CN108748521A - A kind of bamboo product surface anticorrosion coating - Google Patents

A kind of bamboo product surface anticorrosion coating Download PDF

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Publication number
CN108748521A
CN108748521A CN201810715691.1A CN201810715691A CN108748521A CN 108748521 A CN108748521 A CN 108748521A CN 201810715691 A CN201810715691 A CN 201810715691A CN 108748521 A CN108748521 A CN 108748521A
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CN
China
Prior art keywords
product surface
bamboo product
anticorrosion coating
surface anticorrosion
diphosphonic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810715691.1A
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Chinese (zh)
Inventor
孙传庆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Funan County Willow Mingqiang Arts & Crafts Co Ltd
Original Assignee
Funan County Willow Mingqiang Arts & Crafts Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Funan County Willow Mingqiang Arts & Crafts Co Ltd filed Critical Funan County Willow Mingqiang Arts & Crafts Co Ltd
Priority to CN201810715691.1A priority Critical patent/CN108748521A/en
Publication of CN108748521A publication Critical patent/CN108748521A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/12Impregnating by coating the surface of the wood with an impregnating paste
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34Organic impregnating agents
    • B27K3/50Mixtures of different organic impregnating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00Purpose of the treatment

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of bamboo product surface anticorrosion coating, it is related to bamboo product technical field, the 1-hydroxy ethylidene-1,1-diphosphonic acid disodium composite modifier containing its quality 0.8-1.5% in the bamboo product surface anticorrosion coating;Bamboo product surface anticorrosion coating prepared by the present invention has good acidproof and alkaline resistance properties, favorable anti-corrosion effect.

Description

A kind of bamboo product surface anticorrosion coating
Technical field
The invention belongs to bamboo product technical fields, and in particular to a kind of bamboo product surface anticorrosion coating.
Background technology
Bamboo, since growth is fast, material is good, resourceful, is widely used in and makes various daily necessitiess, because rich in bamboo Containing cellulose, hemicellulose, lignin and sugar, fat, wax, protein, minerals etc. can be filled to offers such as moth and termites The nutriment of foot, with the condition that they survive, so, during bamboo product use, easily damage by worms, meanwhile, it is bamboo When in use, surface is easy to aging for product, to the processing of bamboo product in existing method, by providing bamboo product surface coating paint The safeguard procedures of bamboo product, but existing anticorrosion with coat is general, especially resistance to acid and alkali is poor, so that coating makes It is unable to get good guarantee with the service life.
Invention content
The purpose of the present invention is for existing problem, provide a kind of bamboo product surface anticorrosion coating.
The present invention is achieved by the following technical solutions:
A kind of bamboo product surface anticorrosion coating, the hydroxyl second containing its quality 0.8-1.5% in the bamboo product surface anticorrosion coating Pitch Disodium alendronate composite modifier.
Further, the 1-hydroxy ethylidene-1,1-diphosphonic acid disodium composite modifier is made of following component by weight:Hydroxyl Base ethylene-diphosphonic acid disodium 80-82, sodium xylene sulfonate 6-10, glycolic 3-5, diamino monocarboxylate 4-6, zinc chloride 1.2- 1.8, chitosan 1.2-1.4.
Further, the 1-hydroxy ethylidene-1,1-diphosphonic acid disodium composite modifier preparation method is:
(1)1-hydroxy ethylidene-1,1-diphosphonic acid disodium, sodium xylene sulfonate are added in chemical reaction kettle successively, are heated to 80 DEG C, with After 200r/min rotating speeds are stirred 30min, then it is passed through vapor into reaction kettle, is continually fed into 40min;
(2)Stop being passed through vapor to reaction kettle, then adds glycolic, diamino monocarboxylate, chlorination successively into reaction kettle Zinc, chitosan are stirred with 300r/min rotating speeds, and are heated to 150 DEG C, insulation reaction 3 hours, then cooled to room temperature, Attrition grinding, cross 800 mesh sieve to get.
Further, the steam temperature is 100 DEG C.
Further, the bamboo product surface anticorrosion coating is water paint.
Further, the bamboo product surface anticorrosion coating further includes following parts by weight of component:Aqueous polyurethane emulsion 100, hexamethyldisilazane 3, vermiculite power 12, paraffin 6, deionized water 50.
Further, solid content is 45.5% in the aqueous polyurethane emulsion.
Further, the vermiculite Powder Particle Size is 1250 mesh.
The present invention has the following advantages compared with prior art:Bamboo product surface anticorrosion coating prepared by the present invention has good Acidproof and alkaline resistance properties, favorable anti-corrosion effect.A kind of bamboo product surface anticorrosion coating prepared by the present invention has good anti-corrosion Performance and excellent adhesive force, coating is as a kind of mixture of complexity, final performance and ingredient used in it There is directly contact, the present invention can effectively improve painting by reasonably selecting manufacture material composition for type and proportioning The whole performance of material.This coating, for main base matter, passes through a certain amount of hydroxyl second of addition with aqueous polyurethane emulsion Disodium alendronate composite modifier is pitched, modifying function can effectively reduce the degree of polymerization of raw material, the branch link of loose molecule Structure can effectively improve the film forming speed and quality of forming film of coating so that film is even closer, can shield to a certain extent The corrosion factors such as water, oxygen, ion pass through, and cut off the pore in film, the infiltration of corrosion factor have been blocked, to improve The anti-corrosion capability of coating.
Specific implementation mode
Embodiment 1
A kind of bamboo product surface anticorrosion coating, the hydroxy ethylidene two containing its quality 0.8% in the bamboo product surface anticorrosion coating Phosphonic acids disodium composite modifier.
Further, the 1-hydroxy ethylidene-1,1-diphosphonic acid disodium composite modifier is made of following component by weight:Hydroxyl Base ethylene-diphosphonic acid disodium 80, sodium xylene sulfonate 6, glycolic 3, diamino monocarboxylate 4, zinc chloride 1.2, chitosan 1.2.
Further, the 1-hydroxy ethylidene-1,1-diphosphonic acid disodium composite modifier preparation method is:
(1)1-hydroxy ethylidene-1,1-diphosphonic acid disodium, sodium xylene sulfonate are added in chemical reaction kettle successively, are heated to 80 DEG C, with After 200r/min rotating speeds are stirred 30min, then it is passed through vapor into reaction kettle, is continually fed into 40min;
(2)Stop being passed through vapor to reaction kettle, then adds glycolic, diamino monocarboxylate, chlorination successively into reaction kettle Zinc, chitosan are stirred with 300r/min rotating speeds, and are heated to 150 DEG C, insulation reaction 3 hours, then cooled to room temperature, Attrition grinding, cross 800 mesh sieve to get.
Further, the steam temperature is 100 DEG C.
Further, the bamboo product surface anticorrosion coating is water paint.
Further, the bamboo product surface anticorrosion coating further includes following parts by weight of component:Aqueous polyurethane emulsion 100, hexamethyldisilazane 3, vermiculite power 12, paraffin 6, deionized water 50.
Further, solid content is 45.5% in the aqueous polyurethane emulsion.
Further, the vermiculite Powder Particle Size is 1250 mesh.
Embodiment 2
A kind of bamboo product surface anticorrosion coating, the hydroxy ethylidene two containing its quality 1.5% in the bamboo product surface anticorrosion coating Phosphonic acids disodium composite modifier.
Further, the 1-hydroxy ethylidene-1,1-diphosphonic acid disodium composite modifier is made of following component by weight:Hydroxyl Base ethylene-diphosphonic acid disodium 82, sodium xylene sulfonate 10, glycolic 5, diamino monocarboxylate 6, zinc chloride 1.8, chitosan 1.4.
Further, the 1-hydroxy ethylidene-1,1-diphosphonic acid disodium composite modifier preparation method is:
(1)1-hydroxy ethylidene-1,1-diphosphonic acid disodium, sodium xylene sulfonate are added in chemical reaction kettle successively, are heated to 80 DEG C, with After 200r/min rotating speeds are stirred 30min, then it is passed through vapor into reaction kettle, is continually fed into 40min;
(2)Stop being passed through vapor to reaction kettle, then adds glycolic, diamino monocarboxylate, chlorination successively into reaction kettle Zinc, chitosan are stirred with 300r/min rotating speeds, and are heated to 150 DEG C, insulation reaction 3 hours, then cooled to room temperature, Attrition grinding, cross 800 mesh sieve to get.
Further, the steam temperature is 100 DEG C.
Further, the bamboo product surface anticorrosion coating is water paint.
Further, the bamboo product surface anticorrosion coating further includes following parts by weight of component:Aqueous polyurethane emulsion 100, hexamethyldisilazane 3, vermiculite power 12, paraffin 6, deionized water 50.
Further, solid content is 45.5% in the aqueous polyurethane emulsion.
Further, the vermiculite Powder Particle Size is 1250 mesh.
Embodiment 3
A kind of bamboo product surface anticorrosion coating, the 1-hydroxy ethylene-1,1-diphosphonic containing its quality 1% in the bamboo product surface anticorrosion coating Acid disodium composite modifier.
Further, the 1-hydroxy ethylidene-1,1-diphosphonic acid disodium composite modifier is made of following component by weight:Hydroxyl Base ethylene-diphosphonic acid disodium 81, sodium xylene sulfonate 8, glycolic 4, diamino monocarboxylate 5, zinc chloride 1.6, chitosan 1.3.
Further, the 1-hydroxy ethylidene-1,1-diphosphonic acid disodium composite modifier preparation method is:
(1)1-hydroxy ethylidene-1,1-diphosphonic acid disodium, sodium xylene sulfonate are added in chemical reaction kettle successively, are heated to 80 DEG C, with After 200r/min rotating speeds are stirred 30min, then it is passed through vapor into reaction kettle, is continually fed into 40min;
(2)Stop being passed through vapor to reaction kettle, then adds glycolic, diamino monocarboxylate, chlorination successively into reaction kettle Zinc, chitosan are stirred with 300r/min rotating speeds, and are heated to 150 DEG C, insulation reaction 3 hours, then cooled to room temperature, Attrition grinding, cross 800 mesh sieve to get.
Further, the steam temperature is 100 DEG C.
Further, the bamboo product surface anticorrosion coating is water paint.
Further, the bamboo product surface anticorrosion coating further includes following parts by weight of component:Aqueous polyurethane emulsion 100, hexamethyldisilazane 3, vermiculite power 12, paraffin 6, deionized water 50.
Further, solid content is 45.5% in the aqueous polyurethane emulsion.
Further, the vermiculite Powder Particle Size is 1250 mesh.
Comparative example 1:It is differed only in embodiment 1 and 1-hydroxy ethylidene-1,1-diphosphonic acid disodium composite modifier is replaced with into pure hydroxyl Ethylene-diphosphonic acid disodium.
Comparative example 2:It is differed only in 1-hydroxy ethylidene-1,1-diphosphonic acid disodium composite modifier with embodiment 1 and does not add diamino Monocarboxylic acid.
Comparative example 3:It is differed only in embodiment 1 and does not add 1-hydroxy ethylidene-1,1-diphosphonic acid disodium composite modifier.
Respectively use embodiment and comparative example anticorrosive coating, using long 20cm, width 3cm, thickness 2mm bamboo clappers as test Object is brushed using each group coating respectively, keeps other parameters consistent in painting process, is carried out to the bamboo clappers after drying resistance to Soda acid is tested(It is respectively the hydrochloric acid solution that pH is 1.4 and the hydrogen that pH is 11.2 that acid-proof alkaline, which measures the soda acid used, in experiment Sodium hydroxide solution, test temperature are 40 DEG C, and test process is used and is totally submerged), the results are shown in table below:
Table 1
As can be seen from Table 1, the bamboo product surface anticorrosion coating that prepared by the present invention has good acidproof and alkaline resistance properties, anti-corrosion Effect is good.

Claims (8)

1. a kind of bamboo product surface anticorrosion coating, which is characterized in that contain its quality in the bamboo product surface anticorrosion coating The 1-hydroxy ethylidene-1,1-diphosphonic acid disodium composite modifier of 0.8-1.5%.
2. a kind of bamboo product surface anticorrosion coating according to claim 1, which is characterized in that the 1-hydroxy ethylidene-1,1-diphosphonic acid Disodium composite modifier is made of following component by weight:1-hydroxy ethylidene-1,1-diphosphonic acid disodium 80-82, sodium xylene sulfonate 6- 10, glycolic 3-5, diamino monocarboxylate 4-6, zinc chloride 1.2-1.8, chitosan 1.2-1.4.
3. a kind of bamboo product surface anticorrosion coating according to claim 2, which is characterized in that the 1-hydroxy ethylidene-1,1-diphosphonic acid Disodium composite modifier preparation method is:
(1)1-hydroxy ethylidene-1,1-diphosphonic acid disodium, sodium xylene sulfonate are added in chemical reaction kettle successively, are heated to 80 DEG C, with After 200r/min rotating speeds are stirred 30min, then it is passed through vapor into reaction kettle, is continually fed into 40min;
(2)Stop being passed through vapor to reaction kettle, then adds glycolic, diamino monocarboxylate, chlorination successively into reaction kettle Zinc, chitosan are stirred with 300r/min rotating speeds, and are heated to 150 DEG C, insulation reaction 3 hours, then cooled to room temperature, Attrition grinding, cross 800 mesh sieve to get.
4. a kind of bamboo product surface anticorrosion coating according to claim 2, which is characterized in that the steam temperature is 100℃。
5. a kind of bamboo product surface anticorrosion coating according to claim 1, which is characterized in that the bamboo product surface anticorrosion Coating is water paint.
6. a kind of bamboo product surface anticorrosion coating according to claim 1 or 5, which is characterized in that the bamboo product surface Anticorrosive paint further includes following parts by weight of component:Aqueous polyurethane emulsion 100, hexamethyldisilazane 3, vermiculite power 12, paraffin 6, deionized water 50.
7. a kind of bamboo product surface anticorrosion coating according to claim 6, which is characterized in that the aqueous polyurethane emulsion Middle solid content is 45.5%.
8. a kind of bamboo product surface anticorrosion coating according to claim 6, which is characterized in that the vermiculite Powder Particle Size is 1250 mesh.
CN201810715691.1A 2018-07-03 2018-07-03 A kind of bamboo product surface anticorrosion coating Pending CN108748521A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810715691.1A CN108748521A (en) 2018-07-03 2018-07-03 A kind of bamboo product surface anticorrosion coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810715691.1A CN108748521A (en) 2018-07-03 2018-07-03 A kind of bamboo product surface anticorrosion coating

Publications (1)

Publication Number Publication Date
CN108748521A true CN108748521A (en) 2018-11-06

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810715691.1A Pending CN108748521A (en) 2018-07-03 2018-07-03 A kind of bamboo product surface anticorrosion coating

Country Status (1)

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CN (1) CN108748521A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008221742A (en) * 2007-03-15 2008-09-25 Fukushima Prefecture Method for reinforcing the surface of wooden materials
CN106349908A (en) * 2016-08-31 2017-01-25 安徽阜南县万家和工艺品有限公司 High-performance wickerwork coating
CN106634393A (en) * 2015-08-13 2017-05-10 姹ゅ浆 Novel waterborne baking varnish
CN107022187A (en) * 2017-03-21 2017-08-08 王正恒 A kind of compound polyurethane material of waterproof and its preparation method and application

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008221742A (en) * 2007-03-15 2008-09-25 Fukushima Prefecture Method for reinforcing the surface of wooden materials
CN106634393A (en) * 2015-08-13 2017-05-10 姹ゅ浆 Novel waterborne baking varnish
CN106349908A (en) * 2016-08-31 2017-01-25 安徽阜南县万家和工艺品有限公司 High-performance wickerwork coating
CN107022187A (en) * 2017-03-21 2017-08-08 王正恒 A kind of compound polyurethane material of waterproof and its preparation method and application

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Application publication date: 20181106