CN106830686A - It is a kind of burn till after have concavo-convex texture candy glaze and Imitation Rock Porcelain Tiles preparation method - Google Patents
It is a kind of burn till after have concavo-convex texture candy glaze and Imitation Rock Porcelain Tiles preparation method Download PDFInfo
- Publication number
- CN106830686A CN106830686A CN201710002825.0A CN201710002825A CN106830686A CN 106830686 A CN106830686 A CN 106830686A CN 201710002825 A CN201710002825 A CN 201710002825A CN 106830686 A CN106830686 A CN 106830686A
- Authority
- CN
- China
- Prior art keywords
- glaze
- candy
- ink
- candy glaze
- concavo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000009508 confectionery Nutrition 0.000 title claims abstract description 119
- 238000002360 preparation method Methods 0.000 title abstract description 10
- 239000011449 brick Substances 0.000 claims abstract description 30
- 239000002245 particle Substances 0.000 claims abstract description 18
- 210000003298 dental enamel Anatomy 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 33
- 239000007921 spray Substances 0.000 claims description 25
- 239000000758 substrate Substances 0.000 claims description 17
- 238000001035 drying Methods 0.000 claims description 16
- 239000000314 lubricant Substances 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- 229940084030 carboxymethylcellulose calcium Drugs 0.000 claims description 8
- 238000010304 firing Methods 0.000 claims description 7
- 238000007689 inspection Methods 0.000 claims description 7
- 238000004144 decalcomania Methods 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 5
- 238000007688 edging Methods 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical group O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 235000013399 edible fruits Nutrition 0.000 claims description 4
- 229960000892 attapulgite Drugs 0.000 claims description 3
- 229910052625 palygorskite Inorganic materials 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 24
- 238000005422 blasting Methods 0.000 abstract description 5
- 230000007547 defect Effects 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 17
- 239000000919 ceramic Substances 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 230000001788 irregular Effects 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 238000010791 quenching Methods 0.000 description 4
- 230000000171 quenching effect Effects 0.000 description 4
- 230000000903 blocking effect Effects 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 230000001795 light effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 229910052656 albite Inorganic materials 0.000 description 1
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000009469 supplementation Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Finishing Walls (AREA)
Abstract
It is a kind of burn till after have concavo-convex texture candy glaze and Imitation Rock Porcelain Tiles preparation method, it is described burn till after have concavo-convex texture candy glaze, candy glaze glaze include stamp-pad ink and clear frit；The stamp-pad ink is (2.5~3.5) with the mass ratio of the transparent thin frit：(0.5~1.5), and the clear frit is the ball shaped particles of rule；The present invention has the candy glaze of concavo-convex texture after proposing to burn till, the concavo-convex texture of the brick face effect after burning till is finer and smoother, decorative effect more enriches, the preparation method of its Imitation Rock Porcelain Tiles has preparation process is simple, it is easy to operate, need not be processed by shot blasting, brick face effect third dimension is strong, the low advantage of defect rate.
Description
Technical field
The present invention relates to building ceramic decoration field of material technology, more particularly to it is a kind of burn till after there is the sugar of concavo-convex texture
The preparation method of fruit glaze and Imitation Rock Porcelain Tiles.
Background technology
In existing candy glazed brick production technology, the main of concave-convex brick face effect is obtained using glaze two kinds of sides
Formula, one kind is after charity base glaze then random or fixed point charity contains surface tension after the melting such as such as vanadic anhydride
The special glaze different from base glaze, concavo-convex texture is obtained after making burning；Another kind is to use some high temperature frits, and its charity is existed
Billet surface, after high temperature sintering, high temperature frit incomplete fusion can form certain concavo-convex texture.For the second way,
It is essentially by the way of at present after by clear frit crush, it is imposed on into billet surface by way of spraying charity,
Using being deposited by the way of charity frit granules again after spraying adhesive or present billet surface charity adhesive after traditional charity
In certain defect, such as kiln hood negative-pressure adsorption effect can greatly reduce frit.
Therefore, it has been proposed that frit granules are mixed with the stamp-pad ink of Production of Ceramics, the slurry that formation can be sprayed, by spray
Its charity in billet surface, but is presently limited to condition limitation by the mode of pouring, and the mode of this spray also has more drawback, example
Such as, the clear frit shape of identical fineness is different in existing spray candy glaze glaze, and the irregular shape of clear frit makes
During glaze is sprayed, the situation of spray gun blocking is easily caused；Carrying out after high temperature burns till, what is had carries out soft throwing treatment,
Although what is had does not make polishing, when being burnt till by high temperature, the clear frit in candy glaze glaze easily melts flattening, leads
Cause burn till after candy glazed brick concavo-convex texture it is not strong fine and smooth enough, it is not fine and smooth enough to touch feel, therefore finally processes
The candy glazed brick third dimension for arriving is not strong.
The content of the invention
It is an object of the invention to the candy glaze for proposing that there is after a kind of burning till concavo-convex texture, brick face effect after burning till
Concavo-convex texture is finer and smoother, and decorative effect more enriches.
It is another object of the present invention to propose a kind of method that use candy glaze prepares candy glaze Imitation Rock Porcelain Tiles, with system
Standby process is simple, easy to operate, without being processed by shot blasting, brick face effect third dimension is strong, the low advantage of defect rate.
It is that, up to this purpose, the present invention uses following technical scheme：
It is a kind of burn till after have concavo-convex texture candy glaze, candy glaze glaze include stamp-pad ink and clear frit；The stamp-pad ink
It is (2.5~3.5) with the mass ratio of the transparent thin frit：(0.5~1.5), and the clear frit is the spherical shape of rule
Particle.
Further illustrate, the fineness of the clear frit is 80~250 mesh.
Further illustrate, also include anti-settling agent in the stamp-pad ink, the anti-settling agent is carboxymethylcellulose calcium and/or concavo-convex
Rod stone clay, the content of the carboxymethylcellulose calcium is 0.5~1%, and the content of the attapulgite is 3~5%.
Further illustrate, lubricant is also included in the candy glaze glaze, the lubricant is talcum powder and/or graphite
Powder, the content of the lubricant is 0.3~0.6%.
A kind of method that use candy glaze prepares candy glaze Imitation Rock Porcelain Tiles, comprises the following steps：
(1) candy glaze glaze is prepared：By the clear frit of stamp-pad ink and different fineness according to 3：1 mass ratio mixing, system
Obtain candy glaze glaze；
(2) ground-coat enamel charity：To the billet surface charity ground-coat enamel after dried process；
(3) candy glaze glaze is sprayed：Base substrate after charity ground-coat enamel is sprayed into the candy glaze glaze；
(4) drying, high temperature burn till：After the brick blank drying after the candy glaze glaze will be sprayed, high temperature burns till, and is ground
After the quality inspection of side, obtaining surface has the candy glaze Imitation Rock Porcelain Tiles of concavo-convex texture.
Further illustrate, ink-jet printed operation is also included between the step (2) and step (3), by ink jet printer to cloth
Applying the base substrate after ground-coat enamel carries out ink-jet printed, the belt speed 20m/mim of the ink jet printer, and stamp with the size is 910 × 910mm.
Further illustrate, after the ink-jet printed operation also carry out spray light ink operation, will after ink-jet printed base
Body is dried according to the requirement being pre-designed after spray light ink is carried out to part decalcomania.
Further illustrate, the glaze amount of the ground-coat enamel in step (2) is 590g/m2, flow velocity is 4.77g/s, and proportion is
1.89, fineness is 325 mesh, and siccative percentage by weight is 0.3%.
Further illustrate, the glaze amount of the candy glaze glaze in step (3) is 490g/m2, flow velocity is 2.77g/s, than
Weight is 1.10.
Further illustrate, the temperature that the high temperature in step (4) burns till be 1170~1240 DEG C, firing time be 60~
70mim。
Beneficial effects of the present invention：The present invention is mainly adjusted by the formula rate system in the clear frit,
Will the stamp-pad ink be adjusted to 3 with the mass ratio of the transparent thin frit：1, and the clear frit is set to not at the same level
The fineness matched somebody with somebody, improves melting temperature, and firing range expands；The clear frit combines the good lubricity of the stamp-pad ink
With appropriate viscosity so that clear frit has certain suction viscous force and compared with small flow.By difference by way of spray
Clear frit of the level with fineness is more uniformly and stably distributed, and what is combined with base substrate is even closer；And after high temperature sintering, be difficult
It is melt flat, the glaze paint of the uneven texture for enriching exquisiteness can be formed in ceramic tile surface, if having printed layer under glazed layer, can be with
Obtain more three-dimensional abundant decorative effect；Also have by the way that the clear frit to be set to the ball shaped particles of rule in addition
Effect avoids the situation of spray gun blocking, reduces the limitation to nozzle diameter, easily facilitates the use for adjusting pressure and controlling glaze
Amount, the brick face touch feeling of the ceramic tile after burning till is finer and smoother, and need not be processed by shot blasting, third dimension is stronger, not only increases
Plus decoration functions, and also add the performances such as the wearability and rupture strength in brick face.
Brief description of the drawings
Fig. 1 is the schematic diagram of the spherical shaped transparent frit that the present invention is obtained by the way of particle crashes；
Fig. 2 is the schematic diagram of the clear frit that existing use water quenching method is obtained.
Specific embodiment
Further illustrate technical scheme below in conjunction with the accompanying drawings and by specific embodiment.
It is a kind of burn till after have concavo-convex texture candy glaze, it is characterised in that：Candy glaze glaze includes stamp-pad ink and transparent molten
Block；The stamp-pad ink is (2.5~3.5) with the mass ratio of the transparent thin frit：(0.5~1.5), and the clear frit is rule
Ball shaped particles then.
There is the candy glaze of concavo-convex texture, mainly by matching somebody with somebody in the clear frit after being burnt till described in proposed by the present invention
Square comparative system is adjusted, will the stamp-pad ink be adjusted to 3 with the mass ratio of the transparent thin frit：1, and will be described
Bright frit is set to the fineness of different gradation, improves melting temperature, and firing range expands；The clear frit combines described
The good lubricity and appropriate viscosity of stamp-pad ink, so that clear frit has certain suction viscous force and compared with small flow.It is logical
The candy glaze glaze cloth is imposed on billet surface by the mode for crossing spray, realizes that the clear frit of different gradation fineness is more uniform
Stably it is distributed, what is combined with base substrate is even closer, it is to avoid its situation about being layered after being siphoned away or burnt by negative pressure；And in high temperature sintering
Afterwards, the clear frit is difficult to be melt flat, the glaze paint of the uneven texture for enriching exquisiteness can be formed in ceramic tile surface, if in glaze
There is printed layer under surface layer, more three-dimensional abundant decorative effect can be obtained.Also it is set to by by the clear frit in addition
The ball shaped particles of rule, effectively prevent the situation of spray gun blocking, reduce the limitation to nozzle diameter, easily facilitate regulation pressure
Power and control the usage amount of glaze, the brick face touch feeling of the ceramic tile after burning till is finer and smoother, and need not be processed by shot blasting,
Third dimension is stronger, not only increases decoration functions, and also add the performances such as the wearability and rupture strength in brick face.
Further illustrate, the fineness of the clear frit is 80~250 mesh.It is transparent thin in due to the candy glaze glaze
The effect of frit is glaze paint is melted at high temperature, because the level of the transparent thin frit in the candy glaze glaze is different with fineness,
The clear frit of different gradation fineness that will be in the range of 80~250 mesh is mixed, and after being prepared in proportion with the stamp-pad ink,
It is put into mixer to be stirred uniformly, obtains the candy glaze glaze, it will not melt flat when high temperature burns till, is fired into bricks face generation
Uneven sense, under the shining of light, transparent thin frit can glitter, and effect more enriches exquisiteness.Supplementary notes, it is described
Potassium feldspar, albite, dolomite, lime stone, sodium carbonate, cunning that the raw material components of clear frit are known to the skilled person
Stone, aluminum oxide, barium carbonate etc., its chemical composition, include according to parts by weight：8~18 parts of Al2O3, 55~65 parts of SiO2、
10~18 parts of CaO, 5~10 parts of K2O, 5~12 parts of MgO, 4~10 parts of Ba2O3, 2~5 parts of ZnO.
The clear frit is melted by existing technique, but bulk clear frit is carried out by water quenching method with existing
Grinding is broken, and the mode for obtaining the clear frit of irregular particle is different, and the present invention uses the mode that particle crashes and carries out
It is broken, using intergranular mutual abrasive action power, so as to be retrieved as spherical regular clear frit particle；Realize the candy
Glaze glaze can use high-pressure spray gun during being sprayed, and more small-bore nozzle can be used, and reduce to nozzle
The limitation of size, it is to avoid shower nozzle blocks, improves the effect of spray glaze, increases the Modulatory character of spray.
Further illustrate, also include anti-settling agent in the stamp-pad ink, the anti-settling agent is carboxymethylcellulose calcium and/or concavo-convex
Rod stone clay, the content of the carboxymethylcellulose calcium is 0.5~1%, and the content of the attapulgite is 3~5%.Due to described
Stamp-pad ink is a kind of aqueous polymer, it is necessary to certain stability after mixing with clear frit stirring, it is ensured that short
The storage candy glaze glaze of phase will not occur obvious change, therefore by the anti-settling agent, that is, add a certain amount of institute
Carboxymethylcellulose calcium or the Concave-convex clay rod are stated, the precipitated and separated of the candy glaze glaze can be effectively reduced, institute can be made
Stating candy glaze glaze standing time greatly prolongs, and improves the stability of the candy glaze glaze.
Further illustrate, lubricant is also included in the candy glaze glaze, the lubricant is talcum powder and/or graphite
Powder, the content of the lubricant is 0.3~0.6%.Due in order to ensure by the candy glaze glaze spray by way of cloth
The uniformity of distribution when imposing on the billet surface, then need to increase the lubricity of the candy glaze glaze, makes sprayed
Sprinkling equipment will not be blocked during pouring, so as to be added in improving the uniformity and Modulatory character of spray, therefore the candy glaze glaze
Corresponding lubricant, improves the greasy property of the candy glaze glaze of the clear frit containing different fineness, optimizes charity effect, from
And improve the brick face decorative effect after burning till.
A kind of method that use candy glaze prepares candy glaze Imitation Rock Porcelain Tiles, comprises the following steps：
(1) candy glaze glaze is prepared：By the clear frit of stamp-pad ink and different fineness according to 3：1 mass ratio mixing, system
Obtain candy glaze glaze；
(2) ground-coat enamel charity：To the billet surface charity ground-coat enamel after dried process；
(3) candy glaze glaze is sprayed：Base substrate after charity ground-coat enamel is sprayed into the candy glaze glaze；
(4) drying, high temperature burn till：After the brick blank drying after the candy glaze glaze will be sprayed, high temperature burns till, and is ground
After the quality inspection of side, obtaining surface has the candy glaze Imitation Rock Porcelain Tiles of concavo-convex texture.
The method of the candy glaze Imitation Rock Porcelain Tiles prepared using the candy glaze with concavo-convex texture proposed by the present invention, first
In one layer of ground-coat enamel of adobe surface charity, after the glossiness certain to ensure its brick face, then the charity of the candy glaze glaze is carried out,
So as to obtain the candy glaze Imitation Rock Porcelain Tiles of the concavo-convex texture that can form finer and smoother after high temperature burns till, it has preparation technology letter
Single, easy to operate, without being processed by shot blasting, and the decorative effect in the brick face for obtaining enriches, and third dimension is strong, and defect rate is low excellent
Point.
Further illustrate, ink-jet printed operation is also included between the step (2) and step (3), by ink jet printer to cloth
Applying the base substrate after ground-coat enamel carries out ink-jet printed, the belt speed 20m/mim of the ink jet printer, and stamp with the size is 910 × 910mm.
By the ink-jet printed operation, decalcomania is mutually set off with the glaze layer of concave-convex effect, it is more three-dimensional abundant so as to reach
Brick face effect, further increase the dicoration of the candy glaze Imitation Rock Porcelain Tiles.
Further illustrate, after the ink-jet printed operation also carry out spray light ink operation, will after ink-jet printed base
Body is dried according to the requirement being pre-designed after spray light ink is carried out to part decalcomania.Light ink is that a kind of low temperature is saturating
Bright ink, place of the contrast without spray light ink seems more shinny after burning till；Therefore by the spray light ink
Light ink, according to design requirement, is sprayed in some areas by operation, then the ground that light ink is sprayed after burning till can produce light to imitate
Really, and the place for not spraying light ink does not have light effect then, so as to reach striking contrast, decalcomania is more enriched thin
It is greasy true to nature, increase the decorative effect in brick face.
Further illustrate, the glaze amount of the ground-coat enamel in step (2) is 590g/m2, flow velocity is 4.77g/s, and proportion is
1.89, fineness is 325 mesh, and siccative percentage by weight is 0.3%.Require supplementation with explanation：The ground-coat enamel is by the change by product examine
Work material is formed according to formula rate is well mixed, and its chemical composition includes SiO2, Al2O3, CaO, MgO, ZnO, K2O, Na2O, and
ZrO2, the ground-coat enamel also will by ball milling detection could use.
Further illustrate, the glaze amount of the candy glaze glaze in step (3) is 490g/m2, flow velocity is 2.77g/s, than
Weight is 1.10.By parameters such as the flow velocitys and proportion that control the candy glaze glaze certain, so that it is guaranteed that its cloth imposes on base substrate table
The uniformity in face and the tight ness rating combined with base substrate.
Further illustrate, the temperature that the high temperature in step (4) burns till be 1170~1240 DEG C, firing time be 60~
70mim。
A kind of surfaces of embodiment 1- have the preparation method of the Imitation Rock Porcelain Tiles of concavo-convex texture, comprise the following steps：
(1) acquisition bulk clear frit is founded by existing technique, bulk clear frit is broken by water quenching method
It is broken, obtain the clear frit of irregular particle；
(2) glaze is prepared：By the clear frit of stamp-pad ink and the irregular particle according to 3：1 mass ratio mixing, system
Obtain glaze；
(3) ground-coat enamel charity：To the billet surface charity ground-coat enamel after dried process；
(4) glaze is sprayed：Base substrate after charity ground-coat enamel is sprayed into the glaze；
(5) drying, high temperature burn till：After the brick blank drying after the glaze will be sprayed, high temperature burns till, and carries out edging quality inspection
Afterwards, obtaining surface has the Imitation Rock Porcelain Tiles 1 of concavo-convex texture.
A kind of surfaces of comparative example 1- have the preparation method of the Imitation Rock Porcelain Tiles of concavo-convex texture, comprise the following steps：
(1) acquisition bulk clear frit is founded by existing technique, is crushed by the way of particle crashes, obtained not
With the clear frit of the spherical rule of fineness, wherein fineness is 80~250 mesh；
(2) ground-coat enamel charity：To the billet surface charity ground-coat enamel after dried process；
(3) clear frit is dispensed：Billet surface after charity ground-coat enamel is equably dispensed into clear frit, and sprayed glues make
Be bonded in billet surface；
(4) drying, high temperature burn till：After the brick blank drying after clear frit will be dispensed, high temperature burns till, and carries out edging polishing
Afterwards, obtaining surface has the Imitation Rock Porcelain Tiles 2 of concavo-convex texture.
A kind of use candy glaze of comparative example 2- prepares the method that surface has the Imitation Rock Porcelain Tiles of concavo-convex texture, including as follows
Step：
(1) acquisition bulk clear frit is founded by existing technique, is crushed by the way of particle crashes, obtained not
With the clear frit of the spherical rule of fineness, wherein fineness is 80~250 mesh；
(2) candy glaze glaze is prepared：By the clear frit of stamp-pad ink and different fineness according to 3：1 mass ratio mixing, system
Obtain candy glaze glaze；
(3) ground-coat enamel charity：To the billet surface charity ground-coat enamel after dried process；
(4) candy glaze glaze is sprayed：Base substrate after charity ground-coat enamel is sprayed into the candy glaze glaze；
(5) drying, high temperature burn till：After the brick blank drying after the candy glaze glaze will be sprayed, high temperature burns till, and is ground
After the quality inspection of side, obtaining surface has the candy glaze Imitation Rock Porcelain Tiles 3 of concavo-convex texture.
Embodiment 1, comparative example 1 and comparative example 2 are contrasted, it can be seen that use in embodiment 1
It is the clear frit of existing common water quenching method acquisition irregular particle, but during to the spray for carrying out glaze, holds
Easily there is the phenomenon of obstruction；Though and the spherical rule that the mode that particle crashes obtains different fineness are employed in comparative example 1
Clear frit then, but due to being that its direct cloth is imposed on into billet surface and by glue bonding, cause to appear in portion when burning till
The situation for dividing clear frit to be siphoned away by negative pressure；And in comparative example 2 by by with different fineness it is spherical rule it is transparent
Frit is with stamp-pad ink according to 1：3 mass ratio mixing, not only its spray is smooth by the way of spray, and clear frit distribution is equal
It is even, and will not be siphoned away by negative pressure when being burnt till by high temperature, the brick face effect for more enriching fine and smooth concavo-convex texture can be obtained；Table
The brick face effect of the candy glaze Imitation Rock Porcelain Tiles that 1 expression embodiment 1 and comparative example 1,2 obtain compares；
The brick face effect of the different candy glaze Imitation Rock Porcelain Tiles of table 1
| Detection project | Candy glaze Imitation Rock Porcelain Tiles 3 | Candy glaze Imitation Rock Porcelain Tiles 2 | Candy glaze Imitation Rock Porcelain Tiles 1 |
| Glaze paint camber size | Greatly | In | It is small |
| Frit abundance | It is many | It is few | It is few |
A kind of use candy glaze of comparative example 3- prepares the method that surface has the Imitation Rock Porcelain Tiles of concavo-convex texture, including as follows
Step：
(1) acquisition bulk clear frit is founded by existing technique, is crushed by the way of particle crashes, obtained not
With the clear frit of the spherical rule of fineness, wherein fineness is 80~250 mesh；
(2) candy glaze glaze is prepared：By the clear frit of stamp-pad ink and different fineness according to 3：1 mass ratio mixing, and
And carboxymethylcellulose calcium is added as anti-settling agent and talcum powder as lubricant, candy glaze glaze is obtained, wherein, the candy
The glaze amount of glaze glaze is 490g/m2, flow velocity is 2.77g/s, and proportion is 1.10；
(3) ground-coat enamel charity：To the billet surface charity ground-coat enamel after dried process, wherein the glaze amount of the ground-coat enamel is 590g/
m2, flow velocity is 4.77g/s, and proportion is 1.89, and fineness is 325 mesh, and siccative percentage by weight is 0.3%；
(4) candy glaze glaze is sprayed：Base substrate after charity ground-coat enamel is sprayed into the candy glaze glaze；
(5) drying, high temperature burn till：After the brick blank drying after the candy glaze glaze will be sprayed, high temperature burns till, the high temperature
The temperature burnt till is 1240 DEG C, and firing time is 60mim；And after carrying out edging quality inspection, obtaining surface has the sugar of concavo-convex texture
Fruit glaze Imitation Rock Porcelain Tiles 4.
Comparative example 2 and comparative example 3 are compared and can obtained, it is anti-by adding in comparative example 3
The candy glaze glaze of heavy agent and lubricant with do not add the candy glaze glaze of anti-settling agent and lubricant to carry out experiment to compare, by trying
Test after obtaining adding anti-settling agent, standing time of the candy glaze glaze can extend 2.5~3.5 more than hour, and not
What is added can only place 0.3~0.5 hour, as shown in table 2 below,；And after lubricant, the degree of lubrication of the candy glaze glaze
Increase, it is not only evener to spraying effect smooth, and also the clear frit is more uniform and stable in the distribution of billet surface.
The standing time deck watch of the candy glaze glaze of table 2
The method that a kind of use candy glaze of comparative example 4- prepares the Imitation Rock Porcelain Tiles with concavo-convex texture, including following step
Suddenly：
(1) acquisition bulk clear frit is founded by existing technique, is crushed by the way of particle crashes, obtained not
With the clear frit of the spherical rule of fineness, wherein fineness is 80~250 mesh；
(2) candy glaze glaze is prepared：By the clear frit of stamp-pad ink and different fineness according to 3：1 mass ratio mixing, and
And it is lubricant to add Concave-convex clay rod as anti-settling agent and graphite powder, and candy glaze glaze is obtained, wherein, the candy glaze
The glaze amount of glaze is 490g/m2, flow velocity is 2.77g/s, and proportion is 1.10；
(3) ground-coat enamel charity：To the billet surface charity ground-coat enamel after dried process, wherein the glaze amount of the ground-coat enamel is 590g/
m2, flow velocity is 4.77g/s, and proportion is 1.89, and fineness is 325 mesh, and siccative percentage by weight is 0.3%；
(4) ink-jet printed operation：The base substrate after charity ground-coat enamel is carried out by ink jet printer it is ink-jet printed, the ink jet printer
Belt speed 20m/mim, stamp with the size is 910 × 910mm；
(5) light ink operation is sprayed：By the base substrate after ink-jet printed according to the requirement being pre-designed, to part stamp figure
Case is dried after carrying out spray light ink；
(6) candy glaze glaze is sprayed：Base substrate after charity ground-coat enamel is sprayed into the candy glaze glaze；
(7) drying, high temperature burn till：After the brick blank drying after the candy glaze glaze will be sprayed, high temperature burns till, the high temperature
The temperature burnt till is 1170 DEG C, and firing time is 70mim；And after carrying out edging quality inspection, obtaining surface has the sugar of concavo-convex texture
Fruit glaze Imitation Rock Porcelain Tiles 5.
Comparative example 3 and comparative example 4 are compared and can obtained, in comparative example 4, by increased
The ink-jet printed operation and spray light ink operation, decalcomania, light effect and concavo-convex texture are combined, its third dimension
More obvious, pattern more enriches exquisiteness, can not only increase the dicoration of the candy glaze Imitation Rock Porcelain Tiles, and its brick face light
Damp degree is greatly improved；Table 2 is directed to Performance comparision of the above example to different candy glaze Imitation Rock Porcelain Tiles, as shown in Table 3, by right
The obvious increase of glazed thickness of the candy glaze Imitation Rock Porcelain Tiles obtained than the preparation method of embodiment 4,3 and 2, its rupture strength and water suction
Rate is also more excellent relative to the candy glaze Imitation Rock Porcelain Tiles of embodiment 1；And the glaze thickness of the candy glaze Imitation Rock Porcelain Tiles obtained in comparative example 2
Degree, because when burning till, part is reduced by the glazed thickness that causes that negative pressure is siphoned away, and embodiment 1 is then due to reducing glaze after polishing
Thickness degree.
The Performance comparision of the different candy glaze Imitation Rock Porcelain Tiles of table 3
Know-why of the invention is described above in association with specific embodiment.These descriptions are intended merely to explain of the invention
Principle, and can not by any way be construed to limiting the scope of the invention.Based on explanation herein, the technology of this area
Personnel associate other specific embodiments of the invention by would not require any inventive effort, these modes fall within
Within protection scope of the present invention.
Claims (10)
1. it is a kind of burn till after have concavo-convex texture candy glaze, it is characterised in that：Candy glaze glaze includes stamp-pad ink and clear frit；
The stamp-pad ink is (2.5~3.5) with the mass ratio of the transparent thin frit：(0.5~1.5), and the clear frit is rule
Ball shaped particles.
2. it is according to claim 1 it is a kind of burn till after have concavo-convex texture candy glaze, it is characterised in that：It is described transparent molten
The fineness of block is 80~250 mesh.
3. it is according to claim 1 it is a kind of burn till after have concavo-convex texture candy glaze, it is characterised in that：In the stamp-pad ink
Also include anti-settling agent, the anti-settling agent is carboxymethylcellulose calcium and/or Concave-convex clay rod, the carboxymethylcellulose calcium contains
It is 0.5~1% to measure, and the content of the attapulgite is 3~5%.
4. it is according to claim 1 it is a kind of burn till after have concavo-convex texture candy glaze, it is characterised in that：The candy glaze
Also include lubricant in glaze, the lubricant is talcum powder and/or graphite powder, the content of the lubricant for 0.3~
0.6%.
5. a kind of method that candy glaze using as described in any one in Claims 1 to 4 prepares candy glaze Imitation Rock Porcelain Tiles, it is special
Levy and be：Comprise the following steps：
(1) candy glaze glaze is prepared：By the clear frit of stamp-pad ink and different fineness according to 3：1 mass ratio mixing, is obtained sugar
Fruit glaze glaze；
(2) ground-coat enamel charity：To the billet surface charity ground-coat enamel after dried process；
(3) candy glaze glaze is sprayed：Base substrate after charity ground-coat enamel is sprayed into the candy glaze glaze；
(4) drying, high temperature burn till：After the brick blank drying after the candy glaze glaze will be sprayed, high temperature burns till, and carries out edging matter
After inspection, obtaining surface has the candy glaze Imitation Rock Porcelain Tiles of concavo-convex texture.
6. the method that a kind of use candy glaze according to claim 5 prepares candy glaze Imitation Rock Porcelain Tiles, it is characterised in that：It is described
Also include ink-jet printed operation between step (2) and step (3), ink-jet print is carried out to the base substrate after charity ground-coat enamel by ink jet printer
Flower, the belt speed 20m/mim of the ink jet printer, stamp with the size is 910 × 910mm.
7. the method that a kind of use candy glaze according to claim 6 prepares candy glaze Imitation Rock Porcelain Tiles, it is characterised in that：It is described
Also carry out spraying light ink operation after ink-jet printed operation, it is right by the base substrate after ink-jet printed according to the requirement being pre-designed
Part decalcomania is dried after carrying out spray light ink.
8. the method that a kind of use candy glaze according to claim 5 prepares candy glaze Imitation Rock Porcelain Tiles, it is characterised in that：Step
(2) the glaze amount of the ground-coat enamel in is 590g/m2, flow velocity is 4.77g/s, and proportion is 1.89, and fineness is 325 mesh, siccative weight
Percentage is 0.3%.
9. the method that a kind of use candy glaze according to claim 5 prepares candy glaze Imitation Rock Porcelain Tiles, it is characterised in that：Step
(3) the glaze amount of the candy glaze glaze in is 490g/m2, flow velocity is 2.77g/s, and proportion is 1.10.
10. the method that a kind of use candy glaze according to claim 5 prepares candy glaze Imitation Rock Porcelain Tiles, it is characterised in that：Step
Suddenly the temperature that the high temperature in (4) burns till is 1170~1240 DEG C, and firing time is 60~70mim.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710002825.0A CN106830686A (en) | 2017-01-03 | 2017-01-03 | It is a kind of burn till after have concavo-convex texture candy glaze and Imitation Rock Porcelain Tiles preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710002825.0A CN106830686A (en) | 2017-01-03 | 2017-01-03 | It is a kind of burn till after have concavo-convex texture candy glaze and Imitation Rock Porcelain Tiles preparation method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106830686A true CN106830686A (en) | 2017-06-13 |
Family
ID=59117591
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710002825.0A Pending CN106830686A (en) | 2017-01-03 | 2017-01-03 | It is a kind of burn till after have concavo-convex texture candy glaze and Imitation Rock Porcelain Tiles preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106830686A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111099923A (en) * | 2019-12-30 | 2020-05-05 | 肇庆乐华陶瓷洁具有限公司 | Colorful ceramic tile and preparation method thereof |
| CN111592380A (en) * | 2020-05-14 | 2020-08-28 | 东莞市唯美陶瓷工业园有限公司 | Fine alignment etched non-light anti-slip ceramic tile and manufacturing method thereof |
| CN112340990A (en) * | 2020-11-25 | 2021-02-09 | 珠海市白兔陶瓷有限公司 | Antiskid brick and production process thereof |
| CN113651613A (en) * | 2021-07-06 | 2021-11-16 | 蓝思科技（长沙）有限公司 | Zirconia ceramic rear cover, preparation method thereof and 3D glaze |
| CN116395966A (en) * | 2023-03-09 | 2023-07-07 | 箭牌家居集团股份有限公司 | Glaze for flash ceramic, flash ceramic product, and manufacturing method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103435369A (en) * | 2013-08-12 | 2013-12-11 | 广东家美陶瓷有限公司 | Method for manufacturing wear-resistant antiskid dry-particle ceramic tile |
| CN103880474A (en) * | 2014-01-26 | 2014-06-25 | 广东宏陶陶瓷有限公司 | Glazed tile with wallpaper or bark-shaped surface and concave and convex effect and preparation method |
| CN103922815A (en) * | 2014-03-25 | 2014-07-16 | 广东金意陶陶瓷有限公司 | Manufacturing process of ceramic brick with candy effect |
| CN105218158A (en) * | 2015-08-27 | 2016-01-06 | 广东博华陶瓷有限公司 | A kind of happy ceramic tile |
-
2017
- 2017-01-03 CN CN201710002825.0A patent/CN106830686A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103435369A (en) * | 2013-08-12 | 2013-12-11 | 广东家美陶瓷有限公司 | Method for manufacturing wear-resistant antiskid dry-particle ceramic tile |
| CN103880474A (en) * | 2014-01-26 | 2014-06-25 | 广东宏陶陶瓷有限公司 | Glazed tile with wallpaper or bark-shaped surface and concave and convex effect and preparation method |
| CN103922815A (en) * | 2014-03-25 | 2014-07-16 | 广东金意陶陶瓷有限公司 | Manufacturing process of ceramic brick with candy effect |
| CN105218158A (en) * | 2015-08-27 | 2016-01-06 | 广东博华陶瓷有限公司 | A kind of happy ceramic tile |
Non-Patent Citations (2)
| Title |
|---|
| 余康泰: "《现代陶瓷色釉料与装饰技术手册》", 31 May 1999, 武汉工业大学出版社 * |
| 闻瑞昌等: "《搪瓷技术》", 31 January 1987, 轻工业出版社 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111099923A (en) * | 2019-12-30 | 2020-05-05 | 肇庆乐华陶瓷洁具有限公司 | Colorful ceramic tile and preparation method thereof |
| CN111592380A (en) * | 2020-05-14 | 2020-08-28 | 东莞市唯美陶瓷工业园有限公司 | Fine alignment etched non-light anti-slip ceramic tile and manufacturing method thereof |
| CN112340990A (en) * | 2020-11-25 | 2021-02-09 | 珠海市白兔陶瓷有限公司 | Antiskid brick and production process thereof |
| CN112340990B (en) * | 2020-11-25 | 2022-05-24 | 珠海市白兔陶瓷有限公司 | Antiskid brick and production process thereof |
| CN113651613A (en) * | 2021-07-06 | 2021-11-16 | 蓝思科技（长沙）有限公司 | Zirconia ceramic rear cover, preparation method thereof and 3D glaze |
| CN116395966A (en) * | 2023-03-09 | 2023-07-07 | 箭牌家居集团股份有限公司 | Glaze for flash ceramic, flash ceramic product, and manufacturing method and application thereof |
| CN116395966B (en) * | 2023-03-09 | 2024-03-08 | 箭牌家居集团股份有限公司 | Glaze for flash ceramic, flash ceramic product, and manufacturing method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103435369B (en) | Method for manufacturing wear-resistant antiskid dry-particle ceramic tile | |
| CN105272378B (en) | A kind of preparation method and product of the parian thickness glazed brick of the sagging texture of combination | |
| CN107963814B (en) | Composite glaze, composite glaze slip and 4-8 degree soft surface wear-resistant porcelain archaized brick | |
| CN106830686A (en) | It is a kind of burn till after have concavo-convex texture candy glaze and Imitation Rock Porcelain Tiles preparation method | |
| CN104140297B (en) | The glaze of embossment phantom ornamental brick and preparation | |
| CN110204306A (en) | Thin,tough silk matter exquisiteness matt ceramic brick and preparation method thereof | |
| CN110436963B (en) | Dry grain glaze, dry grain ceramic tile with white suspended floccules and preparation method thereof | |
| KR900008985B1 (en) | How to apply tile glaze, glaze on tile and tile manufacturing method | |
| CN109053226B (en) | Method for preparing matte dry particle glazed tile | |
| CN109279918A (en) | A kind of sheen brick and preparation method thereof | |
| CN114454303A (en) | Ceramic rock plate with low-gloss, fine and frosted effect surface and preparation method thereof | |
| CN104130032B (en) | A kind of manufacture method of glazed tile and products thereof | |
| CN106746651A (en) | A kind of dry granular glaze with diamond luster effect | |
| CN114163225A (en) | Preparation method of ceramic tile with super matte effect | |
| CN109665870A (en) | A kind of flexible die line porcelain Antique Imitation Tiles and preparation method thereof | |
| CN110104952A (en) | A kind of super abrasive Dali stone ceramic tile formula and processing technology | |
| CN104385106A (en) | Production method for glazed brick with matte effect | |
| CN107337455A (en) | A kind of powder dry-pressing formed for Ceramic Tiles and preparation method thereof | |
| CN107903086A (en) | A kind of ceramic tile that can produce low-light dry granular effect and preparation method thereof | |
| CN110885256A (en) | Digital dry particle inner wall brick with stereoscopic luminous effect and preparation method thereof | |
| CN108623331A (en) | A kind of glazed tile and its preparation process with crack effect | |
| CN106007800A (en) | Background wall brick preparing method and background wall preparing method | |
| CN102838386B (en) | Manufacturing method of glass-ceramic composite plate | |
| CN118545909B (en) | Colored flash dry particle, colored dazzling ceramic tile and preparation method thereof | |
| CN116395966B (en) | Glaze for flash ceramic, flash ceramic product, and manufacturing method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170613 |