CN106948176A - A kind of silicon nitride fiber sizing agent and preparation method thereof - Google Patents
A kind of silicon nitride fiber sizing agent and preparation method thereof Download PDFInfo
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- CN106948176A CN106948176A CN201710182433.7A CN201710182433A CN106948176A CN 106948176 A CN106948176 A CN 106948176A CN 201710182433 A CN201710182433 A CN 201710182433A CN 106948176 A CN106948176 A CN 106948176A
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- sizing agent
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 37
- 239000000835 fiber Substances 0.000 title claims abstract description 37
- 238000004513 sizing Methods 0.000 title claims abstract description 36
- 229910052581 Si3N4 Inorganic materials 0.000 title claims abstract description 30
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000003822 epoxy resin Substances 0.000 claims abstract description 15
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 15
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 8
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 8
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 8
- 239000000314 lubricant Substances 0.000 claims abstract description 7
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 6
- 239000002002 slurry Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 7
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 238000005520 cutting process Methods 0.000 claims description 5
- 238000004945 emulsification Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims description 3
- 229940070765 laurate Drugs 0.000 claims description 3
- 229940106691 bisphenol a Drugs 0.000 claims 1
- 239000002736 nonionic surfactant Substances 0.000 claims 1
- 241000108463 Hygrophila <snail> Species 0.000 abstract description 6
- 229920000642 polymer Polymers 0.000 abstract description 5
- 230000002708 enhancing effect Effects 0.000 abstract description 4
- 239000011159 matrix material Substances 0.000 abstract description 4
- 239000005416 organic matter Substances 0.000 abstract description 2
- 230000006641 stabilisation Effects 0.000 abstract description 2
- 238000011105 stabilization Methods 0.000 abstract description 2
- 230000010148 water-pollination Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 4
- 238000009955 starching Methods 0.000 description 4
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- 239000004917 carbon fiber Substances 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- -1 alkyl phenol Chemical compound 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 229920001558 organosilicon polymer Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/55—Epoxy resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention proposes a kind of silicon nitride fiber sizing agent, includes by weight：5 15 parts of main slurry；15 parts of emulsifying agent；0.1 1 parts of lubricant；80 95 parts of deionized water.On the one hand hydrophily is improved using epoxy resin in the present invention, the emulsion for the stabilization for being dissolved in water is formed；On the other hand diglycidyl ether is added, the polymer of formation improves the interface characteristics of sizing agent, the external force that matrix is born passes to enhancing phase, play the function served as bridge between matrix and enhancing phase, the intensity and pliability of synnema are improved, can also increase its adhesion prevents that fiber surface from producing lousiness and fracture of wire phenomenon.The sizing agent adhesion strength is high, and overall performance is stable, without any volatile organic matter, is conducive to the protection of environment.
Description
Technical field
The present invention relates to a kind of silicon nitride fiber sizing agent and preparation method thereof.
Background technology
Silicon nitride fiber is wide because of its superior performance in the performance such as mechanical property, heat endurance, resistance to oxidation, corrosion-resistant
It is general to be applied to the fields such as petrochemical industry, automobile engine, electron electric power, Aero-Space and nuclear industry.With by organosilicon polymer
Prepare silicon carbide fibre similar, silicon nitride fiber can also be prepared using the converting method of preceramic polymer, i.e., by poly- silicon nitrogen
The polymer such as alkane, polycarbosilazanes are constituted through synthesis, spinning, cure treatment and the step preparation section of high temperature sintering 4.
Compared to developed countries such as the U.S., Japan, France, exploitation of the China to silicon nitride fiber is started late.In fiber
Commercial process in be very easy to produce synnema and rub, so as to cause the generation of a large amount of lousiness, had a strong impact on fibre
Being smoothed out for continuous production is tieed up, so starching processing must be carried out to silicon nitride fiber surface.Starching processing can be simple
Ground is understood as coating layer protecting film on silicon nitride fiber surface, and the main function of this tunic is：(1) moisture in air is avoided
Or pollution of other impurity to silicon nitride fiber surface；(2) make silicon nitride fiber boundling, improve its processing performance；(3) nitrogen is reduced
The interfibrous friction of SiClx, reduction lousiness and fracture of wire phenomenon, (4) improve the intensity of silicon nitride fiber, improve the quality of product.
In the production of country variant silicon nitride fiber, the technique of starching is similar, but the Ju Ti Pei Fang of sizing agent belongs to
Top trade secret, it is difficult to the formula of sizing agent and relevant information of offshore company are found, and both at home and abroad on carbon fiber sizing agent
Document it is but relatively many.It can make carbon fiber that there is pliability as Japanese this grease of bamboo company develops one kind, and it is fine to improve carbon
The sizing agent of wearability is tieed up, it can effectively suppress the generation of filoplume phenomenon, control the fracture of synnema；Zhang Xiping etc. is in epoxy
Serial emulsifying agent of alkyl phenol etc. is added in resin and is configured to emulsion pasting agent, as a result shows that the interlayer of material after being handled through starching is cut
Shearing stress substantially increases；Li Yang etc. have developed the sizing agent of the epoxy resin that is modified using oleamide as main component；Yu Mu
Fire etc. reports a kind of epoxy resin sizing agent of carbon nano-tube modification；Zhang Zhi is modest etc., and to develop a kind of Epoxy/Nano SiO2 miscellaneous
Change sizing agent.
Compared with carbon fiber, silicon nitride fiber diameter prepared by the converting method of preceramic polymer is bigger, for fiber
The gathering of synnema, the arrangement difficulty of lousiness are also bigger, therefore requirement of the silicon nitride fiber to sizing agent is then higher tightened up.
The content of the invention
In order to overcome the deficiencies in the prior art, the present invention proposes a kind of environment-friendly silicon nitride fiber sizing agent, should
Sizing agent adhesion strength is high, and overall performance is stable.On the one hand hydrophily is improved using epoxy resin in the present invention, formation is dissolved in water
Stabilization emulsion；On the other hand diglycidyl ether is added, the polymer of formation improves the interface characteristics of sizing agent, and matrix is held
The external force received passes to enhancing phase, plays the function served as bridge between matrix and enhancing phase, improves the intensity and pliability of synnema,
Its adhesion, which can be increased, prevents that fiber surface from producing lousiness and fracture of wire phenomenon.
The technical proposal of the invention is realized in this way：
A kind of silicon nitride fiber sizing agent, includes by weight：5-15 parts of main slurry；1-5 parts of emulsifying agent；Lubricant
0.1-1 parts；80-95 parts of deionized water.
Preferably, described main slurry is the mixture of epoxy resin and diglycidyl ether, and its weight ratio is 3:1~1:
1。
Preferably, described epoxy resin is bisphenol A type epoxy resin E51.
Preferably, described emulsifying agent is nonionic surface active agent：Tween-40.
Preferably, described lubricant is polyethylene glycol laurate.
A kind of preparation method of silicon nitride fiber sizing agent, comprises the following steps：
(1) by the epoxy resin of 5-15 parts by weight and diglycidyl ether by weight 3:1~1:1 mixing, at 60 DEG C
5min is stirred with 800r/min, it is well mixed and system A is made；
(2) 1-5 parts by weight Emulsifier and 0.1-1 parts by weight lubricants are added in said mixture system A, 60 DEG C with
System B is made in 1000r/min stirrings more than 30min；
(3) 40 DEG C with the emulsification of 5000r/min high rotating speed cutting under toward being slowly added to 80- with separatory funnel in system B
The deionized water of 95 parts by weight, with the increase of rate of water added, system phase inversion adds water in 60min and continued after finishing with 800r/min
20min is stirred until forming uniform and stable emulsion, silicon nitride fiber sizing agent is obtained after cooling.
What the present invention was produced has the beneficial effect that：(1) present invention is a kind of aqueous epoxy emulsion type silicon nitride fiber sizing agent,
Its emulsifying process is simple, and raw material is easy to get and low cost.(2) sizing agent is conducive to environment without any volatile organic matter
Protection.(3) sizing agent can effectively improve synnema intensity, reduce fiber surface lousiness and fracture of wire, with convergence it is good and
The advantages of pliability is good.
Embodiment
Technical scheme is clearly and completely described below in conjunction with the embodiment of the present invention, it is clear that retouched
The embodiment stated is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, sheet
The every other embodiment that field those of ordinary skill is obtained under the premise of creative work is not made, belongs to the present invention
The scope of protection.
Embodiment 1
The preparation method of sizing agent comprises the following steps in the present embodiment：
(1) by 5 parts of bisphenol A type epoxy resin E51 and diglycidyl ether by weight 3:1 mixing, at 60 DEG C with
800r/min stirs 5min, is well mixed it and system A is made；
(2) in said mixture system A add 1 part of Tween-40 and 0.1 part of polyethylene glycol laurate, 60 DEG C with
System B is made in 1000r/min stirrings more than 30min；
(3) 40 DEG C with the emulsification of 5000r/min high rotating speed cutting under toward being slowly added to 95 parts with separatory funnel in system B
Deionized water, with the increase of rate of water added, system phase inversion adds water in 60min and continues to stir 20min with 800r/min after finishing
Until forming uniform and stable emulsion, silicon nitride fiber sizing agent is obtained after cooling.
Embodiment 2
The preparation method of sizing agent comprises the following steps in the present embodiment：
(1) by 10 parts of epoxy resin E51 and diglycidyl ether by weight 2:1 mixing, with 800r/ at 60 DEG C
Min stirs 5min, is well mixed it and system A is made；
(2) in said mixture system A add 3 parts of Tween-40 and 0.5 part of polyethylene glycol laurates, 60 DEG C with
System B is made in 1000r/min stirrings more than 30min；
(3) 40 DEG C with the emulsification of 5000r/min high rotating speed cutting under toward being slowly added to 86.5 with separatory funnel in system B
The deionized water of part, with the increase of rate of water added, system phase inversion is added water in 60min and continues to be stirred with 800r/min after finishing
20min is until the uniform and stable emulsion of formation, obtains silicon nitride fiber sizing agent after cooling.
Embodiment 3
The preparation method of sizing agent comprises the following steps in the present embodiment：
(1) by 15 parts of epoxy resin E51 and diglycidyl ether by weight 1:1 mixing, with 800r/ at 60 DEG C
Min stirs 5min, is well mixed it and system A is made；
(2) in said mixture system A add 5 parts of Tween-40 and 1 part of polyethylene glycol laurates, 60 DEG C with
System B is made in 1000r/min stirrings more than 30min；
(3) 40 DEG C with the emulsification of 5000r/min high rotating speed cutting under toward being slowly added to 80 parts with separatory funnel in system B
Deionized water, with the increase of rate of water added, system phase inversion adds water in 60min and continues to stir 20min with 800r/min after finishing
Until forming uniform and stable emulsion, silicon nitride fiber sizing agent is obtained after cooling.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention, all essences in the present invention
God is with principle, and any modifications, equivalent substitutions and improvements made etc. should be included within the scope of the present invention.
Claims (6)
1. a kind of silicon nitride fiber sizing agent, it is characterised in that include by weight：5-15 parts of main slurry；Emulsifying agent 1-5
Part；0.1-1 parts of lubricant；80-95 parts of deionized water.
2. a kind of silicon nitride fiber sizing agent as claimed in claim 1, it is characterised in that described main slurry is epoxy resin
With the mixture of diglycidyl ether, its weight ratio is 3:1~1:1.
3. a kind of silicon nitride fiber sizing agent as claimed in claim 2, it is characterised in that described epoxy resin is bisphenol-A
Type epoxy resin E51.
4. a kind of silicon nitride fiber sizing agent as claimed in claim 1, it is characterised in that described emulsifying agent is nonionic
Surfactant：Tween-40.
5. a kind of silicon nitride fiber sizing agent as claimed in claim 1, it is characterised in that described lubricant is polyethylene glycol
Laurate.
6. a kind of preparation method of silicon nitride fiber sizing agent, it is characterised in that comprise the following steps：
(1) by the epoxy resin of 5-15 parts by weight and diglycidyl ether by weight 3:1~1:1 mixing, at 60 DEG C with
800r/min stirs 5min, is well mixed it and system A is made；
(2) 1-5 parts by weight Emulsifier and 0.1-1 parts by weight lubricants are added in said mixture system A, 60 DEG C with
System B is made in 1000r/min stirrings more than 30min；
(3) 40 DEG C with the emulsification of 5000r/min high rotating speed cutting under weigh toward being slowly added to 80-95 with separatory funnel in system B
The deionized water of part is measured, with the increase of rate of water added, system phase inversion is added water in 60min and continues to be stirred with 800r/min after finishing
20min is until the uniform and stable emulsion of formation, obtains silicon nitride fiber sizing agent after cooling.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710182433.7A CN106948176A (en) | 2017-03-24 | 2017-03-24 | A kind of silicon nitride fiber sizing agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710182433.7A CN106948176A (en) | 2017-03-24 | 2017-03-24 | A kind of silicon nitride fiber sizing agent and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106948176A true CN106948176A (en) | 2017-07-14 |
Family
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| CN201710182433.7A Pending CN106948176A (en) | 2017-03-24 | 2017-03-24 | A kind of silicon nitride fiber sizing agent and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107620208A (en) * | 2017-09-27 | 2018-01-23 | 中国人民解放军国防科技大学 | Nitride fiber impregnating compound and coating method thereof |
| CN108755123A (en) * | 2018-05-15 | 2018-11-06 | 天津工业大学 | A kind of silicon nitride fiber surface conditioning agent and preparation method thereof |
| CN110184821A (en) * | 2019-05-05 | 2019-08-30 | 宜兴市新立织造有限公司 | A kind of alumina fibre flexible modifying agent and preparation method thereof |
| CN110305464A (en) * | 2019-07-05 | 2019-10-08 | 天津工业大学 | A kind of continuous nitride silica fibre reinforced resin base composite wire and preparation method thereof |
| CN114855458A (en) * | 2022-06-17 | 2022-08-05 | 福建立亚新材有限公司 | A kind of oil for remediating wear wave-transmitting silicon nitride fiber and preparation method thereof |
| CN115182162A (en) * | 2022-07-21 | 2022-10-14 | 武汉纺织大学 | Preparation method and application method of special sizing agent for nitride fibers |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107620208A (en) * | 2017-09-27 | 2018-01-23 | 中国人民解放军国防科技大学 | Nitride fiber impregnating compound and coating method thereof |
| CN107620208B (en) * | 2017-09-27 | 2019-07-19 | 中国人民解放军国防科技大学 | Nitride fiber impregnating compound and coating method thereof |
| CN108755123A (en) * | 2018-05-15 | 2018-11-06 | 天津工业大学 | A kind of silicon nitride fiber surface conditioning agent and preparation method thereof |
| CN110184821A (en) * | 2019-05-05 | 2019-08-30 | 宜兴市新立织造有限公司 | A kind of alumina fibre flexible modifying agent and preparation method thereof |
| CN110184821B (en) * | 2019-05-05 | 2022-02-11 | 宜兴市新立织造有限公司 | Alumina fiber flexible modifier and preparation method thereof |
| CN110305464A (en) * | 2019-07-05 | 2019-10-08 | 天津工业大学 | A kind of continuous nitride silica fibre reinforced resin base composite wire and preparation method thereof |
| CN114855458A (en) * | 2022-06-17 | 2022-08-05 | 福建立亚新材有限公司 | A kind of oil for remediating wear wave-transmitting silicon nitride fiber and preparation method thereof |
| CN115182162A (en) * | 2022-07-21 | 2022-10-14 | 武汉纺织大学 | Preparation method and application method of special sizing agent for nitride fibers |
| CN115182162B (en) * | 2022-07-21 | 2023-12-22 | 武汉纺织大学 | Preparation method and application method of a special sizing agent for nitride fibers |
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Application publication date: 20170714 |