CN109627890B - Fluorine-silicon modified water-based marking paint - Google Patents
Fluorine-silicon modified water-based marking paint Download PDFInfo
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- CN109627890B CN109627890B CN201811428661.9A CN201811428661A CN109627890B CN 109627890 B CN109627890 B CN 109627890B CN 201811428661 A CN201811428661 A CN 201811428661A CN 109627890 B CN109627890 B CN 109627890B
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- water
- parts
- agent
- modified
- calcium carbonate
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 69
- 229910001868 water Inorganic materials 0.000 title claims abstract description 54
- 239000003973 paint Substances 0.000 title claims abstract description 43
- ZHPNWZCWUUJAJC-UHFFFAOYSA-N fluorosilicon Chemical compound [Si]F ZHPNWZCWUUJAJC-UHFFFAOYSA-N 0.000 title claims abstract description 15
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical class [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 51
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000000839 emulsion Substances 0.000 claims abstract description 30
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 29
- 238000002360 preparation method Methods 0.000 claims abstract description 18
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 15
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 14
- 239000000080 wetting agent Substances 0.000 claims abstract description 14
- 239000002562 thickening agent Substances 0.000 claims abstract description 13
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 21
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 19
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- 239000011259 mixed solution Substances 0.000 claims description 15
- 239000008367 deionised water Substances 0.000 claims description 13
- 229910021641 deionized water Inorganic materials 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 10
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical group CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 9
- -1 tridecyl octyl Chemical group 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000003999 initiator Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 235000019441 ethanol Nutrition 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 6
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000008247 solid mixture Substances 0.000 claims description 6
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical group N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims description 5
- 239000012986 chain transfer agent Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 3
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 claims description 3
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- 239000007788 liquid Substances 0.000 claims description 3
- 238000006386 neutralization reaction Methods 0.000 claims description 3
- 229940065472 octyl acrylate Drugs 0.000 claims description 3
- 238000010992 reflux Methods 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical group OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 20
- 239000011248 coating agent Substances 0.000 abstract description 18
- 238000001035 drying Methods 0.000 abstract description 8
- 239000003513 alkali Substances 0.000 abstract description 5
- 239000003921 oil Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 8
- 238000010276 construction Methods 0.000 description 8
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- 239000002270 dispersing agent Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000000049 pigment Substances 0.000 description 5
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
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- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
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- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
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- 239000000853 adhesive Substances 0.000 description 3
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- 239000011324 bead Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000011256 inorganic filler Substances 0.000 description 3
- 229910003475 inorganic filler Inorganic materials 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
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- 239000004814 polyurethane Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 2
- 239000012943 hotmelt Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 description 2
- 229910052912 lithium silicate Inorganic materials 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 239000012745 toughening agent Substances 0.000 description 2
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical group C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
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- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- RNFAKTRFMQEEQE-UHFFFAOYSA-N Tripropylene glycol butyl ether Chemical compound CCCCOC(CC)OC(C)COC(O)CC RNFAKTRFMQEEQE-UHFFFAOYSA-N 0.000 description 1
- ZGUQGPFMMTZGBQ-UHFFFAOYSA-N [Al].[Al].[Zr] Chemical compound [Al].[Al].[Zr] ZGUQGPFMMTZGBQ-UHFFFAOYSA-N 0.000 description 1
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- 150000001298 alcohols Chemical group 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
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- 230000036571 hydration Effects 0.000 description 1
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- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
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- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
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- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
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- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
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- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
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- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- Paints Or Removers (AREA)
Abstract
The invention relates to a fluorine-silicon modified water-based marking paint and a preparation method thereof, which comprises 20-30 parts of fluorine-silicon modified water-based acrylic emulsion, 40-50 parts of modified calcium carbonate, 5-8 parts of titanium dioxide, and optionally a wetting agent, a defoaming agent, a thickening agent and a film-forming auxiliary agent. Can greatly improve the drying speed of the coating, and has excellent wear resistance, weather resistance, water resistance and alkali resistance.
Description
Technical Field
The invention relates to a water-based polyacrylic acid coating, in particular to a water-based polyacrylic acid pavement marking. And (4) coating.
Background
The marking paint is classified according to the marking paint recorded in the traffic industry standard JT/T280-2004 pavement marking paint of the people's republic of China from the construction condition to the paint variety: solvent-based coating, hot-melt coating, two-component coating and water-based coating.
CN1156546C protects a water-based road marking reflective coating and a preparation method thereof, and the water-based road marking reflective coating comprises the following raw materials: 68-92 parts of sodium silicate, 7-13 parts of sodium fluosilicate, 4-10 parts of zinc oxide, 9-32 parts of water-soluble acrylic resin, 0.01-0.8 part of titanate, 0.01-0.04 part of silane, 0.2-0.7 part of sodium hexametaphosphate, 0.08-0.12 part of sodium polyacrylate, 1.5-7 parts of alcohol ester, 4-7 parts of titanium dioxide, 4-6 parts of silicon lithium powder, 8-11 parts of heavy calcium carbonate, 19-21 parts of light calcium carbonate, 0.2-0.6 part of dimethyl silicon oil, 1.5-3.5 parts of ethylene glycol, 1.5-2.5 parts of glass beads, 0.3-0.5 part of carboxymethyl cellulose and water as a solvent for dissolving and diluting. The manufacturing method comprises the following steps: (1) taking materials; (2) carrying out reaction; (3) carrying out continuous reaction; (4) dispersing; (5) and (4) mixing. It solves the problems of high cost, complex construction and brittle and falling off of the existing hot-melt road sign reflecting paint at over-high and over-low temperature.
CN102676008B protects a low-temperature-construction water-based pavement marking paint which comprises the following components in percentage by weight: acrylic latex: 15 to 60 percent; defoaming agent: 0.07-0.9%; surfactant (b): 0.05 to 0.5 percent; dispersing auxiliary agent: 0.1 to 1.5 percent; pigment: 3 to 15 percent; filling: 5 to 65 percent; solvent: 0.3 to 5 percent; film-forming auxiliary agent: 1 to 7 percent; an antifreezing agent: 0 to 5.0 percent; rheological aid: 0.05 to 0.8 percent; and the balance: and (3) water. Wherein the antifreeze is alcohols such as propylene glycol, ethanol or methanol, preferably methanol; the acrylic latex may be a water-soluble acrylic latex. The paint can reach and exceed solvent type or hot melt type paint, has low VOC content, can be constructed at normal temperature, can also be constructed and maintained under the condition of low temperature (about minus 5 ℃), can also reach excellent performance, can save organic solvent, reduce air pollution and expand construction conditions; has the characteristics of low energy consumption and environmental protection, and can solve the problems of poor adhesion and the like.
CN102775872A discloses a self-cleaning bi-component road marking paint, which comprises A, B bi-components, wherein the mass ratio of the component A to the component B is 1: 2-2: 1; the formula of the component A comprises the following components in parts by mass: 35-40 parts of prepolymer I, 10-15 parts of modified fluorosilicone resin, 0.3-0.5 part of dispersing agent, 1-3 parts of anti-settling agent, 25-30 parts of pigment, 10-15 parts of filler, 1-3 parts of ultraviolet absorbent, 1-2.5 parts of toughening agent and 0.1-0.3 part of anti-aging agent; the formula of the component B comprises the following components in parts by mass: 35-40 parts of prepolymer II; 0.3-0.5 part of a dispersing agent; 1-3 parts of an anti-settling agent; 30-35 parts of pigment; 15-20 parts of a filler; 1-3 parts of an ultraviolet absorber; 1-2.5 parts of a toughening agent; 0.8-2 parts of a curing agent; 0.1 to 0.3 portion of age resister. Wherein the prepolymer I is alkyl acrylate; the modified fluorosilicone resin is fluorine modified silicone resin; the prepolymer II is alkyl methacrylate; the curing agent is dibenzoyl peroxide (BPO). The modified fluorosilicone resin has super-amphiphobicity (namely hydrophobicity and oleophobicity), can form a lotus effect on the surface of the marking coating, and has the advantages of good coating construction performance, high bonding strength, strong durability, compact marking coating, anti-fouling performance and good guiding and prompting functions on vehicle running; the paint has good self-cleaning effect, prolongs the service life of the marking and improves the use effect of the marking.
CN105017904A discloses a waterborne road sign emulsion, which is composed of the following raw materials in parts by weight: 40-50 parts of anionic self-crosslinking silicone-acrylate emulsion; 1-5 parts of propylene glycol monobutyl ether; 0.5-4 parts of polyacrylamide; 0.2 to 0.5 portion of silicone oil; 5-10 parts of titanium dioxide; 20-60 parts of heavy calcium carbonate; 0.1-0.2 parts of hydroxyethyl cellulose thickener; 0.5-1 part of triethanolamine; 0.5-1 part of a sterilization mildew inhibitor; 1-8 parts of distilled water. The road marking paint can solve the problem that the existing road marking paint is easy to become brittle, the adhesive force is improved, the road marking paint is not easy to fall off, the chemical stability of a paint film is enhanced, the whole paint emulsion has better compatibility, no coloring, hydrolysis resistance, no pollution, and good toughness and heat resistance processability.
CN106609087A discloses a normal temperature type thermoplastic acrylic road marking paint, which is prepared from 20-25 parts of thermoplastic acrylic resin, 10-12 parts of rutile titanium dioxide, 10-20 parts of ground limestone, 5-10 parts of quartz powder, 10-15 parts of ultrafine talcum powder, 5-10 parts of precipitated barium sulfate, 0.5-1 part of dispersant, 1-2 parts of anti-settling agent, 2-4 parts of chlorinated paraffin and 20-25 parts of solvent by mass. The titanium dioxide is nano-grade rutile titanium dioxide. The solvent is a mixed solvent of butyl acetate and toluene. The paint has the characteristics of quick drying, strong adhesive force, long durability, good whiteness, excellent construction performance, good pollution resistance and the like, and has the covering power of less than or equal to 190 g/square meter, solid content of more than or equal to 60 percent, water resistance of more than or equal to 24 hours, alkali resistance of more than or equal to 18 hours, wear resistance of more than or equal to 40mg and viscosity of more than or equal to 60KU (25 ℃).
CN107189595A discloses an environment-friendly road marking paint, which comprises the following components in parts by weight: 35-53 parts of water-based acrylic resin, 0.02-0.05 part of bactericide, 0.7-0.9 part of defoaming agent, 0.6-0.7 part of dispersing agent, 0.02-0.03 part of thickening dispersing agent, 1-2 parts of distilled water, 2-10 parts of titanium dioxide, 33-47 parts of inorganic filler, 0.01-0.02 part of wetting agent, 18-21 parts of glass beads, 4-5 parts of volatile solvent and 2-3 parts of film-forming agent. The inorganic filler is one or more of kaolin, heavy calcium powder, light calcium powder, talcum powder, chlorine-free calcium carbonate and barium sulfate. The coating has the advantages of strong adhesive force, quick drying, good adhesion with glass beads, high hardness, bright color, good weather resistance, wear resistance and skid resistance effects, good visibility at night, no toxicity, no odor, environmental protection, low carbon and energy conservation.
CN107573838B protects a marking paint, which comprises horse oil modified waterborne polyurethane, epoxy acrylate graft modified waterborne polyurethane, bisphenol A epoxy resin, waterborne acrylic emulsion, waterborne polyhydroxy fluorocarbon resin, waterborne lithium silicate, fatty alcohol polyoxyethylene ether, calcium methyl silicate, nano titanium dioxide, nano calcium carbonate, calcined kaolin, calcium chloride, inorganic asbestos fiber, high molecular fiber, sodium methyl disulfonate, hexamethyldisiloxane, tripropylene glycol butyl ether, propylene glycol, ethylene glycol butyl ether, waterborne polyamide wax, organic bentonite, aluminum zirconium coupling agent, silane coupling agent, tetrahydroperfluorodecyl trichlorosilane, polyvinylpyrrolidone, vinyl fatty acid ester, photoinitiator, photosensitive dilution active monomer and pigment; reacting horse oil, formic acid and hydrogen peroxide to obtain epoxy horse oil, and then reacting with anhydrous lactic acid to obtain horse oil modified polyol; reacting maleic anhydride with horse oil to obtain carboxyl-containing horse oil; and (2) reacting the horse oil modified polyol, diisocyanate and the horse oil containing carboxyl to obtain the horse oil modified waterborne polyurethane. The road marking paint has the advantages of good film forming and curing performance, good permeability and adhesion with the road surface, good water resistance, wear resistance, aging resistance, mechanical strength, antifouling and easy-to-clean performance, improved stability and service life of the marking, and good low-temperature crack resistance.
CN108003713A discloses a water-based marking paint and a preparation method and a construction method thereof. Based on the total weight of the water-based marking paint, the water-based marking paint comprises the following components: 15-35 wt% of water-based acrylic emulsion, 5-10 wt% of fluorocarbon emulsion, 5-10 wt% of water-based epoxy emulsion, 1-3 wt% of film-forming assistant, 1-3 wt% of water-based wax emulsion, 0.5-5 wt% of organic bentonite, 0.1-0.5 wt% of defoaming agent, 0.1-0.5 wt% of thickening agent, 10-20 wt% of nano silicon carbide, 15-40 wt% of heavy calcium carbonate, 5-10 wt% of titanium pigment, 1-3 wt% of ethanol, 0.1-0.5 wt% of water-based dispersant, 0.5-1.5 wt% of water-based drier, 0.2-0.5 wt% of multifunctional assistant and the balance of deionized water; the grain diameter of the silicon carbide is 600-900 nm. The water-based marking paint has good quick-drying property, wear resistance, weather resistance and stain resistance.
CN108102490A discloses a water-based heavy paste marking paint and a preparation method thereof. The coating consists of aqueous acrylic emulsion, aqueous dispersant, silicon-aluminum porous microspheres, inorganic filler, chlorinated paraffin, aqueous polyethylene wax emulsion, dichloromethane, ethanol, water, lithium silicate, sodium silicate, edible alkali, sodium chloride, coupling agent, film forming auxiliary agent and pigment; the raw materials act synergistically within a limited dosage range, and the prepared thick-paste marking paint has the advantages of high solid content, high drying speed, strong permeability, strong binding force with the ground, high strength, snow shoveling resistance and rutting resistance, and can be used for scraping construction under the normal temperature condition. The preparation method limits the mixing sequence, heating temperature and stirring time of all raw materials, and carries out emulsification and shearing under a certain pressure condition, so that the prepared thick slurry marking coating has good stability, and the drying speed of the marking prepared from the coating, the binding force with the ground and the marking strength are further improved.
It can be seen that the drying speed, abrasion resistance, weather resistance and water and alkali resistance of the coating are always the properties sought by the prior art, and the prior art selects different types of acrylic emulsion and various auxiliary agents for blending, and ignores the modification of the acrylic emulsion. On the other hand, calcium carbonate currently used in the market has a water content of 3 to 5 wt% and needs to be treated so that the water content thereof is reduced to 0.1 wt% or contains almost no water, and then added to a coating component.
Disclosure of Invention
The invention provides a fluorosilicone modified water-based marking paint and a preparation method thereof, which can greatly improve the drying speed of the paint and have excellent wear resistance, weather resistance, water resistance and alkali resistance. The invention is realized by the following technical scheme:
a fluorine-silicon modified water-based marking paint comprises, by weight, 20-30 parts of fluorine-silicon modified water-based acrylic emulsion, 40-50 parts of modified calcium carbonate, 5-8 parts of titanium dioxide, and optionally a wetting agent, a defoaming agent, a thickening agent and a film-forming aid.
Preferably, the preparation method of the fluorosilicone modified water-based acrylic emulsion comprises the following steps: adding acetone into an initiator, stirring to completely dissolve the initiator, adding a chain transfer agent and the mixed monomer, heating, refluxing and preserving heat for reaction under stirring, cooling to room temperature after the reaction is finished, adding a pH regulator, adding deionized water after neutralization, and distilling and recovering the acetone to obtain a water-based acrylic emulsion; wherein the monomer consists of methyl methacrylate, acrylic acid, hydroxyethyl acrylate, vinyl trimethoxy silane and tridecyl octyl acrylate, and the molar ratio of the monomer is 1-2:1-2:1-2:0.1-0.2: 0.01-0.05;
preferably, the preparation method of the modified calcium carbonate is as follows: dispersing calcium carbonate in deionized water, stirring uniformly under ultrasonic, adding ammonia water, ethyl silicate, absolute ethyl alcohol and deionized water, stirring uniformly at room temperature to obtain a mixed solution, standing the mixed solution until the mixed solution is naturally dried to obtain a solid mixture, heating the solid mixture to the temperature of 100-150 ℃, and keeping the temperature for 1-2 hours to obtain a compound, and grinding the compound into powder to obtain silicon dioxide coated calcium carbonate powder; wherein the calcium carbonate dispersion liquid: ammonia water: ethyl silicate: anhydrous ethanol: the volume ratio of the deionized water is 15-25:0.5-2:4-6:4-6: 0.5-1.5.
Preferably, the chain transfer agent in the preparation method of the fluorine-silicon modified water-based acrylic emulsion is mercaptoethanol; the pH regulator is triethylamine; the initiator is azobisisobutyronitrile.
Preferably, the calcium carbonate in the preparation method of the modified calcium carbonate is 800-1000 meshes.
Preferably, the wetting agent is
American cyanogen super-efficient wetting agent ot-75.
Preferably, the coalescent is an alcohol ester twelve.
Preferably the anti-foaming agent is one of the aqueous anti-foaming agents OS-5201, FoamStar A10.
Preferably the thickener is Rohm and Hass ASE-60.
Preferably, the titanium dioxide is rutile titanium dioxide R800.
The invention also provides a preparation method of the water-based marking paint, which comprises the following steps:
mixing the fluorine-silicon modified water-based acrylic emulsion, the defoaming agent and the titanium dioxide at a low speed, and stirring until the mixture is uniformly mixed to obtain a mixed solution;
adding modified calcium carbonate, a wetting agent, a thickening agent and a film-forming auxiliary agent into the mixed solution, uniformly stirring, filtering, and standing the filtrate to obtain the water-based marking paint.
Detailed Description
Preparation of fluorine-silicon modified water-based acrylic emulsion
Adding acetone into an initiator azodiisobutyronitrile, stirring to completely dissolve the initiator, adding a chain transfer agent mercaptoethanol and a well-mixed monomer, heating to a reflux state under stirring, carrying out heat preservation reaction, cooling the obtained mixture to room temperature after the reaction is finished, adding triethylamine, neutralizing, stirring, adding deionized water after the neutralization is finished, stirring for hydration, distilling and recovering an acetone solvent, and thus obtaining the water-based acrylic emulsion. Wherein the monomer molar ratio of methyl methacrylate, acrylic acid, hydroxyethyl acrylate, vinyl trimethoxy silane and tridecyl octyl acrylate is 1:1:1:0.1: 0.02.
Preparation of modified calcium carbonate
Dispersing calcium carbonate in deionized water, stirring uniformly under ultrasound, adding ammonia water, ethyl silicate, absolute ethyl alcohol and deionized water, stirring uniformly at room temperature to obtain a mixed solution, standing the mixed solution until the mixed solution is naturally dried to obtain a solid mixture, heating the solid mixture to 120 ℃ and keeping the temperature for 1.5 hours to obtain a compound, and grinding the compound into powder to obtain silicon dioxide coated calcium carbonate powder; wherein the calcium carbonate dispersion liquid: ammonia water: ethyl silicate: anhydrous ethanol: the volume ratio of the deionized water is 20:1:5:5: 1. Preparation of the coating
Example 1
Mixing the fluorine-silicon modified water-based acrylic emulsion, the defoaming agent and the titanium dioxide at a low speed, and stirring until the mixture is uniformly mixed to obtain a mixed solution; adding modified calcium carbonate, a wetting agent, a thickening agent and a film-forming auxiliary agent into the mixed solution, uniformly stirring, filtering, and standing the filtrate to obtain the water-based marking paint. Wherein, 25 parts of fluorine-silicon modified water-based acrylic emulsion, 45 parts of modified calcium carbonate, 8 parts of titanium dioxide, 1.5 parts of wetting agent, 1 part of defoaming agent, 0.5 part of thickening agent and 0.2 part of film-forming additive.
Example 2
The procedure is as in example 1 except that no thickener is added.
Example 3
The procedure of example 1 was repeated except that no wetting agent was added.
Example 4
The procedure is as in example 1 except that no film-forming aid is added.
Comparative example 1
Calcium carbonate was unmodified, other example 1.
Comparative example 2
The procedure of example 1 was repeated except that the fluorosilicone-modified acrylic emulsion was not used.
Comparative example 3
The procedure of example 1 was repeated, except that neither the fluorosilicone-modified acrylic emulsion nor the calcium carbonate-modified acrylic emulsion was used.
The performance of the waterborne coatings was tested according to JT/T280-2004 and the results are shown in Table 1 below.
TABLE 1 Properties of the Water-borne coatings
Claims (8)
1. A fluorine-silicon modified water-based marking paint comprises, by weight, 20-30 parts of fluorine-silicon modified water-based acrylic emulsion, 40-50 parts of modified calcium carbonate, 5-8 parts of titanium dioxide, and optionally a wetting agent, a defoaming agent, a thickening agent and a film-forming aid, wherein the preparation method of the fluorine-silicon modified water-based acrylic emulsion comprises the following steps: adding acetone into an initiator, stirring to completely dissolve the initiator, adding a chain transfer agent and the mixed monomer, heating, refluxing and preserving heat for reaction under stirring, cooling to room temperature after the reaction is finished, adding a pH regulator, adding deionized water after neutralization, and distilling and recovering the acetone to obtain a water-based acrylic emulsion; wherein the monomer consists of methyl methacrylate, acrylic acid, hydroxyethyl acrylate, vinyl trimethoxy silane and tridecyl octyl acrylate, and the molar ratio of the monomer is 1-2:1-2:1-2:0.1-0.2: 0.01-0.05;
the preparation method of the modified calcium carbonate comprises the following steps: dispersing calcium carbonate in deionized water, stirring uniformly under ultrasonic, adding ammonia water, ethyl silicate, absolute ethyl alcohol and deionized water, stirring uniformly at room temperature to obtain a mixed solution, standing the mixed solution until the mixed solution is naturally dried to obtain a solid mixture, heating the solid mixture to the temperature of 100-150 ℃, and keeping the temperature for 1-2 hours to obtain a compound, and grinding the compound into powder to obtain silicon dioxide coated calcium carbonate powder; wherein the calcium carbonate dispersion liquid: ammonia water: ethyl silicate: anhydrous ethanol: the volume ratio of the deionized water is 15-25:0.5-2:4-6:4-6: 0.5-1.5.
2. The fluorosilicone modified aqueous reticle paint of claim 1, wherein in the preparation method of the fluorosilicone modified aqueous acrylic emulsion, the chain transfer agent is mercaptoethanol; the pH regulator is triethylamine; the initiator is azobisisobutyronitrile.
3. The fluorosilicone modified aqueous reticle paint of claim 1, wherein the calcium carbonate in the preparation method of the modified calcium carbonate is 800-1000 mesh.
4. The fluorosilicone modified aqueous reticle paint of any one of claims 1 to 3, wherein the wetting agent is cf-10 or the american cyanide high performance wetting agent ot-75; the film-forming additive is alcohol ester twelve; the defoaming agent is one of aqueous defoaming agents OS-5201 and FoamStar A10.
5. The fluorosilicone modified aqueous reticle paint of any one of claims 1 to 3, wherein the thickener is Rohm and Hass ASE-60.
6. The fluorosilicone modified water-based reticle paint according to any one of claims 1 to 3, wherein the titanium dioxide is rutile type titanium dioxide R800.
7. A method for preparing the fluorosilicone modified water-based reticle paint of any one of claims 1 to 6, comprising the steps of:
mixing the fluorine-silicon modified water-based acrylic emulsion, the defoaming agent and the titanium dioxide at a low speed, and stirring until the mixture is uniformly mixed to obtain a mixed solution;
adding modified calcium carbonate, a wetting agent, a thickening agent and a film-forming auxiliary agent into the mixed solution, uniformly stirring, filtering, and standing the filtrate to obtain the water-based marking paint.
8. The method of claim 7, comprising 1 to 2 parts of a wetting agent, 1 to 2 parts of a defoaming agent, 0.2 to 1 part of a thickener, and 0.1 to 0.5 part of a film-forming aid.
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| CN110757851B (en) * | 2019-10-30 | 2021-07-06 | 常州乐棋舒康纺织有限公司 | Oil-proof and water-proof tablecloth production process |
| CN113025147A (en) * | 2019-12-09 | 2021-06-25 | 广东顺德三和化工有限公司 | Water-based wall surface hand-sprayed paint and preparation method thereof |
| CN112795246A (en) * | 2021-01-15 | 2021-05-14 | 湖州和悦新材料科技股份有限公司 | A kind of water-based fluorocarbon outdoor paint and preparation method thereof |
| CN115449348B (en) * | 2022-10-12 | 2023-06-27 | 江西广源化工有限责任公司 | Grinding aid and preparation method and application thereof |
| CN115521678A (en) * | 2022-10-24 | 2022-12-27 | 金华市美林涂料有限公司 | Single-component water-based quick-drying wood paint and preparation method thereof |
| CN115895373A (en) * | 2022-11-14 | 2023-04-04 | 金华市美林涂料有限公司 | Outdoor wood lacquer containing inorganic resin and preparation method thereof |
| CN117070114B (en) * | 2023-10-18 | 2023-12-26 | 广州中海涂装科技有限公司 | Quick rain-resistant weather-resistant water-based silicon-fluorine acrylic finish paint and preparation method thereof |
| CN118222146B (en) * | 2024-03-14 | 2025-12-05 | 金华市普慧涂料有限公司 | A water-based artistic coating and its preparation method |
| CN119931468B (en) * | 2025-04-03 | 2025-08-01 | 四川兄弟路标科技有限公司 | Quick-drying modified road marking paint and preparation method thereof |
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| CN101463108A (en) * | 2008-12-29 | 2009-06-24 | 西北师范大学 | Organosilicon modified tert-fluoro emulsion and preparation of luminescent coating with the emulsion as base material |
| CN102277060A (en) * | 2011-08-10 | 2011-12-14 | 天津大学 | Hydrophobic ice-snow preventing coating material of fluorosilicone acrylate copolymer and preparation method of coating layer thereof |
| CN102676008B (en) * | 2012-06-05 | 2014-12-03 | 浙江永固为华涂料有限公司 | Water-based pavement marking coating with low-temperature constructability and preparation method thereof |
| CN105131786B (en) * | 2015-08-21 | 2017-07-18 | 山东大学 | A kind of environmentally friendly anticorrosive paint, preparation method and its painting method |
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Denomination of invention: A Fluorosilicone Modified Waterborne Marking Paint Effective date of registration: 20221124 Granted publication date: 20200825 Pledgee: Changxin Zhejiang rural commercial bank Limited by Share Ltd. Pledgor: ZHEJIANG OLD TRAFFIC TECHNOLOGY Co.,Ltd. Registration number: Y2022980023174 |