CN106959480A - A kind of high briliancy composite reflective film - Google Patents

A kind of high briliancy composite reflective film Download PDF

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Publication number
CN106959480A
CN106959480A CN201710300104.8A CN201710300104A CN106959480A CN 106959480 A CN106959480 A CN 106959480A CN 201710300104 A CN201710300104 A CN 201710300104A CN 106959480 A CN106959480 A CN 106959480A
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China
Prior art keywords
reflective film
layer
composite reflective
briliancy
high briliancy
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CN201710300104.8A
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Chinese (zh)
Inventor
金亚东
熊斐
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Ningbo Solartron Technology Co Ltd
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Ningbo Solartron Technology Co Ltd
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Priority to CN201710300104.8A priority Critical patent/CN106959480A/en
Publication of CN106959480A publication Critical patent/CN106959480A/en
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/12Reflex reflectors
    • G02B5/126Reflex reflectors including curved refracting surface

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention relates to optical thin film, more particularly to a kind of high briliancy composite reflective film.In order to the reflectance coating briliancy for solving existing surface coated particle it is not enough the problem of, the present invention provides a kind of high briliancy composite reflective film.Described composite reflective film includes brightening structure layer, layer of polyurethane, reflective substrate successively, and described layer of polyurethane is coated on the surface of reflective substrate, and the surface of the layer of polyurethane, which makes, brightening structure layer, and described brightening structure layer has micro-prism structure.The high briliancy composite reflective film that the present invention is provided is by making brightening structure layer on layer of polyurethane surface, there is provided preferable anti-scratch performance and anti-adsorption, and the briliancy of reflectance coating is added while anti-adsorption function is reached, it is to avoid because reflectance coating briliancy caused by coated particle is lost.

Description

A kind of high briliancy composite reflective film
Technical field
The present invention relates to optical thin film, more particularly to a kind of high briliancy composite reflective film.
Background technology
Reflectance coating is applied in display backlight module, is the diaphragm for playing light compensation effect, its reflection to light Ability plays key effect to the integral brightness and visual effect of display.At present, reflector plate market due to display gradually 60 cun, the oversizes such as 80 cun are increased to, the requirement to display integral brightness and light source mildness is also stepped up, and this is to anti- Penetrate piece and propose higher requirement, therefore progressively occur in that the mode in reflector plate surface coated particle solves to go out during assembling The problems such as existing absorption shadow, but the mode of coated particle would generally make reflector plate lose a certain degree of briliancy, this causes The briliancy of large scale reflector plate becomes a subject matter.At present, the reflection film manufacturer such as toray, Japanese Supreme Being people is anti- Piece is penetrated because reflection film base material briliancy itself is higher, even if also can still keeping higher briliancy after coated particle, and it is domestic Expansion type BOPET reflector plates have certain gap in terms of base material briliancy or with Japanese producers, therefore pass through and be coated with increase The briliancy of reflector plate becomes a new developing way.
In order to improve the problem of adsorbing shadow after reflector plate assembling, domestic most of producer on reflector plate surface by applying The mode of cloth particle improves the roughness on reflectance coating surface, so as to form air barrier between reflector plate and LGP (light guide plate) Layer, it is to avoid absorption shadow, but this way would generally reduce 1-5% reflector plate briliancy after coating, ultimately result in reflection Piece briliancy performance in large-sized monitor is not enough.
Publication No. 103064139A (publication date:On April 24th, 2013) Chinese patent application disclose a kind of anti scuffing Optical reflectance coating and preparation method thereof, its core technology be by reflectance coating surface coating flexible particle and non-flexible particle, Flexible particle is adjusted simultaneously and uses big particle diameter, and non-flexible particle meets the purpose of anti-absorption simultaneously by the way of small particle, so And this mode is limited due to the material of flexible particle, its refractive index between glue is difficult to match, and most causes at last after coating Briliancy heavy losses;Publication No. 105109166A (publication date is on December 2nd, 2015) Chinese patent application discloses one Kind anti-absorption application type reflection polyester film and preparation method thereof, its core technology be in reflectance coating surface coated particle, The effect of anti-absorption is reached, this mode needs to be coated with substantial amounts of particle, to reach anti-adsorption effect, and number of particles is larger, meeting Reflector plate surface is set to occur a large amount of unrestrained transmittings so that a large amount of light cannot be introduced into visual angular region, cause briliancy to be lost.
The content of the invention
In order to the reflectance coating briliancy for solving existing surface coated particle it is not enough the problem of, the present invention provides a kind of high briliancy and answered Close reflectance coating.The high briliancy composite reflective film that the present invention is provided by layer of polyurethane surface make brightening structure layer there is provided Preferable anti-scratch performance and anti-adsorption, and add while anti-adsorption function is reached the briliancy of reflectance coating, it is to avoid Because reflectance coating briliancy caused by coated particle is lost.
In order to solve the above problems, the present invention uses following technical proposals.
The present invention provides a kind of high briliancy composite reflective film, and described composite reflective film includes brightening structure layer, gathered successively Urethane layer, reflective substrate, described layer of polyurethane are coated on the surface of reflective substrate, and the surface of the layer of polyurethane is provided with increasing Bright structure sheaf, described brightening structure layer has micro-prism structure.Further, the surface of the layer of polyurethane, which makes, blast Structure sheaf.
The reflective substrate is also referred to as reflective substrate layer, substrate layer or reflection basement membrane.The reflective substrate can select existing Some reflectance coatings.Polyurethane precoated shet is coated with existing reflectance coating surface.The one side coating of reflective substrate has polyurethane precoating Layer.Polyurethane precoated shet is also referred to as layer of polyurethane.The effect of polyurethane precoated shet is increase no-solvent type ultraviolet-curing resin glue The tack of water.The thickness of polyurethane precoated shet is 0.1-3 μm.
Further, in described high briliancy composite reflective film, described micro-prism structure is by some microprism bar groups Into.
Further, described microprism bar is arranged in parallel.
Further, described microprism bar covers layer of polyurethane.
Further, in described high briliancy composite reflective film, the cross section of described microprism bar is triangle.Enter One step, the drift angle of the triangle is fillet.The radius of the fillet is also referred to as corner radii.
Further, in described high briliancy composite reflective film, the height of described microprism bar (abbreviation microprism) It it is 20-50 μm, the angle of drift angle is 90 °, and corner radii is 0-2.5 μm.
Further, the corner radii is 2-2.5 μm.
Further, in described high briliancy composite reflective film, the raw material of described brightening structure layer is no-solvent type Ultraviolet-curing resin glue.
Further, in described high briliancy composite reflective film, described no-solvent type ultraviolet-curing resin glue Refractive index is 1.53-1.56.Further, the refractive index of described no-solvent type ultraviolet-curing resin glue is 1.55-1.56.
Further, in described high briliancy composite reflective film, the height of described microprism bar is 44-50 μm, top The angle at angle is 90 °, and corner radii is 2-2.5 μm.Foregoing technical scheme correspondence embodiment 16-18,25-27, relative luminance In 103-106%, anti-adsorptivity is outstanding, and site is without scratch.
Further, the height of described microprism bar is 48-50 μm, and the angle of drift angle is 90 °, and corner radii is 2.5 μ M, the refractive index of glue is 1.55-1.56.Foregoing technical scheme correspondence embodiment 26-27, relative luminance is 106%, anti-to inhale Attached property is outstanding, and site is without scratch.
The present invention also provides a kind of method for preparing described high briliancy composite reflective film, and the preparation method includes following Step:
(1) it is coated with a surface of reflective substrate after polyurethane resin glue, polyurethane resin glue curing and forms poly- Urethane layer;
(2) no-solvent type ultraviolet-curing resin glue is coated with the surface of layer of polyurethane, utilizes structure roller formation microprism Bar, forms brightening structure layer after solidification.
Further, the step of making brightening structure layer includes:By no-solvent type ultraviolet-curing resin glue application in poly- The surface of urethane layer;Structure roller extrusion forming;High voltage mercury lamp radiation, solidifying and setting.
Further, using high voltage mercury lamp radiation brightening structure layer, its solidifying and setting is made.Further, described high pressure The irradiation energy of mercury lamp reaches 450mj/cm2, the linear velocity of the coating line is 6-20m/min.
Due to doing blast micro-structural on reflectance coating surface, the cost of reflectance coating can be significantly increased, so existing reflectance coating In preparation, the situation of micro-structural is not done on reflectance coating surface.
The easy scratch light guide plate of reflectance coating of existing surface coated particle, the high briliancy composite reflective film that the present invention is provided is difficult Scratch light guide plate, with preferable scratch resistance.
The present invention on the reflectance coating surface of existing one side polyurethane precoated shet by way of making brightening structure so that increases Air layer between bright structure peak plays a part of preventing that reflector plate from adsorbing with LGP, and by adjusting the top radius at structure peak, Preferably anti-scratch performance is provided, is reflected due to the light that brightening structure is reflected to reflectance coating inside and surface, converged again Utilize, improve the briliancy of reflectance coating, it is to avoid due to reflectance coating briliancy loss caused by coating.
Compared with existing coating reflectance coating, the high briliancy composite reflective film that provides of the present invention possess good anti-absorption, Scratch resistance energy, is provided simultaneously with outstanding briliancy performance.
Brief description of the drawings
The structural representation for the composite reflective film that Fig. 1 provides for the present invention.
Embodiment:
With reference to embodiment and accompanying drawing, the invention will be further elaborated, and following examples are to the detailed of the present invention Describe in detail bright, be not the restriction to claimed scope of the invention.Methods described is conventional method unless otherwise instructed.It is described Raw material are commercially available prod unless otherwise instructed.
As shown in figure 1, the present invention provides a kind of high briliancy composite reflective film, the composite reflective film includes reflection film base material 3rd, layer of polyurethane 2 and micro-prism structure layer 1.
The high briliancy composite reflective film that the present invention is prepared, carries out performance test by the following method:
Relative luminance:Reflectance coating (the i.e. reflection base in the composite reflective film that embodiment 1-27 is provided provided with comparative example 1 Material) briliancy be 100%, calculate the relative luminance of embodiment 1-27 and comparative example 2.The computational methods of relative luminance are:(measure Briliancy/comparative example 1 provide reflectance coating briliancy) × 100%.
Anti- absorption test:Reflectance coating sanction sample is assembled into 18.5 cun of backlights (side entering type), observes whether backlight has after lighting Speck.Represent that the anti-adsorptivity of reflectance coating is poor if any speck, such as represent that the anti-adsorptivity of reflectance coating is outstanding without speck.Zero represents The anti-adsorptivity of reflectance coating is outstanding;△ represents that the anti-adsorptivity of reflectance coating is general (there is local white point after assembling);× represent anti- The anti-adsorptivity for penetrating piece is poor (there is local hickie after assembling).
Anti-scratch test:Sample is cut into 10 × 10mm, by abrasion wear test machine, in PMMA printing light guide plate mesh point printings Face rubs, counterweight weight 1000g, speed 10 times/min, after reciprocal 50 times, observes the abrasion condition of printing net-point, and zero represents net Point is without scratch;△ represents the slight scratch in site;× represent the serious scratch in site.
The reflective substrate used in the composite reflective film that embodiment 1-27 is provided is the production of ningbo of china Chang Yang scientific & technical corporation Reflectance coating DJX300, the thickness of the reflective substrate is 300 μm.
Embodiment 1
A kind of high briliancy composite reflective film is provided, described composite reflective film include successively brightening structure layer, layer of polyurethane, Reflective substrate, described layer of polyurethane is coated on the surface of reflective substrate, and the surface of the layer of polyurethane, which makes, brightening structure Layer, described brightening structure layer has micro-prism structure.
Polyurethane precoated shet is prepared in the one side of reflective substrate, no-solvent type ultra-violet curing glue is (referred to as ultraviolet solid Tensol) polyurethane coating surface is coated in, by engraved roll extrusion forming, utilize high voltage mercury lamp radiation no-solvent type ultra-violet curing The structure of glue formation, makes it solidify to form brightening structure layer, the linear velocity of production line is 6-20m/min, high voltage mercury lamp radiation Energy reaches 450mj/cm2.Finally give high briliancy composite reflective film.
Described brightening structure layer has micro-prism structure.Described micro-prism structure is made up of some microprism bars.Institute The cross section for the microprism bar (abbreviation microprism) stated is triangle.
The height of the microprism is 20 microns, and the angle of drift angle is 90 °, and corner radii is 0 μm.
The refractive index of the ultra-violet curing glue is 1.53.
Embodiment 2
Condition of molding such as embodiment 1.
The height of the microprism is 20 microns, and the angle of drift angle is 90 °, and corner radii is 0 μm.
The refractive index of the ultra-violet curing glue is 1.55.
Embodiment 3
Condition of molding such as embodiment 1.
The height of the microprism is 20 microns, and the angle of drift angle is 90 °, and corner radii is 0 μm.
The refractive index of the ultra-violet curing glue is 1.56.
Embodiment 4
Condition of molding such as embodiment 1.
The height of the microprism is 20 microns, and the angle of drift angle is 90 °, and corner radii is 1.5 μm.
The refractive index of the ultra-violet curing glue is 1.53.
Embodiment 5
Condition of molding such as embodiment 1.
The height of the microprism is 20 microns, and the angle of drift angle is 90 °, and corner radii is 1.5 μm.
The refractive index of the ultra-violet curing glue is 1.55.
Embodiment 6
Condition of molding such as embodiment 1.
The height of the microprism is 20 microns, and the angle of drift angle is 90 °, and corner radii is 1.5 μm.
The refractive index of the ultra-violet curing glue is 1.56.
Embodiment 7
Condition of molding such as embodiment 1.
The height of the microprism is 20 microns, and the angle of drift angle is 90 °, and corner radii is 2.5 μm.
The refractive index of the ultra-violet curing glue is 1.53.
Embodiment 8
Condition of molding such as embodiment 1.
The height of the microprism is 20 microns, and the angle of drift angle is 90 °, and corner radii is 2.5 μm.
The refractive index of the ultra-violet curing glue is 1.55.
Embodiment 9
Condition of molding such as embodiment 1.
The height of the microprism is 20 microns, and the angle of drift angle is 90 °, and corner radii is 2.5 μm.
The refractive index of the ultra-violet curing glue is 1.56.
Embodiment 10
Condition of molding such as embodiment 1.
The height of the microprism is 44 microns, and the angle of drift angle is 90 °, and corner radii is 0 μm.
The refractive index of the ultra-violet curing glue is 1.53.
Embodiment 11
Condition of molding such as embodiment 1.
The height of the microprism is 44 microns, and the angle of drift angle is 90 °, and corner radii is 0 μm.
The refractive index of the ultra-violet curing glue is 1.55.
Embodiment 12
Condition of molding such as embodiment 1.
The height of the microprism is 44 microns, and the angle of drift angle is 90 °, and corner radii is 0 μm.
The refractive index of the ultra-violet curing glue is 1.56.
Embodiment 13
Condition of molding such as embodiment 1.
The height of the microprism is 44 microns, and the angle of drift angle is 90 °, and corner radii is 1.5 μm.
The refractive index of the ultra-violet curing glue is 1.53.
Embodiment 14
Condition of molding such as embodiment 1.
The height of the microprism is 44 microns, and the angle of drift angle is 90 °, and corner radii is 1.5 μm.
The refractive index of the ultra-violet curing glue is 1.55.
Embodiment 15
Condition of molding such as embodiment 1.
The height of the microprism is 44 microns, and the angle of drift angle is 90 °, and corner radii is 1.5 μm.
The refractive index of the ultra-violet curing glue is 1.56.
Embodiment 16
Condition of molding such as embodiment 1.
The height of the microprism is 44 microns, and the angle of drift angle is 90 °, and corner radii is 2 μm.
The refractive index of the ultra-violet curing glue is 1.53.
Embodiment 17
Condition of molding such as embodiment 1.
The height of the microprism is 44 microns, and the angle of drift angle is 90 °, and corner radii is 2.5 μm.
The refractive index of the ultra-violet curing glue is 1.55.
Embodiment 18
Condition of molding such as embodiment 1.
The height of the microprism is 44 microns, and the angle of drift angle is 90 °, and corner radii is 2.5 μm.
The refractive index of the ultra-violet curing glue is 1.56.
Embodiment 19
Condition of molding such as embodiment 1.
The height of the microprism is 50 microns, and the angle of drift angle is 90 °, and corner radii is 0 μm.
The refractive index of the ultra-violet curing glue is 1.53.
Embodiment 20
Condition of molding such as embodiment 1.
The height of the microprism is 50 microns, and the angle of drift angle is 90 °, and corner radii is 0 μm.
The refractive index of the ultra-violet curing glue is 1.55.
Embodiment 21
Condition of molding such as embodiment 1.
The height of the microprism is 50 microns, and the angle of drift angle is 90 °, and corner radii is 0 μm.
The refractive index of the ultra-violet curing glue is 1.56.
Embodiment 22
Condition of molding such as embodiment 1.
The height of the microprism is 50 microns, and the angle of drift angle is 90 °, and corner radii is 1.5 μm.
The refractive index of the ultra-violet curing glue is 1.53.
Embodiment 23
Condition of molding such as embodiment 1.
The height of the microprism is 50 microns, and the angle of drift angle is 90 °, and corner radii is 1.5 μm.
The refractive index of the ultra-violet curing glue is 1.55.
Embodiment 24
Condition of molding such as embodiment 1.
The height of the microprism is 50 microns, and the angle of drift angle is 90 °, and corner radii is 1.5 μm.
The refractive index of the ultra-violet curing glue is 1.56.
Embodiment 25
Condition of molding such as embodiment 1.
The height of the microprism is 48 microns, and the angle of drift angle is 90 °, and corner radii is 2.5 μm.
The refractive index of the ultra-violet curing glue is 1.53.
Embodiment 26
Condition of molding such as embodiment 1.
The height of the microprism is 48 microns, and the angle of drift angle is 90 °, and corner radii is 2.5 μm.
The refractive index of the ultra-violet curing glue is 1.55.
Embodiment 27
Condition of molding such as embodiment 1.
The height of the microprism is 50 microns, and the angle of drift angle is 90 °, and corner radii is 2.5 μm.
The refractive index of the ultra-violet curing glue is 1.56.
Comparative example 1
The reflectance coating DJX300 of ningbo of china Chang Yang scientific & technical corporation production.
Comparative example 2
The reflectance coating of existing surface coated particle:The reflectance coating DJX300P of ningbo of china Chang Yang scientific & technical corporation production.Belong to Shipment amount is larger in the market, the preferable coated particle type reflectance coating of anti-scratch, anti-adsorption.
The performance test results for the reflectance coating that the comparative example 1-2 of table 1, embodiment 1-27 are provided
Comparative example 1 is uncoated reflective substrate, and comparative example 2 is the reflectance coating production of the good coated particle of Market Feedback Product;As seen from the data in Table 1:Embodiment 1-9 anti-adsorptions are unstable and poor, and embodiment 16-18 and embodiment 25-27 possess Preferable scratch resistance energy and anti-adsorption, further, embodiment 26-27 are lifted greatly in briliancy, are optimal case.
The above, only presently preferred embodiments of the present invention is not intended to limit the scope of the present invention.It is every In the impartial change done according to present invention and modification, the scope of the claims for being encompassed by the present invention.

Claims (10)

1. a kind of high briliancy composite reflective film, it is characterised in that described composite reflective film includes brightening structure layer, poly- ammonia successively Ester layer, reflective substrate, described layer of polyurethane are coated on the surface of reflective substrate, and the surface of the layer of polyurethane is provided with blast Structure sheaf, described brightening structure layer has micro-prism structure.
2. high briliancy composite reflective film according to claim 1, it is characterised in that described micro-prism structure is by some micro- Prism bar is constituted.
3. high briliancy composite reflective film according to claim 2, it is characterised in that the cross section of described microprism bar is Triangle.
4. high briliancy composite reflective film according to claim 3, it is characterised in that the drift angle of the triangle is fillet.
5. high briliancy composite reflective film according to claim 3, it is characterised in that described microprism bar (referred to as micro- rib Mirror) height be 20-50 μm, the angle of drift angle is 90 °, and corner radii is 0-2.5 μm.
6. high briliancy composite reflective film according to claim 5, it is characterised in that the corner radii is 2-2.5 μm.
7. high briliancy composite reflective film according to claim 2, it is characterised in that the raw material of described brightening structure layer is No-solvent type ultraviolet-curing resin glue.
8. high briliancy composite reflective film according to claim 5, it is characterised in that described no-solvent type ultra-violet curing tree The refractive index of fat glue is 1.53-1.56.
9. high briliancy composite reflective film according to claim 5, it is characterised in that the height of described microprism bar is 44-50 μm, the angle of drift angle is 90 °, and corner radii is 2-2.5 μm.
10. a kind of method of the high briliancy composite reflective film prepared according to any one of claim 1-9, its feature exists In the preparation method comprises the steps:
(1) polyurethane is formed after being coated with polyurethane resin glue, polyurethane resin glue curing on a surface of reflective substrate Layer;
(2) no-solvent type ultraviolet-curing resin glue is coated with the surface of layer of polyurethane, using structure roller formation microprism bar, Gu Brightening structure layer is formed after change.
CN201710300104.8A 2017-05-02 2017-05-02 A kind of high briliancy composite reflective film Pending CN106959480A (en)

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Publication number Priority date Publication date Assignee Title
CN108089249A (en) * 2017-11-29 2018-05-29 宁波激智科技股份有限公司 A kind of hot-forming reflectance coating and preparation method thereof
CN109270611A (en) * 2018-12-11 2019-01-25 宁波激智科技股份有限公司 A kind of complex optical film that high brightness height covers
CN115616694A (en) * 2022-11-04 2023-01-17 宁波东旭成新材料科技有限公司 An environment-friendly microstructure reflective film
CN113900170B (en) * 2021-10-13 2023-09-19 安徽晟华光学科技有限公司 A high-brightness anti-adsorption and scratch-resistant prism film and its preparation method

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CN105093367A (en) * 2015-08-11 2015-11-25 宁波长阳科技有限公司 Composite brightness enhancement film and preparation method thereof
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CN1916670A (en) * 2001-08-03 2007-02-21 3M创新有限公司 Optical film having microeplicated structures, and its production method
CN201876560U (en) * 2010-11-16 2011-06-22 江西联创致光科技有限公司 Polarization and reflection type composite brightening film
CN102141638A (en) * 2011-04-02 2011-08-03 袁帅 Prism film of cambered microstructure
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108089249A (en) * 2017-11-29 2018-05-29 宁波激智科技股份有限公司 A kind of hot-forming reflectance coating and preparation method thereof
CN109270611A (en) * 2018-12-11 2019-01-25 宁波激智科技股份有限公司 A kind of complex optical film that high brightness height covers
CN113900170B (en) * 2021-10-13 2023-09-19 安徽晟华光学科技有限公司 A high-brightness anti-adsorption and scratch-resistant prism film and its preparation method
CN115616694A (en) * 2022-11-04 2023-01-17 宁波东旭成新材料科技有限公司 An environment-friendly microstructure reflective film

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Application publication date: 20170718