CN106830862A - A kind of lime base raw-soil texture ornament materials and preparation method thereof - Google Patents

A kind of lime base raw-soil texture ornament materials and preparation method thereof Download PDF

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CN106830862A
CN106830862A CN201710032012.6A CN201710032012A CN106830862A CN 106830862 A CN106830862 A CN 106830862A CN 201710032012 A CN201710032012 A CN 201710032012A CN 106830862 A CN106830862 A CN 106830862A
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raw
soil
lime
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ornament materials
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CN106830862B (en
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朱绘美
李辉
刘文欢
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Xian University of Architecture and Technology
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • C04B28/12Hydraulic lime
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention relates to a kind of lime base raw-soil texture ornament materials and preparation method thereof.The weight fraction of each component is as follows:White lime is 25~40 parts, Desulphurization is 10~20 parts, vinyl redispersable latex powder is 0.4~1.2 part, HEMC is 0.03~0.15 part, organosilicon moisture repellent is 0.1~0.3 part, raw-soil binding agent is 0.5~1.0 part, and fiber is 0.05~0.2 part, and gross weight number is 100 parts.The construction wall compatibility of lime base raw-soil texture ornament materials of the present invention and various base materials, matching are good, and there is good workability, adhesive property, gas permeability and water proofing property, construction wall can be made to possess the decoration texture similar with traditional earth building wall, can apply to the wall facing decoration engineering of various base materials, and largely utilize industrial solid castoff, financial cost is relatively low, with good environmental protection and energy-conserving profit waste effect.

Description

一种石灰基生土质感装饰材料及其制备方法A kind of lime-based raw soil texture decorative material and preparation method thereof

技术领域technical field

本发明属于建筑材料技术领域,具体涉及到一种石灰基生土感装饰材料及制备方法。The invention belongs to the technical field of building materials, and in particular relates to a lime-based earth-feeling decorative material and a preparation method thereof.

背景技术Background technique

我国有大量的历史建筑采用生土建造,其外观具有生土墙体独特、自然、古朴的特色,但在这些历史建筑的修复和保护过程中发现,历史建筑所在区域内存在大量采用其他建筑材料如砖、石、混凝土等建造的建筑物,其内外墙装饰多采用涂料、瓷砖等现代装饰材料,外观与传统历史建筑极不协调,严重破坏了历史建筑街区的整体风貌。为使历史建筑周围的现代建筑具有与传统生土建筑一致的内、外观风貌,维持历史建筑街区的风貌协调性,需设计一种与各种基材的建筑墙体相容性好、粘结性优异且具有生土墙体外观的装饰材料,以满足不同墙体基材内、外层装饰的要求。There are a large number of historical buildings in my country built with raw soil, and their appearance has the unique, natural, and simple characteristics of raw soil walls. However, during the restoration and protection of these historical buildings, it was found that a large number of other building materials were used in the area where the historical buildings were located. Buildings made of brick, stone, concrete, etc., the interior and exterior walls are mostly decorated with modern decorative materials such as paint and ceramic tiles. The appearance is extremely inconsistent with traditional historical buildings, which seriously damages the overall style of historical buildings. In order to make the modern buildings around the historical buildings have the same internal and external appearance as the traditional earthen buildings, and maintain the harmony of the historical building blocks, it is necessary to design a building wall with good compatibility and bonding with various base materials. It is a decorative material with excellent durability and the appearance of raw earth wall, so as to meet the requirements of interior and exterior decoration of different wall substrates.

发明内容Contents of the invention

本发明通过科学研究和实践检验,综合利用循环流化床锅炉脱硫灰与石灰的活性激发作用,生土的外观装饰效果,聚合物添加剂的粘结强度以及生土粘结剂的加固作用,并通过制备工艺研究,成功制备出一种满足不同基材建筑墙体装饰工程需要的、具备传统生土建筑外观的、单组份的石灰基生土质感装饰材料,而且还大量综合利用工业固体废弃物,具有显著的经济效益、社会效益和环境效益。Through scientific research and practical testing, the present invention comprehensively utilizes the activation effect of circulating fluidized bed boiler desulfurization ash and lime, the appearance decoration effect of raw soil, the bonding strength of polymer additives and the reinforcement effect of raw soil binder, and Through the research on the preparation process, a single-component lime-based raw soil texture decorative material that meets the needs of building wall decoration projects with different base materials and has the appearance of traditional raw soil buildings has been successfully prepared, and a large number of industrial solid wastes are also comprehensively utilized. It has significant economic, social and environmental benefits.

针对现有技术存在的不足,本发明的目的在于,通过配合比优化以及制备方法研究,制备出物理力学性能优良稳定、具有良好的墙体装饰效果和粘结性能的石灰基生土质感装饰材料及制备方法,并大量综合利用工业固体废弃物,节约资源和能源,保护环境。In view of the deficiencies in the prior art, the purpose of the present invention is to prepare a lime-based raw soil texture decorative material with excellent and stable physical and mechanical properties, good wall decoration effect and bonding performance through the optimization of the mix ratio and the research of the preparation method and preparation method, and a large amount of comprehensive utilization of industrial solid waste, saving resources and energy, and protecting the environment.

为了解决上述技术问题,本申请采用如下技术方案予以实现:In order to solve the above-mentioned technical problems, the application adopts the following technical solutions to achieve:

一种石灰基生土质感装饰材料,由以下原料组成:生土、熟石灰、脱硫灰、乙烯基可再分散乳胶粉、羟乙基甲基纤维素、有机硅憎水剂、生土粘结剂和纤维。A lime-based raw soil texture decorative material, which is composed of the following raw materials: raw soil, slaked lime, desulfurized ash, vinyl redispersible latex powder, hydroxyethyl methylcellulose, silicone water repellent, raw soil binder and fiber.

以重量单位计,按以下原料组成:生土为45~65份,熟石灰为25~40份,脱硫灰为10~20份,乙烯基可再分散乳胶粉为0.4~1.2份,羟乙基甲基纤维素为0.03~0.15份,有机硅憎水剂为0.1~0.3份,生土粘结剂为0.5~1.0份,纤维为0.05~0.2份,总重量份数为100份。In terms of weight unit, it is composed of the following raw materials: 45-65 parts of raw soil, 25-40 parts of slaked lime, 10-20 parts of desulfurized ash, 0.4-1.2 parts of vinyl redispersible latex powder, hydroxyethyl methyl 0.03-0.15 parts of cellulose base, 0.1-0.3 parts of organosilicon water repellent, 0.5-1.0 parts of raw soil binder, 0.05-0.2 parts of fiber, and the total parts by weight are 100 parts.

具体的,所述生土为过筛目数在100目以下的生土粉末。Specifically, the raw soil is raw soil powder with a sieve mesh number below 100 mesh.

优选的,所述脱硫灰为循环流化床锅炉脱硫灰。Preferably, the desulfurization ash is a circulating fluidized bed boiler desulfurization ash.

具体的,所述羟乙基甲基纤维素黏度为10000~45000mPa·s。Specifically, the viscosity of the hydroxyethyl methylcellulose is 10000-45000 mPa·s.

具体的,所述纤维为直径为0.5~3mm的木质纤维。Specifically, the fibers are wood fibers with a diameter of 0.5-3 mm.

具体的,所述生土粘结剂为模数3.3的钠水玻璃,分子式为Na2O·nSiO2Specifically, the raw soil binder is sodium water glass with a modulus of 3.3 and a molecular formula of Na 2 O·nSiO 2 .

优选的,以重量单位计,按以下原料组成:熟石灰为38份,脱硫灰为12份,乙烯基可再分散乳胶粉为1.0份,羟乙基甲基纤维素为0.08份,有机硅憎水剂为0.3份,生土粘结剂为0.8份,纤维为0.1份,生土为47.72份,其总重量份数为100份。Preferably, in units of weight, the following raw materials are composed: 38 parts of slaked lime, 12 parts of desulfurized ash, 1.0 part of vinyl redispersible latex powder, 0.08 part of hydroxyethyl methylcellulose, and silicone hydrophobic Agent is 0.3 part, raw soil binder is 0.8 part, fiber is 0.1 part, raw soil is 47.72 parts, and its total parts by weight is 100 parts.

所述的石灰基生土质感装饰材料的制备方法:The preparation method of described lime-based raw soil texture decoration material:

以所述石灰基生土质感装饰材料的原料配方为基准,Based on the raw material formula of the lime-based raw soil texture decorative material,

该方法包括以下过程:首先,向高速混合机中加入乙烯基可再分散乳胶粉、羟乙基甲基纤维素、有机硅憎水剂、生土粘结剂和纤维,在500~1000r/min的混合速率下混合均匀,然后,调节高速混合机的混合的混合速率为80~250r/min,加入熟石灰、脱硫灰和生土,混合均匀,即制得石灰基生土质感装饰材料。The method includes the following process: First, add vinyl redispersible latex powder, hydroxyethyl methylcellulose, organic silicon water repellent, raw soil binder and fiber into the high-speed mixer, at 500 ~ 1000r/min Then, adjust the mixing speed of the high-speed mixer to 80-250r/min, add slaked lime, desulfurized ash and raw soil, and mix evenly to obtain a lime-based raw soil texture decoration material.

本发明所述的石灰基生土质感装饰材料成品为单组分的粉体材料,施工时只需在施工现场将其与水按给定比例搅拌3~4min,即可使用。The finished lime-based soil-textured decorative material of the present invention is a single-component powder material, which can be used only by stirring it with water at a given ratio for 3-4 minutes at the construction site during construction.

本发明提出的石灰基生土质感装饰材料检测结果如表1所示。The test results of the lime-based raw soil texture decorative material proposed by the present invention are shown in Table 1.

表1石灰基生土质感装饰材料基本性能Table 1 Basic properties of lime-based raw soil texture decorative materials

由表1可以看出,本发明提出的石灰基生土质感装饰材料,其物理力学性能良好,均可满足或超过相关标准要求,具有良好的耐水性和粘结强度,以及优异的外墙装饰效果。It can be seen from Table 1 that the lime-based raw soil texture decorative material proposed by the present invention has good physical and mechanical properties, can meet or exceed the requirements of relevant standards, has good water resistance and bonding strength, and excellent exterior wall decoration Effect.

本发明与现有技术相比,有益的技术效果是:Compared with the prior art, the present invention has beneficial technical effects as follows:

本发明提出的石灰基生土质感装饰材料,采用生土作为填料和颜料,以熟石灰作为主要胶凝材料,同时添加循环流化床锅炉脱硫灰作为水硬性添加剂改善熟石灰材料的强度和耐水性等,一方面可减少利用水泥所产生的高能耗,另一方面还能促进固体废弃物的资源化利用。The lime-based raw soil texture decorative material proposed by the present invention adopts raw soil as filler and pigment, uses slaked lime as the main gelling material, and simultaneously adds circulating fluidized bed boiler desulfurization ash as a hydraulic additive to improve the strength and water resistance of the slaked lime material, etc. , On the one hand, it can reduce the high energy consumption caused by the use of cement, and on the other hand, it can also promote the resource utilization of solid waste.

本发明提出的石灰基生土质感装饰材料,应用范围广,适用于各种建筑内外墙抹面工程,尤其是需要与生土墙体装饰效果一致的各种抹面工程。本发明具有优异的施工性能,可操作时间长、吸水率低、抗压强度高、结性能好、装饰效果好、还具有特别突出的耐候性及长期性能。The lime-based raw soil texture decorative material proposed by the invention has a wide range of applications, and is suitable for various plastering projects of interior and exterior walls of buildings, especially various plastering projects that need to be consistent with the decorative effect of raw soil walls. The invention has excellent construction performance, long operating time, low water absorption, high compressive strength, good knot performance, good decorative effect, and particularly outstanding weather resistance and long-term performance.

本发明提出的石灰基生土质感装饰材料各性能指标优良,制备方法简便易行,产品品质易于控制,施工性能优异,装饰效果突出,长期性能优越,耐久性好,适用于各种建筑外墙抹面工程,便于大规模推广应用。The lime-based raw soil texture decorative material proposed by the present invention has excellent performance indicators, simple and easy preparation method, easy control of product quality, excellent construction performance, outstanding decorative effect, superior long-term performance and good durability, and is suitable for various building exterior walls The plastering project is convenient for large-scale promotion and application.

具体实施方式detailed description

下面通过实施例进一步说明本发明。The present invention is further illustrated below by way of examples.

实施例1:一种石灰基生土质感装饰材料,其组分及配比(质量百分比)为:熟石灰为38份,脱硫灰为12份,乙烯基可再分散乳胶粉为1.0份,羟乙基甲基纤维素为0.08份,有机硅憎水剂为0.3份,生土粘结剂为0.8份,纤维为0.1份,生土为47.72份,其总重量份数为100份。Embodiment 1: A kind of lime-based raw soil texture decoration material, its component and proportioning ratio (mass percentage): 38 parts of slaked lime, 12 parts of desulfurized ash, 1.0 parts of vinyl redispersible latex powder, hydroxyethyl 0.08 parts of methyl cellulose, 0.3 parts of silicone water repellent, 0.8 parts of raw soil binder, 0.1 part of fiber, 47.72 parts of raw soil, and the total parts by weight are 100 parts.

检测测试得到的性能结果如表2所示。The performance results obtained by the detection test are shown in Table 2.

表2实施例1的石灰基生土质感装饰材料性能测试结果The performance test result of the lime-based raw soil texture decorative material of Table 2 Example 1

项目project 实测性能Measured performance 可操作时间Operational time 180min180min 初期干燥抗裂性Initial drying crack resistance 无裂纹no crack 30min吸水量/g30min water absorption/g 0.80.8 240min吸水量/g240min water absorption/g 1.51.5 抗折强度/MPaFlexural strength/MPa 5.65.6 抗压强度/MPaCompressive strength/MPa 8.58.5 拉伸粘结强度/MPaTensile bond strength/MPa 1.51.5 抗泛碱性Anti-pantothenic 无可见泛碱,不掉粉No visible efflorescence, no powder shedding 耐沾污性Stain resistance 11 耐候性weather resistance 28次雨水淋蚀后外观无变化No change in appearance after 28 times of rain erosion

实施例2:一种石灰基生土质感装饰材料,其组分及配比(质量百分比)为:熟石灰为25份,脱硫灰为18份,乙烯基可再分散乳胶粉为0.8份,羟乙基甲基纤维素为0.06份,憎水剂为0.25份,生土粘结剂为0.6份,纤维为0.15份,生土为55.14份,其总重量份数为100份。Embodiment 2: A kind of lime-based raw soil texture decoration material, its component and proportioning ratio (mass percentage): 25 parts of slaked lime, 18 parts of desulfurized ash, 0.8 part of vinyl redispersible latex powder, hydroxyethyl 0.06 parts of methyl cellulose, 0.25 parts of water repellent, 0.6 parts of raw soil binder, 0.15 parts of fiber, 55.14 parts of raw soil, and the total parts by weight are 100 parts.

检测测试得到的性能结果如表3所示。The performance results obtained by the detection test are shown in Table 3.

表3实施例2的石灰基生土质感装饰材料性能测试结果The performance test results of the lime-based raw soil texture decorative material of Table 3 Example 2

实施例3:一种石灰基生土质感装饰材料,其组分及配比(质量百分比)为:熟石灰为35份,脱硫灰为20份,乙烯基可再分散乳胶粉为1.0份,羟乙基甲基纤维素为0.12份,憎水剂为0.3份,生土粘结剂为1.0份,纤维为0.15份,生土为42.43份,其总重量份数为100份。Embodiment 3: A kind of lime-based raw soil texture decoration material, its component and proportioning ratio (mass percentage): 35 parts of slaked lime, 20 parts of desulfurized ash, 1.0 parts of vinyl redispersible latex powder, hydroxyethyl 0.12 parts of methyl cellulose, 0.3 parts of water repellent, 1.0 part of raw soil binder, 0.15 parts of fiber, 42.43 parts of raw soil, and the total parts by weight are 100 parts.

检测测试得到的性能结果如表4所示。The performance results obtained by the detection test are shown in Table 4.

表4实施例3的石灰基生土质感装饰材料性能测试结果The performance test results of the lime-based raw soil texture decorative material of Table 4 Example 3

项目project 实测性能Measured performance 可操作时间Operational time 130min130min 初期干燥抗裂性Initial drying crack resistance 无裂纹no crack 30min吸水量/g30min water absorption/g 0.80.8 240min吸水量/g240min water absorption/g 1.31.3 抗折强度/MPaFlexural strength/MPa 5.05.0 抗压强度/MPaCompressive strength/MPa 9.59.5 拉伸粘结强度/MPaTensile bond strength/MPa 1.81.8 抗泛碱性Anti-pantothenic 无可见泛碱,不掉粉No visible efflorescence, no powder shedding 耐沾污性Stain resistance 11 耐候性weather resistance 28次雨水淋蚀后外观无变化No change in appearance after 28 times of rain erosion

由以上实施例可见,本发明提出的石灰基生土质感装饰材料,可根据建筑工程的要求,配制出相应的产品。各项性能指标均满足或超过相关标准和工程要求,可作为建筑外墙装饰工程材料,起到良好的装饰效果,可以广泛推广应用于各种建筑外墙抹面工程。It can be seen from the above examples that the lime-based raw soil texture decorative material proposed by the present invention can be formulated into corresponding products according to the requirements of construction projects. All performance indicators meet or exceed relevant standards and engineering requirements, and can be used as building exterior wall decoration engineering materials to achieve good decorative effects, and can be widely used in various building exterior wall plastering projects.

Claims (8)

1. a kind of lime base raw-soil texture ornament materials, it is characterised in that:It is made up of following raw material:The raw-soil, white lime, desulfurization Ash, vinyl redispersable latex powder, HEMC, organosilicon moisture repellent, raw-soil binding agent and fiber.
2. lime base raw-soil texture ornament materials as claimed in claim 1, it is characterised in that:With weight basis, by following Raw material is constituted:The raw-soil is 45~65 parts, and white lime is 25~40 parts, and Desulphurization is 10~20 parts, vinyl Redispersable latex Powder is 0.4~1.2 part, and HEMC is 0.03~0.15 part, and organosilicon moisture repellent is 0.1~0.3 part, and the raw-soil glues Knot agent is 0.5~1.0 part, and fiber is 0.05~0.2 part, and the parts by weight sum of raw material is 100 parts.
3. lime base raw-soil texture ornament materials as claimed in claim 1, it is characterised in that:The raw-soil was that grit number exists Raw-soil powder below 100 mesh.
4. lime base raw-soil texture ornament materials as claimed in claim 1, it is characterised in that:The Desulphurization is ciculation fluidized Bed boiler desulfurization ash.
5. lime base raw-soil texture ornament materials as claimed in claim 1, it is characterised in that:The HEMC Viscosity is 10000~45000mPas.
6. lime base raw-soil texture ornament materials as claimed in claim 1, it is characterised in that:The fibre diameter be 0.5~ The wood fibre of 3mm.
7. lime base raw-soil texture ornament materials as claimed in claim 1, it is characterised in that:The raw-soil binding agent is modulus 3.3 sodium silicate, molecular formula is Na2O·nSiO2
8. a kind of preparation method of lime base raw-soil texture ornament materials, it is characterised in that:The method using as claim 1 to The formula of the lime base raw-soil texture ornament materials described in 7 any claims;
The method includes procedure below:First, to addition vinyl redispersable latex powder, hydroxyethyl methyl in high-speed mixer Cellulose, organosilicon moisture repellent, raw-soil binding agent and fiber, are well mixed, so under the mixing rate of 500~1000r/min Afterwards, the mixing rate of the mixing of regulation high-speed mixer is 80~250r/min, adds white lime, Desulphurization and the raw-soil, mixing Uniformly, that is, lime base raw-soil texture ornament materials is obtained.
CN201710032012.6A 2017-01-17 2017-01-17 A kind of lime base raw-soil texture ornament materials and preparation method thereof Active CN106830862B (en)

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CN110194638A (en) * 2019-06-24 2019-09-03 西安建筑科技大学 A kind of earth building reinforcement and repair slag reconciliation water lime mortar and preparation method thereof
CN110317029A (en) * 2019-07-03 2019-10-11 西安建筑科技大学 A kind of masonry ancient building reinforcement and repair silicon ash reconciliation water lime mortar and preparation method
CN112940545A (en) * 2021-02-08 2021-06-11 天津城建大学 Decorative waterproof coating for protecting raw soil surface and construction method
CN117088666A (en) * 2023-08-22 2023-11-21 青海省建筑建材科学研究院有限责任公司 An antique restoration material for ancient buildings in loess areas and its application

Families Citing this family (1)

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CN110240459A (en) * 2019-06-29 2019-09-17 西安建筑科技大学 A kind of sulfur-fixed ash mixed hydraulic lime mortar for strengthening and repairing masonry ancient buildings and its preparation method

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CN104844090A (en) * 2015-05-05 2015-08-19 中国建筑材料科学研究总院 Raw soil plastering binding material suitable for raw soil building blocks and preparation method of binding material

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CN102010173A (en) * 2010-11-15 2011-04-13 重庆大学 Method for preparing heat insulation anti-cracking raw soil bricks
CN104844090A (en) * 2015-05-05 2015-08-19 中国建筑材料科学研究总院 Raw soil plastering binding material suitable for raw soil building blocks and preparation method of binding material

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110194638A (en) * 2019-06-24 2019-09-03 西安建筑科技大学 A kind of earth building reinforcement and repair slag reconciliation water lime mortar and preparation method thereof
CN110317029A (en) * 2019-07-03 2019-10-11 西安建筑科技大学 A kind of masonry ancient building reinforcement and repair silicon ash reconciliation water lime mortar and preparation method
CN112940545A (en) * 2021-02-08 2021-06-11 天津城建大学 Decorative waterproof coating for protecting raw soil surface and construction method
CN117088666A (en) * 2023-08-22 2023-11-21 青海省建筑建材科学研究院有限责任公司 An antique restoration material for ancient buildings in loess areas and its application

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