CN106957579A - One-component acrylate paint with anti-corrosion, anti-wear performance - Google Patents
One-component acrylate paint with anti-corrosion, anti-wear performance Download PDFInfo
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- CN106957579A CN106957579A CN201710191997.7A CN201710191997A CN106957579A CN 106957579 A CN106957579 A CN 106957579A CN 201710191997 A CN201710191997 A CN 201710191997A CN 106957579 A CN106957579 A CN 106957579A
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- Prior art keywords
- corrosion
- component
- parts
- wear performance
- paint
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- 239000003973 paint Substances 0.000 title claims abstract description 56
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 title claims abstract description 42
- 238000005260 corrosion Methods 0.000 title claims abstract description 37
- 238000000576 coating method Methods 0.000 claims abstract description 43
- 239000011248 coating agent Substances 0.000 claims abstract description 27
- 239000000839 emulsion Substances 0.000 claims abstract description 26
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 125000005396 acrylic acid ester group Chemical group 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000002562 thickening agent Substances 0.000 claims abstract description 8
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 7
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 6
- 238000004132 cross linking Methods 0.000 claims description 11
- -1 acrylic ester Chemical class 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 229910000765 intermetallic Inorganic materials 0.000 claims description 4
- IBDVWXAVKPRHCU-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCOC(=O)C(C)=C IBDVWXAVKPRHCU-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical group CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 2
- 239000011258 core-shell material Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 239000004816 latex Substances 0.000 claims description 2
- 229920000126 latex Polymers 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 17
- 230000007797 corrosion Effects 0.000 abstract description 6
- 239000013530 defoamer Substances 0.000 abstract description 6
- 239000002270 dispersing agent Substances 0.000 abstract description 6
- 238000001035 drying Methods 0.000 abstract description 6
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 5
- 230000003260 anti-sepsis Effects 0.000 abstract description 5
- 239000003899 bactericide agent Substances 0.000 abstract description 5
- 239000000080 wetting agent Substances 0.000 abstract description 4
- 230000005587 bubbling Effects 0.000 abstract description 3
- 230000035699 permeability Effects 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 abstract description 3
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 241000276489 Merlangius merlangus Species 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- YEQBHMVRNHTCPJ-UHFFFAOYSA-N 2-methylprop-2-enoic acid;3-oxobutanoic acid Chemical compound CC(=C)C(O)=O.CC(=O)CC(O)=O YEQBHMVRNHTCPJ-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 150000004696 coordination complex Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000004494 ethyl ester group Chemical group 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- SGUQCKMQPFUEDZ-UHFFFAOYSA-N 6-butoxyhexyl acetate Chemical compound CCCCOCCCCCCOC(C)=O SGUQCKMQPFUEDZ-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000005739 Bordeaux mixture Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000004807 desolvation Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 239000006115 industrial coating Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/04—Polymer mixtures characterised by other features containing interpenetrating networks
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/53—Core-shell polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of one-component acrylate paint with anti-corrosion, anti-wear performance, belong to coating preparation field, it is above-mentioned that there is anti-corrosion, the one-component acrylate paint of anti-wear performance to be made up of the component of following parts by weight：Special 200 400 parts of acrylic acid ester emulsion, 1 10 parts of propane diols, 20 40 parts of titanium dioxide, blanc fixe 10 20,20 50 parts of coalescents, 5 10 parts of dispersant, 15 parts of defoamer, 0.1 1 parts of wetting agent, 0.1 1 parts of bactericide, 0.5 2 parts of multifunctional assistant, 0.1 1 parts of thickener, 0.1 1 parts of levelling agent, 0.1 1 parts of acrylic thickener.Water resistance, corrosion resistance and the wearability of the present invention is good, drying time is fast, good permeability, film not bubbling, do not fall off, can be used in 20 DEG C to 95 DEG C environment, available for the industrial antisepsis such as floor coatings, metal anti-corrosive paint, marine paint field.
Description
Technical field
It is more particularly to a kind of that there is anti-corrosion, the one-component propylene of anti-wear performance the present invention relates to a kind of acrylate paint
Acid esters coating.
Background technology
As economy is developed rapidly, the industrial coating of China obtains fast development, and floor coatings have excellent thing with it
Manage mechanical performance, electrical insulation capability, the performance such as resistance to chemical corrosion obtains everybody attention and extensive use, its consumption by
Year is continuously increased.But domestic floor coatings about 80% are solvent based coatings at present, organic solvent content is big, is producing and is making
Organic solvent is evaporate into air during, causes the more serious wasting of resources and environmental pollution, and the body and mind of influence people is good for
Health, and with great potential safety hazard.As Environmental protection increasingly enhancing and environmental protection legislation are increasingly strict, with low dirt
Contaminate, do not fire, aqueous floor coatings research the features such as excellent performance, construction safety facilitate turns into trend.
In the market in aqueous floor coatings based on water-base epoxy and water-based polyurethane double-component floor coatings, pass
The aqueous epoxy floor coating and aqueous polyurethane floor coatings of system, are to produce epoxy resin or polyurethane tree by solvent method
Fat, then by mechanical means in specific device, in the presence of emulsifying agent, be distributed in water, water-base resin is made, then with water
Property resin and solid powder slurry be mixed and made into water paint.The property of the floor coatings depends entirely on the performance of resin.By
What it is in epoxy resin and polyurethane resin is, using solvent method synthesis, then to carry out desolvation during water emulsification, therefore, is made
Water paint in solvent residual quantity will be far above acrylic acid ester emulsion polymerization process in remain (typically 100PPM with
Under) content of monomer.Needing live host and curing agent now to match somebody with somebody by a certain percentage when using now makes, and operation is cumbersome, to metering essence
Degree and Personnel Skill Levels require high, and above-mentioned coating has the advantages such as gloss is high, hardness is high, wearability is good.But, with country
Increasing to environmental protection dynamics, solvent based coating has been included in restricted product as the product of high VOC emission, and it is used
Place, usage amount will be severely limited.
Domestic market acrylate paint product is mainly used in architecture inside and outside decoration, its reason one be building coating into
The performance of membrane substance emulsion does not have self-crosslinking energy or self-crosslinking degree less demanding；Two be that the powder of building coating is generally used
Titanium dioxide, fine particle calcium carbonate, coarse whiting etc., such material is without property monomer crosslinked in promotion emulsion；Three be fine particle calcium carbonate, coarse whiting class product
In carbonate meet acidic materials easily decompose；Four be carbonate material itself hardness it is relatively low, therefore, need it is wear-resisting, anti-
Technical requirements can not be met in terms of the floor coatings and anticorrosive paint of rotten performance.
Aqueous one-component acrylic acid floor coatings product because low VOC emission, without APEO, gloss is high, have excellent weather resistance, resistance to
Good wide market hot good, water-fast and resistant to chemical etching.The related introduction of water paint is as follows in the prior art：
CN102634273A discloses a kind of acrylate mono-component waterproofing paint, it by following weight than component group
Into：Acrylic emulsion 50-70, preservative 0.02-0.04, powdered whiting 5-7, titanium dioxide 10-20, thickener 0.1-0.3, two
Butyl ester 3-6, ammonia nertralizer 0.04-0.06, cellulose 2-4, defoamer 0.01-0.03, water 6-8, inserts 1-2.The invention with
Pure acrylate emulsion addition high-quality p fillers, the one-component high polymer aqueous waterproofing paint of auxiliary agent configuration, it has good
Impermeability, cohesive force and flexibility, overall elasticity and ductility, can realize coating water-repellent paint there is 2-3mm in concrete
Width ftractures and impermeable effect.But the crosslinking degree of acrylic acid ester emulsion is relatively low in the present invention, its hardness etc. is poor.
The content of the invention
To solve the problems such as acrylate emulsion crosslinking degree is low in the prior art causes poor-performing, the present invention provides one
Planting has anti-corrosion, the one-component acrylate paint of anti-wear performance.Wherein, what prepared by the present invention has anti-corrosion, wearability
The one-component acrylate paint of energy has high rigidity, high-wearing feature and anti-corrosive properties, the advantages of setting rate is fast.
In order to solve the above technical problems, present invention offer technical scheme is as follows：
On the one hand, the present invention provides a kind of with anti-corrosion, the one-component acrylate paint of anti-wear performance, by following weight
The component of part is made：
It is preferred that, it is described that there is anti-corrosion, the one-component acrylate paint of anti-wear performance, it is made up of the component of following parts by weight：
It is preferred that, it is described that there is anti-corrosion, the one-component acrylate paint of anti-wear performance, by the component system of following parts by weight
Into：
Further, the special acrylic acid ester emulsion is by cross-linking monomer acetoacetate methacrylic acid
The acrylate core-shell latex coating that metallic compound is prepared, preferably Beijing Hua Teng Dongguang section are added in the emulsion of ethyl ester
The HYD-5816 of skill Development Co., Ltd production.
Further, the metallic compound is inorganic salts, organic salt, oxide or the hydroxide of zinc or aluminium.
The further coalescents are alcohol, alcohol ester, alcohol ethers, remaining after moisture evaporation during dried coating film
The polymer droplets that coalescents make dissolve and are fused into continuous film, and coalescents can be phenmethylol, 12 carbon in the present invention
One or more in alcohol ester, butyl glycol ether, propane diols phenylate, glycol ether, hexylene glycol monobutyl ether acetate.
The dispersant is water paint common dispersants, can be polycarboxylate sodium COATEX PE737 or PE908, gather
Acrylic acid sodium salt ECODIS 40, COATEX P30 or COATEX P50, ammonium polyacrylate salt ECODIS 80 or COATEX P90
Deng conventional water paint dispersant.
The defoamer can be polysiloxanes defoaming agents and/or silicone oil emulsion defoamer.
The wetting agent can be any in polysiloxanes, BD-3032, anion surfactant.
The bactericide is to have good compatibility on coating, on color and luster, levelability, adhesion performance without influence
Bactericide is used equally for the present invention.It is specifically as follows appointing in KLN-15B, KLN-16B, KLN-17B, KLN-19B, Bordeaux mixture
One is a kind of.
The thickener is hydroxymethyl cellulose and/or hydroxyethyl cellulose.
Further, the levelling agent is commercially available organosilicon levelling agent；
The acrylic thickener is ATX-01；
The multifunctional assistant is AMP-95.
Further, the titanium dioxide particle diameter is the mesh of 1000 mesh -3000；
The blanc fixe particle diameter is the mesh of 1000 mesh -3000.
The present invention also provides a kind of above-mentioned with anti-corrosion, the application of the one-component acrylate paint of anti-wear performance, by third
Glycol, titanium dioxide, blanc fixe, coalescents, dispersant, defoamer, wetting agent, bactericide, multifunctional assistant, thickening
Agent, levelling agent are added in skin grinder, are added special acrylic acid ester emulsion, are started mixer and be sufficiently stirred for 1~1.5h of grinding, mistake
Sieve, the coating of preparation can be used for the industrial antisepsis purposes such as floor coatings, metal anti-corrosive paint, crew quarter coating.
The one-component acrylate paint of the present invention is used as adhesive, the special acrylic acid using special acrylic acid ester emulsion
Contain AAEM in ester emulsion, self-crosslinking can occur during emulsion film forming, make macromolecule
Polymer forms inierpeneirating network structure in film forming, improves pliability, impact resistance and the resistance to ionic of polymeric membrane；Meanwhile,
By adding special powder material, with the carboxylate radical of the presence in emulsion macromolecular chain complex reaction can occur for the powder, be formed not
Be dissolved in the metal complex of water, further improve the crosslink density of coating, greatly improve the water resistance of coating, corrosion resistance and
Wearability；By two kinds of cross-linked forms, the drying setting rate of the coating prepared is improved.
The invention provides a kind of one-component acrylate paint with anti-corrosion, anti-wear performance, with following beneficial effect
Really：
1) polymer of the invention used, promoter material meet low VOC, without APEO environmental protection indexs, content of beary metal symbol
Standardization requirement；
2) present invention is acrylate one-component coating, easy construction；
3) using special acrylic acid ester emulsion, the self-crosslinking composition contained by itself, the pliability of increase film forming,
Impact resistance etc.；
4) by outside addition special powder, it is made to be reacted with the carboxylate radical in special acrylic acid ester emulsion, by being formed
Water insoluble metal complex, improve coating crosslink density, water resistance, the corrosion resistance of coating are further improved with this
And wearability；
5) the anti-corrosion that prepared by the present invention, the one-component acrylate paint drying time of anti-wear performance fast, good permeability, painting
Film not bubbling, do not fall off, can be at -20 DEG C to 95 DEG C while there is excellent chemicals-resistant aggressivity and resistance to oil stains
Used in environment, available for the industrial antisepsis such as floor coatings, metal anti-corrosive paint, marine paint field.
Embodiment
To make the technical problem to be solved in the present invention, technical scheme and advantage clearer, below in conjunction with specific implementation
Example is described in detail.
Such scheme is described further below in conjunction with specific embodiment.It should be understood that these embodiments are to be used to illustrate
The present invention and be not limited to limit the scope of the present invention.The implementation condition used in embodiment can be done according to the situation of specific product
Further adjustment, unreceipted implementation condition is usually the condition in normal experiment.
Material, reagent used etc., are commercially obtained in following embodiments.
The present invention provides a kind of with anti-corrosion, the one-component acrylate paint of anti-wear performance, and detailed process is referring to following
Embodiment.
Embodiment 1
It is a kind of that there is anti-corrosion, the one-component acrylate paint of anti-wear performance, it is made up of the component of following parts by weight：
Embodiment 2
It is a kind of that there is anti-corrosion, the one-component acrylate paint of anti-wear performance, it is made up of the component of following parts by weight：
Embodiment 3
It is a kind of that there is anti-corrosion, the one-component acrylate paint of anti-wear performance, it is made up of the component of following parts by weight：
Embodiment 4
It is a kind of that there is anti-corrosion, the one-component acrylate paint of anti-wear performance, it is made up of the component of following parts by weight：
Embodiment 5
It is a kind of that there is anti-corrosion, the one-component acrylate paint of anti-wear performance, it is made up of the component of following parts by weight：
For further illustrate the present invention prepare have anti-corrosion, the performance of the one-component acrylate paint of anti-wear performance,
Following comparative example is built by taking embodiment 3 as an example.
Comparative example 1
A kind of acrylate paint, special acrylic acid ester emulsion HYD-5816 is replaced with common commercially available acrylic emulsion, its
Remaining component and consumption are same as Example 3.
Comparative example 2
A kind of acrylate paint, removes titanium dioxide, remaining component and consumption are same as Example 3.
Comparative example 3
A kind of acrylate paint, removes blanc fixe, remaining component and consumption are same as Example 3.
The present invention also provides a kind of above-mentioned with anti-corrosion, the application of the one-component acrylate paint of anti-wear performance, by third
Glycol, titanium dioxide, blanc fixe, coalescents, dispersant, defoamer, wetting agent, bactericide, multifunctional assistant, thickening
Agent, levelling agent are added in skin grinder, are added special acrylic acid ester emulsion, are started mixer and be sufficiently stirred for 1~1.5h of grinding, mistake
Sieve, the coating of preparation can be used for the industrial antisepsis purposes such as floor coatings, metal anti-corrosive paint, marine paint.
The acrylate paint prepared to embodiment 1-5 and comparative example 1-2 is according to HG/T 3829-2006 (slim) terrace
Coating standard carries out performance detection, the results are shown in Table 1.
Table 1
As shown in Table 1, what prepared by the present invention has anti-corrosion, the one-component acrylate paint of anti-wear performance and comparative example phase
Than with solid content is high, drying time is fast, adhesive force is strong, hardness is high, acid-alkali-corrosive-resisting it is strong, while its flexility and wear-resisting
Performance is also preferable.
This is probably due on the one hand, having cross-linking monomer acetoacetate methacrylic acid in special acrylic acid ester emulsion
The presence of ethyl ester (AAEMA), can carry out ambient self-crosslinking effect, AAEMA is in polyalcohol emulsion particle shell rich in more double
Carbonyl functional group, it is easier to its self-crosslinking, makes high molecular polymer form inierpeneirating network structure in film forming, improves polymeric membrane
Pliability, impact resistance and resistance to ionic；On the other hand there is metal ion in special acrylic acid ester emulsion, itself and addition
With the carboxylate radical of the presence in acrylic acid ester emulsion macromolecular chain complex reaction occurs for titanium and barium jointly, forms water insoluble gold
Belong to complex compound, further improve the crosslink density of coating, greatly improve water resistance, corrosion resistance and the wearability of coating；It is logical
Two kinds of cross-linked forms are crossed, the drying setting rate of the coating prepared is improved.
In summary, it is water-fast the invention provides a kind of one-component acrylate paint with anti-corrosion, anti-wear performance
Property, corrosion resistance and wearability it is good, drying time is fast, good permeability, film not bubbling, do not fall off, can be in -20 DEG C to 95 DEG C rings
Used in border, available for the industrial antisepsis such as floor coatings, metal anti-corrosive paint, marine paint field.
Experiment provided above is only the preferably example of the present invention, the protection domain being not intended to limit the present invention.Should
, for those skilled in the art, can be with the premise of principle of the present invention is not departed from when pointing out
Some improvements and modifications are made, these improvements and modifications also should be regarded as protection scope of the present invention.
Claims (8)
1. a kind of have anti-corrosion, the one-component acrylic ester aquosity coating of anti-wear performance, it is characterised in that by following parts by weight
Component is made：
2. according to claim 1 have anti-corrosion, the one-component acrylate paint of anti-wear performance, it is characterised in that by
The component of following parts by weight is made：
3. according to claim 1 have anti-corrosion, the one-component acrylate paint of anti-wear performance, it is characterised in that by
The component of following parts by weight is made：
4. according to any described one-component acrylate paints with anti-corrosion, anti-wear performance of claim 1-3, its feature exists
In the special acrylic acid ester emulsion is by adding into the emulsion with cross-linking monomer AAEM
Plus the acrylate core-shell latex coating that metallic compound is prepared.
5. according to claim 4 have anti-corrosion, the one-component acrylate paint of anti-wear performance, it is characterised in that institute
It is zinc or inorganic salts, organic salt, oxide or the hydroxide of aluminium to state metallic compound.
6. according to any described one-component acrylate paints with anti-corrosion, anti-wear performance of claim 1-3, its feature exists
In the levelling agent is organosilicon levelling agent 2020；
The acrylic thickener is ATX-01；
The multifunctional assistant is AMP-95.
7. according to any described one-component acrylate paints with anti-corrosion, anti-wear performance of claim 1-3, its feature exists
In the titanium dioxide particle diameter is the mesh of 1000 mesh -3000；
The blanc fixe particle diameter is the mesh of 1000 mesh -3000.
8. having anti-corrosion, the application of the one-component acrylate paint of anti-wear performance described in claim 1 to 7 is any, it is special
Levy and be, the coating is used for floor coatings, metal anti-corrosive paint, marine paint.
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| CN108203558A (en) * | 2017-11-22 | 2018-06-26 | 宁波宣伯涂料科技有限公司 | One-component acrylic ester aquosity coating with anti-corrosion, wear-resisting property |
| CN109021738A (en) * | 2018-05-31 | 2018-12-18 | 无锡市海轮涂料有限公司 | A kind of weather-proof cross-linking aqueous acrylic acid top-coat |
| CN110713760A (en) * | 2019-11-04 | 2020-01-21 | 广州昊特建材有限公司 | Water-based acrylic floor paint and preparation method thereof |
| CN112724761A (en) * | 2020-12-29 | 2021-04-30 | 苏州大乘环保新材有限公司 | Water-based acrylic floor coating and preparation method thereof |
| CN115612366A (en) * | 2022-12-16 | 2023-01-17 | 广东天骄体育发展有限公司 | Tennis court floor with high tensile bonding strength |
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Application publication date: 20170718 |