CN108564287A - A kind of heavy haul railway bridge pier sulphate corrosion risk evaluating method - Google Patents

A kind of heavy haul railway bridge pier sulphate corrosion risk evaluating method Download PDF

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CN108564287A
CN108564287A CN201810355157.4A CN201810355157A CN108564287A CN 108564287 A CN108564287 A CN 108564287A CN 201810355157 A CN201810355157 A CN 201810355157A CN 108564287 A CN108564287 A CN 108564287A
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刘永前
李晓永
陈树礼
吴立朋
杨明
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Shijiazhuang Tiedao University
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Abstract

The invention discloses a kind of heavy haul railway bridge pier sulphate corrosion risk evaluating methods, belong to science of bridge building field.Three broad aspect of environmental factor, raw material factor and Surface layer's concrete qualitative factor is considered.Environmental factor is divided into Climate Dryness/Wetness, underground water and soil sulfate ingredient and three subclass of content;Raw material factor is divided into three tricalcium aluminate content in cement, flyash and fine slag contents subclass;Surface layer's concrete quality is indicated with interconnected pore rate;Corresponding subitem risk index is assigned to above each factor, integrated risk index is obtained by the adduction of each subitem risk index, and passes through its corrosion risk of the integrated risk index assessment.The present invention can be used for heavy haul railway concrete pier and be evaluated by sulphate corrosion risk, and method is relatively simple, calculate simplicity, and distinction is strong.

Description

一种重载铁路桥墩硫酸盐腐蚀风险评价方法A risk assessment method for sulfate corrosion of heavy-duty railway bridge piers

技术领域technical field

本发明涉及一种腐蚀风险评价方法,具体的说是一种重载铁路桥墩硫酸盐腐蚀风险评价方法,属于桥梁工程领域。The invention relates to a corrosion risk assessment method, in particular to a sulfate corrosion risk assessment method for heavy-duty railway bridge piers, which belongs to the field of bridge engineering.

背景技术Background technique

世界范围内混凝土工程应用日益广泛,尽管在普通环境中,混凝土被认为是一种耐久的建筑材料,但在恶劣的服役环境中,其耐久性问题却日益突出。化学腐蚀是混凝土面临的一种较为严重的腐蚀类别,其中硫酸盐腐蚀是化学腐蚀最普遍的形式。我国幅员辽阔,在西北地区和东部沿海区域有不少盐碱地,特别是西北内陆盐湖及东部黄河三角洲(含黄河故道附近)区域硫酸盐侵蚀尤为突出。一些交通基础设施和电力基础设施投入使用十几年甚至几年就出现严重腐蚀,不得不加固改造或者拆除重建,中断设施使用,造成不良社会影响。我国重载铁路建造时间较早,当时对耐久性认识尚不充分,在工程设计时往往没有考虑耐久性问题,现场调研表明,东部盐碱地区域的混凝土桥墩腐蚀已经凸现。经文献检索,未发现国内外有综合考虑环境、材料和混凝土质量的硫酸盐腐蚀风险评价方法。本发明旨在提供一种综合评定方法。Concrete engineering is widely used all over the world. Although concrete is considered as a durable building material in ordinary environments, its durability problems are becoming more and more prominent in harsh service environments. Chemical corrosion is a relatively serious corrosion category faced by concrete, and sulfate corrosion is the most common form of chemical corrosion. my country has a vast territory, and there are many saline-alkali lands in the northwest and eastern coastal areas, especially the sulfate erosion in the inland salt lakes in the northwest and the Yellow River Delta in the east (including near the old course of the Yellow River). Some transportation infrastructure and power infrastructure have been severely corroded after being in use for more than ten years or even a few years, and have to be reinforced and rebuilt or demolished and rebuilt, interrupting the use of facilities and causing adverse social impacts. my country's heavy-haul railways were built earlier. At that time, the understanding of durability was not sufficient, and durability issues were often not considered in engineering design. On-site investigations showed that the corrosion of concrete piers in the eastern saline-alkaline area has become prominent. After searching the literature, no risk assessment method for sulfate corrosion that comprehensively considers the environment, materials and concrete quality has been found at home and abroad. The present invention aims to provide a comprehensive evaluation method.

发明内容Contents of the invention

为了解决现有技术中存在的上述问题,本发明提供了一种重载铁路桥墩硫酸盐腐蚀风险评价方法,通过对混凝土工程所处环境、所用原材料和配合比,以及表层混凝土的质量的评价,得到一种综合的腐蚀风险评价指数,对于混凝土受硫酸盐腐蚀风险判断具有参考意义。In order to solve the above-mentioned problems existing in the prior art, the present invention provides a kind of heavy-duty railway pier sulfate corrosion risk assessment method, through the assessment of the environment of the concrete engineering, the raw materials used and the mix ratio, and the quality of the surface layer concrete, A comprehensive corrosion risk evaluation index is obtained, which has reference significance for judging the risk of sulfate corrosion of concrete.

为了解决上述技术问题,本发明采用了如下技术方案:In order to solve the problems of the technologies described above, the present invention adopts the following technical solutions:

一种重载铁路桥墩硫酸盐腐蚀风险评价方法,综合考虑环境因素、原材料因素和表层混凝土质量因素三大方面,将环境因素分为气候环境、地下水及土壤硫酸盐成分和含量三个子类别;将原材料因素分为水泥中铝酸三钙含量、粉煤灰和矿渣掺加三个子类别;将表层混凝土质量用连通孔隙率k表示;其中,所述土壤硫酸盐成分和含量子类别包括土壤中可溶性硫酸盐含量以及土壤中可溶性硫酸盐成分的相对浓度,而土壤中可溶性硫酸盐成分的相对浓度又分为土壤中硫酸镁、硫酸钠和硫酸钙的浓度;所述粉煤灰子类别包括混凝土配合比中一级粉煤灰用量占所有胶凝材料质量的百分比;所述矿渣掺加子类别包括混凝土配合比中粒化高炉矿渣用量占所有胶凝材料质量的百分比;对以上各因素赋予对应的分项风险指数,通过各分项风险指数的加和得到综合风险指数,并通过该综合风险指数评价其腐蚀风险。A risk assessment method for sulfate corrosion of heavy-duty railway bridge piers, which comprehensively considers three major aspects: environmental factors, raw material factors and surface concrete quality factors, and divides environmental factors into three subcategories: climate environment, groundwater and soil sulfate composition and content; Raw material factors are divided into three subcategories of tricalcium aluminate content in cement, fly ash and slag admixture; the surface concrete quality is represented by connected porosity k; wherein, the soil sulfate composition and content subcategory includes soluble Sulfate content and the relative concentration of soluble sulfate components in the soil, which in turn is divided into concentrations of magnesium sulfate, sodium sulfate, and calcium sulfate in the soil; the fly ash subcategory includes concrete mix The percentage of the amount of primary fly ash in the mass of all cementitious materials in the ratio; the slag addition subcategory includes the percentage of the amount of granulated blast furnace slag in the mass of all cementitious materials in the concrete mix ratio; assign corresponding values to the above factors The sub-item risk index, the comprehensive risk index is obtained by summing the sub-item risk indexes, and the corrosion risk is evaluated through the comprehensive risk index.

优选的,对于气候环境来说,所述气候环境若为干旱地区,则分项风险指数 R0=0;若为湿润地区,则分项风险指数R0=1;若为干湿交替地区,则分项风险指数R0=2;Preferably, for the climate environment, if the climate environment is an arid area, then the sub-item risk index R 0 =0; if it is a humid area, then the sub-item risk index R 0 =1; if it is a dry-wet alternate area, Then the sub-item risk index R 0 =2;

对于地下水来说,所述地下水情况若无地下水,分项风险指数R1=0;则若地下水为浅层滞水,则分项风险指数R1=1;若为流动水,则分项风险指数R1=2;For groundwater, if the groundwater has no groundwater, the sub-item risk index R 1 =0; if the groundwater is shallow stagnant water, then the sub-item risk index R 1 =1; Index R 1 =2;

对于土壤中可溶性硫酸盐含量p来说,若p≥4000mg/Kg,则分项风险指数 R2=3;若2000mg/Kg<p<4000mg/Kg,则分项风险指数R2=2;若400 mg/Kg<p≤2000mg/Kg,则分项风险指数R2=1;若p≤400mg/Kg,则硫酸盐腐蚀风险可忽略,直接取综合风险指数R=0;For the soluble sulfate content p in the soil, if p≥4000mg/Kg, then the sub-item risk index R 2 =3; if 2000mg/Kg<p<4000mg/Kg, then the sub-item risk index R 2 =2; if 400 mg/Kg<p≤2000mg/Kg, then the sub-item risk index R 2 =1; if p≤400mg/Kg, the sulfate corrosion risk can be ignored, and the comprehensive risk index R=0;

对于土壤中硫酸镁、硫酸钠和硫酸钙的浓度来说,所述土壤中硫酸镁、硫酸钠和硫酸钙的浓度,分别记作CMg、CNa和CCa,若CMg>max{CNa,CCa},则分项风险指数R3=3;若CNa>max{CMg,CCa},则分项风险指数R3=2;若CCa>max{CMg, CNa},则分项风险指数R3=1;For the concentration of magnesium sulfate, sodium sulfate and calcium sulfate in the soil, the concentrations of magnesium sulfate, sodium sulfate and calcium sulfate in the soil are respectively recorded as C Mg , C Na and C Ca , if C Mg >max{C Na , C Ca }, then the sub-item risk index R 3 =3; if C Na >max{C Mg ,C Ca }, then the sub-item risk index R 3 =2; if C Ca >max{C Mg , C Na }, then the sub-item risk index R 3 =1;

对于水泥中铝酸三钙含量来说,若该含量大于9%,则分项风险指数R4=2,否则分项风险指数R4=1;For the content of tricalcium aluminate in cement, if the content is greater than 9%, the sub-item risk index R 4 =2, otherwise the sub-item risk index R 4 =1;

对于混凝土配合比中一级粉煤灰用量占所有胶凝材料质量的百分比来说,若该百分比大于25%,则分项风险指数R5=1;否则分项风险指数R5=2;For the percentage of the amount of primary fly ash in the concrete mix ratio to the mass of all cementitious materials, if the percentage is greater than 25%, then the sub-item risk index R 5 =1; otherwise, the sub-item risk index R 5 =2;

对于混凝土配合比中粒化高炉矿渣用量占所有胶凝材料质量的百分比来说,若该百分比大于60%,则分项风险指数R6=0;否则分项风险指数R6=1。Regarding the percentage of the amount of granulated blast furnace slag to the mass of all cementitious materials in the concrete mix, if the percentage is greater than 60%, the sub-item risk index R 6 =0; otherwise, the sub-item risk index R 6 =1.

对于混凝土质量来说,若连通孔隙率k>0.12,则分项风险指数R7=2;若 7≤k≤12,则分项风险指数R7=1;若k<7,分项风险指数R7=0。For concrete quality, if the connected porosity k>0.12, then the sub-item risk index R 7 =2; if 7≤k≤12, then the sub-item risk index R 7 =1; if k<7, the sub-item risk index R 7 =0.

优选的,对于混凝土质量来说,应在易受硫酸盐侵蚀部位钻孔取芯,钻孔直径不大于50mm,钻孔深度不小于混凝土保护层厚度;用清水洗净芯样,放入混凝土真空饱水机内饱水,使真空泵读数小于0.1个大气压,保持真空度注入蒸馏水,持续抽真空48小时;取出芯样擦干表面水迹,立即用精度大于十分之一克的电子秤称重,记质量为m1,再将芯样放至80℃~90℃的环境中烘烤72小时,用同一个电子秤称重,记质量为m2,计算k=2.4×(m1-m2)/m2Preferably, for the quality of concrete, cores should be drilled at the parts susceptible to sulfate corrosion, the diameter of the drilled holes should not be greater than 50 mm, and the drilled depth should not be less than the thickness of the concrete protective layer; the core samples should be washed with clean water and put into the concrete vacuum Saturate the machine with water so that the reading of the vacuum pump is less than 0.1 atmospheric pressure, keep the vacuum and inject distilled water, and continue vacuuming for 48 hours; take out the core sample and wipe off the water on the surface, and immediately weigh it with an electronic scale with an accuracy greater than one tenth of a gram , record the mass as m 1 , put the core sample in an environment of 80°C to 90°C and bake for 72 hours, weigh it with the same electronic scale, record the mass as m 2 , and calculate k=2.4×(m 1 -m 2 )/m 2 .

优选的,所述综合风险指数根据表1查取风险等级:Preferably, the comprehensive risk index Check the risk level according to Table 1:

表1Table 1

与现有技术相比,本发明的有益效果在于:Compared with prior art, the beneficial effect of the present invention is:

1.该方法可对重载铁路混凝土桥墩受硫酸盐侵蚀风险进行综合定性评价。1. This method can be used for a comprehensive qualitative evaluation of the sulfate erosion risk of heavy-duty railway concrete piers.

2.该方法结合了现场调查及实验室测试,考虑因素较为全面,且所需的实验仪器少,操作简便。2. This method combines on-site investigation and laboratory test, and the consideration factors are relatively comprehensive, and the required experimental instruments are few, and the operation is simple.

3.该方法较为简单,计算简明,区分性强。3. The method is relatively simple, the calculation is concise, and the distinction is strong.

具体实施方式Detailed ways

下面结合具体实施例对本发明作进一步详细描述,但不作为对本发明的限定。The present invention will be described in further detail below in conjunction with specific examples, but not as a limitation of the present invention.

山东省东营市某铁路桥墩,处于干湿交替环境,分项风险指数R0=2;地下水为浅层滞水,分项风险指数R1=1;土壤中可溶性硫酸盐含量为3860mg/Kg,分项风险指数R2=2;土壤中硫酸钠的浓度高于硫酸镁和硫酸钙的浓度,分项风险指数R3=2;水泥化学组分中铝酸三钙的含量为8%,分项风险指数R4=1;一级粉煤灰用量占所有胶凝材料质量的百分比为30%,分项风险指数R5=1;未掺加矿渣,分项风险指数R6=1;在同一桥墩三个不同部位钻孔取芯,按照上述流程计算k=8.2,分项风险指数R7=1。计算得综合风险指数R=11,查表1为极高风险。事实上,该桥墩已于2012年8月份经专家鉴定为危险墩,已加固改造。A railway bridge pier in Dongying City, Shandong Province is in an alternating dry and wet environment, and the sub-item risk index R 0 =2; the groundwater is shallow stagnant water, and the sub-item risk index R 1 =1; the soluble sulfate content in the soil is 3860mg/Kg, The sub-item risk index R 2 =2; the concentration of sodium sulfate in the soil is higher than the concentration of magnesium sulfate and calcium sulfate, the sub-item risk index R 3 =2; the content of tricalcium aluminate in the cement chemical components is 8%, the sub-item risk index Item risk index R 4 =1; the percentage of primary fly ash to all cementitious materials is 30%, sub-item risk index R 5 =1; no slag is added, sub-item risk index R 6 =1; Coring is drilled at three different parts of the same pier, k=8.2 is calculated according to the above process, and the sub-item risk index R 7 =1. Calculated comprehensive risk index R = 11, look up Table 1 as extremely high risk. In fact, the pier was identified as a dangerous pier by experts in August 2012 and has been reinforced and reconstructed.

上述实施例只是为了更清楚说明本发明的技术方案做出的列举,并非对本发明的限定,本领域的普通技术人员根据本领域的公知常识对本申请技术方案的变通亦均在本申请保护范围之内,总之,上述实施例仅为列举,本申请的保护范围以所附权利要求书范围为准。The above-mentioned embodiments are only enumerations made to illustrate the technical solutions of the present invention more clearly, and are not intended to limit the present invention. Any modification of the technical solutions of the present application by those of ordinary skill in the art according to the common knowledge in the field is also within the scope of protection of the present application. In a word, the above-mentioned embodiments are merely examples, and the scope of protection of the present application shall be subject to the scope of the appended claims.

Claims (4)

1. a kind of heavy haul railway bridge pier sulphate corrosion risk evaluating method, it is characterised in that:Consider environmental factor, former material Environmental factor is divided into climatic environment, underground water and soil sulfate by three broad aspect of material factor and Surface layer's concrete qualitative factor Three subclass of ingredient and content;Raw material factor is divided into tricalcium aluminate content in cement, flyash and slag and adds three Subclass;Surface layer's concrete quality is indicated with interconnected pore rate k;Wherein, the soil sulfate ingredient and content subclass Include the relative concentration of soluble sulphate ingredient in soluble sulphate content in soil and soil, and it is soluble in soil The relative concentration of sulfuric acid salt component is divided into as the concentration of magnesium sulfate, sodium sulphate and calcium sulfate in soil;The flyash subclass The percentage of all cementitious material quality is accounted for including level-one flyash dosage in concrete mix;The slag adds subclass The percentage of all cementitious material quality is accounted for including granulated blast-furnace slag dosage in concrete mix;Above each factor is assigned Corresponding subitem risk index obtains integrated risk index by the adduction of each subitem risk index, and passes through the integrated risk Its corrosion risk of index assessment.
2. a kind of heavy haul railway bridge pier sulphate corrosion risk evaluating method according to claim 1, it is characterised in that:
For climatic environment, the climatic environment is if arid area, then itemize risk index R0=0;If moistening ground Area, then itemize risk index R0=1;If alternation of wetting and drying area, then itemize risk index R0=2;
For underground water, if the groundwater condition is without underground water, subitem risk index R1=0;If then underground water is shallow-layer Backwater, then itemize risk index R1=1;If circulating water, then itemize risk index R1=2;
For soluble sulphate content p in soil, if p >=4000mg/Kg, itemize risk index R2=3;If 2000mg/Kg<p<4000mg/Kg, then itemize risk index R2=2;If 400mg/Kg<P≤2000mg/Kg, then risk of itemizing Index R2=1;If p≤400mg/Kg, sulphate corrosion risk is negligible, directly takes integrated risk index R=0;
For the concentration of magnesium sulfate, sodium sulphate and calcium sulfate in soil, magnesium sulfate, sodium sulphate and calcium sulfate in the soil Concentration, be denoted as C respectivelyMg、CNaAnd CCaIf CMg>max{CNa,CCa, then itemize risk index R3=3;If CNa>max{CMg, CCa, then itemize risk index R3=2;If CCa>max{CMg,CNa, then itemize risk index R3=1;
For tricalcium aluminate content in cement, if the content is more than 9%, itemize risk index R4=2, wind of otherwise itemizing Dangerous index R4=1;
Level-one flyash dosage in concrete mix is accounted for for the percentage of all cementitious material quality, if the percentage More than 25%, then itemize risk index R5=1;Otherwise subitem risk index R5=2;
Granulated blast-furnace slag dosage in concrete mix is accounted for for the percentage of all cementitious material quality, if the percentage Than being more than 60%, then itemize risk index R6=0;Otherwise subitem risk index R6=1.
For concrete quality, if interconnected pore rate k>0.12, then itemize risk index R7=2;If 7≤k≤12 are divided Item risk index R7=1;If k<7, subitem risk index R7=0.
3. a kind of heavy haul railway bridge pier sulphate corrosion risk evaluating method according to claim 2, it is characterised in that:It is right For concrete quality, Ying Yi is not more than 50mm by sulfate attack position boring and coring, bore diameter, and drilling depth is not Less than thickness of concrete cover;Core sample is cleaned with clear water, water of satisfying is put into the full water dispenser of concrete vacuum, keeps vacuum pump reading small In 0.1 atmospheric pressure, keeps vacuum degree to inject distilled water, persistently vacuumize 48 hours;It takes out core sample and dries surface water mark, immediately It is more than 1/10th grams of electronic scale weighing with precision, note quality is m1, then core sample is put into 80 DEG C~90 DEG C of environment and is dried 72 hours roasting, with the same electronic scale weighing, note quality is m2, calculate k=2.4 × (m1-m2)/m2
4. a kind of heavy haul railway bridge pier sulphate corrosion risk evaluating method according to claim 3, it is characterised in that:
The integrated risk indexIt is looked into according to table 1 and takes risk class:
Table 1
CN201810355157.4A 2018-04-19 2018-04-19 A kind of heavy haul railway bridge pier sulphate corrosion risk evaluating method Pending CN108564287A (en)

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