CN107815234A - Termite-proof Furniture panel coating and production method - Google Patents
Termite-proof Furniture panel coating and production method Download PDFInfo
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- CN107815234A CN107815234A CN201711166242.8A CN201711166242A CN107815234A CN 107815234 A CN107815234 A CN 107815234A CN 201711166242 A CN201711166242 A CN 201711166242A CN 107815234 A CN107815234 A CN 107815234A
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- termite
- proof
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- furniture panel
- production method
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- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 2
- GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical compound CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 claims description 2
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of termite-proof Furniture panel coating and production method, the raw material that it includes has polyurethane, epoxy resin, emulsion, tossa, composite coupler, water, termite-proof medicament, thickener, anti-wear agent, levelling agent, defoamer, the termite-proof Furniture panel coating paint adhesion of the present invention is strong, it is not easy to peel off, peeling will not be produced, it is wear-resisting, acid-alkali-corrosive-resisting, salt fog resistance is excellent, product is heat-resisting, it is cold-resistant, service life is grown, improve the hardness of paint film of coatings for furniture, improve anti-after tack, greatly shorten drying time, non-toxic, environmental friendly, its film not only has excellent surface gloss, richness, hardness, water resistance, chemical proofing, and pliability is good, it is small to solidify post-shrinkage ratio, air-drying property is good, its preparation method is fairly simple simultaneously, cost is than less expensive.Termide-proof and insect-proof efficiency high, decorative effect are good, easy construction.
Description
Technical field
The present invention relates to a kind of coatings for furniture, more particularly to termite-proof Furniture panel coating and production method.
Background technology
Wood furniture has the features such as Environmental Safety, elegant in appearance, is the preferred furniture of many families.But if will
Timber is exposed outside, it is easy to is infected with dirt, is also easy to be worn.Therefore, typically all can be in the wood surface of wood furniture
Coast of paint is coated, for protecting timber in itself.
At present, the consumption of coating per capita of developed country reaches more than 10kg, and modern coatings industry turns into modern chemistry
One important industry of industry.China is currently global maximum Furniture manufacturing and big export country, can all be consumed every year substantial amounts of
Coatings for furniture（Often it is referred to as " woodcare paint "）.
With the development of China's economic, the raising and improvement of living standards of the people, Chinese indoor environment cause has length
The development of foot, people are improving constantly to living environment pollution consciousness, but aggregate level still allows of no optimist, and room air is dirty
Dye is still one of primary killers for polluting health.It is introduced that at present Chinese indoor environment primary pollution source from build,
Decoration and furniture, formaldehyde, benzene, ammonia pollute the exceeded health for having had a strong impact on people.
At present, in the market coatings for furniture uses modified alkyd resin, polyester resin, polyurethane, toluene and some additives,
These additives, which work it out coatings for furniture, can discharge toxic gas, seriously endanger the health of human body, and its is inflammable and explosive, makes
Production and transportation generate great potential safety hazard.Existing timber paint has pollution to environment, human body is harmful to, it is impossible to full
The needs of sufficient people's daily life.
Termite-proof coating, this kind of Coating Market are in great demand, but this kind of coating is never applied well
And development, its main cause are to be that such coating can kill the ageing too short of the sanitary insect pests such as mosquitos and flies, i.e., coating is firm
It is fine to various Pest killing effects in the short time of application, but the continuation of this effect is too short.
The content of the invention
The purpose of the present invention is overcome the deficiencies in the prior art, there is provided a kind of termite-proof Furniture panel coating and producer
Method, having prevents termite damage furniture, and efficacy is lasting, non-volatile, can be retained in for a long time in film, good timeliness
The characteristics such as property.
Termite-proof Furniture panel coating and production method, it includes the raw material of following parts by weight：
40~60 parts of polyurethane,
30~50 parts of epoxy resin,
5~15 parts of emulsion,
10~20 parts of tossa,
2~4 parts of composite coupler,
20~25 parts of water,
Termite-proof 3~5 parts of medicament,
1~3 part of thickener,
1~4 part of anti-wear agent,
1~3 part of levelling agent,
2~3 parts of defoamer；
The polyurethane, it is the polyurethane, is water curable type polyurethane, IPDI is made with polyethylene glycol reaction
Standby performed polymer, using glycerine and trimethylolpropane as chain extender, hexadecanol is end-capping reagent, and the water for being prepared for hub-and-spoke configuration is consolidated
Property polyurethane；
The epoxy resin, it is modified epoxy, with epoxy resin esterification occurs for phosphoric acid, makees to draw with benzoyl peroxide
Agent is sent out, forms active methylene group free radical, then be total to acrylic acid, styrene, butyl acrylate and methyl methacrylate-grafted
It is poly-, finally neutralized with N, N- dimethylethanolamines, obtain modified epoxy；
The emulsion, it is styrene and acrylate by weight proportion 1:The styrene-acrylic emulsion that 1 copolymerization forms；
The tossa, 0.3 μm of silk powder is less than for granularity；
The composite coupler, be vinyl triacyloxysilanes and 3-（2,3 the third oxygen of epoxy）Propyl trimethoxy silicane mixes
Close, part by weight 1:2；
The termite-proof medicament, the termite-proof medicament, it is Frontline and chrysanthemum esters by weight proportion 1:3 ratio mixing；
The thickener, it is hydroxyethyl cellulose；
The anti-wear agent, it is one or more mixing of carborundum, fine-grained alumina or mineral powder；
The levelling agent, it is acetylbutyrylcellulose；
The defoamer, organic silicon defoamer.
Termite-proof Furniture panel coating, production process comprise the following steps：
（1）, sequentially add the water of formula ratio, termite-proof medicament, thickener, anti-wear agent, levelling agent, 1/2 defoaming in a mixer
Agent, stir, rotating speed is 300 revs/min, is stirred 15~25 minutes, forms colloidal solution；
（2）, by step（1）Resulting solution is ground to granularity as within 30 microns by skin grinder, then solution is put back into blender；
（3）, tossa, polyurethane mixed in formulation weight ratio, rotating speed is 1000~1500 revs/min, obtains mixing molten
Liquid；
（4）, by step（3）The mixed solution input step of gained（2）In blender；
（5）, put into epoxy resin, composite coupler, emulsion, 1/2 defoamer successively into blender again, with step（4）In
Solution mixes, and stirs, and rotating speed is to 300~400 revs/min；
（6）, be filtered to remove coarse granule and impurity.
By coating hardened coating in the timber for forming furniture, after being handled with drier, then at assembly.
Compared with prior art, the substantive distinguishing features that the present invention protrudes and significantly progress are：
1st, polyurethane
Polyurethane is a kind of polymer of the main chain containing-NHCOO-constitutional repeating unit, english abbreviation PU, and aqueous polyurethane is
Using water as decentralized medium, polyurethane resin is dissolved or dispersed in the binary colloid system formed in water, with the water-based of its preparation
Without or with minimal amount of organic solvent in polyurethane coating.Aqueous polyurethane coating, not only with nontoxic odorless, without dirt
Dye, nonflammable, cost is low, not easy damaged, by coating surface it is easy for construction, be easy to cleaning the advantages that, also gather with solvent-borne type
The excellent properties such as the intrinsic high rigidity of urethane coating, wear-resistant, thus in woodwork coating, car paint, building coating, plastics
Many fields such as coating, paper coating and fabric and leather finish are widely used, and are welcome by user.
Due to containing highly polar carbamate groups, insoluble in non-polar group, there is good oil resistivity, toughness, resistance to
Mill property, resistance to ag(e)ing and cohesive.
2nd, epoxy resin
In today that environmental consciousness constantly strengthens, Environmentally friendly coatings increasingly show its importance.Epoxy resin has excellent
Different physical and chemical performance, especially with excellent water resistance, chemical-resistant, splendid Adhesion property and be widely used in coating
Field, it is one of coatings industry B-C post product, thus environmental protection coating material is also one of study hotspot of coating circle.Realize low VOC
Approach predominantly greatly develop the new coatings such as high solid coating, water paint, powdery paints and radiation curable coating.
It is pollution-free, and melting viscosity is low, and film is firm, good leveling property, it is not necessary to which primer coating film, mechanical property is good, has excellent
Different reactivity and storage-stable, corrosion resistance, chemical proofing, the color matching of coating well, curing agent range of choice is wide,
Have a wide range of application.
Epoxy resin and termite-proof medicament mixture, termite-proof medicament have most strong poisoning termite performance, and medicine glue compares wood
Material amount loss rate has a great influence, and epoxy resin there is very strong physical isolation to act on, lumber quality loss late without toxic action
Substantially reduce, there is long-term economics and environment protection significance.
3rd, styrene-acrylic emulsion
Styrene-acrylic emulsion is that more system is studied in emulsion polymerization, and there is the ten big non-of essential industry application value the world today
One of cross-linked type latex emulsion.Styrene-acrylic emulsion has very extensive purposes, now main use as a kind of important middle chemical products
Make building coating, metal surface latex paint, floor coating, paper adhesives, adhesive etc..Styrene-acrylic emulsion adhesive force is good, glue
Film is transparent, and water-fast, oil resistant, heat-resisting, ageing-resistant performance is good.Styrene-acrylic emulsion is used as paper product adhesive, also can be with starch, polyethylene
The adhesive such as alcohol, sodium carboxymethylcellulose are used cooperatively.
4th, tossa
Jute (Classification system Corchorus capsularis L), belong to Tiliaceae Corchorus, bast fiber crop, annual grass
This plant, likes the weather of warm and moist, short day crop, alias fire is numb, green fiber crops, network fiber crops, water network are numb, wild mestha, circle fruit jute,
Circle capsule jute, bitter sesame slices, ox mud thatch, three pearls grass, day purple perilla, boon are first-class, are a kind of length and softness, glossiness plant fibre
Dimension, the coarse filament of high intensity can be made into.Tossa is one of most cheap natural fiber, plantation amount and purposes it is wide
It is general to be all only second to cotton, have the characteristics that moisture pick-up properties is good, the moisture that scatters and disappears is fast.
With the increase for adding tossa quality, the weight-loss ratio of coating gradually reduces, and improves the intensity of coating, jute
There are higher specific strength and specific modulus, preferable wellability, good natural antibacterial performance.
As world's every profession and trade is towards green, degradable, low energy consumption, low emission, light-weighted development, jute reinforcing material
There is superior prospects for commercial application.
5th, composite coupler
Composite coupler by vinyl triacyloxysilanes and 3-（2,3 the third oxygen of epoxy）Propyl trimethoxy silicane is combined,
Coupling agent is the bridge between organic binder matter and inorganic filler, makes filler more preferable, is dispersed in faster in organic matter.Can
Improve the adhesive force of coating（Make the combination of organic matter and coat side closer）Improve the durability of coating, weatherability, toughness
（Make the combination of organic matter and filling paint closer）Painting color is evenly（The dispersion viscosity of filler is reduced, in organic matter
It is scattered evenly）.
For silane coupler after coatings, silane can move to the interface of coating and ground, close inorganic group with it is inorganic
Reaction of moisture on surface, hydrogen bond is formed, makes coating more firm combined with interface.It is even if silane coupled under the conditions of water logging
The coating that agent is modified still adheres to well in various inorganic surface of bottom material.
Silane coupler be used for priming coat enhancing ground with apply interlayer adhesion, for improve pigment or filler molten
The dispersiveness of agent coating or water paint；For the modification of coating resin, so that new functional paint is made.Silane is used as promoting
The additive of adhesive force, coating is set to be incorporated on various different surface of bottom material, such combination is not only reduced in wet environment
Corrosion and the peeling of paint film, and marresistance and environment resistant can be improved.Silane is widely used in acrylate, asphalt mixtures modified by epoxy resin
It is effective in solvent borne, high solidity and water paint in fat and polyurethane coating, it can both use as priming paint, also might be used
To admix auxiliary agent use.Silane can also play pigment dispersing agent and bonding agent in coating, and they can be firmly bonded to
On various inorganic pigments and filler, silane is once attached on the surface of filler, and they are filled out with regard to that can reduce the viscosity of coating, improvement
The dispersiveness of material, so as to improve covering power and improve the durability and scrubbability of coating.
6th, termite-proof medicament
Termite-proof medicament is mixed by Frontline with chrysanthemum esters.
Strength spy is a kind of Phenylpyrazole insecticides, desinsection wide spectrum, to insect based on stomach poison function, has concurrently and tags and one
Fixed systemic action, its insecticidal mechanism is the chloride metabolism for hindering the control of insect γ-aminobutyric acid, a kind of to numerous species
Insect all has the broad spectrum insecticide of outstanding preventive effect, and it is to insects such as Semiptera, Lepidoptera, Thysanoptera, coleoptera and right
The insect that cyclopentadiene, chrysanthemum esters, carbamate insecticides have developed immunity to drugs all has high sensitiveness.
Chrysanthemum esters medicament is broad spectrum insecticide, has quick-acting, efficient, less toxic, low-residual, the features such as to crop safety,
In addition to having special efficacy to the preventing and treating of 140 various pests, some pyrethrin pesticides also have preferable preventing and treating to subterranean pest-insect and mite pest
Effect.
7th, thickener
Thickener is a kind of auxiliary rheological agents, can not only thicken coating, prevents sagging phenomenon occur in construction, and can assign
The excellent mechanical performance of coating and bin stability.It is that very important one kind helps for the relatively low water paint of viscosity
Agent.
Hydroxyethyl cellulose (HEC) is a kind of white or faint yellow, tasteless, nontoxic threadiness or pulverulent solids, by
Alkali cellulose and oxirane（Or chlorethanol）Prepared by etherified reaction, belong to nonionic soluble fibre element ethers.Due to HEC
With good thickening, suspension, scattered, emulsification, bonding, film forming, protection moisture and the characteristics such as protecting colloid are provided, it is extensive
Apply in fields such as oil exploitation, coating, building, medicine food, weaving, papermaking and macromolecular polymerization reactions.
8th, anti-wear agent
Coating is a kind of additive for improving film abrasion resistance with anti-wear agent.It is resistance to bearing friction addition in use
Mill
After agent, the film abrasion loss caused by friction is reduced, so as to extend the service life of film and service life, or
Improve processability.
The wearability of film refers to resist coating film friction, scratch, a kind of ability corroded, has with many performances of film
Close, bag
Include hardness, scratch resistance, cohesive force, tensile strength, modulus of elasticity and toughness etc..It is generally acknowledged that the toughness of film is resistance to its
The influence of mill property is more than influence of the hardness of film to its wearability.
After coating adds anti-wear agent and solidification of constructing, most of anti-wear agent micro- can protrude from film coated surface, and be uniform
Distribution, when film is by friction behavior, its wearing part is the highest part for protruding from film coated surface first, i.e. anti-wear agent portion
Point.Actually film, which is protected, exempts from or is rubbed less.In use, anti-wear agent applies film such as " aggregate ", " sharing "
The frictional force that film is born, so as to extend the service life of film, assign film wearability.
9th, levelling agent
Levelling agent is a kind of conventional coating additive, it can promote coating formed during drying and forming-film one it is smooth, smooth,
Uniform film.It can effectively reduce and cover with paint, lacquer, colour wash, etc. liquid surface tension, improve its levelability and a kind of material of uniformity.Covering with paint can be improved
The permeability of liquid, the possibility that spot and spot are produced when brushing can be reduced, increase coverage property, makes film forming uniform, natural.
10th, defoamer
Avoid that foam occurs, it is really impossible in the making of water paint, thus defoaming measure must be taken.As before
Described, all be present bubble problem in water paint making, the multiple working procedure used, certainly will will be pacified per sequence using mechanical defoaming method
If set of device.So the defoaming of water paint, is all using the method for adding defoamer, in fact, in all water paints all
Defoamer be present.
11st, paint adhesion is strong, is not easy to peel off, and will not produce peeling, and wear-resisting, acid-alkali-corrosive-resisting, salt fog resistance is excellent, production
Product are heat-resisting, cold-resistant, service life length, when improving the hardness of paint film of coatings for furniture, improving anti-after tack, greatly shorten dry
Between, non-toxic, environmental friendly, adhesion property is excellent, its film not only have excellent surface gloss, richness, hardness, water resistance,
Chemical proofing, and pliability is good, and solidification post-shrinkage ratio is small, and air-drying property is good, while its preparation method is fairly simple, cost
Than less expensive.Termide-proof and insect-proof efficiency high, decorative effect are good, easy construction.
Embodiment
Described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.Based on the present invention
In embodiment, all other implementation that those of ordinary skill in the art are obtained under the premise of creative work is not made
Example, belongs to the scope of protection of the invention.
Embodiment 1
Termite-proof Furniture panel coating and production method, it includes the raw material of following parts by weight：40 parts of polyurethane, epoxy resin
30 parts, 5 parts of emulsion, 10 parts of tossa, 2 parts of composite coupler, 20 parts of water, termite-proof 3 parts of medicament, hydroxyethyl cellulose thickening
1 part of agent, 1 part of carborundum anti-wear agent, 1 part of acetylbutyrylcellulose levelling agent, 2 parts of defoamer；
Termite-proof Furniture panel coating, production process comprise the following steps：
（1）, sequentially add the water of formula ratio, termite-proof medicament, thickener, anti-wear agent, levelling agent, 1/2 defoaming in a mixer
Agent, stir, rotating speed is 300 revs/min, is stirred 15 minutes, forms colloidal solution；
（2）, by step（1）Resulting solution is ground to granularity as within 30 microns by skin grinder, then solution is put back into blender；
（3）, by tossa, polyurethane in formulation weight ratio mix, rotating speed be 1000 revs/min, obtain mixed solution；
（4）, by step（3）The mixed solution input step of gained（2）In blender；
（5）, put into epoxy resin, composite coupler, emulsion, 1/2 defoamer successively into blender again, with step（4）In
Solution mixes, and stirs, and rotating speed is to 300 revs/min；
（6）, be filtered to remove coarse granule and impurity.
Embodiment 2
Termite-proof Furniture panel coating and production method, it includes the raw material of following parts by weight：45 parts of polyurethane, epoxy resin
40 parts, 10 parts of emulsion, 12 parts of tossa, 3 parts of composite coupler, 23 parts of water, termite-proof 4 parts of medicament, hydroxyethyl cellulose increasing
Thick dose 2 parts, 2 parts of carborundum anti-wear agent, 2 parts of acetylbutyrylcellulose levelling agent, 3 parts of defoamer；
Termite-proof Furniture panel coating, production process comprise the following steps：
（1）, sequentially add the water of formula ratio, termite-proof medicament, thickener, anti-wear agent, levelling agent, 1/2 defoaming in a mixer
Agent, stir, rotating speed is 300 revs/min, is stirred 20 minutes, forms colloidal solution；
（2）, by step（1）Resulting solution is ground to granularity as within 30 microns by skin grinder, then solution is put back into blender；
（3）, by tossa, polyurethane in formulation weight ratio mix, rotating speed be 1200 revs/min, obtain mixed solution；
（4）, by step（3）The mixed solution input step of gained（2）In blender；
（5）, put into epoxy resin, composite coupler, emulsion, 1/2 defoamer successively into blender again, with step（4）In
Solution mixes, and stirs, and rotating speed is to 400 revs/min；
（6）, be filtered to remove coarse granule and impurity.
Embodiment 3
Termite-proof Furniture panel coating and production method, it includes the raw material of following parts by weight：50 parts of polyurethane, epoxy resin
50 parts, 15 parts of emulsion, 15 parts of tossa, 4 parts of composite coupler, 25 parts of water, termite-proof 5 parts of medicament, hydroxyethyl cellulose increasing
Thick dose 3 parts, 3 parts of mineral powder anti-wear agent, 3 parts of acetylbutyrylcellulose levelling agent, 3 parts of defoamer；
Termite-proof Furniture panel coating, production process comprise the following steps：
（1）, sequentially add the water of formula ratio, termite-proof medicament, thickener, anti-wear agent, levelling agent, 1/2 defoaming in a mixer
Agent, stir, rotating speed is 300 revs/min, is stirred 25 minutes, forms colloidal solution；
（2）, by step（1）Resulting solution is ground to granularity as within 30 microns by skin grinder, then solution is put back into blender；
（3）, by tossa, polyurethane in formulation weight ratio mix, rotating speed be 1500 revs/min, obtain mixed solution；
（4）, by step（3）The mixed solution input step of gained（2）In blender；
（5）, put into epoxy resin, composite coupler, emulsion, 1/2 defoamer successively into blender again, with step（4）In
Solution mixes, and stirs, and rotating speed is to 400 revs/min；
（6）, be filtered to remove coarse granule and impurity.
Embodiment 4
Termite-proof Furniture panel coating and production method, it includes the raw material of following parts by weight：60 parts of polyurethane, epoxy resin
50 parts, 15 parts of emulsion, 20 parts of tossa, 4 parts of composite coupler, 25 parts of water, termite-proof 5 parts of medicament, hydroxyethyl cellulose increasing
Thick dose 3 parts, 4 parts of mineral powder anti-wear agent, 3 parts of acetylbutyrylcellulose levelling agent, 3 parts of defoamer；
Termite-proof Furniture panel coating, production process comprise the following steps：
（1）, sequentially add the water of formula ratio, termite-proof medicament, thickener, anti-wear agent, levelling agent, 1/2 defoaming in a mixer
Agent, stir, rotating speed is 300 revs/min, is stirred 25 minutes, forms colloidal solution；
（2）, by step（1）Resulting solution is ground to granularity as within 30 microns by skin grinder, then solution is put back into blender；
（3）, by tossa, polyurethane in formulation weight ratio mix, rotating speed be 1500 revs/min, obtain mixed solution；
（4）, by step（3）The mixed solution input step of gained（2）In blender；
（5）, put into epoxy resin, composite coupler, emulsion, 1/2 defoamer successively into blender again, with step（4）In
Solution mixes, and stirs, and rotating speed is to 400 revs/min；
（6）, be filtered to remove coarse granule and impurity.
After testing, quality and technical index is as follows：
0 grade represents that performance is best, and 1 grade is taken second place, and 5 grades worst.
Claims (9)
1. termite-proof Furniture panel coating and production method, it is characterised in that it includes the raw material of following parts by weight：
40~60 parts of polyurethane,
30~50 parts of epoxy resin,
5~15 parts of emulsion,
10~20 parts of tossa,
2~4 parts of composite coupler,
20~25 parts of water,
Termite-proof 3~5 parts of medicament,
1~3 part of thickener,
1~4 part of anti-wear agent,
1~3 part of levelling agent,
2~3 parts of defoamer；
Described termite-proof Furniture panel coating, production process comprise the following steps：
（1）, sequentially add the water of formula ratio, termite-proof medicament, thickener, anti-wear agent, levelling agent, 1/2 defoaming in a mixer
Agent, stir, rotating speed is 300 revs/min, is stirred 15~25 minutes, forms colloidal solution；
（2）, by step（1）Resulting solution is ground to granularity as within 30 microns by skin grinder, then solution is put back into blender；
（3）, tossa, polyurethane mixed in formulation weight ratio, rotating speed is 1000~1500 revs/min, obtains mixing molten
Liquid；
（4）, by step（3）The mixed solution input step of gained（2）In blender；
（5）, put into epoxy resin, composite coupler, emulsion, 1/2 defoamer successively into blender again, with step（4）In
Solution mixes, and stirs, and rotating speed is to 300~400 revs/min；
（6）, be filtered to remove coarse granule and impurity.
2. termite-proof Furniture panel coating according to claim 1 and production method, it is characterised in that the polyurethane,
For water curable type polyurethane, IPDI prepares performed polymer with polyethylene glycol reaction, with glycerine and trihydroxy methyl
For propane as chain extender, hexadecanol is end-capping reagent, is prepared for the water curable polyurethane of hub-and-spoke configuration.
3. termite-proof Furniture panel coating according to claim 1 and production method, it is characterised in that the asphalt mixtures modified by epoxy resin
Fat, it is modified epoxy, with epoxy resin esterification occurs for phosphoric acid, makees initiator with benzoyl peroxide, is formed active
Methylene free radicals, then be copolymerized with acrylic acid, styrene, butyl acrylate and methyl methacrylate-grafted, finally with N, N-
Dimethylethanolamine neutralizes, and obtains modified epoxy.
4. termite-proof Furniture panel coating according to claim 1 and production method, it is characterised in that the emulsion, be
Styrene and acrylate by weight proportion 1:The styrene-acrylic emulsion that 1 copolymerization forms.
5. termite-proof Furniture panel coating according to claim 1 and production method, it is characterised in that the jute is fine
Dimension, 0.3 μm of silk powder is less than for granularity.
6. termite-proof Furniture panel coating according to claim 1 and production method, it is characterised in that the compound coupling
Agent, be vinyl triacyloxysilanes and 3-（2,3 the third oxygen of epoxy）Propyl trimethoxy silicane mixes, part by weight 1:2.
7. termite-proof Furniture panel coating according to claim 1 and production method, it is characterised in that the termite-proof medicine
Agent, the termite-proof medicament, it is Frontline and chrysanthemum esters by weight proportion 1:3 ratio mixing.
8. termite-proof Furniture panel coating according to claim 1 and production method, it is characterised in that the anti-wear agent,
For the one or more mixing of carborundum, fine-grained alumina or mineral powder.
9. termite-proof Furniture panel coating according to claim 1 and production method, it is characterised in that the thickener,
For hydroxyethyl cellulose；The levelling agent, it is acetylbutyrylcellulose；The defoamer, it is organic silicon defoamer.
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| CN116496683A (en) * | 2023-03-09 | 2023-07-28 | 广州翔铭环保新材料有限公司 | Preparation method of water-based UV (ultraviolet) coating |
| CN116784349A (en) * | 2023-06-16 | 2023-09-22 | 中国林业科学研究院木材工业研究所 | Insect-resist agent for artificial board and preparation and use methods thereof |
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Application publication date: 20180320 |