CN108049011A - A kind of preparation method of Roman cloth - Google Patents
A kind of preparation method of Roman cloth Download PDFInfo
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- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
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Abstract
Description
技术领域technical field
本发明涉及纺织品制备技术领域,更具体地说,它涉及一种罗马布的制备方法。The invention relates to the technical field of textile preparation, more specifically, it relates to a method for preparing Roman cloth.
背景技术Background technique
罗马布是一种由大圆机织成的针织面料,俗称打鸡布,罗马布的布面没有普通双面布平整,面料横竖弹性都较好,但横向拉伸性能不如双面布,吸湿性强,用于制作贴身衣物,透气,柔软,穿着舒适。Roman cloth is a kind of knitted fabric woven by a large circular machine, commonly known as chicken cloth. The cloth surface of Roman cloth is not as smooth as ordinary double-sided cloth. Strong, used to make close-fitting clothing, breathable, soft and comfortable to wear.
锦纶具有优异的强力、耐磨性及手感柔软、质感轻盈等良好的服用性能,同时锦纶织物的回潮率较高,达4.5%-7%,是罗马布常用的纤维材料;氨纶弹性优异、强度高且耐酸碱性、耐汗、耐海水性、耐干洗性、耐磨性均较好。由于锦纶和氨纶的优异性能,罗马布常采用锦纶和氨纶的混纺纤维。锦/氨纶混纺罗马布具有吸湿效果好、横向竖向的弹性均较好,且耐磨、耐汗等。Nylon has good wearing properties such as excellent strength, abrasion resistance, soft hand feeling and light texture. At the same time, nylon fabric has a high moisture regain rate of 4.5%-7%, which is a commonly used fiber material for Roman cloth; spandex has excellent elasticity and strength. High acid and alkali resistance, sweat resistance, sea water resistance, dry cleaning resistance, abrasion resistance are good. Due to the excellent properties of nylon and spandex, blended fibers of nylon and spandex are often used in Roman cloth. Nylon/spandex blended Roman cloth has good moisture absorption effect, good horizontal and vertical elasticity, and is wear-resistant and sweat-resistant.
目前,公布号为CN104818570A的中国发明专利公开了一种针织全锦纶罗马布及其生产工艺,属于纺织面料的技术领域,采用70D的锦纶和40D的氨纶加捻后的纱线织造而成,或者采用50D的锦纶和40D的氨纶加捻后的纱线织造而成,具体包括以下步骤:将70D的锦纶和40D的氨纶加捻后的纱线织造成坯布,或者将50D的锦纶和40D的氨纶加捻后的纱线织造成坯布→退卷→冷堆→平整→预定→前处理→染色→开幅→烘干→成品定型→打卷、包装,其中染色工序采用酸性染料。At present, the Chinese invention patent with the publication number CN104818570A discloses a knitted all-nylon roman cloth and its production process, which belongs to the technical field of textile fabrics, and is woven from twisted yarns of 70D nylon and 40D spandex, or It is woven with 50D nylon and 40D spandex twisted yarn, which specifically includes the following steps: Weaving 70D nylon and 40D spandex twisted yarn into gray fabric, or weaving 50D nylon and 40D spandex The twisted yarn is woven into gray fabric→unwinding→cold stacking→leveling→scheduling→pretreatment→dyeing→opening→drying→finished product shaping→rolling and packaging, in which acid dyes are used in the dyeing process.
由于罗马布常用做贴身衣物,因而对于色牢度的要求比较高,传统酸性染料染锦纶的色牢度在3-4级之间,贴身衣服在与外侧衣服摩擦以及受到汗渍的影响,容易掉色沾染外侧衣物。Because Roman cloth is often used as underwear, the requirements for color fastness are relatively high. The color fastness of nylon dyed with traditional acid dyes is between 3 and 4. Underwear is easy to fade when it rubs against the outer clothes and is affected by sweat stains. Stains outer clothing.
发明内容Contents of the invention
针对现有技术存在的不足,本发明的目的在于提供一种罗马布的制备方法,通过采用两次练碱、分批加入染料和固色处理,解决了罗马布受摩擦以及汗渍易褪色的问题,其具有提高罗马布耐摩擦色牢度和耐汗渍色牢度的优点。Aiming at the deficiencies in the prior art, the object of the present invention is to provide a method for preparing Roman cloth, which solves the problems that Roman cloth is rubbed and sweat stains are easy to fade by adopting alkali training twice, adding dyes in batches and color fixing , which has the advantages of improving the color fastness to rubbing and perspiration of Roman cloth.
为实现上述目的,本发明提供了如下技术方案:To achieve the above object, the present invention provides the following technical solutions:
一种罗马布的制备方法,包括以下步骤:A preparation method of Roman cloth, comprising the following steps:
(1)纱线预处理:将锦纶和氨纶纱线在碱液中浸泡一段时间后,取出清洗干净;(1) Yarn pretreatment: After soaking nylon and spandex yarns in lye for a period of time, take them out and clean them;
(2)蒸汽定型:将锦纶和氨纶纱线放入蒸汽罐中,抽真空后向蒸汽罐内充入蒸汽,保持真空罐的温度为100-120℃,保持50-80分钟;(2) Steam setting: put nylon and spandex yarns in a steam tank, fill the steam tank with steam after vacuuming, keep the temperature of the vacuum tank at 100-120°C for 50-80 minutes;
(3)采用大圆机将锦纶和氨纶编织成坯布;(3) Weaving nylon and spandex into gray cloth by large circular knitting machine;
(4)坯布前处理:将坯布浸轧练碱液,取出洗净,将坯布拉幅定型、烧毛;(4) Gray cloth pre-treatment: soak the gray cloth with lye, take it out and wash it, shape and singe the gray cloth;
(5)染色:在染缸中加入染料助剂和第一染料,常温开始升温,升温速度为1-1.5℃/min,升温至60℃,保温30-50min,添加染料助剂和第二染料,以1-2℃/min的速度升温至90℃,保温20-30min,以1.5-2℃/min的速度缓慢降温至40-50℃,取出洗净;(5) Dyeing: Add dye auxiliaries and the first dye to the dye vat, start to heat up at room temperature, the heating rate is 1-1.5°C/min, heat up to 60°C, keep warm for 30-50min, add dye auxiliaries and the second dye, Raise the temperature to 90°C at a speed of 1-2°C/min, keep it warm for 20-30min, and slowly cool down to 40-50°C at a speed of 1.5-2°C/min, take it out and wash it;
(6)固色处理:将洗净的坯布在固色整理液中浸轧后,烘干;(6) Color-fixing treatment: after padding the washed gray cloth in the color-fixing finishing solution, dry it;
(7)后整理:将坯布在后整理液中浸轧,后整理液包括柔软剂、抗静电剂,温度40-45℃,浸轧时间为10-20min,然后将坯布经过热定型机170-180℃,机速40r/min,并适当超喂对坯布定型;(7) After-finishing: pad the gray cloth in the finishing solution, the finishing solution includes softener and antistatic agent, the temperature is 40-45°C, the padding time is 10-20min, and then the gray cloth is passed through a heat setting machine for 170- 180°C, machine speed 40r/min, and proper overfeeding to shape the gray cloth;
(8)检验,打卷包装,得到罗马布。(8) Inspection, rolling and packaging to obtain Roman cloth.
通过上述技术方案,步骤(1)和(4)两次练碱可以去除纱线和坯布附带的油渍、色渍和杂质,降低对后续染色的影响,减少了色花、色点的出现;染色过程中通过缓慢升温和阶梯保温并且分批加入染料,减缓了染料的上染速度,使染色更加均匀;通过在染色后进行固色处理,提高了坯布的色牢度;同时对固色后的织物进行后整理,消除了固色剂使织物手感变硬的缺陷,本发明制备的罗马布受摩擦以及汗渍的影响不易褪色,色牢度好。Through the above-mentioned technical scheme, step (1) and (4) two alkali exercises can remove the oil stains, color stains and impurities attached to the yarn and gray cloth, reduce the impact on subsequent dyeing, and reduce the appearance of color flowers and color spots; dyeing During the process, by slowly heating up and stepwise heat preservation and adding dyes in batches, the dyeing speed of the dyes is slowed down and the dyeing is more uniform; the color fastness of the gray cloth is improved by the color fixing treatment after dyeing; The after-finishing of the fabric eliminates the defect that the color-fixing agent makes the fabric feel hard, and the Roman cloth prepared by the invention is not easy to fade under the influence of friction and perspiration, and has good color fastness.
染色助剂可以采用木质素磺酸钠盐和冰醋酸,也可以采用本领域常规的其他助剂。As the dyeing auxiliaries, lignosulfonic acid sodium salt and glacial acetic acid can be used, and other auxiliaries conventional in the art can also be used.
进一步优选为,所述步骤(1)中碱液浓度为220-250g/L,初始温度控制在40℃,然后以2℃/min缓慢升温至80℃,保温50min后,取出洗净甩干。It is further preferred that the alkali solution concentration in the step (1) is 220-250g/L, the initial temperature is controlled at 40°C, and then the temperature is slowly raised to 80°C at 2°C/min, kept for 50 minutes, taken out, washed and dried.
通过上述技术方案,烧碱溶液可以降解油渍并溶解油渍,提高去油效果,水温控制在40℃可以降低高温条件下碱液对纤维的损伤;同时碱液会使纤维表面局部溶解,释放上染点并且使纤维粗糙,便于后续染料上染纤维,不易脱落,纤维表面粗糙还可以避免滑丝、脱丝,提高手感。Through the above technical scheme, the caustic soda solution can degrade the oil stains and dissolve the oil stains, and improve the oil removal effect. Controlling the water temperature at 40°C can reduce the damage of the alkali solution to the fiber under high temperature conditions; at the same time, the alkali solution will partially dissolve the fiber surface and release the dyed spots. And make the fiber rough, which is convenient for the subsequent dyeing of the fiber, and it is not easy to fall off. The rough surface of the fiber can also avoid slipping and stripping, and improve the hand feeling.
进一步优选为,所述步骤(4)具体包括:将纱线织成的坯布浸轧练碱液,水温控制在40℃,加入练碱液,所述练碱液包括去油剂100-150g/L、渗透剂50-60g/L和烧碱220-250g/L,然后以2℃/min缓慢升温至80℃,保温50min后,取出洗净甩干,将粗坯拉幅定型,调节车速为40r/min,将坯布进行烧毛。Further preferably, the step (4) specifically includes: padding the gray cloth woven from the yarn into lye, controlling the water temperature at 40°C, adding lye, and the lye includes 100-150g/ L. Penetrating agent 50-60g/L and caustic soda 220-250g/L, then slowly raise the temperature to 80°C at 2°C/min, keep warm for 50min, take it out, wash and dry it, set the rough billet into a tenter shape, and adjust the speed to 40r /min, singeing the gray cloth.
其中去油剂为浙江传化股份有限公司的乳化去油剂TF-115D,渗透剂为渗透剂FFA。Wherein the degreaser is the emulsified degreaser TF-115D of Zhejiang Transfar Co., Ltd., and the penetrant is the penetrant FFA.
通过上述技术方案,去油剂可以去除纱线上附带的油渍、色渍和杂质,渗透剂协助去油剂渗入纤维内部,碱液可以降解油渍并溶解油渍,提高去油效果,温度由30-40℃缓慢升温,是为了降低高温条件下碱液对纤维损伤;同时碱液会使纤维表面局部溶解,释放上染点并且使纤维粗糙,便于染料上染纤维,不易脱落,纤维表面粗糙还可以避免避免滑丝、脱丝,提高手感。Through the above technical scheme, the degreaser can remove the oil stains, color stains and impurities attached to the yarn, the penetrant assists the degreaser to penetrate into the fiber, the lye can degrade the oil stain and dissolve the oil stain, and improve the degreasing effect. The temperature is from 30- The temperature rises slowly at 40°C to reduce the damage of lye to the fiber under high temperature conditions; at the same time, the lye will partially dissolve the surface of the fiber, release the dyed spots and make the fiber rough, which is convenient for the dye to dye the fiber, not easy to fall off, and the fiber surface is rough. Avoid slipping and stripping, and improve the hand feeling.
进一步优选为,所述步骤(5)中第一染料为低温型分散染料,第二染料为酸性染料。Further preferably, in the step (5), the first dye is a low-temperature disperse dye, and the second dye is an acid dye.
通过上述技术方案,分散染料的配伍性较好,低温型分散染料的分子小,容易上染纤维内部,先加入分散染料通过范德华力与纤维结合,分散染料首先附着纤维表面,随着温度升高,纤维的链段运动,分散染料进入纤维的内部,后期加入酸性染料,酸性染料通过离子键和范德华力上染锦纶,具有饱和点,酸性染料进一步上染纤维与纤维结合,这样酸性染料与纤维的结合牢度高,表面的酸性染料也不易脱落,同时纤维内部的分散染料不易脱落,增强罗马布耐摩擦和耐汗渍色牢度。Through the above technical scheme, the compatibility of disperse dyes is better, and the molecules of low-temperature disperse dyes are small, and it is easy to dye the inside of the fiber. First, the disperse dyes are combined with the fibers through van der Waals force. The disperse dyes first adhere to the surface of the fibers, and as the temperature increases , the chain segment movement of the fiber, the disperse dye enters the interior of the fiber, and the acid dye is added later, and the acid dye dyes the nylon through the ionic bond and van der Waals force, which has a saturation point, and the acid dye further dyes the fiber and combines with the fiber, so that the acid dye and the fiber The combination fastness is high, the acid dyes on the surface are not easy to fall off, and the disperse dyes inside the fiber are not easy to fall off, which enhances the color fastness of Roman cloth to rubbing and perspiration.
低温型分散染料采用本领域常规的分散染料,例如,分散橙80,分散红82,分散蓝148,分散蓝366;酸性染料采用本领域常规的酸性染料,例如,酸性红37,酸性红89,酸性红145,酸性黄42,酸性黄49,酸性蓝215、酸性蓝277、酸性蓝344。Low-temperature disperse dyes adopt conventional disperse dyes in the field, such as disperse orange 80, disperse red 82, disperse blue 148, and disperse blue 366; acid dyes use conventional acid dyes in the field, such as acid red 37, acid red 89, Acid red 145, acid yellow 42, acid yellow 49, acid blue 215, acid blue 277, acid blue 344.
进一步优选为,所述步骤(6)中使用的固色整理液为聚丙烯酸甲酯,浓度为70-80g/L,粘度为1000Cs。More preferably, the color-fixing finishing solution used in the step (6) is polymethylacrylate, the concentration is 70-80g/L, and the viscosity is 1000Cs.
通过上述技术方案,聚丙烯酸甲酯的成膜性较好、透明度高并且耐摩擦性能优良,可以使染料与织物牢固固着且不影响染料的色泽,采用分子量较小的聚丙烯酸甲酯更容易渗进纤维之间,实现单根纤维的包覆,提高织物的色牢度,同时单根纤维包覆对织物的手感影响较小。Through the above-mentioned technical scheme, polymethyl acrylate has good film-forming properties, high transparency and excellent friction resistance, which can firmly fix the dye to the fabric without affecting the color of the dye, and it is easier to use polymethyl acrylate with a smaller molecular weight. Into the fiber, to achieve the coating of a single fiber, improve the color fastness of the fabric, and at the same time, the coating of a single fiber has little effect on the hand feeling of the fabric.
进一步优选为,所述步骤(6)中坯布经过固色整理液一浸一轧,在60℃温度下预烘5-15min,然后在120℃温度下焙烘10-20min。More preferably, in the step (6), the gray cloth is dipped and rolled in the color-fixing solution, prebaked at 60°C for 5-15 minutes, and then baked at 120°C for 10-20 minutes.
通过上述技术方案,低温预烘是为了降低织物的含水率,避免已经上染织物的染料产生泳移,导致织物表面产生色花;高温焙烘使聚丙烯酸甲酯在纤维表面流动,可以更好的包覆单根纤维,同时120℃纤维的链段发生运动,便于染料进一步迁移至纤维内部,同时便于固色剂渗入纤维内部。Through the above technical scheme, low-temperature pre-drying is to reduce the moisture content of the fabric, avoid the dyes that have dyed the fabric from migrating, and cause color patterns on the surface of the fabric; high-temperature baking makes polymethylacrylate flow on the surface of the fiber, which can be better At the same time, the chain segment of the fiber at 120°C moves, which facilitates the further migration of the dye to the interior of the fiber, and at the same time facilitates the penetration of the color fixing agent into the interior of the fiber.
进一步优选为,所述步骤(6)中固色整理液中还包括尿素,所述尿素的浓度为10-20g/L。Further preferably, the color fixing solution in the step (6) further includes urea, and the concentration of the urea is 10-20 g/L.
通过上述技术方案,尿素可以促进固色剂渗入纤维的内部。Through the above technical scheme, urea can promote the penetration of the color fixing agent into the fiber.
进一步优选为,所述步骤(6)固色处理在抽真空蒸汽箱中进行,固色整理液混入蒸汽中,温度控制在120℃。Further preferably, the color fixing treatment in the step (6) is carried out in a vacuum steam box, the color fixing liquid is mixed into the steam, and the temperature is controlled at 120°C.
通过上述技术方案,固色剂更容易渗进纤维内部对单根纤维包覆,同时可以提高纤维的强度;固色剂在纤维表面成膜,提高纤维表面的光滑度,进而提高织物的色泽鲜艳度;除此之外,缩短了工艺流程,提高了的生产效率。Through the above technical scheme, the color-fixing agent can penetrate into the fiber more easily to cover a single fiber, and at the same time can improve the strength of the fiber; the color-fixing agent forms a film on the surface of the fiber to improve the smoothness of the fiber surface, thereby improving the bright color of the fabric In addition, the process flow is shortened and the production efficiency is improved.
进一步优选为,所述后整理液中柔软剂为有机硅柔软剂,浓度为220-250g/L,所述抗静电剂为烷基磷酸酯二乙醇胺盐,浓度为80-90g/L。More preferably, the softener in the finishing liquid is a silicone softener with a concentration of 220-250 g/L, and the antistatic agent is an alkyl phosphate diethanolamine salt with a concentration of 80-90 g/L.
通过上述技术方案,有机硅柔软剂可以赋予罗马布柔软的手感,抗静电剂能够使罗马布具有除静电效果。Through the above technical proposal, the silicone softener can give the Roman cloth a soft feel, and the antistatic agent can make the Roman cloth have an antistatic effect.
综上所述,与现有技术相比,本发明具有以下有益效果:In summary, compared with the prior art, the present invention has the following beneficial effects:
(1)在步骤(1)和(4)对织物纱线和坯布的预处理过程中,不仅去除了织物表面的油渍、色渍和杂质,碱液对纤维的局部降解,使得纱线在织造过程中,相互之间抱和更加牢固,不容易脱丝、滑丝,同时增加了纤维之间的缝隙并且释放更多的上染点,便于染料渗进内部以及通过离子键和范德华力上染纤维,提高罗马布耐摩擦色牢度和耐汗渍色牢度;(1) In the pretreatment process of fabric yarn and gray cloth in steps (1) and (4), not only the oil stains, color stains and impurities on the surface of the fabric are removed, but also the local degradation of the fiber by the lye makes the yarn During the process, the mutual embracing is more firm, and it is not easy to take off and slip. At the same time, the gap between the fibers is increased and more dyeing points are released, which is convenient for the dye to penetrate into the interior and dye through ionic bonds and van der Waals force. fiber, improve the color fastness to rubbing and perspiration of Roman cloth;
(2)在步骤(5)染色过程中,通过分批加入染料,缓慢升温且分阶段保温,有利于避免染色初期上染速率过快,造成染色不均匀的问题,同时第一阶段加入配伍性好且分子量小的分散染料,第二阶段加入与锦纶织物亲和力高的酸性染料,有利于提高上染率,并且分子量小分散染料上染纤维内部不易脱落,纤维表面的酸性染料与纤维的结合牢度高,不易脱落,提高了织物的色牢度;(2) During the dyeing process in step (5), by adding dyes in batches, slowly raising the temperature and keeping warm in stages, it is beneficial to avoid the problem of uneven dyeing caused by too fast dyeing rate in the early stage of dyeing. At the same time, compatibility is added in the first stage Good and small molecular weight disperse dyes, adding acid dyes with high affinity with nylon fabrics in the second stage is beneficial to improve the dye uptake rate, and the dyed fibers with small molecular weight disperse dyes are not easy to fall off, and the combination of acid dyes on the fiber surface and fibers is firm High density, not easy to fall off, improving the color fastness of the fabric;
(3)染色后,使用聚丙烯酸甲酯对织物进行固色处理,固色剂在纤维表面成膜,既可以提高染料的色牢度,又提高了纤维表面的光滑度和纤维强度。(3) After dyeing, use polymethyl acrylate to fix the color of the fabric. The color fixing agent forms a film on the surface of the fiber, which can not only improve the color fastness of the dye, but also improve the smoothness and fiber strength of the fiber surface.
附图说明Description of drawings
图1为本发明的工艺流程图。Fig. 1 is a process flow diagram of the present invention.
具体实施方式Detailed ways
下面结合附图和实施例,对本发明进行详细描述。The present invention will be described in detail below in conjunction with the accompanying drawings and embodiments.
实施例1:如图1所示,一种罗马布的制备方法,包括以下步骤:Embodiment 1: as shown in Figure 1, a kind of preparation method of Roman cloth comprises the following steps:
(1)纱线预处理:将锦纶和氨纶纱线在烧碱溶液中浸泡,碱液浓度为220-250g/L,初始温度控制在40℃,然后以2℃/min缓慢升温至80℃,保温50min后,取出洗净甩干;(1) Yarn pretreatment: Soak nylon and spandex yarns in caustic soda solution, the concentration of lye solution is 220-250g/L, the initial temperature is controlled at 40°C, and then the temperature is slowly raised to 80°C at 2°C/min, and kept warm After 50 minutes, take it out, wash and dry;
(2)蒸汽定型:将锦纶和氨纶纱线放入蒸汽罐中,抽真空后向蒸汽罐内充入蒸汽,保持真空罐的温度为100℃,保持80分钟;(2) Steam setting: put nylon and spandex yarns in a steam tank, fill the steam tank with steam after vacuuming, and keep the temperature of the vacuum tank at 100°C for 80 minutes;
(3)采用大圆机将锦纶和氨纶编织成坯布;(3) Weaving nylon and spandex into gray cloth by large circular knitting machine;
(4)坯布前处理:将坯布浸轧练碱液,水温控制在40℃,练碱液包括去油剂100g/L、渗透剂50g/L和烧碱220g/L,然后以2℃/min缓慢升温至80℃,保温50min后,取出洗净甩干,将粗坯拉幅定型,调节车速为40r/min,将坯布进行烧毛;(4) Pre-treatment of gray cloth: pad the gray cloth with lye, the water temperature is controlled at 40°C, the lye includes 100g/L degreasing agent, 50g/L penetrating agent and 220g/L caustic soda, and then slow down at 2°C/min Raise the temperature to 80°C, keep it warm for 50 minutes, take it out, wash and dry it, set the tenter of the rough blank, adjust the speed to 40r/min, and singe the gray fabric;
(5)染色:在染缸中加入染料助剂和第一染料,第一染料为低温型分散染料,常温开始升温,升温速度为1℃/min,升温至60℃,保温30min,添加染料助剂和第二染料,第二染料为酸性染料,以1℃/min的速度升温至90℃,保温20min,以1.5℃/min的速度缓慢降温至40℃,取出洗净;(5) Dyeing: Add dye auxiliaries and the first dye to the dye vat, the first dye is a low-temperature disperse dye, start to heat up at room temperature, the heating rate is 1°C/min, raise the temperature to 60°C, keep warm for 30min, add dye auxiliaries and the second dye, the second dye is an acid dye, the temperature is raised to 90°C at a rate of 1°C/min, kept for 20 minutes, and slowly cooled to 40°C at a rate of 1.5°C/min, taken out and washed;
(6)固色处理:坯布经过固色整理液一浸一轧,固色整理液为聚丙烯酸甲酯,浓度为70g/L,粘度为1000Cs,在60℃温度下预烘5min,然后在120℃温度下焙烘10min;(6) Color-fixing treatment: the gray cloth is dipped and rolled in a color-fixing solution. The color-fixing solution is polymethyl acrylate with a concentration of 70g/L and a viscosity of 1000Cs. Bake at ℃ for 10 minutes;
(7)后整理:将坯布在后整理液中浸轧,后整理液包括柔软剂、抗静电剂,后整理液中柔软剂为有机硅柔软剂,浓度为220g/L,抗静电剂为烷基磷酸酯二乙醇胺盐,浓度为80g/L,温度40℃,浸轧时间为10min,然后将坯布经过热定型机170℃,机速40r/min,并适当超喂对坯布定型;(7) Finishing: the gray cloth is dipped in the finishing liquid, the finishing liquid includes a softener and an antistatic agent, and the softening agent in the finishing liquid is a silicone softener with a concentration of 220g/L, and the antistatic agent is an alkane Phosphate-based diethanolamine salt, the concentration is 80g/L, the temperature is 40°C, the padding time is 10min, then the gray cloth is passed through the heat setting machine at 170°C, the machine speed is 40r/min, and the gray cloth is shaped by proper overfeeding;
(8)检验,打卷包装,得到罗马布。(8) Inspection, rolling and packaging to obtain Roman cloth.
其中,染色助剂可以采用木质素磺酸钠盐和冰醋酸,也可以采用本领域常规的其他助剂。Wherein, lignosulfonate sodium salt and glacial acetic acid can be used as dyeing auxiliaries, and other auxiliaries conventional in the art can also be used.
去油剂为浙江传化股份有限公司的乳化去油剂TF-115D,渗透剂为渗透剂FFA。The degreaser is emulsified degreaser TF-115D of Zhejiang Transfar Co., Ltd., and the penetrant is penetrant FFA.
低温型分散染料采用本领域常规的分散染料,例如,分散橙80,分散红82,分散蓝148,分散蓝366;酸性染料采用本领域常规的酸性染料,例如,酸性红37,酸性红89,酸性红145,酸性黄42,酸性黄49,酸性蓝215、酸性蓝277、酸性蓝344。Low-temperature disperse dyes adopt conventional disperse dyes in the field, such as disperse orange 80, disperse red 82, disperse blue 148, and disperse blue 366; acid dyes use conventional acid dyes in the field, such as acid red 37, acid red 89, Acid red 145, acid yellow 42, acid yellow 49, acid blue 215, acid blue 277, acid blue 344.
实施例2:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(1)中碱液的浓度为235g/L。Embodiment 2: a kind of preparation method of roman cloth, differs from embodiment 1 in that the concentration of lye in step (1) is 235g/L.
实施例3:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(1)中碱液的浓度为250g/L。Embodiment 3: a kind of preparation method of roman cloth, differs from embodiment 1 in that, the concentration of lye in step (1) is 250g/L.
实施例4:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(2)中蒸汽定型温度为110℃,时间为65分钟。Embodiment 4: A preparation method of Roman cloth, the difference from embodiment 1 is that the steam setting temperature in step (2) is 110° C., and the time is 65 minutes.
实施例5:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(2)中蒸汽定型温度为120℃,时间为50分钟。Embodiment 5: A preparation method of roman cloth, the difference from embodiment 1 is that the steam setting temperature in step (2) is 120° C., and the time is 50 minutes.
实施例6:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(4)中练碱液包括去油剂125g/L、渗透剂55g/L和烧碱235g/L。Embodiment 6: a kind of preparation method of roman cloth, the difference with embodiment 1 is, in the step (4), lye leaching comprises degreasing agent 125g/L, penetrating agent 55g/L and caustic soda 235g/L.
实施例7:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(4)中练碱液包括去油剂150g/L、渗透剂60g/L和烧碱250g/L。Embodiment 7: a kind of preparation method of roman cloth, the difference with embodiment 1 is that in the step (4), the caustic lye comprises degreaser 150g/L, penetrating agent 60g/L and caustic soda 250g/L.
实施例8:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(5)为:在染缸中加入染料助剂和第一染料,第一染料为低温型分散染料,常温开始升温,升温速度为1.25℃/min,升温至60℃,保温40min,添加染料助剂和第二染料,第二染料为酸性染料,以1℃/min的速度升温至90℃,保温20min,以1.5℃/min的速度缓慢降温至40℃,取出洗净。Embodiment 8: A preparation method of Roman cloth, the difference from Example 1 is that step (5) is: add dye auxiliary agent and the first dye in the dye vat, the first dye is low-temperature type disperse dye, normal temperature Start to heat up at a rate of 1.25°C/min, raise the temperature to 60°C, keep it warm for 40 minutes, add dye auxiliaries and the second dye, the second dye is an acid dye, raise the temperature to 90°C at a rate of 1°C/min, and keep it warm for 20 minutes, Slowly cool down to 40°C at a rate of 1.5°C/min, take it out and wash it.
实施例9:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(5)为:在染缸中加入染料助剂和第一染料,第一染料为低温型分散染料,常温开始升温,升温速度为1.5℃/min,升温至60℃,保温50min,添加染料助剂和第二染料,第二染料为酸性染料,以1℃/min的速度升温至90℃,保温20min,以1.5℃/min的速度缓慢降温至40℃,取出洗净。Embodiment 9: A preparation method of Roman cloth, the difference from Example 1 is that step (5) is: add dye auxiliaries and the first dye in the dye vat, the first dye is a low-temperature type disperse dye, and Start to heat up at a rate of 1.5°C/min, raise the temperature to 60°C, keep it warm for 50 minutes, add dye auxiliaries and the second dye, the second dye is an acid dye, raise the temperature to 90°C at a rate of 1°C/min, keep it for 20 minutes, Slowly cool down to 40°C at a rate of 1.5°C/min, take it out and wash it.
实施例10:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(5)为:在染缸中加入染料助剂和第一染料,第一染料为低温型分散染料,常温开始升温,升温速度为1℃/min,升温至60℃,保温30min,添加染料助剂和第二染料,第二染料为酸性染料,以1.75℃/min的速度升温至90℃,保温25min,以1.5℃/min的速度缓慢降温至40℃,取出洗净。Embodiment 10: A preparation method of Roman cloth, the difference from Example 1 is that step (5) is: adding dye auxiliaries and the first dye in the dye vat, the first dye is a low-temperature disperse dye, and Start to heat up at a rate of 1°C/min, raise the temperature to 60°C, keep it warm for 30 minutes, add dye auxiliaries and a second dye, the second dye is an acid dye, raise the temperature to 90°C at a rate of 1.75°C/min, and keep it warm for 25 minutes, Slowly cool down to 40°C at a rate of 1.5°C/min, take it out and wash it.
实施例11:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(5)为:在染缸中加入染料助剂和第一染料,第一染料为低温型分散染料,常温开始升温,升温速度为1℃/min,升温至60℃,保温30min,添加染料助剂和第二染料,第二染料为酸性染料,以2℃/min的速度升温至90℃,保温30min,以1.5℃/min的速度缓慢降温至40℃,取出洗净。Example 11: A preparation method of Roman cloth, the difference from Example 1 is that step (5) is: add dye auxiliaries and the first dye in the dye vat, the first dye is a low-temperature disperse dye, and Start to heat up at a rate of 1°C/min, raise the temperature to 60°C, keep it warm for 30 minutes, add dye auxiliaries and the second dye, the second dye is an acid dye, raise the temperature to 90°C at a rate of 2°C/min, and keep it warm for 30 minutes, Slowly cool down to 40°C at a rate of 1.5°C/min, take it out and wash it.
实施例12:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(5)为:在染缸中加入染料助剂和第一染料,第一染料为低温型分散染料,常温开始升温,升温速度为1℃/min,升温至60℃,保温30min,添加染料助剂和第二染料,第二染料为酸性染料,以1.5℃/min的速度升温至90℃,保温20min,以1.75℃/min的速度缓慢降温至45℃,取出洗净。Example 12: A preparation method of Roman cloth, the difference from Example 1 is that step (5) is: adding dye auxiliaries and the first dye in the dye vat, the first dye is a low-temperature disperse dye, and the temperature is Start to heat up at a rate of 1°C/min, raise the temperature to 60°C, keep it warm for 30 minutes, add dye auxiliaries and the second dye, the second dye is an acid dye, raise the temperature to 90°C at a rate of 1.5°C/min, and keep it warm for 20 minutes, Slowly cool down to 45°C at a rate of 1.75°C/min, take it out and wash it.
实施例13:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(5)为:在染缸中加入染料助剂和第一染料,第一染料为低温型分散染料,常温开始升温,升温速度为1℃/min,升温至60℃,保温30min,添加染料助剂和第二染料,第二染料为酸性染料,以1.5℃/min的速度升温至90℃,保温20min,以2℃/min的速度缓慢降温至50℃,取出洗净。Example 13: A preparation method of Roman cloth, the difference from Example 1 is that step (5) is: add dye auxiliaries and the first dye in the dye vat, the first dye is a low-temperature disperse dye, and Start to heat up at a rate of 1°C/min, raise the temperature to 60°C, keep it warm for 30 minutes, add dye auxiliaries and the second dye, the second dye is an acid dye, raise the temperature to 90°C at a rate of 1.5°C/min, and keep it warm for 20 minutes, Slowly cool down to 50°C at a rate of 2°C/min, take it out and wash it.
实施例14:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(6)中聚丙烯酸甲酯浓度为75g/L。Embodiment 14: a preparation method of Roman cloth, the difference from embodiment 1 is that the concentration of polymethyl acrylate in step (6) is 75g/L.
实施例15:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(6)中聚丙烯酸甲酯浓度为80g/L。Embodiment 15: a preparation method of Roman cloth, the difference from embodiment 1 is that the concentration of polymethyl acrylate in step (6) is 80g/L.
实施例16:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(6)为:坯布经过固色整理液一浸一轧,固色整理液为聚丙烯酸甲酯,浓度为70g/L,粘度为1000Cs,在60℃温度下预烘10min,然后在120℃温度下焙烘15min。Embodiment 16: A preparation method of Roman cloth, the difference from Example 1 is that step (6) is: the gray cloth is dipped and rolled in the color-fixing finishing solution, the color-fixing finishing solution is polymethylacrylate, and the concentration 70g/L, viscosity 1000Cs, pre-baked at 60°C for 10min, then baked at 120°C for 15min.
实施例17:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(6)为:坯布经过固色整理液一浸一轧,固色整理液为聚丙烯酸甲酯,浓度为70g/L,粘度为1000Cs,在60℃温度下预烘15min,然后在120℃温度下焙烘20min。Example 17: A preparation method of Roman cloth, the difference from Example 1 is that step (6) is: the gray cloth is dipped and rolled in the color-fixing solution, the color-fixing solution is polymethyl acrylate, and the concentration It is 70g/L, the viscosity is 1000Cs, pre-baked at 60°C for 15 minutes, and then baked at 120°C for 20 minutes.
实施例18:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(7)中柔软剂为浓度为235g/L,抗静电剂浓度为85g/L。Embodiment 18: A preparation method of Roman cloth, the difference from Example 1 is that in step (7), the concentration of the softening agent is 235g/L, and the concentration of the antistatic agent is 85g/L.
实施例19:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(7)中柔软剂为浓度为250g/L,抗静电剂浓度为90g/L。Embodiment 19: A preparation method of Roman cloth, the difference from Example 1 is that in step (7), the concentration of the softening agent is 250g/L, and the concentration of the antistatic agent is 90g/L.
实施例20:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(6)为:坯布经过固色整理液一浸一轧,固色整理液包括浓度为70g/L的聚丙烯酸甲酯和浓度为10g/L的尿素,聚丙烯酸甲酯粘度为1000Cs,在60℃温度下预烘5min,然后在120℃温度下焙烘10min。Example 20: A preparation method of Roman cloth, the difference from Example 1 is that step (6) is: the gray cloth is dipped and rolled in the color-fixing solution, and the color-fixing solution includes 70g/L Polymethyl acrylate and urea with a concentration of 10g/L, the viscosity of polymethyl acrylate is 1000Cs, prebaked at 60°C for 5min, and then baked at 120°C for 10min.
实施例21:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(6)为:坯布经过固色整理液一浸一轧,固色整理液包括浓度为70g/L的聚丙烯酸甲酯和浓度为15g/L的尿素,聚丙烯酸甲酯粘度为1000Cs,在60℃温度下预烘5min,然后在120℃温度下焙烘10min。Example 21: A preparation method of Roman cloth, the difference from Example 1 is that step (6) is: the gray cloth is dipped and rolled in the color-fixing solution, and the color-fixing solution includes 70g/L Polymethyl acrylate and urea with a concentration of 15g/L, the viscosity of polymethyl acrylate is 1000Cs, prebaked at 60°C for 5min, and then baked at 120°C for 10min.
实施例22:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(6)为:坯布经过固色整理液一浸一轧,固色整理液包括浓度为70g/L的聚丙烯酸甲酯和浓度为20g/L的尿素,聚丙烯酸甲酯粘度为1000Cs,在60℃温度下预烘5min,然后在120℃温度下焙烘10min。Example 22: A method for preparing Roman cloth, the difference from Example 1 is that step (6) is: the gray cloth is dipped and rolled in the color-fixing solution, and the color-fixing solution includes 70g/L Polymethyl acrylate and urea with a concentration of 20g/L, the viscosity of polymethyl acrylate is 1000Cs, prebaked at 60°C for 5min, and then baked at 120°C for 10min.
实施例23:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(7)为:将坯布置于抽真空蒸汽箱中,固色整理液混入蒸汽中,温度控制在120℃,坯布经过固色整理液一浸一轧,固色整理液为聚丙烯酸甲酯,浓度为70g/L,粘度为1000Cs,在60℃温度下预烘5min,然后在120℃温度下焙烘10min。Example 23: A method for preparing Roman cloth, the difference from Example 1 is that step (7) is: arrange the base in a vacuumed steam box, mix the color fixing liquid into the steam, and control the temperature at 120 ℃, the gray cloth is dipped and rolled in the color-fixing solution, the color-fixing solution is polymethylacrylate, the concentration is 70g/L, the viscosity is 1000Cs, pre-baked at 60℃ for 5min, and then baked at 120℃ 10min.
对比例1:一种罗马布的制备方法,与实施例1的不同之处在于,锦纶和氨纶纱线未经过(1)纱线预处理。Comparative Example 1: A method for preparing Roman cloth, the difference from Example 1 is that nylon and spandex yarns are not subjected to (1) yarn pretreatment.
对比例2:一种罗马布的制备方法,与实施例1的不同之处在于,坯布未经过(4)坯布前处理。Comparative example 2: a preparation method of Roman cloth, the difference from Example 1 is that the gray cloth has not been subjected to (4) gray cloth pretreatment.
对比例3:一种罗马布的制备方法,与实施例1的不同之处在于,步骤(5)中第一染料和第二染料均为酸性染料。Comparative example 3: a preparation method of Roman cloth, the difference from Example 1 is that the first dye and the second dye are both acid dyes in step (5).
对比例4:一种罗马布的制备方法,与实施例1的不同之处在于,坯布未经过(6)固色处理。Comparative example 4: a preparation method of Roman cloth, the difference from Example 1 is that the gray cloth has not been subjected to (6) color-fixing treatment.
性能检测performance testing
检测样品:采用实施例1-23中获得的罗马布作为试验样品1-23,采用对比例1-4中获得的罗马布作为对照样品1-4。Test samples: the Roman cloth obtained in Example 1-23 was used as test sample 1-23, and the Roman cloth obtained in Comparative Example 1-4 was used as control sample 1-4.
检测方法:采用下述测试标准检测试验样品1-23和对照样品1-4的耐汗渍色牢度和耐摩擦色牢度。Detection method: the color fastness to perspiration and the color fastness to rubbing of test samples 1-23 and control samples 1-4 were tested using the following test standards.
耐汗渍色牢度:ISO 105-E04等同GB/T8427-1995(纺织品耐人造光色牢度);Color fastness to perspiration: ISO 105-E04 is equivalent to GB/T8427-1995 (color fastness to artificial light of textiles);
耐摩擦色牢度:ISO 105-X12等同GB/T3920-2008(纺织品耐摩擦色牢度);Color fastness to rubbing: ISO 105-X12 is equivalent to GB/T3920-2008 (color fastness to rubbing of textiles);
检测结果如表1-2所示。The test results are shown in Table 1-2.
表1试验样品1-23和对照样品1-4的耐汗渍色牢度检测结果The color fastness to perspiration test result of table 1 test sample 1-23 and control sample 1-4
表2试验样品1-23和对照样品1-4的耐摩擦色牢度检测结果The color fastness to rubbing test result of table 2 test sample 1-23 and contrast sample 1-4
试验结果:试验样品1-23和对照样品1-4的检测结果如表1-2所示。由表1-2可知,本发明采用两次练碱、分批加入低温型分散染料、酸性染料和固色处理,能够提高罗马布耐摩擦色牢度和耐汗渍色牢度。Test results: the test results of test samples 1-23 and control samples 1-4 are shown in Table 1-2. It can be seen from Table 1-2 that the present invention can improve the color fastness to rubbing and perspiration of Roman cloth by two times of alkali training, batch addition of low-temperature disperse dyes, acid dyes and color fixation treatment.
以上所述仅是本发明的优选实施方式,本发明的保护范围并不仅局限于上述实施例,凡属于本发明思路下的技术方案均属于本发明的保护范围。应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理前提下的若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。The above descriptions are only preferred implementations of the present invention, and the protection scope of the present invention is not limited to the above-mentioned embodiments, and all technical solutions under the idea of the present invention belong to the protection scope of the present invention. It should be pointed out that for those skilled in the art, some improvements and modifications without departing from the principles of the present invention should also be regarded as the protection scope of the present invention.
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