CN109135547A - A kind of insulation and fire-proof paint - Google Patents
A kind of insulation and fire-proof paint Download PDFInfo
- Publication number
- CN109135547A CN109135547A CN201810762456.XA CN201810762456A CN109135547A CN 109135547 A CN109135547 A CN 109135547A CN 201810762456 A CN201810762456 A CN 201810762456A CN 109135547 A CN109135547 A CN 109135547A
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- China
- Prior art keywords
- mixing
- fire
- mass ratio
- insulation
- proof paint
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- 238000009413 insulation Methods 0.000 title claims abstract description 38
- 239000003973 paint Substances 0.000 title claims abstract description 36
- 239000007788 liquid Substances 0.000 claims abstract description 63
- 239000004814 polyurethane Substances 0.000 claims abstract description 34
- 229920002635 polyurethane Polymers 0.000 claims abstract description 34
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 28
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 27
- 239000002131 composite material Substances 0.000 claims abstract description 27
- 239000013335 mesoporous material Substances 0.000 claims abstract description 27
- 235000019795 sodium metasilicate Nutrition 0.000 claims abstract description 27
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 27
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229960000502 poloxamer Drugs 0.000 claims abstract description 26
- 229920001983 poloxamer Polymers 0.000 claims abstract description 26
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 20
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000005011 phenolic resin Substances 0.000 claims abstract description 14
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 14
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005058 Isophorone diisocyanate Substances 0.000 claims abstract description 7
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims description 82
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 32
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 31
- 239000000376 reactant Substances 0.000 claims description 27
- 238000010792 warming Methods 0.000 claims description 22
- 239000004094 surface-active agent Substances 0.000 claims description 21
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- 238000004321 preservation Methods 0.000 claims description 20
- 239000006185 dispersion Substances 0.000 claims description 19
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 18
- 239000002274 desiccant Substances 0.000 claims description 18
- 238000002360 preparation method Methods 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 239000000284 extract Substances 0.000 claims description 17
- 238000002803 maceration Methods 0.000 claims description 17
- 239000011324 bead Substances 0.000 claims description 15
- 239000011521 glass Substances 0.000 claims description 15
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 14
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 14
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 235000019441 ethanol Nutrition 0.000 claims description 13
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 12
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 12
- 229960004756 ethanol Drugs 0.000 claims description 12
- 239000000706 filtrate Substances 0.000 claims description 12
- 238000001914 filtration Methods 0.000 claims description 12
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims description 12
- 229920001451 polypropylene glycol Polymers 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 8
- -1 amine carbonate Chemical class 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 229920001661 Chitosan Polymers 0.000 claims description 6
- CTENFNNZBMHDDG-UHFFFAOYSA-N Dopamine hydrochloride Chemical compound Cl.NCCC1=CC=C(O)C(O)=C1 CTENFNNZBMHDDG-UHFFFAOYSA-N 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 6
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 6
- 125000005227 alkyl sulfonate group Chemical group 0.000 claims description 6
- 239000001110 calcium chloride Substances 0.000 claims description 6
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 6
- 230000006837 decompression Effects 0.000 claims description 6
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 6
- 239000012975 dibutyltin dilaurate Substances 0.000 claims description 6
- 229960001149 dopamine hydrochloride Drugs 0.000 claims description 6
- 235000019359 magnesium stearate Nutrition 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 235000019260 propionic acid Nutrition 0.000 claims description 6
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 150000004040 pyrrolidinones Chemical class 0.000 claims description 5
- 238000010008 shearing Methods 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- FHHJDRFHHWUPDG-UHFFFAOYSA-N peroxysulfuric acid Chemical compound OOS(O)(=O)=O FHHJDRFHHWUPDG-UHFFFAOYSA-N 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 239000007822 coupling agent Substances 0.000 claims description 2
- 229960000443 hydrochloric acid Drugs 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 238000009423 ventilation Methods 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims 3
- 239000002994 raw material Substances 0.000 abstract description 6
- 229910052681 coesite Inorganic materials 0.000 abstract description 4
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 239000000377 silicon dioxide Substances 0.000 abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052682 stishovite Inorganic materials 0.000 abstract description 4
- 229910052905 tridymite Inorganic materials 0.000 abstract description 4
- 239000002250 absorbent Substances 0.000 abstract description 2
- 230000002745 absorbent Effects 0.000 abstract description 2
- 239000004566 building material Substances 0.000 abstract description 2
- 235000003642 hunger Nutrition 0.000 abstract description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 2
- 230000001788 irregular Effects 0.000 abstract description 2
- 238000002955 isolation Methods 0.000 abstract description 2
- 239000011148 porous material Substances 0.000 abstract description 2
- 230000037351 starvation Effects 0.000 abstract description 2
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 229920000469 amphiphilic block copolymer Polymers 0.000 abstract 1
- 239000000463 material Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 239000006087 Silane Coupling Agent Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000006196 deacetylation Effects 0.000 description 4
- 238000003381 deacetylation reaction Methods 0.000 description 4
- 230000001804 emulsifying effect Effects 0.000 description 4
- 239000004519 grease Substances 0.000 description 4
- 230000010355 oscillation Effects 0.000 description 4
- 238000000643 oven drying Methods 0.000 description 4
- 238000012719 thermal polymerization Methods 0.000 description 4
- 230000003213 activating effect Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 229910008051 Si-OH Inorganic materials 0.000 description 1
- 229910006358 Si—OH Inorganic materials 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/28—Glass
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Organic Insulating Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of insulation and fire-proof paints, belong to the field of building materials.The present invention makes composite modified polyurethane, polyurethane composite S iO using sodium metasilicate as raw material2, form tridimensional network, and SiO2The adsorbed hydroxyl content is high, it can polymerize with the group in isophorone diisocyanate and polyurethane, so that the internal performance of insulation and fire-proof paint system is promoted, the raw materials such as the metakaolin in auxiliary agent, it can be under heat effect, isolation film is formed in air and ground part, it can effective flame-resistant high-temperature-resistant, using phenol and formaldehyde as raw material, it makes prefabricated phenolic resin and mixes liquid, cooperate amphiphilic block copolymer poloxamer, large specific surface area processed, the suitable complex mesoporous material of Pore genesis, provides non-polar absorbent power CO absorption2, by irregular porous release CO can be stimulated when high temperature2Play the role of efficiently starvation, thus play fire extinguishing, improves fire protecting performance.The present invention solves the problems, such as to commonly use insulation and fire-proof paint heat insulating ability, heat resistance at present bad.
Description
Technical field
The present invention relates to the field of building materials, in particular to a kind of insulation and fire-proof paint.
Background technique
Due to the generation of a lot of building heat preservation event of fire in recent years, the thinking of each bound pair insulated fire is caused, has kept the temperature
The unprecedented great attention for causing all circles in the industry of the fire protecting performance of material.However, many thermal insulation materials it is on fire be all
It is generated in work progress, such as: electric welding, open fire, undesirable construction habit.What these materials constantly generated in combustion melts
Object and toxic smoke are dripped, while the gases such as chlorofluorocarbons, hydrofluorocarbons, freon released can not also neglect the harm of environment
Depending on.For this purpose, there are many fire proof and thermo-insulation coating materials in market.Common insulation and fire-proof paint heat insulating ability, heat resistance are bad at present, no
It is able to satisfy the demand of people.
Summary of the invention
The technical problems to be solved by the invention: bad for current common insulation and fire-proof paint heat insulating ability, heat resistance
Problem provides a kind of insulation and fire-proof paint.
In order to solve the above technical problems, the present invention is using technical solution as described below:
A kind of insulation and fire-proof paint, according to the mass fraction, including following component: 5 ~ 10 parts of auxiliary agents, 3 ~ 8 parts of glass beads, 6 ~ 10
Part surfactant, 2 ~ 5 rosin, 25 ~ 40 parts of water, which is characterized in that further include: 20 ~ 45 parts of composite modified polyurethane, 15 ~ 30
Part complex mesoporous material.
The preparation method of the composite modified polyurethane, includes the following steps:
(1) in 10 ~ 15 DEG C, 1:5 ~ 10 take sodium metasilicate, hydrochloric acid solution mixing in mass ratio, and the silicon of sodium metasilicate quality 20 ~ 35% is added
The mixing of alkane coupling agent, reacts 3 ~ 5h, and the solvent mixing of NaCl and sodium metasilicate quality 30 ~ 45% that sodium metasilicate quality 8 ~ 15% is added are stirred
It mixes, stands, filtering takes filtrate 4 ~ 9:1 in mass ratio that desiccant is added, it is mixed, closed standing, addition filtrate quality 20 ~
30% polyoxypropyleneglycol, ultrasonic wave dispersion, decompression filter, and obtain dispersion liquid；
(2) in 80 ~ 90 DEG C, 1:1:10 ~ 15:2 in mass ratio takes polyoxypropyleneglycol, dihydromethyl propionic acid, dispersion liquid, N- first
Base pyrrolidones mixing, ventilation protection, is warming up to 100 ~ 110 DEG C of heat preservations, is cooled to 75 ~ 85 DEG C, obtains mixed reactant, take mixing
Reactant 8 ~ 12:1 in mass ratio ~ 3:1 adds dibutyl tin dilaurate, isophorone diisocyanate mixing, reacts 2 ~ 5h, drop
Temperature obtains feed liquid, and triethylamine, acrylic acid, viscosity-controlling agent mixing is added in feeding liquid 4 ~ 8:1:2:1 in mass ratio, and shearing dispersion adds
Enter the over cure potassium of feed liquid quality 16 ~ 25%, heat up, keep the temperature 3 ~ 5h, is evaporated under reduced pressure to get composite modified polyurethane.
Solvent in the step (1): 1:4 ~ 8 take acetone, ethyl alcohol mixing to get solvent in mass ratio.
Desiccant in the step (1): 5:1 ~ 2 take CaSO in mass ratio4、CaCl2Mixing is to get desiccant.
Viscosity-controlling agent in the step (2): urea, hydroxylamine hydrochloride, any one in hydroxyl sulfate.
The preparation method of the complex mesoporous material, includes the following steps:
S1. in 40 ~ 60 DEG C, 1:6 ~ 10 take phenol, NaOH solution to be mixed in mass ratio, and 3 ~ 7 times of formaldehyde of phenol quality are added
Solution mixing, is warming up to 70 ~ 85 DEG C, stirs, cooling, adjusts pH, is concentrated under reduced pressure, and is evaporated in vacuo, obtains reactant, reactant is taken to add
Enter 3 ~ 5 times of reactant quality of dehydrated alcohol, be uniformly mixed, obtains prefabricated phenolic resin and mix liquid；
S2. take poloxamer liquid 5 ~ 8:2:4 in mass ratio that ethyl orthosilicate is added, prefabricated phenolic resin mixes liquid, stirring, hot polymerization
It closes, nitrogen protection, temperature programming to 350 ~ 500 DEG C of heat preservations is warming up to 800 ~ 900 DEG C of 1 ~ 2h of heat preservation, obtains heat treatment object, and it is cooling,
3 ~ 5 times of heat-treated substance amount of maceration extract is added to impregnate, filtering takes filter residue and drying to get complex mesoporous material.
Poloxamer liquid in the step S2: 1:3 ~ 5:6 in mass ratio takes poloxamer, ethyl alcohol, hydrochloric acid solution mixing,
Up to poloxamer liquid.
Maceration extract in the step S2: 1:1 ~ 3:10 ~ 15 take chitosan, Dopamine hydrochloride, acetic acid solution in mass ratio
Mixing is to get maceration extract.
The surfactant: 4:1 ~ 2 take empgen BB, sodium secondary alkyl sulfonate mixing to get table in mass ratio
Face activating agent.
The auxiliary agent: 6:1:1 ~ 2 take metakaolin, amine carbonate, magnesium stearate mixing to get auxiliary agent in mass ratio.
The present invention is compared with other methods, and advantageous effects are:
(1) present invention makes composite modified polyurethane using sodium metasilicate as raw material, has excellent long-term effect, durability, chemical stabilization
Property, the SiO of sodium metasilicate hydrolysis generation2Particle and its Si-OH on surface and polyurethane molecular form physics crosslinked action, so that poly-
The movement of urethane molecule segment is fettered, and tensile strength is caused to increase, SiO2For rigid particles, reduce elongation at break,
After effect reaches to a certain degree, due to SiO2The aggtegation of particle, so that physical crosslinking density reduces, tensile strength and fracture are stretched
Long rate decline, polyurethane composite S iO2, form tridimensional network, and SiO2The adsorbed hydroxyl content is high, can be different with isophorone two
Group in cyanate and polyurethane polymerize, so that the internal performance of insulation and fire-proof paint system is promoted；
(2) raw materials such as metakaolin in auxiliary agent of the present invention can form glassy net as inorganic anti-flaming material under heat effect,
To form isolation film in air and ground part, can effective flame-resistant high-temperature-resistant, cooperate glass bead,
, the thermal insulation property of system can be greatly promoted, using phenol and formaldehyde as raw material, prefabricated phenolic resin is made and mixes liquid, cooperate both sexes
Block copolymer poloxamer, large specific surface area processed, the suitable complex mesoporous material of Pore genesis provide the suction of non-polar absorbent power
Attached CO2, by irregular porous release CO can be stimulated when high temperature2Play the role of efficiently starvation, thus play fire extinguishing,
Improve fire protecting performance.
Specific embodiment
Solvent: 1:4 ~ 8 take acetone, ethyl alcohol mixing to get solvent in mass ratio.
Desiccant: 5:1 ~ 2 take CaSO in mass ratio4、CaCl2Mixing is to get desiccant.
Viscosity-controlling agent: urea, hydroxylamine hydrochloride, any one in hydroxyl sulfate.
Surfactant: 4:1 ~ 2 take empgen BB, sodium secondary alkyl sulfonate mixing living to get surface in mass ratio
Property agent.
Auxiliary agent: 6:1:1 ~ 2 take metakaolin, amine carbonate, magnesium stearate mixing to get auxiliary agent in mass ratio.
Poloxamer liquid: 1:3 ~ 5:6 in mass ratio takes the hydrochloric acid solution mixing of poloxamer, ethyl alcohol, concentration 0.1mol/L,
Up to poloxamer liquid.
Maceration extract: 1:1 ~ 3:10 ~ 15 chitosan, Dopamine hydrochloride, mass fraction that take deacetylation 90% in mass ratio
10% acetic acid solution mixes to get maceration extract.
The preparation method of composite modified polyurethane, includes the following steps:
(1) in 10 ~ 15 DEG C, 1:5 ~ 10 take the hydrochloric acid solution of sodium metasilicate, concentration 0.1mol/L to mix in mass ratio, and sodium metasilicate is added
The silane coupling agent of quality 20 ~ 35% mixes, and reacts 3 ~ 5h, be added sodium metasilicate quality 8 ~ 15% NaCl and sodium metasilicate quality 30 ~
45% solvent mixing, stirs 2 ~ 4h with 250 ~ 400r/min, stands 25 ~ 40min, and filtering takes filtrate 4 ~ 9:1 in mass ratio to add
Entering desiccant, is mixed 10 ~ 15min, room temperature is closed to stand 20 ~ for 24 hours, the polypropylene oxide two of filtrate quality 20 ~ 30% is added
Alcohol disperses 15 ~ 25min with 300W ultrasonic wave, and decompression filters, and obtains dispersion liquid；
(2) 80 ~ 90 DEG C are bathed in grease, 1:1:10 ~ 15:2 in mass ratio takes polyoxypropyleneglycol, dihydromethyl propionic acid, dispersion
Liquid, N-Methyl pyrrolidone mixing, lead to nitrogen protection, are warming up to 100 ~ 110 DEG C of 20 ~ 30min of heat preservation, are cooled to 75 ~ 85 DEG C, obtain
Mixed reactant takes mixed reactant 8 ~ 12:1 in mass ratio ~ 3:1 to add dibutyl tin dilaurate, isophorone diisocyanate
Ester mixing, reacts 2 ~ 5h, is cooled to 55 ~ 65 DEG C, obtains feed liquid, and triethylamine, propylene is added in feeding liquid 4 ~ 8:1:2:1 in mass ratio
Acid, viscosity-controlling agent mixing and emulsifying shear 15 ~ 30min of dispersion with 300 ~ 500r/min, the over cure of feed liquid quality 16 ~ 25% are added
Change potassium, be warming up to 65 ~ 75 DEG C, keep the temperature 3 ~ 5h, is evaporated under reduced pressure to get composite modified polyurethane.
The preparation method of complex mesoporous material, includes the following steps:
S1. in 40 ~ 60 DEG C of water-bath, the 1:6 ~ 10 NaOH solution mixing that takes phenol, mass fraction 15% in mass ratio, with 300 ~
450r/min stirs 20 ~ 45min, and the formalin that the mass fraction for being added 3 ~ 7 times of phenol quality is 25% mixes, it is warming up to 70 ~
85 DEG C, continue 10 ~ 20min of stirring, cooled to room temperature adjusts pH to 6.8 ~ 7.2 with the hydrochloric acid solution of concentration 1mol/L, subtracts
Pressure concentration, is evaporated in vacuo to constant weight, obtains reactant, takes reactant that 3 ~ 5 times of reactant quality of dehydrated alcohol is added, and mixing is equal
It is even, it obtains prefabricated phenolic resin and mixes liquid；
S2. take poloxamer liquid 5 ~ 8:2:4 in mass ratio that the mixed liquid of ethyl orthosilicate, prefabricated phenolic resin is added, with 300 ~ 350r/
Min stirring moves to tube furnace after 90 ~ 100 DEG C of thermal polymerizations 20 ~ for 24 hours, under nitrogen protection, with 5 ~ 10 DEG C/min temperature programming
To 350 ~ 500 DEG C of 3 ~ 5h of heat preservation, 800 ~ 900 DEG C of 1 ~ 2h of heat preservation are warming up to, obtain heat treatment object, after cooled to room temperature, are added
Enter 3 ~ 5 times of heat-treated substance amount of maceration extract and impregnate 2 ~ 5h, filtering takes filter residue in 60 ~ 80 DEG C of oven dryings to get composite mesopore
Material.
A kind of insulation and fire-proof paint, according to the mass fraction, including following component: 5 ~ 10 parts of auxiliary agents, 3 ~ 8 parts of glass beads, 6
~ 10 parts of surfactants, 2 ~ 5 rosin, 25 ~ 40 parts of water, which is characterized in that further include: 20 ~ 45 parts of composite modified polyurethane, 15 ~
30 parts of complex mesoporous materials.
A kind of preparation method of insulation and fire-proof paint, includes the following steps:
(1) according to the mass fraction, 5 ~ 10 parts of auxiliary agents, 3 ~ 8 parts of glass beads, 6 ~ 10 parts of surfactants, 2 ~ 5 rosin, 25 ~ 40 are taken
Part water, 20 ~ 45 parts of composite modified polyurethane, 15 ~ 30 parts of complex mesoporous materials；
(2) auxiliary agent, glass bead, rosin, water is taken to mix in reaction kettle, prior to 30 ~ 45 DEG C with 300 ~ 500r/min magnetic agitation
After 25 ~ 50min, be added composite modified polyurethane, surfactant, complex mesoporous material mixing, with 300W supersonic oscillations 20 ~
30min is passed through CO in 0.9MPa, 20 ~ 25 DEG C with 200 ~ 300mL/min2, 2 ~ 4h is stood to get insulation and fire-proof paint.
Embodiment 1
Solvent: 1:4 in mass ratio takes acetone, ethyl alcohol mixing to get solvent.
Desiccant: 5:1 takes CaSO in mass ratio4、CaCl2Mixing is to get desiccant.
Viscosity-controlling agent: urea.
Surfactant: 4:1 in mass ratio takes empgen BB, sodium secondary alkyl sulfonate mixing to get surface-active
Agent.
Auxiliary agent: 6:1:1 in mass ratio takes metakaolin, amine carbonate, magnesium stearate mixing to get auxiliary agent.
Poloxamer liquid: 1:3:6 in mass ratio takes the hydrochloric acid solution mixing of poloxamer, ethyl alcohol, concentration 0.1mol/L, i.e.,
Obtain poloxamer liquid.
Maceration extract: 1:1:10 in mass ratio takes the second of the chitosan of deacetylation 90%, Dopamine hydrochloride, mass fraction 10%
Acid solution mixes to get maceration extract.
The preparation method of composite modified polyurethane, includes the following steps:
(1) in 10 DEG C, 1:5 in mass ratio takes the hydrochloric acid solution mixing of sodium metasilicate, concentration 0.1mol/L, and sodium metasilicate quality is added
20% silane coupling agent mixing, reacts 3h, and the NaCl of sodium metasilicate quality 8% and the solvent mixing of sodium metasilicate quality 30% is added, with
25r/min stirs 2h, stands 25min, and filtering takes filtrate 4:1 in mass ratio that desiccant is added, and 10min is mixed, and room temperature is close
It closes and stands 20h, the polyoxypropyleneglycol of filtrate quality 20% is added, min is dispersed with 300W ultrasonic wave, decompression filters, must disperse
Liquid；
(2) 80 DEG C are bathed in grease, 1:1:10:2 in mass ratio takes polyoxypropyleneglycol, dihydromethyl propionic acid, dispersion liquid, N- first
The mixing of base pyrrolidones, leads to nitrogen protection, is warming up to 100 DEG C of heat preservation 20min, is cooled to 75 DEG C, obtains mixed reactant, take mixing
Reactant 8:1:1 in mass ratio adds dibutyl tin dilaurate, isophorone diisocyanate mixing, reacts 2h, is cooled to 55
DEG C, feed liquid is obtained, triethylamine, acrylic acid, viscosity-controlling agent mixing and emulsifying is added in feeding liquid 4:1:2:1 in mass ratio, with 300r/
Min shearing dispersion 15min, is added the over cure potassium of feed liquid quality 16%, is warming up to 65 DEG C, keep the temperature 3h, be evaporated under reduced pressure to get multiple
Close modified polyurethane.
The preparation method of complex mesoporous material, includes the following steps:
S1. in 40 DEG C of water-bath, 1:6 in mass ratio takes the NaOH solution mixing of phenol, mass fraction 15%, is stirred with 300r/min
20min, the formalin that the mass fraction for being added 3 times of phenol quality is 25% mix, and are warming up to 70 DEG C, continue to stir 10min,
Cooled to room temperature adjusts pH to 6.8 with the hydrochloric acid solution of concentration 1mol/L, is concentrated under reduced pressure, is evaporated in vacuo to constant weight, obtains instead
Object is answered, takes reactant that 3 times of reactant quality of dehydrated alcohol is added, is uniformly mixed, prefabricated phenolic resin is obtained and mixes liquid；
S2. it takes poloxamer liquid 5:2:4 in mass ratio that the mixed liquid of ethyl orthosilicate, prefabricated phenolic resin is added, is stirred with 300r/min
It mixes, after 90 DEG C of thermal polymerization 20h, moves to tube furnace, under nitrogen protection, with 5 DEG C/min temperature programming to 350 DEG C of heat preservation 3h
Afterwards, 800 DEG C of heat preservation 1h are warming up to, obtain heat treatment object, after cooled to room temperature, 3 times of heat-treated substance amount of maceration extract is added
2h is impregnated, filtering takes filter residue in 60 DEG C of oven dryings to get complex mesoporous material.
A kind of insulation and fire-proof paint, according to the mass fraction, including following component: 5 parts of auxiliary agents, 3 parts of glass beads, 6 parts of tables
Face activating agent, 2 rosin, 25 parts of water, which is characterized in that further include: 20 parts of composite modified polyurethane, 15 parts of complex mesoporous materials.
A kind of preparation method of insulation and fire-proof paint, includes the following steps:
(1) according to the mass fraction, take 5 parts of auxiliary agents, 3 parts of glass beads, 6 parts of surfactants, 2 rosin, 25 parts of water, 20 parts it is compound
Modified polyurethane, 15 parts of complex mesoporous materials；
(2) auxiliary agent, glass bead, rosin, water is taken to mix in reaction kettle prior to 30 DEG C, after 300r/min magnetic agitation 25min,
Composite modified polyurethane, surfactant, complex mesoporous material mixing is added, with 300W supersonic oscillations 20min, in
0.9MPa, 20 DEG C CO is passed through with 200mL/min2, 2h is stood to get insulation and fire-proof paint.
Embodiment 2
Solvent: 1:6 in mass ratio takes acetone, ethyl alcohol mixing to get solvent.
Desiccant: 5:1.5 takes CaSO in mass ratio4、CaCl2Mixing is to get desiccant.
Viscosity-controlling agent: hydroxylamine hydrochloride.
Surfactant: 4:1.5 in mass ratio takes empgen BB, sodium secondary alkyl sulfonate mixing living to get surface
Property agent.
Auxiliary agent: 6:1:1.5 in mass ratio takes metakaolin, amine carbonate, magnesium stearate mixing to get auxiliary agent.
Poloxamer liquid: 1:4:6 in mass ratio takes the hydrochloric acid solution mixing of poloxamer, ethyl alcohol, concentration 0.1mol/L, i.e.,
Obtain poloxamer liquid.
Maceration extract: 1:2:13 in mass ratio takes the second of the chitosan of deacetylation 90%, Dopamine hydrochloride, mass fraction 10%
Acid solution mixes to get maceration extract.
The preparation method of composite modified polyurethane, includes the following steps:
(1) in 12 DEG C, 1:7 in mass ratio takes the hydrochloric acid solution mixing of sodium metasilicate, concentration 0.1mol/L, and sodium metasilicate quality is added
30% silane coupling agent mixing, reacts 4h, and the NaCl of sodium metasilicate quality 12% and the solvent mixing of sodium metasilicate quality 40% is added,
3h is stirred with 320r/min, stands 30min, filtering takes filtrate 5:1 in mass ratio that desiccant is added, and 13min, room is mixed
The closed standing 22h of temperature, is added the polyoxypropyleneglycol of filtrate quality 25%, disperses 20min with 300W ultrasonic wave, and decompression filters,
Obtain dispersion liquid；
(2) 85 DEG C are bathed in grease, 1:1:12:2 in mass ratio takes polyoxypropyleneglycol, dihydromethyl propionic acid, dispersion liquid, N- first
The mixing of base pyrrolidones, leads to nitrogen protection, is warming up to 105 DEG C of heat preservation 25min, is cooled to 80 DEG C, obtains mixed reactant, take mixing
Reactant 9:2:1 in mass ratio adds dibutyl tin dilaurate, isophorone diisocyanate mixing, reacts 4h, is cooled to 60
DEG C, feed liquid is obtained, triethylamine, acrylic acid, viscosity-controlling agent mixing and emulsifying is added in feeding liquid 5:1:2:1 in mass ratio, with 350r/
Min shearing dispersion 20min, is added the over cure potassium of feed liquid quality 20%, is warming up to 70 DEG C, keep the temperature 4h, be evaporated under reduced pressure to get multiple
Close modified polyurethane.
The preparation method of complex mesoporous material, includes the following steps:
S1. in 50 DEG C of water-bath, 1:8 in mass ratio takes the NaOH solution mixing of phenol, mass fraction 15%, is stirred with 400r/min
30min, the formalin that the mass fraction for being added 5 times of phenol quality is 25% mix, and are warming up to 80 DEG C, continue to stir 15min,
Cooled to room temperature adjusts pH to 7 with the hydrochloric acid solution of concentration 1mol/L, is concentrated under reduced pressure, is evaporated in vacuo to constant weight, must react
Object takes reactant that 4 times of reactant quality of dehydrated alcohol is added, and is uniformly mixed, and obtains prefabricated phenolic resin and mixes liquid；
S2. it takes poloxamer liquid 7:2:4 in mass ratio that the mixed liquid of ethyl orthosilicate, prefabricated phenolic resin is added, is stirred with 320r/min
It mixes, after 95 DEG C of thermal polymerization 22h, moves to tube furnace, under nitrogen protection, with 7 DEG C/min temperature programming to 450 DEG C of heat preservation 4h
Afterwards, 850 DEG C of heat preservation 1.5h are warming up to, obtain heat treatment object, after cooled to room temperature, 4 times of heat-treated substance amount of dipping is added
Liquid impregnates 3h, and filtering takes filter residue in 70 DEG C of oven dryings to get complex mesoporous material.
A kind of insulation and fire-proof paint, according to the mass fraction, including following component: 7 parts of auxiliary agents, 6 parts of glass beads, 8 parts of tables
Face activating agent, 3 rosin, 35 parts of water, which is characterized in that further include: 32 parts of composite modified polyurethane, 25 parts of complex mesoporous materials.
A kind of preparation method of insulation and fire-proof paint, includes the following steps:
(1) according to the mass fraction, take 7 parts of auxiliary agents, 5 parts of glass beads, 8 parts of surfactants, 4 rosin, 32 parts of water, 36 parts it is compound
Modified polyurethane, 25 parts of complex mesoporous materials；
(2) auxiliary agent, glass bead, rosin, water is taken to mix in reaction kettle prior to 40 DEG C, after 400r/min magnetic agitation 35min,
Composite modified polyurethane, surfactant, complex mesoporous material mixing is added, with 300W supersonic oscillations 25min, in
0.9MPa, 22 DEG C CO is passed through with 250mL/min2, 3h is stood to get insulation and fire-proof paint.
Embodiment 3
Solvent: 1:8 in mass ratio takes acetone, ethyl alcohol mixing to get solvent.
Desiccant: 5:2 takes CaSO in mass ratio4、CaCl2Mixing is to get desiccant.
Viscosity-controlling agent: hydroxyl sulfate.
Surfactant: 4:2 in mass ratio takes empgen BB, sodium secondary alkyl sulfonate mixing to get surface-active
Agent.
Auxiliary agent: 6:1:2 in mass ratio takes metakaolin, amine carbonate, magnesium stearate mixing to get auxiliary agent.
Poloxamer liquid: 1:5:6 in mass ratio takes the hydrochloric acid solution mixing of poloxamer, ethyl alcohol, concentration 0.1mol/L, i.e.,
Obtain poloxamer liquid.
Maceration extract: 1:3:15 in mass ratio takes the second of the chitosan of deacetylation 90%, Dopamine hydrochloride, mass fraction 10%
Acid solution mixes to get maceration extract.
The preparation method of composite modified polyurethane, includes the following steps:
(1) in 15 DEG C, 1:10 in mass ratio takes the hydrochloric acid solution mixing of sodium metasilicate, concentration 0.1mol/L, and sodium metasilicate quality is added
35% silane coupling agent mixing, reacts 5h, and the NaCl of sodium metasilicate quality 15% and the solvent mixing of sodium metasilicate quality 45% is added,
4h is stirred with 400r/min, stands 40min, filtering takes filtrate 9:1 in mass ratio that desiccant is added, and 15min, room is mixed
For 24 hours, the polyoxypropyleneglycol of filtrate quality 30% is added in the closed standing of temperature, disperses 25min with 300W ultrasonic wave, and decompression filters,
Obtain dispersion liquid；
(2) 90 DEG C are bathed in grease, 1:1:15:2 in mass ratio takes polyoxypropyleneglycol, dihydromethyl propionic acid, dispersion liquid, N- first
The mixing of base pyrrolidones, leads to nitrogen protection, is warming up to 110 DEG C of heat preservation 30min, is cooled to 85 DEG C, obtains mixed reactant, take mixing
Reactant 12:3:1 in mass ratio adds dibutyl tin dilaurate, isophorone diisocyanate mixing, reacts 5h, is cooled to 65
DEG C, feed liquid is obtained, triethylamine, acrylic acid, viscosity-controlling agent mixing and emulsifying is added in feeding liquid 8:1:2:1 in mass ratio, with 500r/
Min shearing dispersion 30min, is added the over cure potassium of feed liquid quality 25%, is warming up to 75 DEG C, keep the temperature 5h, be evaporated under reduced pressure to get multiple
Close modified polyurethane.
The preparation method of complex mesoporous material, includes the following steps:
S1. in 60 DEG C of water-bath, 1:10 in mass ratio takes the NaOH solution mixing of phenol, mass fraction 15%, is stirred with 450r/min
45min, the formalin that the mass fraction for being added 7 times of phenol quality is 25% mix, and are warming up to 85 DEG C, continue to stir 20min,
Cooled to room temperature adjusts pH to 7.2 with the hydrochloric acid solution of concentration 1mol/L, is concentrated under reduced pressure, is evaporated in vacuo to constant weight, obtains instead
Object is answered, takes reactant that 5 times of reactant quality of dehydrated alcohol is added, is uniformly mixed, prefabricated phenolic resin is obtained and mixes liquid；
S2. it takes poloxamer liquid 8:2:4 in mass ratio that the mixed liquid of ethyl orthosilicate, prefabricated phenolic resin is added, is stirred with 350r/min
It mixes, after 100 DEG C of thermal polymerizations for 24 hours, moves to tube furnace, under nitrogen protection, with 10 DEG C/min temperature programming to 500 DEG C of heat preservation 5h
Afterwards, 900 DEG C of heat preservation 2h are warming up to, obtain heat treatment object, after cooled to room temperature, 5 times of heat-treated substance amount of maceration extract is added
5h is impregnated, filtering takes filter residue in 80 DEG C of oven dryings to get complex mesoporous material.
A kind of insulation and fire-proof paint, according to the mass fraction, including following component: 10 parts of auxiliary agents, 8 parts of glass beads, 10 parts
Surfactant, 5 rosin, 40 parts of water, which is characterized in that further include: 45 parts of composite modified polyurethane, 30 parts of composite mesopore materials
Material.
A kind of preparation method of insulation and fire-proof paint, includes the following steps:
(1) according to the mass fraction, take 10 parts of auxiliary agents, 8 parts of glass beads, 10 parts of surfactants, 5 rosin, 40 parts of water, 45 parts it is multiple
Close modified polyurethane, 30 parts of complex mesoporous materials；
(2) auxiliary agent, glass bead, rosin, water is taken to mix in reaction kettle prior to 45 DEG C, after 500r/min magnetic agitation 50min,
Composite modified polyurethane, surfactant, complex mesoporous material mixing is added, with 300W supersonic oscillations 30min, in
0.9MPa, 25 DEG C CO is passed through with 300mL/min2, 4h is stood to get insulation and fire-proof paint.
Comparative example 1: it is essentially identical with the preparation method of embodiment 2, it has only the difference is that lacking composite modified polyurethane.
Comparative example 2: it is essentially identical with the preparation method of embodiment 2, it has only the difference is that lacking complex mesoporous material.
Comparative example 3: the insulation and fire-proof paint of company of Hebei province production.
Embodiment 1,2,3 and comparative example are prepared into insulation and fire-proof paint and carry out Determination of conductive coefficients: by each sample while being set
It moves back to drier and is cooled to room temperature in insulating box, drying to constant weight at a temperature of 378 scholar 5K；Open adding for thermal conductivity test instrument
Each sample is individually placed in heating furnace position above and below testing element by hot stove lid, and the surface of sample each as far as possible keeps more close
Contact, can test after shutting heating furnace cover；General supply is connected, control heating furnace automatic temperature control switch disk is allocated to scheduled control
Furnace temperature (360K, 460K, 560K, 660K, 760K, 860K)；Test macro switch is opened, is entered just to every test condition
Normal state；Automatic calibration knob is opened, correction finishes, and calibrating knob slew test shelves automatically process data through microcomputer
Afterwards, liquid crystal display watch starts to show the mean temperature and thermal coefficient at this temperature of tested sample, and each sample is at each temperature
Thermal coefficient take three to the statistical average of (six pieces) random sampling.Test result such as table 1.
Table 1:
In conclusion as shown in Table 1, insulation and fire-proof paint good heat preservation performance prepared by the present invention, heat resistance are strong, are worth advocating energetically
It uses.
Claims (10)
1. a kind of insulation and fire-proof paint, according to the mass fraction, including following component: 5 ~ 10 parts of auxiliary agents, 3 ~ 8 parts of glass beads, 6 ~
10 parts of surfactants, 2 ~ 5 rosin, 25 ~ 40 parts of water, which is characterized in that further include: 20 ~ 45 parts of composite modified polyurethane, 15 ~
30 parts of complex mesoporous materials.
2. a kind of insulation and fire-proof paint according to claim 1, which is characterized in that the preparation side of the composite modified polyurethane
Method includes the following steps:
(1) in 10 ~ 15 DEG C, 1:5 ~ 10 take sodium metasilicate, hydrochloric acid solution mixing in mass ratio, and the silicon of sodium metasilicate quality 20 ~ 35% is added
The mixing of alkane coupling agent, reacts 3 ~ 5h, and the solvent mixing of NaCl and sodium metasilicate quality 30 ~ 45% that sodium metasilicate quality 8 ~ 15% is added are stirred
It mixes, stands, filtering takes filtrate 4 ~ 9:1 in mass ratio that desiccant is added, it is mixed, closed standing, addition filtrate quality 20 ~
30% polyoxypropyleneglycol, ultrasonic wave dispersion, decompression filter, and obtain dispersion liquid；
(2) in 80 ~ 90 DEG C, 1:1:10 ~ 15:2 in mass ratio takes polyoxypropyleneglycol, dihydromethyl propionic acid, dispersion liquid, N- first
Base pyrrolidones mixing, ventilation protection, is warming up to 100 ~ 110 DEG C of heat preservations, is cooled to 75 ~ 85 DEG C, obtains mixed reactant, take mixing
Reactant 8 ~ 12:1 in mass ratio ~ 3:1 adds dibutyl tin dilaurate, isophorone diisocyanate mixing, reacts 2 ~ 5h, drop
Temperature obtains feed liquid, and triethylamine, acrylic acid, viscosity-controlling agent mixing is added in feeding liquid 4 ~ 8:1:2:1 in mass ratio, and shearing dispersion adds
Enter the over cure potassium of feed liquid quality 16 ~ 25%, heat up, keep the temperature 3 ~ 5h, is evaporated under reduced pressure to get composite modified polyurethane.
3. a kind of insulation and fire-proof paint according to claim 2, which is characterized in that the solvent in the step (1): pressing quality
Take acetone, ethyl alcohol mixing to get solvent than 1:4 ~ 8.
4. a kind of insulation and fire-proof paint according to claim 2, which is characterized in that the desiccant in the step (1): pressing matter
Amount takes CaSO than 5:1 ~ 24、CaCl2Mixing is to get desiccant.
5. a kind of insulation and fire-proof paint according to claim 2, which is characterized in that the viscosity-controlling agent in the step (2):
Urea, hydroxylamine hydrochloride, any one in hydroxyl sulfate.
6. a kind of insulation and fire-proof paint according to claim 1, which is characterized in that the preparation side of the complex mesoporous material
Method includes the following steps:
S1. in 40 ~ 60 DEG C, 1:6 ~ 10 take phenol, NaOH solution to be mixed in mass ratio, and 3 ~ 7 times of formaldehyde of phenol quality are added
Solution mixing, is warming up to 70 ~ 85 DEG C, stirs, cooling, adjusts pH, is concentrated under reduced pressure, and is evaporated in vacuo, obtains reactant, reactant is taken to add
Enter 3 ~ 5 times of reactant quality of dehydrated alcohol, be uniformly mixed, obtains prefabricated phenolic resin and mix liquid；
S2. take poloxamer liquid 5 ~ 8:2:4 in mass ratio that ethyl orthosilicate is added, prefabricated phenolic resin mixes liquid, stirring, hot polymerization
It closes, nitrogen protection, temperature programming to 350 ~ 500 DEG C of heat preservations is warming up to 800 ~ 900 DEG C of 1 ~ 2h of heat preservation, obtains heat treatment object, and it is cooling,
3 ~ 5 times of heat-treated substance amount of maceration extract is added to impregnate, filtering takes filter residue and drying to get complex mesoporous material.
7. a kind of insulation and fire-proof paint according to claim 6, which is characterized in that the poloxamer liquid in the step S2:
1:3 ~ 5:6 in mass ratio takes poloxamer, ethyl alcohol, hydrochloric acid solution mixing to get poloxamer liquid.
8. a kind of insulation and fire-proof paint according to claim 6, which is characterized in that the maceration extract in the step S2: pressing matter
Amount takes chitosan, Dopamine hydrochloride, acetic acid solution mixing to get maceration extract than 1:1 ~ 3:10 ~ 15.
9. a kind of insulation and fire-proof paint according to claim 1, which is characterized in that the surfactant: 4:1 in mass ratio
~ 2 take empgen BB, sodium secondary alkyl sulfonate mixing to get surfactant.
10. a kind of insulation and fire-proof paint according to claim 1, which is characterized in that the auxiliary agent: 6:1:1 ~ 2 in mass ratio
Take metakaolin, amine carbonate, magnesium stearate mixing to get auxiliary agent.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113549190A (en) * | 2021-08-06 | 2021-10-26 | 扬州工业职业技术学院 | Polyurethane bottom material for preparing microfiber leather |
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| CN105968789A (en) * | 2016-04-27 | 2016-09-28 | 宁波高新区夏远科技有限公司 | A light organic-inorganic composite thermal insulation foam material and its preparation method |
| CN107602807A (en) * | 2017-09-30 | 2018-01-19 | 安徽朗凯奇建材有限公司 | A kind of Flame-retardant waterproof material and its preparation technology |
Cited By (1)
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| CN113549190A (en) * | 2021-08-06 | 2021-10-26 | 扬州工业职业技术学院 | Polyurethane bottom material for preparing microfiber leather |
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Application publication date: 20190104 |