CN106968047A - A kind of rigid warming sandwich air layer face fabric and preparation method thereof of HMLS terylene - Google Patents
A kind of rigid warming sandwich air layer face fabric and preparation method thereof of HMLS terylene Download PDFInfo
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- CN106968047A CN106968047A CN201710178075.2A CN201710178075A CN106968047A CN 106968047 A CN106968047 A CN 106968047A CN 201710178075 A CN201710178075 A CN 201710178075A CN 106968047 A CN106968047 A CN 106968047A
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- 239000004744 fabric Substances 0.000 title claims abstract description 58
- 238000010792 warming Methods 0.000 title claims abstract description 22
- 229920004933 Terylene® Polymers 0.000 title claims abstract description 20
- 239000005020 polyethylene terephthalate Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title abstract description 9
- 239000000835 fiber Substances 0.000 claims abstract description 97
- 239000003365 glass fiber Substances 0.000 claims abstract description 33
- 229920000728 polyester Polymers 0.000 claims abstract description 29
- 239000004753 textile Substances 0.000 claims abstract description 29
- 239000002253 acid Substances 0.000 claims abstract description 28
- 229920000297 Rayon Polymers 0.000 claims abstract description 26
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 238000009940 knitting Methods 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 10
- 239000012530 fluid Substances 0.000 claims abstract description 9
- 230000004048 modification Effects 0.000 claims description 16
- 238000012986 modification Methods 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 238000005406 washing Methods 0.000 claims description 10
- 239000000654 additive Substances 0.000 claims description 8
- 230000000996 additive effect Effects 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000007822 coupling agent Substances 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- 150000002460 imidazoles Chemical class 0.000 claims description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 2
- 238000009941 weaving Methods 0.000 claims description 2
- VYFYYTLLBUKUHU-UHFFFAOYSA-N dopamine Chemical compound NCCC1=CC=C(O)C(O)=C1 VYFYYTLLBUKUHU-UHFFFAOYSA-N 0.000 claims 2
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 1
- 229960003638 dopamine Drugs 0.000 claims 1
- 238000009413 insulation Methods 0.000 claims 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 230000001681 protective effect Effects 0.000 abstract description 5
- CTENFNNZBMHDDG-UHFFFAOYSA-N Dopamine hydrochloride Chemical compound Cl.NCCC1=CC=C(O)C(O)=C1 CTENFNNZBMHDDG-UHFFFAOYSA-N 0.000 description 5
- 229960001149 dopamine hydrochloride Drugs 0.000 description 5
- 230000008901 benefit Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- WWSNLNXXISONLQ-UHFFFAOYSA-N C(CCCCCCCCCCCCCCC)Cl(C)(C)C Chemical compound C(CCCCCCCCCCCCCCC)Cl(C)(C)C WWSNLNXXISONLQ-UHFFFAOYSA-N 0.000 description 1
- 206010054949 Metaplasia Diseases 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical group [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000015689 metaplastic ossification Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/22—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/415—Amides of aromatic carboxylic acids; Acylated aromatic amines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/02—Inorganic fibres based on oxides or oxide ceramics, e.g. silicates
- D10B2101/06—Glass
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/20—Cellulose-derived artificial fibres
- D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
- D10B2201/24—Viscose
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/063—Load-responsive characteristics high strength
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Woven Fabrics (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of preparation method of the rigid warming sandwich air layer face fabric of HMLS terylene, comprise the following steps：(1) raw material is selected：It is raw material to choose glass fiber for textile use, Chinese fiber crops and viscose rayon, high-strength polyester fiber, acid fiber by polylactic；(2) fiber is pre-processed：Above-mentioned raw materials are placed in pretreatment fluid respectively and pre-processed；(3) spin：It is the first yarn and the second yarn by pretreated raw fibre blending；(4) weave：Sandwich air layer fabric is prepared into using two-sided circular knitting machine；(5) HMLS terylene rigidly warming sandwich air layer face fabric is made in Final finishing.The preparation method of present invention knitting fabric is simple, it is adapted to industrialized production, can be widely applied to building trade and production industry needs the warming work clothes of the stiffer wear-resistant of HMLS terylene, and processes in the productions of product such as various case and bag, kit bag, protective cover and tent.
Description
Technical field
The present invention relates to knitting fabric field, more particularly to a kind of rigid warming sandwich air aspect of HMLS terylene
Material and preparation method thereof.
Background technology
In general, compared with woven fabric, there is knitted fabric soft feel and excellent elasticity to be widely used, but
Because the tuck vent canopy of knitted fabric is higher than woven fabric, when being worn as autumn and winter clothing, feel with easily ventilative
Cold shortcoming.In order to solve this problem, it has therefore been proposed that excessively several solutions.For example, in the backside coating of knitted fabric
The method of resin or attaching film, and in the back side collection floor height texture fabric of knitted fabric, plucking or raising improve fabric
Ventilative performance.Although these methods make moderate progress to ventilative shortcoming, usual such knitted fabric is more thick and heavy, is not suitable for interior
Clothing is used, and poor air permeability, is worn uncomfortable.
With the continuous improvement of people's living standards, requirement of the people to clothing performance is also improved constantly.Make clothes
Fabric, cloth cover glossiness, feel and style etc. are increasingly paid close attention to by people.However, in different industries to fabric
It is required that it is also different, for example, needing the fabric of acid and alkali-resistance in the laboratory of chemical industry；Need to protect in the industry of low temperature resistant operation
Warm fabric, the warming fabric of the stiffer wear-resistant of HMLS terylene is needed in building trade and production industry.Therefore, in order to protect
Our safety of itself are protected, the need for how developing a kind of protective fabric of high-modulus to meet current special industry, are turned into
Those skilled in the art's technical problem urgently to be resolved hurrily.
The content of the invention
The present invention is solves above mentioned problem of the prior art, and proposing a kind of HMLS terylene, rigidly warming sandwich is empty
Gas-bearing formation fabric and preparation method thereof, present invention generally provides a kind of protective fabric, raw material is made using glass fiber for textile use, weaving
With the superhigh intensity of glass fibre, high-modulus, high temperature resistant, acid and alkali-resistance, it is lightweight the advantages of, with Chinese fiber crops and viscose rayon, high-strength
Polyester fiber, the blending of acid fiber by polylactic raw material are combined, and advantage mutually increases, and shortcoming is complementary, makes fabric performance more perfect.By pre- place
Fibrous raw material after reason causes fabric to have good mechanicalness and thermal property.
To achieve the above object, the present invention uses following technical scheme：
The first aspect of the invention is to provide a kind of system of the rigid warming sandwich air layer face fabric of HMLS terylene
Preparation Method, comprises the following steps：
(1) raw material is selected：Choose glass fiber for textile use, Chinese fiber crops and viscose rayon, high-strength polyester fiber, acid fiber by polylactic
For raw material；
(2) fiber is pre-processed：Respectively by glass fiber for textile use, Chinese fiber crops and viscose rayon, high-strength polyester fiber and poly- breast
Sour fiber is placed in 70-80 DEG C of the pretreatment fluid containing surface modification liquid and antistatic additive, circulates 30-45min, continues to be incubated
After circular response 15-30min, fiber is dried after washing；
(3) spin：It is the first yarn by pretreated glass fiber for textile use, high-strength polyester fiber blending, will locates in advance
Chinese fiber crops and viscose rayon and acid fiber by polylactic blending after reason are the second yarn；
(4) weave：On two-sided circular knitting machine, using fixed knitting sequence, triangle arrangement and mode of entrying, by
One yarn and the second yarn are woven into two panels intermediate course fabric, and the method knitted by running-on is prepared into sandwich air layer base
Cloth；
(5) Final finishing：By fabric through soft treatment, open-width, washing, drying, setting, HMLS terylene is made and rigidly protects
Warm sandwich air layer face fabric.
Further, the fineness of glass fiber for textile use is 5-7dtex in the step (1)；The Chinese fiber crops and viscose glue are fine
The fineness of dimension is 3-5dtex；The high-strength polyester fiber is the polyester fiber or length of high-strength flatness HMLS anti-fluffing and anti-pilling
Silk, fineness is 3-5dtex；The fineness of the acid fiber by polylactic is 6-8dtex.
Further, glass fiber for textile use is TM high-strength high-modulus glass fibers in the step (1).
Further, pretreatment fluid is surface modification liquid and 0.3-0.8wt% containing 1-3wt% in the step (2)
Antistatic additive the aqueous solution.
Further, pretreatment fluid is the anti-of the surface modification liquid containing 1.5wt% and 0.6wt% in the step (2)
The aqueous solution of electrostatic agent.
Further, in the step (2) surface modification liquid by dopamine hydrochloride 10-20wt%, N- hydroxy-N-phenyl
Propionamide 20-30wt%, KH550 coupling agent 5-10wt% and ethanol 50-60wt% configuration are formed.
Further, in the step (2) surface modification liquid by dopamine hydrochloride 15wt%, N- hydroxy-N-phenyl third
Acid amides 25wt%, KH550 coupling agent 8wt% and ethanol 52wt% configuration are formed.
Further, antistatic additive is selected from the derivative of quaternary ammonium salt, imidazoles or ethylene oxide in the step (2).
Further, antistatic additive is hexadecyltrimethylammonium chloride or aliphatic alcohol polyethenoxy in the step (2)
Ether.
Further, 30-40wt% containing glass fiber for textile use, high-strength polyester are fine in the first yarn in the step (3)
Tie up 60-70wt%；Containing Chinese fiber crops and viscose rayon 40-60wt%, acid fiber by polylactic 40-60wt% in second yarn.
Further, 35wt% containing glass fiber for textile use, high-strength polyester fiber in the first yarn in the step (3)
65wt%；Containing Chinese fiber crops and viscose rayon 55wt%, acid fiber by polylactic 45wt% in second yarn.
Further, glass fiber for textile use, high-strength polyester fiber, Yi Jisuo are contained in the step (3) in the first yarn
State containing Chinese fiber crops and viscose rayon, acid fiber by polylactic in the second yarn, these fibers can be colored fibre, achromatic fibrils or fiber crops
Grey yarn.
Further, the rigid warming sandwich air layer face fabric grammes per square metre of obtained HMLS terylene in the step (5)
For 100-250g/cm2。
The second aspect of the invention is to provide HMLS terylene prepared by a kind of use above method rigidly warming three
Mingzhi's air layer face fabric.
The present invention uses above-mentioned technical proposal, compared with prior art, have the following technical effect that：
Present invention employs the glass fiber for textile use of high-modulus, the glass fiber for textile use and the Chinese of the high-modulus are numb and viscous
Glue fiber, high-strength polyester fiber, the obtained knitting fabric of acid fiber by polylactic blending have superhigh intensity, high-modulus, high temperature resistant, resistance to
Soda acid, it is lightweight the advantages of；Feel according to actual needs simultaneously and stiffness requirement, table is carried out to different modulus raw fibre
Face is modified, and improves the ageing resistace of fabric, touches slipping, effectively improves every color jail of existing protective fabric
Degree, slows down damage of the ultraviolet to fabric, and anti-stain characteristic can be strong；The knitted side preparation method for material of the present invention is simple, is adapted to industry
Metaplasia is produced, and can be widely applied to building trade and production industry, it is necessary to the warming work clothes of the stiffer wear-resistant of HMLS terylene,
And for processing in the production of the products such as various case and bag, kit bag, protective cover and tent.
Embodiment
The present invention is described in more detail below by specific embodiment, for a better understanding of the present invention,
But following embodiments are not intended to limit the scope of the invention.
The preparation of the rigid warming sandwich air layer face fabric of the HMLS terylene of embodiment 1
(1) raw material is selected：Choose TM high strength and modulus glass fiber for textile use, Chinese fiber crops and viscose rayon, high-strength flatness
Polyester fiber or long filament, the acid fiber by polylactic of HMLS anti-fluffing and anti-pilling are raw material；
(2) fiber is pre-processed：Respectively by TM high strength and modulus glass fiber for textile use, Chinese fiber crops and viscose rayon, high-strength
Polyester fiber and acid fiber by polylactic are placed in 70 DEG C of the cetyl trimethyl chlorine containing 2wt% surfaces modification liquid and 0.5wt%
In the pretreatment fluid for changing ammonium, after circulation 40min, continue after soak cycles reaction 20min, fiber is dried after washing；Wherein, table
Face modification liquid is by dopamine hydrochloride 15wt%, N- hydroxy-N-phenyl propionamide 25wt%, KH550 coupling agent 8wt% and ethanol
52wt% configurations are formed；
(3) spin：By pretreated TM high strength and modulus glass fiber for textile use, high-strength polyester fiber by weight hundred
Point than glass fiber for textile use 35wt%, high-strength polyester fiber 65wt% blending be the first yarn, by the pretreated Chinese fiber crops and
Viscose rayon and acid fiber by polylactic Chinese fiber crops by weight percentage and viscose rayon 50wt%, acid fiber by polylactic 50wt% dimension blending are
Second yarn；
(4) weave：On two-sided circular knitting machine, using fixed knitting sequence, triangle arrangement and mode of entrying, by
One yarn and the second yarn are woven into two panels intermediate course fabric, and the method knitted by running-on is prepared into sandwich air layer base
Cloth；
(5) Final finishing：By fabric through soft treatment, open-width, washing, drying, setting, it is 100g/cm that grammes per square metre, which is made,2Height
The rigid warming sandwich air layer face fabric of modulus lower shrinkage.
The preparation of the rigid warming sandwich air layer face fabric of the HMLS terylene of embodiment 2
(1) raw material is selected：Choose TM high strength and modulus glass fiber for textile use, Chinese fiber crops and viscose rayon, high-strength flatness
Polyester fiber or long filament, the acid fiber by polylactic of HMLS anti-fluffing and anti-pilling are raw material；
(2) fiber is pre-processed：Respectively by TM high strength and modulus glass fiber for textile use, Chinese fiber crops and viscose rayon, high-strength
The polyester fiber and acid fiber by polylactic of flatness HMLS be placed in 70 DEG C containing 1.2wt% surfaces modification liquid and 0.8wt%
In the pretreatment fluid of AEO, after circulation 40min, continue after soak cycles reaction 20min, fiber is after washing
Dry；Wherein, surface modification liquid is coupled by dopamine hydrochloride 15wt%, N- hydroxy-N-phenyl propionamide 25wt%, KH550
Agent 8wt% and ethanol 52wt% configurations are formed；
(3) spin：By pretreated TM high strength and modulus glass fiber for textile use, high-strength polyester fiber by weight hundred
It is the first yarn to divide than TM high strength and modulus glass fiber for textile use 40wt%, high-strength polyester fiber 60wt% blending, will be pre-
Chinese fiber crops and viscose rayon and acid fiber by polylactic Chinese fiber crops and viscose rayon 45wt%, acid fiber by polylactic by weight percentage after processing
55wt% dimension blending is the second yarn；
(4) weave：On two-sided circular knitting machine, using fixed knitting sequence, triangle arrangement and mode of entrying, by
One yarn and the second yarn are woven into two panels intermediate course fabric, and the method knitted by running-on is prepared into sandwich air layer base
Cloth；
(5) Final finishing：By fabric through soft treatment, open-width, washing, drying, setting, it is 150g/cm that grammes per square metre, which is made,2Height
The rigid warming sandwich air layer face fabric of modulus lower shrinkage.
The preparation of the rigid warming sandwich air layer face fabric of the HMLS terylene of embodiment 3
(1) raw material is selected：Choose TM high strength and modulus glass fiber for textile use, Chinese fiber crops and viscose rayon, high-strength flatness
Polyester fiber or long filament, the acid fiber by polylactic of HMLS anti-fluffing and anti-pilling are raw material；
(2) fiber is pre-processed：Respectively by TM high strength and modulus glass fiber for textile use, Chinese fiber crops and viscose rayon, high-strength
The polyester fiber and acid fiber by polylactic of flatness HMLS are placed in 80 DEG C of ten containing 3wt% surfaces modification liquid and 0.3wt%
In the pretreatment fluid of six alkyl trimethyl ammonium chlorides, after circulation 30min, continue after soak cycles reaction 30min, fiber is through washing
After dry；Wherein, surface modification liquid is even by dopamine hydrochloride 12wt%, N- hydroxy-N-phenyl propionamide 27wt%, KH550
Connection agent 6wt% and ethanol 55wt% configurations are formed；
(3) spin：By pretreated TM high strength and modulus glass fiber for textile use, high-strength polyester fiber by weight hundred
It is the first yarn to divide than TM high strength and modulus glass fiber for textile use 42wt%, high-strength polyester fiber 58wt% blending, will be pre-
Chinese fiber crops and viscose rayon and acid fiber by polylactic Chinese fiber crops and viscose rayon 55wt%, acid fiber by polylactic by weight percentage after processing
45wt% dimension blending is the second yarn；
(4) weave：On two-sided circular knitting machine, using fixed knitting sequence, triangle arrangement and mode of entrying, by
One yarn and the second yarn are woven into two panels intermediate course fabric, and the method system knitted by running-on is prepared into sandwich air layer
Fabric；
(5) Final finishing：By fabric through soft treatment, open-width, washing, drying, setting, it is 250g/cm that grammes per square metre, which is made,2Height
The rigid warming sandwich air layer face fabric of modulus lower shrinkage.
The specific embodiment of the present invention is described in detail above, but it is intended only as example, and the present invention is not limited
It is formed on particular embodiments described above.To those skilled in the art, it is any to the equivalent modifications that carry out of the present invention and
Substitute also all among scope of the invention.Therefore, the impartial conversion made without departing from the spirit and scope of the invention and
Modification, all should be contained within the scope of the invention.
Claims (10)
1. the preparation method of the rigid warming sandwich air layer face fabric of a kind of HMLS terylene, it is characterised in that including following
Step：
(1) raw material is selected：It is original to choose glass fiber for textile use, Chinese fiber crops and viscose rayon, high-strength polyester fiber, acid fiber by polylactic
Material；
(2) fiber is pre-processed：It is respectively that glass fiber for textile use, Chinese fiber crops and viscose rayon, high-strength polyester fiber and PLA is fine
Dimension is placed in 70-80 DEG C of the pretreatment fluid containing surface modification liquid and antistatic additive, after circulation 30-45min, is continued insulation and is followed
After ring reaction 15-30min, fiber is dried after washing；
(3) spin：It is the first yarn by pretreated glass fiber for textile use, high-strength polyester fiber blending, after pretreatment
Chinese fiber crops and viscose rayon and acid fiber by polylactic blending be the second yarn；
(4) weave：On two-sided circular knitting machine, using fixed knitting sequence, triangle arrangement and mode of entrying, by the first yarn
Line and the second yarn are woven into two panels intermediate course fabric, and the method knitted by running-on is prepared into sandwich air layer fabric；
(5) Final finishing：By fabric through soft treatment, open-width, washing, drying, setting, obtained HMLS terylene rigidly warming three
Mingzhi's air layer face fabric.
2. preparation method according to claim 1, it is characterised in that glass fiber for textile use is thin in the step (1)
Spend for 5-7dtex；The fineness of the Chinese fiber crops and viscose rayon is 3-5dtex；The high-strength polyester fiber is high-strength flatness Gao Mo
The polyester fiber or long filament of low-shrinkage anti-fluffing and anti-pilling, fineness is 3-5dtex；The fineness of the acid fiber by polylactic is 6-8dtex.
3. preparation method according to claim 2, it is characterised in that glass fiber for textile use is TM in the step (1)
High-strength high-modulus glass fiber.
4. preparation method according to claim 1, it is characterised in that pretreatment fluid is to contain 1- in the step (2)
The aqueous solution of 3wt% surface modification liquid and 0.3-0.8wt% antistatic additive.
5. preparation method according to claim 1, it is characterised in that surface modification liquid is by dopamine in the step (2)
Hydrochloride 10-20wt%, N- hydroxy-N-phenyl propionamide 20-30wt%, KH550 coupling agent 5-10wt% and ethanol 50-
60wt% configurations are formed.
6. preparation method according to claim 1, it is characterised in that in the step (2) antistatic additive be selected from quaternary ammonium salt,
The derivative of imidazoles or ethylene oxide.
7. preparation method according to claim 1, it is characterised in that antistatic additive is cetyl in the step (2)
Trimethyl ammonium chloride or AEO.
8. preparation method according to claim 1, it is characterised in that used in the step (3) in the first yarn containing weaving
Glass fibre 30-40wt%, high-strength polyester fiber 60-70wt%；Containing Chinese fiber crops and viscose rayon 40- in second yarn
60wt%, acid fiber by polylactic 40-60wt%.
9. preparation method according to claim 1, it is characterised in that obtained HMLS terylene in the step (5)
The warming sandwich air layer face fabric grammes per square metre of rigidity is 100-250g/cm2。
10. the rigid warming sandwich air layer face fabric of the HMLS terylene prepared such as any one of claim 1-9 methods described.
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Application publication date: 20170721 |