CN109096830A - A kind of anti-pollution latex paint preparation method - Google Patents

A kind of anti-pollution latex paint preparation method Download PDF

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Publication number
CN109096830A
CN109096830A CN201810676621.XA CN201810676621A CN109096830A CN 109096830 A CN109096830 A CN 109096830A CN 201810676621 A CN201810676621 A CN 201810676621A CN 109096830 A CN109096830 A CN 109096830A
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parts
agent
pollution
mixture
latex paint
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肖坤学
李光明
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Guizhou Paint Jinzhou Paint Co Ltd
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Guizhou Paint Jinzhou Paint Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D101/00Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
    • C09D101/08Cellulose derivatives
    • C09D101/26Cellulose ethers
    • C09D101/28Alkyl ethers
    • C09D101/286Alkyl ethers substituted with acid radicals
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • C09D5/024Emulsion paints including aerosols characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • C09D5/024Emulsion paints including aerosols characterised by the additives
    • C09D5/025Preservatives, e.g. antimicrobial agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of anti-pollution latex paint preparation methods, the anti-pollution latex paint includes the raw material of following parts by weight: 10-18 parts of sodium carboxymethylcellulose, 50-150 parts of titanium dioxide, it is titanium valve 5-35 parts high, 1-8 parts of bunt gypsum powder, 3-15 parts of film forming agent, 2-40 parts of calcium-free fillers, 1-38 parts of talcum powder, 5-40 parts of diatomite, 1-9 parts of mica powder, 3-18 parts of nano zine oxide, 2-7 parts of defoaming agent, 1-9 parts of dispersing agent, 2-10 parts of antifreezing agent, 3-15 parts of anti-flooding agent, 5-15 parts of antioxidant, 2-12 parts of anti-pollution auxiliary agent of nanometer, 2-9 parts of deionized water, 2-5 parts of acrylate cream, 18-25 parts of additive.Sodium carboxymethylcellulose, titanium dioxide and high titanium valve are added in the present invention into anti-pollution latex paint, to providing a large amount of oxidation material in anti-pollution latex paint, be conducive to carry out oxygenolysis to dirt to anti-pollution latex paint, add suitable Honegsukle flower P.E, improve the fragrance of anti-pollution latex paint.

Description

A kind of anti-pollution latex paint preparation method
Technical field
The invention belongs to emulsion paint technical field more particularly to a kind of anti-pollution latex paint preparation methods.
Background technique
Emulsion paint is being commonly called as latex paint, is born in mid-to-late 1970s, is with acrylic ester copolymer Lotion is a major class synthetic resin emulsion coating of representative.Emulsion paint is water-dispersible paint, it is to be with synthetic resin emulsion The refined coating of various auxiliary agents is added in base-material, filler after grinding distribution.Emulsion paint has and traditional metope coating Different many merits, such as being easy to, brushing, drying is rapid, paint film is water-fast, scrub resistance is good.In China, people traditionally Synthetic resin emulsion is base-material, using water as decentralized medium, pigment, filler (also known as extender pigment) and auxiliary agent is added, through certain work Coating made of skill process is called emulsion paint, is also latex paint.
Exterior wall latex paint is a kind of coating using macromolecule emulsion as film forming matter, and easy for construction, environmental pollution is small, application It is relatively broad.Exterior wall latex paint belongs to construction material, usually to consider mechanical property, antifouling property, wear-resisting property, health to it Performance, flexility, anti-width penetrate energy, waterproof performance, appearance property, production, workability and environmental-protecting performance etc..Exterior wall cream at present Shellac varnish anti-stain characteristic is poor, seriously affects appearance and other performance;It wears no resistance, is also easy to produce scratch etc., once stain or dirty spot print On wall, it will be difficult to wipe, and scrubbing resistance, service life is not short for common interiro wall latex paint.
Summary of the invention
The present invention in view of the above technical problems, provides a kind of anti-pollution latex paint preparation method.
The technical scheme adopted by the invention is as follows: a kind of anti-pollution latex paint preparation method, the anti-pollution latex paint include with The raw material of lower parts by weight: 10-18 parts of sodium carboxymethylcellulose, 50-150 parts of titanium dioxide, titanium valve 5-35 parts high, bunt gypsum powder 1-8 It is part, 3-15 parts of film forming agent, 2-40 parts of calcium-free fillers, 1-38 parts of talcum powder, 5-40 parts of diatomite, 1-9 parts of mica powder, nano oxidized 3-18 parts of zinc, 1-9 parts of dispersing agent, 2-10 parts of antifreezing agent, 3-15 parts of anti-flooding agent, 5-15 parts of antioxidant, is received 2-7 parts of defoaming agent Rice 2-12 parts of anti-pollution auxiliary agent, 2-9 parts of deionized water, 2-5 parts of acrylate cream, 18-25 parts of additive;The anti-pollution latex paint Preparation method the following steps are included:
S1, homogeneous: sodium carboxymethylcellulose is weighed according to deal proportion, sodium carboxymethylcellulose and additive are poured into band Have in the homogenizer of temperature control system, the temperature of homogenizer is controlled at 150 DEG C -180 DEG C and stirred 25-40 minutes, is obtained Mixture A;
S2, removal of impurities: weighing high titanium valve, deionized water and acrylate cream according to deal proportion, high titanium valve cleaned removal of impurities, Then high titanium valve is screened into 30-50 mesh by screening machine, the high titanium valve after screening is put into container and deionized water is added With acrylate cream, is stirred 3-6 minutes with blender, obtain mixture B;
S3, refining: bunt gypsum powder, film forming agent, calcium-free fillers, talcum powder, diatomite, mica are weighed according to deal proportion Powder, nano zine oxide, defoaming agent, dispersing agent, antifreezing agent, anti-flooding agent, antioxidant and nanometer anti-pollution auxiliary agent, by bunt gypsum powder, Film forming agent, calcium-free fillers, talcum powder, diatomite, mica powder, nano zine oxide, defoaming agent, dispersing agent, antifreezing agent, anti-loose colour Agent, antioxidant and nanometer anti-pollution auxiliary agent are soaked in water 2-4 days, and soak is then carried out refining 2-6 hours with boiler, will be refined Solution afterwards is precipitated, and is filtered with sand stick filter, is removed the impurity in solution, is obtained mixture C;
S4, heat treatment: titanium dioxide is weighed according to deal proportion, titanium dioxide is poured into boiler, with 100-120 DEG C of high temperature pair It is heated, and heating time is 3-5 minutes, obtains mixture D;
S5, preheating: the half of mixture A is poured into preheating can, with preheating temperature 10-20 minutes of 60-80 DEG C, Mixture B is poured into preheating can after preheating, with identical preheating temperature 3-8 minutes, is then fallen remaining mixture A Enter in preheating can, the temperature of preheating can is controlled at 150-300 DEG C, heats 1-3 hours, obtains mixture E;
S6, water is removed;Mixture C and mixture D are added in centrifuge and carry out centrifugal dehydration, obtains sticky mixture F
Mixture E and mixture F are added in blender by S7, mixing, and mixture E and mixture F are mixed.
Preferably, the anti-pollution latex paint includes the raw material of following parts by weight: the anti-pollution latex paint includes following weight Part raw material: 14-16 parts of sodium carboxymethylcellulose, 90-110 parts of titanium dioxide, titanium valve 10-30 parts high, 4-6 parts of bunt gypsum powder, at 9-11 parts of film, 10-30 parts of calcium-free fillers, 10-30 parts of talcum powder, 10-30 parts of diatomite, 4-6 parts of mica powder, nano zine oxide 9-11 parts, 4-6 parts of defoaming agent, 4-6 parts of dispersing agent, 4-6 parts of antifreezing agent, 4-6 parts of anti-flooding agent, 9-11 parts of antioxidant, nanometer it is anti- Dirty auxiliary agent 4-6 parts, 5-7 parts of deionized water, 3-5 parts of acrylate cream, 18-25 parts of additive.
Preferably, 15 parts of sodium carboxymethylcellulose, 100 parts of titanium dioxide, 20 parts of high titanium valve, 5 parts of bunt gypsum powder, film forming agent 10 Part, 20 parts of calcium-free fillers, 20 parts of talcum powder, 20 parts of diatomite, 5 parts of mica powder, 10 parts of nano zine oxide, 5 parts of defoaming agent, dispersion 5 parts of agent, 5 parts of antifreezing agent, 5 parts of anti-flooding agent, 10 5 parts of part, nanometer anti-pollution auxiliary agent of antioxidant, 6 parts of deionized water, acrylate cream 4 parts, 18-25 parts of additive.
Preferably, the additive is wolf tail grass extract, modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium, institute Stating the laurel alcohol ether phosphate potassium content in additive is 30%.
Preferably, the talcum powder, diatomite, mica powder weight ratio be 1-38:5-40:5-40.
Preferably, the antifreezing agent, anti-flooding agent, antioxidant weight ratio be 2-10:3-15:5-15.
Preferably, the bunt gypsum powder, film forming agent, calcium-free fillers, talcum powder, diatomite, mica powder, nano zine oxide, Defoaming agent, dispersing agent, antifreezing agent, anti-flooding agent, antioxidant and nanometer anti-pollution auxiliary agent are soaked in water 3 days.
Preferably, in the S4, titanium dioxide is weighed according to deal proportion, titanium dioxide is poured into boiler, with 110 DEG C of high temperature It is heated, heating time is 4 minutes, obtains mixture D.
The invention has the benefit that
1, sodium carboxymethylcellulose, titanium dioxide and high titanium valve are added into anti-pollution latex paint, to providing in anti-pollution latex paint A large amount of oxidation material is conducive to carry out oxygenolysis to dirt to anti-pollution latex paint;
2, the tannin in wolf tail grass extract plays condensation to dicalcium powder, improves poly- between coarse whiting powder particles Cooperation is used, and can be improved the cementitiousness of emulsion paint film after so that dicalcium powder is added to emulsion paint preparation process, on compact film A large amount of fine, soft fur holes, improve the hardness and compactness of paint film, meanwhile, tannin can reduce surface of the paint film tension, can reduce painting Film enhances emulsion paint surface coating intensity to the adsorptivity of pollutant after being added to dicalcium powder in emulsion paint preparation process, To improve the contaminated resistance of emulsion paint;
3, suitable Honegsukle flower P.E is added, the fragrance of anti-pollution latex paint is improved;
4, sodium carbonate and calcium chloride are sequentially added by modified Honegsukle flower P.E during the preparation process, the two is in reactant The calcium carbonate generated in system generates one and reacts to each other or be complexed with the fractions of additive, generates light calcium to change Surface nature can increase substantially the contaminated resistance of emulsion paint in this way when it is added in emulsion paint;
5, wolf tail grass extract, the various enzymes being modified in Honegsukle flower P.E, wherein the oxidizing component contained can be one The growth for inhibiting bacterium in degree is determined, to improve the anti-microbial property and pollution resistance of emulsion paint.
Specific embodiment
Combined with specific embodiments below the present invention is made further to explain.
Embodiment 1
A kind of anti-pollution latex paint preparation method, the anti-pollution latex paint include the raw material of following parts by weight: carboxymethyl cellulose 10 parts of plain sodium, 50 parts of titanium dioxide, 5 parts of high titanium valve, 1 part of bunt gypsum powder, 3 parts of film forming agent, 2 parts of calcium-free fillers, 1 part of talcum powder, silicon 5 parts of diatomaceous earth, 3 parts of nano zine oxide, 2 parts of defoaming agent, 1 part of dispersing agent, 2 parts of antifreezing agent, 3 parts of anti-flooding agent, resists 1 part of mica powder 52 parts of part, nanometer anti-pollution auxiliary agent of oxygen agent, 2 parts of deionized water, 2 parts, 18 parts of additive of acrylate cream;The preparation of anti-pollution latex paint Method the following steps are included:
S1, homogeneous: sodium carboxymethylcellulose is weighed according to deal proportion, sodium carboxymethylcellulose and additive are poured into band Have in the homogenizer of temperature control system, the temperature of homogenizer is controlled at 150 DEG C and stirred 25 minutes, mixture A is obtained;
S2, removal of impurities: weighing high titanium valve, deionized water and acrylate cream according to deal proportion, high titanium valve cleaned removal of impurities, Then high titanium valve is screened into 30 mesh by screening machine, the high titanium valve after screening is put into container and deionized water and third is added Olefin(e) acid ester cream, is stirred 3 minutes with blender, obtains mixture B;
S3, refining: bunt gypsum powder, film forming agent, calcium-free fillers, talcum powder, diatomite, mica are weighed according to deal proportion Powder, nano zine oxide, defoaming agent, dispersing agent, antifreezing agent, anti-flooding agent, antioxidant and nanometer anti-pollution auxiliary agent, by bunt gypsum powder, Film forming agent, calcium-free fillers, talcum powder, diatomite, mica powder, nano zine oxide, defoaming agent, dispersing agent, antifreezing agent, anti-loose colour Agent, antioxidant and nanometer anti-pollution auxiliary agent are soaked in water 2 days, soak are then carried out refining 2 hours with boiler, after refining Solution is precipitated, and is filtered with sand stick filter, is removed the impurity in solution, is obtained mixture C;
S4, heat treatment: according to deal proportion weigh titanium dioxide, titanium dioxide is poured into boiler, with 100 DEG C of high temperature to its into Row heat treatment, heating time are 3 minutes, obtain mixture D;
S5, preheating: the half of mixture A is poured into preheating can, with preheating temperature 10 minutes of 60 DEG C, has been preheated Mixture B is poured into preheating can after finishing, with identical preheating temperature 3 minutes, remaining mixture A is then poured into preheating can It is interior, the temperature of preheating can is controlled at 150 DEG C, heats 1 hour, obtains mixture E;
S6, water is removed;Mixture C and mixture D are added in centrifuge and carry out centrifugal dehydration, obtains sticky mixture F
Mixture E and mixture F are added in blender by S7, mixing, and mixture E and mixture F are mixed.
Embodiment 2
A kind of anti-pollution latex paint preparation method, the anti-pollution latex paint include the raw material of following parts by weight: carboxymethyl cellulose 14 parts of plain sodium, 90 parts of titanium dioxide, 10 parts of high titanium valve, 4 parts of bunt gypsum powder, 9 parts of film forming agent, 10 parts of calcium-free fillers, 10 parts of talcum powder, 10 parts of diatomite, 4 parts of mica powder, 91 parts of nano zine oxide, 4 parts of defoaming agent, 4 parts of dispersing agent, 4 parts of antifreezing agent, anti-flooding agent 4 Part, 3 parts, 21 parts of additive of 94 parts of part, nanometer anti-pollution auxiliary agent of antioxidant, 5 parts of deionized water, acrylate cream;Anti-pollution latex paint Preparation method the following steps are included:
S1, homogeneous: sodium carboxymethylcellulose is weighed according to deal proportion, sodium carboxymethylcellulose and additive are poured into band Have in the homogenizer of temperature control system, the temperature of homogenizer is controlled at 160 DEG C and stirred 30 minutes, mixture A is obtained;
S2, removal of impurities: weighing high titanium valve, deionized water and acrylate cream according to deal proportion, high titanium valve cleaned removal of impurities, Then high titanium valve is screened into 35 mesh by screening machine, the high titanium valve after screening is put into container and deionized water and third is added Olefin(e) acid ester cream, is stirred 4 minutes with blender, obtains mixture B;
S3, refining: bunt gypsum powder, film forming agent, calcium-free fillers, talcum powder, diatomite, mica are weighed according to deal proportion Powder, nano zine oxide, defoaming agent, dispersing agent, antifreezing agent, anti-flooding agent, antioxidant and nanometer anti-pollution auxiliary agent, by bunt gypsum powder, Film forming agent, calcium-free fillers, talcum powder, diatomite, mica powder, nano zine oxide, defoaming agent, dispersing agent, antifreezing agent, anti-loose colour Agent, antioxidant and nanometer anti-pollution auxiliary agent are soaked in water 3 days, soak are then carried out refining 3 hours with boiler, after refining Solution is precipitated, and is filtered with sand stick filter, is removed the impurity in solution, is obtained mixture C;
S4, heat treatment: according to deal proportion weigh titanium dioxide, titanium dioxide is poured into boiler, with 105 DEG C of high temperature to its into Row heat treatment, heating time are 4 minutes, obtain mixture D;
S5, preheating: the half of mixture A is poured into preheating can, with preheating temperature 15 minutes of 70 DEG C, has been preheated Mixture B is poured into preheating can after finishing, with identical preheating temperature 5 minutes, remaining mixture A is then poured into preheating can It is interior, the temperature of preheating can is controlled at 200 DEG C, heats 2 hours, obtains mixture E;
S6, water is removed;Mixture C and mixture D are added in centrifuge and carry out centrifugal dehydration, obtains sticky mixture F
Mixture E and mixture F are added in blender by S7, mixing, and mixture E and mixture F are mixed.
Embodiment 3
A kind of anti-pollution latex paint preparation method, the anti-pollution latex paint include the raw material of following parts by weight: carboxymethyl cellulose 15 parts of plain sodium, 100 parts of titanium dioxide, 20 parts of high titanium valve, 5 parts of bunt gypsum powder, 10 parts of film forming agent, 20 parts of calcium-free fillers, talcum powder 20 Part, 20 parts of diatomite, 5 parts of mica powder, 10 parts of nano zine oxide, 5 parts of defoaming agent, 5 parts of dispersing agent, 5 parts of antifreezing agent, anti-flooding agent 5 parts, 10 5 parts of part, nanometer anti-pollution auxiliary agent of antioxidant, 6 parts of deionized water, 4 parts, 22 parts of additive of acrylate cream;Anti-pollution latex The preparation method of paint the following steps are included:
S1, homogeneous: sodium carboxymethylcellulose is weighed according to deal proportion, sodium carboxymethylcellulose and additive are poured into band Have in the homogenizer of temperature control system, the temperature of homogenizer is controlled at 170 DEG C and stirred 35 minutes, mixture A is obtained;
S2, removal of impurities: weighing high titanium valve, deionized water and acrylate cream according to deal proportion, high titanium valve cleaned removal of impurities, Then high titanium valve is screened into 40 mesh by screening machine, the high titanium valve after screening is put into container and deionized water and third is added Olefin(e) acid ester cream, is stirred 4 minutes with blender, obtains mixture B;
S3, refining: bunt gypsum powder, film forming agent, calcium-free fillers, talcum powder, diatomite, mica are weighed according to deal proportion Powder, nano zine oxide, defoaming agent, dispersing agent, antifreezing agent, anti-flooding agent, antioxidant and nanometer anti-pollution auxiliary agent, by bunt gypsum powder, Film forming agent, calcium-free fillers, talcum powder, diatomite, mica powder, nano zine oxide, defoaming agent, dispersing agent, antifreezing agent, anti-loose colour Agent, antioxidant and nanometer anti-pollution auxiliary agent are soaked in water 4 days, soak are then carried out refining 5 hours with boiler, after refining Solution is precipitated, and is filtered with sand stick filter, is removed the impurity in solution, is obtained mixture C;
S4, heat treatment: according to deal proportion weigh titanium dioxide, titanium dioxide is poured into boiler, with 110 DEG C of high temperature to its into Row heat treatment, heating time are 4 minutes, obtain mixture D;
S5, preheating: the half of mixture A is poured into preheating can, with preheating temperature 18 minutes of 60-80 DEG C, in advance Mixture B is poured into preheating can after heat, with identical preheating temperature 7 minutes, is then poured into remaining mixture A pre- In hot tank, the temperature of preheating can is controlled at 250 DEG C, heats 2.5 hours, obtains mixture E;
S6, water is removed;Mixture C and mixture D are added in centrifuge and carry out centrifugal dehydration, obtains sticky mixture F
Mixture E and mixture F are added in blender by S7, mixing, and mixture E and mixture F are mixed.
Embodiment 4
A kind of anti-pollution latex paint preparation method;The anti-pollution latex paint includes the raw material of following parts by weight: carboxymethyl cellulose 16 parts of plain sodium, 110 parts of titanium dioxide, 30 parts of high titanium valve, 6 parts of bunt gypsum powder, 11 parts of film forming agent, 30 parts of calcium-free fillers, talcum powder 30 Part, 30 parts of diatomite, 6 parts of mica powder, 11 parts of nano zine oxide, 6 parts of defoaming agent, 6 parts of dispersing agent, 6 parts of antifreezing agent, anti-flooding agent 6 parts, 11 6 parts of part, nanometer anti-pollution auxiliary agent of antioxidant, 7 parts of deionized water, 5 parts, 23 parts of additive of acrylate cream;Anti-pollution latex The preparation method of paint the following steps are included:
S1, homogeneous: sodium carboxymethylcellulose is weighed according to deal proportion, sodium carboxymethylcellulose and additive are poured into band Have in the homogenizer of temperature control system, the temperature of homogenizer is controlled at 180 DEG C and stirred 35 minutes, mixture A is obtained;
S2, removal of impurities: weighing high titanium valve, deionized water and acrylate cream according to deal proportion, high titanium valve cleaned removal of impurities, Then high titanium valve is screened into 40 mesh by screening machine, the high titanium valve after screening is put into container and deionized water and third is added Olefin(e) acid ester cream, is stirred 5 minutes with blender, obtains mixture B;
S3, refining: bunt gypsum powder, film forming agent, calcium-free fillers, talcum powder, diatomite, mica are weighed according to deal proportion Powder, nano zine oxide, defoaming agent, dispersing agent, antifreezing agent, anti-flooding agent, antioxidant and nanometer anti-pollution auxiliary agent, by bunt gypsum powder, Film forming agent, calcium-free fillers, talcum powder, diatomite, mica powder, nano zine oxide, defoaming agent, dispersing agent, antifreezing agent, anti-loose colour Agent, antioxidant and nanometer anti-pollution auxiliary agent are soaked in water 4 days, soak are then carried out refining 6 hours with boiler, after refining Solution is precipitated, and is filtered with sand stick filter, is removed the impurity in solution, is obtained mixture C;
S4, heat treatment: according to deal proportion weigh titanium dioxide, titanium dioxide is poured into boiler, with 120 DEG C of high temperature to its into Row heat treatment, heating time are 5 minutes, obtain mixture D;
S5, preheating: the half of mixture A is poured into preheating can, with preheating temperature 18 minutes of 80 DEG C, has been preheated Mixture B is poured into preheating can after finishing, with identical preheating temperature 5 minutes, remaining mixture A is then poured into preheating can It is interior, the temperature of preheating can is controlled at 300 DEG C, heats 3 hours, obtains mixture E;
S6, water is removed;Mixture C and mixture D are added in centrifuge and carry out centrifugal dehydration, obtains sticky mixture F
Mixture E and mixture F are added in blender by S7, mixing, and mixture E and mixture F are mixed.
Embodiment 5
A kind of anti-pollution latex paint preparation method, the anti-pollution latex paint include the raw material of following parts by weight: carboxymethyl cellulose 18 parts of plain sodium, 150 parts of titanium dioxide, 35 parts of high titanium valve, 8 parts of bunt gypsum powder, 15 parts of film forming agent, 40 parts of calcium-free fillers, talcum powder 38 Part, 40 parts of diatomite, 9 parts of mica powder, 18 parts of nano zine oxide, 7 parts of defoaming agent, 9 parts of dispersing agent, 10 parts of antifreezing agent, anti-loose colour 15 parts of agent, 15 12 parts of part, nanometer anti-pollution auxiliary agent of antioxidant, 9 parts of deionized water, 5 parts, 25 parts of additive of acrylate cream;Anti-pollution The preparation method of emulsion paint the following steps are included:
S1, homogeneous: sodium carboxymethylcellulose is weighed according to deal proportion, sodium carboxymethylcellulose and additive are poured into band Have in the homogenizer of temperature control system, the temperature of homogenizer is controlled at 180 DEG C and stirred 40 minutes, mixture A is obtained;
S2, removal of impurities: weighing high titanium valve, deionized water and acrylate cream according to deal proportion, high titanium valve cleaned removal of impurities, Then high titanium valve is screened into 50 mesh by screening machine, the high titanium valve after screening is put into container and deionized water and third is added Olefin(e) acid ester cream, is stirred 6 minutes with blender, obtains mixture B;
S3, refining: bunt gypsum powder, film forming agent, calcium-free fillers, talcum powder, diatomite, mica are weighed according to deal proportion Powder, nano zine oxide, defoaming agent, dispersing agent, antifreezing agent, anti-flooding agent, antioxidant and nanometer anti-pollution auxiliary agent, by bunt gypsum powder, Film forming agent, calcium-free fillers, talcum powder, diatomite, mica powder, nano zine oxide, defoaming agent, dispersing agent, antifreezing agent, anti-loose colour Agent, antioxidant and nanometer anti-pollution auxiliary agent are soaked in water 4 days, soak are then carried out refining 6 hours with boiler, after refining Solution is precipitated, and is filtered with sand stick filter, is removed the impurity in solution, is obtained mixture C;
S4, heat treatment: according to deal proportion weigh titanium dioxide, titanium dioxide is poured into boiler, with 120 DEG C of high temperature to its into Row heat treatment, heating time are 5 minutes, obtain mixture D;
S5, preheating: the half of mixture A is poured into preheating can, with preheating temperature 15 minutes of 75 DEG C, has been preheated Mixture B is poured into preheating can after finishing, with identical preheating temperature 3 minutes, remaining mixture A is then poured into preheating can It is interior, the temperature of preheating can is controlled at 180 DEG C, heats 2 hours, obtains mixture E;
S6, water is removed;Mixture C and mixture D are added in centrifuge and carry out centrifugal dehydration, obtains sticky mixture F
Mixture E and mixture F are added in blender by S7, mixing, and mixture E and mixture F are mixed.
Sodium carboxymethylcellulose, titanium dioxide and high titanium valve are added in the present invention into anti-pollution latex paint, gives anti-pollution latex paint It is middle that a large amount of oxidation material is provided, be conducive to carry out oxygenolysis to dirt to anti-pollution latex paint;Tan in wolf tail grass extract Confrontation dicalcium powder plays condensation, improves the polymerization between coarse whiting powder particles, dicalcium powder is made to be added to emulsion paint It can be improved the cementitiousness of emulsion paint film after preparation process, the hardness of paint film is improved in a large amount of fine, soft fur holes on compact film And compactness, meanwhile, tannin can reduce surface of the paint film tension, can reduce film to the adsorptivity of pollutant, make dicalcium powder Emulsion paint surface coating intensity is enhanced after being added in emulsion paint preparation process, to improve the contaminated resistance of emulsion paint; Suitable honeysuckle is added, the fragrance of anti-pollution latex paint is improved;By being modified Honegsukle flower P.E during the preparation process successively Sodium carbonate and calcium chloride is added, the two calcium carbonate generated in the reaction system generates the fractions phase i.e. with additive one Mutual reactance or complexing, so that changing the surface nature of generation light calcium can significantly mention in this way when it is added in emulsion paint The contaminated resistance of high emulsion paint;Various enzymes in wolf tail grass extract, modified Honegsukle flower P.E, wherein what is contained is oxidized to The growth of bacterium can be inhibited to a certain extent by dividing, to improve the anti-microbial property and pollution resistance of emulsion paint.
It is by anti-pollution latex paint produced by the invention and common on the market in order to examine the effect of anti-pollution latex paint in the present invention Anti-pollution latex paint as experimental group agent, choose 40 cubic metres of room, stochastic averagina is divided into two groups, and first group in room Wall smear anti-pollution latex paint (20 kilograms of anti-pollution latex paints are uniformly applied on metope), second group be put into 20 kilograms it is common anti- Dirty emulsion paint (being uniformly applied to 20 kilograms of anti-pollution latex paints on metope), experiment number of days are 60 days.
By above-mentioned experimental data it is found that the stain resistance of this programme anti-pollution latex paint is apparently higher than common anti-pollution cream on the market The level of shellac varnish makes the air in room become faint scent, the time required to wall dirt generates using the anti-pollution latex paint of embodiment 3 Postpone significantly, has a good application prospect.
5 embodiments of the invention are described in detail above, but the content is only preferable implementation of the invention Example, should not be considered as limiting the scope of the invention.It is all according to all the changes and improvements made by the present patent application range Deng should still be within the scope of the patent of the present invention.

Claims (8)

1. a kind of anti-pollution latex paint preparation method, which is characterized in that the anti-pollution latex paint includes the raw material of following parts by weight: carboxylic 10-18 parts of sodium carboxymethylcellulose pyce, 50-150 parts of titanium dioxide, titanium valve 5-35 parts high, 1-8 parts of bunt gypsum powder, 3-15 parts of film forming agent, nothing 2-40 parts of calcium filler, 1-38 parts of talcum powder, 5-40 parts of diatomite, 1-9 parts of mica powder, 3-18 parts of nano zine oxide, defoaming agent 2-7 Part, 2-12 parts of nanometer anti-pollution auxiliary agent, is gone 1-9 parts of dispersing agent, 2-10 parts of antifreezing agent, 3-15 parts of anti-flooding agent, 5-15 parts of antioxidant 2-9 parts of ionized water, 2-5 parts of acrylate cream, 18-25 parts of additive;The preparation method of the anti-pollution latex paint includes following step It is rapid:
S1, homogeneous: sodium carboxymethylcellulose is weighed according to deal proportion, sodium carboxymethylcellulose and additive are poured into temperature It spends in the homogenizer of control system, the temperature of homogenizer is controlled at 150 DEG C -180 DEG C and stirred 25-40 minutes, is mixed Object A;
S2, removal of impurities: high titanium valve, deionized water and acrylate cream are weighed according to deal proportion, high titanium valve is cleaned into removal of impurities, then High titanium valve is screened into 30-50 mesh by screening machine, the high titanium valve after screening is put into container and deionized water and third is added Olefin(e) acid ester cream, is stirred 3-6 minutes with blender, obtains mixture B;
S3, refining: bunt gypsum powder is weighed according to deal proportion, film forming agent, calcium-free fillers, talcum powder, diatomite, mica powder, is received Rice zinc oxide, defoaming agent, dispersing agent, antifreezing agent, anti-flooding agent, antioxidant and nanometer anti-pollution auxiliary agent, by bunt gypsum powder, film forming Agent, talcum powder, diatomite, mica powder, nano zine oxide, defoaming agent, dispersing agent, antifreezing agent, anti-flooding agent, resists calcium-free fillers Oxygen agent and nanometer anti-pollution auxiliary agent are soaked in water 2-4 days, soak are then carried out refining 2-6 hours with boiler, after refining Solution is precipitated, and is filtered with sand stick filter, is removed the impurity in solution, is obtained mixture C;
S4, heat treatment: according to deal proportion weigh titanium dioxide, titanium dioxide is poured into boiler, with 100-120 DEG C of high temperature to its into Row heat treatment, heating time are 3-5 minutes, obtain mixture D;
S5, preheating: the half of mixture A is poured into preheating can, with preheating temperature 10-20 minutes of 60-80 DEG C, preheating After mixture B is poured into preheating can, with identical preheating temperature 3-8 minutes, then remaining mixture A is poured into pre- In hot tank, the temperature of preheating can is controlled at 150-300 DEG C, heats 1-3 hours, obtains mixture E;
S6, water is removed;Mixture C and mixture D are added in centrifuge and carry out centrifugal dehydration, obtains sticky mixture F
Mixture E and mixture F are added in blender by S7, mixing, and mixture E and mixture F are mixed.
2. a kind of anti-pollution latex paint preparation method according to claim 1, which is characterized in that the anti-pollution latex paint includes The raw material of following parts by weight: 14-16 parts of sodium carboxymethylcellulose, 90-110 parts of titanium dioxide, titanium valve 10-30 parts high, bunt gypsum powder 4-6 parts, 9-11 parts of film forming agent, 10-30 parts of calcium-free fillers, 10-30 parts of talcum powder, 10-30 parts of diatomite, 4-6 parts of mica powder, receive Rice 9-11 parts of zinc oxide, 4-6 parts of defoaming agent, 4-6 parts of dispersing agent, 4-6 parts of antifreezing agent, 4-6 parts of anti-flooding agent, antioxidant 9-11 Part, 4-6 parts of nanometer anti-pollution auxiliary agent, 5-7 parts of deionized water, 3-5 parts of acrylate cream, 21-23 parts of additive.
3. a kind of anti-pollution latex paint preparation method according to claim 1, which is characterized in that the anti-pollution latex paint includes The raw material of following parts by weight: 15 parts of sodium carboxymethylcellulose, 100 parts of titanium dioxide, 20 parts of high titanium valve, 5 parts of bunt gypsum powder, film forming agent 10 parts, 20 parts of calcium-free fillers, 20 parts of talcum powder, 20 parts of diatomite, 5 parts of mica powder, 10 parts of nano zine oxide, defoaming agent 5 part, point 5 parts of powder, 5 parts of antifreezing agent, 5 parts of anti-flooding agent, 10 5 parts of part, nanometer anti-pollution auxiliary agent of antioxidant, 6 parts of deionized water, acrylate 4 parts, 22 parts of additive of cream.
4. a kind of anti-pollution latex paint preparation method according to claim 1, which is characterized in that the additive is wolf tail grass Extract is modified Honegsukle flower P.E and laurel alcohol ether phosphate potassium, the laurel alcohol ether phosphate potassium content in the additive It is 30%.
5. a kind of anti-pollution latex paint preparation method according to claim 1, which is characterized in that the talcum powder, diatomite, The weight ratio of mica powder is 1-38:5-40:5-40.
6. a kind of anti-pollution latex paint preparation method according to claim 1, which is characterized in that the antifreezing agent, anti-loose colour Agent, antioxidant weight ratio be 2-10:3-15:5-15.
7. a kind of preparation process of anti-pollution latex paint preparation method according to claim 1, which is characterized in that the salt stone Cream powder, calcium-free fillers, talcum powder, diatomite, mica powder, nano zine oxide, defoaming agent, dispersing agent, antifreezing agent, is prevented film forming agent Loose colour agent, antioxidant and nanometer anti-pollution auxiliary agent are soaked in water 3 days.
8. a kind of preparation process of anti-pollution latex paint preparation method according to claim 1, which is characterized in that the S4 In, titanium dioxide is weighed according to deal proportion, titanium dioxide is poured into boiler, it is heated with 110 DEG C of high temperature, is heated Time is 4 minutes, obtains mixture D.
CN201810676621.XA 2018-06-27 2018-06-27 A kind of anti-pollution latex paint preparation method Pending CN109096830A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110200264A (en) * 2019-06-27 2019-09-06 江苏赛欧信越消泡剂有限公司 A kind of preparation method of the defoaming agent of resistance to highly basic and masses hit
CN112457726A (en) * 2020-11-25 2021-03-09 德清品高新材料有限公司 Manufacturing method of anti-fading spray material
CN113122082A (en) * 2021-05-19 2021-07-16 广西标牌化学科技有限公司 Preparation process of moisture-proof emulsion paint

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110200264A (en) * 2019-06-27 2019-09-06 江苏赛欧信越消泡剂有限公司 A kind of preparation method of the defoaming agent of resistance to highly basic and masses hit
CN112457726A (en) * 2020-11-25 2021-03-09 德清品高新材料有限公司 Manufacturing method of anti-fading spray material
CN113122082A (en) * 2021-05-19 2021-07-16 广西标牌化学科技有限公司 Preparation process of moisture-proof emulsion paint

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Application publication date: 20181228