CN106832108A - A kind of aqueous double-component floor paint resin dispersion liquid and preparation method thereof - Google Patents
A kind of aqueous double-component floor paint resin dispersion liquid and preparation method thereof Download PDFInfo
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- CN106832108A CN106832108A CN201710080876.5A CN201710080876A CN106832108A CN 106832108 A CN106832108 A CN 106832108A CN 201710080876 A CN201710080876 A CN 201710080876A CN 106832108 A CN106832108 A CN 106832108A
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- dispersion liquid
- resin dispersion
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- floor paint
- component floor
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- 239000003973 paint Substances 0.000 title claims abstract description 63
- 239000006185 dispersion Substances 0.000 title claims abstract description 37
- 239000007788 liquid Substances 0.000 title claims abstract description 36
- 239000011347 resin Substances 0.000 title claims abstract description 35
- 229920005989 resin Polymers 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 20
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002904 solvent Substances 0.000 claims abstract description 14
- 239000003999 initiator Substances 0.000 claims abstract description 10
- 239000000049 pigment Substances 0.000 claims abstract description 10
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 3
- 150000002148 esters Chemical class 0.000 claims abstract description 3
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 11
- 238000009835 boiling Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 8
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 claims description 7
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 7
- 229960002887 deanol Drugs 0.000 claims description 7
- 239000012972 dimethylethanolamine Substances 0.000 claims description 7
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims description 7
- 239000000376 reactant Substances 0.000 claims description 7
- 235000010265 sodium sulphite Nutrition 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 6
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 claims description 5
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 1
- FYIBPWZEZWVDQB-UHFFFAOYSA-N dicyclohexyl carbonate Chemical class C1CCCCC1OC(=O)OC1CCCCC1 FYIBPWZEZWVDQB-UHFFFAOYSA-N 0.000 claims 1
- 125000005634 peroxydicarbonate group Chemical group 0.000 claims 1
- FYLJKQFMQFOLSZ-UHFFFAOYSA-N cyclohexylperoxycyclohexane Chemical group C1CCCCC1OOC1CCCCC1 FYLJKQFMQFOLSZ-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 230000003260 anti-sepsis Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- -1 color Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1806—C6-(meth)acrylate, e.g. (cyclo)hexyl (meth)acrylate or phenyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of aqueous double-component floor paint resin dispersion liquid, it is prepared by the component including following volume parts：Methacrylic acid 15 ~ 25 parts of ester, 5 ~ 10 parts of styrene, 10 ~ 15 parts of acrylic acid first butyl ester, 2 ~ 5 parts of acrylic acid, 3 ~ 8 parts of initiator, 5 ~ 10 parts of solvent, 0.5 ~ 3 part of industrial naptha, 2 ~ 5 parts of diatomite, 1 ~ 5 part of pigment, preparation method and application the invention also discloses above-mentioned aqueous woodware paint resin dispersion liquid, the aqueous double-component floor paint prepared using the aqueous woodware paint resin dispersion liquid has the advantages that hardness is high, water resistance strong, it is good to be difficult to take off skin, richness.
Description
Technical field
The invention belongs to water paint technical field, and in particular to a kind of aqueous double-component floor paint resin dispersion liquid and its
Preparation method.
Background technology
Floor paint was invented in 1934 by Germany, was mainly made up of oil plant, tree material, color, solvent etc., mainly
It is divided into ornamental floor paint, heavy antisepsis floor paint, resistance to heavily loaded floor paint etc..Floor paint by various different materials it is blended, dissolving,
Many end production process such as dispersion are manufactured and constituted.The features such as floor paint has beautiful, true, attractive in appearance, wear-resisting, waterproof, anti-corrosion,
It is mainly used in the places such as gymnasium, factory, parking lot.
Oiliness floor paint is commercially widely used, but with the continuous lifting of consumer's environmental consciousness, environmentally friendly political affairs
The pressure of plan, provinces and cities especially in all parts of the country have put into effect VOC emission limit standard, encourage furniture enterprise, public place to use non-molten
Formulation coating, the application of oil paint is restricted.Although traditional coating is still in occupation of the larger market share, aqueous
Paint is pollution-free industry, is the direction for painting class future development, and the water paint leading enterprise in domestic native country emerges.Water paint
Development and the shared market share have been undisputable facts increasing year by year, and have the trend of speed-raising.Some enterprises are
Recognize the wide market potential of water paint, research and develop one after another, march, expanding water paint market.
Although water paint superior traditional paint on environmental-protecting performance, in physical property, water paint product is present
Construction is difficult, not water-fast, easily take off the defects such as the poor, difference of hardness of skin, richness.Paint due to hardness it is strong, paint film richness is high, apply
The features such as work is tolerant, first-selected coating when being still many people's decorations.Defect only in physical property is resolved, very
To beyond tradition paint, consumer just can more actively select to use water paint.Only consumer is catered on environmental-protecting performance,
Consumer cannot be met on construction technology, decorative effect, the market of water paint is still difficult to open.This needs water paint to give birth to
Produce enterprise and do technological innovation in water paint performance.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of aqueous double-component floor paint resin dispersion liquid.
The technical problem also to be solved of the invention is to provide the preparation of above-mentioned aqueous double-component floor paint resin dispersion liquid
Method.
A kind of aqueous double-component floor paint resin dispersion liquid, it is prepared by the component including following volume parts
's：
Methacrylic acid 15 ~ 25 parts of ester
5 ~ 10 parts of styrene
10 ~ 15 parts of acrylic acid first butyl ester
2 ~ 5 parts of acrylic acid
3 ~ 8 parts of initiator
5 ~ 10 parts of solvent
0.5 ~ 3 part of industrial naptha
2 ~ 5 parts of diatomite
1 ~ 5 part of pigment.
Wherein, described initiator is in di-cyclohexylperoxy di-carbonate, peroxy dicarbonate isopropyl ester, sodium sulfite
The composition of one or more.
Wherein, described solvent is：EGME, ethylene glycol ethyl ether, butyl glycol ether, in diethylene glycol dimethyl ether one
Plant or several compositions.
Wherein, the boiling range of the industrial naptha is 150 DEG C ~ 200 DEG C.
The preparation method of above-mentioned aqueous double-component floor paint resin dispersion liquid, comprises the following steps：
(1) it is according to volume ratio by solvent and industrial naptha（15~25）：（0.5~3）Add in reactor, be warming up to 100 ~ 120
℃；
(2) by methacrylic acid ester, styrene, acrylic acid first butyl ester, acrylic acid, initiator, diatomite, pigment according to body
Accumulating ratio is（15~25）：（5~10）：（10~15）：（2~5）：（5~8）：（2~5）：（1~5）It is well mixed, then it is progressively added drop-wise to
In reactor, time for adding is 3 ~ 5h；
(3) 2 ~ 3h is incubated after completion of dropwise addition at 110 ~ 120 DEG C, the temperature in reactor is down to 90 ~ 100 DEG C；
(4) dimethylethanolamine is added, stirring is neutralized, is added after water makes reactant scatter, cooled, make reactor
The temperature of middle material is down to 30 ~ 40 DEG C；
(5) filter, that is, obtain aqueous woodware paint resin dispersion liquid.
Wherein, described solvent is that propane diols ether solvent is EGME, ethylene glycol ethyl ether, butyl glycol ether, two
The composition of one or more in EGME；The boiling range of the industrial naptha is 150 DEG C ~ 200 DEG C；Described initiator
It is the composition of one or more in di-cyclohexylperoxy di-carbonate, peroxy dicarbonate isopropyl ester, sodium sulfite.
The aqueous double-component floor paint that the preparation method of above-mentioned aqueous double-component floor paint resin dispersion liquid is prepared
Use resin dispersion liquid.
Application of the above-mentioned aqueous double-component floor paint resin dispersion liquid in aqueous double-component floor paint is prepared.
Beneficial effect：
The invention discloses a kind of aqueous double-component floor paint resin dispersion liquid and preparation method thereof, this utilizes the resin dispersion
The double-component floor paint that liquid is prepared has the advantages that hardness is high, water resistance strong, it is good to be difficult to take off skin, richness.
Specific embodiment
According to following embodiments, the present invention may be better understood.However, as it will be easily appreciated by one skilled in the art that real
Apply the content described by example and be merely to illustrate the present invention, without should also without limitation on sheet described in detail in claims
Invention.
Embodiment 1：
The preparation method of aqueous double-component floor paint resin dispersion liquid, comprises the following steps：
(1) by EGME and industrial naptha（Boiling range is 150 DEG C ~ 200 DEG C）It is 15 according to volume ratio：2 add reactor
In, it is warming up to 110 DEG C；
(2) by methacrylic acid ester, styrene, acrylic acid first butyl ester, acrylic acid, peroxy dicarbonate isopropyl ester, diatom
Soil, pigment are 15 according to volume ratio：5：10：3：6：2：1 is well mixed, then it is progressively added drop-wise in reactor, time for adding
It is 3 ~ 5h；
(3) 2 ~ 3h is incubated after completion of dropwise addition at 110 ~ 120 DEG C, the temperature in reactor is down to 90 ~ 100 DEG C；
(4) dimethylethanolamine is added, it is neutrality that stirring is neutralized to pH, is added after water makes reactant scatter, cooling drop
Temperature, makes the temperature of material in reactor be down to 30 ~ 40 DEG C；
(5) filter, that is, obtain aqueous woodware paint resin dispersion liquid.
Embodiment 2：
The preparation method of aqueous double-component floor paint resin dispersion liquid, comprises the following steps：
(1) by ethylene glycol ethyl ether and industrial naptha（Boiling range is 180 DEG C ~ 200 DEG C）It is 20 according to volume ratio：1 adds reactor
In, it is warming up to 100 ~ 120 DEG C；
(2) by methacrylic acid ester, styrene, acrylic acid first butyl ester, acrylic acid, di-cyclohexylperoxy di-carbonate, diatom
Soil, pigment are 25 according to volume ratio：10：15：5：6：4：3 are well mixed, then it are progressively added drop-wise in reactor, time for adding
It is 3 ~ 5h；
(3) 2 ~ 3h is incubated after completion of dropwise addition at 110 ~ 120 DEG C, the temperature in reactor is down to 90 ~ 100 DEG C；
(4) dimethylethanolamine is added, stirring is neutralized, is added after water makes reactant scatter, cooled, make reactor
The temperature of middle material is down to 30 ~ 40 DEG C；
(5) filter, that is, obtain aqueous woodware paint resin dispersion liquid.
Embodiment 3：
The preparation method of aqueous double-component floor paint resin dispersion liquid, comprises the following steps：
(1) by butyl glycol ether and industrial naptha（Boiling range is 150 DEG C ~ 200 DEG C）It is 20 according to volume ratio：2 add reactor
In, it is warming up to 100 ~ 120 DEG C；
(2) by methacrylic acid ester, styrene, acrylic acid first butyl ester, acrylic acid, sodium sulfite, diatomite, pigment according to
Volume ratio is 20：6：13：3：6：3：4 are well mixed, then it is progressively added drop-wise in reactor, and time for adding is 3 ~ 5h；
(3) 2 ~ 3h is incubated after completion of dropwise addition at 110 ~ 120 DEG C, the temperature in reactor is down to 90 ~ 100 DEG C；
(4) dimethylethanolamine is added, stirring is neutralized, is added after water makes reactant scatter, cooled, make reactor
The temperature of middle material is down to 30 ~ 40 DEG C；
(5) filter, that is, obtain aqueous woodware paint resin dispersion liquid.
Embodiment 4：
The preparation method of aqueous double-component floor paint resin dispersion liquid, comprises the following steps：
(1) it is 15 according to volume ratio by diethylene glycol dimethyl ether and industrial naptha：In 0.5 addition reactor, 100 ~ 120 are warming up to
℃；
(2) by methacrylic acid ester, styrene, acrylic acid first butyl ester, acrylic acid, sodium sulfite, diatomite, pigment according to
Volume ratio is 22：9：11：2：7：2：5 are well mixed, then it is progressively added drop-wise in reactor, and time for adding is 3 ~ 5h；
(3) 2 ~ 3h is incubated after completion of dropwise addition at 110 ~ 120 DEG C, the temperature in reactor is down to 90 ~ 100 DEG C；
(4) dimethylethanolamine is added, stirring is neutralized, is added after water makes reactant scatter, cooled, make reactor
The temperature of middle material is down to 30 ~ 40 DEG C；
(5) filter, that is, obtain aqueous woodware paint resin dispersion liquid.
Wherein, described solvent is that propane diols ether solvent is EGME, ethylene glycol ethyl ether, butyl glycol ether, two
The composition of one or more in EGME；The boiling range of the industrial naptha is 150 DEG C ~ 200 DEG C；Described initiator
It is the composition of one or more in di-cyclohexylperoxy di-carbonate, peroxy dicarbonate isopropyl ester, sodium sulfite.
Embodiment 5：
The preparation method of aqueous double-component floor paint resin dispersion liquid, comprises the following steps：
(1) by diethylene glycol dimethyl ether and industrial naptha（Boiling range is 150 DEG C ~ 200 DEG C）It is 10 according to volume ratio：1 adds reactor
In, it is warming up to 100 ~ 120 DEG C；
(2) by methacrylic acid ester, styrene, acrylic acid first butyl ester, acrylic acid, peroxy dicarbonate isopropyl ester, diatom
Soil, pigment are 18 according to volume ratio：5：12：4：7：2：5 are well mixed, then it are progressively added drop-wise in reactor, time for adding
It is 3 ~ 5h；
(3) 2 ~ 3h is incubated after completion of dropwise addition at 110 ~ 120 DEG C, the temperature in reactor is down to 90 ~ 100 DEG C；
(4) dimethylethanolamine is added, stirring is neutralized, is added after water makes reactant scatter, cooled, make reactor
The temperature of middle material is down to 30 ~ 40 DEG C；
(5) filter, that is, obtain aqueous woodware paint resin dispersion liquid.
Claims (8)
1. a kind of aqueous double-component floor paint resin dispersion liquid, it is characterised in that it is by the group including following volume parts
What part prepared：
Methacrylic acid 15 ~ 25 parts of ester
5 ~ 10 parts of styrene
10 ~ 15 parts of acrylic acid first butyl ester
2 ~ 5 parts of acrylic acid
3 ~ 8 parts of initiator
5 ~ 10 parts of solvent
0.5 ~ 3 part of industrial naptha
2 ~ 5 parts of diatomite
1 ~ 5 part of pigment.
2. aqueous double-component floor paint dispersion liquid according to claim 1, it is characterised in that described initiator was
Aoxidize the composition of one or more in two dicyclohexyl carbonates, peroxy dicarbonate isopropyl ester, sodium sulfite.
3. aqueous double-component floor paint resin dispersion liquid according to claim 1, it is characterised in that described solvent
For：EGME, ethylene glycol ethyl ether, butyl glycol ether, the composition of one or more in diethylene glycol dimethyl ether.
4. aqueous double-component floor paint resin dispersion liquid according to claim 1, it is characterised in that the industrial naptha
Boiling range be 150 DEG C ~ 200 DEG C.
5. the preparation method of aqueous double-component floor paint resin dispersion liquid described in claim 1 ~ 4, it is characterised in that including such as
Lower step：
(1) it is according to volume ratio by solvent and industrial naptha（15~25）：（0.5~3）Add in reactor, be warming up to 100 ~ 120
℃；
(2) by methacrylic acid ester, styrene, acrylic acid first butyl ester, acrylic acid, initiator, diatomite, pigment according to body
Accumulating ratio is（15~25）：（5~10）：（10~15）：（2~5）：（5~8）：（2~5）：（1~5）It is well mixed, then it is progressively added drop-wise to
In reactor, time for adding is 3 ~ 5h；
(3) 2 ~ 3h is incubated after completion of dropwise addition at 110 ~ 120 DEG C, the temperature in reactor is down to 90 ~ 100 DEG C；
(4) dimethylethanolamine is added, stirring is neutralized, is added after water makes reactant scatter, cooled, make reactor
The temperature of middle material is down to 30 ~ 40 DEG C；
(5) filter, that is, obtain aqueous woodware paint resin dispersion liquid.
6. the preparation method of aqueous double-component floor paint resin dispersion liquid according to claim 5, it is characterised in that institute
The solvent stated is that propane diols ether solvent is EGME, ethylene glycol ethyl ether, butyl glycol ether, in diethylene glycol dimethyl ether one
Plant or several compositions；The boiling range of the industrial naptha is 150 DEG C ~ 200 DEG C；Described initiator is peroxy dicarbonate two
The composition of one or more in cyclohexyl, peroxy dicarbonate isopropyl ester, sodium sulfite.
7. what the preparation method of the aqueous double-component floor paint resin dispersion liquid described in claim 5,6 was prepared is aqueous double
Component floor paint resin dispersion liquid.
8. the aqueous double-component floor paint resin dispersion liquid described in claim 7 in aqueous double-component floor paint is prepared should
With.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710080876.5A CN106832108A (en) | 2017-02-15 | 2017-02-15 | A kind of aqueous double-component floor paint resin dispersion liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710080876.5A CN106832108A (en) | 2017-02-15 | 2017-02-15 | A kind of aqueous double-component floor paint resin dispersion liquid and preparation method thereof |
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| CN106832108A true CN106832108A (en) | 2017-06-13 |
Family
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| CN201710080876.5A Pending CN106832108A (en) | 2017-02-15 | 2017-02-15 | A kind of aqueous double-component floor paint resin dispersion liquid and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3320196A (en) * | 1965-08-13 | 1967-05-16 | Johnson & Son Inc S C | Coating composition comprising a terpolymer, an alkali soluble resin, and a zirconyl-fugitive ligand compound |
| US6476108B1 (en) * | 1999-04-22 | 2002-11-05 | Jsr Corporation | Aqueous coating composition |
| CN101457005A (en) * | 2008-12-25 | 2009-06-17 | 浙江环达漆业集团有限公司 | Method for preparing hydroxyl acrylic acid water dispersoid |
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Application publication date: 20170613 |