CN106883706B - 一种超低voc水性金属效果塑胶漆及其制备方法 - Google Patents
一种超低voc水性金属效果塑胶漆及其制备方法 Download PDFInfo
- Publication number
- CN106883706B CN106883706B CN201710157245.9A CN201710157245A CN106883706B CN 106883706 B CN106883706 B CN 106883706B CN 201710157245 A CN201710157245 A CN 201710157245A CN 106883706 B CN106883706 B CN 106883706B
- Authority
- CN
- China
- Prior art keywords
- water
- metal effect
- based metal
- zero voc
- plastic paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 70
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 39
- 239000002184 metal Substances 0.000 title claims abstract description 39
- 230000000694 effects Effects 0.000 title claims abstract description 35
- 239000003973 paint Substances 0.000 title claims abstract description 34
- 239000004033 plastic Substances 0.000 title claims abstract description 34
- 229920003023 plastic Polymers 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000012855 volatile organic compound Substances 0.000 claims abstract description 50
- 239000008367 deionised water Substances 0.000 claims abstract description 19
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 19
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 18
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000839 emulsion Substances 0.000 claims abstract description 18
- 239000000049 pigment Substances 0.000 claims abstract description 18
- 239000002562 thickening agent Substances 0.000 claims abstract description 15
- 150000002148 esters Chemical class 0.000 claims abstract description 12
- 150000007530 organic bases Chemical class 0.000 claims abstract description 12
- 239000000080 wetting agent Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims description 19
- 238000003756 stirring Methods 0.000 claims description 19
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- 239000006210 lotion Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004568 cement Substances 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- JCTXKRPTIMZBJT-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,3-diol Chemical compound CC(C)C(O)C(C)(C)CO JCTXKRPTIMZBJT-UHFFFAOYSA-N 0.000 claims description 2
- PESZCXUNMKAYME-UHFFFAOYSA-N Citroflex A-4 Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)C(C(C)=O)C(=O)OCCCC PESZCXUNMKAYME-UHFFFAOYSA-N 0.000 claims description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-O N-dimethylethanolamine Chemical compound C[NH+](C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-O 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical class CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 1
- 230000008961 swelling Effects 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 6
- 230000001070 adhesive effect Effects 0.000 abstract description 6
- 238000005034 decoration Methods 0.000 abstract description 3
- 239000000428 dust Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000007790 scraping Methods 0.000 description 2
- OMVSWZDEEGIJJI-UHFFFAOYSA-N 2,2,4-Trimethyl-1,3-pentadienol diisobutyrate Chemical compound CC(C)C(=O)OC(C(C)C)C(C)(C)COC(=O)C(C)C OMVSWZDEEGIJJI-UHFFFAOYSA-N 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 210000004556 brain Anatomy 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004710 electron pair approximation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 235000013618 yogurt Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/38—Paints containing free metal not provided for above in groups C09D5/00 - C09D5/36
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
一种超低VOC水性金属效果塑胶漆，其由下列重量百分比含量的原料混合而成：全固型水性铝颜料6‑12%、去离子水30‑35%、水性乳液47.6%‑58.5%、增稠剂1.6‑2%、有机碱0.4‑0.5%、重酯2.5‑3%、润湿剂0.4%‑0.5%；其中，所述全固型水性铝颜料的挥发性有机化合物含量低于1000ppm。本发明还公开超低VOC水性金属效果塑胶漆的制备方法。本发明制备的超低VOC水性金属效果塑胶漆的VOC含量接近零，对环境非常友好。金属感高，遮盖力强，附着力好。可用于汽车饰配、摩托车、家用电器、电脑、电动车、吸尘器、手机、电动工具、玩具等。
Description
技术领域
本发明涉及一种水性金属效果塑胶漆，尤其涉及是一种超低VOC水性金属效果塑胶漆及其的制备方法。
背景技术
挥发性有机化合物(VOC)，对人体健康有巨大影响，对环境也有巨大的影响。在人们环保意识日益增强的今天,无毒、无味和低VOC甚至“零VOC”的环保型涂料越来越受欢迎.低VOC涂料是指VOC含量(质量浓度)低于30g/L的涂料产品；“零VOC”涂料则是VOC含量低于10g/L的涂料(根据美国VOC测试标准EPA Methods 24)。目前水性金属效果塑胶漆都有一定量的VOC，主要来源是金属颜料中带有的有机溶剂，如异丙醇(IPA),乙二醇丁醚(EB),丙二醇甲醚(PM)；添加的成膜助剂，如醇酯-12，乙二醇丁醚(EB)；矿物油类消泡剂和缔合型增稠剂等；乳液中的残留单体等。
如何使得水性金属效果塑胶漆的VOC含量降到极低，为社会提供一种环保安全的水性金属效果塑胶漆事业界亟待解决的问题。
发明内容
本发明为了解决现有水性金属效果塑胶漆的VOC含量较高的技术问题，提供一种VOC含量接近零，对环境非常友好，金属感高，遮盖力强，附着力好的超低VOC水性金属效果塑胶漆及其制备方法。
本发明提供的一种超低VOC水性金属效果塑胶漆，其由下列重量百分比含量的原料混合而成：
全固型水性铝颜料6-12％、去离子水30-35％、水性乳液47.6％-58.5％、增稠剂1.6-2％、有机碱0.4-0.5％、重酯2.5-3％、润湿剂0.4％-0.5％；
其中，所述全固型水性铝颜料的挥发性有机化合物(VOC)含量低于1000ppm。
本发明还提供了超低VOC水性金属效果塑胶漆的制备方法，其制备步骤如下：
步骤1：根据制备所述超低VOC水性金属效果塑胶漆的配比，称量所述的全固型水性铝颜料、去离子水、水性乳液、增稠剂，有机碱、重酯、润湿剂；
步骤2：制备A液
将所述去离子水倒入搅拌机，以每分钟200转的转速搅拌，再将所述全固型水性铝颜料缓慢加入正在搅拌的去离子水中，全固型水性铝颜料与去离子水按1：1.5配制，继续搅拌10分钟，成均匀的银色浆液，制得A液；
步骤3：制备B液
将所述的增稠剂加入到步骤1中剩余的去离子水中，再加入所述的有机碱，搅拌机搅拌成透明的膏体，转速为每分钟200转；搅拌所述的水性乳液，然后再将所述透明膏状体加入正在搅拌中的水性乳液中，继续搅拌10分钟，制得B液；
步骤4：将所述的A液与B液进行混合，并边搅拌边把所述的重酯和润湿剂加入混合料中，搅拌机转速为每分钟200转，继续搅拌10分钟，制得所述的超低VOC水性金属效果塑胶漆。
与现有技术相比，本发明制备的超低VOC水性金属效果塑胶漆的VOC含量接近零，对环境非常友好。金属感高，遮盖力强，附着力好。可用于汽车饰配、摩托车、家用电器、电脑、电动车、吸尘器、手机、电动工具、玩具等。
具体实施方式
以下结合实施例对本发明进行进一步的说明。
本发明提供一种超低VOC水性金属效果塑胶漆，其由下列重量百分比含量的原料混合而成：
全固型水性铝颜料6-12％、去离子水30-35％、水性乳液47.6％-58.5％、增稠剂1.6-2％、有机碱0.4-0.5％、重酯2.5-3％、润湿剂0.4％-0.5％；
所述全固型水性铝颜料是固体形态的水性铝颜料，有相关专利文献公开。用真空加热除去了有机溶剂，即挥发性有机化合物(VOC)含量低于1000ppm。水性乳液是水性丙烯酸乳液或经过改性的水性丙烯酸乳液，其单体残余量低1000ppm。增稠剂是非缔合型的碱溶胀型的增稠剂。有机碱为N,N-二甲基乙醇胺(DMEA)或2一氨基一2一甲基一1一丙醇(AMP-95)。重酯为乙酰柠檬酸三丁酯(ATBC)或者2,2,4-三甲基-1,3-戊二醇双异丁酸酯(TXIB)的一种。润湿剂为聚醚改性有机硅。
根据需要，可以采用不同的原料配比制备超低VOC水性金属效果塑胶漆，如下表给出的1、2、3三种实施例的配方：
本发明提供的超低VOC水性金属效果塑胶漆的制备方法，其制备步骤如下：
步骤1：根据制备所述的超低VOC水性金属效果塑胶漆的配比(阅配方表)，称量所述的全固型水性铝颜料、去离子水、水性乳液、增稠剂，有机碱、重酯、润湿剂；
步骤2：制备A液
将所述去离子水倒入搅拌机，以每分钟200转的转速搅拌，再将所述全固型水性铝颜料缓慢加入正在搅拌的去离子水中，全固型水性铝颜料与去离子水按1：1.5配制，继续搅拌10分钟，成均匀的银色浆液，制得A液；
步骤3：制备B液
将所述的增稠剂加入到步骤1中剩余的去离子水中，再加入所述的有机碱，搅拌机搅拌成透明的膏体，转速为每分钟200转；搅拌所述的水性乳液，然后再将所述透明膏状体加入正在搅拌中的水性乳液中，继续搅拌10分钟，制得B液；
步骤4：将所述的A液与B液进行混合，并边搅拌边把所述的重酯和润湿剂加入混合料中，搅拌机转速为每分钟200转，继续搅拌10分钟，制得所述的超低VOC水性金属效果塑胶漆。
对根据所述1、2、3三种实施例的配方制得的超低VOC水性金属效果塑胶漆中VOC含量进行测试，测试结果如下：
将超低VOC水性金属效果塑胶漆用线棒在标准遮盖力测试卡纸(BGD 1103-OPACITY-DISPLAY)上刮板，并在70℃烘箱中烘烤30分钟。用X-Rite RM200QC测得的Lab值如下表所示。
| 实施例1 | 实施例2 | 实施例3 | |
| L | 51.8 | 52.5 | 55.3 |
| a | 0.2 | -0.6 | -0.3 |
| b | -3.8 | -3.9 | -4.0 |
将超低VOC水性金属效果塑胶漆用线棒在标准遮盖力测试卡纸(BGD 1103-OPACITY-DISPLAY)上刮板，在70℃烘箱中烘烤30分钟。用不同线棒所刮的板遮盖力如下表所示
将超低VOC水性金属效果塑胶漆干喷在ABS塑料板上，使其刚好达到全遮盖，在70℃烘箱中烘烤30分钟。用Scotch 3M600高级透明百格测试胶带测试附着力。
| 实施例A | 实施例B | 实施例C | |
| 附着力 | 不掉银 | 掉银量极少 | 掉银量极少 |
本发明制备的超低VOC水性金属效果塑胶漆的VOC含量接近零，对环境非常友好。金属感高，遮盖力强，附着力好。可用于汽车饰配、摩托车、家用电器、电脑、电动车、吸尘器、手机、电动工具、玩具等。
以上结合实施方式对本发明进行了具体描述，但是本技术领域内的技术人员可以对这些实施方式做出多种变更或变化，这些变更和变化应落入本发明保护的范围之内。
Claims (6)
1.一种超低VOC水性金属效果塑胶漆，其特征在于，其由下列重量百分
比含量的原料混合而成：
全固型水性铝颜料 6-12%、去离子水30-35%、水性乳液 47.6%-58.5%、增稠剂1.6-2%、
有机碱 0.4-0.5% 、重酯 2.5-3%、润湿剂 0.4%-0.5%；
其中，所述全固型水性铝颜料的挥发性有机化合物含量低于1000ppm；
所述的重酯为乙酰柠檬酸三丁酯或者2,2,4-三甲基-1,3-戊二醇双异丁酸酯的一种。
2.如权利要求1所述的超低VOC水性金属效果塑胶漆，其特征在于，所述的水性乳液是水性丙烯酸乳液或经过改性的水性丙烯酸乳液，其单体残余量低于1000ppm。
3.如权利要求1所述的超低VOC水性金属效果塑胶漆，其特征在于，所述的增稠剂是非缔合型的碱溶胀型的增稠剂。
4.如权利要求1所述的超低VOC水性金属效果塑胶漆，其特征在于，所述的有机碱为N,N-二甲基乙醇胺或2一氨基一2一甲基一1一丙醇。
5.如权利要求1所述的超低VOC水性金属效果塑胶漆，其特征在于，所述的润湿剂为聚醚改性有机硅。
6.一种如权利要求1所述的超低VOC水性金属效果塑胶漆的制备方法，其制备步骤如下：
步骤1： 根据所述超低VOC水性金属效果塑胶漆的配比，称量所述的全固型水性铝颜料、去离子水、水性乳液、增稠剂，有机碱、重酯、润湿剂；
步骤2：制备A液
将所述去离子水倒入搅拌机，以每分钟200转的转速搅拌，再将所述全固型水性铝颜料缓慢加入正在搅拌的去离子水中，全固型水性铝颜料与去离子水按1 ：1.5配制，继续搅拌10分钟，成均匀的银色浆液，制得A液；
步骤3：制备B液
将所述的增稠剂加入到步骤1中剩余的去离子水中，再加入所述的有机碱，搅拌机搅拌成透明的膏体，转速为每分钟200转；搅拌所述的水性乳液，然后再将所述透明膏状体加入正在搅拌中的水性乳液中，继续搅拌10分钟，制得B液；
步骤4：将所述的A液与B液进行混合，并边搅拌边把所述的重酯和润湿剂加入混合料中，搅拌机转速为每分钟200转，继续搅拌10分钟，制得所述的超低VOC水性金属效果塑胶漆。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710157245.9A CN106883706B (zh) | 2017-03-16 | 2017-03-16 | 一种超低voc水性金属效果塑胶漆及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710157245.9A CN106883706B (zh) | 2017-03-16 | 2017-03-16 | 一种超低voc水性金属效果塑胶漆及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106883706A CN106883706A (zh) | 2017-06-23 |
| CN106883706B true CN106883706B (zh) | 2019-04-09 |
Family
ID=59181554
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710157245.9A Active CN106883706B (zh) | 2017-03-16 | 2017-03-16 | 一种超低voc水性金属效果塑胶漆及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106883706B (zh) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109796808B (zh) * | 2019-03-04 | 2022-01-28 | 上海秉印玻璃科技有限公司 | 一种水性油墨及其制备方法 |
| CN110204964A (zh) * | 2019-05-07 | 2019-09-06 | 深圳市小为新材料有限公司 | 一种乳胶专用银色色浆及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1807532A (zh) * | 2006-02-15 | 2006-07-26 | 长春赛纳纳米漆有限公司 | 水性纳米铝塑漆 |
| CN102558991A (zh) * | 2010-12-24 | 2012-07-11 | 管静 | 一种纳米铝塑漆 |
| CN105602295A (zh) * | 2015-12-17 | 2016-05-25 | 徐昶 | 固型颜料组合物及其制备方法 |
-
2017
- 2017-03-16 CN CN201710157245.9A patent/CN106883706B/zh active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1807532A (zh) * | 2006-02-15 | 2006-07-26 | 长春赛纳纳米漆有限公司 | 水性纳米铝塑漆 |
| CN102558991A (zh) * | 2010-12-24 | 2012-07-11 | 管静 | 一种纳米铝塑漆 |
| CN105602295A (zh) * | 2015-12-17 | 2016-05-25 | 徐昶 | 固型颜料组合物及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106883706A (zh) | 2017-06-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102618126B (zh) | 一种硝基透明底漆及其应用 | |
| CN102020905B (zh) | 一种单组份水性哑光清漆及其制备方法 | |
| CN102002292A (zh) | 一种双组份水性木器哑光白面漆 | |
| CN105505148B (zh) | 一种水性双组份聚氨酯改性醇酸木器清漆的制备方法 | |
| CN102220082A (zh) | 一种双组分低voc油性聚氨酯底漆 | |
| CN102226051B (zh) | 一种用于水性木器涂装的格丽斯擦色剂及其制备方法 | |
| CN102492359A (zh) | 一种装饰装修用油性聚氨酯透明底漆及其制备方法 | |
| CN104946121B (zh) | 一种pu哑光清面漆及其制备方法 | |
| CN107083138A (zh) | 一种基于耐酒浸泡的玻璃酒瓶基材用水性丙烯酸氨基涂料 | |
| CN106883706B (zh) | 一种超低voc水性金属效果塑胶漆及其制备方法 | |
| CN114163887A (zh) | 一种环保型单组份地坪漆及其制备方法 | |
| CN102732113B (zh) | 一种轻防腐乳胶漆 | |
| CN105524548A (zh) | 一种水性环保高温涂料及其制备方法 | |
| CN105713132A (zh) | 一种高硬度水性木器漆及其制备方法 | |
| CN101270254B (zh) | 水性改性丙烯酸双组分塑胶涂料及其制备方法 | |
| CN113801549A (zh) | 一种环境友好型水性醇酸树脂涂料及制备方法 | |
| CN109294421A (zh) | 一种保温杯专用耐污手感水漆及其制备方法 | |
| CN104449333B (zh) | 一种高透明度、高丰满度的溶剂型哑光木器漆及其制备方法 | |
| CN103756471A (zh) | 水性半光清面漆 | |
| CN109988445A (zh) | 一种去水去污去渍的超级水性涂料 | |
| CN105131763A (zh) | 一种木制品家具用水性漆及其制备方法 | |
| CN108587274A (zh) | 一种环保水性漆及其制备方法 | |
| CN108707410A (zh) | 家具用漆 | |
| CN105219246B (zh) | 一种水性暖木底漆及其制备方法 | |
| CN104861772B (zh) | 水性环氧树脂基连结料、水性油墨及其制法和应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Ultralow VOC (Volatile Organic Compound) plastic paint with waterborne metal effect and preparation method thereof Effective date of registration: 20191122 Granted publication date: 20190409 Pledgee: Shenzhen SME financing Company limited by guarantee Pledgor: SHENZHEN SHINEMAX ADVANCED MATERIALS TECHNOLOGY CO.,LTD. Registration number: Y2019990000574 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20190409 Pledgee: Shenzhen SME financing Company limited by guarantee Pledgor: SHENZHEN SHINEMAX ADVANCED MATERIALS TECHNOLOGY CO.,LTD. Registration number: Y2019990000574 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right |