CN108242501A - magnetostrictive device and preparation method thereof - Google Patents

magnetostrictive device and preparation method thereof Download PDF

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Publication number
CN108242501A
CN108242501A CN201611226594.3A CN201611226594A CN108242501A CN 108242501 A CN108242501 A CN 108242501A CN 201611226594 A CN201611226594 A CN 201611226594A CN 108242501 A CN108242501 A CN 108242501A
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Prior art keywords
belt carcass
magnetostriction
magnetostrictive device
magnetostrictive
prepared
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CN201611226594.3A
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CN108242501B (en
Inventor
罗阳
谢佳君
彭海军
于敦波
闫文龙
权宁涛
杨远飞
豆亚坤
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Grirem Advanced Materials Co Ltd
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Grirem Advanced Materials Co Ltd
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Priority to CN201611226594.3A priority Critical patent/CN108242501B/en
Priority to ZA2017/08492A priority patent/ZA201708492B/en
Priority to JP2017245685A priority patent/JP2018137427A/en
Publication of CN108242501A publication Critical patent/CN108242501A/en
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N35/00Magnetostrictive devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N35/00Magnetostrictive devices
    • H10N35/01Manufacture or treatment
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N35/00Magnetostrictive devices
    • H10N35/80Constructional details
    • H10N35/85Magnetostrictive active materials

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Soft Magnetic Materials (AREA)
  • General Electrical Machinery Utilizing Piezoelectricity, Electrostriction Or Magnetostriction (AREA)

Abstract

A kind of magnetostrictive device is disclosed, the device includes a magnetostriction belt carcass, which is characterized in that the magnetostriction belt carcass is in the form of a column structure, has helical loop with respect to section, the winding of belt carcass outer circle circumferential direction generates the induction coil in magnetic field;The magnetostriction belt carcass is by flat strip coil around into lamination coefficient N is 75%~85%.The eddy-current loss reduced under magnetostriction materials high frequency can be improved the actuating precision of magnetostriction materials, widens the application field of material by magnetostrictive device;Meanwhile also improve the utilization ratio of fast quenching magnetostriction materials.

Description

Magnetostrictive device and preparation method thereof
Technical field
The present invention relates to a kind of magnetostrictive devices and preparation method thereof, belong to magnetic material devices field.
Background technology
Fe-Ga alloys are a kind of novel magnetostriction materials, and compared to traditional Terfenol-D, the characteristics of it is maximum is With relatively low saturation magnetic field and higher mechanical strength, saturation field it is low be only 8-17kA/m, about the 1/10 of Terfenol-D, Magnetic field sensitivity is high.In some applications, the prestressed structure using complexity is not required to, device structure design is relatively easy.Fe-Ga Alloy is metal solid solution, and intensity is high, and brittleness is small, while has higher tensile strength (500MPa) and ductility, especially suitable For those with the strong mal-condition of strong motion, impact, big load, corrosion.In addition, the alloy also has very high magnetic conductivity, Curie temperature is high, has good temperature characterisitic, can be used within the scope of very wide temperature, therefore, in sensor and actuator side There is good application prospect in face.
The saturation magnetostriction constant of Fe-Ga alloys prepared by traditional directional solidification method only has 200-300ppm, this is remote 2000ppm less than Terfenol-D.In addition, since the conductivity of Fe-Ga alloys is higher, when the alloy block material is in high frequency Under the conditions of use when will appear big eddy-current loss.These are restricted its application range, so improving the magnetic of Fe-Ga alloys Telescopicing performance is caused, eddy-current loss when reducing its military service becomes one of key factor of its application.
In view of the above-mentioned problems, since FeGa alloys have preferable ductility, in practical applications, Fe-Ga can be closed The nanocrystalline strip of very thin thickness is made of the method for fast quenching or rolling for gold.Material can be greatly lowered in high frequency in this way Eddy-current loss, expand the use scope of material.
For example, Chinese patent application CN103320682 A propose to prepare Fe using melt-quenching method100-x-yGaxMyMaterial, Fast quenching thin strap is not obtained using copper crucible method.Chinese patent application CN103556045 A propose a FeGa and TbDyFe Pseudo-binary system material obtains the fast quenching with large magneto-strain, low driving field, strong mechanical performance using anisotropy compensation principle FeGa materials.Chinese patent application CN105177227 A are proposed for fast quenching FeGa materials.
However, in practical applications, how using thin ribbon shaped FeGa materials, the magnetostriction for making full use of its big is special Property, and Magnetostrictive Properties and accurate actuating stability under its high frequency are improved, it is still the larger skill that people face Art problem.
Invention content
In order to solve the above technical problems, inventor proposes a kind of novel magnetostriction bulk devices and its preparation side Method.The device has high-magnetostriction coefficient, low eddy-current loss.
To achieve the above object, on the one hand, the present invention intends taking following technical scheme:A kind of magnetostrictive device, it is described Device includes a magnetostriction belt carcass, which is characterized in that the magnetostriction belt carcass is in the form of a column structure, has spiral with respect to section Circuit, the winding of belt carcass outer circle circumferential direction generate the induction coil in magnetic field;The magnetostriction belt carcass by flat strip coil around and Into lamination coefficient N is 75%~85%.
In actual use, induction coil is powered, generates magnetic field, the magnetostriction belt carcass of coil inside is made in magnetic field With lower generation magnetostriction.
Traditional method is produced for laminated layer method, i.e., is stacked on magnetostriction thin slice prepared by quick quenching technique or rolling Together, it is low using these method stock utilizations.Importantly, when applying magnetic field, it is difficult to ensure that field homogeneity is distributed in material On material, therefore each lamination is caused to be stretched inconsistent, it is difficult to reach accurate actuation control by Magnetic field inhomogeneity.
In the present invention, since coil is annular, it is distributed in ring-shaped inner part field homogeneity, in the case, passes through winding method Magnetostriction belt carcass is prepared, can reach that Distribution of Magnetic Field is uniform, and each helical loop is stretched uniformly, more accurate so as to realize Control.
Therefore, magnetostriction belt carcass be using flat strip coil around into.In the present invention, prepared by preferred flat shape band Mode is quick quenching technique, and this method is quickly cooled down to obtain, pass through by the way that the alloy molten steel of melting is spread on the roller of rotation This method not only effectively can inhibit alloying component to be segregated, but also be conducive to the accurate control of magnetostriction band width and thickness System, so as to reach winding after belt carcass high consistency.
By magnetostriction belt carcass prepared by the quick quenching technique by winding, column structure is formed, there is spiral with respect to section Circuit.
According to aforementioned magnetostrictive device, wherein, the lamination coefficient N is the effective area coefficient of belt carcass, passes through survey The internal diameter D1 of amount belt carcass, outer diameter D 2, helical loop the piece number n, thickness d are calculated by following equation:
Lamination coefficient is higher, and the effective area of belt carcass is bigger.Advantageously, the lamination coefficient of the helical loop for 75~ 85%.Lamination coefficient is less than 75%, illustrates that helical loop is unevenly distributed in belt carcass, influences the effect of final accurate actuating, folds Piece coefficient is too high, on the one hand brings larger trouble to manufacture, on the other hand also influences performance under high frequency.
According to aforementioned magnetostrictive device, wherein, the magnetostriction belt carcass main component is Fe100-x-yGaxMy, M is It is one or more in Al, Ni, Co, Si, B, La, Y, Ce, wherein 5≤x≤25,0≤y≤10, are mass ratio.
Be mainly in view of using FeGa materials compared to traditional Terfenol-D, the characteristics of it is maximum be have it is relatively low full With magnetic field and higher mechanical strength, saturation field it is low be only 8-17kA/m, about the 1/10 of Terfenol-D, magnetic field sensitivity It is high.It is not required in some applications using complicated prestressed structure, device structure design is relatively easy, while Fe-Ga alloys are Metal solid solution, intensity is high, and brittleness is small, while has higher tensile strength (500MPa) and ductility, especially suitable for that A little mal-conditions strong with strong motion, impact, big load, corrosion.
According to aforementioned magnetostrictive device, wherein, the magnetostriction belt carcass main component is prepared into using quick quenching technique It arrives.The FeGa materials being prepared using quick quenching technique are conducive to play the advantage of its mechanical property, and strap thickness is prepared only Have the 1/10 of about rolled strip, so as to be more advantageous to playing performance under its high frequency.
In the FeGa ingredients of the present invention, 5≤x≤25,0≤y≤10 are mass ratio.It is advantageous in the composition range In obtaining single A2 phase alloys, the appearance of the ordered phases such as DO3, DO19, L12 is avoided.It is single-phase to be conducive to obtain more high-magnetostriction Performance.The addition of a certain amount of third element M can keep the basic structure property of Fe-Ga alloys, and can improve alloy The addition of Magnetostriction, Curie temperature, machinability etc., wherein Al, Ni can improve the machinability of material, carry The ductility of the high flat band of fast quenching improves strap flatness;The addition of Co can improve its temperature;Si's and B It adds in, the stability of fast quenching can be improved, reduce strap surface roughness, be conducive to the formation of single A2 structures;La, Y, Ce's Addition can improve its soft magnet performance, improve the magnetic temperature stability of material under high frequency.The content of M in the range of 0~10wt.%, Wherein y=0 is expressed as single FeGa materials, and M contents can cause the reduction of Magnetostriction apparent higher than 10wt.%.
According to aforementioned magnetostrictive device, wherein, the flat thickness of strip is 50~150 μm, and width is more than 10mm。
Advantageously, in magnetostriction belt carcass, flat thickness of strip is 50~150 μm, and width is more than 10mm.Thickness is herein In the range of be conducive to improve the high frequency performance of magnetostrictive device, but be planar as thickness of strip can cause to prepare less than 50 μm it is tired Difficulty, the poor flatness of flat band, lamination coefficient is low, and thickness is more than 150 μm of performances that can be unfavorable under high frequency.Generally Ground, in order to reach the using effect of device, strip width of the invention is more than 10mm, can be fitted according to specifically used size Degree is cut.
According to aforementioned magnetostrictive device, wherein, filled with insulation between the helical loop of the magnetostriction belt carcass Binding agent.
The presence of insulating adhesive further reduces the eddy-current loss under magnetostrictive device high frequency, reduces the hair of device Heat improves device application stability and precision.
According to aforementioned magnetostrictive device, wherein, the insulating adhesive is selected from epoxy resin.
According to aforementioned magnetostrictive device, wherein, in order to further improve the actuating precision of magnetostrictive device, need Distribution of Magnetic Field is uniform in device, advantageously, soft magnetic materials is further increased in belt carcass core, to reach the mesh to form magnetic loop 's.
According to aforementioned magnetostrictive device, wherein, the soft magnetic materials include FeNi powder cores, FeSiAl powder cores, FeNiMo powder cores, ferrocart core, ferrite powder core.
On the other hand, the present invention also provides a kind of method for preparing the aforementioned magnetostrictive device of the present invention, including as follows Step:
(1) prepared by flat band:The alloy molten solution of melting is ejected on the roller of rotation by sensing spray to cast method, soon Flat band is but prepared in quickly cooling;
(2) it winds:It squeezes and winds the flat band, form tape wrapping body, that is, belt carcass, the belt carcass is spiral Circuit;
(3) prepared by coil:Induction coil is externally wrapped in belt carcass, obtains magnetostrictive device.
According to aforementioned method, wherein, after step (2), including an impregnation process;The process immerses tape wrapping body Into melting insulating adhesive, make filling adhesive between helical loop.
According to aforementioned method, wherein, after step (2), including a heat treatment procedure;The process is by the band after extruding Coiling body is heat-treated in the range of 50~300 DEG C.
Compared with prior art, the present invention has following advantage:
On the one hand the eddy-current loss reduced under magnetostriction materials high frequency can be improved magnetic by the magnetostrictive device of the present invention The actuating precision of telescopic material is caused, widens the application field of material;On the other hand, the profit of fast quenching magnetostriction materials is also improved Use efficiency.
Description of the drawings
Fig. 1 is magnetostriction belt carcass schematic diagram of the present invention.
Specific embodiment
The invention will be further elucidated with reference to specific embodiments.It should be understood that these embodiments are merely to illustrate this hair It is bright rather than limit the scope of the invention.In addition, it should also be understood that, after present disclosure has been read, those skilled in the art The present invention can be made various changes or modifications, such equivalent forms equally fall within what the application the appended claims were limited Range.
It will be helpful to understand the present invention, but cannot limit the scope of the invention by following embodiments.
Embodiment
Magnetostrictive device of the present invention, mainly obtains in the following ways:
(1) prepared by flat band
Be ejected on the roller of rotation by sensing spray to cast method by the alloy molten solution of melting be quickly cooled down be prepared it is flat Shape band.
In the preparation process, band ingredient, thickness d (unit is μm), width W (unit mm) are as shown in table 1.
Wherein material composition is measured using ICP, and thickness is measured with width using micrometer caliper.
(2) it winds
It squeezes and winds the flat band, form tape wrapping body, the tape wrapping body is helical loop.
After winding, the lamination coefficient of magnetostriction belt carcass is can measure, in of the invention, by measuring the internal diameter D1 of belt carcass, Outer diameter D 2, helical loop the piece number n, can calculate lamination coefficient N is:
(3) prepared by coil
Induction coil is externally wrapped in belt carcass, obtains magnetostrictive device.
Coil is copper enameled wire, and the number of turn, copper wire diameter are advisable with the 70~95% of belt carcass width.
In order to further improve application characteristic under the high frequency of magnetostriction materials, increase following impregnation and heat treatment procedure.
Impregnation:Tape wrapping body is immersed in melting insulating adhesive, makes filling adhesive between helical loop.
Heat treatment:Coiling body after extruding is heat-treated in the range of 50~300 DEG C.
The loss P (unit W/kg) and magnetostriction coefficient λ of resulting devices are also seen in table 1.
1 magnetostrictive device ingredient of table and performance
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, that is made any repaiies Change, equivalent replacement, improvement etc., be all contained within protection scope of the present invention.

Claims (10)

1. a kind of magnetostrictive device, the device includes a magnetostriction belt carcass, which is characterized in that the magnetostriction belt carcass Structure is in the form of a column, there is helical loop with respect to section, the winding of belt carcass outer circle circumferential direction generates the induction coil in magnetic field;The mangneto Flexible belt carcass is by flat strip coil around into lamination coefficient N is 75%~85%;
The lamination coefficient N is the effective area coefficient of belt carcass, by measuring the internal diameter D1 of belt carcass, outer diameter D 2, helical loop piece Number n, thickness d are calculated by following equation:
2. magnetostrictive device according to claim 1, which is characterized in that the magnetostriction belt carcass main component is Fe100-x-yGaxMy, it is one or more in M Al, Ni, Co, Si, B, La, Y, Ce, wherein 5≤x≤25,0≤y≤10 are Mass ratio.
3. magnetostrictive device according to claim 1, which is characterized in that the flat thickness of strip is 50~150 μ M, width are more than 10mm.
4. magnetostrictive device according to claim 1, which is characterized in that the magnetostriction belt carcass main component uses Quick quenching technique is prepared.
5. magnetostrictive device according to claim 1, which is characterized in that the helical loop of the magnetostriction belt carcass it Between be filled with insulating adhesive.
6. magnetostrictive device according to claim 5, which is characterized in that the insulating adhesive includes epoxy resin.
7. magnetostrictive device according to claim 1, which is characterized in that the magnetostriction belt carcass core further increases Add soft magnetic materials.
A kind of 8. method for preparing any one of the claim 1-7 magnetostrictive devices, which is characterized in that including walking as follows Suddenly:
(1) prepared by flat band:The alloy molten solution of melting is ejected on the roller of rotation by sensing spray to cast method, fast quickly cooling But flat band is prepared;
(2) it winds:It squeezes and winds the flat band, form tape wrapping body, that is, belt carcass, the belt carcass is helical loop;
(3) prepared by coil:Induction coil is externally wrapped in belt carcass, obtains magnetostrictive device.
9. according to the method described in claim 8, it is characterized in that, after step (2), including an impregnation process;The process Tape wrapping body is immersed in melting insulating adhesive, makes filling adhesive between helical loop.
10. according to the method described in claim 8, it is characterized in that, after step (2), including a heat treatment procedure;The work Tape wrapping body after extruding is heat-treated by sequence in the range of 50~300 DEG C.
CN201611226594.3A 2016-12-27 2016-12-27 Magnetostrictive device and preparation method thereof Active CN108242501B (en)

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CN201611226594.3A CN108242501B (en) 2016-12-27 2016-12-27 Magnetostrictive device and preparation method thereof
ZA2017/08492A ZA201708492B (en) 2016-12-27 2017-12-14 A magnetostrictive device and the preparation method thereof
JP2017245685A JP2018137427A (en) 2016-12-27 2017-12-22 Magnetostriction device and manufacturing method therefor

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CN108242501B (en) * 2016-12-27 2022-02-22 有研稀土新材料股份有限公司 Magnetostrictive device and preparation method thereof
CN115415514A (en) * 2022-08-26 2022-12-02 清华大学 Magnetostrictive composite material and preparation method thereof

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CN110513658A (en) * 2019-05-14 2019-11-29 一码一路(海南)人工智能有限公司 Environmental protection and energy saving coloured silk leaf street lamp setting method

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CN110513658A (en) * 2019-05-14 2019-11-29 一码一路(海南)人工智能有限公司 Environmental protection and energy saving coloured silk leaf street lamp setting method

Cited By (3)

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Publication number Priority date Publication date Assignee Title
CN108242501B (en) * 2016-12-27 2022-02-22 有研稀土新材料股份有限公司 Magnetostrictive device and preparation method thereof
CN115415514A (en) * 2022-08-26 2022-12-02 清华大学 Magnetostrictive composite material and preparation method thereof
CN115415514B (en) * 2022-08-26 2024-04-09 清华大学 A magnetostrictive composite material and preparation method thereof

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ZA201708492B (en) 2020-06-24
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