CN108998974A - A kind of preparation method of ultraviolet protection curtain fabric - Google Patents
A kind of preparation method of ultraviolet protection curtain fabric Download PDFInfo
- Publication number
- CN108998974A CN108998974A CN201811054579.4A CN201811054579A CN108998974A CN 108998974 A CN108998974 A CN 108998974A CN 201811054579 A CN201811054579 A CN 201811054579A CN 108998974 A CN108998974 A CN 108998974A
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- CN
- China
- Prior art keywords
- fabric
- ultraviolet
- fabric blank
- absorbing agent
- benzotriazole
- Prior art date
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- 239000004744 fabric Substances 0.000 title claims abstract description 72
- 230000006750 UV protection Effects 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000000835 fiber Substances 0.000 claims abstract description 28
- 239000006096 absorbing agent Substances 0.000 claims abstract description 25
- 229920002334 Spandex Polymers 0.000 claims abstract description 12
- 239000004759 spandex Substances 0.000 claims abstract description 12
- 102000014171 Milk Proteins Human genes 0.000 claims abstract description 11
- 108010011756 Milk Proteins Proteins 0.000 claims abstract description 11
- 235000021239 milk protein Nutrition 0.000 claims abstract description 11
- 239000004952 Polyamide Substances 0.000 claims abstract description 10
- 229920002647 polyamide Polymers 0.000 claims abstract description 10
- 238000005470 impregnation Methods 0.000 claims abstract description 9
- -1 benzene ketone compounds Chemical class 0.000 claims description 26
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 26
- 239000012964 benzotriazole Substances 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 14
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 11
- 239000003063 flame retardant Substances 0.000 claims description 9
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 4
- 238000005660 chlorination reaction Methods 0.000 claims description 4
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 claims description 2
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 claims description 2
- 238000007598 dipping method Methods 0.000 claims 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims 1
- 229960004889 salicylic acid Drugs 0.000 claims 1
- 239000002250 absorbent Substances 0.000 abstract description 5
- 230000002745 absorbent Effects 0.000 abstract description 5
- 230000009286 beneficial effect Effects 0.000 abstract description 4
- 230000035699 permeability Effects 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 3
- 230000000116 mitigating effect Effects 0.000 abstract description 2
- 230000008520 organization Effects 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract description 2
- 238000010521 absorption reaction Methods 0.000 description 10
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 7
- 238000004043 dyeing Methods 0.000 description 6
- 239000000975 dye Substances 0.000 description 5
- 230000004224 protection Effects 0.000 description 5
- 230000000903 blocking effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 235000013336 milk Nutrition 0.000 description 3
- 239000008267 milk Substances 0.000 description 3
- 210000004080 milk Anatomy 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 201000009030 Carcinoma Diseases 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000021120 animal protein Nutrition 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000013527 degreasing agent Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 208000017983 photosensitivity disease Diseases 0.000 description 1
- 230000021715 photosynthesis, light harvesting Effects 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/137—Acetals, e.g. formals, or ketals
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/38—Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Curtains And Furnishings For Windows Or Doors (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of preparation methods of ultraviolet protection curtain fabric, including fabric blank is carried out impregnation in ultraviolet absorbing agent, then carry out high temperature thermal finalization, obtain the ultraviolet protection curtain fabric.In the preferred scheme, which has elasticity and translucency using polyamide fibre and spandex as organization material polymer；Milk protein fiber is also used, there is gas permeability and glossiness.It can be used simultaneously organic uv absorbers and inorganic ultraviolet absorbent in the fabric, ultraviolet light 99% can be kept out, while mitigating infrared ray, the visible light for effectively leaving natural beneficial acts on interior.
Description
Technical field
The present invention relates to textile processing technical fields, and in particular to a kind of preparation method of ultraviolet protection curtain fabric.
Background technique
The main function of curtain is to be isolated from the outside world, and keeps the privacy in room, while it is that house ornamentation is indispensable again
Ornament.Modern curtain both can be with dim light, shading, to adapt to demand of the people to light varying strength；Can prevent fires again, is windproof,
Dedusting, warming, noise elimination, heat-insulated, radiation protection, antiultraviolet etc., improve room weather and environment.Therefore, decorative and practicability
Ingenious combination, be the greatest feature of modern curtain.
Due to the destruction of earth's ozone layer, the intensity of the ultraviolet light in sunlight is more and more stronger.Ultraviolet light strong effect is in skin
When skin, photodermatitis can be caused, occur erythema on skin, itch, blister, oedema etc., it is serious also to cause cutaneum carcinoma.For a long time
Through sun light direct beam, furnishings accelerated ageing can also be promoted to fade.In order to be lowered into indoor ultraviolet light to human body and
There is the ultraviolet protection curtain that primary raw material is flat filament at present in the injury of furniture.The section of flat filament is triangle, is passed through
Weaving process continuously regularly forms the small prism of triangular pyramidal on fabric.Incident light is reflected in each face of small prism, thus
Most ultraviolet reflection is gone out, the function of antiultraviolet is formed.But the window curtain fabric mainly passes through physical reflection
Principle shielding ultraviolet rays, the ultraviolet light reflected from different perspectives can also enter the room, cannot thoroughly play stop it is ultraviolet
The effect of line.
In consideration of it, the present invention is specifically proposed.
Summary of the invention
The purpose of the present invention is to provide a kind of preparation methods of ultraviolet protection curtain fabric.
To achieve the above object, technical scheme is as follows:
The present invention relates to a kind of preparation methods of ultraviolet protection curtain fabric, including by fabric blank in ultraviolet absorbing agent
Then middle carry out impregnation carries out high temperature thermal finalization, obtains the ultraviolet protection curtain fabric.
Preferably, first the fabric blank is dyed, impregnation is then carried out in ultraviolet absorbing agent.
Preferably, the fabric blank is the blended fabric of polyamide fibre and spandex, and the weight ratio of the two is (70~90): (10
~30).
Preferably, the fabric blank also contains milk protein fiber, the weight of the polyamide fibre, spandex and milk protein fiber
Amount is than being (70~90): (10~30): (5~10).
Preferably, the ultraviolet absorbing agent used is selected from salicylic acid compounds, benzene ketone compounds, benzotriazole
Close at least one of object, cyanoacrylate acids compound.
Preferably, the salicylic acid compounds are septichen phenyl ester, and the benzene ketone compounds are selected from 2,4-
At least one of dihydroxy benaophenonel, ESCALOL 567,2-hydroxy-4-n-octoxybenzophenone,
The benzotriazole compound is selected from 2- (2 '-hydroxyls -3 ', 5 '-two tertiary phenyl) -5- chlorination benzotriazole, 2- (2 '-hydroxyls -
At least one of 5 '-aminomethyl phenyls) benzotriazole.
Preferably, use benzene ketone compounds and/or benzotriazole compound as ultraviolet absorbing agent.
Preferably, the weight ratio of benzene ketone compounds and benzotriazole compound is (1~5): 1.
Preferably, after fabric blank being carried out impregnation in ultraviolet absorbing agent, then the fabric blank impregnated
Final finishing is carried out in post-finishing liquid.
Preferably, in the post-finishing liquid contain following parts by weight raw material: 1~5 part of fire retardant, silane coupling agent 1~
10 parts, 1~5 part of nano-titanium dioxide.
Preferably, the condition of high temperature thermal finalization are as follows: 1~5min is toasted at 150~170 DEG C.
Beneficial effects of the present invention:
The present invention provides a kind of ultraviolet protection curtain fabrics to have using polyamide fibre and spandex as organization material polymer
Elasticity and translucency.Milk protein fiber is also used in the preferred scheme, and there is gas permeability and glossiness.It can in the fabric
Organic uv absorbers and inorganic ultraviolet absorbent are used simultaneously, can keep out ultraviolet light 99%, while mitigating infrared ray,
The visible light for effectively leaving natural beneficial acts on interior.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, technical solution of the present invention will be carried out below
Detailed description.Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Base
Embodiment in the present invention, those of ordinary skill in the art are obtained all without making creative work
Other embodiment belongs to the range that the present invention is protected.
The present embodiments relate to a kind of preparation methods of ultraviolet protection curtain fabric, including by fabric blank in ultraviolet light
Impregnation is carried out in absorbent, is then carried out high temperature thermal finalization, is obtained ultraviolet protection curtain fabric of the invention.
In one embodiment of the invention, first fabric blank is dyed, then inhales fabric blank in ultraviolet light
It receives in agent and carries out impregnation.If first carrying out UV absorption processing to dye again, ultraviolet absorbing agent can be lost in coloring agent,
And coloring agent can wrap up ultraviolet absorbing agent, decline ultraviolet absorption ability.
In one embodiment of the invention, the temperature of dyeing is 80~100 DEG C, and soaking time is 1.5~3h.More preferably
Fabric blank is placed in dye liquor at room temperature, then carries out being warming up to dyeing temperature with the speed of 0.1 DEG C/min.The dye used
Material can be iridescent cream, such as red, orange, yellow, green, blue, indigo, purple color.Nontoxic fluorescent chemicals also have absorption to light
Ability, and can further be converted to ultraviolet light beneficial to coloured light, reduce injury of the natural light to human body.
In one embodiment of the invention, before dyeing, washing first is carried out with fixed to fabric blank, it is therefore an objective to remove
The greasy dirt and electrostatic on fabric blank surface, in order to avoid influence dyeing effect.Further, washing, which is matched, is scheduled on electrostatic degreaser, such as
It is carried out in the solution of M700.
In one embodiment of the invention, fabric blank is the blended fabric of polyamide fibre and spandex, and the weight ratio of the two is
(70~90): (10~30), preferably 85:15.The content of spandex is too small, the rebound degree decline of fabric blank, retractility and intensity
It is bad.The content of spandex is excessive, and the integral strength of fabric blank can be made to reduce, and the easy fracture after stretching and folding are scratched leads to curtain
The intensity of fabric is declined.
In one embodiment of the invention, fabric blank also contains milk protein fiber.Milk protein fiber is with ox
Cream is used as base stock, by dehydration, de-oiling, degreasing, separation, purification, makes a kind of with linear macromolecule structure
Milk casein.It is blended, is crosslinked, is grafted using high-tech means with polyacrylonitrile again, be prepared into spinning solution.Finally by
Wet spinning is at made of fibre, solidification, drawing-off, drying, curling, setting, staple fiber cutting (winding filament).It is a kind of different
In the novel animal protein fibre of natural fiber, regenerated fiber and synthetic fibers, also known as milk filaments or milk fibre.Its advantage
It is with graceful natural gloss, good flexibility, skin-friendly, gas permeability and warmth retention property.Also, milk protein fiber is resistance to
Mill property, is strongly superior to wool at anti-pilling, coloring, is a kind of artificial fiber with excellent properties.But due to its cost
Much higher than polyamide fibre and spandex, the additive amount in fabric blank should not be excessive.When the weight of polyamide fibre, spandex and milk protein fiber
Amount than be (70~90): (10~30): when (5~10), the window curtain fabric being prepared will have good reflecting feel and thoroughly
Gas.
In one embodiment of the invention, using organic ultraviolet absorbing agent, realize window curtain fabric to ultraviolet light
Absorption.Contain hydroxyl in the structure of matter, stablizes the absorption ultraviolet energy in the process such as hydrogen bond, hydrogen bond chelate ring being formed
And it is transformed into heat energy dissipation.The ultraviolet absorbing agent that the present invention uses be selected from salicylic acid compounds, benzene ketone compounds,
At least one of benzotriazole compound, cyanoacrylate acids compound.Wherein, effective absorption of salicylic acid compounds
Wavelength is 290-330nm；Effective absorbing wavelength of benzene ketone compounds is 280-340nm and two kinds of 270-380nm；Benzotriazole
Effective absorbing wavelength of class compound is 270-380nm；Effective absorbing wavelength of cyanoacrylate acids compound is 270-
350nm。
Further, salicylic acid compounds are septichen phenyl ester, and benzene ketone compounds are selected from 2,4- dihydroxy
Benzophenone (UV-O), ESCALOL 567 (UV-9), 2-hydroxy-4-n-octoxybenzophenone (UV-
At least one of 531), benzotriazole compound is selected from 2- (2 '-hydroxyls -3 ', 5 '-two tertiary phenyl) -5- chlorination benzo three
At least one of azoles (UVP-327), 2- (2 '-hydroxyls -5 '-aminomethyl phenyl) benzotriazole (UV-P).
Applicants have found that while using benzophenone compound and benzene ketone compounds as ultraviolet absorbing agent
When, there is best ultraviolet absorption effect.It is preferred that the weight ratio of the two is (1~5): 1.Fabric blank after sizing is carried out purple
Outer absorption processing, is to impregnate fabric blank in the feed liquid containing ultraviolet absorbing agent, absorbent is dense in feed liquid
Degree is 1~10 mass %, preferably 2~5 mass %.
In one embodiment of the invention, after fabric blank being carried out impregnation in ultraviolet absorbing agent, then will
Fabric blank, which is impregnated in post-finishing liquid, carries out final finishing.The temperature of post-finishing liquid can be 50~55 DEG C, and fabric blank is with after
The weight ratio of finishing fluid can be (15~30): (100~200), utilize the removing of lye discharging machine extra after impregnating 10~20min
Post-finishing liquid, repeat the process 1~3 time, that is, complete fabric blank final finishing.
Further, in post-finishing liquid contain following parts by weight raw material: 1~5 part of fire retardant, silane coupling agent 1~10
Part, 1~5 part of nano-titanium dioxide.
The preferred FRC fire-retardant agent of fire retardant, silane coupling agent are selected from A151 (vinyltriethoxysilane), A171
At least one of (vinyltrimethoxysilane), A172 (vinyl three (beta-methoxy ethyoxyl) silane), nanometer titanium dioxide
The partial size of titanium is 30~80nm.Nano-titanium dioxide can be used as inorganic ultraviolet reflection agent, is reflected ultraviolet light and is dissipated
It penetrates to prevent it through fabric, plays the role of physical sunscreen.
In one embodiment of the invention, the condition of high temperature thermal finalization is that 1~5min is toasted at 150~170 DEG C.Tool
Body be by fabric blank in heating room through Hot-blast Heating, envelope degree is stretched to certain size, heats out cooling behind room, and temperature drops
To the glass transition temperature of fiber, to reach stable dimensions.Purpose using high temperature thermal finalization is the physics for making fabric blank
It is more stable with chemical property, such as: shrink, breadth etc. are not easy to change, and cloth cover is also more smooth.Meanwhile in this work of being formed
Some functional processing, such as waterproof, softness, fire-retardant etc. can also be carried out in section.
The ultraviolet protection curtain fabric being prepared by the above method not only has the function of blocking ultraviolet light, also have
The soft comfortable sense of touch of preferable elasticity, gas permeability and clothing.
Embodiment
A kind of preparation method of ultraviolet protection curtain fabric, comprising the following steps:
(1) fabric blank wash matching using M700 solution and be determined, to remove the greasy dirt and electrostatic on surface.Wherein, it knits
The raw material type of object fabric, each weight ratio of constituents are shown in Table 1.
(2) fabric blank is placed in dye liquor, carries out being warming up to 90 DEG C with the speed of 0.1 DEG C/min, to fabric blank into
Row dyeing and drying.Dyestuff used is fluorescence color.
(3) UV absorption processing is carried out to the fabric blank after dyeing drying.Available ultraviolet absorbing agent includes: 2,4-
Dihydroxy benaophenonel (UV-O), ESCALOL 567 (UV-9), 2-hydroxy-4-n-octoxybenzophenone
(UV-531), 2- (2 '-hydroxyls -3 ', 5 '-two tertiary phenyl) -5- chlorination benzotriazole (UVP-327), 2- (2 '-hydroxyls -5 '-first
Base phenyl) benzotriazole (UV-P).The specific type of ultraviolet absorbing agent is shown in Table 1.Ultraviolet absorbing agent is dense in feed liquid
Degree is 5 mass %.
(4) final finishing is carried out to UV absorption treated fabric blank, the temperature of post-finishing liquid is 55 DEG C, fabric blank
Weight ratio with post-finishing liquid is 20:150, utilizes lye discharging machine to remove extra post-finishing liquid after impregnating 20min, and repeating should
Process 2 times, that is, complete the final finishing of fabric blank.The reagent used is shown in Table 1.
(5) by UV absorption, treated that fabric blank is placed in that heating is indoor, toasted at 150~170 DEG C 1~5min into
Row high temperature thermal finalization, reaches stable dimensions, and examine firmness.
Table 1
In table 1, "-" expression does not carry out the operation.
The test of fire-retardant and ultraviolet resistance is carried out to Uvr Protective Fabric prepared in the above embodiments, the results are shown in Table 2.
Table 2
In conjunction with Tables 1 and 2 as can be seen that embodiment 1-1 to 1-5 all has preferable flame retardant property and anti-uv
Energy.Ultraviolet light blocking rate is 96% or more.When using bi-component organic uv absorbers, UV resistance can be further promoted
Linearly can, ultraviolet light blocking rate is close to 99%.Embodiment 1-10 using organic and inorganic UV absorbent, has best simultaneously
Ultraviolet resistance.
Embodiment 1-6 and 1-7 change the amount ratio of polyamide fibre and spandex, flame retardant property and ultraviolet resistance under
Drop, but still in preferable range.
Embodiment 1-8 and 1-9 do not carry out final finishing, i.e., not to window curtain fabric carrying inorganic ultraviolet absorbing agent, therefore
Ultraviolet light blocking rate is declined.
Embodiment 1-9 and 1-10 joined milk protein fiber in fabric, not have shadow to anti-flammability and sun-proof performance
It rings, but the glossiness and flexibility of fabric can be significantly improved.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
Those familiar with the art in the technical scope disclosed by the present invention, can easily think of the change or the replacement, and should all contain
Lid is within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.
Claims (10)
1. a kind of preparation method of ultraviolet protection curtain fabric, which is characterized in that including by fabric blank in ultraviolet absorbing agent
Then middle carry out impregnation carries out high temperature thermal finalization, obtains the ultraviolet protection curtain fabric.
2. the method according to claim 1, wherein first being dyed to the fabric blank, then ultraviolet
Impregnation is carried out in light absorbers.
3. the method according to claim 1, wherein the fabric blank be polyamide fibre and spandex blended fabric,
The weight ratio of the two is (70~90): (10~30).
4. described according to the method described in claim 3, it is characterized in that, the fabric blank also contains milk protein fiber
The weight ratio of polyamide fibre, spandex and milk protein fiber is (70~90): (10~30): (5~10).
5. the method according to claim 1, wherein the ultraviolet absorbing agent used is selected from salicylic acid chemical combination
At least one of object, benzene ketone compounds, benzotriazole compound, cyanoacrylate acids compound.
6. according to the method described in claim 5, it is characterized in that, the salicylic acid compounds are septichen benzene
Ester, the benzene ketone compounds are being selected from 2,4-DihydroxyBenzophenone, ESCALOL 567,2- hydroxyl -4- just
At least one of octyloxybenzophenone, the benzotriazole compound are selected from 2- (2 '-hydroxyls -3 ', 5 '-two tertiary benzene
Base) -5- chlorination benzotriazole, at least one of 2- (2 '-hydroxyls -5 '-aminomethyl phenyl) benzotriazole.
7. according to the method described in claim 6, it is characterized in that, using benzene ketone compounds and/or benzotriazole chemical combination
Object is (1~5) as ultraviolet absorbing agent, the weight ratio of the two: 1.
8. the method according to claim 1, wherein fabric blank is carried out at dipping in ultraviolet absorbing agent
After reason, then the fabric blank is impregnated in post-finishing liquid and carries out final finishing.
9. according to the method described in claim 8, it is characterized in that, containing the raw material of following parts by weight in the post-finishing liquid:
1~5 part of fire retardant, 1~10 part of silane coupling agent, 1~5 part of nano-titanium dioxide.
10. the method according to claim 1, wherein the condition of high temperature thermal finalization are as follows: dried at 150~170 DEG C
Roasting 1~5min.
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| CN110359269A (en) * | 2019-08-07 | 2019-10-22 | 李小虎 | A method of improving umbrella cloth ultraviolet resistance |
| CN110948970A (en) * | 2019-12-03 | 2020-04-03 | 温州安戈警用装备有限公司 | Anti-ultraviolet fabric and processing method thereof |
| CN111235723A (en) * | 2020-01-14 | 2020-06-05 | 义乌市顺泰纺织科技有限公司 | Hyaluronic acid fabric and manufacturing method thereof |
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| CN112160171A (en) * | 2020-09-17 | 2021-01-01 | 广州市白云区新生实业有限公司 | Grass-proof cloth and preparation method thereof |
| CN113293611A (en) * | 2021-04-20 | 2021-08-24 | 杭州拓路者服饰有限公司 | Preparation method of sun-proof fabric |
| CN116377641A (en) * | 2023-03-14 | 2023-07-04 | 佛山市摩力克家居布业有限公司 | A kind of processing method of anti-ultraviolet sunscreen curtain |
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Application publication date: 20181214 |