CN108166330A - One kind is except formaldehyde PVC wallpaper and preparation method thereof - Google Patents
One kind is except formaldehyde PVC wallpaper and preparation method thereof Download PDFInfo
- Publication number
- CN108166330A CN108166330A CN201711467895.XA CN201711467895A CN108166330A CN 108166330 A CN108166330 A CN 108166330A CN 201711467895 A CN201711467895 A CN 201711467895A CN 108166330 A CN108166330 A CN 108166330A
- Authority
- CN
- China
- Prior art keywords
- parts
- nano
- formaldehyde
- pvc wallpaper
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims abstract description 177
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 43
- -1 siloxanes Chemical class 0.000 claims abstract description 16
- 239000012190 activator Substances 0.000 claims abstract description 15
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 15
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 15
- 239000004094 surface-active agent Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003610 charcoal Substances 0.000 claims abstract description 13
- 239000012153 distilled water Substances 0.000 claims abstract description 13
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 13
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 13
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229940070527 tourmaline Drugs 0.000 claims abstract description 12
- 229910052613 tourmaline Inorganic materials 0.000 claims abstract description 12
- 239000011032 tourmaline Substances 0.000 claims abstract description 12
- 238000000498 ball milling Methods 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 238000010521 absorption reaction Methods 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 12
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 230000000630 rising effect Effects 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000004575 stone Substances 0.000 claims description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 2
- MMKQUGHLEMYQSG-UHFFFAOYSA-N oxygen(2-);praseodymium(3+) Chemical compound [O-2].[O-2].[O-2].[Pr+3].[Pr+3] MMKQUGHLEMYQSG-UHFFFAOYSA-N 0.000 claims description 2
- 229910003447 praseodymium oxide Inorganic materials 0.000 claims description 2
- 229910001952 rubidium oxide Inorganic materials 0.000 claims description 2
- CWBWCLMMHLCMAM-UHFFFAOYSA-M rubidium(1+);hydroxide Chemical compound [OH-].[Rb+].[Rb+] CWBWCLMMHLCMAM-UHFFFAOYSA-M 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 229930182470 glycoside Natural products 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 14
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 3
- 238000013016 damping Methods 0.000 abstract description 3
- 238000004332 deodorization Methods 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 27
- 238000000034 method Methods 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 239000003344 environmental pollutant Substances 0.000 description 5
- 231100000719 pollutant Toxicity 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- 239000000809 air pollutant Substances 0.000 description 1
- 231100001243 air pollutant Toxicity 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 210000005252 bulbus oculi Anatomy 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 210000000987 immune system Anatomy 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Laminated Bodies (AREA)
Abstract
For one kind except formaldehyde PVC wallpaper and preparation method thereof, PVC wallpaper superficial layer is equipped with formaldehyde removal layer；Formaldehyde removal layer includes the component of following parts by weight：25~40 parts of supermolecule poly cage type siloxanes, 4~12 parts of nano level active charcoal, 5~12 parts of nano diatomite, 5~12 parts of nano-titanium dioxide, 6~15 parts of nano-tourmaline, 3~8 parts of nano silicon dioxide, 2~5 parts of surfactant, 15~30 parts of distilled water, 5~9 parts of rare earth activators；Preparation method is mixes slowly the heating coating drying of ball milling moderate-speed mixer.The present invention has the advantage that：It is not only permanent effectively except formaldehyde, and service life is long；Peculiar smell can also be removed simultaneously, there is damping, breathe freely, mould proof deodorization；Effect continued up to 10 15 years.
Description
Technical field
The present invention relates to a kind of wallpapers, and in particular to one kind is except formaldehyde PVC wallpaper and preparation method thereof.
Background technology
With the development of economy with the raising of living standards of the people, diversified building and ornament materials have been enter into household and
The use of office space, this but also the emission problem getting worse of indoor polluted gas, wherein, with the most prominent the problem of formaldehyde
Go out.The main source of formaldehyde is in the ornament materials such as glued board, Blockboard, paint, the coating of indoor decoration, it can be to eye
Eyeball, skin and respiratory tract generate stimulation, cause the malfunction of nervous system, immune system and internal system, generally
For, the deenergized period of the formaldehyde in furniture, Long-term absorption formaldehyde gas can give rise to diseases, serious up to 5 to 10 years
The life security of entail dangers to human body.Therefore, it is necessary to carry out the improvement of air pollutants to the interior space after finishing, make its control
Within national standard, one healthy and safe living environment of people is gone back.
At present, the common method except formaldehyde of family includes ventilation method, plant absorption method, active carbon adsorption, chemistry examination
Agent method of purification etc..Ventilation method is good method, can effectively reduce the content of indoor formaldehyde, but sleep at night when
It waits, it is often necessary to close door and window, limit the use of ventilation method；The assimilation effect of plant absorption method is not fine；Activity
Carbon adsorption can be by formaldehyde absorbing, but can not remove, and activated carbon has been used after a certain period of time, and adsorption effect is big
Amplitude reduction；Purification of chemical reagents method is complicated for operation, there is the risk of secondary pollution, and can not use daily, limitation
Its clean-up effect.For the environment of house, exploitation one kind can recycle, can effectively remove formaldehyde, while beautiful big
The formaldehyde products of going of side are very necessary.
Invention content
It is an object of the invention to provide one kind except formaldehyde PVC wallpaper, it is not only permanent effectively except formaldehyde, and except first
Aldehyde effect is good, without side-effects to human body；It is a further object of the present invention to provide a kind of except the preparation method of formaldehyde PVC wallpaper.
It is realized the purpose of the present invention is technical solution in this way, one kind is except formaldehyde PVC wallpaper, PVC wallpaper surface
Layer is equipped with formaldehyde and removes layer；Formaldehyde removal layer includes the component of following parts by weight：25~40 parts of supermolecule poly cage type siloxanes,
4~12 parts of nano level active charcoal, 5~12 parts of nano diatomite, 5~12 parts of nano-titanium dioxide, 6~15 parts of nano-tourmaline,
3~8 parts of nano silicon dioxide, 2~5 parts of surfactant, 15~30 parts of distilled water, 5~9 parts of rare earth activators.
In the present invention, supermolecule poly cage type siloxanes is organosilicon, and effect is mainly and inertia in room air
Benzene series chemical pollutant generate the crosslinked action of supramolecular structure, inierpeneirating network structure is formed, so as to dissociate in fixed air
Benzene homologues and some long-chains stablize organic polymer chemistry pollutant；Diatomite is the plant remains heap by being grown in extra large lake
Product changes for 1000000 years；Since diatomite itself has countless pores, the adsorbable peculiar smell decomposed in air makes it have
Damping, the function of ventilative, mould proof deodorization；By the effect of the nano diatomite and activated carbon of high absorption property, Interior Space
Noxious pollutant in gas absorbed, while the nano-titanium dioxide being attached in its aperture passage will be in nano-tourmaline powder
Under the double action of negative ion powder, pollutant is quickly resolved into water and carbon dioxide, pollution is effectively removed so as to reach
Effect；Electrostatic adsorption is cooperateed with using organosilicon and nano-tourmaline, PM2.5 dust pollutions is effectively settled, persistently improves
Interior climate environment, the effect for purifying air；Meanwhile nano-titanium dioxide has good anti-ultraviolet function, is coated on
Finishing material surface can extend wallpaper service life, achieve the effect that anti-old；PVC wallpaper all surface is all provided in the present invention
There is formaldehyde to remove layer, protection is comprehensive, and nontoxic using nano material itself, and chemical property is stablized, and continues effect up to 10-
15 years.
Further, surfactant is sodium sulfate of polyethenoxy ether of fatty alcohol, ethoxylated alkyl sulfate or alkyl
Glucosides.
Further rare earth activators are lanthana, cerium oxide, rubidium oxide or praseodymium oxide.
It is realized it is another object of the present invention to technical solution in this way, it is above-mentioned except the preparation side of formaldehyde PVC wallpaper
Method：
S1, by supermolecule poly cage type siloxanes, nano level active charcoal, nano diatomite, nano-titanium dioxide, nanometer electricity
Gas stone, nano silicon dioxide, surfactant, distilled water and rare earth activators are added in blender by above-mentioned number value with 40
It is stirred 0.5~1 hour under the low speed of~50r/min；
S2 is put into ball mill and carries out ball milling, and ball milling speed is 55~80r/min；
S3 is placed into blender and is mixed 30~50 minutes with the moderate-speed mixer of 400~700r/min；
S4 is heated after stirring, and heating temperature is 200~400 DEG C, and heating time is 4~5.5h, obtains formaldehyde absorption
Layer base-material；
The PVC wallpaper layer of machine-shaping is carried out fast frozen, then formaldehyde absorption layer base-material is uniformly applied to PVC by S5
Wallpaper layer upper surface；Thickness of the formaldehyde absorption layer base-material on PVC wallpaper layer is 1.5~2.5mm；
Smear after the completion of carry out drying and processing, drying initial temperature be 35~55 DEG C, with the speed of 10 DEG C/min it is uniform on
It rises, until rising to 80~90 DEG C, then persistently dries 18~35min.
By adopting the above-described technical solution, the present invention has the advantage that：It is not only permanent effectively except formaldehyde, and
Service life is long；Peculiar smell can also be removed simultaneously, there is damping, breathe freely, mould proof deodorization；Effect continues up to 10-15.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, make below in conjunction with specific embodiment into one
Step ground detailed description.
Embodiment 1
For one kind except formaldehyde PVC wallpaper, PVC wallpaper superficial layer is equipped with formaldehyde removal layer；Formaldehyde removal layer includes following weight
Measure the component of part：25~40 parts of supermolecule poly cage type siloxanes, 4~12 parts of nano level active charcoal, nano diatomite 5~12
Part, 5~12 parts of nano-titanium dioxide, 6~15 parts of nano-tourmaline, 3~8 parts of nano silicon dioxide, 2~5 parts of surfactant,
15~30 parts of distilled water, 5~9 parts of rare earth activators.
Embodiment 2
For one kind except formaldehyde PVC wallpaper, PVC wallpaper superficial layer is equipped with formaldehyde removal layer；Formaldehyde removal layer includes following weight
Measure the component of part：25 parts of supermolecule poly cage type siloxanes, 4 parts of nano level active charcoal, 5 parts of nano diatomite, nanometer titanium dioxide
5 parts of titanium, 6 parts of nano-tourmaline, 3 parts of nano silicon dioxide, 2 parts of surfactant, 15 parts of distilled water, 5 parts of rare earth activators.
Embodiment 3
For one kind except formaldehyde PVC wallpaper, PVC wallpaper superficial layer is equipped with formaldehyde removal layer；Formaldehyde removal layer includes following weight
Measure the component of part：40 parts of supermolecule poly cage type siloxanes, 12 parts of nano level active charcoal, 12 parts of nano diatomite, nano-silica
Change 12 parts of titanium, 15 parts of nano-tourmaline, 8 parts of nano silicon dioxide, 5 parts of surfactant, 30 parts of distilled water, rare earth activators 9
Part.
Embodiment 4
For one kind except formaldehyde PVC wallpaper, PVC wallpaper superficial layer is equipped with formaldehyde removal layer；Formaldehyde removal layer includes following weight
Measure the component of part：30 parts of supermolecule poly cage type siloxanes, 8 parts of nano level active charcoal, 9 parts of nano diatomite, nanometer titanium dioxide
9 parts of titanium, 10 parts of nano-tourmaline, 6 parts of nano silicon dioxide, 4 parts of surfactant, 20 parts of distilled water, 7 parts of rare earth activators.
Embodiment 5
One kind removes formaldehyde PVC wallpaper, and preparation method is：
S1, by supermolecule poly cage type siloxanes, nano level active charcoal, nano diatomite, nano-titanium dioxide, nanometer electricity
Gas stone, nano silicon dioxide, surfactant, distilled water and rare earth activators are added in blender by above-mentioned number value with 40
It is stirred 0.5~1 hour under the low speed of~50r/min；
S2 is put into ball mill and carries out ball milling, and ball milling speed is 55~80r/min；
S3 is placed into blender and is mixed 30~50 minutes with the moderate-speed mixer of 400~700r/min；
S4 is heated after stirring, and heating temperature is 200~400 DEG C, and heating time is 4~5.5h, obtains formaldehyde absorption
Layer base-material；
The PVC wallpaper layer of machine-shaping is carried out fast frozen, then formaldehyde absorption layer base-material is uniformly applied to PVC by S5
Wallpaper layer upper surface；Thickness of the formaldehyde absorption layer base-material on PVC wallpaper layer is 1.5~2.5mm；It is dried after the completion of smearing
Processing, drying initial temperature is 35~55 DEG C, is uniformly risen with the speed of 10 DEG C/min, until rising to 80~90 DEG C, then hold
18~35min of continuous drying.
Performance test：
The wallpaper prepared by obtained embodiment 2,3 and 4 prepared by method in embodiment 5 is attached to formaldehyde gas
In room (10 square metres) inner wall surface, content of formaldehyde is 14 (mg/ ㎡) in room, and equipped with above-mentioned equal conditions but non-wallpaper
Blank group, by 1 day, 3 days, 7 days, content of formaldehyde was as follows in 13 days test spaces：
It is as shown in the table, it is a kind of except formaldehyde PVC wallpaper performance indicator for the present invention：
Formaldehyde PVC wallpaper of removing in the present invention it can be seen from table has excellent performance, and it is indoor to can be widely used for removal
Pollutant especially formaldehyde, so as to create more healthy living environment.
The foregoing is merely presently preferred embodiments of the present invention, is not intended to limit the invention, it is all the present invention spirit and
Within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.
Claims (7)
1. one kind removes formaldehyde PVC wallpaper, which is characterized in that PVC wallpaper superficial layer is equipped with formaldehyde and removes layer；Formaldehyde removal layer includes
The component of following parts by weight：25~40 parts of supermolecule poly cage type siloxanes, 4~12 parts of nano level active charcoal, nano diatomite 5
~12 parts, 5~12 parts of nano-titanium dioxide, 6~15 parts of nano-tourmaline, 3~8 parts of nano silicon dioxide, surfactant 2~
5 parts, 15~30 parts of distilled water, 5~9 parts of rare earth activators.
2. according to claim 1 remove formaldehyde PVC wallpaper, which is characterized in that formaldehyde removal layer includes following parts by weight
Component：25 parts of supermolecule poly cage type siloxanes, 4 parts of nano level active charcoal, 5 parts of nano diatomite, 5 parts of nano-titanium dioxide,
6 parts of nano-tourmaline, 3 parts of nano silicon dioxide, 2 parts of surfactant, 15 parts of distilled water, 5 parts of rare earth activators.
3. according to claim 1 remove formaldehyde PVC wallpaper, which is characterized in that formaldehyde removal layer includes following parts by weight
Component：40 parts of supermolecule poly cage type siloxanes, 12 parts of nano level active charcoal, 12 parts of nano diatomite, nano-titanium dioxide 12
Part, 15 parts of nano-tourmaline, 8 parts of nano silicon dioxide, 5 parts of surfactant, 30 parts of distilled water, 9 parts of rare earth activators.
4. according to claim 1 remove formaldehyde PVC wallpaper, which is characterized in that formaldehyde removal layer includes following parts by weight
Component：30 parts of supermolecule poly cage type siloxanes, 8 parts of nano level active charcoal, 9 parts of nano diatomite, 9 parts of nano-titanium dioxide,
10 parts of nano-tourmaline, 6 parts of nano silicon dioxide, 4 parts of surfactant, 20 parts of distilled water, 7 parts of rare earth activators.
5. remove formaldehyde PVC wallpaper according to Claims 1-4 any claim, which is characterized in that surfactant is
Sodium sulfate of polyethenoxy ether of fatty alcohol, ethoxylated alkyl sulfate or alkyl glycosides.
6. remove formaldehyde PVC wallpaper according to Claims 1-4 any claim, which is characterized in that rare earth activators are
Lanthana, cerium oxide, rubidium oxide or praseodymium oxide.
7. according to Claims 1-4 any claim is except the preparation method of formaldehyde PVC wallpaper, which is characterized in that
Include the following steps：
S1, supermolecule poly cage type siloxanes, nano level active charcoal, nano diatomite, nano-titanium dioxide, nanometer is electrical
Stone, nano silicon dioxide, surfactant, distilled water and rare earth activators are added in blender with 40 by above-mentioned number value~
It is stirred 0.5~1 hour under the low speed of 50r/min；
S2 is put into ball mill and carries out ball milling, and ball milling speed is 55~80r/min；
S3 is placed into blender and is mixed 30~50 minutes with the moderate-speed mixer of 400~700r/min；
S4 is heated after stirring, and heating temperature is 200~400 DEG C, and heating time is 4~5.5h, obtains formaldehyde absorption layer base
Material；
The PVC wallpaper layer of machine-shaping is carried out fast frozen, then formaldehyde absorption layer base-material is uniformly applied to PVC wallpaper by S5
Layer upper surface；Thickness of the formaldehyde absorption layer base-material on PVC wallpaper layer is 1.5~2.5mm；It is carried out at drying after the completion of smearing
Reason, drying initial temperature is 35~55 DEG C, is uniformly risen with the speed of 10 DEG C/min, until rising to 80~90 DEG C, then is continued
Dry 18~35min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711467895.XA CN108166330A (en) | 2017-12-29 | 2017-12-29 | One kind is except formaldehyde PVC wallpaper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711467895.XA CN108166330A (en) | 2017-12-29 | 2017-12-29 | One kind is except formaldehyde PVC wallpaper and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108166330A true CN108166330A (en) | 2018-06-15 |
Family
ID=62519621
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711467895.XA Pending CN108166330A (en) | 2017-12-29 | 2017-12-29 | One kind is except formaldehyde PVC wallpaper and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108166330A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111569951A (en) * | 2020-05-26 | 2020-08-25 | 霸州市纽莱客家具有限公司 | Composition for removing formaldehyde and peculiar smell of furniture |
| CN113201161A (en) * | 2021-04-22 | 2021-08-03 | 佛山市南海天元茂新新材料有限公司 | PVC decorative material for durably and efficiently purifying formaldehyde and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101537201A (en) * | 2009-04-27 | 2009-09-23 | 贺燕婷 | Multieffect nano air purificant and preparation method thereof |
| CN101633782A (en) * | 2009-08-21 | 2010-01-27 | 赵东育 | Liquid active carbon colloid emulsion |
| CN104775587A (en) * | 2015-03-24 | 2015-07-15 | 江苏北台壁纸实业有限公司 | Environment-friendly pollution-free PVC wallpaper capable of removing formaldehyde |
| CN107189563A (en) * | 2017-08-02 | 2017-09-22 | 合肥安力电力工程有限公司 | A kind of environmental protection is except decorative material for wall surface of formaldehyde and preparation method thereof |
-
2017
- 2017-12-29 CN CN201711467895.XA patent/CN108166330A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101537201A (en) * | 2009-04-27 | 2009-09-23 | 贺燕婷 | Multieffect nano air purificant and preparation method thereof |
| CN101633782A (en) * | 2009-08-21 | 2010-01-27 | 赵东育 | Liquid active carbon colloid emulsion |
| CN104775587A (en) * | 2015-03-24 | 2015-07-15 | 江苏北台壁纸实业有限公司 | Environment-friendly pollution-free PVC wallpaper capable of removing formaldehyde |
| CN107189563A (en) * | 2017-08-02 | 2017-09-22 | 合肥安力电力工程有限公司 | A kind of environmental protection is except decorative material for wall surface of formaldehyde and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111569951A (en) * | 2020-05-26 | 2020-08-25 | 霸州市纽莱客家具有限公司 | Composition for removing formaldehyde and peculiar smell of furniture |
| CN111569951B (en) * | 2020-05-26 | 2022-12-06 | 上海希望树生物科技有限公司 | Composition for removing formaldehyde and peculiar smell of furniture |
| CN113201161A (en) * | 2021-04-22 | 2021-08-03 | 佛山市南海天元茂新新材料有限公司 | PVC decorative material for durably and efficiently purifying formaldehyde and preparation method and application thereof |
| CN113201161B (en) * | 2021-04-22 | 2023-03-03 | 佛山市南海天元茂新新材料有限公司 | PVC decorative material for durably and efficiently purifying formaldehyde and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103525138B (en) | A kind of Nano-photocatalyst air-purification wall paint and preparation method thereof | |
| CN109575728B (en) | Environment-friendly interior wall coating and preparation method thereof | |
| CN107335320B (en) | Environment-friendly odor-removing and formaldehyde-removing composition and preparation method thereof | |
| CN107821480A (en) | A kind of formaldehyde scavenger and preparation method thereof | |
| CN105542595A (en) | Graphene-diatomaceous-earth anti-formaldehyde coating and preparing method thereof | |
| CN112375445A (en) | Long-acting antibacterial radiation-proof negative oxygen ion far-infrared coating and preparation method thereof | |
| CN105295600A (en) | Interior wall coating having multiple functions of temperature and humidity regulation and photocatalysis and preparation method thereof | |
| CN102702807A (en) | Photo-catalytic composite coating and preparation method thereof | |
| CN107129709A (en) | A kind of compound finished product diatom ooze of potassium silicate and preparation method thereof | |
| CN108864907A (en) | A kind of aqueous inner wall paint and preparation method thereof | |
| CN108166330A (en) | One kind is except formaldehyde PVC wallpaper and preparation method thereof | |
| CN105622017B (en) | Unburned diatom ecological brick and its production method | |
| CN102872917B (en) | Negative oxygen ion generator and preparation method thereof | |
| CN105689006A (en) | Nano-photocatalyst and preparation method thereof | |
| CN104946051A (en) | Healthy and environment-friendly building inner wall coating | |
| CN108976956A (en) | A kind of environment-friendly water-based paint composition and preparation method thereof | |
| CN106947348A (en) | A kind of antibacterial is except emulsion paint of aldehyde and preparation method thereof | |
| CN105478075A (en) | Air-purifying modified nano-composite material for aqueous system | |
| CN108906019A (en) | Nano photo-catalytic | |
| CN105218017A (en) | Based on diatomite ultrafine powder except formaldehyde in indoor air diatom ooze and preparation method thereof | |
| CN106587813A (en) | Multifunctional wall covering material and preparation method thereof | |
| CN109401498A (en) | Ageing-resistant antimicrobial nano coating | |
| KR102294159B1 (en) | Watersoluble Fire Proof Paint for Coating | |
| CN115260891B (en) | Environment-friendly shell powder finishing coating and preparation process thereof | |
| CN105482707A (en) | Formaldehyde-removing waterborne sealing primer used for artificial board |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180615 |