CN108221390A - A kind of silk fabric hydrophilic softening agent and preparation method thereof - Google Patents
A kind of silk fabric hydrophilic softening agent and preparation method thereof Download PDFInfo
- Publication number
- CN108221390A CN108221390A CN201711328093.0A CN201711328093A CN108221390A CN 108221390 A CN108221390 A CN 108221390A CN 201711328093 A CN201711328093 A CN 201711328093A CN 108221390 A CN108221390 A CN 108221390A
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- China
- Prior art keywords
- silk fabric
- softening agent
- hydrophilic softening
- quaternary ammonium
- acid
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- Granted
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- 239000004744 fabric Substances 0.000 title claims abstract description 64
- 239000004902 Softening Agent Substances 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- -1 amido silicon Chemical compound 0.000 claims abstract description 32
- 150000002500 ions Chemical class 0.000 claims abstract description 29
- 239000003921 oil Substances 0.000 claims abstract description 25
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 23
- 239000010703 silicon Substances 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 20
- 239000008367 deionised water Substances 0.000 claims abstract description 18
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 18
- 239000012875 nonionic emulsifier Substances 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 13
- 150000002148 esters Chemical class 0.000 claims abstract description 13
- 150000007524 organic acids Chemical class 0.000 claims abstract description 11
- 150000003839 salts Chemical class 0.000 claims abstract description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 32
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 18
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 16
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 16
- 150000003333 secondary alcohols Chemical class 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Natural products CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 9
- 239000001632 sodium acetate Substances 0.000 claims description 9
- 235000017281 sodium acetate Nutrition 0.000 claims description 9
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 6
- 238000012856 packing Methods 0.000 claims description 6
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- 229960004275 glycolic acid Drugs 0.000 claims description 2
- 150000001261 hydroxy acids Chemical class 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000001509 sodium citrate Substances 0.000 claims description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 2
- 235000019441 ethanol Nutrition 0.000 claims 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 244000248349 Citrus limon Species 0.000 claims 1
- 235000005979 Citrus limon Nutrition 0.000 claims 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims 1
- 150000001447 alkali salts Chemical class 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 238000002242 deionisation method Methods 0.000 claims 1
- 239000002932 luster Substances 0.000 abstract description 4
- 239000004753 textile Substances 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 17
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 230000010148 water-pollination Effects 0.000 description 7
- 229920013822 aminosilicone Polymers 0.000 description 6
- 229920002545 silicone oil Polymers 0.000 description 6
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 5
- 239000005695 Ammonium acetate Substances 0.000 description 5
- 229940043376 ammonium acetate Drugs 0.000 description 5
- 235000019257 ammonium acetate Nutrition 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 150000001408 amides Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000003368 amide group Chemical group 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 1
- 150000008431 aliphatic amides Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 210000000085 cashmere Anatomy 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000675 fabric finishing Substances 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 238000009962 finishing (textile) Methods 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 238000002559 palpation Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 230000008733 trauma Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/11—Oleophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of silk fabric hydrophilic softening agents and preparation method thereof, belong to textile fabric softening agent field.The silk fabric is made of by mass percentage with hydrophilic softening agent following components：Amphoteric ion type amido silicon oil is 1%~20%, ester based quaternary ammonium salt is 5%~20%, nonionic emulsifier is 1%~10%, strong base-weak acid salt is 0.1~0.5%, organic acid is 0.1~0.5% and deionized water is surplus.The mutual coordinated of each component in the silk fabric hydrophilic softening agent of the present invention, quality stability is good, it can not only assign silk fabric soft, fluffy, elegant feel, and not influence splitting and the color and luster of silk fabric, while increase the hydrophile function of silk fabric.
Description
Technical field
The invention belongs to textile fabric softening agent fields, and in particular to a kind of silk fabric hydrophilic softening agent.
Background technology
Silk is with the feel of the wearability of its comfort health-care, the appearance of elegant pendency and smooth pliable, as high-end
Garment material is got the favour of people.Silk fabric is generally aliphatic amide type softening agent, cation form with softening agent at present
Face activating agent and a small amount of amino-modified silicone oil are used cooperatively, and only have the function of single improvement feel, and quality is steady
Qualitative, hydrophily and feel are to be improved.
Chinese patent 201210426114.3 (notification number CN 102952273B) discloses a kind of amphoteric ion type amino silicone
Oil, the lotion of the amphoteric ion type amido silicon oil have higher stability, and when handling fabric with higher reaction
Property, treated fabric have good yellowing resistance, washability and fluffy sense.But directly use the amphoteric ion type amino
The hydrophily and feel of silicone oil processing fabric need to be improved, and also not publicly use the amphoteric ion type amino in the prior art
The softening agent for being suitable for silk fabric and using prepared by silicone oil.
Invention content
Therefore in order to overcome the problems of the above-mentioned prior art, the purpose of the present invention is to provide a kind of silk fabrics
With hydrophilic softening agent, silk fabric provided by the invention is good with hydrophilic softening agent quality stability, can not only assign silk fabric
Soft, fluffy, elegant feel, and splitting and the color and luster of silk fabric are not influenced, while increase the hydrophily of silk fabric
Energy.
The silk fabric of the present invention is made of by mass percentage with hydrophilic softening agent following components：Amphoteric ion type amino
Silicone oil is 1%~20%, ester based quaternary ammonium salt is 5%~20%, nonionic emulsifier is 1%~10%, strong base-weak acid salt 0.1
~0.5%, organic acid is 0.1~0.5% and deionized water is surplus；
Preferably, component is by mass percentage：Amphoteric ion type amido silicon oil is 5~20%, ester based quaternary ammonium salt 5
~15%, nonionic emulsifier is 3~10%, strong base-weak acid salt is 0.2~0.5%, organic acid is 0.3% and deionized water is
Surplus.
It is further preferred that its component is by mass percentage：Amphoteric ion type amido silicon oil is 5%, ester based quaternary ammonium salt
For 15%, nonionic emulsifier 3%, strong base-weak acid salt 0.2%, organic acid is 0.3% and deionized water is surplus.
The amphoteric ion type amido silicon oil is represented by the formula,
Wherein, R1For C1~C12Alkyl, alkoxy or hydroxyl；R2For methyl or hydroxyl；R3For monoamine group；R4For
Anion-modified monoamine group；X, y, z are positive integer, 5≤x+y+z≤1000.
Preferably,
It is further preferred that R1=CH3；R2=hydroxyl；X=10, y=5, z=200.
Preferably, the ester based quaternary ammonium salt is triethanolamine ester based quaternary ammonium salt and N, N- bis- (amido-ethyl)-methyl season
One kind or composition in ammonium salt.
Preferably, the nonionic emulsifier is isomeric alcohol polyethenoxy ether or secondary alcohol polyoxyethylene ether.
Preferably, the isomeric alcohol polyethenoxy ether is preferredOne or both of XP's 50 and XP 90
Mixing,XP 50 and XP 90 is the trade mark of isomeric alcohol polyethenoxy ether that BASF provides；The secondary alcohol polyoxy second
Alkene ether is preferredThe mixing of one or both of 15-S-5,15-S-9,15-S-12 and 15-S-15,15-S-9,15-S-12 and 15-S-15 are the trade mark of secondary alcohol polyoxyethylene ether that DOW Chemical provides.
Further, the preferred XP50 of the isomeric alcohol polyethenoxy ether：XP90=1：4 mixing isomery alcohol polyoxyethylene
Ether.
Or further, the preferred 15-S-5 of secondary alcohol polyoxyethylene ether：15-S-9=3：7、15-S-5：15-S-12
=2：3 or 15-S-5：15-S-15=1：1 mixing secondary alcohol polyoxyethylene ether.
Preferably, the strong base-weak acid salt is one kind or two in ammonium acetate, sodium acetate, hydroxy acid sodium and sodium citrate
Kind or more (including two kinds).
Preferably, the organic acid is one or more of acetic acid, citric acid, hydroxyacetic acid and terephthalic acid (TPA)
(including two kinds).
The present invention also aims to provide the preparation method of the silk fabric hydrophilic softening agent, the method according to
Following step carries out：
It is matched according to above-mentioned raw materials, amphoteric ion type amido silicon oil and non-ionic emulsifier is first added in variable-ratio mixer
Agent stirs evenly, then add ester based quaternary ammonium salt stirring, finally by proportioning be slowly added to strong base-weak acid salt, organic acid and go from
Sub- water, emulsion reaction；Stir evenly packing.
The positive effect of the present invention is：
Compared with prior art, the amphoteric ion type amido silicon oil in silk fabric hydrophilic softening agent of the invention, both
The unmodified amido silicon oil in part is remained, and increases anionic hydrophilic group, quaternary ammonium cationic groups and hydroxyl.By this
Silk fabric after silicone oil emulsion arrangement, the softness of the existing silk fabric after amido silicon oil arranges, elegant feel, simultaneously
The yellowing of fabric is reduced again；Hydroxyl in silicone oil structure can carry out dehydrating condensation with hydroxyl, the carboxyl in fabric, improve it
Reactivity, washability；The presence of quaternary ammonium cation in silicone oil structure can improve the fluffy sense after Application for Silk Fabric Finishing.This is soft
Ester based quaternary ammonium salt in soft dose, not only irritation is small, but also is compounded with amphoteric ion type amido silicon oil, can effectively improve processing and knit
The feel and hydrophilicity of object.And nonionic emulsifier can effectively improve emulsifying effectiveness when preparing softening agent, promote softening agent
Stability.Strong base-weak acid salt and organic acid can further improve the quality stability of softening agent as pH adjusting agent.It is above-mentioned each
The mutual coordinated of component so that silk fabric of the invention is good with hydrophilic softening agent quality stability, can not only assign silk
Soft fabric, fluffy, elegant feel, and splitting and the color and luster of silk fabric are not influenced, while increase the parent of silk fabric
Aqueous energy.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail, it should be understood that these embodiments are merely to illustrate this hair
Bright rather than the limitation present invention application range.
Amphoteric ion type amido silicon oil is purchased from Shanghai Fu Ju chemical products limited company, model in following embodiment
SF6150；Ester based quaternary ammonium salt is triethanolamine ester based quaternary ammonium salt and N, N- bis- (amido-ethyl)-methyl quaternary ammonium；Nonionic Emulsion
Agent secondary alcohol polyoxyethylene ether is purchased from BASF or DOW Chemical；Variable-ratio mixer is purchased from IKA, model
RW20digitil。
Amphoteric ion type amido silicon oil SF6150 is represented by the formula：
Wherein, R1=CH3；R2=hydroxyl；
X=10, y=5, z=200.
Embodiment 1
A kind of silk fabric hydrophilic softening agent of the present invention, component and mass percent are as follows：Amphoteric ion type amino silicone
Oily SF 6150 is that 5%, N, N- bis- (amido-ethyl)-methyl quaternary ammonium is 15%, nonionic emulsifier XP50：XP90=1：4
Isomeric alcohol polyethenoxy ether be 3%, sodium acetate 0.2%, citric acid are 0.3% and deionized water is 76.5%.
Preparation process：In variable-ratio mixer amphoteric ion type amido silicon oil SF 6150 and nonionic are first added in by proportioning
Emulsifier XP50：XP90=1：4 isomeric alcohol polyethenoxy ether stirs evenly, and then adds in N, bis- (amide groups of N- by proportioning again
Ethyl) stirring of-methyl quaternary ammonium, finally sodium acetate, citric acid and deionized water, emulsion reaction are slowly added to by proportioning.Stirring
Uniformly packing.
Embodiment 2
A kind of silk fabric hydrophilic softening agent of the present invention, component and mass percent are as follows：Amphoteric ion type amino silicone
Oily SF 6150 is 15%, N, N- bis- (amido-ethyl)-methyl quaternary ammonium and triethanolamine ester based quaternary ammonium salt 1：1 is mixed into
10%th, nonionic emulsifier 15-S-5：15-S-9=3：7 secondary alcohol polyoxyethylene ether is 8%, sodium acetate 0.5%, acetic acid are
0.3% and deionized water be 66.2%.
Preparation process：In variable-ratio mixer amphoteric ion type amido silicon oil SF 6150 and nonionic are first added in by proportioning
Emulsifier 15-S-5：15-S-9=3：7 secondary alcohol polyoxyethylene ether stirs evenly, and then adds in N, bis- (amides of N- by proportioning again
Base ethyl)-methyl quaternary ammonium and triethanolamine ester based quaternary ammonium salt mixture stirring, be finally slowly added to sodium acetate, second by proportioning
Acid and deionized water, emulsion reaction.Stir evenly packing.
Embodiment 3
A kind of silk fabric hydrophilic softening agent of the present invention, component and mass percent are as follows：Amphoteric ion type amino silicone
Oily SF 6150 is 20%, triethanolamine ester based quaternary ammonium salt is 5%, nonionic emulsifier 15-S-5：15-S-12=2：3 secondary alcohol
Polyoxyethylene ether is 10%, ammonium acetate 0.2%, acetic acid are 0.3% and deionized water is 64.5%.
Preparation process：In variable-ratio mixer amphoteric ion type amido silicon oil SF 6150 and nonionic are first added in by proportioning
Emulsifier 15-S-5：15-S-12=2：3 secondary alcohol polyoxyethylene ether stirs evenly, then again by proportioning triethanolamine ester group season
Ammonium salt stirs, and is finally slowly added to ammonium acetate, acetic acid and deionized water, emulsion reaction by proportioning.Stir evenly packing.
Embodiment 4
A kind of silk fabric hydrophilic softening agent of the present invention, component and mass percent are as follows：Amphoteric ion type amino silicone
Oily SF 6150 is that 1%, N, N- bis- (amido-ethyl)-methyl quaternary ammonium is 20%, nonionic emulsifier 15-S-5：15-S-15
=1：1 secondary alcohol polyoxyethylene ether is 2%, sodium acetate 0.2%, acetic acid are 0.3% and deionized water is 76.5%.
Preparation process：In variable-ratio mixer amphoteric ion type amido silicon oil SF 6150 and nonionic are first added in by proportioning
Emulsifier 15-S-5：15-S-15=1：1 secondary alcohol polyoxyethylene ether stirs evenly, and then adds in N, bis- (amides of N- by proportioning again
Base ethyl) stirring of-methyl quaternary ammonium, finally sodium acetate, acetic acid and deionized water, emulsion reaction are slowly added to by proportioning.Stirring
Uniformly packing.
Comparative example 1
Common silk softening agent, component and mass percent are as follows currently on the market：Amino modified siloxanes 6%, fat
Fat race amides softening agent is 8%, cationic surfactant 6%, emulsifier 3%, acetic acid is 0.2% and deionized water
It is 76.8%.
Comparative example 2
Component and mass percent are as follows：Amphoteric ion type amido silicon oil SF 6150 is 14%, nonionic emulsifier 15-
S-5：15-S-9=3：7 secondary alcohol polyoxyethylene ether is 7%, ammonium acetate 0.2%, acetic acid are 0.3% and deionized water is
78.5%.
Comparative example 3
Component and mass percent are as follows：Amphoteric ion type amido silicon oil SF 6150 is 5%, (the amide groups second of N, N- bis-
Base)-methyl quaternary ammonium for 15%, nonionic emulsifier XP50：XP90=1：4 isomeric alcohol polyethenoxy ether is 3%, citric acid
It is 76.7% for 0.3% and deionized water.
Comparative example 4
Component and mass percent are as follows：Triethanolamine ester based quaternary ammonium salt is 20%, ammonium acetate 0.2%, acetic acid are
0.3% and deionized water be 79.5%.
The preparation process of comparative example 1~4 is with reference to the preparation process of Examples 1 to 4.
Effect example
With the dressing liquid of the product configuration 10g/L made by above-mentioned Examples 1 to 4 and comparative example 1~4, yarn rule are arranged
The true qualities weight crape silk fabric that lattice are No. 2.8.It two is rolled through two leachings, liquid carrying rate control is treated back after 120 degrees Celsius of drying 60%
Following performance test is carried out after tide：
(1) feel
By 5 seasoned professionals feel is evaluated with digital palpation for examination of trauma.1 grade shows that feel is worst, and 5 grades show feel most
It is good.
(2) hydrophily
According to AATCC 79-2000《The water imbibition of textile measures》It measures, respiratory time is faster, and surface hydrophilicity is got over
It is good.
(3) whiteness
Whiteness is detected using SBDY-1 digital display whiteness instrument.Numerical value shows that more greatly whiteness is better.
The application performance of the silk fabric hydrophilic softening agent of 1 present invention of table
| Fabric | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| Feel/grade | 1 | 4 | 4 | 4 | 3 |
| Hydrophily/s | 120 | 5 | 8 | 15 | 4 |
| Whiteness/% | 72 | 71.6 | 71.5 | 71.2 | 71.8 |
The application performance of the corresponding comparative example of 2 present invention of table
| Fabric | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 | |
| Feel/grade | 1 | 3 | 4 | 3 | 2 |
| Hydrophily/s | 120 | >600 | 25 | 6 | 4 |
| Whiteness/% | 72 | 71 | 71.2 | 71.5 | 72 |
The not only quality stability of silk fabric hydrophilic softening agent made from the embodiment of the present invention 1~4 is fabulous, but also from table
1 and 2 as can be seen that treated that silk fabric not only has using silk fabric hydrophilic softening agent made from Examples 1 to 4
Preferable feel, and hydrophily also greatly improves.
Compared to embodiment 1, comparative example 1 is common cashmere softening agent in the market, and compositional difference is larger, and comparative example 2
Be not added with ester based quaternary ammonium salt, comparative example 3 is not added with sodium acetate, comparative example 4 be not added with amphoteric ion type amido silicon oil SF6150 and
Nonionic emulsifier.Contrast table 1 and 2 is it can be found that use treated the silk of silk fabric hydrophilic softening agent made from embodiment 1
Silk fabric fabric, the silk fabric than the processing of comparative example 1~4 show clear superiority, while whiteness in feel and hydrophilicity
Substantially without influence.Wherein treated that fabric feeling is preferable for comparative example 2, it is hydrophilic still, but fabric can dissolve splitting, influence to make
Use performance.It can be seen that each component plays a key effect in the present invention, the mutual coordinated of each component so that silk of the invention
Silk fabric fabric softener quality stability is good, can not only assign silk fabric soft, fluffy, elegant feel, and do not influence silk
The splitting of silk fabric fabric and color and luster, while increase the hydrophilicity of silk fabric.
The preferred embodiment of the invention is illustrated above, but the invention be not limited to it is described
Embodiment, those skilled in the art can also make various be equal under the premise of without prejudice to the invention spirit
Modification or replacement, these equivalent modifications or replacement are all contained in the application claim limited range.
Claims (10)
1. a kind of silk fabric hydrophilic softening agent is made of by mass percentage following components：Amphoteric ion type amido silicon oil
For 1%~20%, ester based quaternary ammonium salt be 5%~20%, nonionic emulsifier is 1%~10%, strong base-weak acid salt be 0.1~
0.5%th, organic acid is 0.1~0.5% and deionized water is surplus.
2. silk fabric hydrophilic softening agent according to claim 1, which is characterized in that its component is by mass percentage
For：Amphoteric ion type amido silicon oil is 5~20%, ester based quaternary ammonium salt is 5~15%, nonionic emulsifier is 3~10%, highly basic
Salt of weak acid is 0.2~0.5%, organic acid is 0.3% and deionized water is surplus.
3. silk fabric hydrophilic softening agent according to claim 1, which is characterized in that the amphoteric ion type amido silicon oil
General formula it is as follows,
Wherein, R1For C1~C12Alkyl, alkoxy or hydroxyl；R2For methyl or hydroxyl；R3For monoamine group；R4For anion
Modified monoamine group；X, y, z are positive integer, 5≤x+y+z≤1000.
4. silk fabric hydrophilic softening agent according to claim 3, which is characterized in that
5. silk fabric hydrophilic softening agent according to claim 1, which is characterized in that the ester based quaternary ammonium salt is three ethyl alcohol
Amine ester based quaternary ammonium salt and one kind or composition in N, N- bis- (amido-ethyl)-methyl quaternary ammonium.
6. a kind of silk fabric hydrophilic softening agent according to claim 1, which is characterized in that the nonionic emulsifier is
Isomeric alcohol polyethenoxy ether or secondary alcohol polyoxyethylene ether.
7. silk fabric hydrophilic softening agent according to claim 6, which is characterized in that wherein isomeric alcohol polyethenoxy ether is
XP50：XP90=1：4 mixing isomeric alcohol polyethenoxy ether, wherein secondary alcohol polyoxyethylene ether are 15-S-5：15-S-9=3：7、
15-S-5：15-S-12=2：3 or 15-S-5：15-S-15=1：1 mixing secondary alcohol polyoxyethylene ether.
8. silk fabric hydrophilic softening agent according to claim 1, which is characterized in that the strong base-weak acid salt is acetic acid
One or more of ammonium, sodium acetate, hydroxy acid sodium and sodium citrate.
9. silk fabric hydrophilic softening agent according to claim 1, which is characterized in that the organic acid is acetic acid, lemon
One or more of acid, hydroxyacetic acid and terephthalic acid (TPA).
10. the preparation method of silk fabric hydrophilic softening agent described in claim 1, carries out as steps described below：
It is matched according to above-mentioned raw materials, first adds in amphoteric ion type amido silicon oil in variable-ratio mixer and nonionic emulsifier stirs
It mixes uniformly, then adds ester based quaternary ammonium salt stirring, be finally slowly added to strong base-weak acid salt, organic acid and deionization by proportioning
Water, emulsion reaction；Stir evenly packing.
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Denomination of invention: A hydrophilic softener for silk fabrics and its preparation method Effective date of registration: 20231219 Granted publication date: 20210319 Pledgee: Shanghai Rural Commercial Bank Co.,Ltd. Jinshan sub branch Pledgor: SHANGHAI SHINCHEM CHEMICALS CO.,LTD. Registration number: Y2023310000888 |