CN107028811B - Composite emulsifier and skin-moistening facial cleanser containing same - Google Patents
Composite emulsifier and skin-moistening facial cleanser containing same Download PDFInfo
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- CN107028811B CN107028811B CN201710223865.8A CN201710223865A CN107028811B CN 107028811 B CN107028811 B CN 107028811B CN 201710223865 A CN201710223865 A CN 201710223865A CN 107028811 B CN107028811 B CN 107028811B
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- skin
- facial cleanser
- moistening
- grease
- emulsifier
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- 239000003995 emulsifying agent Substances 0.000 title claims abstract description 57
- 230000001815 facial effect Effects 0.000 title claims abstract description 49
- 239000002131 composite material Substances 0.000 title claims abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 30
- 239000004519 grease Substances 0.000 claims abstract description 30
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229920002701 Polyoxyl 40 Stearate Polymers 0.000 claims abstract description 22
- 239000004359 castor oil Substances 0.000 claims abstract description 22
- 235000019438 castor oil Nutrition 0.000 claims abstract description 22
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 22
- 239000004094 surface-active agent Substances 0.000 claims description 34
- 239000003381 stabilizer Substances 0.000 claims description 21
- 230000008719 thickening Effects 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000008367 deionised water Substances 0.000 claims description 14
- 229910021641 deionized water Inorganic materials 0.000 claims description 14
- 239000002480 mineral oil Substances 0.000 claims description 12
- 235000010446 mineral oil Nutrition 0.000 claims description 12
- 239000003963 antioxidant agent Substances 0.000 claims description 11
- 230000003078 antioxidant effect Effects 0.000 claims description 11
- 239000003906 humectant Substances 0.000 claims description 11
- 239000003755 preservative agent Substances 0.000 claims description 11
- 230000002335 preservative effect Effects 0.000 claims description 11
- 229940057950 sodium laureth sulfate Drugs 0.000 claims description 5
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims description 5
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 4
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- 239000000679 carrageenan Substances 0.000 claims description 4
- 235000010418 carrageenan Nutrition 0.000 claims description 4
- 229920001525 carrageenan Polymers 0.000 claims description 4
- 229940113118 carrageenan Drugs 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
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- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 4
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 4
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 4
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 4
- 239000000230 xanthan gum Substances 0.000 claims description 4
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- 229920001285 xanthan gum Polymers 0.000 claims description 4
- 229940082509 xanthan gum Drugs 0.000 claims description 4
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 4
- 229920002907 Guar gum Polymers 0.000 claims description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 3
- 239000010495 camellia oil Substances 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 3
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- GWTCIAGIKURVBJ-UHFFFAOYSA-L dipotassium;dodecyl phosphate Chemical compound [K+].[K+].CCCCCCCCCCCCOP([O-])([O-])=O GWTCIAGIKURVBJ-UHFFFAOYSA-L 0.000 claims description 3
- 239000000665 guar gum Substances 0.000 claims description 3
- 235000010417 guar gum Nutrition 0.000 claims description 3
- 229960002154 guar gum Drugs 0.000 claims description 3
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 claims description 3
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 claims description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 3
- 229940033623 potassium lauryl phosphate Drugs 0.000 claims description 3
- 108700004121 sarkosyl Proteins 0.000 claims description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 3
- 229940079781 sodium cocoyl glutamate Drugs 0.000 claims description 3
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 claims description 3
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 claims description 3
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004264 Petrolatum Substances 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- -1 alkyl glucoside Chemical class 0.000 claims description 2
- 229930182478 glucoside Natural products 0.000 claims description 2
- 239000008169 grapeseed oil Substances 0.000 claims description 2
- 229940066842 petrolatum Drugs 0.000 claims description 2
- 235000019271 petrolatum Nutrition 0.000 claims description 2
- 229940080230 sodium c12-14 olefin sulfonate Drugs 0.000 claims description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims 1
- 239000003921 oil Substances 0.000 abstract description 22
- 239000006260 foam Substances 0.000 abstract description 18
- 238000003756 stirring Methods 0.000 description 23
- 235000019198 oils Nutrition 0.000 description 21
- 238000005187 foaming Methods 0.000 description 15
- 230000000694 effects Effects 0.000 description 13
- 230000006872 improvement Effects 0.000 description 12
- 238000004140 cleaning Methods 0.000 description 8
- 230000001804 emulsifying effect Effects 0.000 description 8
- 239000006071 cream Substances 0.000 description 7
- 238000001816 cooling Methods 0.000 description 6
- 238000007599 discharging Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000006210 lotion Substances 0.000 description 6
- 230000003020 moisturizing effect Effects 0.000 description 6
- 239000000344 soap Substances 0.000 description 6
- 230000000087 stabilizing effect Effects 0.000 description 6
- 238000007689 inspection Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 230000002421 anti-septic effect Effects 0.000 description 4
- 238000005238 degreasing Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 3
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 3
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 3
- 230000000875 corresponding effect Effects 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000008267 milk Substances 0.000 description 3
- 210000004080 milk Anatomy 0.000 description 3
- 235000013336 milk Nutrition 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000004255 Butylated hydroxyanisole Substances 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- 235000019282 butylated hydroxyanisole Nutrition 0.000 description 2
- 229940043253 butylated hydroxyanisole Drugs 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000003974 emollient agent Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000008172 hydrogenated vegetable oil Substances 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 235000010356 sorbitol Nutrition 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 238000000194 supercritical-fluid extraction Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- CLAHOZSYMRNIPY-UHFFFAOYSA-N 2-hydroxyethylurea Chemical compound NC(=O)NCCO CLAHOZSYMRNIPY-UHFFFAOYSA-N 0.000 description 1
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- 208000002874 Acne Vulgaris Diseases 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 206010000496 acne Diseases 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
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- 239000006185 dispersion Substances 0.000 description 1
- WSDISUOETYTPRL-UHFFFAOYSA-N dmdm hydantoin Chemical compound CC1(C)N(CO)C(=O)N(CO)C1=O WSDISUOETYTPRL-UHFFFAOYSA-N 0.000 description 1
- 230000037336 dry skin Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229940031575 hydroxyethyl urea Drugs 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 230000036620 skin dryness Effects 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Cosmetics (AREA)
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Abstract
The invention discloses a composite emulsifier which comprises PEG40 stearate and PEG60 hydrogenated castor oil. The invention also discloses a skin-moistening facial cleanser, which comprises the compound emulsifier and the grease. The skin-moistening facial cleanser disclosed by the invention uses the specific compound emulsifier, so that the oil can be stably solubilized and emulsified, and an emulsified body is in a special stable state; meanwhile, an emulsified body generated after the compound emulsifier emulsifies the grease has small influence on foam, the grease is released and adsorbed on the skin after being cleaned, and the moistening feeling is obvious.
Description
Technical Field
The invention belongs to the field of daily skin care products, and particularly relates to a composite emulsifier and a skin-moistening face-cleaning lotion containing the same.
Background
With the rapid development of the economy of China and the improvement of the living standard of people, the skin care consciousness is gradually enhanced. The face cleanser has been developed from an initial simple cleansing function to a multifunctional direction of cleansing, skin care, whitening, acne removal and the like. But also increasingly used as one of the skin cleaning products essential to the life of modern people.
The face cleansing cream is mainly divided into three categories, namely foam type, solvent type and foamless type. Among them, the foam type facial cleanser is most popular with consumers; the cleaning agent contains the surfactant, can generate foam, is soft and comfortable to touch in use, is strong in cleaning capacity, enables oil and fat dirt to stably exist in water through the surfactant, and is dissolved in water to achieve a cleaning effect. The solvent type face cleansing cream mainly uses an oily solvent, removes oily dirt by means of the dissolving capacity of oil and oil, and mainly aims at the oily dirt. The non-foaming face cleanser combines the characteristics of the two types, not only uses a proper amount of oil but also contains partial surfactant, but also has little or no foam due to the need of emulsified oil, and has good moisturizing property and insufficient cleaning capability after use.
Because the cleansing cream has obvious advantages, manufacturers pay more attention to the research and development of the foam type cleansing cream, and try to overcome the defects of excessive cleansing, large irritation, dry skin after use and the like. Currently, the mainstream foam facial cleanser has the following modes for improving the dryness of the skin after washing:
the soap-based facial cleanser system has the advantages that the pure soap-based facial cleanser system is neutralized by animal vegetable oil and alkali to form soap, the foaming is rapid, the foam is richest and gentler, the pH value is high, the alkalinity is strong, the skin is stimulated, the sebum eluting capacity is strong, and the skin is tight and dry. Manufacturers mostly compound water-soluble fat-endowing agents, humectants or cationic conditioners to improve the skin moistening degree, but the effect is not obvious in a soap-based system.
The other is a pure surfactant system, and the degreasing force in the foam is adjustable. Manufacturers mainly use various surfactants to compound surfactants with low mild degreasing force (such as amino acid surfactants and the like) as foaming cleaning components, have low skin irritation, and compound water-soluble fat-endowing components; although the effect is slightly better, the water-soluble skin moisturizing and lipid-forming component has the defect that the water-soluble skin moisturizing and lipid-forming component is easy to wash away in washing, and the skin moisturizing effect is limited after actual use.
And the soap surface compound system has foam performance close to that of a soap base system and skin feel of a surfactant system, and the pH value, the degreasing capability and the skin dryness after use are between the two.
Fourthly, the face cleanser contains oil and has a special stable system. The cleanser is foamed and stabilized by using a large amount of a specific surfactant, so that a high oil content can be contained and a high foam amount can be maintained. The skin is moist after washing, and the comfort level is high. Secondly, a special thickening stabilizer is used for stabilizing grease, and then the grease is forcibly foamed by a surfactant with high content and high foaming amount (the surfactant is converted into at least 15 percent of active matter), so that the corresponding foaming amount is achieved. However, in the first case, the oil content is limited, generally only hydrogenated vegetable oil or non-polar oil can be used, polar oil cannot be used, and meanwhile, the cost is difficult to control due to the addition of a large amount of special surfactants, and a severe and complicated production process is also used, so that the production cost is high, and the product sale is influenced; in the second case, only hydrogenated vegetable oils are generally used to reduce the antifoaming properties, while the addition of large amounts of high foaming surfactants leads to a significant increase in formulation costs, while large amounts of surfactants further lead to increased cleansing power, increased skin irritation, and increased degreasing capacity, thus counteracting some of the emollient effects of the oils.
Disclosure of Invention
In one aspect, the invention provides a compound emulsifier for solving the defects in the prior art.
The technical scheme adopted by the invention is as follows: a composite emulsifier comprises PEG40 stearate and PEG60 hydrogenated castor oil.
As a further improvement to the technical scheme, the weight ratio of the PEG40 stearate to the PEG60 hydrogenated castor oil is 1: 2-10: 1.
PEG40 stearate and PEG60 hydrogenated castor oil are matched with each other, so that the grease can be stably solubilized and emulsified, an emulsified body is in a special stable state, and the foaming performance of the surfactant is slightly influenced by the composite emulsifier. Particularly, when the weight ratio of PEG40 stearate to PEG60 hydrogenated castor oil is within the above range, the stabilizing effect is better and the influence on the foaming property of the surfactant is less.
As a further improvement to the technical scheme, in the composite emulsifier, the weight ratio of PEG40 stearate to PEG60 hydrogenated castor oil is 3: 1. Compared with other weight ratios, the composite emulsifier obtained when the weight ratio of the PEG40 stearate to the PEG60 hydrogenated castor oil is 3:1 has better using effect.
On the other hand, the invention also provides a skin-moistening facial cleanser which comprises the compound emulsifier and the grease.
As a further improvement on the technical scheme, the weight percentage content of the composite emulsifier in the skin-moistening facial cleanser is 1-4%; the weight percentage content of the grease is 0.5-10%. When the dosage of the compound emulsifier and the grease is in the above range, the compound emulsifier has better stabilizing effect on the grease.
The grease can be various polar or nonpolar greases, including inorganic grease, animal and vegetable grease and the like; as a further improvement of the technical scheme, the grease is at least one selected from mineral oil, petrolatum, isopropyl palmitate, hydrogenated grape seed oil, supercritical extraction camellia oil, caprylic/capric triglyceride and C15-19 alkane.
As a further improvement to the technical scheme, the skin-moistening facial cleanser further comprises a thickening stabilizer; the weight percentage content of the thickening stabilizer is 0.5 percent to 5 percent. The thickening stabilizer is added for stabilizing an emulsified body generated after the compound emulsifier provided by the invention emulsifies grease, and can help the system to be stable through emulsification assisting and dispersion suspension, and when the weight percentage of the thickening stabilizer is 0.5-5%, the stabilizing effect is better.
The skin-moistening facial cleanser is realized by compounding one or more corresponding thickening stabilizers, and as a further improvement of the technical scheme, the thickening stabilizers are selected from at least one of xanthan gum, sodium carboxymethyl cellulose, guar gum, hydroxyethyl cellulose, carrageenan, hydroxypropyl methyl cellulose and acrylic acid (ester) copolymers.
As a further improvement to the technical scheme, the skin-moistening facial cleanser further comprises a surfactant; the weight percentage of the surfactant is 5-20% (before the active matter is converted). Under the condition of using the compound emulsifier of the invention, the addition amount of the surfactant for foaming and cleaning can reach moderate foam amount under the condition of relatively low addition amount, the mass percentage content of the actual active matter after the conversion accounts for 5-10% of the total formula amount, and the actual active content of the common like products after the conversion is at least more than 15%. The reduction of the dosage of the surfactant is beneficial to the reduction of the formula cost, and simultaneously, the irritation of the surfactant to the skin can be reduced, the sebum elution capability is reduced, and the skin adsorption of grease is facilitated.
As a further improvement of the technical proposal, the surfactant is at least one selected from sodium laureth sulfate, cocamidopropyl betaine, sodium laureth sulfate, sodium C12-14 olefin sulfonate, sodium cocoyl glutamate, sodium lauroyl sarcosinate, C12-16 alkyl glucoside and potassium lauryl phosphate.
As a further improvement of the technical scheme, the skin-moistening facial cleanser further comprises at least one of a humectant, essence, an antioxidant, a preservative and deionized water. The specific raw materials of these components are not necessarily limited to the present invention, and do not have a major influence on the effects of the present invention, so that only a part of the raw materials is selected, and the following raw materials having the corresponding effects can be selected without being limited thereto. The skin care product can be added with the auxiliary materials and the auxiliary agents according to the needs of the product, and certainly, the auxiliary materials and the auxiliary agents are not limited to the above materials, and other suitable auxiliary materials and auxiliary agents can be selected and added by a person skilled in the art according to the needs.
As a further improvement to the technical scheme, the humectant is selected from at least one of sorbitol, propylene glycol, glycerin, 1, 3-butanediol, PEG400, hydroxyethyl urea and the like;
the antioxidant is at least one selected from butylated hydroxyanisole and butylated hydroxytoluene.
The preservative is at least one selected from methylisothiazolinone, methylchloroisothiazolinone and DMDM hydantoin.
As a further improvement to the technical scheme, the skin-moistening facial cleanser comprises the following components in percentage by weight: 1-4% of compound emulsifier, 0.5-5% of thickening stabilizer, 0.5-8% of grease, 5-20% of surfactant (before conversion of active substances), 1-10% of humectant, 0.01-0.1% of antioxidant, 0.1-0.8% of essence, 0.1-0.5% of preservative and the balance of deionized water.
In order to achieve the goal of higher oil content in the foaming cleanser, the nonionic stabilizing emulsifier critical to the cleanser of the present invention is that a specific emulsifier combination, i.e., the complex emulsifier of the present invention, must be used. The compound emulsifier is added into the facial cleanser in a proper amount, so that the oil can be stably solubilized and emulsified, and an emulsified body is in a special stable state. The emulsifying product of the common emulsifier has great influence on the foaming performance of the surfactant, so that the product has no bubbles and less bubbles. The composite emulsifier provided by the invention has little influence on foam by an emulsified body generated after the compound emulsifier emulsifies the grease, and the grease is released and adsorbed on the skin after being cleaned, so that the moistening feeling is obvious.
The skin-moistening facial cleanser is simple and easy to produce. The preparation method of the skin-moistening facial cleanser comprises the following steps: adding deionized water, an emulsifier, grease, a surfactant and an antioxidant into an emulsifying pot, stirring at a low speed in a vacuum state (the vacuum degree is less than or equal to-0.02 MPa) at a stirring speed of 20-50 r/min, heating to 75-80 ℃, keeping the temperature for 20-50 min, adding a thickening stabilizer, cooling, adding essence and a preservative at 45 ℃, stopping stirring at 39 ℃, starting discharging, inspecting and filling after qualification, thus obtaining the skin-moistening facial cleanser.
In still another aspect, the invention also provides the application of the compound emulsifier in cosmetics.
The complex emulsifier of the present invention can be used in cosmetics as an emulsifier in, for example, a shampoo, a conditioner, an emollient, a lotion, or a cream.
Compared with the prior art, the invention has the beneficial effects that:
the skin-moistening facial cleanser disclosed by the invention uses the specific compound emulsifier, so that the oil can be stably solubilized and emulsified, and an emulsified body is in a special stable state; meanwhile, an emulsified body generated after the compound emulsifier emulsifies the grease has small influence on foam, the grease is released and adsorbed on the skin after being cleaned, and the moistening feeling is obvious.
The skin-moistening facial cleanser does not need to be added with water-soluble oil easy to wash, and can also be added with no cationic skin conditioner. The use effect of the product is obviously improved by adding a proper amount of grease, the cost is low, the production is simple and convenient, the skin is not easy to tighten after the use, and the moistening feeling is good.
Drawings
Fig. 1 is a schematic flow chart of an embodiment of a method for preparing the skin-moistening facial cleanser of the present invention.
Detailed Description
Fig. 1 is a schematic flow chart of an embodiment of a method for preparing a skin-moistening facial cleanser according to the present invention, and the method includes the following steps: adding deionized water, an emulsifier, grease, a surfactant, a humectant and an antioxidant into an emulsifying pot, stirring at a low speed in a vacuum state (the vacuum degree is less than or equal to-0.02 MPa) at a stirring speed of 20-50 r/min, heating to 75-80 ℃, preserving heat for 20-50 min, adding a thickening stabilizer, then continuously stirring for 10-30 min, cooling, adding an essence preservative at 45 ℃, stopping stirring at 39 ℃, starting discharging, and filling after the inspection is qualified.
To better illustrate the objects, aspects and advantages of the present invention, the present invention will be further described with reference to specific examples.
Example 1
The skin-moistening facial cleanser comprises the following components in percentage by weight: sodium laureth sulfate (70% content) 8%, cocamidopropyl betaine (30% content) 5%, PEG40 stearate 0.8%, PEG60 hydrogenated castor oil 0.8%, caprylic/capric triglyceride 3%, butyl hydroxy anisole 0.1%; 5% of glycerin, 1.5% of xanthan gum, 0.1% of essence and 0.35% of preservative. The balance of deionized water.
The preparation method of the skin-moistening facial cleanser in the embodiment comprises the following steps: adding deionized water, emulsifier, oil, surfactant, humectant and antioxidant into an emulsifying pot, stirring at low speed (vacuum degree is less than or equal to-0.02 MPa) under vacuum condition at stirring speed of 20 r/min, heating to 75 deg.C, maintaining the temperature for 50 min, adding thickening stabilizer, stirring for 30 min, cooling, adding essence and antiseptic at 45 deg.C, stopping stirring at 39 deg.C, discharging, and packaging after inspection.
Example 2
The skin-moistening facial cleanser comprises the following components in percentage by weight: 5% of C12-14 olefin sodium sulfonate, 6% of sodium lauroyl sarcosinate (content of 30%), 0.5% of PEG40 stearate, 1% of PEG60 hydrogenated castor oil, 5% of acrylic acid (ester) copolymer, 4% of mineral oil, 5% of sorbitol, 0.05% of butylated hydroxytoluene, 0.2% of essence, 0.45% of preservative and the balance of deionized water.
The preparation method of the skin-moistening facial cleanser in the embodiment comprises the following steps: adding deionized water, emulsifier, oil, surfactant, humectant and antioxidant into an emulsifying pot, stirring at low speed under vacuum condition (vacuum degree is less than or equal to-0.02 MPa) at stirring speed of 50 r/min, heating to 80 deg.C, maintaining for 20 min, adding thickening stabilizer, stirring for 10 min, cooling, adding essence and antiseptic at 45 deg.C, stopping stirring at 39 deg.C, discharging, and packaging after inspection.
Example 3
The skin-moistening facial cleanser comprises the following components in percentage by weight: 10 percent of sodium lauryl sulfate (70 percent content), 10 percent of potassium lauryl phosphate (30 percent content), 1.5 percent of PEG40 stearate, 1.5 percent of PEG60 hydrogenated castor oil, 5 percent of supercritical extraction camellia oil, 6 percent of 1, 3-butanediol, 0.05 percent of butylated hydroxytoluene, 1 percent of carrageenan, 1 percent of hydroxypropyl methyl cellulose, 0.3 percent of essence and 0.5 percent of preservative. The balance of deionized water.
The preparation method of the skin-moistening facial cleanser in the embodiment comprises the following steps: adding deionized water, emulsifier, oil, surfactant, humectant and antioxidant into an emulsifying pot, stirring at low speed (vacuum degree is less than or equal to-0.02 MPa) under vacuum condition at stirring speed of 35 r/min, heating to 78 deg.C, maintaining the temperature for 35 min, adding thickening stabilizer, stirring for 20 min, cooling, adding essence and antiseptic at 45 deg.C, stopping stirring at 39 deg.C, discharging, and packaging after inspection.
Example 4
The skin-moistening facial cleanser comprises the following components in percentage by weight: 5% of C12-14 olefin sodium sulfonate, 10% of sodium cocoyl glutamate, 3.2% of PEG40 stearate, 0.8% of PEG60 hydrogenated castor oil, 8% of isopropyl palmitate, 10% of PEG 40010%, 0.01% of butylated hydroxyanisole, 1% of hydroxyethyl cellulose, 0.5% of essence and 0.1% of preservative. The balance of deionized water.
The preparation method of the skin-moistening facial cleanser in the embodiment comprises the following steps: adding deionized water, emulsifier, oil, surfactant, humectant and antioxidant into an emulsifying pot, stirring at low speed (vacuum degree is less than or equal to-0.02 MPa) under vacuum condition at stirring speed of 40 r/min, heating to 78 deg.C, maintaining for 40 min, adding thickening stabilizer, stirring for 20 min, cooling, adding essence and antiseptic at 45 deg.C, stopping stirring at 39 deg.C, discharging, and packaging after inspection.
Example 5
The lather generation effects of the skin lotion were compared for the following three cases under the same basic formula: (1) the skin-moistening cleansing cream is not added with emulsifier and grease; (2) 2 wt% of compound emulsifier I (wherein the weight ratio of PEG40 stearate to PEG60 hydrogenated castor oil is 1:1) and 5 wt% of mineral oil are added into the skin-moistening cleansing milk; (3) the skin-moistening cleansing cream is not added with a compound emulsifier, and only 5 wt% of mineral oil is added; (4) 2 wt% of compound emulsifier II (wherein, the weight ratio of PEG40 stearate to PEG60 hydrogenated castor oil is 1:2) and 5 wt% of mineral oil are added into the skin-moistening cleansing milk; (5) the skin-moistening cleansing milk is added with 2 wt% of compound emulsifier III (wherein the weight ratio of PEG40 stearate to PEG60 hydrogenated castor oil is 3:1) and 5 wt% of mineral oil. The lather levels of the skin moisturizing cleanser were measured using a Roche lathering instrument for three conditions and are shown in Table 1.
TABLE 1
As can be seen from the table above, the amount of foam generated is greatly reduced by only adding the grease, and the composite emulsifier of the invention has little influence on the amount of foam.
Meanwhile, 10 test persons were selected to test the after-wash tightness of the skin-moisturizing facial cleansers, the ordinary top-active facial cleansers and the skin-moisturizing component-free facial cleansers in examples 1 to 4 of the present invention, and the results are shown in table 2.
TABLE 2
| Name (R) | The invention discloses skin-moistening facial cleanser | Common surface-active face cleanser | Cleanser without skin moistening component |
| The tightness after washing is the lightest | 9 | 1 | 0 |
In conclusion, the skin-moistening facial cleanser provided by the invention has the advantages that the foaming amount and the facial cleaning effect are obviously improved.
Example 6
The lather production efficacy of the skin lotion was compared under the same basic formula for three cases: the compound emulsifier (wherein, the weight ratio of PEG40 stearate to PEG60 hydrogenated castor oil is 1:1) and 5 wt% of mineral oil are added into the fruit (1) skin-moistening facial cleanser; (2) PEG40 stearate and 5 wt% mineral oil are added into the skin-moistening facial cleanser; (3) adding PEG60 hydrogenated castor oil and 5% mineral oil into the skin-moistening facial cleanser; wherein the same oil and fat are used in (1) - (3), and the addition amount of the emulsifier is 2 wt%. The lather levels of the skin moisturizing cleanser were measured using a Roche lathering instrument for the three conditions and are shown in Table 3.
TABLE 3
As can be seen from the above table, the combination of PEG40 stearate and PEG60 hydrogenated castor oil significantly improved the amount of foaming compared to the use of PEG40 stearate or PEG60 hydrogenated castor oil alone.
Example 7
PEG40 stearate was mixed with several other emulsifiers selected at a ratio of 1:1 to form a compound emulsifier; under the same condition of the basic formula, the foam generation effects of the skin-moistening facial cleanser obtained by adding 5% of mineral oil and different compound emulsifiers (the addition amounts are 2 wt%) are compared. The amount of lather was measured using a Roche lathering instrument for various skin lotions and the results are shown in Table 4.
TABLE 4
PEG60 hydrogenated castor oil was mixed with selected several other emulsifiers at a ratio of 1:1 to form a compound emulsifier; under the same condition of the basic formula, the foam generation effects of the skin-moistening facial cleanser obtained by adding 5% of mineral oil and different compound emulsifiers (the addition amounts are 2 wt%) are compared. The amount of lather was measured using a Roche lathering instrument for various skin lotions and the results are shown in Table 5.
TABLE 5
The sizes of micelles or emulsified bodies formed by the similar emulsifier combinations under the same condition are different, the surface activities are different, and the solubilizing and emulsifying capacities to oil are different, and the comparison between the table 4 and the table 5 shows that the influence of other emulsifier combinations on the foaming amount of the product is larger than that of the proportional combination of PEG40 stearate and PEG60 hydrogenated castor oil in the application, and the relatively good foaming effect cannot be achieved.
Finally, it should be noted that the above embodiments are only used for illustrating the technical solutions of the present invention and not for limiting the protection scope of the present invention, and although the present invention is described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions can be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention.
Claims (6)
1. The skin-moistening facial cleanser is characterized in that: comprises a compound emulsifier and grease; the composite emulsifier comprises PEG40 stearate and PEG60 hydrogenated castor oil; the weight ratio of the PEG40 stearate to the PEG60 hydrogenated castor oil is 3:1, the grease is selected from at least one of mineral oil, petrolatum, isopropyl palmitate, hydrogenated grape seed oil, supercritical extracted camellia oil, caprylic/capric triglyceride and C15-19 alkane, and the weight percentage content of the composite emulsifier in the skin-moistening facial cleanser is 1% -4%; the weight percentage of the grease is 0.5-10%.
2. The skin-moisturizing cleanser according to claim 1, characterized in that: the skin-moistening facial cleanser further comprises a thickening stabilizing agent; the weight percentage content of the thickening stabilizer is 0.5% -5%;
the thickening stabilizer is at least one selected from xanthan gum, sodium carboxymethylcellulose, guar gum, hydroxyethyl cellulose, carrageenan, hydroxypropyl methylcellulose and acrylic acid copolymer.
3. The skin-moisturizing cleanser according to claim 1, characterized in that: the skin-moistening facial cleanser further comprises a thickening stabilizing agent; the weight percentage content of the thickening stabilizer is 0.5% -5%;
the thickening stabilizer is at least one selected from xanthan gum, sodium carboxymethylcellulose, guar gum, hydroxyethyl cellulose, carrageenan, hydroxypropyl methylcellulose and acrylate copolymer.
4. The skin-moisturizing cleanser according to claim 1, characterized in that: the skin-moistening facial cleanser further comprises a surfactant; the weight percentage content of the surfactant is 5-20%;
the surfactant is selected from at least one of sodium laureth sulfate, cocamidopropyl betaine, sodium laureth sulfate, sodium C12-14 olefin sulfonate, sodium cocoyl glutamate, sodium lauroyl sarcosinate, C12-16 alkyl glucoside, and potassium lauryl phosphate.
5. The skin-moisturizing cleanser according to claim 1, characterized in that: the skin-moistening facial cleanser further comprises at least one of a humectant, essence, an antioxidant, a preservative and deionized water.
6. The skin-moisturizing cleanser according to claim 1, characterized in that: the skin-moistening facial cleanser comprises the following components in percentage by weight: 1-4% of compound emulsifier, 0.5-5% of thickening stabilizer, 0.5-8% of grease, 5-20% of surfactant (before conversion of active substances), 1-10% of humectant, 0.01-0.1% of antioxidant, 0.1-0.8% of essence, 0.1-0.5% of preservative and the balance of deionized water.
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| KR101507090B1 (en) * | 2012-12-21 | 2015-04-01 | 광주여자대학교 산학협력단 | Essence cosmetic composition with high moisturing effects in gel type |
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| CN102228419A (en) * | 2011-06-28 | 2011-11-02 | 中国人民解放军南京军区福州总医院 | Emulsified sunscreen cosmetic |
| CN103191027A (en) * | 2013-04-27 | 2013-07-10 | 珀莱雅化妆品股份有限公司 | Solid makeup removing cream having warm sense in using process |
| CN103301035B (en) * | 2013-05-29 | 2014-10-08 | 美晨集团股份有限公司 | Skin moistening product for preventing skin from being dried and chapped and preparation method of skin moistening product |
| CN105687038A (en) * | 2016-03-05 | 2016-06-22 | 广州丹奇日用化工厂有限公司 | Skin-care makeup remover cream with skin surface lipid film repairing function and preparation method of skin-care makeup remover cream |
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