CN107090071A - A kind of non-solvent foamed plastic cement race track of large volume high resiliency and its preparation method - Google Patents
A kind of non-solvent foamed plastic cement race track of large volume high resiliency and its preparation method Download PDFInfo
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- CN107090071A CN107090071A CN201710382724.0A CN201710382724A CN107090071A CN 107090071 A CN107090071 A CN 107090071A CN 201710382724 A CN201710382724 A CN 201710382724A CN 107090071 A CN107090071 A CN 107090071A
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- 239000004033 plastic Substances 0.000 title claims abstract description 34
- 229920003023 plastic Polymers 0.000 title claims abstract description 34
- 239000002904 solvent Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000004568 cement Substances 0.000 title claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 112
- 238000002156 mixing Methods 0.000 claims description 22
- 239000011265 semifinished product Substances 0.000 claims description 15
- -1 phenyl ester Chemical class 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 10
- 239000000047 product Substances 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000003292 glue Substances 0.000 claims description 8
- 229920001451 polypropylene glycol Polymers 0.000 claims description 7
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- IRFSXVIRXMYULF-UHFFFAOYSA-N 1,2-dihydroquinoline Chemical compound C1=CC=C2C=CCNC2=C1 IRFSXVIRXMYULF-UHFFFAOYSA-N 0.000 claims description 3
- HGRNRWNRNVPVMM-UHFFFAOYSA-N benzene-1,3-diol;benzoic acid Chemical compound OC1=CC=CC(O)=C1.OC(=O)C1=CC=CC=C1 HGRNRWNRNVPVMM-UHFFFAOYSA-N 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 2
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 claims description 2
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical class C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- XTNOEYFQXCQKLC-UHFFFAOYSA-N 18-(oxiren-2-yl)octadeca-15,17-dienoic acid Chemical compound C1=C(C=CC=CCCCCCCCCCCCCCC(=O)O)O1 XTNOEYFQXCQKLC-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 239000006096 absorbing agent Substances 0.000 claims 1
- 230000003712 anti-aging effect Effects 0.000 claims 1
- 235000013339 cereals Nutrition 0.000 claims 1
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- 238000001802 infusion Methods 0.000 claims 1
- 229920000570 polyether Polymers 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 238000009472 formulation Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 5
- 239000013530 defoamer Substances 0.000 description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- IBOFVQJTBBUKMU-UHFFFAOYSA-N 4,4'-methylene-bis-(2-chloroaniline) Chemical compound C1=C(Cl)C(N)=CC=C1CC1=CC=C(N)C(Cl)=C1 IBOFVQJTBBUKMU-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 241001112258 Moca Species 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- YFNONBGXNFCTMM-UHFFFAOYSA-N butoxybenzene Chemical compound CCCCOC1=CC=CC=C1 YFNONBGXNFCTMM-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4812—Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1515—Three-membered rings
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2101/00—Manufacture of cellular products
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- C08G2350/00—Acoustic or vibration damping material
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C08K2003/2241—Titanium dioxide
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- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
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Abstract
The invention discloses a kind of non-solvent foamed plastic cement race track of large volume high resiliency and its preparation method, mainly include PPG 1000D, PPG 2000D and PPG 330N, a kind of preparation method of the non-solvent foamed plastic cement race track of large volume high resiliency, it is main to include 7 steps, plastic cement race track made from the formula and preparation method provided according to the present invention, the dispensing used in being not only formulated is the material of health environment-friendly, and the formula charge ratio provided is accurate, raw material is easy to get, the preparation method that the present invention is provided is easy to learn, is adapted to industrialization large-scale production.
Description
Technical field
The present invention relates to Material Field, and in particular to a kind of non-solvent foamed plastic cement race track of large volume high resiliency and its system
Method.
Background technology
There is poisonous and harmful substance because plastic cement race track is prepared in material in recent years, so as to cause the event that student is poisoned repeatly
See not fresh, the problem of present inventor is according to existing, it is proposed that a kind of non-solvent foamed plastic cement race track of large volume high resiliency and its
Preparation method.
The content of the invention
Goal of the invention：The purpose of the present invention be for prior art is not enough and defect there is provided a kind of large volume high resiliency without
Solvent foamed plastic runway and its preparation method, the plastic cement race track being made according to technical scheme provided by the present invention have excellent ring
Guaranteed cost and elastomeric property.
Technical scheme：In order to realize foregoing invention purpose, the technical solution adopted in the present invention is：
DDL-1000D is PPG 1000D.
DL-2000D is PPG -2000D, two degrees of functionality, 2000 molecular weight, hydroxyl value 54.5-57.5, epoxy third
The PPG of alkane polymerization, is mainly used in the production of polyurethane CASE series of products.
EP-330N is PPG -330N, three-functionality-degree, 5000 molecular weight, hydroxyl value 32.5-35.5, expoxy propane
The PPG of polymerization of ethylene oxide end-blocking, is mainly used in the production of polyurethane high-elastic sponge block bubble and molding, can also
Production for polyurethane elastomer.
TDMA is environment friendly curing agent, for polyurethane plastic runway, substitutes curing agent MOCA, not only environmentally friendly, and economical
Benefit is excellent.
A kind of non-solvent foamed plastic material of large volume high resiliency, in terms of the plastic material gross mass 100g, the present invention
Each component quality it is as follows：
First group
Second group
The talcum powder is 1250 mesh.
The silica is gaseous state.
The ultra-violet absorber be septichen phenyl ester, 2- (the 2 ˊ-ˊ of hydroxyl-5-aminomethyl phenyl) BTA,
2,4-DihydroxyBenzophenone, 2-hydroxy-4-n-octoxybenzophenone, 2- (the 2 ˊ-tertiary phenyl of hydroxyl -3 ˊ, 5 ˊ-two) -5- chlorine
Change the one or more combination thing in the Compositional type ultra-violet absorber such as BTA and single benzoic acid resorcinol, at present compared with
It is generally the ultra-violet absorber of Compositional type for preferable ultra-violet absorber/light stabilizer, can obtains than any independent ultraviolet
Absorbent more preferably effect.
The age resister is N- phenyl-α-aniline, N- phenyl-β-naphthylamines, 6- ethyoxyls -2,2,4- trimethyls -1,2-
One or more of compositions in dihyaroquinoline and 2,2,4- trimethyls 1,2- dihydro quinoline condensates.
The defoamer be silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite ether,
Polyoxyethylene polyoxy propyl alcohol amidogen ether, 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2,4,6- tri- (2 ˊ n-butoxy benzene
Base) one kind in -1,3,5-triazines, polypropylene glycerol aether, polyoxyethylene polyoxypropylene glycerin ether and dimethyl silicone polymer
Or several compositions.
The dispersant is polyethylene glycol.
A kind of preparation method of the non-solvent foamed plastic cement race track of large volume high resiliency：
Step A：Prepare a clean mixer and prepare first group base-material 1, the clean mixer of another prepares second group base
The charge ratio of material 1, first group and second group is as follows：
First group
Second group
Side adds the material of corresponding mass charge ratio, while being stirred with mixer, obtains first group base-material 1 and second group base-material
1, the mixing speed of mixer is 3000rad/min；
Step B：Again two clean mixers are prepared, one prepares first group base-material 2, and another prepares second group base-material 2,
According to following formula charge ratios, the component of corresponding mass ratio is sequentially added：
First group
Ultra-violet absorber 0.92g；
Age resister 0.08g；
Second group
Side adds the dispensing of corresponding mass, while being stirred with mixer, obtains first group base-material 2 and second group base-material 2, stirs
The mixing speed for mixing machine is set to 2500rad/min；
Step C：First group base-material and second group base-material are prepared, separately prepares two clean mixers, mixer is opened and is stirred
Mix, the first group base-material 2 that the obtained first group base-materials 1 of step A and step B are obtained simultaneously, slowly pour into mixer, while add while
It is stirred with 2000rad/min mixing speed, addition finishes continuation and stirs 0.5h, stands 24h, obtain first group base-material；
The obtained second group base-material 2 of the obtained second group base-materials 1 of step A and step B simultaneously, is slowly poured into another dispensing
Bucket, is stirred, addition finishes continuation and stirs 0.5h with 2000rad/min mixing speed when adding, stands 24h, obtain
Second group base-material；
The first group base-material after 24h will be stood, reacted 2~3 hours under the conditions of 85~90 DEG C, obtain first group base-material half into
Product；Obtained second group base-material is ground to form into glue solution of sticky shape, second group base-material semi-finished product are obtained；
Step D：By the obtained first group base-material semi-finished product of step C and second group base-material semi-finished product, according to first group base-material semi-finished product：
Second group base-material semi-finished product=1：4 ratio simultaneously, slowly pour into mixer, the mixing speed of mixer is 1000rad/min,
Mixing time is 30min, stands 24h, obtains primer semi-finished product；
Step E：Primer makes
The black glue grain and primer half of primer semi-manufactured goods quality 30~35% are added in the primer semi-finished product obtained into step D
The catalyst of final product quality 8%, obtains primer finished product；
Step F：Face glue makes
By the obtained first group base-material semi-finished product of step C and second group base-material semi-finished product, according to first group base-material semi-finished product：Second group base
Expect semi-finished product=1：3 ratio simultaneously, slowly pour into mixer, the mixing speed of mixer is 1000rad/min, stirring
Time is 30min, stands 24h, obtains face glue finished product；
Step G：Prepare soleplate, the primer finished product obtained in step E, F and face glue finished product are equably coated in soleplate
On so that the coating structure of uniform thickness is formed on soleplate, soleplate is dried by the way of drying, plastic cement is obtained
Runway production board.
The catalyst is the 1 of epoxy lead plumbate and epoxyeicosatrienoic acid zinc：1 scalemic thereof.
Beneficial effect：Compared with prior art, its advantage is the present invention：
1st, a kind of non-solvent foamed plastic cement race track of large volume high resiliency of the invention and its preparation method, are formulated used dispensing equal
It is the material of health environment-friendly.
2nd, a kind of non-solvent foamed plastic cement race track of large volume high resiliency of the invention and its preparation method there is provided formula charge ratio essence
Standard, raw material is easy to get.
3rd, a kind of non-solvent foamed plastic cement race track of large volume high resiliency of the invention and its preparation method there is provided preparation method it is simply easy
Learn, be adapted to industrialization large-scale production.
Embodiment
With reference to embodiment, the present invention is further illustrated.
Embodiment 1
A kind of non-solvent foamed plastic material of large volume high resiliency, in terms of the plastic material gross mass 100g, the present invention
Each component quality it is as follows：
First group
Second group
The talcum powder is 1250 mesh.
The silica is gaseous state.
It is single benzoic acid resorcinol to state ultra-violet absorber.
The age resister is 6- ethyoxyls -2,2,4- trimethyl -1,2- dihyaroquinolines.
The defoamer is dimethyl silicone polymer.
The dispersant is polyethylene glycol.
A kind of preparation method of the non-solvent foamed plastic cement race track of large volume high resiliency：
Step A：Prepare a clean mixer and prepare first group base-material 1, the clean mixer of another prepares second group base
The charge ratio of material 1, first group and second group is as follows：
First group
Second group
Side adds the material of corresponding mass charge ratio, while being stirred with mixer, obtains first group base-material 1 and second group base-material
1, the mixing speed of mixer is 3000rad/min；
Step B：Again two clean mixers are prepared, one prepares first group base-material 2, and another prepares second group base-material 2,
According to following formula charge ratios, the component of corresponding mass ratio is sequentially added：
First group
Ultra-violet absorber 0.92g；
Age resister 0.08g；
Second group
Side adds the dispensing of corresponding mass, while being stirred with mixer, obtains first group base-material 2 and second group base-material 2, stirs
The mixing speed for mixing machine is set to 2500rad/min；
Step C：First group base-material and second group base-material are prepared, separately prepares two clean mixers, mixer is opened and is stirred
Mix, the first group base-material 2 that the obtained first group base-materials 1 of step A and step B are obtained simultaneously, slowly pour into mixer, while add while
It is stirred with 2000rad/min mixing speed, addition finishes continuation and stirs 0.5h, stands 24h, obtain first group base-material；
The obtained second group base-material 2 of the obtained second group base-materials 1 of step A and step B simultaneously, is slowly poured into another dispensing
Bucket, is stirred, addition finishes continuation and stirs 0.5h with 2000rad/min mixing speed when adding, stands 24h, obtain
Second group base-material；
The first group base-material after 24h will be stood, reacted 2~3 hours under the conditions of 85~90 DEG C, obtain first group base-material half into
Product；Obtained second group base-material is ground to form into glue solution of sticky shape, second group base-material semi-finished product are obtained；
Step D：By the obtained first group base-material semi-finished product of step C and second group base-material semi-finished product, according to first group base-material semi-finished product：
Second group base-material semi-finished product=1：4 ratio simultaneously, slowly pour into mixer, the mixing speed of mixer is 1000rad/min,
Mixing time is 30min, stands 24h, obtains primer semi-finished product；
Step E：Primer makes
The black glue grain and primer half of primer semi-manufactured goods quality 30~35% are added in the primer semi-finished product obtained into step D
The catalyst of final product quality 8%, obtains primer finished product；
Step F：Face glue makes
By the obtained first group base-material semi-finished product of step C and second group base-material semi-finished product, according to first group base-material semi-finished product：Second group base
Expect semi-finished product=1：3 ratio simultaneously, slowly pour into mixer, the mixing speed of mixer is 1000rad/min, stirring
Time is 30min, stands 24h, obtains face glue finished product；
Step G：Prepare soleplate, the primer finished product obtained in step E, F and face glue finished product are equably coated in soleplate
On so that the coating structure of uniform thickness is formed on soleplate, soleplate is dried by the way of drying, plastic cement is obtained
Runway production board.
The catalyst is the 1 of epoxy lead plumbate and epoxyeicosatrienoic acid zinc：1 scalemic thereof.
Embodiment 2
A kind of non-solvent foamed plastic material of large volume high resiliency, in terms of the plastic material gross mass 100g, the present invention
Each component quality it is as follows：
First group
Second group
The talcum powder is 1250 mesh.
The silica is gaseous state.
The ultra-violet absorber is 2-hydroxy-4-n-octoxybenzophenone.
The age resister is 2,2,4- trimethyls 1,2- dihydro quinoline condensates.
The defoamer is 4- benzoyloxys -2,2,6,6- tetramethyl piperidines.
The dispersant is polyethylene glycol.
A kind of preparation method of the non-solvent foamed plastic cement race track of large volume high resiliency：
Step A：Prepare a clean mixer and prepare first group base-material 1, the clean mixer of another prepares second group base
The charge ratio of material 1, first group and second group is as follows：
First group
Second group
Side adds the material of corresponding mass charge ratio, while being stirred with mixer, obtains first group base-material 1 and second group base-material
1, the mixing speed of mixer is 3000rad/min；
Step B：Again two clean mixers are prepared, one prepares first group base-material 2, and another prepares second group base-material 2,
According to following formula charge ratios, the component of corresponding mass ratio is sequentially added：
First group
Ultra-violet absorber 0.92g；
Age resister 0.08g；
Second group
Side adds the dispensing of corresponding mass, while being stirred with mixer, obtains first group base-material 2 and second group base-material 2, stirs
The mixing speed of machine is set to 2500rad/min；
Step C：First group base-material and second group base-material are prepared, separately prepares two clean mixers, mixer is opened and is stirred
Mix, the first group base-material 2 that the obtained first group base-materials 1 of step A and step B are obtained simultaneously, slowly pour into mixer, while add while
It is stirred with 2000rad/min mixing speed, addition finishes continuation and stirs 0.5h, stands 24h, obtain first group base-material；
The obtained second group base-material 2 of the obtained second group base-materials 1 of step A and step B simultaneously, is slowly poured into another dispensing
Bucket, is stirred, addition finishes continuation and stirs 0.5h with 2000rad/min mixing speed when adding, stands 24h, obtain
Second group base-material；
The first group base-material after 24h will be stood, reacted 2~3 hours under the conditions of 85~90 DEG C, obtain first group base-material half into
Product；Obtained second group base-material is ground to form into glue solution of sticky shape, second group base-material semi-finished product are obtained；
Step D：By the obtained first group base-material semi-finished product of step C and second group base-material semi-finished product, according to first group base-material semi-finished product：
Second group base-material semi-finished product=1：4 ratio simultaneously, slowly pour into mixer, the mixing speed of mixer is 1000rad/min,
Mixing time is 30min, stands 24h, obtains primer semi-finished product；
Step E：Primer makes
The black glue grain and primer half of primer semi-manufactured goods quality 30~35% are added in the primer semi-finished product obtained into step D
The catalyst of final product quality 8%, obtains primer finished product；
Step F：Face glue makes
By the obtained first group base-material semi-finished product of step C and second group base-material semi-finished product, according to first group base-material semi-finished product：Second group base
Expect semi-finished product=1：3 ratio simultaneously, slowly pour into mixer, the mixing speed of mixer is 1000rad/min, stirring
Time is 30min, stands 24h, obtains face glue finished product；
Step G：Prepare soleplate, the primer finished product obtained in step E, F and face glue finished product are equably coated in soleplate
On so that the coating structure of uniform thickness is formed on soleplate, soleplate is dried by the way of drying, plastic cement is obtained
Runway production board.
The catalyst is the 1 of epoxy lead plumbate and epoxyeicosatrienoic acid zinc：1 scalemic thereof.
Using the above-mentioned desirable embodiment according to the present invention as enlightenment, by above-mentioned description, relevant staff is complete
Various changes and amendments, technology of the invention can be carried out in the range of the technological thought without departing from this invention entirely
Property scope is not limited to the content on specification, it is necessary to its technical scope is determined according to right.
Claims (9)
1. a kind of non-solvent foamed plastic material of large volume high resiliency, it is characterised in that：With the plastic material gross mass 100g
Meter, each component quality of the invention is as follows：
First group
Second group
DDL-1000D is PPG 1000D, and EP-330N is PPG -330N, and DL-2000D is that polyethers is more
First alcohol -2000D, TDMA are environment friendly curing agent.
2. a kind of non-solvent foamed plastic material of large volume high resiliency according to claim 1, it is characterised in that：The cunning
Stone flour is 1250 mesh.
3. a kind of non-solvent foamed plastic material of large volume high resiliency according to claim 1, it is characterised in that：Described two
Silica is gaseous state.
4. a kind of non-solvent foamed plastic material of large volume high resiliency according to claim 1, it is characterised in that：The purple
Ultraviolet absorbers are septichen phenyl ester, 2- (the 2 ˊ-ˊ of hydroxyl-5-aminomethyl phenyl) BTA, 2,4- dihydroxy hexichol
Ketone, 2-hydroxy-4-n-octoxybenzophenone, 2- (the tertiary phenyl of 2'- hydroxyls -3 ˊ, 5 ˊ-two) -5- chlorinations BTAs and list
One or more combination thing in benzoic acid resorcinol.
5. a kind of non-solvent foamed plastic material of large volume high resiliency according to claim 1, it is characterised in that：It is described anti-
Aging agent be N- phenyl-α-aniline, N- phenyl-β-naphthylamines, 6- ethyoxyls -2,2,4- trimethyls -1,2- dihyaroquinoline and 2,
One or more combination thing in 2,4- trimethyls 1,2- dihydro quinoline condensates.
6. a kind of non-solvent foamed plastic material of large volume high resiliency according to claim 1, it is characterised in that：It is described to disappear
Infusion is silicone emulsion, the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy third
Alcohol amidogen ether, 4- benzoyloxys -2,2,6,6- tetramethyl piperidines, 2 are 4,6- tri- (2 ˊ n-butoxyphenyls) -1,3,5-triazines, poly-
One or more combination thing in oxypropylene glycerin ether and polyoxyethylene polyoxypropylene glycerin ether and dimethyl silicone polymer.
7. a kind of non-solvent foamed plastic material of large volume high resiliency according to claim 1, it is characterised in that：Described point
Powder is polyethylene glycol.
8. a kind of preparation method of the non-solvent foamed plastic material of large volume high resiliency：
Step A：Prepare a clean mixer and prepare first group base-material 1, the clean mixer of another prepares second group base-material 1,
The charge ratio of first group and second group is as follows：
First group
Second group
Side adds the material of corresponding mass charge ratio, while being stirred with mixer, obtains first group base-material 1 and second group base-material 1, stirs
The mixing speed for mixing machine is 3000rad/min；
Step B：Again two clean mixers are prepared, one prepares first group base-material 2, and another prepares second group base-material 2, according to
Following formula charge ratios, sequentially add the component of corresponding mass ratio：
First group
Ultra-violet absorber 0.92g；
Age resister 0.08g；
Second group
Side adds the dispensing of corresponding mass, while being stirred with mixer, obtains first group base-material 2 and second group base-material 2, mixer
Mixing speed is set to 2500rad/min；
Step C：First group base-material and second group base-material are prepared, separately prepares two clean mixers, mixer is opened and is stirred, will
The first group base-material 2 that the first group base-material 1 and step B that step A is obtained are obtained simultaneously, slowly pour into mixer, while add while with
2000rad/min mixing speed is stirred, and addition finishes continuation and stirs 0.5h, is stood 24h, is obtained first group base-material；
The obtained second group base-material 2 of the obtained second group base-materials 1 of step A and step B simultaneously, is slowly poured into another mixer,
It is stirred when adding with 2000rad/min mixing speed, addition finishes continuation and stirs 0.5h, stands 24h, obtain second group
Base-material；
The first group base-material after 24h will be stood, reacted 2~3 hours under the conditions of 85~90 DEG C, obtain first group base-material semi-finished product；Will
Obtained second group base-material grinds to form glue solution of sticky shape, obtains second group base-material semi-finished product；
Step D：By the obtained first group base-material semi-finished product of step C and second group base-material semi-finished product, according to first group base-material semi-finished product：Second group
Base-material semi-finished product=1：4 ratio simultaneously, slowly pour into mixer, the mixing speed of mixer is 1000rad/min, stirring
Time is 30min, stands 24h, obtains primer semi-finished product；
Step E：Primer makes
The black glue grain and primer semi-finished product of primer semi-manufactured goods quality 30~35% are added in the primer semi-finished product obtained into step D
The catalyst of quality 8%, obtains primer finished product；
Step F：Face glue makes
By the obtained first group base-material semi-finished product of step C and second group base-material semi-finished product, according to first group base-material semi-finished product：Second group base-material half
Finished product=1：3 ratio simultaneously, slowly pour into mixer, the mixing speed of mixer is 1000rad/min, and mixing time is
30min, stands 24h, obtains face glue finished product；
Step G：Prepare soleplate, the primer finished product obtained in step E, F and face glue finished product are equably coated on soleplate, made
The coating structure that uniform thickness is formed on soleplate is obtained, soleplate is dried by the way of drying, plastic cement race track is obtained
Production board.
9. a kind of preparation method of non-solvent foamed plastic material of large volume high resiliency according to claim 8, it is characterised in that：
The catalyst is the 1 of epoxy lead plumbate and epoxyeicosatrienoic acid zinc：1 scalemic thereof.
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| CN114410272A (en) * | 2022-02-16 | 2022-04-29 | 湖北晟弘新材料有限公司 | Prefabricated runway adhesive |
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