CN108564153A - Security code label and anti-counterfeiting system - Google Patents
Security code label and anti-counterfeiting system Download PDFInfo
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- CN108564153A CN108564153A CN201810386111.9A CN201810386111A CN108564153A CN 108564153 A CN108564153 A CN 108564153A CN 201810386111 A CN201810386111 A CN 201810386111A CN 108564153 A CN108564153 A CN 108564153A
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- G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
- G06K19/00—Record carriers for use with machines and with at least a part designed to carry digital markings
- G06K19/06—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code
- G06K19/06009—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code with optically detectable marking
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Abstract
本发明涉及一种防伪码标签和防伪系统,该防伪码标签包括:基层和印刷在所述基层上的防伪码;所述防伪码包括标准码和干扰码,所述标准码和所述干扰码在可见光下呈现为一体,并且所述干扰码在激发光源照射下产生可见荧光。本发明的防伪码标签方便识别真伪,成本低廉。
This invention relates to an anti-counterfeiting code label and anti-counterfeiting system. The anti-counterfeiting code label includes: a base layer and an anti-counterfeiting code printed on the base layer; the anti-counterfeiting code includes a standard code and an interference code, wherein the standard code and the interference code appear as a single entity under visible light, and the interference code produces visible fluorescence under illumination by an excitation light source. The anti-counterfeiting code label of this invention facilitates the identification of authenticity and is inexpensive.
Description
技术领域technical field
本发明涉及防伪技术领域,具体而言,涉及一种防伪码标签和防伪系统。The invention relates to the technical field of anti-counterfeiting, in particular to an anti-counterfeiting code label and an anti-counterfeiting system.
背景技术Background technique
现有的二维码、条形码等越来越多地进入到人们的生活,在很多的产品上都会提供二维码或条形码来提供相应的产品信息,由此,人们可以通过扫描二维码或条形码来获取产品信息,甚至可以由此确定产品的真伪。Existing two-dimensional codes and barcodes have increasingly entered people's lives. Many products will provide two-dimensional codes or barcodes to provide corresponding product information. Therefore, people can scan the two-dimensional code or Barcodes are used to obtain product information, and even to determine the authenticity of the product.
例如一些热门游戏的卡牌,这些卡牌具有较高的价值,可以通过游戏获得,或者在游戏商店进行购买,当然,也可以由游戏商店回购这些游戏卡。通常是在这些卡牌上印制二维码来确认卡牌的相关信息,然而,由于卡牌价值较高,可能会出现不法分子仿冒的情形,而现有的二维码也很容易被仿制。For example, the cards of some popular games have high value and can be obtained through games or purchased in game stores. Of course, these game cards can also be repurchased by game stores. Usually, two-dimensional codes are printed on these cards to confirm the relevant information of the cards. However, due to the high value of the cards, counterfeiting by criminals may occur, and the existing two-dimensional codes are also easy to be imitated .
因此,在这类应用中,急需一种简单、有效、成本低廉的防伪方法来防止不法分子的仿制。Therefore, in this type of application, there is an urgent need for a simple, effective and low-cost anti-counterfeiting method to prevent imitation by criminals.
发明内容Contents of the invention
鉴于上述问题,本发明提供了一种新的防伪码标签和防伪系统。In view of the above problems, the present invention provides a new anti-counterfeiting code label and anti-counterfeiting system.
本发明的一个实施方式提供一种防伪码标签,包括:基层和印刷在所述基层上的防伪码;One embodiment of the present invention provides an anti-counterfeit code label, comprising: a base layer and an anti-counterfeit code printed on the base layer;
所述防伪码包括标准码和干扰码,所述标准码和所述干扰码在可见光下呈现为一体,并且所述干扰码在激发光源照射下产生可见荧光。The anti-counterfeiting code includes a standard code and an interference code, the standard code and the interference code appear as one under visible light, and the interference code produces visible fluorescence under the illumination of an exciting light source.
在上述的防伪码标签中,所述干扰码包括黑色油墨层和无色油墨层,所述黑色油墨层和所述无色油墨层依次层叠在所述基层上,并且所述无色油墨层在激发光源照射下产生可见荧光。In the above-mentioned anti-counterfeiting code label, the interference code includes a black ink layer and a colorless ink layer, the black ink layer and the colorless ink layer are sequentially stacked on the base layer, and the colorless ink layer is Visible fluorescence is produced when illuminated by an excitation light source.
在上述的防伪码标签中,所述无色油墨层由隐形红外油墨和/或隐形紫外油墨形成。In the above anti-counterfeit code label, the colorless ink layer is formed by invisible infrared ink and/or invisible ultraviolet ink.
在上述的防伪码标签中,所述干扰码由包括红外激发荧光粉的黑色红外油墨和/或包括紫外激发荧光粉的黑色紫外油墨形成。In the above-mentioned anti-counterfeit code label, the interference code is formed by black infrared ink including infrared excitation phosphor powder and/or black ultraviolet ink including ultraviolet excitation phosphor powder.
在上述的防伪码标签中,所述红外激发荧光粉或所述紫外激发荧光粉的粒径为100-200nm。In the aforementioned anti-counterfeit code label, the particle diameter of the infrared-excited phosphor or the ultraviolet-excited phosphor is 100-200 nm.
在上述的防伪码标签中,所述红外激发荧光粉在所述黑色红外油墨中的重量百分比为10-40%。In the above anti-counterfeiting code label, the weight percentage of the infrared excitation fluorescent powder in the black infrared ink is 10-40%.
在上述的防伪码标签中,所述红外激发荧光粉的粒径为150-180nm;所述红外激发荧光在所述黑色红外油墨中的重量百分比为30-35%。In the above anti-counterfeit code label, the particle diameter of the infrared excitation fluorescent powder is 150-180nm; the weight percentage of the infrared excitation fluorescence in the black infrared ink is 30-35%.
在上述的防伪码标签中,所述黑色红外油墨包括用作成膜树脂的聚氨酯树脂。In the above anti-counterfeit code label, the black infrared ink includes polyurethane resin used as a film-forming resin.
在上述的防伪码标签中,所述聚氨酯树脂在所述黑色红外油墨中的重量百分比为5-20%。In the above anti-counterfeit code label, the weight percentage of the polyurethane resin in the black infrared ink is 5-20%.
在上述的防伪码标签中,所述防伪码标签为二维码标签或条形码标签。In the aforementioned anti-counterfeit code label, the anti-counterfeit code label is a two-dimensional code label or a barcode label.
本发明的另一个实施方式提供一种防伪系统,包括:防伪码标签和激发光照射装置;Another embodiment of the present invention provides an anti-counterfeiting system, including: an anti-counterfeiting code label and an excitation light irradiation device;
所述防伪码标签包括基层和印刷在所述基层上的防伪码;所述防伪码包括标准码和干扰码,所述标准码和所述干扰码在可见光下呈现为一体,并且所述干扰码在激发光源照射下产生可见荧光;The anti-counterfeiting code label includes a base layer and an anti-counterfeiting code printed on the base layer; the anti-counterfeiting code includes a standard code and an interference code, and the standard code and the interference code appear as one under visible light, and the interference code Visible fluorescence is produced under the excitation light source;
所述激发光照射装置包括红外线发射器和/或紫外线发射器。The excitation light irradiation device includes an infrared emitter and/or an ultraviolet emitter.
在上述的防伪系统中,所述激发光照射装置包括红外线发射器,并且所述防伪系统还包括可见光发射器,所述可见光发射器发射的光的颜色与所述可见荧光的颜色一致。In the above anti-counterfeiting system, the excitation light irradiation device includes an infrared emitter, and the anti-counterfeiting system further includes a visible light emitter, and the color of the light emitted by the visible light emitter is consistent with the color of the visible fluorescent light.
本发明的防伪码标签和防伪系统生产成本低廉,而且可以简单快捷地识别相应商品的真伪。The anti-counterfeiting code label and the anti-counterfeiting system of the present invention have low production cost, and can identify the authenticity of corresponding commodities simply and quickly.
附图说明Description of drawings
为了更清楚地说明本发明的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,应当理解,以下附图仅示出了本发明的某些实施例,因此不应被看作是对本发明保护范围的限定。在各个附图中,类似的构成部分采用类似的编号。In order to illustrate the technical solution of the present invention more clearly, the following drawings will be briefly introduced in the embodiments. It should be understood that the following drawings only show some embodiments of the present invention, and therefore should not be regarded as It is regarded as limiting the protection scope of the present invention. In the respective drawings, similar components are given similar reference numerals.
图1示出了一个正常二维码实例的示意图。Fig. 1 shows a schematic diagram of an example of a normal two-dimensional code.
图2示出了包括图1所示的正常二维码的防伪二维码实例的示意图。FIG. 2 shows a schematic diagram of an example of an anti-counterfeiting two-dimensional code including the normal two-dimensional code shown in FIG. 1 .
图3示出了图2所示防伪二维码中的干扰码的示意图。FIG. 3 shows a schematic diagram of an interference code in the anti-counterfeiting two-dimensional code shown in FIG. 2 .
图4示出了图2所示的防伪二维码在红外线照射下的示意图。FIG. 4 shows a schematic diagram of the anti-counterfeiting two-dimensional code shown in FIG. 2 under infrared irradiation.
具体实施方式Detailed ways
面将结合本发明实施例中附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。In the following, the technical solutions in the embodiments of the present invention will be clearly and completely described in conjunction with the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only some of the embodiments of the present invention, not all of them.
通常在此处附图中描述和示出的本发明实施例的组件可以以各种不同的配置来布置和设计。因此,以下对在附图中提供的本发明的实施例的详细描述并非旨在限制要求保护的本发明的范围,而是仅仅表示本发明的选定实施例。基于本发明的实施例,本领域技术人员在没有做出创造性劳动的前提下所获得的所有其他实施例,都属于本发明保护的范围。The components of the embodiments of the invention generally described and illustrated in the figures herein may be arranged and designed in a variety of different configurations. Accordingly, the following detailed description of the embodiments of the invention provided in the accompanying drawings is not intended to limit the scope of the claimed invention, but merely represents selected embodiments of the invention. Based on the embodiments of the present invention, all other embodiments obtained by those skilled in the art without making creative efforts belong to the protection scope of the present invention.
在下文中,可在本发明的各种实施例中使用的术语“包括”、“具有”及其同源词仅意在表示特定特征、数字、步骤、操作、元件、组件或前述项的组合,并且不应被理解为首先排除一个或更多个其它特征、数字、步骤、操作、元件、组件或前述项的组合的存在或增加一个或更多个特征、数字、步骤、操作、元件、组件或前述项的组合的可能性。Hereinafter, the terms "comprising", "having" and their cognates that may be used in various embodiments of the present invention are only intended to represent specific features, numbers, steps, operations, elements, components or combinations of the foregoing, And it should not be understood as first excluding the existence of one or more other features, numbers, steps, operations, elements, components or combinations of the foregoing or adding one or more features, numbers, steps, operations, elements, components or a combination of the foregoing possibilities.
在本发明的各种实施例中,表述“A或/和B”包括同时列出的文字的任何组合或所有组合,可包括A、可包括B或可包括A和B二者。In various embodiments of the present invention, the expression "A or/and B" includes any or all combinations of words listed at the same time, may include A, may include B, or may include both A and B.
在本发明的描述中,需要理解的是,术语“纵向”、“横向”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“横向”、“顶”、“底”、“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,术语“第一”、“第二”、“第三”等仅用于区分描述,而不能理解为指示或暗示相对重要性。In describing the present invention, it should be understood that the terms "longitudinal", "transverse", "upper", "lower", "front", "rear", "left", "right", "vertical", The orientation or positional relationship indicated by "horizontal", "top", "bottom", "inner", "outer", etc. is based on the orientation or positional relationship shown in the drawings, and is only for the convenience of describing the present invention and simplifying the description. It is not to indicate or imply that the device or element referred to must have a particular orientation, be constructed in a particular orientation, or operate in a particular orientation, and thus should not be construed as limiting the invention. In addition, the terms "first", "second", "third", etc. are only used for distinguishing descriptions, and should not be construed as indicating or implying relative importance.
在本说明书的描述中,参考术语“一个实施例”、“一些实施例”、“示例”、“具体示例”、或“一些示例”等的描述意指结合该实施例或示例描述的具体特征、结构、材料或者特点包含于本发明的至少一个实施例或示例中。在本说明书中,对上述术语的示意性表述不一定指的是相同的实施例或示例。而且,描述的具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。In the description of this specification, descriptions referring to the terms "one embodiment", "some embodiments", "example", "specific examples", or "some examples" mean that specific features described in connection with the embodiment or example , structure, material or characteristic is included in at least one embodiment or example of the present invention. In this specification, schematic representations of the above terms do not necessarily refer to the same embodiment or example. Furthermore, the specific features, structures, materials or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
在本发明的描述中,除非另有规定和限定,需要说明的是,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是机械连接,也可以是两个元件内部的连通,可以是直接相连,也可以通过中间媒介间接相连,对于本领域的普通技术人员而言,可以根据具体情况理解上述术语的具体含义。除非另有限定,否则在这里使用的所有术语(包括技术术语和科学术语)具有与本发明的各种实施例所属领域普通技术人员通常理解的含义相同的含义。所述术语(诸如在一般使用的词典中限定的术语)将被解释为具有与在相关技术领域中的语境含义相同的含义并且将不被解释为具有理想化的含义或过于正式的含义,除非在本发明的各种实施例中被清楚地限定。In the description of the present invention, unless otherwise stipulated and limited, it should be noted that the terms "installation", "connection" and "connection" should be understood in a broad sense, for example, it can be a mechanical connection or an internal connection between two components. The connection of the above-mentioned terms can be directly connected or indirectly connected through an intermediary, and those skilled in the art can understand the specific meanings of the above terms according to specific situations. Unless otherwise defined, all terms (including technical terms and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which various embodiments of the present invention belong. The terms (such as those defined in commonly used dictionaries) will be interpreted as having the same meaning as the contextual meaning in the relevant technical field and will not be interpreted as having an idealized meaning or an overly formal meaning, Unless clearly defined in various embodiments of the present invention.
本发明的一个实施方式提供一种防伪码标签,可包括基层和印刷在所述基层上的防伪码。One embodiment of the present invention provides an anti-counterfeit code label, which may include a base layer and an anti-counterfeit code printed on the base layer.
本发明中所指的防伪标签可以是直接在产品本身或者产品外包装上印刷防伪码所形成的标签,此时产品本身或产品外包装为上述的基层;也可以是在例如标签贴纸上形成防伪码,然后可以将独立的标签贴纸粘附至产品或产品包装上,此时,标签贴纸为上述的基层。The anti-counterfeiting label referred to in the present invention can be a label formed by printing an anti-counterfeiting code directly on the product itself or on the outer packaging of the product. At this time, the product itself or the outer packaging of the product is the above-mentioned base layer; it can also be formed on, for example, a label sticker code, and then an independent label sticker can be adhered to the product or product packaging. At this time, the label sticker is the above-mentioned base layer.
本发明的防伪码可以是例如二维码、条形码等各种包括文字和/或图像的标识码,较为常用的是二维码和条形码,下面主要以二维码为例进行说明,显然,这些说明也适用于条形码等标识码。The anti-counterfeiting code of the present invention can be various identification codes including characters and/or images such as two-dimensional codes and bar codes. Two-dimensional codes and bar codes are more commonly used. The following mainly uses two-dimensional codes as an example to illustrate. Obviously, these The description also applies to identifiers such as barcodes.
本发明的防伪码包括标准码和干扰码,所述标准码和所述干扰码在可见光下呈现为一体,并且所述干扰码在激发光源照射下产生可见荧光。The anti-counterfeiting code of the present invention includes a standard code and an interference code, the standard code and the interference code are integrated under visible light, and the interference code produces visible fluorescence under the illumination of an exciting light source.
参见图1至图4,图1示出了一个正常二维码的例子。该二维码在利用移动终端等扫码工具进行扫描时,可以正常获取二维码的相关信息。而本发明的防伪码包括标准码,例如可以是图1所示的正常的二维码,在读取后可以获得相关商品的具体信息,例如生产厂家、规格、型号等。Referring to Fig. 1 to Fig. 4, Fig. 1 shows an example of a normal two-dimensional code. When the two-dimensional code is scanned by a scanning tool such as a mobile terminal, relevant information of the two-dimensional code can be obtained normally. The anti-counterfeiting code of the present invention includes a standard code, such as a normal two-dimensional code as shown in FIG. 1 , after reading, specific information of related commodities, such as manufacturer, specification, model, etc., can be obtained.
此外,还包括干扰码,例如可以是图3所示的干扰点,与图1所示的标准码组合在一起就构成了本发明的防伪二维码,如图2所示。由于标准码和干扰码在可见光(例如太阳光、日光灯光、LED灯光)照射下均具有相同的颜色,图中所示为黑色,因此,肉眼或者二维码读码器不能区分出防伪码中哪些是正常的二维码,哪些是干扰点。因此,在可见光照射下,不能获取相关信息。In addition, it also includes an interference code, such as the interference point shown in FIG. 3 , which is combined with the standard code shown in FIG. 1 to form the anti-counterfeiting two-dimensional code of the present invention, as shown in FIG. 2 . Since the standard code and the interference code have the same color under the irradiation of visible light (such as sunlight, fluorescent light, LED light), the picture is shown in black, so the naked eye or two-dimensional code reader cannot distinguish the color of the anti-counterfeit code. Which are normal QR codes and which are interference points. Therefore, under visible light irradiation, relevant information cannot be obtained.
本发明的干扰码在激发光源的照射下会发出可见的荧光,如图4所示。由此,在二维码读码器上不仅能够从二维码内以及外围的空白区域获取反射光,而且能够从干扰码获取激发荧光,由此,诸如移动终端的二维码读码器可以正常读取二维码,获取相关信息。The interference code of the present invention emits visible fluorescence under the illumination of an exciting light source, as shown in FIG. 4 . Therefore, on the two-dimensional code reader, not only the reflected light can be obtained from the blank area inside and outside the two-dimensional code, but also the excited fluorescence can be obtained from the interference code, thus, the two-dimensional code reader such as a mobile terminal can Read the QR code normally to obtain relevant information.
干扰码可以包括黑色油墨层和无色油墨层,所述黑色油墨层和所述无色油墨层依次层叠在所述基层上,并且所述无色油墨层在激发光源照射下产生可见荧光。The interference code may include a black ink layer and a colorless ink layer, the black ink layer and the colorless ink layer are sequentially stacked on the base layer, and the colorless ink layer produces visible fluorescence under the illumination of an exciting light source.
黑色油墨层可以采用常规的用于印刷标准码的油墨,无色油墨层可以采用隐形红外油墨或隐形紫外油墨形成。The black ink layer can be formed by conventional ink used for printing standard codes, and the colorless ink layer can be formed by invisible infrared ink or invisible ultraviolet ink.
隐形紫外油墨可以是应用紫外(200-400nm)照射激发而发出可见光(400-800nm)的油墨。隐形紫外油墨在常态下是无色透明的,在紫外灯照射下可以显示红、黄、绿、蓝等颜色。例如可以采用冠创易佳科技有限公司的Y4-100紫外油墨,其外观为无色,用365nm荧光等照射时,显示绿色;Y4-101紫外油墨,其外观为无色,用365nm荧光灯照射时,可以显示红色。The invisible ultraviolet ink can be an ink that emits visible light (400-800nm) when excited by ultraviolet (200-400nm) irradiation. Invisible UV ink is colorless and transparent under normal conditions, and can display red, yellow, green, blue and other colors under the irradiation of ultraviolet light. For example, you can use Y4-100 ultraviolet ink from Guanchuang Yijia Technology Co., Ltd., its appearance is colorless, and it will show green when irradiated with 365nm fluorescent light; Y4-101 ultraviolet ink, its appearance is colorless, when irradiated with 365nm fluorescent lamp , can display red.
隐形红外激发油墨在正常状态下无色隐形,在激发光源照射下可以呈现红、绿、蓝、黄等不同的颜色。油墨中的染料需要对红外光有强吸收性,还要具有良好的色牢度、耐热性、耐化学品性。酞菁、萘酞菁、芳香胺、次甲基染料中都有适于配置隐形红外油墨的化合物,配制隐形红外油墨的溶剂可以采用乙烷、四氯乙烯、甲苯、氯苯、环己酮、乙醇或它们的混合物。还可以增加一些添加剂,例如,亚麻油和桐油,它们能改善油墨的流变性质(如粘度),并可控制油墨的干燥速度,还可以加入增塑剂、表面活性剂、催化剂和抗氧化剂等。Invisible infrared excitation ink is colorless and invisible under normal conditions, and can present different colors such as red, green, blue, yellow, etc. under the illumination of the excitation light source. The dyes in the ink need to have strong absorption of infrared light, and also have good color fastness, heat resistance, and chemical resistance. Phthalocyanine, naphthalene phthalocyanine, aromatic amines, and methine dyes all have compounds suitable for configuring invisible infrared inks. The solvents for preparing invisible infrared inks can be ethane, tetrachloroethylene, toluene, chlorobenzene, cyclohexanone, ethanol or their mixtures. Some additives can also be added, for example, linseed oil and tung oil, which can improve the rheological properties of the ink (such as viscosity), and can control the drying speed of the ink, and can also add plasticizers, surfactants, catalysts and antioxidants, etc. .
此外,例如可以采用冠创易佳科技有限公司的Y0-102红外油墨,其外观为无色,用980nm激光灯照射时,可以显示蓝色;Y0-101红外油墨,其外观为无色,用980nm激光灯照射时,可以显示红色。In addition, for example, you can use Y0-102 infrared ink from Guanchuang Yijia Technology Co., Ltd., which is colorless in appearance and can display blue when irradiated with a 980nm laser light; Y0-101 infrared ink, which is colorless in appearance When 980nm laser light is irradiated, it can display red.
如果读取防伪码时紫外线照射时间很短暂或者在封闭空间读取防伪码,也可以采用紫外线油墨。因为长期照射或强的紫外线对于人体有伤害,所以优选采用红外激发油墨。UV ink can also be used if the UV exposure time is very short when reading the security code or if the security code is read in a closed space. Because long-term exposure or strong ultraviolet rays are harmful to the human body, infrared excitation inks are preferably used.
在干扰码包括黑色油墨层和无色油墨层时,优选将标准码和干扰码的黑色油墨层采用同样的油墨进行印刷,然后,在干扰码位置采用上述的隐形红外油墨或紫外油墨形成。无色油墨层的厚度很薄,即使覆盖在黑色油墨层上,人们也察觉不出与其他区域存在厚度差。When the interference code includes a black ink layer and a colorless ink layer, it is preferable to print the black ink layer of the standard code and the interference code with the same ink, and then use the above-mentioned invisible infrared ink or ultraviolet ink at the position of the interference code to form. The thickness of the colorless ink layer is very thin, and even if it is covered on the black ink layer, people cannot perceive the thickness difference with other areas.
此外,在无色油墨层中可以采用多种隐形染料,使得印刷图像可以用多用方式进行检测。例如以金属酞菁红外荧光染料为第一隐形染料,这种染料在红外光照射下,可以发出荧光;以香豆素、喹诺酮或嵌二萘作为第二染料,此染料在紫外光照射下,也可以发出荧光。因此,包括此复合隐形油墨的防伪码既可以用红外光系统照射下检测,也可以在紫外光照射系统下进行检测来获取相关信息。In addition, a variety of invisible dyes can be employed in the colorless ink layer, allowing printed images to be detected in a versatile manner. For example, metal phthalocyanine infrared fluorescent dye is used as the first stealth dye, which can emit fluorescence under infrared light irradiation; coumarin, quinolone or pyrene is used as the second dye, and this dye, under ultraviolet light irradiation, Can also fluoresce. Therefore, the anti-counterfeit code including the composite invisible ink can be detected under the irradiation of the infrared light system, and can also be detected under the ultraviolet light irradiation system to obtain relevant information.
在上面的实例中,干扰码部分分为黑色油墨层和无色油墨层,然而,干扰码也可以由包括红外激发荧光粉的黑色红外油墨或包括紫外激发荧光粉的黑色紫外油墨形成。In the above example, the interference code part is divided into a black ink layer and a colorless ink layer, however, the interference code may also be formed of black infrared ink including infrared excitation phosphor or black ultraviolet ink including ultraviolet excitation phosphor.
红外激发荧光粉或所述紫外激发荧光粉的粒径可以为10-1000nm,例如可以为20nm、30nm、40nm、50nm、60nm、70nm、80nm、90nm、100nm、110nm、120nm、130nm、140nm、150nm、160nm、170nm、180nm、190nm、200nm、300nm、400nm、500nm、600nm、700nm、800nm或900nm,优选为100-200nm。The particle size of the infrared excitation phosphor or the ultraviolet excitation phosphor can be 10-1000nm, such as 20nm, 30nm, 40nm, 50nm, 60nm, 70nm, 80nm, 90nm, 100nm, 110nm, 120nm, 130nm, 140nm, 150nm , 160nm, 170nm, 180nm, 190nm, 200nm, 300nm, 400nm, 500nm, 600nm, 700nm, 800nm or 900nm, preferably 100-200nm.
油墨相中荧光粉的粒径减少,荧光油墨的发光效率提高。在粒径小于20nm时,细小的荧光粉容易重新聚集或絮凝,在粒径大于1000nm时,通常而言,相对荧光强度降低,不容易从干扰码处获取足够的荧光,由此导致不能读取二维码信息。The particle size of the fluorescent powder in the ink phase is reduced, and the luminous efficiency of the fluorescent ink is improved. When the particle size is less than 20nm, the fine fluorescent powder is easy to re-aggregate or flocculate. When the particle size is larger than 1000nm, generally speaking, the relative fluorescence intensity decreases, and it is difficult to obtain enough fluorescence from the interference code, resulting in failure to read QR code information.
干扰码优选由包括红外激发荧光粉的黑色红外油墨形成。The jamming code is preferably formed from black infrared ink including infrared excited phosphors.
红外激发荧光粉在黑色红外油墨中的重量百分比可以为10-40%,例如可以为15%、20%、25%、30%或35%。在一定范围内,随着荧光粉含量的增加,介质中颜料粒子的百分比增加,红外荧光油墨的相对荧光强度也逐渐增大。红外激发荧光粉在黑色红外油墨中的重量百分比为10-40%可以满足标准条码信息的读取。在荧光粉的含量超过40%时,荧光粉在油墨体系中的分散性欠佳,导致荧光分子浓度高时容易发生猝灭现象,致使相对荧光强度下降、荧光寿命降低。The weight percentage of the infrared excitation fluorescent powder in the black infrared ink can be 10-40%, for example, it can be 15%, 20%, 25%, 30% or 35%. Within a certain range, as the phosphor content increases, the percentage of pigment particles in the medium increases, and the relative fluorescence intensity of the infrared fluorescent ink also gradually increases. The percentage by weight of the infrared excitation fluorescent powder in the black infrared ink is 10-40%, which can satisfy the reading of standard barcode information. When the content of phosphor powder exceeds 40%, the dispersion of phosphor powder in the ink system is not good, which leads to the phenomenon of quenching when the concentration of fluorescent molecules is high, resulting in a decrease in relative fluorescence intensity and a decrease in fluorescence lifetime.
本发明中优选红外激发荧光粉的粒径为150-180nm;红外激发荧光在所述黑色红外油墨中的重量百分比为30-35%,在上述粒径为150-180nm和重量含量范围内,荧光粉具有良好的分散性而且相对荧光强度也较大。由此,不仅能够在红外激发时很容易获取二维码的相关信息,而且能够确保二维码具有较长的使用寿命。In the present invention, it is preferred that the particle diameter of the infrared excitation fluorescent powder is 150-180nm; the weight percentage of the infrared excitation fluorescence in the described black infrared ink is 30-35%. The powder has good dispersibility and relatively high fluorescence intensity. In this way, not only can the relevant information of the two-dimensional code be easily obtained during infrared excitation, but also the long service life of the two-dimensional code can be ensured.
作为黑色红外油墨的载体,成膜树脂的作用是将粉末状的固体颜料粒子连接起来,并使其最终附着在承印物上。As the carrier of black infrared ink, the function of film-forming resin is to connect the powdery solid pigment particles and make them finally adhere to the substrate.
优选采用聚聚氨酯树脂作为成膜树脂,这是因为聚氨酯树脂的分子结构中含有胺酯键,分子间存在很强的氢键作用力,在收到红外激发前易与基态下的荧光体形成氢键,使得摩尔吸光系数增大,即吸收增强,因此制得的红外荧光油墨的相对荧光强度较高。而在诸如丙烯酸树脂的分子结构中含有羧酸基团,其为荧光消色团,会抵消或抑制荧光的产生,因此制得的红外荧光油墨的相对荧光强度较低。Polyurethane resin is preferably used as the film-forming resin. This is because the molecular structure of polyurethane resin contains urethane bonds, and there is a strong hydrogen bond force between the molecules. It is easy to form hydrogen with the phosphor in the ground state before receiving infrared excitation. bond, so that the molar absorptivity coefficient increases, that is, the absorption is enhanced, so the relative fluorescence intensity of the prepared infrared fluorescent ink is higher. However, in molecular structures such as acrylic resins, there are carboxylic acid groups, which are fluorescent achromatic groups, which can offset or inhibit the generation of fluorescence, so the relative fluorescence intensity of the prepared infrared fluorescent ink is low.
不同成膜树脂含量对于红外荧光油墨的相对荧光强度也有很大影响,这是因为随着成膜树脂含量的增加,油墨体系粘度会增加,减小了激发态分子振动和转动的速率,从而降低了其与其他颜料粒子的碰撞率,提高了红外荧光油墨的相对荧光强度。The content of different film-forming resins also has a great influence on the relative fluorescence intensity of infrared fluorescent inks. This is because as the content of film-forming resins increases, the viscosity of the ink system will increase, reducing the vibration and rotation rates of excited state molecules, thereby reducing The collision rate with other pigment particles is improved, and the relative fluorescence intensity of infrared fluorescent ink is improved.
在红外荧光油墨中还含有黑色颜料粒子,聚氨酯树脂在黑色红外油墨中的重量百分比优选为5-20%,更优选为15-18%,此时的荧光强度最大。当成膜树脂含量超过20%时,随着其含量的增加,相对荧光强度呈现逐渐下降的区域,这是因为成膜树脂阻碍了荧光物质对光的吸收,从而削弱了相对荧光强度。The infrared fluorescent ink also contains black pigment particles, and the weight percentage of the polyurethane resin in the black infrared ink is preferably 5-20%, more preferably 15-18%, and the fluorescence intensity at this time is maximum. When the film-forming resin content exceeds 20%, as its content increases, the relative fluorescence intensity presents a region where the relative fluorescence intensity gradually decreases, because the film-forming resin hinders the absorption of light by the fluorescent substance, thereby weakening the relative fluorescence intensity.
在红外荧光油墨中的黑色油墨的重量百分比为30-55%,例如为35%、40%、45%或50%,还可以包括油墨快干剂、油墨稀释剂等,油墨快干剂的含量可以为1-2%,油墨稀释剂1-5%。The weight percent of the black ink in infrared fluorescent ink is 30-55%, for example is 35%, 40%, 45% or 50%, can also comprise ink quick-drying agent, ink thinner etc., the content of ink quick-drying agent Can be 1-2%, ink thinner 1-5%.
此外,在红外荧光油墨中还可以加入粒径为20-60nm的TiO2,例如30、40或50nm,在红外荧光油墨中的重量百分比可以为0.1-0.5%,可以大幅提高油墨的快干性,从而可以使红外荧光油墨与普通油墨同时对干扰码和标准码进行高速印刷。因此,干扰码采用黑色油墨层和无色油墨层相比,干扰码优选由包括红外激发荧光粉的黑色红外油墨形成,从而可以提高生产效率、降低成本。In addition, TiO 2 with a particle size of 20-60nm, such as 30, 40 or 50nm, can be added to the infrared fluorescent ink, and the weight percentage in the infrared fluorescent ink can be 0.1-0.5%, which can greatly improve the quick-drying property of the ink , so that the infrared fluorescent ink and ordinary ink can simultaneously print the interference code and the standard code at high speed. Therefore, compared with the black ink layer and the colorless ink layer used for the interference code, the interference code is preferably formed of black infrared ink including infrared-excited fluorescent powder, so that the production efficiency can be improved and the cost can be reduced.
本发明的另一实施方式提供一种防伪系统,其包括防伪码标签和激发光照射装置。Another embodiment of the present invention provides an anti-counterfeiting system, which includes an anti-counterfeiting code label and an excitation light irradiation device.
防伪码标签包括基层和印刷在所述基层上的防伪码;所述防伪码包括标准码和干扰码,所述标准码和所述干扰码在可见光下呈现为一体,并且所述干扰码在激发光源照射下产生可见荧光。上述的各种优选项适用于防伪系统中的防伪码标签。激发光照射装置可以是红外线和/或紫外线发射器。The anti-counterfeit code label includes a base layer and an anti-counterfeit code printed on the base layer; the anti-counterfeit code includes a standard code and an interference code, and the standard code and the interference code appear as one under visible light, and the interference code is activated Produces visible fluorescence under light irradiation. The various preferred items mentioned above are applicable to the anti-counterfeiting code label in the anti-counterfeiting system. The excitation light irradiation device may be an infrared and/or ultraviolet emitter.
由于很多地扫描装置中使用红外线发射器,因此,优选使用红外线发射器。Since infrared emitters are used in many scanning devices, the use of infrared emitters is preferred.
此外,所述防伪系统还优选包括可见光发射器,并且所述可见光发射器发射的光的颜色与所述可见荧光的颜色一致。由于干扰码在激光光源照射下产生的是有色可见荧光,因此,可能导致在照射识别防伪码时,干扰码和空白区域的反射光存在较为明显的区别。因此,为了提高防伪性,优选还包括可见光发射器,并且所述可见光发射器发射的光的颜色与所述可见荧光的颜色一致,在此情况下,由于干扰码发射的光的颜色与空白区域反射的颜色一致,不法人员很难发现标准码区域与干扰码区域的区别,增加了仿制的难度。In addition, the anti-counterfeiting system preferably further includes a visible light emitter, and the color of the light emitted by the visible light emitter is consistent with the color of the visible fluorescent light. Since the interference code produces colored and visible fluorescence under the irradiation of the laser light source, there may be obvious differences between the interference code and the reflected light of the blank area when the anti-counterfeiting code is irradiated to identify it. Therefore, in order to improve anti-counterfeiting, it is preferable to also include a visible light emitter, and the color of the light emitted by the visible light emitter is consistent with the color of the visible fluorescent light. The reflected colors are consistent, and it is difficult for criminals to find the difference between the standard code area and the interference code area, which increases the difficulty of imitation.
此外,可以设置专用的封闭扫码装置,即将红外线发射器或紫外线发射器和扫码装置设置在封闭空间中,将需要扫码的防伪标签放置到该封闭空间中,扫码时,操作人员或其他人员无法看到防伪标签上的反射光和激发光,进一步增强防伪性。In addition, a special closed code scanning device can be set up, that is, the infrared emitter or ultraviolet emitter and the code scanning device are set in a closed space, and the anti-counterfeiting label that needs to be scanned is placed in the closed space. When scanning the code, the operator or Other personnel cannot see the reflected light and excitation light on the anti-counterfeiting label, further enhancing the anti-counterfeiting performance.
本发明的防伪码标签和防伪系统生产成本低廉,而且可以简单快捷地识别相应商品的真伪,即使不法分子在拍摄相关防伪码后,印刷出相同图案的标签也不能冒充真实防伪标签。The anti-counterfeiting code label and the anti-counterfeiting system of the present invention have low production cost, and can easily and quickly identify the authenticity of corresponding commodities. Even if criminals print out labels with the same pattern after photographing relevant anti-counterfeiting codes, they cannot pretend to be real anti-counterfeiting labels.
以上所述,仅为本发明的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到变化或替换,都应涵盖在本发明的保护范围之内。The above is only a specific embodiment of the present invention, but the scope of protection of the present invention is not limited thereto. Anyone skilled in the art can easily think of changes or substitutions within the technical scope disclosed in the present invention. Should be covered within the protection scope of the present invention.
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