CN106977342A - A kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements - Google Patents
A kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements Download PDFInfo
- Publication number
- CN106977342A CN106977342A CN201710422480.4A CN201710422480A CN106977342A CN 106977342 A CN106977342 A CN 106977342A CN 201710422480 A CN201710422480 A CN 201710422480A CN 106977342 A CN106977342 A CN 106977342A
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- CN
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- Prior art keywords
- liquid fertilizer
- acid
- amino acids
- trace elements
- amino acid
- Prior art date
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- 239000002131 composite material Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 150000002333 glycines Chemical class 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003617 indole-3-acetic acid Substances 0.000 description 1
- AGPKZVBTJJNPAG-UHFFFAOYSA-N isoleucine Natural products CCC(C)C(N)C(O)=O AGPKZVBTJJNPAG-UHFFFAOYSA-N 0.000 description 1
- 229960000310 isoleucine Drugs 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 230000037353 metabolic pathway Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- DEDOPGXGGQYYMW-UHFFFAOYSA-N molinate Chemical compound CCSC(=O)N1CCCCCC1 DEDOPGXGGQYYMW-UHFFFAOYSA-N 0.000 description 1
- 230000017074 necrotic cell death Effects 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- FWFGVMYFCODZRD-UHFFFAOYSA-N oxidanium;hydrogen sulfate Chemical compound O.OS(O)(=O)=O FWFGVMYFCODZRD-UHFFFAOYSA-N 0.000 description 1
- 108040007629 peroxidase activity proteins Proteins 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 230000037039 plant physiology Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000007198 pollen germination Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 108060006633 protein kinase Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000032895 transmembrane transport Effects 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C11/00—Other nitrogenous fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
The present invention discloses a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, and its constituent includes by weight percentage：Amino acid 30 45%, trace element 15 25%, the water of organic acid 5 20% and surplus.The present invention makes the effect of fertilizer slowly discharge, crop is fully absorbed nutrient by rational proportion relation between amino acid, organic acid and trace element, so as to improve the utilization rate of fertilizer, improves the quality of crop.
Description
Technical field
The present invention relates to technical field of fertilizers, and in particular to a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements.
Background technology
Crop is in its growth and development process, and constantly absorb nourishment composition from surrounding environment, is provided from body and grows
Need.The nutriment that plant growth needs is provided, the fast-growth of crop, and growth and maturity in a short time can be kept.Cause
This, the nutrient that supplement surrounding environment lacks, it is ensured that the healthy growth of crop enables to crop to grow flourishing, main
It is dry crude strong.
At present, people frequently with fertilizer be trace element and amino-acid compound fertilizer material, with supplement surrounding environment shortage
Nutrient.In the growth and development process that the composite is applied to crop, the growth of crop can be promoted.But it exists compound
Fertilizer can be residued in partly in soil, so as to reduce soil permeability, reduction crop causes to make article to the absorbability of nutrient
The shortcoming that matter declines.
The content of the invention
In view of this, the application provides a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, with utilization rate it is high,
Efficiently the advantages of.
To solve above technical problem, the technical scheme that the present invention is provided is a kind of containing Chelates of Amino Acids And Trace Elements
Liquid fertilizer, its constituent includes by weight percentage：
Amino acid 30-45%, trace element 15-25%, organic acid 5-20% and surplus water.
It is preferred that, a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, it is characterised in that its constituent
Include by weight percentage：
Amino acid 35-40%, trace element 20-25%, organic acid 5-10% and surplus water.
It is preferred that, the amino acid includes glycine, proline, lysine, alanine, arginine, leucine or Guang ammonia
One or more in acid.
It is preferred that, the amino acid includes the one or more in glycine, proline, lysine or alanine.
It is preferred that, the trace element includes Zn-ef ficiency, ferro element, boron element, molybdenum element, cobalt element, manganese element, copper coin
One or more in element or selenium element.
It is preferred that, it is described trace element include Zn-ef ficiency, ferro element, boron element, manganese element or copper in one kind or
It is a variety of.
It is preferred that, the micro- Zn-ef ficiency includes zinc sulfate, zinc chloride, basic zinc carbonate, EDTA chelated zincs, vulcanization
One or more in zinc or trbasic zinc phosphate；It is sub- that the micro- ferro element includes ferric sulfate, EDTA chelated irons, a hypophosphite monohydrate
One or more in iron ammonium, fulvic acid diamines iron or iron ammonium sulfate；The micro- boron element includes boric acid, boron magnesium phosphorus
One or more in fertilizer, borax, boric magnesium fertilizer or boron mud；The micro- manganese element includes manganese sulfate, manganese carbonate or EDTA
One or more in Chelated Manganese；The micro- copper include cupric sulfate pentahydrate, copper sulfate monohydrate, cuprous oxide,
One or more in EDTA chelated coppers or basic copper carbonate.
It is preferred that, the micro- Zn-ef ficiency includes one kind in zinc sulfate, zinc chloride, EDTA chelated zincs or zinc sulphide
Or it is a variety of；The micro- ferro element includes the one or more in ferric sulfate, EDTA chelated irons or iron ammonium sulfate；It is described
Micro- boron element includes the one or more in boric acid, borax or boron mud；The micro- manganese element includes manganese sulfate
Or the one or more in EDTA Chelated Manganeses；The micro- copper includes cupric sulfate pentahydrate, copper sulfate monohydrate, oxidation Asia
One or more in copper or EDTA chelated coppers.
It is preferred that, the organic acid includes the one or more in sulfamic acid, citric acid, humic acid or oxalic acid.
It is preferred that, the organic acid includes the one or more in citric acid, humic acid or oxalic acid.
It is preferred that, a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, preparation method comprises the following steps：
1) by amino acid, organic acid and water mixed dissolution, the liquid fertilizer containing amino acid is obtained；
2) by the liquid fertilizer obtained above containing amino acid and micro- mixed dissolution, produce a kind of micro- containing amino acid
The liquid fertilizer of secondary element chelate.
It is preferred that, the step 1) in the liquid fertilizer containing amino acid configuration process it is as follows：By weight percentage by ammonia
Base acid and organic acid are soluble in water successively, that is, obtain the liquid fertilizer containing amino acid.
It is preferred that, it is described be dissolved in 55-65 DEG C under conditions of carry out.
It is preferred that, it is described be dissolved in 55-60 DEG C under conditions of carry out.
The present invention provides a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, and its constituent is by weight percentage
Meter includes：Amino acid 30-45%, trace element 15-25%, organic acid 5-20% and surplus water.First, plant is to amino acid
Absorption, transhipment, application on fertilizer and agricultural chemicals of metabolism and amino acid have been reported both at home and abroad.Plant can direct absorbent earth
Amino acid molecular in earth, its transhipment, distribution, metabolism after absorbing is different because of amino acid classes, and the physiological effect of generation is not yet
It is identical；Agrochemicals of Amino Acids is easily decomposed by daylight or degraded by nature microorganism, and in soil, residual hazard is not stayed in plant, its
Catabolite is alternatively arranged as the nutriment of crops, the quality and yield of crops is improved, using this kind of agricultural chemicals, Ren Xuan
Entirely, without public hazards；Amino acid fertilizer, which also has, to be promoted vine growth and development, enhancing resistance, improves soil regime and improve crop
The effect of yield.
Secondly, though trace element is few in crop in-vivo content, it plays vital work to growing for crop
With being the part of enzyme or coenzyme in crop body, be that crop growth is indispensable and not with very strong selectivity
It can be substituted for each other.Therefore, when crop is in the case of micro- abundance, physiological function will be very vigorous, and this is conducive to
Absorption and utilization of the crop to other elements, it can also improve the colloid chemistry property of cellular plasm, so that plasm
Concentration increase, enhancing crop is to the resistance of poor environment.Meanwhile, amino acid can form stable chelating with trace element
Thing, in use, the effect of fertilizer slowly discharge, and crop is fully absorbed nutrient, so as to improve the utilization rate of fertilizer.
Finally, the quality of soil aeration performance, directly affects effective utilization of soil fertility, and then influence plant growth.
Defective aeration, then oxygen is not enough, will suppress the respiration of crop root, and then weaken the function of Root Absorption liquid manure.
In this application, organic acid is added, it can adjust the acid-base value of soil, increases soil permeability, so as to increase crop root
To the absorption of fertilizer, the utilization rate of fertilizer is improved.The preferred organic acid of the application be citric acid, oxalic acid or humic acid, more
It is preferred that organic acid be citric acid.Reason is：Containing three carboxyl functional groups in citric acid, its produced after hydrolyzing hydrogen ion compared with
It is many, it is acid stronger.
A kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements specifically preferred according to the invention, its constituent by weight hundred
Divide includes than meter：
Glycine 38%, citric acid 8%, zinc sulfate 3%, EDTA chelated irons 5%, boric acid 5%, EDTA Chelated Manganeses 8%, one
Brochanite 3% and water 30%.
Its preparation method is as follows：
1) glycine 38% and citric acid 8% are dissolved in 60 DEG C of water successively, that is, obtain the liquid fertilizer containing amino acid；
2) by the liquid fertilizer obtained above containing amino acid successively with zinc sulfate 3%, EDTA chelated irons 5%, boric acid
5%th, EDTA Chelated Manganeses 8% and the mixed dissolution of copper sulfate monohydrate 3%, produce a kind of liquid containing Chelates of Amino Acids And Trace Elements
Fertilizer.
Liquid fertilizer containing Chelates of Amino Acids And Trace Elements is applied to weak seedling phase of grape, fruit expanding period, crop life
The obstacle phase is managed, water-soluble fertilizer is diluted after 1000~1500 times, the quality of this season grape is significantly improved, increases by 15 pols.
The positive achievement that the present invention is obtained is：
1st, amino acid and trace element are all nutriments necessary to plant growth, while both can chelate to form stabilization
Chelate, in use, the effect of fertilizer slowly discharges, and crop is fully absorbed nutrient, so as to improve the profit of fertilizer
With rate.
2nd, organic acid can adjust soil acidity or alkalinity, increase soil permeability, so as to increase suction of the crop root to fertilizer
Adduction, improves the utilization rate of fertilizer.
In summary, the present invention provides a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, by amino acid, micro-
Rational proportion relation between secondary element and organic acid, so as to improve the utilization rate of fertilizer.
Embodiment
In order that those skilled in the art more fully understands technical scheme, with reference to specific embodiment pair
The present invention is described in further detail.
More than 90% nitrogen is present in organic form in surface soil layer, and amino acid is that main in soil have
Machine nitrogen compound, accounts for the 15%-60% of total soil nitrogen.Meanwhile, plant can absorb amino acid, and Liu Qingcheng etc. has found amino acid
It can directly be absorbed by celery cauline leaf, be permitted the use such as yulan15N marked glycines and leucine, it was demonstrated that amino acid molecular can be directly entered
In plant.Schiller etc. has found that a kind of plant for being grown on Namibia can absorb amino acid conduct when lacking inorganic nitrogen-sourced
Nitrogen source, and main absorption glycine and serine.Studied according to Zhang Fudao etc., into internal glycine not only by turning amino but also passing through
Cross deaminizating and other processes and form various amino acid, while also passing through tricarboxylic acid cycle, glycolysis and other metabolic pathways
The products such as organic acid, sugar are formed, the part of the plants such as protein is finally translated into.
Chen Guilin and high embroidery are auspicious to have studied different groups that the 12d before harvesting uses glycine, isoleucine and proline respectively
Close and urea substitutes influence of 20% nitrate nitrogen to water planting Chinese cabbage and Nitrate Content in Lettuce and quality.As a result show,
It is best to Chinese cabbage and Nitrate Content in Lettuce reducing effect with glycine.Meanwhile, amino acid treatment also improves two kinds
Vegetable leaf soluble protein and sugar matter content, and significantly increase leaf total nitrogen amount.After amino acid replacement nitrate nitrogen, enhance
Chinese cabbage Nitrate Reductase Activity In The Leaves, but weaken romaine lettuce Nitrate Reductase Activity In The Leaves.Amino acid and urea are all reduced
Nitrate content in Chinese cabbage and romaine lettuce body, and to Chinese cabbage, amino acid is close with urea effect, but to life
Dish, amino acid is more more effective than urea, and amino acid moiety, which substitutes nitrate nitrogen, can not only significantly reduce nitrate in two kinds of vegetables bodies
Content, and can be with improving quality.
Though trace element is few in crop in-vivo content, it plays vital effect to growing for plant, is
The part of enzyme or coenzyme in plant, is that crop growth is indispensable and can not phase with very strong selectivity
Trans-substitution.Effect of the iron to plant growth：Iron is the cytochromes and non-blood in photosynthesis, biological nitrogen fixation and respiration
The composition of red pigment ferritin.Iron plays Electron Transfer in the oxidation-reduction process in terms of these metabolism.Due to chloroplaset
The synthesis of some chlorophyll-protein complexes need iron, so, minus green between blade vein occurs during iron deficiency.Manganese is given birth to crop
Long effect：Crop mainly absorbs manganese ion, and manganese ion is many enzyme (such as dehydrogenase, decarboxylase, kinases, oxidizing ferment in cell
And peroxidase) activator, especially influence glycolysis and tricarboxylic acid cycle.Manganese makes photosynthetic reclaimed water be cracked into oxygen, during manganese deficiency,
Minus green between vein, with the generation of small necrosis point.Effect of the boron to plant growth：Boron and mannitol, mannosan, poly sweet dew
Uronic acid and other cell wall constituents composition complex, these complexs are the constituents of cell membrane hemicellulose.While boron
Also compare in the stem apex for concentrating on crop, the tip of a root, blade and floral organ, the elongation of pollen germination and pollen tube can be promoted, thus
Crop, which is fertilized, the influence of mystery.
Effect of the copper to plant growth：Copper is the composition of some oxidizing ferment, can influence oxidation-reduction process.When lacking copper,
Leaf is black green, wherein there is downright bad point, first from tender leaf blade tip, after expand to leaf base along leaf margin, leaf can also roll up wrinkle or deformity.Lack copper
Exaggerate, leaf comes off.Effect of the zinc to plant growth：Be alcohol dehydrogenase, glutamte dehydrogenase and carbonic anhydrase etc. composition into
/ mono-.Zinc-deficiency crop loses the ability of synthesis tryptophan, and tryptophan is the predecessor of heteroauxin, therefore, zinc-deficiency crop
Indoleacetic acid content is low.Zinc is the necessary element of chlorophyll plant.When zinc is not enough, base of the plant internode is short, lotus plexi.Meanwhile,
Amino acid can form stable chelate with trace element chelated, and during the use of fertilizer, the chelate can be by fertilizer
Effect slowly release, so as to improve the utilization rate of fertilizer.
Aluminium content in the earth's crust is only second to oxygen and silicon, is the most metallic element of content, takes up an area the 7.45% of shell gross weight,
It is also the essential element for constituting soil inorganic mineral.Under normal circumstances, the aluminium in soil is with aluminium silicate mineral and oxide etc.
Solidify form to exist.When soil is acidified, aluminium can be changed into soluble status and discharge into the soil liquid, make Aluminium in Soil
Activity increase.Activated aluminum has bad influence to the vegetative activity of plant.The murder by poisoning of aluminium is limitation crop life on acid soil
Long topmost factor of influence.Traditionally, people often use the agronomic measures such as liming and fertilizer to be improved to improve
The pH of soil reduces the activity of aluminium.This measure not only needs to put into substantial amounts of human and material resources, and chronic administration can also destroy soil
The biological effectiveness of the trace element such as Zn, Fe in earth structure, reduction soil.Found by the aluminum tolerance mechanism for understanding plant, outside
In portion's Rejection mechanism, the secretion of organic acid is the most important aluminum tolerance mechanism of plant.Kochian etc. summarizes organic acid secretion in aluminium
Importance in repulsion：Aluminium patience is associated with aluminium activation organic acid secretion；Exogenous Organic Acids are added in aluminum solutions to be alleviated
The aluminium toxicity of aluminium sensitive varieties；The compound of aluminium and organic acid can not carry out transmembrane transport, absolutely prove organic acid to crop
The importance of growth.Meanwhile, it is citric acid, oxalic acid or humic acid in the preferred organic acid of the application, preferred organic acid is
Citric acid.Reason is：Containing three carboxyl functional groups in citric acid, it is produced after hydrolyzing, and hydrogen ion is more, and acidity is stronger.
The technical scheme that the present invention is provided is a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, its constituent
Include by weight percentage：
Amino acid 30-45%, trace element 15-25%, organic acid 5-20% and surplus water.
Wherein, it is preferred that a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, its constituent is by weight
Percentages include：
Amino acid 35-40%, trace element 20-25%, organic acid 5-10% and surplus water.
Wherein, the amino acid includes glycine, proline, lysine, alanine, arginine, leucine or cystine
In one or more, it is preferred that the amino acid include glycine, proline, lysine or alanine in one kind or many
Kind.Wherein, the trace element includes Zn-ef ficiency, ferro element, boron element, molybdenum element, cobalt element, manganese element, copper or selenium
One or more in element, it is preferred that the trace element includes Zn-ef ficiency, ferro element, boron element, manganese element or copper
In one or more.Wherein, the micro- Zn-ef ficiency includes zinc sulfate, zinc chloride, basic zinc carbonate, EDTA chelatings
One or more in zinc, zinc sulphide or trbasic zinc phosphate；The micro- ferro element includes ferric sulfate, EDTA chelated irons, a water
Close the one or more in ferrous ammonium phosphate, fulvic acid diamines iron or iron ammonium sulfate；The micro- boron element includes boron
One or more in acid, boron magnesium-phosphorus fertilizer, borax, boric magnesium fertilizer or boron mud；The micro- manganese element includes manganese sulfate, carbonic acid
One or more in manganese or EDTA Chelated Manganeses；The micro- copper includes cupric sulfate pentahydrate, copper sulfate monohydrate, oxidation
One or more in cuprous, EDTA chelated coppers or basic copper carbonate, it is preferred that the micro- Zn-ef ficiency includes sulfuric acid
One or more in zinc, zinc chloride, EDTA chelated zincs or zinc sulphide；The micro- ferro element includes ferric sulfate, EDTA
One or more in chelated iron or iron ammonium sulfate；The micro- boron element includes one in boric acid, borax or boron mud
Plant or a variety of；The micro- manganese element includes the one or more in manganese sulfate or EDTA Chelated Manganeses；The trace element
Copper includes the one or more in cupric sulfate pentahydrate, copper sulfate monohydrate, cuprous oxide or EDTA chelated coppers.Wherein, it is described
Organic acid includes the one or more in sulfamic acid, citric acid, humic acid or oxalic acid, it is preferred that the organic acid includes lemon
One or more in lemon acid, humic acid or oxalic acid.
A kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements of the present invention, preparation method comprises the following steps：
1) amino acid and organic acid are dissolved in 55-65 DEG C of water successively by weight percentage, that is, obtain the liquid containing amino acid
Body fertilizer；
2) by the liquid fertilizer obtained above containing amino acid and micro- mixed dissolution, produce a kind of micro- containing amino acid
The liquid fertilizer of secondary element chelate.
Wherein, it is preferred that it is described be dissolved in 55-60 DEG C under conditions of carry out.
The commercially available gained of reagent and raw material used in the present invention.
Below in conjunction with embodiments of the invention, technical scheme is clearly and completely described, it is clear that
Described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based on the implementation in the present invention
Example, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made is belonged to
The scope of protection of the invention.
Embodiment one：
A kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, its constituent includes by weight percentage：
Glycine 35%, zinc sulfate 5%, EDTA chelated irons 8%, boric acid 3%, EDTA Chelated Manganeses 2%, copper sulfate monohydrate
5% and water 42%.Its preparation method is as follows：
1) glycine 35% is dissolved in 60 DEG C of water, that is, obtains the liquid fertilizer containing amino acid；
2) by the liquid fertilizer obtained above containing amino acid successively with zinc sulfate 5%, EDTA chelated irons 8%, boric acid
3%th, EDTA Chelated Manganeses 2% and the mixed dissolution of copper sulfate monohydrate 5%, produce a kind of liquid containing Chelates of Amino Acids And Trace Elements
Fertilizer.
By the method for application in embodiment 9, the liquid fertilizer containing Chelates of Amino Acids And Trace Elements in embodiment 1 is applied
For grape, the quality of this season grape is significantly improved, and increases by 1 pol.
Embodiment two：
A kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, its constituent includes by weight percentage：
Citric acid 30%, zinc sulfate 8%, EDTA chelated irons 10%, boric acid 2%, EDTA Chelated Manganeses 8%, copper sulfate monohydrate
10% and water 32%.
It is consistent described in preparation method be the same as Example 1.
By the method for application in embodiment 9, the liquid fertilizer containing Chelates of Amino Acids And Trace Elements in embodiment 2 is applied
For grape, the quality of this season grape is significantly improved, and increases by 0.5 pol.
Embodiment three：
A kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, its constituent includes by weight percentage：
Citric acid 25%, glycine 40% and water 35%.
It is consistent described in preparation method be the same as Example 1.
By the method for application in embodiment 9, the liquid fertilizer containing Chelates of Amino Acids And Trace Elements in embodiment 3 is applied
For grape, the quality of this season grape is significantly improved, and increases by 0.2 pol.
Example IV：
A kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, its constituent includes by weight percentage：
Glycine 35%, citric acid 5%, zinc sulfate 5%, EDTA chelated irons 8%, boric acid 3%, EDTA Chelated Manganeses 2%, one
Brochanite 5% and water 37%.
It is consistent described in preparation method be the same as Example 1.
By the method for application in embodiment 9, the liquid fertilizer containing Chelates of Amino Acids And Trace Elements in embodiment 4 is applied
For grape, the quality of this season grape is significantly improved, and increases by 10 pols.
Embodiment five：
A kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, its constituent includes by weight percentage：
Glycine 38%, citric acid 8%, zinc sulfate 3%, EDTA chelated irons 5%, boric acid 5%, EDTA Chelated Manganeses 8%, one
Brochanite 3% and water 30%.
It is consistent described in preparation method be the same as Example 1.
By the method for application in embodiment 9, the liquid fertilizer containing Chelates of Amino Acids And Trace Elements in embodiment 5 is applied
For grape, the quality of this season grape is significantly improved, and increases by 15 pols.
Embodiment six：
A kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, its constituent includes by weight percentage：
Proline 3 8%, oxalic acid 8%, zinc sulphide 3%, iron ammonium sulfate 5%, borax 5%, manganese sulfate 8%, five water sulfuric acid
Copper 3% and water 30%.
It is consistent described in preparation method be the same as Example 1.
By the method for application in embodiment 9, the liquid fertilizer containing Chelates of Amino Acids And Trace Elements in embodiment 6 is applied
For grape, the quality of this season grape is significantly improved, and increases by 10 pols.
Embodiment seven：
A kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, its constituent includes by weight percentage：
Lysine 38%, humic acid 8%, zinc chloride 3%, ferric sulfate 5%, boron mud 5%, EDTA Chelated Manganeses 8%, EDTA chelas
Close copper 3% and water 30%.
It is consistent described in preparation method be the same as Example 1.
By the method for application in embodiment 9, the liquid fertilizer containing Chelates of Amino Acids And Trace Elements in embodiment 7 is applied
For grape, the quality of this season grape is significantly improved, and increases by 12 pols.
Embodiment eight：
A kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, its constituent includes by weight percentage：
Glycine 38%, citric acid 8%, zinc sulfate 3%, EDTA chelated irons 5%, boric acid 5%, EDTA Chelated Manganeses 8%, one
Brochanite 3% and water 30%.Its preparation method is as follows：
1) glycine 38% and citric acid 8% are dissolved in 55 DEG C of water successively, that is, obtain the liquid fertilizer containing amino acid；
2) by the liquid fertilizer obtained above containing amino acid successively with zinc sulfate 3%, EDTA chelated irons 5%, boric acid
5%th, EDTA Chelated Manganeses 8% and the mixed dissolution of copper sulfate monohydrate 3%, produce a kind of liquid containing Chelates of Amino Acids And Trace Elements
Fertilizer.
By the method for application in embodiment 9, the liquid fertilizer containing Chelates of Amino Acids And Trace Elements in embodiment 8 is applied
For grape, the quality of this season grape is significantly improved, and increases by 8 pols.
Embodiment nine：
The method of application of the liquid fertilizer containing Chelates of Amino Acids And Trace Elements of the present invention：Amino-acid trace element will be contained
In chelate liquid fertilizer application to the growth of grape, in crop weak seedling phase, fruit expanding period, plant physiology obstacle phase, by water
Molten fertilizer is diluted after 1000~1500 times, carries out foliage-spray.
It the above is only the preferred embodiment of the present invention, it is noted that above-mentioned preferred embodiment is not construed as pair
The limitation of the present invention, protection scope of the present invention should be defined by claim limited range.For the art
For those of ordinary skill, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, these change
Enter and retouch and also should be regarded as protection scope of the present invention.
Claims (10)
1. a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements, it is characterised in that its constituent is by weight percentage
Meter includes：
Amino acid 30-45%, trace element 15-25%, organic acid 5-20% and surplus water.
2. a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements according to claim 1, it is characterised in that its group
Include by weight percentage into composition：
Amino acid 35-40%, trace element 20-25%, organic acid 5-10% and surplus water.
3. a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements according to claim 1, it is characterised in that described
Amino acid includes the one or more in glycine, proline, lysine, alanine, arginine, leucine or cystine.
4. a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements according to claim 1, it is characterised in that described
Trace element includes one kind in Zn-ef ficiency, ferro element, boron element, molybdenum element, cobalt element, manganese element, copper or selenium element
Or it is a variety of.
5. a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements according to claim 4, it is characterised in that described
Trace element includes the one or more in Zn-ef ficiency, ferro element, boron element, manganese element or copper.
6. a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements according to claim 5, it is characterised in that described
Micro- Zn-ef ficiency includes one kind in zinc sulfate, zinc chloride, basic zinc carbonate, EDTA chelated zincs, zinc sulphide or trbasic zinc phosphate
Or it is a variety of；The micro- ferro element includes ferric sulfate, EDTA chelated irons, a hypophosphite monohydrate ferrous ammonium, fulvic acid diamines iron
Or the one or more in iron ammonium sulfate；The micro- boron element include boric acid, boron magnesium-phosphorus fertilizer, borax, boric magnesium fertilizer or
One or more in boron mud；The micro- manganese element include manganese sulfate, manganese carbonate or one kind in EDTA Chelated Manganeses or
It is a variety of；The micro- copper includes cupric sulfate pentahydrate, copper sulfate monohydrate, cuprous oxide, EDTA chelated coppers or alkali formula carbon
One or more in sour copper.
7. a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements according to claim 1, it is characterised in that described
Organic acid includes the one or more in sulfamic acid, citric acid, humic acid or oxalic acid.
8. a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements according to claim 1, it is characterised in that prepare
Method comprises the following steps：
1) by amino acid, organic acid and water mixed dissolution, the liquid fertilizer containing amino acid is obtained；
2) by the liquid fertilizer obtained above containing amino acid and micro- mixed dissolution, a kind of micro member containing amino acid is produced
The liquid fertilizer of plain chelate.
9. a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements according to claim 8, it is characterised in that step
1) configuration process of the liquid fertilizer containing amino acid is as follows described in：Amino acid and organic acid are dissolved in successively by weight percentage
In water, that is, obtain the liquid fertilizer containing amino acid.
10. a kind of liquid fertilizer containing Chelates of Amino Acids And Trace Elements according to claim 9, it is characterised in that institute
State and carried out under conditions of being dissolved in 55-65 DEG C.
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| CN108264376A (en) * | 2018-02-05 | 2018-07-10 | 砀山县绿源生态肥料有限公司 | A kind of agricultural amino acid medicine fertilizer |
| CN109369250A (en) * | 2018-11-09 | 2019-02-22 | 中国农业科学院农业资源与农业区划研究所 | A kind of medium nutrient element magnesium chelate carrier and use thereof |
| CN109369254A (en) * | 2018-11-09 | 2019-02-22 | 中国农业科学院农业资源与农业区划研究所 | A kind of micronutrient element chelating carrier and use thereof |
| CN109369252A (en) * | 2018-11-09 | 2019-02-22 | 中国农业科学院农业资源与农业区划研究所 | A kind of micronutrient copper chelate carrier and use thereof |
| CN110862286A (en) * | 2019-12-30 | 2020-03-06 | 山东多芬农业有限公司 | A kind of medium and trace element and its preparation and use method |
| CN112409072A (en) * | 2020-11-25 | 2021-02-26 | 扬州大学 | A kind of preparation method of selenium-enriched substrate fertilizer for rice seedling raising |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108264376A (en) * | 2018-02-05 | 2018-07-10 | 砀山县绿源生态肥料有限公司 | A kind of agricultural amino acid medicine fertilizer |
| CN109369250A (en) * | 2018-11-09 | 2019-02-22 | 中国农业科学院农业资源与农业区划研究所 | A kind of medium nutrient element magnesium chelate carrier and use thereof |
| CN109369254A (en) * | 2018-11-09 | 2019-02-22 | 中国农业科学院农业资源与农业区划研究所 | A kind of micronutrient element chelating carrier and use thereof |
| CN109369252A (en) * | 2018-11-09 | 2019-02-22 | 中国农业科学院农业资源与农业区划研究所 | A kind of micronutrient copper chelate carrier and use thereof |
| CN110862286A (en) * | 2019-12-30 | 2020-03-06 | 山东多芬农业有限公司 | A kind of medium and trace element and its preparation and use method |
| CN112409072A (en) * | 2020-11-25 | 2021-02-26 | 扬州大学 | A kind of preparation method of selenium-enriched substrate fertilizer for rice seedling raising |
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