, and calculate the regenerated coarse aggregate = 1127.81-507.51 = 620.30kg /m 3 .
第六步,计算矿粉用量,矿粉用量=胶凝组分用量*90%,代入相关组分的具体数值,计算得到,矿粉用量=666*0.9=599.4kg/m3。The sixth step is to calculate the amount of mineral powder, the amount of mineral powder = the amount of cementitious components * 90%, and substituting the specific values of the relevant components, the calculation is obtained, the amount of mineral powder = 666 * 0.9 = 599.4 kg/m 3 .
第七步:计算粉煤灰用量,粉煤灰用量=胶凝组分用量-矿粉用量,代入相关组分具体数据,计算得到,粉煤灰用量=666-599.4=66.6kg/m3。Step 7: Calculate the amount of fly ash, the amount of fly ash = the amount of cementitious components - the amount of slag powder, substituting the specific data of the relevant components, the calculation is obtained, the amount of fly ash = 666-599.4 = 66.6kg/m 3 .
最终,得到适合的碱激发再生混凝土具体配合比,如表4所示:Finally, a suitable specific mix ratio of alkali-excited recycled concrete is obtained, as shown in Table 4:
表450MPa碱激发再生混凝土配合比Table 450MPa alkali excited recycled concrete mix ratio
(5)根据(4)所得配合比进行碱激发再生混凝土配制,新拌混凝土塌落度为172mm,未出现离析或泌水现象,施工和易性良好。标准条件下养护至28天,经测试得到其抗压强度平均值为53.1MPa,满足要求。(5) Alkali-excited recycled concrete was prepared according to the mixture ratio obtained in (4), the slump of the fresh concrete was 172 mm, no segregation or bleeding occurred, and the construction workability was good. After curing for 28 days under standard conditions, the average compressive strength is 53.1MPa after testing, which meets the requirements.
(6)由于所使用骨料吸水率、级配、压碎指标等特征均对混凝土性能有直接影响,因此进行配合比设计前必须对原材料性质进行相关检测。(6) Since the characteristics of the water absorption rate, gradation, and crushing index of the aggregate used have a direct impact on the performance of the concrete, the properties of the raw materials must be tested before the design of the mix ratio.
本发明的有益效果是:使用建筑废弃物等再生骨料代替天然骨料的碱激发混凝土,不仅扩大了碱激发混凝土的使用范围,还有充分使得废物资源的再利用,有利于环境保护;通过利用水固比得到适用碱激发再生混凝土的计算模型,并建立了不同碱胶比下对应的回归系数及28d胶砂抗压强度,最终采用浆骨质量比法计算得满足碱激发再生混凝土强度的各组分含量,最终得到碱激发再生混凝土配合比设计方法,根据混凝土各组分之间的实际质量关系进行计算,得到配合比更加准确,其适用范围更广。The beneficial effects of the invention are as follows: the alkali-excited concrete using recycled aggregates such as construction waste instead of natural aggregates not only expands the use range of the alkali-excited concrete, but also fully recycles waste resources, which is beneficial to environmental protection; The water-solid ratio was used to obtain a calculation model suitable for alkali-excited recycled concrete, and the corresponding regression coefficients and 28d compressive strength of mortar under different alkali-binder ratios were established. According to the content of each component, the design method of alkali excited recycled concrete mix ratio is finally obtained. Calculated according to the actual quality relationship between the various components of concrete, the obtained mix ratio is more accurate and has a wider application range.
本发明还提出了一种碱激发再生混凝土配合比设计系统,包括:The present invention also proposes an alkali-excited recycled concrete mix ratio design system, including:
标准差数据库建立单元1,用于根据公式计算得到碱激发再生混凝土不同的抗压强度fcu对应的强度标准差σ,并将抗压强度fcu数值和与其对应的强度标准差σ一一对应存储为标准差数据库。Standard deviation
目标参数单元2,用于根据应用场景的性能要求,确定目标碱激发再生混凝土的目标抗压强度fcu,k,并选定适合的碱胶比A/B和强度标准差σk;The
试配强度计算单元3,用于根据fcu,0≥fcu,k+1.645σk,得到fcu,0具体数值,其中fcu,0为碱激发再生混凝土的试配强度;Trial
水固比计算单元4,用于根据碱胶比A/B,得到对应的回归系数αa、αb和胶砂28d抗压强度fb取值,再根据碱胶比A/B、试配强度fcu,0、回归系数αa、αb和胶砂28d抗压强度fb,计算得到水固比W/GPS;The water-solid
配合比计算单元5,用于根据碱胶比A/B、水固比W/GPS、浆骨质量比和砂率使用浆骨质量比法计算得到碱激发再生混凝土中各组分的含量。The mixing
标准差数据库建立单元1,用于通过上述的强度标准差σ计算公式计算得到不同抗压强度fcu对应的强度标准差σ,并按照表一中强度标准差σ与抗压强度fcu一一对应的形式记录成数据表格,上述的标准差数据库在本实施例中为表1。The standard deviation
其中,目标参数单元2,包括有目标参数模块201,用于在根据实际应用场景确定好混凝土的目标抗压强度fcu,k之后,根据强度指标及普通混凝土配合比设计方法JGJ55-2011《普通混凝土配合比设计规程》的要求确定碱胶比A/B;另外将目标抗压强度fcu,k与表1中抗压强度fcu数据对比,找到与目标抗压强度fcu,k数值相同的抗压强度fcu,并选择抗压强度fcu对应的强度标准差σ数值作为强度标准差σk的数值,以进行下一步的计算。Among them, the
其中,水固比计算单元4,包括有水固比计算模块401,用于通过公式计算得到水固比W/GPS。水固比,为水与固体材料的比值。Among them, the water-solid
其中,配合比计算单元5包括有配合比计算模块501,用于使用以下关系等式进行计算:Wherein, the mixing
胶凝组分用量*碱胶比=碱溶液*碱固体质量分数;The amount of gelling components * alkali to glue ratio = alkali solution * alkali solid mass fraction;
碱溶液*(1-碱固体质量分数)+额外水=(胶凝组分用量+碱溶液*碱固体质量分数)*水固比;Alkaline solution*(1-alkali solid mass fraction)+additional water=(amount of gelling component+alkali solution*alkali solid mass fraction)*water-solid ratio;
(胶凝组分用量+碱溶液+额外水)*浆骨质量比=再生粗骨料+细骨料;(amount of gelling component + alkali solution + additional water) * pulp-bone mass ratio = regenerated coarse aggregate + fine aggregate;
细骨料=(再生粗骨料+细骨料)*砂率;Fine aggregate = (recycled coarse aggregate + fine aggregate) * sand rate;
再生粗骨料=(再生粗骨料+细骨料)-细骨料;Regenerated coarse aggregate = (regenerated coarse aggregate + fine aggregate) - fine aggregate;
矿粉用量=胶凝组分用量*90%;The amount of mineral powder = the amount of gelling components * 90%;
粉煤灰用量=胶凝组分用量-矿粉用量。The amount of fly ash = the amount of cementitious components - the amount of mineral powder.
使用建筑废弃物等再生骨料代替天然骨料的碱激发混凝土,不仅扩大了碱激发混凝土的使用范围,还有充分使得废物资源的再利用,有利于环境保护;通过利用水固比得到适用碱激发再生混凝土的计算模型,并建立了不同碱胶比下对应的回归系数及28d胶砂抗压强度,最终采用浆骨质量比法计算得满足碱激发再生混凝土强度的各组分含量,最终得到碱激发再生混凝土配合比设计方法,根据混凝土各组分之间的实际质量关系进行计算,得到配合比更加准确,其适用范围更广。Alkali-excited concrete that uses recycled aggregates such as construction waste instead of natural aggregates not only expands the use range of alkali-excited concrete, but also fully reuses waste resources, which is conducive to environmental protection; the use of water-solid ratio to obtain suitable alkali The calculation model of stimulated recycled concrete was established, and the corresponding regression coefficient and 28d compressive strength of mortar under different alkali-binder ratios were established. Finally, the slurry-bone mass ratio method was used to calculate the content of each component that meets the strength of alkali-excited recycled concrete, and finally obtained Alkali-induced recycled concrete mix ratio design method is calculated according to the actual quality relationship between the various components of concrete, and the obtained mix ratio is more accurate and has a wider range of applications.
以上所述仅为本发明的优选实施例,并非因此限制本发明的专利范围,凡是利用本发明说明书及附图内容所作的等效结构或等效流程变换,或直接或间接运用在其他相关的技术领域,均同理包括在本发明的专利保护范围内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the scope of the present invention. Any equivalent structure or equivalent process transformation made by using the contents of the description and drawings of the present invention, or directly or indirectly applied to other related All technical fields are similarly included in the scope of patent protection of the present invention.
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