CN108221385A - A kind of environment-friendly type silkete penetrating agent and its production method - Google Patents

A kind of environment-friendly type silkete penetrating agent and its production method Download PDF

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Publication number
CN108221385A
CN108221385A CN201710221490.1A CN201710221490A CN108221385A CN 108221385 A CN108221385 A CN 108221385A CN 201710221490 A CN201710221490 A CN 201710221490A CN 108221385 A CN108221385 A CN 108221385A
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CN
China
Prior art keywords
environment
penetrating agent
friendly type
silkete penetrating
water
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201710221490.1A
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Chinese (zh)
Inventor
傅瑞芳
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SHANGHAI TIANTAN AUXILIARIES CO Ltd
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SHANGHAI TIANTAN AUXILIARIES CO Ltd
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Priority to CN201710221490.1A priority Critical patent/CN108221385A/en
Publication of CN108221385A publication Critical patent/CN108221385A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/262Sulfated compounds thiosulfates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of environment-friendly type silkete penetrating agent and its production methods.It is compounded by three kinds of surfactants and water, including 5 15% alkylol sulfuric ester sodium salt, 40 60% alkyl phosphoric acid ester APEO, 5 15% fatty alcohol polyoxyethylene ether and 20 40% water.Together with alkylol sulfuric ester sodium salt, alkyl phosphoric acid ester APEO and aliphatic amine polyoxyethylene ether these three surfactant compounds, there is synergistic infiltration and peptizaiton, and the resistance to highly basic of these three substances.The environment-friendly type silkete penetrating agent that the present invention is formed by above-mentioned three kinds of surfactants and water compounding, not only with good alkaline-resisting osmotic effect, also with good water solubility.It has quick wetability and permeance property in 15%~20% alkaline media, and moistening and permeance property are good;Still there are wettability and permeability in neutral medium.It is a kind of environment-friendly type silkete penetrating agent wherein without environmentally harmful substance.

Description

A kind of environment-friendly type silkete penetrating agent and its production method
Technical field
The invention belongs to auxiliary chemicals production technical fields, are related to a kind of environment-friendly type silkete penetrating agent and its production method.
Background technology
Mercerization is in order to which cotton fiber is made to generate the same durability gloss of silk, improves the dimensional stability of finished product, The ability for absorbing dyestuff can be also improved simultaneously, and assigns soft fabric and plentiful feel.
In mercerization, using the higher caustic soda of concentration (15%-20%), in continuous mercerized cotton yarn technique, cotton fabric exists Elapsed time generally only has 30-50 seconds in lye, therefore the permeability of mercerising liquid is particularly significant.And in the lye of this concentration In, general bleeding agent can not use, it is necessary to which, using the bleeding agent dedicated for mercerization, therefore, silkete penetrating agent is often made The assistant types special for one.During mercerising, due to the violent contraction of cotton fiber, the permeability of lye is very poor.It uses After silkete penetrating agent, mercerization can be made rapid and uniform, the process time can be shortened, especially to the silk without concise fabric Light, silkete penetrating agent show important especially.
Should mainly have following requirements as silkete penetrating agent:(1) it can be dissolved in mercerising liquid (high alkali liquid), and have excellent Permeability and wetability, are substantially shorter wetting time.(2) resistance to highly basic, maintains a long-term stability in high alkali liquid, effect variation It is small.(3) mercerising liquid is not made to colour and occur stink.
Traditional penetrating power of silkete penetrating agent containing phenol is strong, cheap, but has stink, and spent lye is made to colour or generate Tar and be difficult to recycle, do not meet above-mentioned requirements, and make severe environmental pollution.No phenol mercerising infiltration is currently mainly used Agent.
No phenol silkete penetrating agent is typically all mixture, and alkyl sulphur is generally used in currently used silkete penetrating agent formula For the surfactants such as sour sodium (ABS), alkyl phenol polyoxyethylene ether (APEO) as main component, these substances are harmful to environment, And there are foam it is big the shortcomings of.And the silkete penetrating agent without above-mentioned harmful substance, moistening and permeance property are bad mostly.
Invention content
It is an object of the present invention to overcome the deficiencies of the prior art and provide it is a kind of moistening and permeance property it is good, to environment without Harmful environment-friendly type silkete penetrating agent, that is, environment-friendly type silkete penetrating agent and its production method.
The purpose of the present invention is what is be achieved through the following technical solutions:
The present invention provides a kind of environment-friendly type silkete penetrating agent, it is compounded by three kinds of surfactants and water, each component And mass percent is as follows:Alkylol sulfuric ester sodium salt 5-15%, alkyl phosphoric acid ester APEO 40-60%, poly alkyl alcohol Ethylene oxide ether 5-15%, water 20-40%..
Preferably, each component and mass percent are:Alkylol sulfuric ester sodium salt 10% or so, alkyl phosphate polyoxy second Alkene ether 50% or so, fatty alcohol polyoxyethylene ether 10% or so, water 30% or so.
Wherein, the alkylol is C10-12Natural alcohol;Alkyl in the phosphonate ester is C8;The fatty alcohol is C8-10Natural fatty alcohol;The aggregate number of the alkyl phosphoric acid ester APEO is in 3-5;The fatty alcohol polyoxyethylene ether Aggregate number is in 6-7.
Specifically, the molecular formula of above-mentioned three kinds of substances is:
Alkylol sulfuric ester sodium salt:ROSO3Na R=C10-12
Alkyl phosphoric acid ester APEO ROPO2O(C2H4O)nH R=C8N=3-5
Fatty alcohol polyoxyethylene ether:RO(C2H4O)nH R=C8-10N=6-7
The production method of environment-friendly type silkete penetrating agent of the present invention:
First add water in reaction kettle, then, sequentially add alkylol sulfuric ester sodium salt, alkyl phosphate polyoxy under stiring Vinethene, fatty alcohol polyoxyethylene ether are warming up to 50-60 DEG C or so and are allowed to be uniformly dissolved, and stir 20-60 minutes, as product.
Beneficial effects of the present invention:
The environment-friendly type silkete penetrating agent of the present invention, by alkylol sulfuric ester sodium salt, alkyl phosphoric acid ester APEO, fat These three surfactants of amine polyoxyethylene ether and water compound, and the effect of each component is as follows in formula:
Alkylol sulfuric ester sodium salt has excellent alkaline resistance properties, permeability and water solubility, can be in strong base solution It functions.
Alkyl phosphoric acid ester APEO has extraordinary permeability, good water solubility in strong base solution.
Fatty alcohol polyoxyethylene ether has good alkali resistance, permeability and dispersibility.
The present invention is by countless experiments and gropes to find:Alkylol sulfuric ester sodium salt, alkyl phosphoric acid ester APEO with Aliphatic amine polyoxyethylene ether these three surfactant compounds together, have synergistic infiltration and peptizaiton, moreover, The resistance to highly basic of these three substances.Therefore, the present invention is oozed by the environment-friendly type mercerising that above-mentioned three kinds of surfactants and water compounding form Saturating agent, not only with good alkaline-resisting osmotic effect, also with good water solubility.Experiments have shown that
The silkete penetrating agent of the present invention has quick wetability and permeance property in 15%~20% alkaline media, Moistening and permeance property are good;Still there are wettability and permeability in neutral medium.
In addition, the silkete penetrating agent of the present invention, is gathered using alkylol sulfuric ester sodium salt, the alkyl phosphate of environmental sound Ethylene oxide ether and fatty alcohol polyoxyethylene ether are as main component, wherein without environmentally harmful substance, therefore, it is a kind of green The silkete penetrating agent of color environment-friendly type.
Specific embodiment
The present invention is further illustrated with reference to embodiments.
Embodiment 1
A kind of environment-friendly type silkete penetrating agent of the present invention, it is compounded by three kinds of surfactants and water, each component and matter It is as follows to measure percentage:Alkylol sulfuric ester sodium salt 10%, alkyl phosphoric acid ester APEO 50%, fatty alcohol polyoxyethylene ether 10%, water 30%.
Wherein, alkylol is the natural alcohol of C10-12;Alkyl in phosphonate ester is C8;Fatty alcohol is the day of C8-10 Right fatty alcohol;The aggregate number of alkyl phosphoric acid ester APEO is in 3-5;The aggregate number of fatty alcohol polyoxyethylene ether is in 6-7.
The production method of above-mentioned environment-friendly type silkete penetrating agent:
First add water in reaction kettle, then, sequentially add alkylol sulfuric ester sodium salt, alkyl phosphate polyoxy under stiring Vinethene, fatty alcohol polyoxyethylene ether are warming up to 55 DEG C or so and are allowed to be uniformly dissolved, and stir 30 minutes, as product.
Embodiment 2
A kind of environment-friendly type silkete penetrating agent of the present invention, it is compounded by three kinds of surfactants and water, each component and matter It is as follows to measure percentage:Alkylol sulfuric ester sodium salt 15%, alkyl phosphoric acid ester APEO 40%, fatty alcohol polyoxyethylene ether 5%, water 40%.
Wherein, alkylol is the natural alcohol of C10-12;Alkyl in phosphonate ester is C8;Fatty alcohol is the day of C8-10 Right fatty alcohol;The aggregate number of alkyl phosphoric acid ester APEO is in 3-5;The aggregate number of fatty alcohol polyoxyethylene ether is in 6-7.
The production method of above-mentioned environment-friendly type silkete penetrating agent:
First add water in reaction kettle, then, sequentially add alkylol sulfuric ester sodium salt, alkyl phosphate polyoxy under stiring Vinethene, fatty alcohol polyoxyethylene ether are warming up to 60 DEG C or so and are allowed to be uniformly dissolved, and stir 20 minutes, as product.
Embodiment 3
A kind of environment-friendly type silkete penetrating agent of the present invention, it is compounded by three kinds of surfactants and water, each component and matter It is as follows to measure percentage:Alkylol sulfuric ester sodium salt 5%, alkyl phosphoric acid ester APEO 60%, fatty alcohol polyoxyethylene ether 15%, water 20%.
Wherein, alkylol is the natural alcohol of C10-12;Alkyl in phosphonate ester is C8;Fatty alcohol is the day of C8-10 Right fatty alcohol;The aggregate number of alkyl phosphoric acid ester APEO is in 3-5;The aggregate number of fatty alcohol polyoxyethylene ether is in 6-7.
The production method of above-mentioned environment-friendly type silkete penetrating agent:
First add water in reaction kettle, then, sequentially add alkylol sulfuric ester sodium salt, alkyl phosphate polyoxy under stiring Vinethene, fatty alcohol polyoxyethylene ether are warming up to 50 DEG C or so and are allowed to be uniformly dissolved, and stir 60 minutes, as product.
Application test example:
The environment-friendly type silkete penetrating agent of above-described embodiment 1-3, product reach following physical and chemical index:
Application test shows that above-mentioned environment-friendly type silkete penetrating agent is respectively provided with following characteristic:In 15%~20% alkaline media With quick wetability and permeance property, still there are moistening and permeability in neutral medium
Application range:
Above-mentioned environment-friendly type silkete penetrating agent, the silkete penetrating agent being mainly used as in the processing of cotton fiber mercerising, can improve mercerising Effect shortens the mercerising time, and especially suitable for quick mercerising and fabric mercerization, this product also also serves as other highly basic media Bleeding agent.
Application process:
Above-mentioned silkete penetrating agent is mainly used for the mercerizing process in cotton fiber processing, is moistened in 15~20% aqueous slkali Osmotic effect is best, and general dosage is 3~7 g/l.
Permeate force test method:
The penetration test of above-mentioned silkete penetrating agent is measured according to the regulation of HG/T 2575, at 25 DEG C, 6.5g/L Penetration of the sample in 20%NaOH solution it is suitable with the standard items of penetrating agent JFC 0.9g/L (distilled water), i.e. penetration It is 100%.

Claims (8)

1. a kind of environment-friendly type silkete penetrating agent, which is characterized in that it is compounded by three kinds of surfactants and water, each component and Mass percent is as follows:Alkylol sulfuric ester sodium salt 5-15%, alkyl phosphoric acid ester APEO 40-60%, fatty alcohol polyoxy Vinethene 5-15%, water 20-40%.
2. environment-friendly type silkete penetrating agent as described in claim 1, which is characterized in that each component and mass percent are:Alkyl Alcohol sulfuric ester sodium salt 10%, alkyl phosphoric acid ester APEO 50%, fatty alcohol polyoxyethylene ether 10%, water 30%.
3. environment-friendly type silkete penetrating agent as claimed in claim 1 or 2, which is characterized in that the alkylol is C10-12It is natural Alcohol.
4. environment-friendly type silkete penetrating agent as claimed in claim 1 or 2, which is characterized in that the alkyl in the phosphonate ester For C8
5. environment-friendly type silkete penetrating agent as claimed in claim 1 or 2, which is characterized in that the fatty alcohol is C8-10Natural grease Fat alcohol.
6. environment-friendly type silkete penetrating agent as claimed in claim 1 or 2, which is characterized in that the alkyl phosphate polyoxyethylene The aggregate number of ether is in 3-5.
7. environment-friendly type silkete penetrating agent as claimed in claim 1 or 2, which is characterized in that the fatty alcohol polyoxyethylene ether Aggregate number is in 6-7.
8. the production method of a kind of environment-friendly type silkete penetrating agent as described in claim 1-7 is any, which is characterized in that reacting First add water in kettle, then, sequentially add alkylol sulfuric ester sodium salt, alkyl phosphoric acid ester APEO, fatty alcohol under stiring Polyoxyethylene ether is warming up to 50-60 DEG C and is allowed to be uniformly dissolved, and stirs 20-60 minutes, as product.
CN201710221490.1A 2017-04-06 2017-04-06 A kind of environment-friendly type silkete penetrating agent and its production method Pending CN108221385A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113186725A (en) * 2021-05-21 2021-07-30 江南大学 Environment-friendly mercerizing penetrating agent for cotton fabrics and preparation method thereof
CN113529270A (en) * 2021-07-06 2021-10-22 稳健医疗(武汉)有限公司 Light and thin water-absorbing mercerized all-cotton non-woven fabric, preparation method and application thereof and disposable clothing
CN116856172A (en) * 2023-07-12 2023-10-10 广东尚朴新材料有限公司 An anti-pilling and anti-shrinking mercerized cotton knitted fabric and its preparation process

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113186725A (en) * 2021-05-21 2021-07-30 江南大学 Environment-friendly mercerizing penetrating agent for cotton fabrics and preparation method thereof
CN113186725B (en) * 2021-05-21 2022-03-25 江南大学 A kind of environment-friendly mercerizing penetrant for cotton fabric and preparation method thereof
CN113529270A (en) * 2021-07-06 2021-10-22 稳健医疗(武汉)有限公司 Light and thin water-absorbing mercerized all-cotton non-woven fabric, preparation method and application thereof and disposable clothing
CN116856172A (en) * 2023-07-12 2023-10-10 广东尚朴新材料有限公司 An anti-pilling and anti-shrinking mercerized cotton knitted fabric and its preparation process
CN116856172B (en) * 2023-07-12 2024-04-09 广东尚朴新材料有限公司 Anti-pilling anti-shrinkage mercerized cotton knitted fabric and preparation process thereof

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Application publication date: 20180629