CN107475673A - 五层夹心结构三稳态光致变色薄膜的制备方法 - Google Patents

五层夹心结构三稳态光致变色薄膜的制备方法 Download PDF

Info

Publication number
CN107475673A
CN107475673A CN201710685519.1A CN201710685519A CN107475673A CN 107475673 A CN107475673 A CN 107475673A CN 201710685519 A CN201710685519 A CN 201710685519A CN 107475673 A CN107475673 A CN 107475673A
Authority
CN
China
Prior art keywords
layer
layers
stable state
thick
light
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710685519.1A
Other languages
English (en)
Inventor
蓝碧健
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taicang Biqi New Material Research Development Co Ltd
Original Assignee
Taicang Biqi New Material Research Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taicang Biqi New Material Research Development Co Ltd filed Critical Taicang Biqi New Material Research Development Co Ltd
Priority to CN201710685519.1A priority Critical patent/CN107475673A/zh
Publication of CN107475673A publication Critical patent/CN107475673A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24—Vacuum evaporation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
    • C09K9/02—Organic tenebrescent materials
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0694—Halides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/12—Organic material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14—Metallic material, boron or silicon
    • C23C14/20—Metallic material, boron or silicon on organic substrates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1029—Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1029—Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom
    • C09K2211/1037—Heterocyclic compounds characterised by ligands containing one nitrogen atom as the heteroatom with sulfur
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/10—Non-macromolecular compounds
    • C09K2211/1018—Heterocyclic compounds
    • C09K2211/1025—Heterocyclic compounds characterised by ligands
    • C09K2211/1088—Heterocyclic compounds characterised by ligands containing oxygen as the only heteroatom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Physical Vapour Deposition (AREA)
  • Laminated Bodies (AREA)

Abstract

本发明属于薄膜技术领域，涉及一种五层夹心结构三稳态光致变色薄膜的制备方法；本发明提出的方法是在聚碳酸酯基板上依次蒸镀2‑氨基‑3,8‑二氰基‑4,7‑二(2‑萘基)‑5‑苯基喹啉层、氟化锂层、(2‑亚苯并噻唑啉基)丙二腈层、锌层以及四(4‑甲基‑7‑香豆素氧甲基)甲烷层，构建五层结构O/M/O/M/O复合结构，利用复合结构中各组分间的协同效应，获得三稳态光致变色薄膜。本发明的优点在于：(1)首次获得五层O/M/O/M/O复合结构三稳态光致变色薄膜；(2)制备的三稳态光致变色薄膜在不同波长紫外光照射下，显现不同的颜色，实现了光致变色薄膜颜色的可控性。

Description

五层夹心结构三稳态光致变色薄膜的制备方法
技术领域
本发明属于薄膜材料技术领域，具体涉及一种五层夹心结构三稳态光致变色薄膜的制备方法。
背景技术
光致变色是指单一的化学物种在光的辐射下，可转化为具有明显不同吸收光谱的另一物质，这种物质在光或热的作用下，又可恢复到原来的状态。
随着科学技术的日益发展以及对计算机应用要求的普遍推广，人们对信息数据传递与存储的要求越来越高，开发高存储密度、高响应速度、可擦写的光盘材料，已成为当今世界的研究热点。在空间上达到纳米尺寸，甚至原子尺寸；在时间上达到皮秒甚至飞秒速度响应的光存储材料是研究人员追求的最终目标。到目前为止，研究最广泛的光学记录介质是碲、锗及其合金材料。但无机材料的制作成本较高，而长时间受光照射还容易产生鳞片状的龟裂。从80年代以来大量的研究工作开始转向有机光存储材料。这是因为有机光存储材料吸收带窄而且吸收度低，柔顺性好，可用甩膜法涂布，成本较低：熔点及软化点低，因而灵敏度高：热传导率低，记忆痕迹小，清晰度高；空气或湿气不易使其降解；光学和热变形性质可以通过改变有机分子的结构来进行调变，并且来源广泛，毒性较小。因此有机光致变色化合物在光信息存储领域有着相当广阔的应用前景。
王英利等对一种新型可擦重写有机光致变色材料俘精酸酐/聚甲基丙烯酸甲脂薄膜的光致变色双稳态吸收光谱进行了测量，呈色态的吸收峰在513nm，无色态的吸收峰在370nm。利用该双稳态特性，在10微米俘精酸酐/PMMA薄膜上进行全息图像光存储。实验用氩离子激光器514.5nm波长作为记录光源，测量了衍射效率与曝光量的关系，最大衍射效率约为1％。获得了存储于样品上的全息干涉条纹和参考光再现的衍射像，分析了影响衍射图像像质的因素，记录在样品上的全息图在室温下黑暗处可以保存一年以上(中国激光，2004，31：457-460)。
赵春柳等研究了激发态分子内质子转移有机分子具有光学双稳态、光致变色和光学非线性等性质。激发态分子内质子转移(ESIPT)是指当某些有机分子在光、热、电等作用下，使分子激励到激发态时，分子中某一基团上的氢核(即质子)通过分子内或分子间的氢键，转移到分子内邻近N、S、O等杂原子上，形成互变异构体的过程。由于ESIPT分子的质子转移荧光效率高，斯托克斯位移大，作为激光染料和闪烁器的工作介质，具有突出的优点，已为人们所应用。近年来光电子学和信息科学迅速发展的需要，人们广泛寻求新型的具有光电信息功能的有机材料。ESIPT分子具有光学双稳态、光致变色和光学非线性等诸多特性，而且反应速度快，可达fs量级，并且是可逆的，可望成为光开关、光限幅、光波导、实时光存储等光子学器件的优选材料(光电子与激光，1999，10：990427)。
与现有文件相比，本发明要解决的技术问题是如何通过组份及结构的协同关系，以获得具有黄、绿、蓝三稳态特性的光致变色薄膜，从而扩展光致变色薄膜的应用领域。
发明内容
本发明的目的在于提供一种五层夹心结构三稳态光致变色薄膜的制备方法。
本发明提出的五层夹心结构三稳态光致变色薄膜的制备方法，具体步骤如下：
将厚度为0.2mm、面积为16cm2的聚碳酸酯基板依次用甲醇、乙醇及去离子水洗涤1次，晾干，放置于真空镀膜机中，在真空度为2×10-3Pa下依次蒸镀25nm厚的2-氨基-3,8-二氰基-4,7-二(2-萘基)-5-苯基喹啉层、5nm厚的氟化锂层、45nm厚的(2-亚苯并噻唑啉基)丙二腈层、10nm厚的锌层以及55nm厚的四(4-甲基-7-香豆素氧甲基)甲烷层，得五层夹心结构三稳态光致变色薄膜；用白光、波长为365nm的紫外光以及波长为254nm的紫外光分别照射上述五层夹心结构三稳态光致变色薄膜1分钟，用测色仪检测光照后的五层夹心结构三稳态光致变色薄膜的颜色分别为绿色、黄色及蓝色。
如果不使用氟化锂层，本发明还提供如下技术方案作为对比：
将厚度为0.2mm、面积为16cm2的聚碳酸酯基板依次用甲醇、乙醇及去离子水洗涤1次，晾干，放置于真空镀膜机中，在真空度为2×10-3Pa下依次蒸镀25nm厚的2-氨基-3,8-二氰基-4,7-二(2-萘基)-5-苯基喹啉层、45nm厚的(2-亚苯并噻唑啉基)丙二腈层、10nm厚的锌层以及55nm厚的四(4-甲基-7-香豆素氧甲基)甲烷层，得多层复合薄膜；用白光、波长为365nm的紫外光以及波长为254nm的紫外光分别照射上述多层复合薄膜1分钟，用测色仪检测光照后的多层复合薄膜的颜色分别为绿色、绿色及绿色。
如果不使用锌层，本发明还提供如下技术方案作为对比：
将厚度为0.2mm、面积为16cm2的聚碳酸酯基板依次用甲醇、乙醇及去离子水洗涤1次，晾干，放置于真空镀膜机中，在真空度为2×10-3Pa下依次蒸镀25nm厚的2-氨基-3,8-二氰基-4,7-二(2-萘基)-5-苯基喹啉层、5nm厚的氟化锂层、45nm厚的(2-亚苯并噻唑啉基)丙二腈层以及55nm厚的四(4-甲基-7-香豆素氧甲基)甲烷层，得多层复合薄膜；用白光、波长为365nm的紫外光以及波长为254nm的紫外光分别照射上述多层复合薄膜1分钟，用测色仪检测光照后的多层复合薄膜的颜色分别为绿色、绿色及绿色。
如果不使用2-氨基-3,8-二氰基-4,7-二(2-萘基)-5-苯基喹啉层，本发明还提供如下技术方案作为对比：
将厚度为0.2mm、面积为16cm2的聚碳酸酯基板依次用甲醇、乙醇及去离子水洗涤1次，晾干，放置于真空镀膜机中，在真空度为2×10-3Pa下依次蒸镀5nm厚的氟化锂层、45nm厚的(2-亚苯并噻唑啉基)丙二腈层、10nm厚的锌层以及55nm厚的四(4-甲基-7-香豆素氧甲基)甲烷层，得多层复合薄膜；用白光、波长为365nm的紫外光以及波长为254nm的紫外光分别照射上述多层复合薄膜1分钟，用测色仪检测光照后的多层复合薄膜的颜色分别为浅绿色、浅绿色及浅绿色。
如果不使用(2-亚苯并噻唑啉基)丙二腈层，本发明还提供如下技术方案作为对比：
将厚度为0.2mm、面积为16cm2的聚碳酸酯基板依次用甲醇、乙醇及去离子水洗涤1次，晾干，放置于真空镀膜机中，在真空度为2×10-3Pa下依次蒸镀25nm厚的2-氨基-3,8-二氰基-4,7-二(2-萘基)-5-苯基喹啉层、5nm厚的氟化锂层、10nm厚的锌层以及55nm厚的四(4-甲基-7-香豆素氧甲基)甲烷层，得多层复合薄膜；用白光、波长为365nm的紫外光以及波长为254nm的紫外光分别照射上述多层复合薄膜1分钟，用测色仪检测光照后的多层复合薄膜的颜色分别为黄绿色、黄绿色及黄绿色。
如果不使用四(4-甲基-7-香豆素氧甲基)甲烷层，本发明还提供如下技术方案作为对比：
将厚度为0.2mm、面积为16cm2的聚碳酸酯基板依次用甲醇、乙醇及去离子水洗涤1次，晾干，放置于真空镀膜机中，在真空度为2×10-3Pa下依次蒸镀25nm厚的2-氨基-3,8-二氰基-4,7-二(2-萘基)-5-苯基喹啉层、5nm厚的氟化锂层、45nm厚的(2-亚苯并噻唑啉基)丙二腈层、10nm厚的锌层，得多层复合薄膜；用白光、波长为365nm的紫外光以及波长为254nm的紫外光分别照射上述多层复合薄膜1分钟，用测色仪检测光照后的多层复合薄膜的颜色分别为灰白色、灰白色及灰白色。
如果调换2-氨基-3,8-二氰基-4,7-二(2-萘基)-5-苯基喹啉层与四(4-甲基-7-香豆素氧甲基)甲烷层的蒸镀顺序，本发明还提供如下技术方案作为对比：
将厚度为0.2mm、面积为16cm2的聚碳酸酯基板依次用甲醇、乙醇及去离子水洗涤1次，晾干，放置于真空镀膜机中，在真空度为2×10-3Pa下依次蒸镀25nm厚的四(4-甲基-7-香豆素氧甲基)甲烷层、5nm厚的氟化锂层、45nm厚的(2-亚苯并噻唑啉基)丙二腈层、10nm厚的锌层以及55nm厚的2-氨基-3,8-二氰基-4,7-二(2-萘基)-5-苯基喹啉层，得多层复合薄膜；用白光、波长为365nm的紫外光以及波长为254nm的紫外光分别照射上述多层复合薄膜1分钟，用测色仪检测光照后的多层复合薄膜的颜色分别为黄色、黄色及黄色。
由上述对比技术方案可知，当五层夹心结构三稳态光致变色薄膜中组分或结构改变，则光致变色效应消失，说明本发明的技术效果是所有组分特定协同作用的结果，不能简单增减。不仅如此，本发明制备的光致变色薄膜在白光下为绿色，在波长为365nm的紫外光照射下变为黄色，而在波长为254nm的紫外光照射下变为蓝色，即光致变色薄膜的颜色既可以向长波长转变，也可以向短波长转变，这一性质是以往文献中未曾报道的，产生了意想不到的技术效果，具有创造性。
具体实施方式
下面通过实例进一步描述本发明。
实施例1
将厚度为0.2mm、面积为16cm2的聚碳酸酯基板依次用甲醇、乙醇及去离子水洗涤1次，晾干，放置于真空镀膜机中，在真空度为2×10-3Pa下依次蒸镀25nm厚的2-氨基-3,8-二氰基-4,7-二(2-萘基)-5-苯基喹啉层、5nm厚的氟化锂层、45nm厚的(2-亚苯并噻唑啉基)丙二腈层、10nm厚的锌层以及55nm厚的四(4-甲基-7-香豆素氧甲基)甲烷层，各镀层沉积速率均为0.12nm/s，得红橙黄三稳态光致变色薄膜；用白光、波长为365nm的紫外光以及波长为254nm的紫外光分别照射上述光致变色薄膜1分钟，用测色仪检测光照后的光致变色薄膜的颜色分别为绿色、黄色及蓝色。
实施例2
将厚度为0.2mm、面积为16cm2的聚碳酸酯基板依次用甲醇、乙醇及去离子水洗涤1次，晾干，放置于真空镀膜机中，在真空度为2×10-3Pa下依次蒸镀25nm厚的2-氨基-3,8-二氰基-4,7-二(2-萘基)-5-苯基喹啉层、45nm厚的(2-亚苯并噻唑啉基)丙二腈层、10nm厚的锌层以及55nm厚的四(4-甲基-7-香豆素氧甲基)甲烷层，各镀层沉积速率均为0.12nm/s，得多层复合薄膜；用白光、波长为365nm的紫外光以及波长为254nm的紫外光分别照射上述多层复合薄膜1分钟，用测色仪检测光照后的多层复合薄膜的颜色分别为绿色、绿色及绿色。
实施例3
将厚度为0.2mm、面积为16cm2的聚碳酸酯基板依次用甲醇、乙醇及去离子水洗涤1次，晾干，放置于真空镀膜机中，在真空度为2×10-3Pa下依次蒸镀25nm厚的2-氨基-3,8-二氰基-4,7-二(2-萘基)-5-苯基喹啉层、5nm厚的氟化锂层、45nm厚的(2-亚苯并噻唑啉基)丙二腈层以及55nm厚的四(4-甲基-7-香豆素氧甲基)甲烷层，各镀层沉积速率均为0.12nm/s，得多层复合薄膜；用白光、波长为365nm的紫外光以及波长为254nm的紫外光分别照射上述多层复合薄膜1分钟，用测色仪检测光照后的多层复合薄膜的颜色分别为绿色、绿色及绿色。
实施例4
将厚度为0.2mm、面积为16cm2的聚碳酸酯基板依次用甲醇、乙醇及去离子水洗涤1次，晾干，放置于真空镀膜机中，在真空度为2×10-3Pa下依次蒸镀5nm厚的氟化锂层、45nm厚的(2-亚苯并噻唑啉基)丙二腈层、10nm厚的锌层以及55nm厚的四(4-甲基-7-香豆素氧甲基)甲烷层，各镀层沉积速率均为0.12nm/s，得多层复合薄膜；用白光、波长为365nm的紫外光以及波长为254nm的紫外光分别照射上述多层复合薄膜1分钟，用测色仪检测光照后的多层复合薄膜的颜色分别为浅绿色、浅绿色及浅绿色。
实施例5
将厚度为0.2mm、面积为16cm2的聚碳酸酯基板依次用甲醇、乙醇及去离子水洗涤1次，晾干，放置于真空镀膜机中，在真空度为2×10-3Pa下依次蒸镀25nm厚的2-氨基-3,8-二氰基-4,7-二(2-萘基)-5-苯基喹啉层、5nm厚的氟化锂层、10nm厚的锌层以及55nm厚的四(4-甲基-7-香豆素氧甲基)甲烷层，各镀层沉积速率均为0.12nm/s，得多层复合薄膜；用白光、波长为365nm的紫外光以及波长为254nm的紫外光分别照射上述多层复合薄膜1分钟，用测色仪检测光照后的多层复合薄膜的颜色分别为黄绿色、黄绿色及黄绿色。
实施例6
将厚度为0.2mm、面积为16cm2的聚碳酸酯基板依次用甲醇、乙醇及去离子水洗涤1次，晾干，放置于真空镀膜机中，在真空度为2×10-3Pa下依次蒸镀25nm厚的2-氨基-3,8-二氰基-4,7-二(2-萘基)-5-苯基喹啉层、5nm厚的氟化锂层、45nm厚的(2-亚苯并噻唑啉基)丙二腈层、10nm厚的锌层，各镀层沉积速率均为0.12nm/s，得多层复合薄膜；用白光、波长为365nm的紫外光以及波长为254nm的紫外光分别照射上述多层复合薄膜1分钟，用测色仪检测光照后的多层复合薄膜的颜色分别为灰白色、灰白色及灰白色。
实施例7
将厚度为0.2mm、面积为16cm2的聚碳酸酯基板依次用甲醇、乙醇及去离子水洗涤1次，晾干，放置于真空镀膜机中，在真空度为2×10-3Pa下依次蒸镀25nm厚的四(4-甲基-7-香豆素氧甲基)甲烷层、5nm厚的氟化锂层、45nm厚的(2-亚苯并噻唑啉基)丙二腈层、10nm厚的锌层以及55nm厚的2-氨基-3,8-二氰基-4,7-二(2-萘基)-5-苯基喹啉层，各镀层沉积速率均为0.12nm/s，得多层复合薄膜；用白光、波长为365nm的紫外光以及波长为254nm的紫外光分别照射上述多层复合薄膜1分钟，用测色仪检测光照后的多层复合薄膜的颜色分别为黄色、黄色及黄色。

Claims (1)

1.一种五层夹心结构三稳态光致变色薄膜的制备方法，其特征在于具体步骤如下：
将厚度为0.2mm、面积为16cm2的聚碳酸酯基板依次用甲醇、乙醇及去离子水洗涤1次，晾干，放置于真空镀膜机中，在真空度为2×10-3Pa下依次蒸镀25nm厚的2-氨基-3,8-二氰基-4,7-二(2-萘基)-5-苯基喹啉层、5nm厚的氟化锂层、45nm厚的(2-亚苯并噻唑啉基)丙二腈层、10nm厚的锌层以及55nm厚的四(4-甲基-7-香豆素氧甲基)甲烷层，得五层夹心结构三稳态光致变色薄膜；用白光、波长为365nm的紫外光以及波长为254nm的紫外光分别照射五层夹心结构三稳态光致变色薄膜1分钟，用测色仪检测光照后的五层夹心结构三稳态光致变色薄膜的颜色。
CN201710685519.1A 2017-08-11 2017-08-11 五层夹心结构三稳态光致变色薄膜的制备方法 Pending CN107475673A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710685519.1A CN107475673A (zh) 2017-08-11 2017-08-11 五层夹心结构三稳态光致变色薄膜的制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710685519.1A CN107475673A (zh) 2017-08-11 2017-08-11 五层夹心结构三稳态光致变色薄膜的制备方法

Publications (1)

Publication Number Publication Date
CN107475673A true CN107475673A (zh) 2017-12-15

Family

ID=60600332

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710685519.1A Pending CN107475673A (zh) 2017-08-11 2017-08-11 五层夹心结构三稳态光致变色薄膜的制备方法

Country Status (1)

Country Link
CN (1) CN107475673A (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110408892A (zh) * 2019-08-06 2019-11-05 太仓碧奇新材料研发有限公司 一种多功能光致阻变薄膜的制备方法
CN110453180A (zh) * 2019-08-06 2019-11-15 太仓碧奇新材料研发有限公司 一种多功能光散射薄膜的制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101293409A (zh) * 2008-06-19 2008-10-29 复旦大学 一种具有层叠结构的金属-有机复合功能薄膜及其应用
CN104880885A (zh) * 2015-04-30 2015-09-02 上方能源技术(杭州)有限公司 一种电致变色玻璃的驱动方式

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101293409A (zh) * 2008-06-19 2008-10-29 复旦大学 一种具有层叠结构的金属-有机复合功能薄膜及其应用
CN104880885A (zh) * 2015-04-30 2015-09-02 上方能源技术(杭州)有限公司 一种电致变色玻璃的驱动方式

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110408892A (zh) * 2019-08-06 2019-11-05 太仓碧奇新材料研发有限公司 一种多功能光致阻变薄膜的制备方法
CN110453180A (zh) * 2019-08-06 2019-11-15 太仓碧奇新材料研发有限公司 一种多功能光散射薄膜的制备方法

Similar Documents

Publication Publication Date Title
Corredor et al. Photochromic polymer composites for two-photon 3D optical data storage
Myles et al. 1, 2‐Dithienylethene photochromes and non‐destructive erasable memory
Ummadisingu et al. Revealing the detailed path of sequential deposition for metal halide perovskite formation
Belfield et al. Two-photon photochromism of an organic material for holographic recording
Chen et al. An ultrawide-range photochromic molecular fluorescence emitter
Ishow et al. Two-photon fluorescent holographic rewritable micropatterning
Mori et al. One-color reversible control of photochromic reactions in a diarylethene derivative: three-photon cyclization and two-photon cycloreversion by a near-infrared femtosecond laser pulse at 1.28 μm
Dvornikov et al. Spectroscopy and kinetics of a molecular memory with nondestructive readout for use in 2D and 3D storage systems
Panzer et al. Reversible Laser‐Induced Amplified Spontaneous Emission from Coexisting Tetragonal and Orthorhombic Phases in Hybrid Lead Halide Perovskites
JP5117679B2 (ja) 多光子吸収材料を用いた色素材料、色素材料の製造方法、多光子吸収反応材料、多光子吸収反応材料の反応生成物、多光子吸収反応助剤、および色素溶液
Métivier et al. Fluorescence photoswitching in polymer matrix: mutual influence between photochromic and fluorescent molecules by energy transfer processes
Murase et al. Photochemically induced fluorescence control with intermolecular energy transfer from a fluorescent dye to a photochromic diarylethene in a polymer film
Hong et al. Visible-light-driven bistable photoswitching with enhanced solid state NIR-fluorescence for multi-level optical storage
JP2009221563A (ja) 金ナノロッドとその製造方法、金ナノロッドを用いた電磁波吸収体、色材、光記録材料および二光子反応材料
Karpach et al. Photoinduced reversible modulation of fluorescence of CdSe/ZnS quantum dots in solutions with diarylethenes
JP2008310326A (ja) インクレス再画像形成可能な印刷用紙および方法
JP2005250463A (ja) 光学記録媒体及び光学記録方法
Pariani et al. Kinetics of photochromic conversion at the solid state: Quantum yield of dithienylethene-based films
CN107475673A (zh) 五层夹心结构三稳态光致变色薄膜的制备方法
CN109346110B (zh) 应用于彩色全息存储的碳基纳米复合薄膜及其制造方法
US7964333B1 (en) FRET-based two photon three dimensional optical data storage
Christenson et al. Nonlinear fluorescence modulation of an organic dye for optical data storage
CN110577368A (zh) 一种CDs/TiO2薄膜及其制备方法和应用
Żmija et al. New organic photochromic materials and selected applications
JP4368148B2 (ja) フィルム、フィルムを用いた光メモリ材料、および、フィルムの製造方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20171215