CN108559677A - 一种浓缩型洗洁精及其制作方法 - Google Patents
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- 239000003599 detergent Substances 0.000 title claims abstract description 38
- 239000007788 liquid Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims description 12
- 239000000344 soap Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000010813 municipal solid waste Substances 0.000 claims abstract description 17
- 229920002396 Polyurea Polymers 0.000 claims abstract description 15
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 239000004034 viscosity adjusting agent Substances 0.000 claims abstract description 13
- 239000003974 emollient agent Substances 0.000 claims abstract description 10
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 10
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 9
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 8
- 238000000605 extraction Methods 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 239000002585 base Substances 0.000 claims description 17
- 238000003756 stirring Methods 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 239000004519 grease Substances 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 9
- 239000003921 oil Substances 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- -1 dodecyl dimethyl sulfopropyl Chemical group 0.000 claims description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 4
- 239000008157 edible vegetable oil Substances 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 241000628997 Flos Species 0.000 claims description 3
- 240000001972 Gardenia jasminoides Species 0.000 claims description 3
- 244000242564 Osmanthus fragrans Species 0.000 claims description 3
- 235000019083 Osmanthus fragrans Nutrition 0.000 claims description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 230000003292 diminished effect Effects 0.000 claims description 3
- 239000000686 essence Substances 0.000 claims description 3
- 235000019441 ethanol Nutrition 0.000 claims description 3
- 229930182470 glycoside Natural products 0.000 claims description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 3
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 claims description 3
- 230000010355 oscillation Effects 0.000 claims description 3
- 229940045998 sodium isethionate Drugs 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- JYTNGEWJAZCVAN-UHFFFAOYSA-N 2-hexadecylbenzenesulfonic acid;sodium Chemical compound [Na].CCCCCCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O JYTNGEWJAZCVAN-UHFFFAOYSA-N 0.000 claims description 2
- 229960003237 betaine Drugs 0.000 claims description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 2
- 150000002462 imidazolines Chemical class 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- LADXKQRVAFSPTR-UHFFFAOYSA-M sodium;2-hydroxyethanesulfonate Chemical compound [Na+].OCCS([O-])(=O)=O LADXKQRVAFSPTR-UHFFFAOYSA-M 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 9
- 238000005406 washing Methods 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 3
- 238000010411 cooking Methods 0.000 abstract 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- FXALIOUHXMVTMJ-UHFFFAOYSA-N CCCCCCCCCCCC([Na])=O Chemical group CCCCCCCCCCCC([Na])=O FXALIOUHXMVTMJ-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000021393 food security Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 210000003041 ligament Anatomy 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/047—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on cationic surface-active compounds and soap
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C11D1/29—Sulfates of polyoxyalkylene ethers
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Abstract
本发明提供一种浓缩型洗洁精，原料以质量百分数计包含以下组分：皂基15‑20％、阴离子表面活性剂35‑45％、两性表面活性剂7‑15％、非离子表面活性剂8‑13％、香精0.2％、粘度调节剂0.1‑0.3％、润肤剂0.5‑2％以及余量水；所述皂基采用餐厨垃圾提取制得；所述粘度调节剂为改性后的聚脲化合物。采用本发明的浓缩型洗洁精，皂基由厨余垃圾制得，粘度调节剂的用量小，成本低；将厨余垃圾合理利用，环境友好；整体配方成本低，洗涤效果好。本发明还公开一种上述浓缩型洗洁精的制作方法，步骤精简，工艺容易控制，适于工业化生产。
Description
技术领域
本发明涉及日用化学技术领域，特别地，涉及一种浓缩型洗洁精及其制作方法。
背景技术
餐厨废弃物里面含有大量的食用油脂，统计显示，我国餐厨垃圾占城市生活垃圾的比重大致范围为37％-62％，中国主要城市每年产生餐厨垃圾不低于6000吨，这类垃圾不仅成为一种环境污染物，更冲击着食品安全。
洗洁精用来精洗餐具、水果、蔬菜等，其产品的性能直接影响到人类的健康。普通洗洁精在生产过程中加入大量的水以保障在使用过程中洗洁精有较低的粘度以方便使用，导致洗洁精本身的有效成份不高；此外，长期使用洗洁精会导致皮肤粗糙，甚至开裂；含有家有洗涤剂的污水不经处理就排放到水体中，极易造成水体环境污染。
现有技术中有很多种类洗洁精，但此些洗洁精均不能兼顾成本和洗涤效果。因此，开发一种成本低、洗涤效果好的洗洁精具有重要意义。
发明内容
本发明的第一目的在于提供一种成本低、洗涤效果好的洗洁精，具体技术方案如下：
一种浓缩型洗洁精，原料以质量百分数计包含以下组分：皂基15-20％、阴离子表面活性剂35-45％、两性表面活性剂7-15％、非离子表面活性剂8-13％、香精0.2％、粘度调节剂0.1-0.3％、润肤剂0.5-2％以及余量水；
所述皂基采用餐厨垃圾提取制得；
所述粘度调节剂为改性后的聚脲化合物，所述聚脲化合物的相对分子质量不小于4100，固含量大于等于50％，NH含量大于等于3％。
以上技术方案中优选的，所述皂基的制作方法包括以下步骤：
步骤A、将油脂、碱、无水乙醇和水按比例混合得到混合物，以重量分数计油脂、碱、无水乙醇和水的配比是200：110：250：440；所述碱为氢氧化钠和氢氧化钾中的至少一种；
步骤B、将混合物搅拌并加热30min，加热温度为85℃，搅拌速度为300r/min；
步骤C、冷却后得到皂基。
以上技术方案中优选的，所述步骤A中的油脂的制备方法是：取一定量的餐厨垃圾，将其通过机械搅拌打浆后超声振荡5min，静置6h后取上层食用油脂放入烧瓶中，加入一定量的活性炭，搅拌加热至80℃保持30min，趁热用纱布减压过滤，过滤后得到油脂；所述餐厨垃圾和活性炭的质量配比为50：1。
以上技术方案中优选的，所述阴离子表面活性剂为月桂酰羟乙基磺酸钠、十六烷基苯磺酸钠以及十二烷基醇聚氧乙烯醚硫酸钠中的至少一种；所述两性表面活性剂为棷油基咪唑啉、棷油酰胺丙基二甲基甜菜碱以及十二烷基二甲基磺丙基甜菜碱中的至少一种；所述非离子表面活性剂为：烷基糖苷、棷油脂肪酸二乙醇酰胺以及棷油脂肪酸单乙醇胺中的至少一种；所述香精为金银花提取液、栀子花提取液以及桂花提取液中的至少一种；所述润肤剂为甘油。
以上技术方案中优选的，所述改性后的聚脲化合物的制备方法是：在搅拌下依次加入羟基丙烯酸树脂、溶剂、六亚甲基-1,6-二异氰酸酯，用水浴冷却至10℃以下，搅拌反应3小时即得改性后的聚脲化合物，其中：搅拌速率为100-300r/min。
应用本发明的洗洁精，效果是：本发明所采用的皂基是使用餐厨垃圾提取制备而得，资源回收利用的；本发明采用的一种改性的聚脲化合物作为粘度调节剂，用量少，效果明显，粘度调节剂的加入能显著降低洗洁精浓缩液的粘度(改性聚脲化合物在体系中与洗洁精主要成分形成氢健作用，在剪切力的作用下有很好的触变性：如果剪切力消失，氢键很快形成，黏度韧带增大，因此，在相对静止的情况下，可以增强体系的黏度，即量少的情况下就可以起到调节体系粘度的作用)，提高单位体积洗洁精的有效成份含量，降低洗洁精原液中水的含量；本发明采用的是物美价廉且环境友好的原材料甘油，成本低，保温润肤效果好；本发明作为一个完整的技术方案，具有成本低、环境友好且洗涤效果好的特征。
本发明还公开了一种上述浓缩型洗洁精的制备方法，将皂基、阴离子表面活性剂、两性表面活性剂、非离子表面活性剂、香精、粘度调节剂、润肤剂以及余量水按比例混合；搅拌加热至75-80℃；冷却后得到浓缩型洗洁精，其中搅拌速率为100-300r/min，加热升温速率为2-5℃/min。本发明制备方法步骤精简，工艺容易控制，适于工业化生产。
除了上面所描述的目的、特征和优点之外，本发明还有其它的目的、特征和优点。下面将参照实施例，对本发明作进一步详细的说明。
具体实施方式
以下结合实施例对本发明的技术方案进行详细说明，但是本发明可以根据权利要求限定和覆盖的多种不同方式实施。
实施例1：
一种浓缩型洗洁精，原料以质量百分数计包含以下组分(总量1000g)：皂基150g、阴离子表面活性剂400g、两性表面活性剂100g、非离子表面活性剂100g、香精2g、粘度调节剂2g、润肤剂20g以及水226g。
所述阴离子表面活性剂为月桂酰羟乙基磺酸钠、十六烷基苯磺酸钠以及十二烷基醇聚氧乙烯醚硫酸钠中的至少一种；所述两性表面活性剂为棷油基咪唑啉、棷油酰胺丙基二甲基甜菜碱以及十二烷基二甲基磺丙基甜菜碱中的至少一种；所述非离子表面活性剂为：烷基糖苷、棷油脂肪酸二乙醇酰胺以及棷油脂肪酸单乙醇胺中的至少一种；所述香精为金银花提取液、栀子花提取液以及桂花提取液中的至少一种；所述润肤剂为甘油。
所述皂基采用餐厨垃圾提取制得，具体包括以下步骤：步骤A、将油脂、碱、无水乙醇和水按比例混合得到混合物，以重量分数计油脂、碱、无水乙醇和水的配比是200：110：250：440；所述碱为氢氧化钠；步骤B、将混合物搅拌并加热30min，加热温度为85℃，搅拌速度为300r/min；步骤C、冷却后得到皂基。
上述步骤A中的油脂的制备方法是：取一定量的餐厨垃圾，将其通过机械搅拌打浆后超声振荡5min，静置6h后取上层食用油脂放入烧瓶中，加入一定量的活性炭，搅拌加热至80℃保持30min，趁热用纱布减压过滤，过滤后得到油脂；所述餐厨垃圾和活性炭的质量配比为50：1。
所述粘度调节剂为改性后的聚脲化合物，所述聚脲化合物的相对分子质量不小于4100，固含量大于等于50％，NH含量大于等于3％；所述改性后的聚脲化合物的制备方法是：在搅拌下依次加入羟基丙烯酸树脂、溶剂(卞氨)和六亚甲基-1,6-二异氰酸酯，用水浴冷却至10℃以下，搅拌反应3小时即得改性后的聚脲化合物，其中：搅拌速率为100-300r/min。
本实施例所述浓缩型洗洁精的制作方法，具体是：将皂基、阴离子表面活性剂、两性表面活性剂、非离子表面活性剂、香精、粘度调节剂、润肤剂以及余量水按比例混合；搅拌加热至75-80℃；冷却后得到浓缩型洗洁精，其中搅拌速率为100-300r/min，加热升温速率为2-5℃/min。
通过上述制备方法得到的洗洁精，有怡人的香味，无悬浮物或沉淀。
经检测，活性物含量为60％，去污能力强；在25℃条件下，0.1％浓度的洗洁精pH值为8.5，洗精精的性能温和，不刺激皮肤，并有保护手部皮肤的作用；洗洁精稳定性好，在5℃冰箱中放置24h，取出恢复到室温时观察，不分层，无沉淀，产品透明清澈。进一步检测，每1g洗洁精中的甲醇、甲醛的含量均小于1mg，重金属含量、菌落总数均符合洗手液标准要求。
以上所述仅为本发明的优选实施例而已，并不用于限制本发明，对于本领域的技术人员来说，本发明可以有各种更改和变化。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (6)
1.一种浓缩型洗洁精，其特征在于：原料以质量百分数计包含以下组分：皂基15-20％、阴离子表面活性剂35-45％、两性表面活性剂7-15％、非离子表面活性剂8-13％、香精0.2％、粘度调节剂0.1-0.3％、润肤剂0.5-2％以及余量水；
所述皂基采用餐厨垃圾提取制得；
所述粘度调节剂为改性后的聚脲化合物，所述聚脲化合物的相对分子质量不小于4100，固含量大于等于50％，NH含量大于等于3％。
2.根据权利要求1所述的浓缩型洗洁精，其特征在于：所述皂基的制作方法包括以下步骤：
步骤A、将油脂、碱、无水乙醇和水按比例混合得到混合物，以重量分数计油脂、碱、无水乙醇和水的配比是200：110：250：440；所述碱为氢氧化钠和氢氧化钾中的至少一种；
步骤B、将混合物搅拌并加热30min，加热温度为85℃，搅拌速度为300r/min；
步骤C、冷却后得到皂基。
3.根据权利要求2所述的浓缩型洗洁精，其特征在于：所述步骤A中的油脂的制备方法是：取一定量的餐厨垃圾，将其通过机械搅拌打浆后超声振荡5min，静置6h后取上层食用油脂放入烧瓶中，加入一定量的活性炭，搅拌加热至80℃保持30min，趁热用纱布减压过滤，过滤后得到油脂；所述餐厨垃圾和活性炭的质量配比为50：1。
4.根据权利要求1所述的浓缩型洗洁精，其特征在于：所述阴离子表面活性剂为月桂酰羟乙基磺酸钠、十六烷基苯磺酸钠以及十二烷基醇聚氧乙烯醚硫酸钠中的至少一种；所述两性表面活性剂为棷油基咪唑啉、棷油酰胺丙基二甲基甜菜碱以及十二烷基二甲基磺丙基甜菜碱中的至少一种；所述非离子表面活性剂为：烷基糖苷、棷油脂肪酸二乙醇酰胺以及棷油脂肪酸单乙醇胺中的至少一种；所述香精为金银花提取液、栀子花提取液以及桂花提取液中的至少一种；所述润肤剂为甘油。
5.根据权利要求1-4任意一项所述的浓缩型洗洁精，其特征在于：所述改性后的聚脲化合物的制备方法是：在搅拌下依次加入羟基丙烯酸树脂、溶剂、六亚甲基-1,6-二异氰酸酯，用水浴冷却至10℃以下，搅拌反应3小时即得改性后的聚脲化合物，其中：搅拌速率为100-300r/min。
6.一种如权利要求1-5任意一项所述的浓缩型洗洁精的制作方法，其特征在于：将皂基、阴离子表面活性剂、两性表面活性剂、非离子表面活性剂、香精、粘度调节剂、润肤剂以及余量水按比例混合；搅拌加热至75-80℃；冷却后得到浓缩型洗洁精，其中搅拌速率为100-300r/min，加热升温速率为2-5℃/min。
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