CN106977848A - A kind of automotive line is material modified and preparation method thereof with PVC - Google Patents
A kind of automotive line is material modified and preparation method thereof with PVC Download PDFInfo
- Publication number
- CN106977848A CN106977848A CN201710253942.4A CN201710253942A CN106977848A CN 106977848 A CN106977848 A CN 106977848A CN 201710253942 A CN201710253942 A CN 201710253942A CN 106977848 A CN106977848 A CN 106977848A
- Authority
- CN
- China
- Prior art keywords
- parts
- pvc
- mixture
- material modified
- automotive line
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 78
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 95
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 94
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 86
- 239000003607 modifier Substances 0.000 claims abstract description 33
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 32
- 239000002994 raw material Substances 0.000 claims abstract description 30
- 229920005989 resin Polymers 0.000 claims abstract description 28
- 239000011347 resin Substances 0.000 claims abstract description 28
- 239000004014 plasticizer Substances 0.000 claims abstract description 24
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims abstract description 20
- 238000005299 abrasion Methods 0.000 claims abstract description 17
- 238000009413 insulation Methods 0.000 claims abstract description 14
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims description 171
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 42
- 229920001897 terpolymer Polymers 0.000 claims description 20
- 239000002245 particle Substances 0.000 claims description 16
- 229920000459 Nitrile rubber Polymers 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 14
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 14
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 14
- 239000003963 antioxidant agent Substances 0.000 claims description 13
- 230000003078 antioxidant effect Effects 0.000 claims description 13
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 8
- 238000006116 polymerization reaction Methods 0.000 claims description 8
- 229910000077 silane Inorganic materials 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 claims description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 7
- 239000005995 Aluminium silicate Substances 0.000 claims description 7
- 244000043261 Hevea brasiliensis Species 0.000 claims description 7
- 239000005062 Polybutadiene Substances 0.000 claims description 7
- 239000004793 Polystyrene Substances 0.000 claims description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims description 7
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- 235000013312 flour Nutrition 0.000 claims description 7
- 239000011521 glass Substances 0.000 claims description 7
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 7
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 7
- 229920003052 natural elastomer Polymers 0.000 claims description 7
- 229920001194 natural rubber Polymers 0.000 claims description 7
- 238000005453 pelletization Methods 0.000 claims description 7
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 7
- 229920000728 polyester Polymers 0.000 claims description 7
- 229920002223 polystyrene Polymers 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 235000012424 soybean oil Nutrition 0.000 claims description 7
- 239000003549 soybean oil Substances 0.000 claims description 7
- 235000013311 vegetables Nutrition 0.000 claims description 7
- 239000000347 magnesium hydroxide Substances 0.000 claims description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 6
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 claims 1
- 240000008384 Capsicum annuum var. annuum Species 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 14
- 241000283984 Rodentia Species 0.000 abstract description 7
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 230000002265 prevention Effects 0.000 abstract description 5
- 230000035939 shock Effects 0.000 abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 54
- 235000010215 titanium dioxide Nutrition 0.000 description 27
- -1 dicarboxylic acids salt Chemical class 0.000 description 21
- 239000003063 flame retardant Substances 0.000 description 20
- 239000000843 powder Substances 0.000 description 18
- 239000004408 titanium dioxide Substances 0.000 description 15
- 239000004743 Polypropylene Substances 0.000 description 14
- 229920001155 polypropylene Polymers 0.000 description 14
- 230000002421 anti-septic effect Effects 0.000 description 13
- 238000013329 compounding Methods 0.000 description 13
- 239000000049 pigment Substances 0.000 description 13
- 229910000410 antimony oxide Inorganic materials 0.000 description 8
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 8
- 241000894007 species Species 0.000 description 8
- 229910021536 Zeolite Inorganic materials 0.000 description 7
- 229910000152 cobalt phosphate Inorganic materials 0.000 description 7
- ZBDSFTZNNQNSQM-UHFFFAOYSA-H cobalt(2+);diphosphate Chemical compound [Co+2].[Co+2].[Co+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O ZBDSFTZNNQNSQM-UHFFFAOYSA-H 0.000 description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 7
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 7
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 7
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 7
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 7
- 239000004332 silver Substances 0.000 description 7
- 229910052709 silver Inorganic materials 0.000 description 7
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 7
- 239000010457 zeolite Substances 0.000 description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 description 6
- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 description 6
- 229960002504 capsaicin Drugs 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- 239000000945 filler Substances 0.000 description 4
- 238000005452 bending Methods 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 206010054949 Metaplasia Diseases 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000015689 metaplastic ossification Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000005447 environmental material Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to PVC material technical field, and in particular to a kind of automotive line is material modified and preparation method thereof with PVC, and the automotive line includes the raw material of following parts by weight with PVC is material modified：80 120 parts of polyvinyl chloride resin, 40 80 parts of polymeric plasticizer, cold-resistant 8 12 parts of modifying agent, 37 parts of precipitated calcium carbonate, 37 parts of modifying agent of insulation, 13 parts of heat-proof modifier, 24 parts of fireproof agent, 0.5 1.5 parts of Ratproof agent, 0.5 1.5 parts of abrasion resistance modifier, 1.1 1.5 parts of age resistor.The automotive line of the present invention has preferably cold-resistant, heat-resisting, insulation, anti-wear performance with PVC is material modified, and fire prevention, protection against rodents and anti-aging effect are good, environmental protection, and weather resistance is excellent, intensity is high, excellent shock resistance, good flame retardation effect, processing characteristics is excellent, excellent combination property.
Description
Technical field
The present invention relates to PVC material technical field, and in particular to a kind of automotive line is with PVC is material modified and its preparation side
Method.
Background technology
Polyvinyl chloride（PVC）One of earliest industrialization, widely used general-purpose thermoplastic plastic, it have light weight,
The advantages of intensity height, insulation, fire-retardant, corrosion-resistant, high comprehensive performance, cheap and extensive raw material sources；But there is also
Following shortcoming：1st, poor toughness, easily embrittlement when being hit, therefore cannot act as structural material, in addition, the fragility of polyvinyl chloride by
Temperature influence is very big, and general PVC product uses lower limit to be -15 DEG C, and the use lower limit of flexible PVC is -30 DEG C；2nd, heat endurance
Difference, it begins to decomposite HCl at 100 DEG C, decomposes rapider during higher than 150 DEG C, and PVC melting temperature is about 210
℃；3rd, PVC viscosity is high, mobility extreme difference, and it is limited to a certain extent and is used.People are frequently with addition filler, bullet
The methods such as property body, plasticizer, heat stabilizer, processing aid, heat-proof modifier and flow ability modifying agent improve PVC performance.
But existing automotive line PVC material has cold-resistant, heat-resisting, insulation, wear-resisting, fire prevention, protection against rodents and anti ageing property
The defect such as poor, limits it and uses to a certain extent.
The content of the invention
In order to overcome shortcoming and defect present in prior art, it is an object of the invention to provide a kind of automotive line use
PVC is material modified, and the automotive line has preferably cold-resistant, heat-resisting, insulation, anti-wear performance, fire prevention, protection against rodents with PVC is material modified
It is good with anti-aging effect, environmental protection, and weather resistance is excellent, intensity is high, excellent shock resistance, good flame retardation effect, processing characteristics
It is excellent, excellent combination property.
Another object of the present invention is to provide the preparation method that a kind of automotive line PVC is material modified, the preparation method
Step is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low, up to the production of technical scale metaplasia.
The purpose of the present invention is achieved through the following technical solutions：A kind of automotive line is material modified with PVC, including following weight
The raw material of part：
80-120 parts of polyvinyl chloride resin
40-80 parts of polymeric plasticizer
Cold-resistant 8-12 parts of modifying agent
3-7 parts of precipitated calcium carbonate
Insulate 3-7 parts of modifying agent
1-3 parts of heat-proof modifier
2-4 parts of fireproof agent
0.5-1.5 parts of Ratproof agent
0.5-1.5 parts of abrasion resistance modifier
1.1-1.5 parts of age resistor.
It is preferred that, the polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization in 1000-1100.The present invention is by using upper
Polyvinyl chloride resin is stated, obtained PVC is material modified to have light weight, intensity height, insulation, fire-retardant, corrosion-resistant, high comprehensive performance etc.
Advantage.
The polymeric plasticizer is by epoxidized soybean oil, synthesizes vegetable esters and polyester plasticizer with weight and compare 1-2:0.8-
1.2:The mixture of 1 composition.Species, compounding and weight proportion of the invention by strictly controlling plasticizer, can reduce plastics
The active force of molecule interchain, making the glass transition temperature, flowing temperature and the fusing point of contained crystallite of plastics reduces, and can improve resin
Plasticity, make that product is soft, resistance to low temperature is good.
It is preferred that, the cold-resistant modifying agent is with weight to compare 2-4 by nitrile rubber and butadiene rubber：The mixture of 1 composition.
The present invention by strictly controlling the species of cold-resistant modifying agent, compounding and matching, obtained PVC is material modified have compared with
Good cold tolerance and low temperature impact properties.
The precipitated calcium carbonate is particle diameter in 10-100nm and by the treated precipitated calcium carbonate of silane coupler.
The particle diameter of filler is smaller, and the tensile strength and impact strength to packing material are more beneficial, and the present invention is by selecting
Precipitated calcium carbonate is as filler and controls its particle diameter in 10-100nm, and its crystal structure and Electronic Structure are become
Change, generate quantum size effect, small-size effect, skin effect and macroscopic quantum effect that conventional lightweight calcium carbonate does not have
Should, therefore with good toughened and reinforced effect, it, which is added, can improve bending strength and bending bullet in the edge band of the present invention
The stability of property modulus and heat distortion temperature and size；Filler is to play its effect and control with the good compatibility of resin
The key of addition, the present invention can carry precipitated calcium carbonate and PVC using the precipitated calcium carbonate treated by silane coupler
The compatibility of resin, so as to improve the intensity of material.
It is preferred that, the insulation modifying agent is with weight ratio 1 by kaolin, silica flour and glass microballoon:1.5-2.5:2-4
The mixture of composition.
The present invention by strictly control insulate modifying agent species, compounding and match, obtained PVC it is material modified have compared with
Good insulating properties.
It is preferred that, the heat-proof modifier be by N-phenylmaleimide/fine terpolymer of styrene/propylene, α-
Methyl styrene/styrene/acrylonitrile terpolymer and styrene/propylene it is fine/maleic anhydride terpolymer is with weight ratio
1:0.8-1.2:1.4-2.2 the mixture of composition.
The present invention by strictly control heat-proof modifier species, compounding and match, obtained PVC it is material modified have compared with
Good heat resistance.
It is preferred that, the fireproof agent is with weight ratio by brominated Polystyrene, melamine phosphate and magnesium hydroxide
1.4-2.2:1:The mixture of 0.8-1.2 compositions.
The present invention is by strictly controlling the species of fireproof agent, compounding and proportioning, and obtained PVC is material modified to be had preferably
Flameproof effect.
It is preferred that, the Ratproof agent is by capsaicine, n- Vanillyl pelargonic amide and o- isopropyl phenyl-N- methylaminos
Formic acid esters compares 0.8-1.2 with weight:1：1.5-2.5 the mixture of composition.
The present invention is by strictly controlling the species of Ratproof agent, compounding and proportioning, and obtained PVC is material modified to be had preferably
Protection against rodents effect.
It is preferred that, the abrasion resistance modifier is with weight ratio 1 by butadiene-styrene rubber and natural rubber:1.8-2.6 composition is mixed
Compound.
The present invention can improve material modified resistance to of PVC by strictly controlling the species of abrasion resistance modifier, compounding and matching
Grind performance.
It is preferred that, the age resistor is with weight to compare 0.8-1.2 by antioxidant A, antioxidant A W and anti-aging agent RD:1:1.6-
The mixture of 2.4 compositions.
The present invention is by strictly controlling the species of age resistor, compounding and proportioning, and obtained PVC is material modified to be had preferably
Anti-aging effect.
The automotive line is material modified also including cold-resistant toughened dose 2-6 parts, 1-3 parts of compatilizer and antiseptic 0.5- with PVC
1.5 part.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
1.2-1.8 the mixture of composition.
The present invention is used as cold-resistant toughened dose by using amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater
Compounding use, and control its weight ratio to be 1：1.2-1.8 so that material in -20 DEG C of low temperature toughening effect substantially, more than normal temperature
When impact strength, while rigidly being significantly improved under normal temperature.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.4-2.2 group
Into mixture.
The present invention by using maleic anhydride inoculated polypropylene and styrene-grafted polypropylene as compatilizer compounding use,
And control its weight ratio to be 1：1.4-2.2, can improve inorganic filler and organic resin compatibility, improve stretching, the impact of product
Intensity, realizes high filling, reduces resin demand, improve rheological performance, improve surface smoothness.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate and compare 1.5-2.5 with weight：The mixture of 1 composition.
The present invention is by using zeolite with carrying silver and carries silver-colored cobalt phosphate as antiseptic compounding use, and controls its weight ratio to be
1.5-2.5：1 so that not only tinting strength, tinting power height, good dispersion, spinnability are good for material, also with preferable sterilization, fungistatic effect.
The automotive line also includes 1-5 parts of fire retardant, 0.5-1.5 parts of slipping agent and pigment powder 0.5- with PVC is material modified
1.5 part.
The fire retardant is with weight to compare 0.5-1.5 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
Antimony oxide and line borate are inorganic environment-friendly fire retardant, and the present invention is by using antimony oxide and Firebrake ZB
As fire retardant compounding use, and its weight ratio is controlled to be 0.5-1.5：1, good flame retardant effect can be reached, moreover it is possible to improve
The processing characteristics and mechanical performance of material.
The slipping agent is with weight to compare 1.5-2.5 by erucyl amide, oleamide and N, N'- ethylene bis stearamide：
0.8-1.2：The mixture of 1 composition.
The present invention is by using erucyl amide, oleamide and N, N'- ethylene bis stearamide are as slipping agent and control
Its weight ratio is 1.5-2.5：0.8-1.2：1, mechanical resistant stirring capacity and fingerprinting stress, finished product good forming effect, table can be strengthened
Face is bright and clean, moreover it is possible to strengthen the extensibility of finished product, easy-to-draw not easily broken.
The pigment powder is titanium dioxide of the particle diameter at 1-5 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide
Titanium dioxide compares 1 with weight：1.5-2.5 the mixture of composition.
The present invention using particle diameter in 1-5 μm of titanium dioxide as pigment powder, further using rutile type titanium white and sharp
Titanium-type titanium dioxide compounding use, and control its weight ratio to be 1：1.5-2.5, with superior whiteness, tinting strength, tinting power, covering power, resistance to
Hou Xing, heat resistance and chemical stability, particularly no toxicity.
A kind of automotive line is comprised the following steps with preparation method material modified PVC：
（1）Above-mentioned raw materials are weighed by the parts by weight of constitutive material, are mixed；
（2）Mixed raw material is put into high speed blender, 15-25min is stirred at a temperature of 100-140 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, automotive line is made material modified with PVC；It is described double
The extruder temperature of screw extruder is：One 138-160 DEG C of area's temperature, two 135-160 DEG C of area's temperature, three 135-155 DEG C of area's temperature,
130-148 DEG C of the area's temperature of four area temperature 132-150 DEG CHe five.
The beneficial effects of the present invention are：The present invention automotive line with PVC it is material modified have preferably it is cold-resistant, heat-resisting,
Insulation, anti-wear performance, fire prevention, protection against rodents and anti-aging effect are good, environmental protection, and weather resistance is excellent, and intensity is high, and shock resistance is excellent
Different, good flame retardation effect, processing characteristics is excellent, excellent combination property.
The present invention is using the automotive line material modified smooth in appearance of PVC made from a variety of high-environmental materials, without adjacent benzene two
Formates, without polycyclic aromatic hydrocarbon, without free phenol, not halogen-containing flame retardant, no boron compound, environmental protection better than European Union ROHS,
The international standards such as DEHP, ATBC, can be widely applied to the industrial circles such as automobile.
The preparation method step of the present invention is simple, convenient operation and control, steady quality, and production efficiency is high, and production cost is low,
Up to the production of technical scale metaplasia.
Embodiment
For the ease of the understanding of those skilled in the art, with reference to embodiment, the present invention is further illustrated, real
The content that the mode of applying is referred to not limitation of the invention.
Embodiment 1
A kind of automotive line is material modified with PVC, includes the raw material of following parts by weight：
80 parts of polyvinyl chloride resin
40 parts of polymeric plasticizer
Cold-resistant 8 parts of modifying agent
3 parts of precipitated calcium carbonate
Insulate 3 parts of modifying agent
1 part of heat-proof modifier
2 parts of fireproof agent
0.5 part of Ratproof agent
0.5 part of abrasion resistance modifier
1.1 parts of age resistor.
The polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization 1000；The polymeric plasticizer is by epoxy soybean
Oil, synthesis vegetable esters and polyester plasticizer are with weight ratio 1:0.8:The mixture of 1 composition.
The cold-resistant modifying agent is with weight ratio 2 by nitrile rubber and butadiene rubber：The mixture of 1 composition；The lightweight
Calcium carbonate is particle diameter in 10nm and by the treated precipitated calcium carbonate of silane coupler.
The insulation modifying agent is with weight ratio 1 by kaolin, silica flour and glass microballoon:1.5:The mixture of 2 compositions.
The heat-proof modifier is by N-phenylmaleimide/fine terpolymer of styrene/propylene, Alpha-Methyl benzene second
Alkene/styrene/acrylonitrile terpolymer and styrene/propylene it is fine/maleic anhydride terpolymer is with weight ratio 1:0.8:1.4
The mixture of composition.
The fireproof agent is with weight ratio 1.4 by brominated Polystyrene, melamine phosphate and magnesium hydroxide:1:0.8
The mixture of composition.
The Ratproof agent is by capsaicine, n- Vanillyl pelargonic amide and o- isopropyl phenyl-N- methyl carbamates
Compare 0.8 with weight:1：The mixture of 1.5 compositions.
The abrasion resistance modifier is with weight ratio 1 by butadiene-styrene rubber and natural rubber:The mixture of 1.8 compositions.
The age resistor is with weight ratio 0.8 by antioxidant A, antioxidant A W and anti-aging agent RD:1:1.6 the mixing of composition
Thing.
The automotive line is material modified also including 0.5 part of cold-resistant toughened dose 2 parts, 1 part of compatilizer and antiseptic with PVC.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.2 compositions.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.4 compositions
Mixture.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate with weight ratio 1.5：The mixture of 1 composition.
The automotive line also includes 0.5 part of 1 part of fire retardant, 0.5 part of slipping agent and pigment powder with PVC is material modified.
The fire retardant is with weight ratio 0.5 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is with weight to compare 1.5 by erucyl amide, oleamide and N, N'- ethylene bis stearamide：0.8：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 1 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 1.5 compositions.
A kind of automotive line is comprised the following steps with preparation method material modified PVC：
（1）Above-mentioned raw materials are weighed by the parts by weight of constitutive material, are mixed；
（2）Mixed raw material is put into high speed blender, 15min is stirred at a temperature of 100 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, automotive line is made material modified with PVC；It is described double
The extruder temperature of screw extruder is：One 138 DEG C of area's temperature, 135 DEG C of two area's temperature, 135 DEG C of three area's temperature, four area's temperature 132
130 DEG C of five area's temperature of DEG CHe.
Embodiment 2
A kind of automotive line is material modified with PVC, includes the raw material of following parts by weight：
90 parts of polyvinyl chloride resin
50 parts of polymeric plasticizer
Cold-resistant 9 parts of modifying agent
4 parts of precipitated calcium carbonate
Insulate 4 parts of modifying agent
1.5 parts of heat-proof modifier
2.5 parts of fireproof agent
0.8 part of Ratproof agent
0.8 part of abrasion resistance modifier
1.2 parts of age resistor.
The polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization 1020；The polymeric plasticizer is by epoxy soybean
Oil, synthesis vegetable esters and polyester plasticizer are with weight ratio 1.2:0.9:The mixture of 1 composition.
The cold-resistant modifying agent is with weight ratio 2.5 by nitrile rubber and butadiene rubber：The mixture of 1 composition；It is described light
Matter calcium carbonate is particle diameter in 30nm and by the treated precipitated calcium carbonate of silane coupler.
The insulation modifying agent is with weight ratio 1 by kaolin, silica flour and glass microballoon:1.8:The mixing of 2.5 compositions
Thing.
The heat-proof modifier is by N-phenylmaleimide/fine terpolymer of styrene/propylene, Alpha-Methyl benzene second
Alkene/styrene/acrylonitrile terpolymer and styrene/propylene it is fine/maleic anhydride terpolymer is with weight ratio 1:0.9:1.6
The mixture of composition.
The fireproof agent is with weight ratio 1.6 by brominated Polystyrene, melamine phosphate and magnesium hydroxide:1:0.9
The mixture of composition.
The Ratproof agent is by capsaicine, n- Vanillyl pelargonic amide and o- isopropyl phenyl-N- methyl carbamates
Compare 0.9 with weight:1：The mixture of 1.8 compositions.
The abrasion resistance modifier is with weight ratio 1 by butadiene-styrene rubber and natural rubber:The mixture of 2 compositions.
The age resistor is with weight ratio 0.9 by antioxidant A, antioxidant A W and anti-aging agent RD:1:The mixing of 1.8 compositions
Thing.
The automotive line is material modified also including 0.8 part of cold-resistant toughened dose 3 parts, 1.5 parts of compatilizer and antiseptic with PVC.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.4 compositions.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.6 compositions
Mixture.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate with weight ratio 1.8：The mixture of 1 composition.
The automotive line also includes 0.8 part of 2 parts of fire retardant, 0.8 part of slipping agent and pigment powder with PVC is material modified.
The fire retardant is with weight ratio 0.8 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is with weight to compare 1.8 by erucyl amide, oleamide and N, N'- ethylene bis stearamide：0.9：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 2 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 1.8 compositions.
A kind of automotive line is comprised the following steps with preparation method material modified PVC：
（1）Above-mentioned raw materials are weighed by the parts by weight of constitutive material, are mixed；
（2）Mixed raw material is put into high speed blender, 18min is stirred at a temperature of 110 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, automotive line is made material modified with PVC；It is described double
The extruder temperature of screw extruder is：One 144 DEG C of area's temperature, 141 DEG C of two area's temperature, 140 DEG C of three area's temperature, four area's temperature 136
135 DEG C of five area's temperature of DEG CHe.
Embodiment 3
A kind of automotive line is material modified with PVC, includes the raw material of following parts by weight：
100 parts of polyvinyl chloride resin
60 parts of polymeric plasticizer
Cold-resistant 10 parts of modifying agent
5 parts of precipitated calcium carbonate
Insulate 5 parts of modifying agent
2 parts of heat-proof modifier
6 parts of fireproof agent
1 part of Ratproof agent
1 part of abrasion resistance modifier
1.3 parts of age resistor.
The polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization 1050；The polymeric plasticizer is by epoxy soybean
Oil, synthesis vegetable esters and polyester plasticizer are with weight ratio 1.5:1:The mixture of 1 composition.
The cold-resistant modifying agent is with weight ratio 3 by nitrile rubber and butadiene rubber：The mixture of 1 composition；The lightweight
Calcium carbonate is particle diameter in 50nm and by the treated precipitated calcium carbonate of silane coupler.
The insulation modifying agent is with weight ratio 1 by kaolin, silica flour and glass microballoon:2:The mixture of 3 compositions.
The heat-proof modifier is by N-phenylmaleimide/fine terpolymer of styrene/propylene, Alpha-Methyl benzene second
Alkene/styrene/acrylonitrile terpolymer and styrene/propylene it is fine/maleic anhydride terpolymer is with weight ratio 1:1:1.8 group
Into mixture.
The fireproof agent is with weight ratio 1.8 by brominated Polystyrene, melamine phosphate and magnesium hydroxide:1:1 group
Into mixture.
The Ratproof agent is by capsaicine, n- Vanillyl pelargonic amide and o- isopropyl phenyl-N- methyl carbamates
Compare 1 with weight:1：The mixture of 2 compositions.
The abrasion resistance modifier is with weight ratio 1 by butadiene-styrene rubber and natural rubber:The mixture of 2.2 compositions.
The age resistor is with weight ratio 1 by antioxidant A, antioxidant A W and anti-aging agent RD:1:The mixture of 2 compositions.
The automotive line is material modified also including 1 part of cold-resistant toughened dose 4 parts, 2 parts of compatilizer and antiseptic with PVC.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.5 compositions.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：1.8 compositions
Mixture.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate with weight ratio 2：The mixture of 1 composition.
The automotive line also includes 1 part of 3 parts of fire retardant, 1 part of slipping agent and pigment powder with PVC is material modified.
The fire retardant is with weight ratio 1 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is with weight to compare 2 by erucyl amide, oleamide and N, N'- ethylene bis stearamide：1：1 composition
Mixture.
The pigment powder is titanium dioxide of the particle diameter at 3 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 2 compositions.
A kind of automotive line is comprised the following steps with preparation method material modified PVC：
（1）Above-mentioned raw materials are weighed by the parts by weight of constitutive material, are mixed；
（2）Mixed raw material is put into high speed blender, 20min is stirred at a temperature of 120 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, automotive line is made material modified with PVC；It is described double
The extruder temperature of screw extruder is：One 149 DEG C of area's temperature, 147 DEG C of two area's temperature, 145 DEG C of three area's temperature, four area's temperature 141
139 DEG C of five area's temperature of DEG CHe.
Embodiment 4
A kind of automotive line is material modified with PVC, includes the raw material of following parts by weight：
110 parts of polyvinyl chloride resin
70 parts of polymeric plasticizer
Cold-resistant 11 parts of modifying agent
6 parts of precipitated calcium carbonate
Insulate 6 parts of modifying agent
2.5 parts of heat-proof modifier
3.5 parts of fireproof agent
1.2 parts of Ratproof agent
1.2 parts of abrasion resistance modifier
1.4 parts of age resistor.
The polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization 1080；The polymeric plasticizer is by epoxy soybean
Oil, synthesis vegetable esters and polyester plasticizer are with weight ratio 1.8:1.1:The mixture of 1 composition.
The cold-resistant modifying agent is with weight ratio 3.5 by nitrile rubber and butadiene rubber：The mixture of 1 composition；It is described light
Matter calcium carbonate is particle diameter in 80nm and by the treated precipitated calcium carbonate of silane coupler.
The insulation modifying agent is with weight ratio 1 by kaolin, silica flour and glass microballoon:2.2:The mixing of 3.5 compositions
Thing.
The heat-proof modifier is by N-phenylmaleimide/fine terpolymer of styrene/propylene, Alpha-Methyl benzene second
Alkene/styrene/acrylonitrile terpolymer and styrene/propylene it is fine/maleic anhydride terpolymer is with weight ratio 1:1.1:2 groups
Into mixture.
The fireproof agent is with weight ratio 2 by brominated Polystyrene, melamine phosphate and magnesium hydroxide:1:1.1 group
Into mixture.
The Ratproof agent is by capsaicine, n- Vanillyl pelargonic amide and o- isopropyl phenyl-N- methyl carbamates
Compare 1.1 with weight:1：The mixture of 2.2 compositions.
The abrasion resistance modifier is with weight ratio 1 by butadiene-styrene rubber and natural rubber:The mixture of 2.4 compositions.
The age resistor is with weight ratio 1.1 by antioxidant A, antioxidant A W and anti-aging agent RD:1:The mixing of 2.2 compositions
Thing.
The automotive line is material modified also including 1.2 parts of cold-resistant toughened dose 5 parts, 2.5 parts of compatilizer and antiseptic with PVC.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.6 compositions.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：2 compositions it is mixed
Compound.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate with weight ratio 2.2：The mixture of 1 composition.
The automotive line also includes 1.2 parts of 4 parts of fire retardant, 1.2 parts of slipping agent and pigment powder with PVC is material modified.
The fire retardant is with weight ratio 1.2 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is with weight to compare 2.2 by erucyl amide, oleamide and N, N'- ethylene bis stearamide：1.1：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 4 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 2.2 compositions.
A kind of automotive line is comprised the following steps with preparation method material modified PVC：
（1）Above-mentioned raw materials are weighed by the parts by weight of constitutive material, are mixed；
（2）Mixed raw material is put into high speed blender, 22min is stirred at a temperature of 130 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, automotive line is made material modified with PVC；It is described double
The extruder temperature of screw extruder is：One 155 DEG C of area's temperature, 153 DEG C of two area's temperature, 150 DEG C of three area's temperature, four area's temperature 145
144 DEG C of five area's temperature of DEG CHe.
Embodiment 5
A kind of automotive line is material modified with PVC, includes the raw material of following parts by weight：
120 parts of polyvinyl chloride resin
80 parts of polymeric plasticizer
Cold-resistant 12 parts of modifying agent
7 parts of precipitated calcium carbonate
Insulate 7 parts of modifying agent
3 parts of heat-proof modifier
4 parts of fireproof agent
1.5 parts of Ratproof agent
1.5 parts of abrasion resistance modifier
1.5 parts of age resistor.
The polyvinyl chloride resin is SG-5 type polyvinyl chloride resin of the degree of polymerization 1100；The polymeric plasticizer is by epoxy soybean
Oil, synthesis vegetable esters and polyester plasticizer are with weight ratio 2:1.2:The mixture of 1 composition.
The cold-resistant modifying agent is with weight ratio 4 by nitrile rubber and butadiene rubber：The mixture of 1 composition；The lightweight
Calcium carbonate is particle diameter in 100nm and by the treated precipitated calcium carbonate of silane coupler.
The insulation modifying agent is with weight ratio 1 by kaolin, silica flour and glass microballoon:2.5:The mixture of 4 compositions.
The heat-proof modifier is by N-phenylmaleimide/fine terpolymer of styrene/propylene, Alpha-Methyl benzene second
Alkene/styrene/acrylonitrile terpolymer and styrene/propylene it is fine/maleic anhydride terpolymer is with weight ratio 1:1.2:2.2
The mixture of composition.
The fireproof agent is with weight ratio 2.2 by brominated Polystyrene, melamine phosphate and magnesium hydroxide:1:1.2
The mixture of composition.
The Ratproof agent is by capsaicine, n- Vanillyl pelargonic amide and o- isopropyl phenyl-N- methyl carbamates
Compare 1.2 with weight:1：The mixture of 2.5 compositions.
The abrasion resistance modifier is with weight ratio 1 by butadiene-styrene rubber and natural rubber:The mixture of 2.6 compositions.
The age resistor is with weight ratio 1.2 by antioxidant A, antioxidant A W and anti-aging agent RD:1:The mixing of 2.4 compositions
Thing.
The automotive line is material modified also including 1.5 parts of cold-resistant toughened dose 6 parts, 3 parts of compatilizer and antiseptic with PVC.
Described cold-resistant toughened dose is with weight ratio 1 by amide-type beta crystal-type nucleater and dicarboxylic acids salt beta crystal-type nucleater：
The mixture of 1.8 compositions.
The compatilizer is with weight ratio 1 by maleic anhydride inoculated polypropylene and styrene-grafted polypropylene：2.2 compositions
Mixture.
The antiseptic is by zeolite with carrying silver and carries silver-colored cobalt phosphate with weight ratio 2.5：The mixture of 1 composition.
The automotive line also includes 1.5 parts of 5 parts of fire retardant, 1.5 parts of slipping agent and pigment powder with PVC is material modified.
The fire retardant is with weight ratio 1.5 by antimony oxide and Firebrake ZB：The mixture of 1 composition.
The slipping agent is with weight to compare 2.5 by erucyl amide, oleamide and N, N'- ethylene bis stearamide：1.2：1
The mixture of composition.
The pigment powder is titanium dioxide of the particle diameter at 5 μm；The titanium dioxide is by rutile type titanium white and anatase titanium dioxide titanium
White powder compares 1 with weight：The mixture of 2.5 compositions.
A kind of automotive line is comprised the following steps with preparation method material modified PVC：
（1）Above-mentioned raw materials are weighed by the parts by weight of constitutive material, are mixed；
（2）Mixed raw material is put into high speed blender, 25min is stirred at a temperature of 140 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, automotive line is made material modified with PVC；It is described double
The extruder temperature of screw extruder is：One 160 DEG C of area's temperature, 160 DEG C of two area's temperature, 155 DEG C of three area's temperature, four area's temperature 150
148 DEG C of five area's temperature of DEG CHe.
Automotive line made from embodiment 1-5 is as shown in table 1 with the material modified mechanical and physical performances of PVC：
Table 1
| Test event | Standard value | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Tensile strength（MPa） | ≥15.0 | 33.8 | 35.9 | 37.2 | 37.6 | 34.7 |
| Bending strength（MPa） | ≥15.0 | 58.4 | 60.3 | 62.2 | 65.8 | 56.8 |
| Elongation at break（%） | ≥150 | 303 | 308 | 313 | 326 | 305 |
| Heat distortion temperature（℃） | ≥50.0 | 128.3 | 130.9 | 133.4 | 135.1 | 129.1 |
| Impact brittle temperature（℃） | ≤-20 | -35 | -35 | -40 | -40 | -35 |
| Heat-stable time at 200 DEG C（min） | ≥60 | 100 | 120 | 130 | 130 | 110 |
| Hardness/Shore D | ≥50 | 92 | 95 | 97 | 98 | 93 |
| It is fire-retardant | V0 | V0 | V0 | V0 | V0 | V0 |
| Resistivity（Ω） | ≥1.0×109 | 4.9×1013 | 3.2×1014 | 5.1×1014 | 6.7×1013 | 8.5×1013 |
| Abrasion resistance | ≥2500 | 5100 | 5300 | 5500 | 5400 | 5200 |
| Fire protecting performance | It is poor | Preferably | Preferably | Preferably | Preferably | Preferably |
| Protection against rodents effect | It is poor | Preferably | Preferably | Preferably | Preferably | Preferably |
| Ultraviolet light and aging is tested（h） | ≥504 | 1008 | 1008 | 1008 | 1008 | 1008 |
As it can be seen from table 1 automotive line produced by the present invention with PVC it is material modified have preferably it is cold-resistant, heat-resisting, insulate, it is resistance to
Performance is ground, fire prevention, protection against rodents and anti-aging effect are good, environmental protection, and weather resistance is excellent, and intensity is high, and excellent shock resistance is fire-retardant
Effect is good, and processing characteristics is excellent, excellent combination property.
Above-described embodiment is the present invention preferably implementation, and in addition, the present invention can be realized with other manner,
Any obvious replacement is within protection scope of the present invention on the premise of not departing from present inventive concept.
Claims (10)
1. a kind of automotive line is material modified with PVC, it is characterised in that：Include the raw material of following parts by weight：
80-120 parts of polyvinyl chloride resin
40-80 parts of polymeric plasticizer
Cold-resistant 8-12 parts of modifying agent
3-7 parts of precipitated calcium carbonate
Insulate 3-7 parts of modifying agent
1-3 parts of heat-proof modifier
2-4 parts of fireproof agent
0.5-1.5 parts of Ratproof agent
0.5-1.5 parts of abrasion resistance modifier
1.1-1.5 parts of age resistor.
2. a kind of automotive line according to claim 1 is material modified with PVC, it is characterised in that：The polyvinyl chloride resin is polymerization
Spend the SG-5 type polyvinyl chloride resins in 1000-1100；The polymeric plasticizer is by epoxidized soybean oil, synthesizes vegetable esters and polyester
Plasticizer compares 1-2 with weight:0.8-1.2:The mixture of 1 composition.
3. a kind of automotive line according to claim 1 is material modified with PVC, it is characterised in that：The cold-resistant modifying agent is
2-4 is compared with weight by nitrile rubber and butadiene rubber：The mixture of 1 composition；The precipitated calcium carbonate be particle diameter 10-100nm,
And the precipitated calcium carbonate treated by silane coupler.
4. a kind of automotive line according to claim 1 is material modified with PVC, it is characterised in that：It is described insulation modifying agent be
By kaolin, silica flour and glass microballoon with weight ratio 1:1.5-2.5:The mixture of 2-4 compositions.
5. a kind of automotive line according to claim 1 is material modified with PVC, it is characterised in that：The heat-proof modifier is
By N-phenylmaleimide/fine terpolymer of styrene/propylene, α-methylstyrene/styrene/acrylonitrile ternary polymerization
Thing and styrene/propylene it is fine/maleic anhydride terpolymer is with weight ratio 1:0.8-1.2:1.4-2.2 the mixture of composition.
6. a kind of automotive line according to claim 1 is material modified with PVC, it is characterised in that：The fireproof agent is by bromine
Change polystyrene, melamine phosphate and magnesium hydroxide and 1.4-2.2 is compared with weight:1:The mixture of 0.8-1.2 compositions.
7. a kind of automotive line according to claim 1 is material modified with PVC, it is characterised in that：The Ratproof agent is by peppery
Green pepper is plain, n- Vanillyl pelargonic amide and o- isopropyl phenyl-N- methyl carbamates compare 0.8-1.2 with weight:1：1.5-2.5
The mixture of composition.
8. a kind of automotive line according to claim 1 is material modified with PVC, it is characterised in that：The abrasion resistance modifier is
By butadiene-styrene rubber and natural rubber with weight ratio 1:1.8-2.6 the mixture of composition.
9. a kind of automotive line according to claim 1 is material modified with PVC, it is characterised in that：The age resistor is by preventing
Old agent A, antioxidant A W and anti-aging agent RD compare 0.8-1.2 with weight:1:1.6-2.4 the mixture of composition.
10. a kind of automotive line as described in claim any one of 1-9 is with preparation method material modified PVC, it is characterised in that：
Comprise the following steps：
（1）Above-mentioned raw materials are weighed by the parts by weight of constitutive material, are mixed；
（2）Mixed raw material is put into high speed blender, 15-25min is stirred at a temperature of 100-140 DEG C；
（3）By the raw material after stirring by double screw extruder extruding pelletization, automotive line is made material modified with PVC；It is described double
The extruder temperature of screw extruder is：One 138-160 DEG C of area's temperature, two 135-160 DEG C of area's temperature, three 135-155 DEG C of area's temperature,
130-148 DEG C of the area's temperature of four area temperature 132-150 DEG CHe five.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710253942.4A CN106977848A (en) | 2017-04-18 | 2017-04-18 | A kind of automotive line is material modified and preparation method thereof with PVC |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710253942.4A CN106977848A (en) | 2017-04-18 | 2017-04-18 | A kind of automotive line is material modified and preparation method thereof with PVC |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106977848A true CN106977848A (en) | 2017-07-25 |
Family
ID=59345146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710253942.4A Pending CN106977848A (en) | 2017-04-18 | 2017-04-18 | A kind of automotive line is material modified and preparation method thereof with PVC |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106977848A (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107236228A (en) * | 2017-07-26 | 2017-10-10 | 合肥同佑电子科技有限公司 | A kind of safety monitoring equipment weather proof cable protective cover material and preparation method thereof |
| CN107286516A (en) * | 2017-07-31 | 2017-10-24 | 广东祺龙科技有限公司 | A kind of beach shoes bottom is material modified and preparation method thereof with PVC |
| CN108384149A (en) * | 2018-03-27 | 2018-08-10 | 江苏凤腾塑料有限公司 | A kind of novel high-strength high-flexibility PVC plastic |
| CN108641229A (en) * | 2018-05-04 | 2018-10-12 | 广东祺龙科技有限公司 | A kind of V0 grades of flame-retarded PVC modified material and preparation method thereof |
| CN108641228A (en) * | 2018-05-04 | 2018-10-12 | 广东祺龙科技有限公司 | A kind of PVC modified materials of national standard 3C certifications and preparation method thereof |
| CN108659387A (en) * | 2018-05-04 | 2018-10-16 | 广东祺龙科技有限公司 | A kind of industry easily tears electric wire PVC modified materials and preparation method thereof |
| CN108659386A (en) * | 2018-05-04 | 2018-10-16 | 广东祺龙科技有限公司 | A kind of robot drag chain PVC modified materials and preparation method thereof |
| CN108676278A (en) * | 2018-05-04 | 2018-10-19 | 广东祺龙科技有限公司 | A kind of low temperature is without sulphur without conducting wire PVC modified materials and preparation method thereof |
| CN108676279A (en) * | 2018-05-04 | 2018-10-19 | 广东祺龙科技有限公司 | A kind of flexible light light bar PVC modified materials and preparation method thereof of high brightness |
| CN108841099A (en) * | 2018-05-04 | 2018-11-20 | 广东祺龙科技有限公司 | A kind of automobile charging pile PVC modified material and preparation method thereof |
| CN108841098A (en) * | 2018-05-04 | 2018-11-20 | 广东祺龙科技有限公司 | A kind of English mark PVC modified material and preparation method thereof |
| CN108912529A (en) * | 2018-05-04 | 2018-11-30 | 广东祺龙科技有限公司 | A kind of American Standard fire-resistant screen cloth PVC modified material and preparation method thereof |
| CN108912528A (en) * | 2018-05-04 | 2018-11-30 | 广东祺龙科技有限公司 | A kind of conduction cushion PVC modified material and preparation method thereof |
| CN113897002A (en) * | 2021-10-29 | 2022-01-07 | 四川天邑康和通信股份有限公司 | Environment-friendly polyvinyl chloride optical cable sheathing compound and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967250A (en) * | 2010-09-21 | 2011-02-09 | 王长明 | Cold-resistant temperature-resistant flame-retardant surface migration-resistant polrvinyl chloride insulating material |
| CN103059469A (en) * | 2012-12-25 | 2013-04-24 | 东莞市祺龙电业有限公司 | A kind of high temperature resistant environment-friendly PVC modified material and preparation method thereof |
| CN105440505A (en) * | 2015-12-31 | 2016-03-30 | 东莞市祺龙电业有限公司 | PVC (polyvinyl chloride) foam material for sole and preparation method of PVC foam material |
-
2017
- 2017-04-18 CN CN201710253942.4A patent/CN106977848A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967250A (en) * | 2010-09-21 | 2011-02-09 | 王长明 | Cold-resistant temperature-resistant flame-retardant surface migration-resistant polrvinyl chloride insulating material |
| CN103059469A (en) * | 2012-12-25 | 2013-04-24 | 东莞市祺龙电业有限公司 | A kind of high temperature resistant environment-friendly PVC modified material and preparation method thereof |
| CN105440505A (en) * | 2015-12-31 | 2016-03-30 | 东莞市祺龙电业有限公司 | PVC (polyvinyl chloride) foam material for sole and preparation method of PVC foam material |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107236228A (en) * | 2017-07-26 | 2017-10-10 | 合肥同佑电子科技有限公司 | A kind of safety monitoring equipment weather proof cable protective cover material and preparation method thereof |
| CN107286516A (en) * | 2017-07-31 | 2017-10-24 | 广东祺龙科技有限公司 | A kind of beach shoes bottom is material modified and preparation method thereof with PVC |
| CN108384149A (en) * | 2018-03-27 | 2018-08-10 | 江苏凤腾塑料有限公司 | A kind of novel high-strength high-flexibility PVC plastic |
| CN108641229A (en) * | 2018-05-04 | 2018-10-12 | 广东祺龙科技有限公司 | A kind of V0 grades of flame-retarded PVC modified material and preparation method thereof |
| CN108641228A (en) * | 2018-05-04 | 2018-10-12 | 广东祺龙科技有限公司 | A kind of PVC modified materials of national standard 3C certifications and preparation method thereof |
| CN108659387A (en) * | 2018-05-04 | 2018-10-16 | 广东祺龙科技有限公司 | A kind of industry easily tears electric wire PVC modified materials and preparation method thereof |
| CN108659386A (en) * | 2018-05-04 | 2018-10-16 | 广东祺龙科技有限公司 | A kind of robot drag chain PVC modified materials and preparation method thereof |
| CN108676278A (en) * | 2018-05-04 | 2018-10-19 | 广东祺龙科技有限公司 | A kind of low temperature is without sulphur without conducting wire PVC modified materials and preparation method thereof |
| CN108676279A (en) * | 2018-05-04 | 2018-10-19 | 广东祺龙科技有限公司 | A kind of flexible light light bar PVC modified materials and preparation method thereof of high brightness |
| CN108841099A (en) * | 2018-05-04 | 2018-11-20 | 广东祺龙科技有限公司 | A kind of automobile charging pile PVC modified material and preparation method thereof |
| CN108841098A (en) * | 2018-05-04 | 2018-11-20 | 广东祺龙科技有限公司 | A kind of English mark PVC modified material and preparation method thereof |
| CN108912529A (en) * | 2018-05-04 | 2018-11-30 | 广东祺龙科技有限公司 | A kind of American Standard fire-resistant screen cloth PVC modified material and preparation method thereof |
| CN108912528A (en) * | 2018-05-04 | 2018-11-30 | 广东祺龙科技有限公司 | A kind of conduction cushion PVC modified material and preparation method thereof |
| CN113897002A (en) * | 2021-10-29 | 2022-01-07 | 四川天邑康和通信股份有限公司 | Environment-friendly polyvinyl chloride optical cable sheathing compound and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106977848A (en) | A kind of automotive line is material modified and preparation method thereof with PVC | |
| CN106947187A (en) | A kind of sunlight fabric is material modified and preparation method thereof with PVC | |
| CN106916394A (en) | A kind of anti-slip carpet is material modified and preparation method thereof with PVC | |
| CN105440505A (en) | PVC (polyvinyl chloride) foam material for sole and preparation method of PVC foam material | |
| CN105482310A (en) | Antistatic PVC (polyvinyl chloride) modified material and preparation method thereof | |
| CN106977849A (en) | A kind of curtain is material modified and preparation method thereof with PVC | |
| CN103450669B (en) | A kind of high strength, high tenacity fiberglass reinforced PA/ABS composite material and preparation method thereof | |
| CN105504584A (en) | Tasteless PVC modified material and preparation method thereof | |
| CN106947185A (en) | A kind of table mat is material modified and preparation method thereof with PVC | |
| CN105566805A (en) | Anticorrosive PVC modified material and preparation method thereof | |
| CN105419167A (en) | Carpet environmental protection PVC modified material and preparation method therefor | |
| CN106905641A (en) | A kind of wallpaper cloth is material modified and preparation method thereof with PVC | |
| CN107082949B (en) | High-performance polypropylene plastic packaging barrel and preparation method thereof | |
| WO2014178490A1 (en) | Toughened epoxy resin composition, preparation method therefor, and toughened epoxy resin | |
| CN106905642A (en) | A kind of anti-skid wearable ground cushion and preparation method thereof | |
| CN105419168A (en) | Medical environmental protection PVC modified material and preparation method therefor | |
| JPS601256A (en) | Polyamide resin composition | |
| CN109608833B (en) | High-strength flame-retardant PCT engineering plastic and preparation method thereof | |
| CN106977846A (en) | A kind of waterproof oil resistant carpet is material modified and preparation method thereof with PVC | |
| CN106928596A (en) | A kind of anti-oxidant ground cushion of uvioresistant and preparation method thereof | |
| CN107011622A (en) | A kind of super abrasive POM/PTFE sheet materials and preparation method thereof | |
| CN112625405B (en) | A low smoke density halogen-free flame retardant reinforced PBT/PET composite and its preparation method and application | |
| CN104830015A (en) | A kind of highly wear-resistant environmental protection educational toy and preparation method thereof | |
| CN104497567B (en) | Long carbon chain nylon/calcium silicate whisker composite and its preparation method and application | |
| CN105985552A (en) | Lanthanum-oxide-modified rubber cable material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: Ye Wu industrial zone Dalingshan Meilin Village 523000 Guangdong city of Dongguan Province Applicant after: Guangdong Qi Long Technology Co., Ltd. Address before: Ye Wu industrial zone Dalingshan Meilin Village 523820 Guangdong city of Dongguan Province Applicant before: Dongguan Qilong Electricity Co., Ltd. |
|
| CB02 | Change of applicant information | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170725 |
|
| RJ01 | Rejection of invention patent application after publication |