CN107163655A - DOPO base expanding fire retardants - Google Patents
DOPO base expanding fire retardants Download PDFInfo
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- CN107163655A CN107163655A CN201710495570.6A CN201710495570A CN107163655A CN 107163655 A CN107163655 A CN 107163655A CN 201710495570 A CN201710495570 A CN 201710495570A CN 107163655 A CN107163655 A CN 107163655A
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- dopo
- graphene
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- expanding fire
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- DWSWCPPGLRSPIT-UHFFFAOYSA-N benzo[c][2,1]benzoxaphosphinin-6-ium 6-oxide Chemical compound C1=CC=C2[P+](=O)OC3=CC=CC=C3C2=C1 DWSWCPPGLRSPIT-UHFFFAOYSA-N 0.000 title claims abstract description 53
- 239000003063 flame retardant Substances 0.000 title claims abstract description 41
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 23
- 239000002994 raw material Substances 0.000 claims abstract description 18
- 239000002270 dispersing agent Substances 0.000 claims abstract description 6
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims description 11
- 229930182490 saponin Natural products 0.000 claims description 11
- 150000007949 saponins Chemical class 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- -1 propenoic acid ester Chemical class 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 abstract description 14
- 239000008107 starch Substances 0.000 abstract description 14
- 235000019698 starch Nutrition 0.000 abstract description 14
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 abstract description 12
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 9
- ZMUQGGLSCIDPLS-UHFFFAOYSA-N Saponin 5 Natural products COC(=O)C1(C)CCC2(CCC3(C)C(=CCC4C5(C)CCC(OC6OC(CO)C(O)C(O)C6OC7OC(CO)C(O)C(O)C7OC8OC(C)C(O)C(O)C8O)C(C)(C)C5CCC34C)C2C1)C(=O)O ZMUQGGLSCIDPLS-UHFFFAOYSA-N 0.000 abstract description 4
- 229920000877 Melamine resin Polymers 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract description 2
- 229920000137 polyphosphoric acid Polymers 0.000 abstract description 2
- 230000001988 toxicity Effects 0.000 abstract description 2
- 231100000419 toxicity Toxicity 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 8
- 239000003822 epoxy resin Substances 0.000 description 7
- 229920000058 polyacrylate Polymers 0.000 description 7
- 229920000647 polyepoxide Polymers 0.000 description 7
- 230000000694 effects Effects 0.000 description 4
- 239000013070 direct material Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- UPPXMONNNGGKMB-UHFFFAOYSA-N 3-O-(alpha-L-rhamnopyranosyl-(1->2)-beta-D-glucopyranosyl-(1->2)-beta-D-glucopyranosyl)spergulagenic acid Natural products OC1C(O)C(O)C(C)OC1OC1C(OC2C(OC(CO)C(O)C2O)OC2C(C3C(C4C(C5(CCC6(CCC(C)(CC6C5=CC4)C(O)=O)C(O)=O)C)(C)CC3)(C)CC2)(C)C)OC(CO)C(O)C1O UPPXMONNNGGKMB-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000011889 copper foil Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 239000013071 indirect material Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- GRZJZRHVJAXMRR-UHFFFAOYSA-N 1-cyclohexyl-2-phenylbenzene Chemical group C1CCCCC1C1=CC=CC=C1C1=CC=CC=C1 GRZJZRHVJAXMRR-UHFFFAOYSA-N 0.000 description 1
- BSYJHYLAMMJNRC-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-ol Chemical compound CC(C)(C)CC(C)(C)O BSYJHYLAMMJNRC-UHFFFAOYSA-N 0.000 description 1
- HPVKSGLGOKNQON-UHFFFAOYSA-N 3-O-(beta-D-galactopyranosyl-(1->3)-beta-D-glucopyranosyl)serjanic acid 28-O-beta-D-glucopyranoside Natural products COC(=O)C1(C)CCC2(CCC3(C)C(=CCC4C5(C)CCC(OC6OC(CO)C(O)C(OC7OC(CO)C(O)C(O)C7O)C6O)C(C)(C)C5CCC34C)C2C1)C(=O)OC8OC(CO)C(O)C(O)C8O HPVKSGLGOKNQON-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- AOILXFWEUKCKQQ-UHFFFAOYSA-N Saponin 8 Natural products COC(=O)C1(C)CCC2(CCC3(C)C(=CCC4C5(C)CCC(OC6OC(CO)C(O)C(O)C6OC7OC(CO)C(O)C(O)C7O)C(C)(C)C5CCC34C)C2C1)C(=O)OC8OC(CO)C(O)C(O)C8O AOILXFWEUKCKQQ-UHFFFAOYSA-N 0.000 description 1
- 229920006222 acrylic ester polymer Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical group C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1535—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1545—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/04—Starch derivatives, e.g. crosslinked derivatives
- C08L3/06—Esters
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of DOPO bases expanding fire retardant, it is made up of the raw material of following mass percent：The ﹪ of graphene 50~60 containing DOPO groups, the ﹪ of starch phosphate melamine salt 30~40, the ﹪ of Tea Saponin 5~10, the ﹪ of dispersant 5~10；Rationally, main body fire retardant is the graphene containing DOPO groups to the formula for the DOPO base expanding fire retardants that the present invention is provided, and one side DOPO groups have excellent fire resistance, meanwhile, the mechanical strength for being added with beneficial to raising and keeping institute's film forming of graphene；Starch phosphate melamine salt in formula is a kind of expansion type flame retardant, generally prepared using starch, polyphosphoric acids, melamine, raw material sources are extensive, cost is relatively low, toxicity is smaller, and can and the graphene containing DOPO groups be collectively forming host system, and form between the graphene containing DOPO groups a kind of flame retardant synergistic effect, it is easy to wide popularization and application.
Description
Technical field
The present invention relates to coating technical field of flame retardant, and in particular to a kind of DOPO bases expanding fire retardant.
Background technology
Wiring board is the substrate for carrying electronic component, and it is the bound fraction indirect material on the basis of direct material, is led to
Cross what the tool of production was machined.Wherein, direct material refers to be directly used in production on product or directly connect with product
Tactile main material；Indirect material refers to use the secondary material on product or with product mediate contact indirectly in production.
Topmost direct material has three kinds, i.e. base material, prepreg and copper foil during wiring board makes.Base material (core/laminte) is
Formed by prepreg and copper foil compacting.Prepreg is then to combine different strengthening material and filler system by resin, glass cloth
Make and form.
On the electronic equipment for requiring fire-retardant, in addition it is also necessary to fire-retardant circuit board, these circuit boards are all to scribble flame-retarded resin
Laminate.Epoxide resin material is because of the special energy with many protrusions, such as preferable heat endurance, insulating properties, adhesion, anti-corruption
Corrosion and good mechanical property, are widely used in the fields such as electronics, electrical equipment, and then as currently the most important ones electron chemistry
Material it.However, its oxygen index (OI) is not high, and only 20% or so, belong to flammability material, its fire resistance need to generally be changed
It is good to improve.One of conventional flame resistant method is to introduce the halogens such as chlorine, bromine with fire retarding effect in the epoxy to carry
The fire resistance of high epoxy resin solidfied material.In recent years, people have carried out big in terms of the anti-flammability of epoxide resin material is improved
Amount and in-depth study.
Contain P-H keys in 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, abbreviation DOPO, its structure, to alkene
Hydrocarbon, epoxide and the great activity of carbonyls, can react many derivatives of generation.DOPO and its derivative are due to molecule
Contain cyclohexyl biphenyl, phenanthrene ring, O=P-O keys in structure, so having stronger fire resistance than common organophosphorus ester.By
Saito reported its synthetic route first in 1972.DOPO and its derivative can be as response types and additive flame retardant, and it is closed
Into fire retardant Halogen, smokeless, nontoxic, do not migrate, fire resistance is lasting.While the fire resistance of material is improved, not shadow
Ring the mechanical performances such as the mechanical strength of material.It can be used for the multiple materials such as polyamide, linear polyester, polyurethane, epoxy resin
Flame retardant treatment, foreign countries are widely used in the fire-retardant of the material such as laminate layer, circuit board in plastics for electronics, brass.
The content of the invention
For above-mentioned deficiency, it is an object of the present invention to provide a kind of formula is reasonable, the good DOPO bases expansion resistance of stability
Fire agent.When being added into epoxy resin coating system, with excellent flame retardant effect, when flame retardant agent content reaches 4%
When, solidfied material can reach UL94, V-0 grades.
To achieve the above object, technical scheme provided by the present invention is：
A kind of DOPO bases expanding fire retardant, it is made up of the raw material of following mass percent：
As a preferred embodiment of the present invention, it is made up of the raw material of following mass percent：
As a preferred embodiment of the present invention, it is made up of the raw material of following mass percent：
As a preferred embodiment of the present invention, the graphene containing DOPO groups is that graphenic surface is grafted with 1
Individual or multiple DOPO groups.
As a preferred embodiment of the present invention, the dispersant is hyperbranched propenoic acid ester polymer.Specifically, this hair
Bright dispersant can be Guangzhou Si Luoke Chemical Co., LtdThe hyper-dispersant of 7679 models.
As a preferred embodiment of the present invention, specifically, the Tea Saponin is the Tea Saponin that purity is not less than 98%.This
The selected Tea Saponin of invention is the product of Xi'an four seasons bio tech ltd.
Beneficial effects of the present invention are：The formula for the DOPO base expanding fire retardants that the present invention is provided is reasonable, main body fire retardant
For the graphene containing DOPO groups, one side DOPO groups have excellent fire resistance, meanwhile, the addition of graphene is favourable
In the mechanical strength for improving and keeping institute's film forming；Starch phosphate melamine salt in formula is a kind of expansion type flame retardant, generally
Prepared using starch, polyphosphoric acids, melamine, extensively, cost is relatively low, and toxicity is smaller for raw material sources, and can and contain
The graphene of DOPO groups is collectively forming host system, and forms between the graphene containing DOPO groups a kind of fire-retardant
Cooperative effect；Tea Saponin in formula has good expansion character in itself, and the introducing of Tea Saponin can also be with containing DOPO bases
Cooperative flame retardant and suppression cigarette effect are formed between the graphene of group, the nitrogen source for making up the graphene containing DOPO groups not enough is asked
Topic, and its source is wide, and cost is low, and is improving the interface compatibility of fire retardant and epoxy resin, improves flame-retardant smoke inhibition side
Face has significant effect；It is compatible with system that the introducing of dispersant in formula efficiently solves the graphene containing DOPO groups
The problem of property.
With reference to embodiment, the present invention is further described.
Embodiment
A kind of DOPO bases expanding fire retardant provided in embodiment 1, the present embodiment, its by following mass percent raw material
Composition：The ﹪ of graphene 55 containing DOPO groups, the ﹪ of starch phosphate melamine salt 35, purity are 98% ﹪ of Tea Saponin 5, over-expense
Change the ﹪ of acrylate polymer 5.
A kind of DOPO bases expanding fire retardant provided in embodiment 2, the present embodiment, its by following mass percent raw material
Composition：The ﹪ of graphene 50 containing DOPO groups, the ﹪ of starch phosphate melamine salt 35, purity are 98% ﹪ of Tea Saponin 7, over-expense
Change the ﹪ of acrylate polymer 8.
A kind of DOPO bases expanding fire retardant provided in embodiment 3, the present embodiment, its by following mass percent raw material
Composition：The ﹪ of graphene 60 containing DOPO groups, the ﹪ of starch phosphate melamine salt 30, purity are 98% ﹪ of Tea Saponin 5, over-expense
Change the ﹪ of acrylate polymer 5.
A kind of DOPO bases expanding fire retardant provided in embodiment 4, the present embodiment, its by following mass percent raw material
Composition：The ﹪ of graphene 50 containing DOPO groups, the ﹪ of starch phosphate melamine salt 33, purity are 98% ﹪ of Tea Saponin 10, are surpassed
The ﹪ of branched acrylic ester polymer 7.
A kind of DOPO bases expanding fire retardant provided in embodiment 5, the present embodiment, its by following mass percent raw material
Composition：The ﹪ of graphene 60 containing DOPO groups, the ﹪ of starch phosphate melamine salt 30, purity are 98% ﹪ of Tea Saponin 5, over-expense
Change the ﹪ of acrylate polymer 5.
A kind of DOPO bases expanding fire retardant provided in embodiment 6, the present embodiment, its by following mass percent raw material
Composition：The ﹪ of graphene 51 containing DOPO groups, the ﹪ of starch phosphate melamine salt 33, purity are 98% ﹪ of Tea Saponin 6, over-expense
Change the ﹪ of acrylate polymer 10.
A kind of DOPO bases expanding fire retardant provided in embodiment 7, the present embodiment, its by following mass percent raw material
Composition：The ﹪ of graphene 56 containing DOPO groups, the ﹪ of starch phosphate melamine salt 30, purity are 98% ﹪ of Tea Saponin 6, over-expense
Change the ﹪ of acrylate polymer 8.
A kind of DOPO bases expanding fire retardant provided in embodiment 8, the present embodiment, its by following mass percent raw material
Composition：The ﹪ of graphene 50 containing DOPO groups, the ﹪ of starch phosphate melamine salt 35, purity are 98% ﹪ of Tea Saponin 8, over-expense
Change the ﹪ of acrylate polymer 7.
Comparative example 1, its is substantially the same manner as Example 8, and difference is not add the graphene containing DOPO groups.
Comparative example 2, its is substantially the same manner as Example 8, and difference is not add starch phosphate melamine salt.
Comparative example 3, its is substantially the same manner as Example 8, and difference is the Tea Saponin that not plus purity is 98%.
Comparative example 4, its is substantially the same manner as Example 8, and difference is not plus hyperbranched propenoic acid ester polymer disperses
Agent.
Comparative example 5, its is substantially the same manner as Example 8, and difference is that the purity of the Tea Saponin added is 95%.
Comparative example 6, its is substantially the same manner as Example 8, and difference is, the purity of the Tea Saponin of addition is 90%.
Application Example：The DOPO bases expanding fire retardant that embodiment 1-8 and comparative example 1-6 is obtained adds following system
In：
A kind of DOPO bases expanding fire retardant, it is made up of the raw material of following mass percent：
The DOPO bases expanding fire retardant of acquisition is added in following system：
The paint film of each embodiment and the corresponding epoxy resin formation of comparative example is subjected to UL94 testing vertical flammabilities, as a result table
Shown in 1：
Table 1
Using the above-mentioned desirable embodiment according to the present invention as enlightenment, by above-mentioned description, relevant staff is complete
Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention
Property scope is not limited to the content on specification, it is necessary to its technical scope is determined according to right.
Claims (6)
1. a kind of DOPO bases expanding fire retardant, it is characterised in that it is made up of the raw material of following mass percent：
2. DOPO bases expanding fire retardant according to claim 1, it is characterised in that：Its by following mass percent raw material
Composition：
3. DOPO bases expanding fire retardant according to claim 1, it is characterised in that：Its by following mass percent raw material
Composition：
4. the DOPO base expanding fire retardants according to any one in claim 1-3, it is characterised in that：It is described to contain DOPO
The graphene of group is that graphenic surface is grafted with one or more DOPO groups.
5. the DOPO base expanding fire retardants according to any one in claim 1-3, it is characterised in that：The dispersant is
Hyperbranched propenoic acid ester polymer.
6. the DOPO base expanding fire retardants according to any one in claim 1-3, it is characterised in that：The Tea Saponin is
Purity is not less than 98% Tea Saponin.
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| CN201710495570.6A CN107163655B (en) | 2017-06-26 | 2017-06-26 | DOPO base expanding fire retardant |
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| CN201710495570.6A CN107163655B (en) | 2017-06-26 | 2017-06-26 | DOPO base expanding fire retardant |
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| CN107163655B CN107163655B (en) | 2019-08-13 |
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| CN110964124A (en) * | 2019-12-20 | 2020-04-07 | 江南大学 | A kind of modified starch for preparing halogen-free flame retardant TPV composite material and its preparation |
| CN115197475A (en) * | 2022-07-18 | 2022-10-18 | 福州大学 | DOPO/ATMP modified chitosan loaded aluminum-based single-component intumescent flame retardant, and preparation method and application thereof |
| CN118166577A (en) * | 2024-04-22 | 2024-06-11 | 广东宏元实业集团有限公司 | Formula and production process of fire-retardant paper |
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| CN110964124A (en) * | 2019-12-20 | 2020-04-07 | 江南大学 | A kind of modified starch for preparing halogen-free flame retardant TPV composite material and its preparation |
| CN110964124B (en) * | 2019-12-20 | 2022-01-11 | 江南大学 | Modified starch for preparing halogen-free flame-retardant TPV composite material and preparation thereof |
| CN115197475A (en) * | 2022-07-18 | 2022-10-18 | 福州大学 | DOPO/ATMP modified chitosan loaded aluminum-based single-component intumescent flame retardant, and preparation method and application thereof |
| CN115197475B (en) * | 2022-07-18 | 2023-05-23 | 福州大学 | DOPO/ATMP modified chitosan-loaded aluminum-based single-component intumescent flame retardant as well as preparation method and application thereof |
| CN118166577A (en) * | 2024-04-22 | 2024-06-11 | 广东宏元实业集团有限公司 | Formula and production process of fire-retardant paper |
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|---|---|
| CN107163655B (en) | 2019-08-13 |
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