CN106830343A - The method that the unbalance tail water wetland nitrogen removal rate of carbon nitrogen is improved using water plant - Google Patents
The method that the unbalance tail water wetland nitrogen removal rate of carbon nitrogen is improved using water plant Download PDFInfo
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Abstract
本发明是一种利用水生植物提高碳氮失衡尾水湿地总氮去除率的方法,构建一个复合处理系统,包括稳定塘‑表面流湿地‑生态输水渠‑水平潜流湿地四个子系统,各子系统间通过工艺依次串联。优点:1)降低水生植物群落中不同物种间的竞争,提高水生植物群落的稳定性,避免水生植物残体集中分解形成二次污染;2)降低人才成本,分解的有机质可为湿地反硝化提供碳源,提高氮去除率;3)可使不同子系统及子系统内部的不同区域厌氧和好氧环境交替出现,平衡硝化与反硝化作用,提高总氮去除率;4)减轻湿地净化工程普遍存在的冬季净化能力不足,缓解尾水湿地存在的夏季碳源不足5)实现了提供高效、持续、稳定碳源的目的。
The present invention is a method for improving the total nitrogen removal rate of carbon-nitrogen unbalanced tail water wetland by utilizing aquatic plants, constructing a composite treatment system, including four subsystems of stable pond-surface flow wetland-ecological aqueduct-horizontal subsurface flow wetland, each subsystem The process is sequentially connected in series. Advantages: 1) Reduce the competition between different species in the aquatic plant community, improve the stability of the aquatic plant community, and avoid the secondary pollution caused by the centralized decomposition of aquatic plant residues; 2) Reduce the cost of talents, and the decomposed organic matter can provide wetland denitrification Carbon source, improve nitrogen removal rate; 3) Alternate anaerobic and aerobic environments in different subsystems and different regions within the subsystem, balance nitrification and denitrification, and increase total nitrogen removal rate; 4) Reduce wetland purification projects The ubiquitous lack of purification capacity in winter alleviates the lack of carbon sources in summer in tailwater wetlands 5) The purpose of providing efficient, sustainable and stable carbon sources is achieved.
Description
技术领域technical field
本发明涉及的是一种利用水生植物提高碳氮失衡尾水湿地总氮去除率的方法,属于污水处理厂尾水构造湿地深度处理技术领域。The invention relates to a method for improving the total nitrogen removal rate of carbon-nitrogen unbalanced tail water wetlands by using aquatic plants, and belongs to the technical field of advanced treatment of tail water structure wetlands of sewage treatment plants.
背景技术Background technique
对于氮元素,湿地的去除机理包括挥发、氨化、硝化/反硝化、植物摄取和基质吸附。许多研究表明,湿地中的主要去氮机理是微生物硝化/反硝化,硝化/反硝化去氮量占氮去除总量的70%以上。污水处理厂常采用A/O 工艺,消耗了大量的COD,特别是其中的BOD,使得尾水碳氮比严重失调,从而造成反硝化过程碳源不足,抑制反硝化微生物,降低脱氮效率。此外,与一般湿地相似,尾水湿地受净化能力季节性波动大、冬季净化能力不足问题的困扰,无法满足季节出水量相对均衡的污水处理厂尾水的净化要求。For nitrogen, removal mechanisms in wetlands include volatilization, ammonification, nitrification/denitrification, plant uptake, and substrate adsorption. Many studies have shown that the main nitrogen removal mechanism in wetlands is microbial nitrification/denitrification, and the amount of nitrogen removal by nitrification/denitrification accounts for more than 70% of the total nitrogen removal. Sewage treatment plants often use the A/O process, which consumes a large amount of COD, especially BOD, which causes a serious imbalance in the carbon-nitrogen ratio of the tail water, resulting in insufficient carbon sources in the denitrification process, inhibiting denitrifying microorganisms, and reducing nitrogen removal efficiency. In addition, similar to general wetlands, tailwater wetlands are plagued by large seasonal fluctuations in purification capacity and insufficient purification capacity in winter, and cannot meet the purification requirements of tail water from sewage treatment plants with relatively balanced seasonal water output.
针对碳氮失衡尾水湿地氮去除效率低等问题,国内外已发展了多种解决方案,但是,这些方法在实际应用过程中还存在明显的不足,添加高C/N原污水的方法存在合理投放比例控制困难、容易降低出水水质和效果受到原污水中低分子有机物含量不足限制等问题;添加低分子碳水化合物方法存在运行成本高、碳源的有效利用率低等缺点;而添加植物秸秆方法目前还主要处在技术的研发阶段,对于投加方式、投加量、投加时机等方面还存在争议,难以满足大范围应用的要求。Aiming at the low nitrogen removal efficiency of carbon and nitrogen imbalance tail water wetlands, various solutions have been developed at home and abroad. However, these methods still have obvious deficiencies in the actual application process, and the method of adding high C/N raw sewage is reasonable. It is difficult to control the feeding ratio, it is easy to reduce the quality of effluent water, and the effect is limited by the insufficient content of low-molecular organic matter in raw sewage; the method of adding low-molecular carbohydrates has disadvantages such as high operating costs and low effective utilization of carbon sources; while the method of adding plant straw At present, it is mainly in the research and development stage of the technology, and there are still disputes about the dosing method, dosing amount, dosing timing, etc., and it is difficult to meet the requirements of large-scale applications.
芦苇、菰、菖蒲、再力花等作为目前人工湿地生态工程最常用的水生植物种类;由于这些水生植物的生长旺盛期与反硝化细菌的活性旺盛期几乎完全重叠,使得选择的水生植物难以在微生物碳源需求旺盛期(春夏季)提供足够的碳源;当前选择的水生植物类型及其配置往往会加剧湿地净化能力的季节性波动。Reed, wild rice, calamus, Zailihua, etc. are the most commonly used aquatic plant species in constructed wetland ecological engineering; because the vigorous growth period of these aquatic plants overlaps almost completely with the vigorous activity period of denitrifying bacteria, it is difficult to select aquatic plants in The period of high demand for microbial carbon sources (spring and summer) provides sufficient carbon sources; the types of aquatic plants currently selected and their configurations tend to exacerbate seasonal fluctuations in wetland purification capacity.
发明内容Contents of the invention
本发明提出的是一种利用水生植物提高碳氮失衡尾水湿地总氮去除率的方法,其目的在于有效解决现有技术所存在的碳氮失衡尾水湿地氮去除效能不足的问题。The invention proposes a method for improving the total nitrogen removal rate of carbon-nitrogen unbalanced tailwater wetlands by utilizing aquatic plants, and aims to effectively solve the problem of insufficient nitrogen removal efficiency in carbon-nitrogen unbalanced tailwater wetlands existing in the prior art.
本发明的技术解决方案:一种利用水生植物提高碳氮失衡尾水湿地总氮去除率的方法,构建一个复合处理系统,该复合处理系统包括稳定塘——表面流湿地——生态输水渠——水平潜流湿地四个子系统,各子系统间通过各工艺依次串联;The technical solution of the present invention: a method of using aquatic plants to improve the total nitrogen removal rate of carbon and nitrogen imbalance tail water wetlands, and construct a composite treatment system, which includes stabilization ponds - surface flow wetlands - ecological aqueducts - —Four subsystems of the horizontal subsurface flow wetland, and each subsystem is connected in sequence through each process;
所述各工艺是大量种植的水生植物,冷季型和暖季型水生植物配置面积比2:1,水生植物全年不收割,通过水生植物根系分泌有机质和残体分解作用,逐步改善水体中的碳氮失衡状况,进一步提高氮去除率,而且由于冷季型和暖季型水生植物的配置,避免出现水生植物分解导致的二次污染。Each of the processes described is to plant a large number of aquatic plants. The area ratio of cold-season and warm-season aquatic plants is 2:1. The aquatic plants are not harvested throughout the year. The organic matter secreted by the roots of the aquatic plants and the decomposition of residues are used to gradually improve the water quality. The carbon and nitrogen imbalance can further improve the nitrogen removal rate, and due to the configuration of cool-season and warm-season aquatic plants, secondary pollution caused by the decomposition of aquatic plants can be avoided.
本发明的优点:Advantages of the present invention:
1)冷季型与暖季型间种,不仅可以降低水生植物群落中不同物种间的竞争,提高水生植物群落的稳定性,而且可以避免水生植物残体集中分解,形成二次污染;1) Interplanting between cool-season and warm-season types can not only reduce the competition among different species in the aquatic plant community, improve the stability of the aquatic plant community, but also avoid the centralized decomposition of aquatic plant residues and the formation of secondary pollution;
2)本处理系统水生植物全年不收割,这样可以降低人才成本,同时分解的有机质可为湿地反硝化提供碳源,在降低人力成本的同时提高氮去除率;2) The aquatic plants in this treatment system are not harvested throughout the year, which can reduce the cost of labor, and at the same time, the decomposed organic matter can provide carbon sources for wetland denitrification, which can increase the nitrogen removal rate while reducing labor costs;
3)本处理系统包括稳定塘、生态输水渠、表面流湿地和水平潜流湿地复合处理系统,由于不同系统中在水深、水体扰动程度、水生植物类型上的差异,使得不同子系统及子系统内部的不同区域厌氧和好氧环境交替出现,平衡硝化与反硝化作用,提高总氮去除率;3) The treatment system includes stabilization ponds, ecological aqueducts, surface flow wetlands, and horizontal subsurface flow wetland composite treatment systems. Due to the differences in water depth, water disturbance degree, and aquatic plant types in different systems, different subsystems and subsystems Anaerobic and aerobic environments appear alternately in different regions, balancing nitrification and denitrification, and improving the removal rate of total nitrogen;
4)本发明更加强调冷季型水生植物的种植,不仅有利于减轻湿地净化工程普遍存在的冬季净化能力不足的问题,而且有利于缓解尾水湿地存在的尖锐的夏季碳源不足的问题。4) The present invention puts more emphasis on the planting of cool-season aquatic plants, which not only helps to alleviate the common problem of insufficient purification capacity in winter in wetland purification projects, but also helps to alleviate the acute problem of carbon source shortage in tailwater wetlands in summer.
附图说明Description of drawings
附图1是本发明的实施例示意图。Accompanying drawing 1 is the schematic diagram of embodiment of the present invention.
附图中是浮床植物,是漂浮植物,是挺水植物(冷季型),是挺水植物(暖季型),是沉水植物(冷季型),是沉水植物(暖季型)。In the attached picture It is a floating bed plant, are floating plants, are emergent plants (cool-season), It is an emergent plant (warm season type), are submerged plants (cool-season type), It is a submerged plant (warm season type).
具体实施方式detailed description
一种利用水生植物提高碳氮失衡尾水总氮去除率的方法,构建一个稳定塘——表面流湿地——生态输水渠——水平潜流湿地工艺相串联的复合处理系统,通过水生植物吸收、微生物硝化/反硝化、物理沉降和自然挥发等途径,逐步去除水体硝态氮和氨态氮,其核心在于各工艺中大量种植的水生植物,冷季型和暖季型水生植物配置面积比2:1,水生植物全年不收割,通过水生植物根系分泌有机质和残体分解作用,逐步改善水体中的碳氮失衡状况,进一步提高氮去除率,而且由于冷季型和暖季型水生植物的配置,避免出现了水生植物分解导致的二次污染。A method of using aquatic plants to improve the total nitrogen removal rate of carbon-nitrogen unbalanced tail water, constructing a composite treatment system in series of stable pond-surface flow wetland-ecological aqueduct-horizontal subsurface flow wetland technology, through the absorption of aquatic plants, Microbial nitrification/denitrification, physical sedimentation and natural volatilization can gradually remove nitrate nitrogen and ammonia nitrogen from the water body. The core lies in the large number of aquatic plants planted in each process. The ratio of cold-season and warm-season aquatic plants is 2 : 1. Aquatic plants are not harvested throughout the year. Through the secretion of organic matter from the roots of aquatic plants and the decomposition of residues, the carbon and nitrogen imbalance in the water body can be gradually improved, and the nitrogen removal rate can be further improved. configuration to avoid secondary pollution caused by the decomposition of aquatic plants.
所述的稳定塘——表面流湿地——生态输水渠——水平潜流湿地工艺依次串联;稳定塘水深3.0-4.0 m,生态输水渠最深不超过1.5 m,表面流湿地水深0.3-1.5 m;(稳定塘+生态输水渠+表面流湿地)与水平潜流湿地面积比>5:1,水力停留时间2-4天。The stabilization pond—surface flow wetland—ecological aqueduct—horizontal subsurface flow wetland process is connected in sequence; the depth of the stabilization pond is 3.0-4.0 m, the deepest ecological aqueduct is no more than 1.5 m, and the depth of the surface flow wetland is 0.3-1.5 m; (Stable pond + ecological aqueduct + surface flow wetland) and horizontal subsurface flow wetland area ratio > 5:1, hydraulic retention time 2-4 days.
所述的复合处理系统包括大面积的水生植物群落,水生植物平均盖度不低于50%,通过水生植物根分泌有机质、枯枝落叶和死亡残体的分解作用,逐步提高水体碳氮比,提高氮去除率。The composite treatment system includes a large-area aquatic plant community, the average coverage of aquatic plants is not less than 50%, and the carbon-nitrogen ratio of the water body is gradually increased through the decomposition of organic matter secreted by aquatic plant roots, litter and dead residues, Improve nitrogen removal rate.
所述的水生植物群落实行冷季型和暖季型植物间种,总面积比为2:1。适宜的水生植物群落具体配置方式:稳定塘岸边浅水区挺水植物以芦苇、花叶芦竹、香蒲和水生鸢尾为主,浮叶植物以水葫芦为主,浮床植物以冷季型的水芹为主,植物总体覆盖度大于20%;生态输水渠水生植物群落包括沉水植物和挺水植物,其中,沉水植物包括菹草和穗花狐尾藻,挺水植物以芦苇、花叶芦竹、香蒲和水生鸢尾为主,水面水生植物盖度在30-50%;表面流湿地水生植物包括芦苇、花叶芦竹、香蒲和水生鸢尾;水平潜流湿地水生植物群落以芦苇和水生鸢尾为主。The aquatic flora is interplanted with cool-season and warm-season plants, and the total area ratio is 2:1. Specific configuration of suitable aquatic plant communities: Emergent plants in the shallow water area on the bank of the stable pond are mainly reeds, reeds, cattails and aquatic iris; floating leaf plants are mainly water hyacinth; floating bed plants are mainly cool-season aquatic Celery is dominant, and the overall coverage of plants is greater than 20%. The aquatic plant community of the ecological aqueduct includes submerged plants and emergent plants. Bamboo, cattails and aquatic iris are the main species, and the coverage of aquatic plants on the water surface is 30-50%; aquatic plants in surface flow wetlands include reeds, reeds, cattails and aquatic iris; aquatic plant communities in horizontal subsurface flow wetlands are dominated by reeds and aquatic iris host.
所述的水生植物,全年不收割,通过冷季型和暖季型水生植物配置,避免出现大量植物残体同时分解造成的二次污染问题。The aquatic plants are not harvested throughout the year, and the secondary pollution caused by the simultaneous decomposition of a large number of plant residues is avoided through the configuration of cool-season and warm-season aquatic plants.
所述的水平潜流湿地填料为砾石,粒径3.0-5.0cm,深度1.2-1.5m;次上层为瓦子片,直径1.0-2.0cm,深度10.0cm;最上层为粗沙层,最大粒径 2.0mm,深度5.0cm。The horizontal subsurface flow wetland filler is gravel with a particle size of 3.0-5.0cm and a depth of 1.2-1.5m; the second upper layer is a tile sheet with a diameter of 1.0-2.0cm and a depth of 10.0cm; the uppermost layer is a coarse sand layer with a maximum particle size of 2.0mm, depth 5.0cm.
所述的表面流湿地,采用垄沟结构,垄沟长80.0-100.0m,垄面宽10.0m,垄面水深0.3-0.5m,垄沟宽7.0-8.0 m,深1.5-2.0m。The surface flow wetland adopts a furrow structure, the furrow is 80.0-100.0m long, 10.0m wide, 0.3-0.5m deep, 7.0-8.0m wide, and 1.5-2.0m deep.
所述的生态输水渠边坡系数1-2,底宽1.0-3.0 m,长度因地制宜,总长应大于2.0km。The slope coefficient of the ecological water delivery channel is 1-2, the bottom width is 1.0-3.0 m, the length is adjusted to local conditions, and the total length should be greater than 2.0 km.
下面结合附图对本发明作进一步描述,Below in conjunction with accompanying drawing, the present invention will be further described,
实验处理对象为某城市污水处理厂的尾水,主要污染物年平均浓度为:COD =113.4mg/L,总氮 = 50.6mg/L,总磷 = 2.16mg/L,氨氮 = 12.6mg/L,BOD/TN=1.88。The experimental treatment object is the tail water of a certain urban sewage treatment plant. The annual average concentration of main pollutants is: COD = 113.4mg/L, total nitrogen = 50.6mg/L, total phosphorus = 2.16mg/L, ammonia nitrogen = 12.6mg/L , BOD/TN=1.88.
设计曝气塘40000m2,表面流湿地150000m2,生态输水渠总长2.5km、水面10000m2,潜流湿地40000m2。曝气塘中芦苇 400 m2、花叶芦竹 300 m2、东方香蒲500 m2和水生鸢尾700 m2,水芹浮床5000 m2。The designed aeration pond is 40,000m 2 , the surface flow wetland is 150,000m 2 , the total length of the ecological aqueduct is 2.5km, the water surface is 10,000m 2 , and the subsurface flow wetland is 40,000m 2 . In the aeration pond, there are 400 m 2 reeds, 300 m 2 mosaic reeds, 500 m 2 oriental cattails, 700 m 2 aquatic iris, and 5000 m 2 cress floating beds.
尾水通过水生植物吸收、微生物硝化—反硝化、物理沉降和自然挥发等途径被去除;同时,通过植物根系分泌作用、枯枝落叶和死亡残体分解作用,令目标水体碳氮失衡状况逐步得到改善,由进入系统前的1.88(BOD:TN)到流出系统后的>2.5(BOD:TN),系统TN去除率>85%。Tail water is removed through absorption by aquatic plants, microbial nitrification-denitrification, physical settlement and natural volatilization; at the same time, through the secretion of plant roots, the decomposition of litter and dead residues, the carbon and nitrogen imbalance in the target water body is gradually eliminated. Improvement, from 1.88 (BOD: TN) before entering the system to >2.5 (BOD: TN) after flowing out of the system, and the TN removal rate of the system is > 85%.
水生植物群落具体配置方式:稳定塘岸边浅水区挺水植物以芦苇(P.australis(Cav.) Trin. ex Steud.)、花叶芦竹(A.donax var. versicolor)、香蒲(T.orientalisPresl.)和水生鸢尾(I. pseudacorus)为主,浮叶植物以水葫芦(E.crassipes)为主,浮床植物以冷季型的水芹(O.javanica (B.)DC.)为主,植物总体覆盖度大于20%;生态输水渠水生植物群落包括沉水植物和挺水植物,其中,沉水植物包括菹草(P.crispus)和穗花狐尾藻(M.spicatum),挺水植物以芦苇(P.australis (Cav.) Trin.ex Steud.)、花叶芦竹(A.donax var. versicolor)、香蒲(T.orientalisPresl.)和水生鸢尾(I. pseudacorus)为主,水面水生植物盖度在30-50%之间;表面流湿地水生植物包括芦苇(P.australis (Cav.) Trin. ex Steud.)、花叶芦竹(A.donax var. versicolor)、香蒲(T.orientalisPresl.)和水生鸢尾(I. pseudacorus);水平潜流湿地水生植物群落以芦苇(P.australis (Cav.) Trin. ex Steud.)和水生鸢尾(I. pseudacorus)为主。The specific arrangement of aquatic plant communities: the emergent plants in the shallow water area of the stable pond bank are reed ( P.australis (Cav.) Trin. ex Steud.), mosaic reed bamboo ( A.donax var. versicolor ), cattail ( T. orientalis Presl.) and aquatic iris ( I. pseudacorus ), water hyacinth ( E. crassipes ) was the main floating leaf plant, and cool-season cress ( O.javanica (B.)DC.) was the main floating bed plant. Mainly, the overall coverage of plants is greater than 20%; the aquatic plant community of the ecological aqueduct includes submerged plants and emergent plants, among which, submerged plants include P.cripus and M. spicatum , The water plants are mainly reed ( P.australis (Cav.) Trin.ex Steud.), mosaic reed ( A.donax var. versicolor ), cattail ( T.orientalis Presl.) and aquatic iris ( I. pseudacorus ) , the water surface aquatic plant coverage is between 30-50%; the surface wetland aquatic plants include reed ( P.australis (Cav.) Trin. ex Steud.), mosaic reed bamboo ( A.donax var. versicolor ), cattail ( T.orientalis Presl.) and aquatic iris ( I. pseudacorus ); the aquatic plant community in horizontal subsurface wetlands is dominated by reed ( P.australis (Cav.) Trin. ex Steud.) and aquatic iris ( I. pseudacorus ).
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