CN108221493A - A kind of wallpaper base paper and preparation method thereof - Google Patents
A kind of wallpaper base paper and preparation method thereof Download PDFInfo
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- CN108221493A CN108221493A CN201711488017.6A CN201711488017A CN108221493A CN 108221493 A CN108221493 A CN 108221493A CN 201711488017 A CN201711488017 A CN 201711488017A CN 108221493 A CN108221493 A CN 108221493A
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- wallpaper base
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- retardant
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- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000003063 flame retardant Substances 0.000 claims abstract description 55
- 239000000835 fiber Substances 0.000 claims abstract description 44
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000004816 latex Substances 0.000 claims abstract description 29
- 229920000126 latex Polymers 0.000 claims abstract description 29
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 24
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 22
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 22
- 241001330002 Bambuseae Species 0.000 claims abstract description 22
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 22
- 239000011425 bamboo Substances 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 15
- 239000003292 glue Substances 0.000 claims abstract description 12
- 239000011265 semifinished product Substances 0.000 claims abstract description 12
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims abstract description 11
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims abstract description 11
- 238000007598 dipping method Methods 0.000 claims abstract description 7
- 238000004026 adhesive bonding Methods 0.000 claims abstract description 4
- 238000003490 calendering Methods 0.000 claims abstract description 4
- 238000001035 drying Methods 0.000 claims abstract description 4
- WNVQCJNZEDLILP-UHFFFAOYSA-N dimethyl(oxo)tin Chemical group C[Sn](C)=O WNVQCJNZEDLILP-UHFFFAOYSA-N 0.000 claims description 7
- 230000008859 change Effects 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- -1 trihydroxy methyl phosphorous Chemical compound 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 238000010009 beating Methods 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 210000002966 serum Anatomy 0.000 claims description 3
- 238000004513 sizing Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 claims 1
- KIGXMYYGQYMICF-UHFFFAOYSA-N Diphenylphosphine Acid Chemical class C=1C=CC=CC=1P(=O)(CCCCC(=O)O)C1=CC=CC=C1 KIGXMYYGQYMICF-UHFFFAOYSA-N 0.000 claims 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims 1
- 235000011150 stannous chloride Nutrition 0.000 claims 1
- 239000001119 stannous chloride Substances 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 14
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 241000894006 Bacteria Species 0.000 description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 5
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 5
- RJGHQTVXGKYATR-UHFFFAOYSA-L dibutyl(dichloro)stannane Chemical compound CCCC[Sn](Cl)(Cl)CCCC RJGHQTVXGKYATR-UHFFFAOYSA-L 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 235000010290 biphenyl Nutrition 0.000 description 4
- 239000004305 biphenyl Substances 0.000 description 4
- 125000006267 biphenyl group Chemical group 0.000 description 4
- 238000001354 calcination Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 230000001408 fungistatic effect Effects 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/34—Ignifugeants
Landscapes
- Paper (AREA)
Abstract
A kind of wallpaper base paper includes the component of following parts by weight：20~35 parts of bamboo fibre, 15~75 parts of gou-tree fibre, 10~25 parts of sodium carboxymethylcellulose, 12~18 parts of acrylic latex, 2~4 parts of fire retardant, 2~4 parts of modifying agent；Its production method is to make base paper semi-finished product making modified flame-retardant liquid glue application solution using bamboo fibre and gou-tree fibre to batch the drying gelatinization calendering of base paper semi-finished product dipping and gluing liquid.The beneficial effects of the invention are as follows：Not only good flame retardation effect, and can keep the fire-retardant of anti-flammability for a long time also has effects that good antibacterial, antibacterial.
Description
Technical field
The present invention relates to wallpaper base paper Material Field field, and in particular to a kind of wallpaper base paper and preparation method thereof.
Background technology
Common material when wall paper is current wall surfacing.When socket leaks electricity or has open fire, the resistance of metope wallpaper base paper
Fuel efficiency fruit can prevent the sprawling of fire.Wallpaper base paper is the main base material of flame wallpaper production, can be carried out in wallpaper base paper
Coat fire-retardant glue-line, painted, stamp, embossing, be fabricated to exquisite flame wallpaper, but existing flame wallpaper cannot be done
To two-sided fire-retardant, the one side for often coating fire-retardant glue-line can be fire-retardant to open fire, but the one side of wallpaper base paper is not fire-retardant.Existing resistance
It is as follows to fire the main reason for wallpaper base paper flame retardant property is undesirable.
Firstly, since hard copy body has the characteristics that combustible, the existing practical highest flame retardant rating of flame-retardant wallpaper base paper can only
Reach that B2 grades flammable or B3 grades inflammable.When there is open fire, existing flame-retardant wallpaper base paper still can burn rapidly, can not actually play
Fireproof flame-retardant effect, there are larger security risks.
Secondly, in the production of existing flame-retardant wallpaper base paper, mostly using fire retardant chemistry fiber or with fire-retardant latex as raw material
To improve the anti-flammability of flame-retardant wallpaper base paper, but fire retardant chemistry fiber and fire retardant glue breast are expensive, and fire retardant chemistry per ton is fine
Dimension, fire retardant glue breast valency lattice are up to ten thousand yuan or more, compared to there are huge on cheap, not fire-retardant chemical fibre and latex price
Gap causes flame-retardant wallpaper base paper production cost excessively high, lacks the market competitiveness.
Finally, it is directly mixed into slurry the prior art mainly adopts fire retardant and base paper semi-finished product is made, rear Dipped latex
Mode produce flame-retardant wallpaper base paper.But the wallpaper base paper flame retardant effect that existing method obtains is not lasting, and whiteness mistake
It is low.When being often detected to the base paper just produced, wallpaper base paper can have preferable flame retardant effect and higher whiteness；
But when being put into after warehouse 3-7 days sampling Detection again, wallpaper base paper, which can lead to the problem of flame retardant property, reduces or loses anti-flammability.
In addition, in order to adapt to the needs of special space environment, such as the field that hospital, school be crowded and bacterium is easily propagated
Institute, the wallpaper as decorative material for internal wall should have the function of antibacterial.Chinese patent 201210147905.2 discloses one
Kind antibacterial wallpaper and preparation method thereof, uses inorganic silver antibacterial agent to be added in ink, plays the effect of antibacterial.The method is adopted
With the very high inorganic silver antibacterial agent of cost, many consumers can not bear its fancy price, therefore, people there is an urgent need to
A kind of new good and cheap antibacterial wallpaper.
In summary, the use of wallpaper matrix is very crucial, and existing wallpaper matrix there is flame retardant effect difference and not
Anti-flammability, deficiency of high cost and poor antibacterial can be kept for a long time.
Invention content
The object of the present invention is to provide a kind of low-cost wallpaper base paper, its not only good flame retardation effect, and can be long when
Between keep anti-flammability it is fire-retardant, also there is antibacterial.
Another object of the present invention is just to provide a kind of preparation method of above-mentioned purpose mesospore paper substrate paper.
It is realized the purpose of the present invention is technical solution in this way, a kind of wallpaper base paper, including following parts by weight
Component：20~35 parts of bamboo fibre, 15~75 parts of gou-tree fibre, 10~25 parts of sodium carboxymethylcellulose, acrylic latex 12~18
Part, 2~4 parts of fire retardant, 2~4 parts of modifying agent.
Further, acrylic latex is acrylic latex KJR-01.
Further, fire retardant is trihydroxy methyl phosphorous oxide or diphenyl phosphoester.
Further, modifying agent is dimethyl tin oxide or/and dibutyl tin dichloride.
It is realized it is another object of the present invention to technical solution in this way, a kind of production method of wallpaper base paper,
Step is：
S1 adds in the water that weight is 85-108 times, is beaten, beaten with beater after mixing bamboo fibre and gou-tree fibre
The degree of beating is controlled in 60~62OSR；
S2 adds in sodium carboxymethylcellulose and is stirred evenly in mixed serum；
Mixing slurry is made base paper semi-finished product by S3 by copy paper, squeezing, drying, coiling process；
Fire retardant and modifying agent are mixed evenly and obtain modified flame-retardant liquid, modified flame-retardant liquid is stood by S4 in mass ratio
It adds in acrylic latex and stirs evenly acquisition glue application solution；
S5, base paper semi-finished product dipping and gluing liquid on sizing coating machine, dip time 8~22 minutes, dipping temperature 25~
48℃；
Then S6 dries glue by hot air circulating system at 250~280 DEG C to the glue application solution permeated in base paper semi-finished product
Change, batched through surface machinery calendering, 92~116g/m of paper grammes per square metre is made into2Wallpaper base paper.
A kind of wallpaper base paper of the present invention, bamboo fiber products have natural antibacterial, antibacterial, sterilization effect, because of bamboo
The inside has a kind of unique substance, which is named as " bamboo a kind of jade ", has the function of naturally antibacterial, anti-mite, deodorization, insect prevention.
Observe under the microscope, bacterium in the fibres such as cotton, wood can amount reproduction, and the bacterium on bamboo fiber products is not only not
It can survive for a long time, and can also disappear or reduce in the short time, bacterial death rate is up to more than 75% in 24 hours.Japanese authority
The new discovery of mechanism increases this value-added content of product, by Chinese Cotton Piece Goods product weight Supervision Test Center and China
The detection of Shanghai institute of microbiology of the academy of sciences also demonstrates that (it is on bacterium is thousands of that cotton towel is easily smelly in summer to result above
The result of ten thousand times of procreations).Bamboo fibre and gou-tree fibre are the preferable natural plant fibres of anti-microbial property, while use more can be mutual
It mends, reaches preferably sterilization, fungistatic effect.
Acrylic latex is the acrylic latex that acrylic latex KJR-01 is Xi'an Daoerda Chemical Co., Ltd.'s production,
Its excellent weatherability and resistance to ag(e)ing has remarkable copolymerized ability.
Trihydroxy methyl phosphorous oxide and diphenyl phosphoester and modifying agent dimethyl tin oxide, dibutyl tin dichloride are modified
There can be stable, excellent flame retardant property.The present invention is by the way that fire retardant and modifying agent are mixed in mass ratio in step
Even acquisition modified flame-retardant liquid, modified flame-retardant liquid is added in immediately in acrylic latex and stirs evenly acquisition glue application solution；Modifying agent
Higher activity is stably held in using fire retardant is made.Latex plays the role of modified flame-retardant liquid package, keeps modified flame-retardant
The active permeation of liquid is into the fiber hole of wallpaper base paper；With existing expensive fire-retardant latex and fire retardant chemistry fiber phase
Than fire retardant and modifying agent are cheap used in the present invention, and the fire retardant effects of B1 are can reach with the collocation of not fire retardant chemistry fiber
Fruit.Method using the present invention, by the cost of flame-retardant wallpaper base paper, can be reduced to existing flame-retardant wallpaper base paper cost 30~
40%, the prominent market competitiveness is obtained in price.
By adopting the above-described technical solution, the present invention has the advantage that：Its not only good flame retardation effect, and can growing
Time keeps the fire-retardant of anti-flammability, also has effects that good antibacterial, antibacterial.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, make below in conjunction with specific embodiment into one
Step ground detailed description.
Embodiment 1
A kind of wallpaper base paper includes the component of following parts by weight：20 parts of bamboo fibre, 15 parts of gou-tree fibre, carboxymethyl cellulose
2 parts of plain 10 parts of sodium, 12 parts of acrylic latex, 2 parts of dimethyl tin oxides of trihydroxy methyl phosphorous oxide and dibutyl tin dichloride.
Embodiment 2
A kind of wallpaper base paper includes the component of following parts by weight：35 parts of bamboo fibre, 75 parts of gou-tree fibre, carboxymethyl cellulose
Plain 25 parts of sodium, 18 parts of acrylic latex, 4 parts of trihydroxy methyl phosphorous oxide, 4 parts of dimethyl tin oxide.
Embodiment 3
A kind of wallpaper base paper includes the component of following parts by weight：28 parts of bamboo fibre, 45 parts of gou-tree fibre, carboxymethyl cellulose
Plain 18 parts of sodium, 15 parts of acrylic latex, 3 parts of diphenyl phosphoester, 3 parts of dibutyl tin dichloride.
Embodiment 4
A kind of wallpaper base paper includes the component of following parts by weight：23 parts of bamboo fibre, 30 parts of gou-tree fibre, carboxymethyl cellulose
2.2 parts of plain 12 parts of sodium, 14 parts of acrylic latex, 2.4 parts of diphenyl phosphoester, dimethyl tin oxide and dibutyl tin dichloride.
Embodiment 5
A kind of wallpaper base paper includes the component of following parts by weight：32 parts of bamboo fibre, 68 parts of gou-tree fibre, carboxymethyl cellulose
Plain 22 parts of sodium, 16 parts of acrylic latex, 3.2 parts of trihydroxy methyl phosphorous oxide, 3.8 parts of dimethyl tin oxide.
Embodiment 6
A kind of preparation method of wallpaper base paper, which is characterized in that
S1 adds in the water that weight is 85-108 times, is beaten, beaten with beater after mixing bamboo fibre and gou-tree fibre
The degree of beating is controlled in 60~62OSR；
S2 adds in sodium carboxymethylcellulose and is stirred evenly in mixed serum；
Mixing slurry is made base paper semi-finished product by S3 by copy paper, squeezing, drying, coiling process；
Fire retardant and modifying agent are mixed evenly and obtain modified flame-retardant liquid, modified flame-retardant liquid is stood by S4 in mass ratio
It adds in acrylic latex and stirs evenly acquisition glue application solution；
S5, base paper semi-finished product dipping and gluing liquid on sizing coating machine, dip time 8~22 minutes, dipping temperature 25~
48℃；
Then S6 dries glue by hot air circulating system at 250~280 DEG C to the glue application solution permeated in base paper semi-finished product
Change, batched through surface machinery calendering, 92~116g/m of paper grammes per square metre is made into2Wallpaper base paper.
Performance test：
1st, the wallpaper base paper of embodiment 1-4 is attached on cement and wooden basal plane, while set control group respectively, in room temperature
Under, under conditions of relative humidity 50-70%, store 30 days, detect its fungistatic effect to bacterium, the following (following table of testing result
In bacteriostasis rate data take be testing result in cement and wooden basal plane average value):
By data above it is found that the wallpaper base paper of the present invention has good antibacterial, fungistatic effect.
2nd, clip 50*50mm patterns respectively in wallpaper base paper prepared from embodiment 1-4, to pattern into line label,
It is detected, is measured using YQ-Z-48A type whiteness and colure meters, every part of pattern, which measures 10 times, to be averaged.Anti-flammability
It can test:Setting is not burnt using open fire calcination pattern, 1 minute pattern of igniting, and open fire calcination pattern is dropped back from open fire paper for 3 minutes
Sample burning stopped being fire retardant in 5 seconds；Setting is not burnt or is smoldered using open fire calcination pattern, 30 seconds patterns of igniting, and open fire burns
Sample of burning paper as sacrificial offerings is dropped back from open fire for 1 minute, and pattern has open fire phenomenon, but is burnt and stopped being flammable in 30 seconds；Setting is burnt using open fire
It burns paper as sacrificial offerings sample, 30 seconds patterns of igniting do not burn, and open fire calcination pattern is dropped back from open fire for 1 minute, and pattern has open fire phenomenon and burning is not
It is inflammable to stop；Test result see the table below：
It can be seen that by upper table, the flame retardant effect of burning-resistent wallpaper base paper of the invention is excellent, and places for a long time not
Easily change colour, and can persistently keep excellent flame retardant property.
It should be understood that embodiment is only illustrative of the invention and is not intended to limit the scope of the invention.In addition, it should also be understood that, readding
After having read the content of the invention lectured, those skilled in the art can make the present invention any various changes and modification, these
Equivalent form equally falls within the application the appended claims and is limited.
Claims (10)
1. a kind of wallpaper base paper, which is characterized in that include the component of following parts by weight：20~35 parts of bamboo fibre, gou-tree fibre 15
~75 parts, 10~25 parts of sodium carboxymethylcellulose, 12~18 parts of acrylic latex, 2~4 parts of fire retardant, 2~4 parts of modifying agent.
2. wallpaper base paper according to claim 1, it is characterised in that acrylic latex is acrylic latex KJR-01.
3. wallpaper base paper according to claim 1, which is characterized in that fire retardant is trihydroxy methyl phosphorous oxide or diphenylphosphine
Acid esters.
4. wallpaper base paper according to claim 1, which is characterized in that modifying agent is dimethyl tin oxide or/and dibutyl
Stannous chloride.
5. the wallpaper base paper according to any claim in Claims 1-4, which is characterized in that including following parts by weight
Component：20 parts of bamboo fibre, 15 parts of gou-tree fibre, 10 parts of sodium carboxymethylcellulose, 12 parts of acrylic latex, 2 parts of fire retardant change
2 parts of agent of property.
6. the wallpaper base paper according to any claim in Claims 1-4, which is characterized in that including following parts by weight
Component：35 parts of bamboo fibre, 75 parts of gou-tree fibre, 25 parts of sodium carboxymethylcellulose, 18 parts of acrylic latex, 4 parts of fire retardant change
4 parts of agent of property.
7. the wallpaper base paper according to any claim in Claims 1-4, which is characterized in that including following parts by weight
Component：28 parts of bamboo fibre, 45 parts of gou-tree fibre, 18 parts of sodium carboxymethylcellulose, 15 parts of acrylic latex, 3 parts of fire retardant change
3 parts of agent of property.
8. the wallpaper base paper according to any claim in Claims 1-4, which is characterized in that including following parts by weight
Component：23 parts of bamboo fibre, 30 parts of gou-tree fibre, 12 parts of sodium carboxymethylcellulose, 14 parts of acrylic latex, 2.4 parts of fire retardant,
2.2 parts of modifying agent.
9. the wallpaper base paper according to any claim in Claims 1-4, which is characterized in that including following parts by weight
Component：32 parts of bamboo fibre, 68 parts of gou-tree fibre, 22 parts of sodium carboxymethylcellulose, 16 parts of acrylic latex, 3.2 parts of fire retardant,
3.8 parts of modifying agent.
10. the preparation method based on a kind of wallpaper base paper described in the claims, which is characterized in that
S1 adds in the water that weight is 85-108 times, is beaten with beater, beating degree after mixing bamboo fibre and gou-tree fibre
Control is in 60~62OSR；
S2 adds in sodium carboxymethylcellulose and is stirred evenly in mixed serum；
Mixing slurry is made base paper semi-finished product by S3 by copy paper, squeezing, drying, coiling process；
Fire retardant and modifying agent are mixed evenly and obtain modified flame-retardant liquid, modified flame-retardant liquid is added immediately by S4 in mass ratio
Enter to stir evenly acquisition glue application solution in acrylic latex；
S5, base paper semi-finished product dipping and gluing liquid, dip time 8~22 minutes, 25~48 DEG C of dipping temperature on sizing coating machine；
Then S6 dries gelatinization by hot air circulating system at 250~280 DEG C to the glue application solution permeated in base paper semi-finished product,
It is batched through surface machinery calendering, 92~116g/m of paper grammes per square metre is made into2Wallpaper base paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711488017.6A CN108221493A (en) | 2017-12-30 | 2017-12-30 | A kind of wallpaper base paper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711488017.6A CN108221493A (en) | 2017-12-30 | 2017-12-30 | A kind of wallpaper base paper and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108221493A true CN108221493A (en) | 2018-06-29 |
Family
ID=62647362
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711488017.6A Pending CN108221493A (en) | 2017-12-30 | 2017-12-30 | A kind of wallpaper base paper and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN108221493A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112176775A (en) * | 2020-09-07 | 2021-01-05 | 山东省东平县华东纸业有限责任公司 | Method for producing paper with high dimensional stability |
| CN115141285A (en) * | 2022-08-11 | 2022-10-04 | 湖北亿纬动力有限公司 | Modified carboxymethyl cellulose salt binder and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103614951A (en) * | 2013-12-09 | 2014-03-05 | 淄博欧木特种纸业有限公司 | Flame-retardant wallpaper base paper and preparation method thereof |
| CN104452471A (en) * | 2014-10-09 | 2015-03-25 | 浙江贝思德壁纸制造有限公司 | Antibacterial natural fiber wall paper and preparation method thereof |
| CN105040510A (en) * | 2015-07-24 | 2015-11-11 | 福建省优雅环保壁纸有限公司 | Flame-proof base wallpaper |
| CN105926370A (en) * | 2016-04-22 | 2016-09-07 | 安徽索亚装饰材料有限公司 | Lasting antibacterial flame-retardant wallpaper base paper and preparation method thereof |
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| CN103614951A (en) * | 2013-12-09 | 2014-03-05 | 淄博欧木特种纸业有限公司 | Flame-retardant wallpaper base paper and preparation method thereof |
| CN104452471A (en) * | 2014-10-09 | 2015-03-25 | 浙江贝思德壁纸制造有限公司 | Antibacterial natural fiber wall paper and preparation method thereof |
| CN105040510A (en) * | 2015-07-24 | 2015-11-11 | 福建省优雅环保壁纸有限公司 | Flame-proof base wallpaper |
| CN105926370A (en) * | 2016-04-22 | 2016-09-07 | 安徽索亚装饰材料有限公司 | Lasting antibacterial flame-retardant wallpaper base paper and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112176775A (en) * | 2020-09-07 | 2021-01-05 | 山东省东平县华东纸业有限责任公司 | Method for producing paper with high dimensional stability |
| CN115141285A (en) * | 2022-08-11 | 2022-10-04 | 湖北亿纬动力有限公司 | Modified carboxymethyl cellulose salt binder and preparation method and application thereof |
| CN115141285B (en) * | 2022-08-11 | 2023-09-01 | 湖北亿纬动力有限公司 | A kind of modified carboxymethyl cellulose salt binder and its preparation method and application |
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