CN107057281A - A kind of fire retarding epoxide resin fiberglass - Google Patents
A kind of fire retarding epoxide resin fiberglass Download PDFInfo
- Publication number
- CN107057281A CN107057281A CN201611239382.9A CN201611239382A CN107057281A CN 107057281 A CN107057281 A CN 107057281A CN 201611239382 A CN201611239382 A CN 201611239382A CN 107057281 A CN107057281 A CN 107057281A
- Authority
- CN
- China
- Prior art keywords
- epoxide resin
- fire retarding
- retarding epoxide
- resin fiberglass
- fire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003822 epoxy resin Substances 0.000 title claims abstract description 28
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 28
- 239000011152 fibreglass Substances 0.000 title claims abstract description 27
- 230000000979 retarding effect Effects 0.000 title claims abstract description 23
- 239000012779 reinforcing material Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 239000003085 diluting agent Substances 0.000 claims abstract description 3
- 239000003063 flame retardant Substances 0.000 claims abstract description 3
- 239000012745 toughening agent Substances 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 239000011521 glass Substances 0.000 claims description 10
- 239000000835 fiber Substances 0.000 claims description 8
- 239000004744 fabric Substances 0.000 claims description 7
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 5
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 5
- 229940035423 ethyl ether Drugs 0.000 claims description 5
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical group [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 2
- 229920000877 Melamine resin Polymers 0.000 claims 1
- LEHOTFFKMJEONL-UHFFFAOYSA-N Uric Acid Chemical compound N1C(=O)NC(=O)C2=C1NC(=O)N2 LEHOTFFKMJEONL-UHFFFAOYSA-N 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical group NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims 1
- 239000000945 filler Substances 0.000 abstract description 2
- 239000003365 glass fiber Substances 0.000 description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical group NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000004595 color masterbatch Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 230000001404 mediated effect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical group [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical group [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/40—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34928—Salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides fire retarding epoxide resin fiberglass, it includes the raw material of following parts by weight：Epoxy resin 70~90, curing agent 10~15, releasing agent 2~5, filler 15~30, toughener 5~10, diluent 2~5, reinforcing material 10~25, fire retardant 15~25.The characteristics of fire retarding epoxide resin fiberglass of the present invention, excellent mechanical property, resistance to surface leakage, good impact resistance, good fire resistance.
Description
Technical field
The present invention relates to field of compound material, more particularly to a kind of fire retarding epoxide resin fiberglass.
Background technology
Glass-reinforced plastic material is to be embedded in cured thermosetting resin by fiber glass reinforcement or be wrapped to form by it
The material of composite construction.It is molded in the market more than the glass-reinforced plastic material of production and application using resin Sized glass cloth material.
This method effect of impregnation is good, and prepared content of glass fiber is high.But due to being limited by glass cloth volume and shape, make it special
The product that uniform-compression is difficult for pipe joint, tee pipe fitting, bend pipe tools etc. is not suitable with.In addition, prepared by this method
Glass-reinforced plastic material its impact resistance it is poor, and laminated face is easily layered.In order to solve the above problems, there is researcher by glass
It is that 1000 or so, length is 3~5mm glass fiber powders that glass fiber, which cuts into Fiber Aspect Ratio, then puts into glass fiber powder
Into the mixed liquor being made up of epoxy resin, plasticizer, silane coupler, then it is the addition filler that stirs in ball mill, solid
Agent, is thus prepared into a kind of glass-reinforced plastic material without glass cloth laying.Although the glass-reinforced plastic material gram that this method is provided
Glass cloth caused defect in itself has been taken, but because glass fibre is cut into powdery, thus its fiber is specific in itself
Physical characteristic is also weakened severely.Mode as composite absorbs impact energy is often deformed with Crack Extension extremely by resin
Fracture, fiber are extracted out, 3 kinds of modes of fibrous fracture.Thus it is not difficult to find out when the glass fibre in composite is embedded in powdery
In the thermosetting resin of solidification, when by external impacts, mealiness fiber can absorb energy when no longer there is fiber to extract out
Effect, while the energy that can be absorbed when also losing fibrous fracture.
The content of the invention
It is an object of the present invention in view of the shortcomings of the prior art there is provided a kind of fire retarding epoxide resin fiberglass, to solve
Above-mentioned technical problem.
The technical scheme that is used to achieve the above object of the present invention for：
A kind of fire retarding epoxide resin fiberglass, it includes the raw material of following parts by weight：
Preferably, described diluent is diepoxy propane ethylether.
Preferably, solidfied material is peroxide.
Preferably, described toughener is dioctyl phthalate.
Preferably, described releasing agent is zinc stearate or calcium stearate.
Preferably, described reinforcing material is organic fiber.
Preferably, described reinforcing material is Graphite cloth's band.
Preferably, described reinforcing material is glass rove.
Preferably, described fire retardant is melamine cyanurate.
The fire retarding epoxide resin fiberglass that the present invention is provided, with excellent mechanical property, resistance to surface leakage, impact resistance
Well, the characteristics of good fire resistance.
Embodiment
Embodiment 1
A kind of fire retarding epoxide resin fiberglass is provided, it includes the raw material of following parts by weight：
It is beaten when it is implemented, the epoxy resin, hydrogen peroxide, dioctyl phthalate of above-mentioned weight are added first
In machine, quick stirring 10 minutes.Mediate 5 minutes, then sequentially add next, the slurry stirred is moved into kneader
Mediated 20 minutes after the components such as zinc stearate, calcium carbonate, the melamine cyanurate of above-mentioned weight, be eventually adding diepoxy propane
Continue to mediate 5 minutes after ethylether, organic fiber composition by weight.Obtain the fire retarding epoxide resin glass-reinforced plastic material of true qualities.Root
According to client need that corresponding color masterbatch can also be added to be made into the color of needs.
Embodiment 2
A kind of fire retarding epoxide resin fiberglass is provided, it includes the raw material of following parts by weight：
When it is implemented, the epoxy resin, cumyl peroxide, dioctyl phthalate of above-mentioned weight are added first
Enter in beater, quick stirring 10 minutes.Next, will the slurry that stirred move into kneader in mediate 5 minutes, then according to
Mediated 20 minutes after the components such as secondary calcium stearate, barium sulfate, the melamine cyanurate for adding above-mentioned weight, be eventually adding two rings
Continue to mediate 5 minutes after Ethylene Oxide ethylether, Graphite cloth's band composition by weight.Obtain the fire retarding epoxide resin glass steel of true qualities
Material.According to client need that corresponding color masterbatch can also be added to be made into the color of needs.
Embodiment 3
A kind of fire retarding epoxide resin fiberglass is provided, it includes the raw material of following parts by weight：
When it is implemented, the epoxy resin, cumyl peroxide, dioctyl phthalate of above-mentioned weight are added first
Enter in beater, quick stirring 10 minutes.Next, will the slurry that stirred move into kneader in mediate 5 minutes, then according to
Mediated 20 minutes after the components such as secondary zinc stearate, calcium sulfate, the melamine cyanurate for adding above-mentioned weight, be eventually adding two rings
Continue to mediate 5 minutes after Ethylene Oxide ethylether, glass rove composition by weight.Obtain the fire retarding epoxide resin glass steel of true qualities
Material.According to client need that corresponding color masterbatch can also be added to be made into the color of needs.
There is the performance shown in following table after tested as the unsaturated polyester die plastic obtained by above example：
Certainly, this invention can also have other conversion, it is not limited to which above-mentioned embodiment, those skilled in the art are had
Standby knowledge, can also various changes can be made without departing from the inventive concept of the premise, such change all should fall in this hair
In bright protection domain.
Claims (9)
1. a kind of fire retarding epoxide resin fiberglass, it is characterised in that it includes the raw material of following parts by weight：
。
2. fire retarding epoxide resin fiberglass according to claim 1, it is characterised in that described diluent is diepoxy third
Alkane ethylether.
3. fire retarding epoxide resin fiberglass according to claim 1, it is characterised in that solidfied material is peroxide.
4. fire retarding epoxide resin fiberglass according to claim 1, it is characterised in that described toughener is O-phthalic
Dioctyl phthalate.
5. fire retarding epoxide resin fiberglass according to claim 1, it is characterised in that described releasing agent is zinc stearate
Or calcium stearate.
6. fire retarding epoxide resin fiberglass according to claim 1, it is characterised in that described reinforcing material is organic fibre
Dimension.
7. fire retarding epoxide resin fiberglass according to claim 1, it is characterised in that described reinforcing material is Graphite cloth
Band.
8. fire retarding epoxide resin fiberglass according to claim 1, it is characterised in that described reinforcing material is that glass is thick
Yarn.
9. fire retarding epoxide resin fiberglass according to claim 1, it is characterised in that described fire retardant is melamine
Lithate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611239382.9A CN107057281A (en) | 2016-12-28 | 2016-12-28 | A kind of fire retarding epoxide resin fiberglass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611239382.9A CN107057281A (en) | 2016-12-28 | 2016-12-28 | A kind of fire retarding epoxide resin fiberglass |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107057281A true CN107057281A (en) | 2017-08-18 |
Family
ID=59623465
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611239382.9A Pending CN107057281A (en) | 2016-12-28 | 2016-12-28 | A kind of fire retarding epoxide resin fiberglass |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107057281A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108707315A (en) * | 2018-06-04 | 2018-10-26 | 苏州新益特塑胶科技有限公司 | A kind of flame retardant type plastic rubber material |
| CN108715670A (en) * | 2018-06-04 | 2018-10-30 | 苏州新益特塑胶科技有限公司 | A kind of degradable plastic rubber material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102993642A (en) * | 2012-08-22 | 2013-03-27 | 常熟市筑紫机械有限公司 | Halogen-free flame retardant phenolic epoxy glass reinforced plastic molding material |
| CN103183931A (en) * | 2011-12-27 | 2013-07-03 | 常熟市亚美模特儿衣架有限公司 | Phenolic epoxy glass fibre reinforced plastic forming material |
| CN103254567A (en) * | 2012-02-18 | 2013-08-21 | 河北华强科技开发有限公司 | Preparation method of impact-resistant glass fiber reinforced plastic material |
| CN103254566A (en) * | 2012-02-18 | 2013-08-21 | 河北华强科技开发有限公司 | Impact-resistant glass fiber reinforced plastic material |
-
2016
- 2016-12-28 CN CN201611239382.9A patent/CN107057281A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103183931A (en) * | 2011-12-27 | 2013-07-03 | 常熟市亚美模特儿衣架有限公司 | Phenolic epoxy glass fibre reinforced plastic forming material |
| CN103254567A (en) * | 2012-02-18 | 2013-08-21 | 河北华强科技开发有限公司 | Preparation method of impact-resistant glass fiber reinforced plastic material |
| CN103254566A (en) * | 2012-02-18 | 2013-08-21 | 河北华强科技开发有限公司 | Impact-resistant glass fiber reinforced plastic material |
| CN102993642A (en) * | 2012-08-22 | 2013-03-27 | 常熟市筑紫机械有限公司 | Halogen-free flame retardant phenolic epoxy glass reinforced plastic molding material |
Non-Patent Citations (3)
| Title |
|---|
| 王国建 王凤芳编著: "《建筑防火材料》", 30 June 2006 * |
| 贾润礼，李宁等编著: "《塑料成型加工新技术》", 31 October 2006 * |
| 陈平 王德中编著: "《环氧树脂及其应用》", 28 February 2004 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108707315A (en) * | 2018-06-04 | 2018-10-26 | 苏州新益特塑胶科技有限公司 | A kind of flame retardant type plastic rubber material |
| CN108715670A (en) * | 2018-06-04 | 2018-10-30 | 苏州新益特塑胶科技有限公司 | A kind of degradable plastic rubber material |
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| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170818 |
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| RJ01 | Rejection of invention patent application after publication |