CN108659644A - A kind of softness leather filler and preparation method thereof - Google Patents
A kind of softness leather filler and preparation method thereof Download PDFInfo
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- CN108659644A CN108659644A CN201810475833.1A CN201810475833A CN108659644A CN 108659644 A CN108659644 A CN 108659644A CN 201810475833 A CN201810475833 A CN 201810475833A CN 108659644 A CN108659644 A CN 108659644A
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- Prior art keywords
- parts
- extract
- leather
- cinnamomi camphorae
- lignum cinnamomi
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- 239000010985 leather Substances 0.000 title claims abstract description 94
- 239000000945 filler Substances 0.000 title claims abstract description 60
- 238000002360 preparation method Methods 0.000 title abstract description 23
- 239000000839 emulsion Substances 0.000 claims abstract description 62
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 31
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 31
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 31
- 235000003704 aspartic acid Nutrition 0.000 claims abstract description 30
- 239000004593 Epoxy Substances 0.000 claims abstract description 29
- 235000001510 limonene Nutrition 0.000 claims abstract description 29
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 29
- 239000003549 soybean oil Substances 0.000 claims abstract description 29
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims abstract description 19
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229940087305 limonene Drugs 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 9
- 230000000740 bleeding effect Effects 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 150000003839 salts Chemical class 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 7
- 239000000284 extract Substances 0.000 claims description 76
- 239000000463 material Substances 0.000 claims description 60
- 210000003608 fece Anatomy 0.000 claims description 33
- 150000002191 fatty alcohols Chemical group 0.000 claims description 28
- BYMUNNMMXKDFEZ-UHFFFAOYSA-K trifluorolanthanum Chemical compound F[La](F)F BYMUNNMMXKDFEZ-UHFFFAOYSA-K 0.000 claims description 26
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 25
- 229940105963 yttrium fluoride Drugs 0.000 claims description 25
- RBORBHYCVONNJH-UHFFFAOYSA-K yttrium(iii) fluoride Chemical compound F[Y](F)F RBORBHYCVONNJH-UHFFFAOYSA-K 0.000 claims description 25
- 229940105902 mint extract Drugs 0.000 claims description 21
- 244000246386 Mentha pulegium Species 0.000 claims description 20
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 20
- 235000004357 Mentha x piperita Nutrition 0.000 claims description 20
- 235000001050 hortel pimenta Nutrition 0.000 claims description 20
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 17
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 17
- GKVKQZRNDGUFSY-NSGFTINJSA-L [Na+].C(C)(CCCCCC)/C(=C(/C(=O)[O-])\C(C)CCCCCC)/C(=O)[O-].[Na+] Chemical compound [Na+].C(C)(CCCCCC)/C(=C(/C(=O)[O-])\C(C)CCCCCC)/C(=O)[O-].[Na+] GKVKQZRNDGUFSY-NSGFTINJSA-L 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 15
- -1 rare-earth salts Chemical class 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 13
- 241001104043 Syringa Species 0.000 claims description 12
- 235000004338 Syringa vulgaris Nutrition 0.000 claims description 12
- 238000000605 extraction Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 9
- 238000001556 precipitation Methods 0.000 claims description 9
- 238000002604 ultrasonography Methods 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- 125000005233 alkylalcohol group Chemical group 0.000 claims description 2
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 2
- CDOUZKKFHVEKRI-UHFFFAOYSA-N 3-bromo-n-[(prop-2-enoylamino)methyl]propanamide Chemical group BrCCC(=O)NCNC(=O)C=C CDOUZKKFHVEKRI-UHFFFAOYSA-N 0.000 claims 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 2
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 claims 2
- 239000011976 maleic acid Substances 0.000 claims 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid group Chemical group C(\C=C/C(=O)O)(=O)O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 2
- 240000002853 Nelumbo nucifera Species 0.000 claims 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 claims 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 claims 1
- 229910000420 cerium oxide Inorganic materials 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 239000000835 fiber Substances 0.000 abstract description 4
- 230000035699 permeability Effects 0.000 abstract description 4
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 3
- 230000001050 lubricating effect Effects 0.000 abstract description 2
- 230000003204 osmotic effect Effects 0.000 abstract description 2
- 150000002628 limonene derivativess Chemical class 0.000 description 12
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 11
- 150000001510 aspartic acids Chemical class 0.000 description 11
- 239000003643 water by type Substances 0.000 description 6
- 235000006679 Mentha X verticillata Nutrition 0.000 description 5
- 235000002899 Mentha suaveolens Nutrition 0.000 description 5
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 5
- 235000005979 Citrus limon Nutrition 0.000 description 4
- 244000131522 Citrus pyriformis Species 0.000 description 4
- 238000002242 deionisation method Methods 0.000 description 4
- 238000011056 performance test Methods 0.000 description 3
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- DWNBOPVKNPVNQG-LURJTMIESA-N (2s)-4-hydroxy-2-(propylamino)butanoic acid Chemical compound CCCN[C@H](C(O)=O)CCO DWNBOPVKNPVNQG-LURJTMIESA-N 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 230000035617 depilation Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
The invention discloses a kind of soft leather fillers and preparation method thereof.The soft leather filler of the present invention, is counted, including the following raw material in parts by weight：20~50 parts of emulsion acrylic resins, 15~40 parts of ester-polyurethane resin emulsions, 15~30 parts of modified epoxy soybean oils, 2~8 parts of bleeding agents, 1~5 part of antiseptic, 0.1~1 part of metal salt, 1~5 part of aspartic acid, 1~5 part of limonene, 15~50 parts of water.The soft leather filler of the present invention has specific raw material and proportioning, its permeability is strong, can rapid osmotic into inside leather, with leather fiber firm connection, and one layer of ultra-thin lubricating film is formed in leather surface, to improve the flexibility, toughness and antibacterial and mouldproof of leather, while excellent glossy effect is played to leather, and preparation method is easy, is suitable for large-scale production and application.
Description
Technical field
The present invention relates to leather processing technique field, more particularly to a kind of soft leather filler and preparation method thereof.
Background technology
Leather be through depilation and the physics such as tanning, chemical process is obtained has been denaturalized not perishable Animal Skin.Leather
It is made of in three dimensions close weave natural protein fibre, there is a kind of special grain layer on surface, has nature
Graining and gloss, comfortable feel..The market potential of leather and leather products is prodigious, and global leather aggregate demand is about 1.0
Hundred million square metres, it is equivalent to the yield of 300,000,000 ox-hides (standard skin), Chinese leather yield converts into nearly 70,000,000 of standard skin, accounts for about
The 23.33% of global leather yield.But the enterprise of Chinese leather shoemaking and its related industry also could envisage that, 21 century
We are not leather power although China is leather big producer in the world there is also shortcoming at many aspects,
Still in weak position in terms of quality, value, need to be tempered and improved in the overall situation in this market.For light leather plus
For work, surface dry-packing has become an indispensable process.It can effectively improve loose side phenomenon, reinforce local
Filling effect, and the other performance of finished leather can be improved.
But the performance of most filler is unstable at present, permeability is weaker, so that leather is hardened after use, and shape
At sticky oil mark, and do not have anti-microbial property.Therefore, it is badly in need of developing a kind of novel soft leather filler, improves skin
Flexibility, antibiotic property, the toughness of leather.
Invention content
The technical problem to be solved in the present invention is to provide a kind of soft leather filler and preparation method thereof, the softness leathers
Filler is strong to the permeability of leather, can rapid osmotic into inside leather, with leather fiber firm connection, skin can be effectively improved
Flexibility, toughness and the antibacterial and mouldproof of leather, while excellent glossy effect is played to leather, and preparation method is easy, fits
In large-scale production and application.
In order to solve the above-mentioned technical problem, the technical scheme is that：
In a first aspect, a kind of soft leather filler provided by the invention, is counted, including the following raw material in parts by weight：
20~50 parts of emulsion acrylic resins, 15~40 parts of ester-polyurethane resin emulsions, 15~30 parts of modified epoxy soybean oils,
2~8 parts of bleeding agents, 1~5 part of antiseptic, 0.1~1 part of metal salt, 1~5 part of aspartic acid, 1~5 part of limonene, 15~50 parts
Water.
Preferably, the bleeding agent in disecoctylmaleate sodium sulfonate, fatty alcohol polyoxyethylene ether one
Kind or two kinds.
It is further preferred that the bleeding agent includes disecoctylmaleate sodium sulfonate, fatty alcohol polyoxyethylene ether,
Wherein, the weight ratio of the disecoctylmaleate sodium sulfonate and the fatty alcohol polyoxyethylene ether is 1~3:1.
Preferably, the one kind or more of the antiseptic in Faeces Passeris extract, lignum cinnamomi camphorae extract, mint extract
Kind.
It is further preferred that the antiseptic includes Faeces Passeris extract, lignum cinnamomi camphorae extract, mint extract, wherein
The Faeces Passeris extract, lignum cinnamomi camphorae extract, mint extract weight ratio be 0.1~0.5:0.2~0.5:1.
It is further preferred that the Faeces Passeris extract is to be made using following methods：Extremely by white lilac crushed after being dried
50~100 mesh obtain white lilac powder, add the water of 50~80 times of amounts of the white lilac powder weight, after mixing, in
60~70 DEG C, 30~35KHz, 30~50min of ultrasound, are filtered to remove precipitation, re-dry obtains Faeces Passeris extract.
It is further preferred that the lignum cinnamomi camphorae extract is to be made using following methods：Extremely by lignum cinnamomi camphorae crushed after being dried
50~80 mesh obtain lignum cinnamomi camphorae end, the water for stating 50~80 times of amounts of lignum cinnamomi camphorae powder weight are added, after mixing, in 60
~70 DEG C, 40~45KHz, 30~50min of ultrasound, are filtered to remove precipitation, and re-dry obtains stating lignum cinnamomi camphorae extract.
It is further preferred that the mint extract is to be made using following methods：By peppermint crushed after being dried to 40~
60 mesh obtain peppermint powder, add the water of 50~80 times of peppermint powder weight amount, after mixing, in 50~60 DEG C,
25~30KHz, 30~50min of ultrasound, are filtered to remove precipitation, and re-dry obtains mint extract.
Preferably, the metal salt is rare-earth salts.
It is further preferred that the rare-earth salts is selected from nanometer lanthanum fluoride, nanometer yttrium fluoride, nano yttrium oxide, nano oxidized
It is one or more in cerium, nano lanthanum oxide.
Second aspect, a kind of method preparing soft leather filler as described in relation to the first aspect provided by the invention, packet
Include following steps：
(1) modified epoxy soybean oil, emulsion acrylic resin, ester-polyurethane resin emulsion are sequentially added into water, are heated to
60~80 DEG C and 5~30min of insulated and stirred, obtain material I；
(2) bleeding agent, metal salt are sequentially added into the material I obtained by step (1), are continued in 60~80 DEG C of insulated and stirreds
5~20min obtains material II；
(2) antiseptic, aspartic acid, limonene are sequentially added into the material II obtained by step (2), are continued 60~80
DEG C 3~10min of insulated and stirred, obtains soft leather filler.
Compared with prior art, the beneficial effects of the present invention are：
Soft leather filler obtained by the present invention has specific raw material and proportioning, and permeability is strong, can quickly ooze
It penetrates into inside leather, it is strong bonded with leather fiber, and one layer of ultra-thin lubricating film is formed in leather surface, to improve leather
Flexibility, toughness and antibacterial and mouldproof, while excellent glossy effect is played to leather, after testing, the softness through the present invention
The processed leather of leather filler has excellent inhibition, suppression to staphylococcus aureus, aspergillus niger, Candida albicans
Bacterium rate respectively reaches 96%, 97%, 95% or more；The extension at break of the processed leather of soft leather filler through the present invention
Rate reaches 94.3%, and pliability reaches 6.7, and color inhibition grade reaches 5 grades.The preparation method of the soft leather filler of the present invention
Simplicity is suitable for large-scale production and application.
Description of the drawings
Fig. 1 is the flow chart of the preparation method of soft leather filler.
Specific implementation mode
The specific implementation mode of the present invention is described further below in conjunction with the accompanying drawings.It should be noted that for
The explanation of these embodiments is used to help understand the present invention, but does not constitute limitation of the invention.In addition, disclosed below
The each embodiment of the present invention in involved technical characteristic can be combined with each other as long as they do not conflict with each other.
In following embodiment, the Faeces Passeris extract is to be made using following methods：Extremely by white lilac crushed after being dried
80 mesh obtain white lilac powder, the water of 70 times of amounts of the white lilac powder weight are added, after mixing, in 65 DEG C, 32KHz
Ultrasonic 40min, is filtered to remove precipitation, and re-dry obtains Faeces Passeris extract.
In following embodiment, the lignum cinnamomi camphorae extract is to be made using following methods：Extremely by lignum cinnamomi camphorae crushed after being dried
60 mesh obtain lignum cinnamomi camphorae end, the water for stating 70 times of amounts of lignum cinnamomi camphorae powder weight are added, after mixing, in 65 DEG C, 42KHz
Ultrasonic 45min, is filtered to remove precipitation, and re-dry obtains stating lignum cinnamomi camphorae extract.
In following embodiment, the mint extract is to be made using following methods：By peppermint crushed after being dried to 50 mesh
Peppermint powder is obtained, the water of 70 times of amounts of the peppermint powder weight is added, after mixing, in 55 DEG C, 28KHz ultrasounds
35min, is filtered to remove precipitation, and re-dry obtains mint extract.
In following embodiment, the flow chart of the preparation method of soft leather filler is as shown in Figure 1.
Embodiment 1
The preparation method of the soft leather filler of the present embodiment, includes the following steps：
Take following raw materials counted in parts by weight：
35 parts of emulsion acrylic resins, 33 parts of ester-polyurethane resin emulsions, 24 parts of modified epoxy soybean oils, 4 parts of maleics two
Sour di-sec-octyl sodium sulfonate, 2 parts of fatty alcohol polyoxyethylene ether, 0.4 part of Faeces Passeris extract, 0.8 part of lignum cinnamomi camphorae extract, 2 parts
Mint extract, 0.2 part of nanometer lanthanum fluoride, 0.6 part of nanometer yttrium fluoride, 2 parts of aspartic acids, 3 parts of limonenes, 18 parts of deionizations
Water.
(1) modified epoxy soybean oil, emulsion acrylic resin, ester-polyurethane resin emulsion are sequentially added into water, are heated to
70 DEG C and insulated and stirred 12min, obtain material I；
(2) disecoctylmaleate sodium sulfonate, fatty alcohol polyoxy are sequentially added into the material I obtained by step (1)
Vinethene, nanometer lanthanum fluoride, nanometer yttrium fluoride continue, in 70 DEG C of insulated and stirred 10min, to obtain material II；
(3) Faeces Passeris extract, lignum cinnamomi camphorae extract, peppermint extraction are sequentially added into the material II obtained by step (2)
Object, aspartic acid, limonene continue, in 70 DEG C of insulated and stirred 5min, to obtain soft leather filler.
Embodiment 2
The preparation method of the soft leather filler of the present embodiment, includes the following steps：
Take following raw materials counted in parts by weight：
40 parts of emulsion acrylic resins, 35 parts of ester-polyurethane resin emulsions, 28 parts of modified epoxy soybean oils, 2.5 parts of maleics
Diacid di-sec-octyl sodium sulfonate, 2.5 parts of fatty alcohol polyoxyethylene ether, 0.3 part of Faeces Passeris extract, 0.3 part of lignum cinnamomi camphorae extract,
1 part of mint extract, 0.3 part of nanometer lanthanum fluoride, 0.6 part of nanometer yttrium fluoride, 2 parts of aspartic acids, 3 parts of limonenes, 20 parts go from
Sub- water.
(1) modified epoxy soybean oil, emulsion acrylic resin, ester-polyurethane resin emulsion are sequentially added into water, are heated to
65 DEG C and insulated and stirred 15min, obtain material I；
(2) disecoctylmaleate sodium sulfonate, fatty alcohol polyoxy are sequentially added into the material I obtained by step (1)
Vinethene, nanometer lanthanum fluoride, nanometer yttrium fluoride continue, in 65 DEG C of insulated and stirred 12min, to obtain material II；
(3) Faeces Passeris extract, lignum cinnamomi camphorae extract, peppermint extraction are sequentially added into the material II obtained by step (2)
Object, aspartic acid, limonene continue, in 65 DEG C of insulated and stirred 7min, to obtain soft leather filler.
Embodiment 3
The preparation method of the soft leather filler of the present embodiment, includes the following steps：
Take following raw materials counted in parts by weight：
45 parts of emulsion acrylic resins, 38 parts of ester-polyurethane resin emulsions, 25 parts of modified epoxy soybean oils, 5 parts of maleics two
Sour di-sec-octyl sodium sulfonate, 2 parts of fatty alcohol polyoxyethylene ether, 0.4 part of Faeces Passeris extract, 0.6 part of lignum cinnamomi camphorae extract, 2 parts
Mint extract, 0.1 part of nanometer lanthanum fluoride, 0.5 part of nanometer yttrium fluoride, 2 parts of aspartic acids, 2 parts of limonenes, 22 parts of deionizations
Water.
(1) modified epoxy soybean oil, emulsion acrylic resin, ester-polyurethane resin emulsion are sequentially added into water, are heated to
75 DEG C and insulated and stirred 8min, obtain material I；
(2) disecoctylmaleate sodium sulfonate, fatty alcohol polyoxy are sequentially added into the material I obtained by step (1)
Vinethene, nanometer lanthanum fluoride, nanometer yttrium fluoride continue, in 75 DEG C of insulated and stirred 8min, to obtain material II；
(3) Faeces Passeris extract, lignum cinnamomi camphorae extract, peppermint extraction are sequentially added into the material II obtained by step (2)
Object, aspartic acid, limonene continue, in 75 DEG C of insulated and stirred 5min, to obtain soft leather filler.
Embodiment 4
The preparation method of the soft leather filler of the present embodiment, includes the following steps：
Take following raw materials counted in parts by weight：
28 parts of emulsion acrylic resins, 22 parts of ester-polyurethane resin emulsions, 24 parts of modified epoxy soybean oils, 3 parts of maleics two
Sour di-sec-octyl sodium sulfonate, 2 parts of fatty alcohol polyoxyethylene ether, 0.4 part of Faeces Passeris extract, 0.8 part of lignum cinnamomi camphorae extract, 2 parts
Mint extract, 0.1 part of nanometer lanthanum fluoride, 0.4 part of nanometer yttrium fluoride, 1.5 parts of aspartic acids, 1.5 parts of limonenes, 17 parts go from
Sub- water.
(1) modified epoxy soybean oil, emulsion acrylic resin, ester-polyurethane resin emulsion are sequentially added into water, are heated to
70 DEG C and insulated and stirred 15min, obtain material I；
(2) disecoctylmaleate sodium sulfonate, fatty alcohol polyoxy are sequentially added into the material I obtained by step (1)
Vinethene, nanometer lanthanum fluoride, nanometer yttrium fluoride continue, in 70 DEG C of insulated and stirred 7min, to obtain material II；
(3) Faeces Passeris extract, lignum cinnamomi camphorae extract, peppermint extraction are sequentially added into the material II obtained by step (2)
Object, aspartic acid, limonene continue, in 70 DEG C of insulated and stirred 5min, to obtain soft leather filler.
Embodiment 5
The preparation method of the soft leather filler of the present embodiment, includes the following steps：
Take following raw materials counted in parts by weight：
30 parts of emulsion acrylic resins, 30 parts of ester-polyurethane resin emulsions, 20 parts of modified epoxy soybean oils, 2.4 parts of maleics
Diacid di-sec-octyl sodium sulfonate, 1 part of fatty alcohol polyoxyethylene ether, 0.4 part of Faeces Passeris extract, 0.8 part of lignum cinnamomi camphorae extract, 2
Part mint extract, 0.1 part of nanometer lanthanum fluoride, 0.2 part of nanometer yttrium fluoride, 1.5 parts of aspartic acids, 2 parts of limonenes, 16 parts go from
Sub- water.
(1) modified epoxy soybean oil, emulsion acrylic resin, ester-polyurethane resin emulsion are sequentially added into water, are heated to
65 DEG C and insulated and stirred 15min, obtain material I；
(2) disecoctylmaleate sodium sulfonate, fatty alcohol polyoxy are sequentially added into the material I obtained by step (1)
Vinethene, nanometer lanthanum fluoride, nanometer yttrium fluoride continue, in 65 DEG C of insulated and stirred 10min, to obtain material II；
(3) Faeces Passeris extract, lignum cinnamomi camphorae extract, peppermint extraction are sequentially added into the material II obtained by step (2)
Object, aspartic acid, limonene continue, in 65 DEG C of insulated and stirred 5min, to obtain soft leather filler.
Embodiment 6
The preparation method of the soft leather filler of the present embodiment, includes the following steps：
Take following raw materials counted in parts by weight：
20 parts of emulsion acrylic resins, 15 parts of ester-polyurethane resin emulsions, 15 parts of modified epoxy soybean oils, 1 part of maleic two
Sour di-sec-octyl sodium sulfonate, 1 part of fatty alcohol polyoxyethylene ether, 0.1 part of Faeces Passeris extract, 0.2 part of lignum cinnamomi camphorae extract, 1 part
Mint extract, 0.05 part of nanometer lanthanum fluoride, 0.05 part of nanometer yttrium fluoride, 1 part of aspartic acid, 1 part of limonene, 15 parts of deionizations
Water.
(1) modified epoxy soybean oil, emulsion acrylic resin, ester-polyurethane resin emulsion are sequentially added into water, are heated to
60 DEG C and insulated and stirred 5min, obtain material I；
(2) disecoctylmaleate sodium sulfonate, fatty alcohol polyoxy are sequentially added into the material I obtained by step (1)
Vinethene, nanometer lanthanum fluoride, nanometer yttrium fluoride continue, in 60 DEG C of insulated and stirred 5min, to obtain material II；
(3) Faeces Passeris extract, lignum cinnamomi camphorae extract, peppermint extraction are sequentially added into the material II obtained by step (2)
Object, aspartic acid, limonene continue, in 60 DEG C of insulated and stirred 3min, to obtain soft leather filler.
Embodiment 7
The preparation method of the soft leather filler of the present embodiment, includes the following steps：
Take following raw materials counted in parts by weight：
50 parts of emulsion acrylic resins, 40 parts of ester-polyurethane resin emulsions, 30 parts of modified epoxy soybean oils, 6 parts of maleics two
Sour di-sec-octyl sodium sulfonate, 2 parts of fatty alcohol polyoxyethylene ether, 1.2 parts of Faeces Passeris extracts, 1.2 parts of lignum cinnamomi camphorae extracts, 2.4
Part mint extract, 0.4 part of nanometer lanthanum fluoride, 0.6 part of nanometer yttrium fluoride, 5 parts of aspartic acids, 5 parts of limonenes, 25 parts of deionizations
Water.
(1) modified epoxy soybean oil, emulsion acrylic resin, ester-polyurethane resin emulsion are sequentially added into water, are heated to
80 DEG C and insulated and stirred 30min, obtain material I；
(2) disecoctylmaleate sodium sulfonate, fatty alcohol polyoxy are sequentially added into the material I obtained by step (1)
Vinethene, nanometer lanthanum fluoride, nanometer yttrium fluoride continue, in 80 DEG C of insulated and stirred 20min, to obtain material II；
(3) Faeces Passeris extract, lignum cinnamomi camphorae extract, peppermint extraction are sequentially added into the material II obtained by step (2)
Object, aspartic acid, limonene continue, in 80 DEG C of insulated and stirred 10min, to obtain soft leather filler.
Embodiment 8
The preparation method of the soft leather filler of the present embodiment, includes the following steps：
35 parts of emulsion acrylic resins, 33 parts of ester-polyurethane resin emulsions, 4 parts of disecoctylmaleate sodium sulfonates, 2 parts
Fatty alcohol polyoxyethylene ether, 0.4 part of Faeces Passeris extract, 0.8 part of lignum cinnamomi camphorae extract, 2 parts of mint extracts, 0.2 part of nanometer
Lanthanum fluoride, 0.6 part of nanometer yttrium fluoride, 2 parts of aspartic acids, 3 parts of limonenes, 18 parts of deionized waters.
(1) emulsion acrylic resin, ester-polyurethane resin emulsion are sequentially added into water, are heated to 70 DEG C and insulated and stirred
12min obtains material I；
(2) disecoctylmaleate sodium sulfonate, fatty alcohol polyoxy are sequentially added into the material I obtained by step (1)
Vinethene, nanometer lanthanum fluoride, nanometer yttrium fluoride continue, in 70 DEG C of insulated and stirred 10min, to obtain material II；
(3) Faeces Passeris extract, lignum cinnamomi camphorae extract, peppermint extraction are sequentially added into the material II obtained by step (2)
Object, aspartic acid, limonene continue, in 70 DEG C of insulated and stirred 5min, to obtain soft leather filler.
Embodiment 9
The preparation method of the soft leather filler of the present embodiment, includes the following steps：
35 parts of emulsion acrylic resins, 33 parts of ester-polyurethane resin emulsions, 24 parts of modified epoxy soybean oils, 4 parts of maleics two
Sour di-sec-octyl sodium sulfonate, 2 parts of fatty alcohol polyoxyethylene ether, 0.8 part of lignum cinnamomi camphorae extract, 2 parts of mint extracts, 0.2 part receive
Rice lanthanum fluoride, 0.6 part of nanometer yttrium fluoride, 2 parts of aspartic acids, 3 parts of limonenes, 18 parts of deionized waters.
(1) modified epoxy soybean oil, emulsion acrylic resin, ester-polyurethane resin emulsion are sequentially added into water, are heated to
70 DEG C and insulated and stirred 12min, obtain material I；
(2) disecoctylmaleate sodium sulfonate, fatty alcohol polyoxy are sequentially added into the material I obtained by step (1)
Vinethene, nanometer lanthanum fluoride, nanometer yttrium fluoride continue, in 70 DEG C of insulated and stirred 10min, to obtain material II；
(3) lignum cinnamomi camphorae extract, mint extract, aspartic acid, lemon are sequentially added into the material II obtained by step (2)
Lemon alkene continues, in 70 DEG C of insulated and stirred 5min, to obtain soft leather filler.
Embodiment 10
The preparation method of the soft leather filler of the present embodiment, includes the following steps：
35 parts of emulsion acrylic resins, 33 parts of ester-polyurethane resin emulsions, 24 parts of modified epoxy soybean oils, 4 parts of maleics two
Sour di-sec-octyl sodium sulfonate, 2 parts of fatty alcohol polyoxyethylene ether, 0.4 part of Faeces Passeris extract, 2 parts of mint extracts, 0.2 part receive
Rice lanthanum fluoride, 0.6 part of nanometer yttrium fluoride, 2 parts of aspartic acids, 3 parts of limonenes, 18 parts of deionized waters.
(1) modified epoxy soybean oil, emulsion acrylic resin, ester-polyurethane resin emulsion are sequentially added into water, are heated to
70 DEG C and insulated and stirred 12min, obtain material I；
(2) disecoctylmaleate sodium sulfonate, fatty alcohol polyoxy are sequentially added into the material I obtained by step (1)
Vinethene, nanometer lanthanum fluoride, nanometer yttrium fluoride continue, in 70 DEG C of insulated and stirred 10min, to obtain material II；
(3) Faeces Passeris extract, mint extract, aspartic acid, lemon are sequentially added into the material II obtained by step (2)
Lemon alkene continues, in 70 DEG C of insulated and stirred 5min, to obtain soft leather filler.
Embodiment 11
The preparation method of the soft leather filler of the present embodiment, includes the following steps：
35 parts of emulsion acrylic resins, 33 parts of ester-polyurethane resin emulsions, 24 parts of modified epoxy soybean oils, 0.4 portion of white lilac
Extract, 0.8 part of lignum cinnamomi camphorae extract, 2 parts of mint extracts, 0.2 part of nanometer lanthanum fluoride, 0.6 part of nanometer yttrium fluoride, 2 parts of days
Winter propylhomoserin, 3 parts of limonenes, 18 parts of deionized waters.
(1) modified epoxy soybean oil, emulsion acrylic resin, ester-polyurethane resin emulsion are sequentially added into water, are heated to
70 DEG C and insulated and stirred 12min, obtain material I；
(2) a nanometer lanthanum fluoride, nanometer yttrium fluoride are sequentially added into the material I obtained by step (1), continue to keep the temperature at 70 DEG C
10min is stirred, material II is obtained；
(3) Faeces Passeris extract, lignum cinnamomi camphorae extract, peppermint extraction are sequentially added into the material II obtained by step (2)
Object, aspartic acid, limonene continue, in 70 DEG C of insulated and stirred 5min, to obtain soft leather filler.
Embodiment 12
The preparation method of the soft leather filler of the present embodiment, includes the following steps：
35 parts of emulsion acrylic resins, 33 parts of ester-polyurethane resin emulsions, 24 parts of modified epoxy soybean oils, 4 parts of maleics two
Sour di-sec-octyl sodium sulfonate, 2 parts of fatty alcohol polyoxyethylene ether, 0.4 part of Faeces Passeris extract, 0.8 part of lignum cinnamomi camphorae extract, 2 parts
Mint extract, 2 parts of aspartic acids, 3 parts of limonenes, 18 parts of deionized waters.
(1) modified epoxy soybean oil, emulsion acrylic resin, ester-polyurethane resin emulsion are sequentially added into water, are heated to
70 DEG C and insulated and stirred 12min, obtain material I；
(2) disecoctylmaleate sodium sulfonate, fatty alcohol polyoxy are sequentially added into the material I obtained by step (1)
Vinethene continues, in 70 DEG C of insulated and stirred 10min, to obtain material II；
(3) Faeces Passeris extract, lignum cinnamomi camphorae extract, peppermint extraction are sequentially added into the material II obtained by step (2)
Object, aspartic acid, limonene continue, in 70 DEG C of insulated and stirred 5min, to obtain soft leather filler.
Embodiment 13
The preparation method of the soft leather filler of the present embodiment, includes the following steps：
35 parts of emulsion acrylic resins, 33 parts of ester-polyurethane resin emulsions, 24 parts of modified epoxy soybean oils, 2 parts of poly alkyl alcohols
Ethylene oxide ether, 0.4 part of Faeces Passeris extract, 0.8 part of lignum cinnamomi camphorae extract, 2 parts of mint extracts, 0.2 part of nanometer lanthanum fluoride,
0.6 part of nanometer yttrium fluoride, 2 parts of aspartic acids, 3 parts of limonenes, 18 parts of deionized waters.
(1) modified epoxy soybean oil, emulsion acrylic resin, ester-polyurethane resin emulsion are sequentially added into water, are heated to
70 DEG C and insulated and stirred 12min, obtain material I；
(2) fatty alcohol polyoxyethylene ether, nanometer lanthanum fluoride, nanometer fluorination are sequentially added into the material I obtained by step (1)
Yttrium continues, in 70 DEG C of insulated and stirred 10min, to obtain material II；
(3) Faeces Passeris extract, lignum cinnamomi camphorae extract, peppermint extraction are sequentially added into the material II obtained by step (2)
Object, aspartic acid, limonene continue, in 70 DEG C of insulated and stirred 5min, to obtain soft leather filler.
Performance test：
(1) the soft leather filler in above-described embodiment is applied on leather, antibacterial effect such as 1 institute of table of leather
Show.
The anti-microbial property test data of the soft leather filler of 1 embodiment of table, 1~13 gained
(2) the soft leather filler in above-described embodiment is applied on leather, the performance test results such as table 2 of leather
It is shown.
The performance test data of the soft leather filler of 2 embodiment of table, 1~13 gained
Embodiments of the present invention are explained in detail above in association with attached drawing, but the present invention is not limited to described implementations
Mode.For a person skilled in the art, in the case where not departing from the principle of the invention and spirit, to these embodiments
A variety of change, modification, replacement and modification are carried out, are still fallen in protection scope of the present invention.
Claims (10)
1. a kind of softness leather filler, it is characterised in that：It counts in parts by weight, including the following raw material：
20~50 parts of emulsion acrylic resins, 15~40 parts of ester-polyurethane resin emulsions, 15~30 parts of modified epoxy soybean oils, 2~8
Part bleeding agent, 1~5 part of antiseptic, 0.1~1 part of metal salt, 1~5 part of aspartic acid, 1~5 part of limonene, 15~50 parts of water.
2. softness leather filler according to claim 1, it is characterised in that：The bleeding agent is selected from maleic acid two
One or both of secondary dioctyl sodium sulfosuccinate, fatty alcohol polyoxyethylene ether.
3. softness leather filler according to claim 2, it is characterised in that：The bleeding agent includes maleic acid two
Secondary dioctyl sodium sulfosuccinate, fatty alcohol polyoxyethylene ether, wherein the disecoctylmaleate sodium sulfonate and the poly alkyl alcohol
The weight ratio of ethylene oxide ether is 1~3:1.
4. softness leather filler according to claim 1, it is characterised in that：The antiseptic is extracted selected from white lilac
It is one or more in object, lignum cinnamomi camphorae extract, mint extract.
5. softness leather filler according to claim 4, it is characterised in that：The antiseptic includes white lilac extraction
Object, lignum cinnamomi camphorae extract, mint extract, wherein the Faeces Passeris extract, lignum cinnamomi camphorae extract, mint extract weight
Amount is than being 0.1~0.5:0.2~0.5:1.
6. softness leather filler according to claim 4, it is characterised in that：The Faeces Passeris extract is using following
Method is made：White lilac crushed after being dried to 50~100 mesh is obtained into white lilac powder, adds the white lilac powder weight
The water of 50~80 times of amounts in 60~70 DEG C, 30~35KHz, 30~50min of ultrasound, is filtered to remove precipitation, then do after mixing
It is dry to obtain Faeces Passeris extract.
7. softness leather filler according to claim 4, it is characterised in that：The lignum cinnamomi camphorae extract is using following
Method is made：Lignum cinnamomi camphorae crushed after being dried to 50~80 mesh is obtained into lignum cinnamomi camphorae end, adds and described states lignum cinnamomi camphorae powder weight
The water of 50~80 times of amounts in 60~70 DEG C, 40~45KHz, 30~50min of ultrasound, is filtered to remove precipitation, then do after mixing
It is dry to obtain stating lignum cinnamomi camphorae extract.
8. softness leather filler according to claim 4, it is characterised in that：The mint extract is to use following sides
Method is made：Peppermint crushed after being dried to 40~60 mesh is obtained into peppermint powder, adds 50~80 times of the peppermint powder weight
The water of amount in 50~60 DEG C, 25~30KHz, 30~50min of ultrasound, is filtered to remove precipitation, re-dry obtains thin after mixing
Lotus extract.
9. softness leather filler according to claim 1, it is characterised in that：The metal salt is rare-earth salts, described dilute
Earth salt is one or more in nanometer lanthanum fluoride, nanometer yttrium fluoride, nano yttrium oxide, nano-cerium oxide, nano lanthanum oxide.
10. a kind of preparing the method such as claim 1~9 any one of them softness leather filler, include the following steps：
(1) modified epoxy soybean oil, emulsion acrylic resin, ester-polyurethane resin emulsion are sequentially added into water, it is heated to 60~
80 DEG C and 5~30min of insulated and stirred, obtain material I；
(2) sequentially add bleeding agent, metal salt into the material I obtained by step (1), continue 60~80 DEG C of insulated and stirreds 5~
20min obtains material II；
(3) antiseptic, aspartic acid, limonene are sequentially added into the material II obtained by step (2), continue to protect at 60~80 DEG C
Temperature 3~10min of stirring, obtains soft leather filler.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810475833.1A CN108659644A (en) | 2018-05-17 | 2018-05-17 | A kind of softness leather filler and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810475833.1A CN108659644A (en) | 2018-05-17 | 2018-05-17 | A kind of softness leather filler and preparation method thereof |
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Cited By (3)
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| CN111534650A (en) * | 2020-05-20 | 2020-08-14 | 杭州天龙手袋股份有限公司 | Durable antibacterial soft leather for leather bags and preparation method thereof |
| CN114133779A (en) * | 2021-11-08 | 2022-03-04 | 哈尔滨恒山建筑材料有限公司 | Composition for architectural coating, additive and application thereof |
| CN115948068A (en) * | 2022-12-30 | 2023-04-11 | 百草边大生物科技(青岛)有限公司 | Preparation method of macrobiological functional agent containing masson pine active substances |
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| CN111534650A (en) * | 2020-05-20 | 2020-08-14 | 杭州天龙手袋股份有限公司 | Durable antibacterial soft leather for leather bags and preparation method thereof |
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