CN109629097A - Antistatic light luxurious worsted fabric - Google Patents
Antistatic light luxurious worsted fabric Download PDFInfo
- Publication number
- CN109629097A CN109629097A CN201811559097.4A CN201811559097A CN109629097A CN 109629097 A CN109629097 A CN 109629097A CN 201811559097 A CN201811559097 A CN 201811559097A CN 109629097 A CN109629097 A CN 109629097A
- Authority
- CN
- China
- Prior art keywords
- fiber
- wool
- minutes
- water
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 230000007547 defect Effects 0.000 claims abstract 2
- 238000009958 sewing Methods 0.000 claims abstract 2
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 102
- VFLDPWHFBUODDF-FCXRPNKRSA-N curcumin Chemical compound C1=C(O)C(OC)=CC(\C=C\C(=O)CC(=O)\C=C\C=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-FCXRPNKRSA-N 0.000 claims description 100
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- VFLDPWHFBUODDF-UHFFFAOYSA-N diferuloylmethane Natural products C1=C(O)C(OC)=CC(C=CC(=O)CC(=O)C=CC=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-UHFFFAOYSA-N 0.000 claims description 49
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 48
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- 238000007654 immersion Methods 0.000 claims 2
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
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- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical group [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 125000001493 tyrosinyl group Chemical group [H]OC1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])(N([H])[H])C(*)=O 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/22—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration
- D04B1/24—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes specially adapted for knitting goods of particular configuration wearing apparel
- D04B1/246—Upper torso garments, e.g. sweaters, shirts, leotards
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/59—Polyamides; Polyimides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/02—Wool
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Woven Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Coloring (AREA)
Abstract
本发明公开了抗静电轻奢精纺毛织物，使用包括以下步骤的工艺制备得到：A络筒：去除纱线瑕疵，将纱线络筒；B毛织：根据电脑录入的版型将络筒后的纱线编织成型，得到前后片、衣领和袖子；C毛盘：将前后片、衣领和袖子缝合，获得成衣；D修理：人工去除成衣缝合产生的线头；E整理；F蒸汽定型。本发明所述抗静电轻奢精纺毛织物与普通仿毛织物比较，手感丰满，弹性好，低静电，克服了手感差、弹性回复不好、起静电等缺点，不仅服用性能好，舒适透气吸湿，而且富有弹性，毛织物风格强，能保持服装的外形美观。The invention discloses an antistatic light luxury worsted woolen fabric, which is prepared by a process comprising the following steps: A winding: removing yarn defects, and winding the yarn; B woolen fabric: winding the winding according to the pattern entered by the computer The final yarn is knitted and formed to obtain front and rear pieces, collars and sleeves; C wool disc: sew the front and rear pieces, collars and sleeves to obtain garments; D Repair: Manually remove the thread ends produced by the sewing of garments; E Finishing; F Steam setting . Compared with ordinary wool-like fabrics, the antistatic light luxury worsted fabric of the present invention has fuller hand feeling, good elasticity and low static electricity, overcomes the disadvantages of poor hand feeling, poor elastic recovery and static electricity, and not only has good wearing performance, but also is comfortable and breathable. It is hygroscopic and elastic, and the wool fabric has a strong style, which can keep the appearance of the garment beautiful.
Description
Technical field
The present invention relates to textile technology fields, more particularly to antistatic light luxurious worsted fabric.
Background technique
With the continuous improvement of social and economic level, more and more functional textiles are familiar with and are received by people,
Wool fabric is liked with its warming performance by people.But wool fabric equally exists certain disadvantage, for example is easy to produce quiet
Electricity influences its wearing comfort and application range to bring some unnecessary troubles during taking and wearing.It is existing
It is some wool fabric be usually arranged by the postfinishing process of antistatic finishing agent, arrangement after fabric it is antistatic
Performance lasting not strong, after taking a period of time, after repeatedly washing dress, antistatic effect is decreased obviously, if can mention
For a kind of compound wool fabric itself with antistatic anti-static ability, it will solve the above problems.
Application number 201610462828.8 discloses a kind of the hydrophilic of single side wool fabric, antistatic finish device and arrangement side
Method, the collating unit is by high pressure generator, electrode group, treatment tube, hydrophilic finishing agent sprayer, drying unit, feed preparation unit roller, receipts cloth
Rod composition, it adds hydrophilic finishing agent using atmospheric pressure lower class glow discharge region using the principle of Glow-like discharge under atmospheric pressure
Sprayer and the structure of drying are used for the hydrophilic modification of wool fabric single side.Uniform " mist " electric discharge is generated, so that voltage is equal
Even processing wool fabric single side, will not generate voltage breakdown, influence the back side of process face.Meanwhile hydrophilic finishing agent sprayer hangs down
Directly one-sided spraying processing is carried out in wool fabric cloth cover.The modified wool fabric obtained in this way is that a kind of single side is hydrophilic, anti-
Electrostatic wool fabric.
Application number 201710907203.2 discloses the antistatic compound wool fabric of one kind and its blending method, including 50%
~80% wool fiber, 10%~40% wool blended fiber, 5% antistatic finishing agent；First by villus fiber, chamber hair
Fiber, the blended of coarse wool fibre and wool fiber are wool fiber, then carry out blended, the Zhi Houzai of three kinds of wool blended fibers respectively
Compound at wool blended fiber, finally by wool fiber made of compound and wool blended fiber carry out it is blended be prepared into it is compound
Wool fabric, the present invention pass through the ratio and type of the various fibers of rational allocation, and are aided under the action of antistatic finishing agent,
So that compound wool fabric has both more preferably comfortable pliability while having excellent antistatic property, and has and more preferably protect
Warm performance, suitable for the production of winter various wool fabrics, and wash durability and long service life.
Summary of the invention
The present invention is intended to provide a kind of antistatic light luxurious worsted fabric, antistatic property, color fastness, pilling resistance and
Wrinkle resistance is all better than common wool-like fabric, has relatively good wearability.
Based on this, the invention discloses a kind of antistatic light luxurious worsted fabrics, use the technique system included the following steps
It is standby to obtain:
A winder: removal yarn flaws, by yarn bobbin winding；
B woolens: according to the version type of computer data inputting by the yarn knitting forming after winder, front and rear panel, collar and sleeve are obtained；
C hair disc: front and rear panel, collar and sleeve are sutured, and obtain ready-made clothes；
D is repaired: the end of a thread that the suture of artificial removal's ready-made clothes generates；
E final finishing；
F steam shaping.
Further, wool fiber, creeping chill dye after antistatic light luxurious worsted fabric of the present invention is dyed with creeping chill
The yarn that the Supercool fiber blend after vinegar blueness fiber and creeping chill dyeing after color obtains is as raw material, using including following
The technique of step is prepared:
The dyeing of A wool fiber creeping chill；
The dyeing of B vinegar blueness fiber creeping chill；
The dyeing of C Supercool fiber creeping chill；
D is blended: after wool fiber after creeping chill is dyed, the vinegar blueness fiber after creeping chill dyeing and creeping chill dyeing
Supercool fiber is according to mass ratio (1~3): (1~3): (1~3) is blended, obtains scribbled；
E winder: removing the flaw of scribbled, by scribbled winder；
F woolens: according to the version type of computer data inputting by the scribbled knitting forming after winder, obtain front and rear panel, collar and
Sleeve；
G hair disc: front and rear panel, collar and sleeve are sutured, and obtain ready-made clothes；
H is repaired: the end of a thread that the suture of artificial removal's ready-made clothes generates；
I final finishing；
J steam shaping.
Wool fiber is due to thermal conductivity is small, warmth retention property is good, scale layer is hydrophobic etc., seldom in black or deep purplish blue color etc.
Dark color is to use on fabric.But black and navy blue are one of high-end situation of selling well Fabrics classics colour systems, are passed through in the present invention
Wool fiber, vinegar blueness fiber and Supercool fiber are subjected to cold black dyeing, dark fabric is obtained, makes dark fabric to light
Reflectivity up to 60~80%, become reflecting thermal energy from absorption thermal energy；Meanwhile by wool fiber, vinegar blueness fiber and
Supercool fiber it is blended, increase the moisture absorbing and sweat releasing ability of wool fabric, solve wool worsted fabric not absorbing sweat, asking of not perspiring
Topic.
Further, wool fiber, creeping chill dye after antistatic light luxurious worsted fabric of the present invention is dyed with creeping chill
The yarn that the Supercool fiber blend after vinegar blueness fiber and creeping chill dyeing after color obtains is as raw material, using including following
The technique of step is prepared:
A wool fiber creeping chill dyeing: by wool fiber and water with weight ratio 1:(15~20) it mixes, it is warming up to 40~45
℃；It is subsequently added into 0.5~1%owf defoaming agent, 3~5%owf anhydrous sodium sulphate, and adjusts pH value to 4.0~4.4 using glacial acetic acid,
Stirring 5~10 minutes；The cold black dyes of 5.5~8.7%owf are then added, stir 5~10 minutes；It is continuously heating to 95~
98 DEG C, keep the temperature 40~50 minutes；After heat preservation, dye liquor is released, with wool fiber and water weight ratio 1:(15~20) it is added
Water, adds the wool softening agent CS-82D-73 of 2~3%owf, and stirring 5~after ten minutes；70~80 DEG C are then warming up to, is protected
Temperature 15~30 minutes, releases water, drains, the wool fiber after being dyed；
The dyeing of B vinegar blueness fiber creeping chill: it is woolen dyed identical in staining procedure and step A, wool fiber is only replaced with into vinegar
Green fiber；
C Supercool fiber creeping chill dyeing: by Supercool fiber and water with mass ratio 1:(15~20) it mixes, it rises
Temperature is to 40~45 DEG C；It is subsequently added into the nonionic penetrant of 2~3%owf, and adjusts pH value to 4.5~5.5 using glacial acetic acid；
It is subsequently added into the creeping chill auxiliary agent LT-JLG01 of 1~3%owf, is stirred 5~10 minutes；The Foron that 2~5%owf is then added is red
Beautiful dyestuff stirs 5~10 minutes；100~110 DEG C are warming up to, is stirred 5~10 minutes；After terminating stirring, it is warming up to 130~135
DEG C, keep the temperature 40~50 minutes；After heat preservation, dye liquor is released, is drained, the Supercool fiber after being dyed；
D is blended: after wool fiber after creeping chill is dyed, the vinegar blueness fiber after creeping chill dyeing and creeping chill dyeing
Supercool fiber is according to mass ratio (1~3): (1~3): (1~3) is blended, obtains scribbled；
E winder: removing the flaw of scribbled, by scribbled winder；
F woolens: according to the version type of computer data inputting by the scribbled knitting forming after winder, obtain front and rear panel, collar and
Sleeve；
G hair disc: front and rear panel, collar and sleeve are sutured, and obtain ready-made clothes；
H is repaired: the end of a thread that the suture of artificial removal's ready-made clothes generates；
I is arranged: the ready-made clothes after removal the end of a thread is immersed to the waterborne organic silicon polyurethane finishing agent aqueous solution of 20~40g/L
In, bath raio 1:(10~40), it is stirred 40~100 minutes in 40~65 DEG C；After the completion of stirring, ready-made clothes is taken out, washing is arranged
Fabric afterwards；
J steam shaping: by the fabric after arrangement in 110~120 DEG C steam ironing 4~8 minutes.
It is worth noting that, on the basis of fabric weight, the fabric dye dosage of 100 kilograms of dye is concentration in dyeing and finishing technology
4%owf refers to that is contaminating the dyestuff that these fabrics need 100 × 0.04=4 kilograms.Bath raio refers to weight ratio.
Further, the wool fiber is Conventional wool fiber or modified woolen fiber.
Further, the preparation process of the modified woolen fiber are as follows:
(1) dichloroisocyanuric acid salt pre-process: after wool fiber is washed with 40~50 DEG C of hot water, 20~30 DEG C two
With bath raio 1:(20~30 in chlorine isocyanurate pretreatment fluid) dipping 30~50 minutes；After pulling out, in mass fraction 3~4%
Solution of sodium bisulfite in bath raio 1:(20~30) dipping 20~50 minutes after, the phosphate 30~40 DEG C of pH7~9
With bath raio 1:(20~30 in buffer) dipping 10~30 minutes；Wool fiber after finally pulling phosphate buffer dipping out,
It is washed with cold water, 45~55 DEG C of drying are stand-by；The composition of the dichloroisocyanuric acid salt pretreatment fluid are as follows: dichloroisocyanuric acid salt
0.02~0.06g/L, nonionic penetrant 1~2g/L of JFC, surplus are water, pH3.5~4.5；
(2) by the pretreated wool fiber of dichloroisocyanuric acid salt with bath raio 1:(20~30) it is impregnated at polylysine
It manages in liquid, is stirred 12~16 hours at 40~50 DEG C, then pull wool fiber out, washed with cold water, 45~55 DEG C of drying are stand-by；
The polylysine treatment fluid the preparation method is as follows: to pH value be 6.5~6.8 phosphate buffer in add its weight
0.02~0.04 times of epsilon-polylysine and 0.02~0.04 times of glutamy transaminase, mix well to obtain the final product.
Further, the composition of the cold black dyes are as follows: 5.1~7wt% of curcumin, orchid take in the fresh green F-BL 4.3~
5.5wt%, 0.2~1.5wt% of levelling agent, 13~20wt% of sulphur ammonium, surplus are the dark blue S-3G in nylon mountain.
Further, the composition of the cold black dyes are as follows: esterification 5.1~7wt% of curcumin, orchid are taken in the fresh green F-BL
4.3~5.5wt%, 0.2~1.5wt% of levelling agent, 13~20wt% of sulphur ammonium, surplus are the dark blue S-3G in nylon mountain, wherein described
Being esterified curcumin is ethyl esterified curcumin and/or butyl ester curcumin.
Further, the composition of the cold black dyes are as follows: esterification 5.1~7wt% of curcumin, orchid are taken in the fresh green F-BL
4.3~5.5wt%, 0.2~1.5wt% of levelling agent, 13~20wt% of sulphur ammonium, 0.1~0.3wt% of antioxidant, surplus are nylon
The dark blue S-3G in mountain, wherein the esterification curcumin is ethyl esterified curcumin and/or butyl ester curcumin.
In above-mentioned three kinds of technical solutions, the levelling agent is levelling agent SET or cardanol polyoxyethylene ether sodium sulfovinate.
Preferably, the antioxidant is n -Propyl gallate and/or Quercetin.It is highly preferred that the antioxidant is not
The mixture that gallate-based n-propyl and Quercetin are formed with mass ratio 1:1.
Further, the preparation process of the antistatic light luxurious worsted fabric further includes dedusting and quality inspection packaging.
Usual wool fiber seldom uses in summer fabric, first, the hydrophobicity of wool fiber scale makes human body sweat again
Liquid cannot export volatilization in time, skintight suit used time summer, people be allowed to have feeling of oppression and heat；Second, wool surface has lipoid knot
The scale layer of structure, hydrophobicity is big, when envionmental humidity is lower than 40%, can generate electrostatic phenomenon, easily absorption dust, influences
Woolen appearance and comfort during taking, does not meet modern society to the demand of wearing easy to maintain arranged well.So
By on the one hand improving the wool fiber and vinegar blueness fiber, the use of Supercool fiber blend after hydrophilic modifying in the present invention
The antistatic property of fabric solves the problems, such as the easy dust suction soil pick-up of summer fabric, on the other hand improves the hydrophily of fabric, and wet work is led in quickening
It is obtained being suitable for that the moisture conductive quick-drying taken of summer dress, cool feeling be comfortable, antistatic dark woolens antifouling, elasticity is crease-resistant with, exploitation
Object plane material.
For antistatic light luxurious worsted fabric of the present invention compared with common wool-like fabric, good hand feeling, elasticity is good, low quiet
Electricity, overcome feel is poor, elastic recovery is bad, rise electrostatic the disadvantages of, not only wearability is good, comfortable ventilating moisture absorption, Er Qiefu
Flexible, woolen style is strong, is able to maintain the good appearance of clothes.
Specific embodiment
Raw material is described below in embodiment:
Wool fiber, Nanjing Hua Tai felt factory provide, and 19.8 μm of average fineness, fineness discrete 19.9%, Hauteur
89.5mm, discrete length 36.8%.
Vinegar blueness fiber, Jilin grotesque peak company, chemical fibre group provide, fibre fineness 1.33dtex.Vinegar blueness fiber and general nitrile
Synthetic fibre fiber is compared, and strength is high, and wearability is good, has good warmth retention property, comfort and dimensional stability, and antistatic property is changed
It is kind, electrostatic can be accumulated to avoid due to friction, enable a wearer to feel comfortable.
Supercool fiber, Shanghai is expensive to be provided up to company, average fineness 2.0D, Hauteur 84.8mm, length variation system
Number 21.1%.For Supercool fiber compared with common polyester fiber, specific surface area increases by 100% or more, not only increases moisture absorption
Face accelerates wet guilding, but also increases the evaporating surface of sweat, reaches quickening and perspires effect；In addition, due to the surface ditch of fiber
Slot can form numerous capillary effects in fabric construction, and sweat can be made to make through a series of wicking such as moisture absorption, conduction, evaporation
With, rapidly by skin sweat and moisture transfer transport fabric surface and be dispersed into air, thus reach moisture absorbing and sweat releasing, steam
Hair heat absorption, adjust body temperature purpose, make skin keep it is dry and comfortable with it is pleasantly cool.
High speed cone winder, by Wuxi City three, sharp Textile Machinery Co., Ltd is provided.
Defoaming agent, the new ten thousand one-tenth Environmental Protection Technology Co., Ltd in Hefei, model F4168A, main component butadiene-styrene latex.
Anhydrous sodium sulphate, No. CAS: 7757-82-6, Huaian Hong Yu Chemical Co., Ltd. provides, 100 mesh of granularity.
Wool softening agent CS-82D-73, Hebei multidimensional health auxiliary agent Co., Ltd provide, model C S-82D-73, main component
It is the organic silicon emulsion containing active group.
The dark blue S-3G in nylon mountain, Kai Da dye chemical industry Co., Ltd provide, and brand Klein, model S-3G belongs to weak acid
Property dyestuff.
Orchid is taken in the fresh green F-BL, and Shanghai Ping Bo trade Co., Ltd provides, and model F-BL belongs to acid dyes.
Levelling agent SET, Jiangsu Tang Mu textile technology Co., Ltd provide, and model SET belongs to amphoteric ion levelling agent.
Sulphur ammonium, i.e. ammonium sulfate, Hong Jiafu Science and Technology Ltd., Changshu City provide, No. CAS: 7783-20-2, model KD-21.
Nonionic penetrant JFC, Zhuo Yuan Chemical Co., Ltd., Shaoxin City provide, main component 2-Ethylhexyl Alcohol and epoxy second
The polyethers of alkane synthesis.
Creeping chill auxiliary agent LT-JLG01, upper sea green copper goods and materials Co., Ltd provide, and main composition is xylitol and peppermint.
Foron ruby dye, Kai Da Chemical Co., Ltd. provide, brand Clariant, model s-wf, specification 33mm.
The embodiment one of waterborne organic silicon polyurethane finishing agent, referenced patent application number 201410571017.2 is prepared into
It arrives.
PH value be 6.5 phosphate buffer, by 31.5mL molar concentration 0.2mol/L disodium phosphate soln and
The sodium dihydrogen phosphate of 68.5mL molar concentration 0.2mol/L is mixed to get.
Epsilon-polylysine, Nanjing Xin Jiehui Biotechnology Co., Ltd provide.
Glutamy transaminase, Shandong Sheng Xie Biotechnology Co., Ltd provide, 100,000 U/g of enzyme activity.
Hydrogen peroxide, the hydrogen peroxide of specifically used mass fraction 50%.
It soaps liquid, the soap flakes and water provided by Wuxi Rui Xi International Trading Company Ltd are mixed to get with mass ratio 1:25.
Dichloroisocyanuric acid salt, No. CAS: 2782-57-2.
The phosphate buffer of pH8, by the disodium phosphate soln of 94.7mL molar concentration 0.2mol/L and 5.3mL moles
The sodium dihydrogen phosphate of concentration 0.2mol/L is mixed to get.
The preparation of ethyl esterified curcumin: curcumin is dissolved in acetone with solid-to-liquid ratio 1:45 (g/mL), is slowly added to second
The solid-to-liquid ratio of acid anhydrides and p-methyl benzenesulfonic acid, curcumin and acetic anhydride is 1:5 (g/mL), the quality of curcumin and p-methyl benzenesulfonic acid
Than being heated to 60 DEG C with 2 DEG C/min for 1:0.02, reacted 6 hours in 60 DEG C；Reaction gained mixture is removed in 55 DEG C of heating
Acetone pours into distilled water after being sufficiently stirred, and methylene chloride is added and extracts 3 times to remove acetic anhydride；Lower layer's organic phase is taken, in 50
Methylene chloride is removed in DEG C heating, obtains the ethyl esterified curcumin.
The preparation of butyl ester curcumin: curcumin is dissolved in acetone with solid-to-liquid ratio 1:45 (g/mL), is slowly added to fourth
The mass ratio of acid anhydrides and p-methyl benzenesulfonic acid, curcumin and butyric anhydride is 1:2, and the mass ratio of curcumin and p-methyl benzenesulfonic acid is 1:
0.02,65 DEG C are heated to 2 DEG C/min, is reacted 7 hours in 65 DEG C；Reaction gained mixture removes acetone in 55 DEG C of heating,
Enter after being sufficiently stirred in distilled water, methylene chloride is added and extracts 3 times to remove acetic anhydride；Lower layer's organic phase is taken, is heated in 50 DEG C
Methylene chloride is removed, the ethyl esterified curcumin is obtained.
Curcumin, No. CAS: 458-37-7.
N -Propyl gallate, No. CAS: 121-79-9.
Quercetin, No. CAS: 117-39-5.
Cardanol polyoxyethylene ether sodium sulfovinate with reference to Cai Xiang Master's thesis " synthesis of cashew nut phenols surfactant and its
Application in high temperature levelling agent " it is prepared.
In the unspecified situation of the present invention, speed of agitator is 100 revs/min.
Embodiment 1
Antistatic light luxurious worsted fabric, vinegar blueness fiber after wool fiber, creeping chill dyeing after being dyed with creeping chill and cold
The yarn that Supercool fiber blend after infection color obtains is prepared as raw material using the technique included the following steps:
The dyeing of A wool fiber creeping chill: by wool fiber and water with weight ratio 1:15 mixing, 40 are warming up to 2 DEG C/min
℃；It is subsequently added into 1%owf defoaming agent FFA, 5%owf anhydrous sodium sulphate, and adjusting pH value using glacial acetic acid is 4.2, is stirred 10 minutes；
The cold black dyes of 7.5%owf are then added, stir 10 minutes；98 DEG C are warming up to 0.8 DEG C/min, keeps the temperature 50 minutes；It protects
After temperature, dye liquor is released, water is added with wool fiber and water weight ratio 1:15, adds the wool softening agent of 3%owf
CS-82D-73, stirring is after five minutes；80 DEG C then are warming up to 2 DEG C/min, 30 minutes is kept the temperature, water is released, is drained, is obtained
Wool fiber after dyeing；The composition of the cold black dyes are as follows: curcumin 6.4wt%, orchid are taken in the fresh green F-BL 4.6wt%,
Levelling agent SET 1wt%, sulphur ammonium 17wt%, surplus is the dark blue S-3G in nylon mountain；
The dyeing of B vinegar blueness fiber creeping chill: it is woolen dyed identical in staining procedure and step A, wool fiber is only replaced with into vinegar
Green fiber；
C Supercool fiber creeping chill dyeing: by Supercool fiber and water with mass ratio 1:15 mixing, with 2 DEG C/minute
Clock is warming up to 45 DEG C；It is subsequently added into the nonionic penetrant JFC of 3%owf, and adjusts pH value to 5.5 using glacial acetic acid；Then plus
Enter the creeping chill auxiliary agent LT-JLG01 of 3%owf, stirs 10 minutes；The Foron ruby dye of 5%owf is then added, stirs 10 points
Clock；110 DEG C are warming up to 1.2 DEG C/min, is stirred 5 minutes；After terminating stirring, 130 DEG C are warming up to 1 DEG C/min, heat preservation 50
Minute；After heat preservation, dye liquor is released, is drained, the Supercool fiber after being dyed；
D is blended: after wool fiber after creeping chill is dyed, the vinegar blueness fiber after creeping chill dyeing and creeping chill dyeing
Supercool fiber is blended according to mass ratio 2.5:1:1, obtains scribbled；
E winder: removing the flaw of scribbled, by scribbled winder；
F woolens: according to the version type of computer data inputting by the scribbled knitting forming after winder, obtain front and rear panel, collar and
Sleeve；
G hair disc: front and rear panel, collar and sleeve are sutured, and obtain ready-made clothes；
H is repaired: the end of a thread that the suture of artificial removal's ready-made clothes generates；
I is arranged: the ready-made clothes after removal the end of a thread being immersed in the waterborne organic silicon polyurethane finishing agent aqueous solution of 40g/L, bath
Than 1:30, stirred 100 minutes in 40 DEG C；After the completion of stirring, ready-made clothes is taken out, with 200 times of water washing of its weight, after obtaining arrangement
Fabric；
J steam shaping: by the fabric after arrangement in 120 DEG C steam ironing 4 minutes.
Embodiment 2
Antistatic light luxurious worsted fabric, the vinegar blueness fiber after modified woolen fiber, creeping chill dyeing after being dyed with creeping chill
The yarn obtained with the Supercool fiber blend after creeping chill dyeing is prepared as raw material using the technique included the following steps
It obtains:
The dyeing of A wool fiber creeping chill: it by modified woolen fiber and water with weight ratio 1:15 mixing, is warming up to 2 DEG C/min
40℃；It is subsequently added into 1%owf defoaming agent FFA, 5%owf anhydrous sodium sulphate, and adjusting pH value using glacial acetic acid is 4.2, stirs 10 points
Clock；The cold black dyes of 7.5%owf are then added, stir 10 minutes；98 DEG C are warming up to 0.8 DEG C/min, keeps the temperature 50 minutes；
After heat preservation, dye liquor is released, water is added with modified woolen fiber and water weight ratio 1:15, the wool for adding 3%owf is soft
Soft dose of CS-82D-73, stirring is after five minutes；80 DEG C then are warming up to 2 DEG C/min, 30 minutes is kept the temperature, water is released, is drained,
Modified woolen fiber after being dyed；The composition of the cold black dyes are as follows: curcumin 6.4wt%, orchid are taken in the fresh green F-BL
4.6wt%, levelling agent SET 1wt%, sulphur ammonium 17wt%, surplus is the dark blue S-3G in nylon mountain；
The dyeing of B vinegar blueness fiber creeping chill: it is woolen dyed identical in staining procedure and step A, wool fiber is only replaced with into vinegar
Green fiber；
C Supercool fiber creeping chill dyeing: by Supercool fiber and water with mass ratio 1:15 mixing, with 2 DEG C/minute
Clock is warming up to 45 DEG C；It is subsequently added into the nonionic penetrant JFC of 3%owf, and adjusts pH value to 5.5 using glacial acetic acid；Then plus
Enter the creeping chill auxiliary agent LT-JLG01 of 3%owf, stirs 10 minutes；The Foron ruby dye of 5%owf is then added, stirs 10 points
Clock；110 DEG C are warming up to 1.2 DEG C/min, is stirred 5 minutes；After terminating stirring, 130 DEG C are warming up to 1 DEG C/min, heat preservation 50
Minute；After heat preservation, dye liquor is released, is drained, the Supercool fiber after being dyed；
D is blended: after wool fiber after creeping chill is dyed, the vinegar blueness fiber after creeping chill dyeing and creeping chill dyeing
Supercool fiber is blended according to mass ratio 2.5:1:1, obtains scribbled；
E winder: removing the flaw of scribbled, by scribbled winder；
F woolens: according to the version type of computer data inputting by the scribbled knitting forming after winder, obtain front and rear panel, collar and
Sleeve；
G hair disc: front and rear panel, collar and sleeve are sutured, and obtain ready-made clothes；
H is repaired: the end of a thread that the suture of artificial removal's ready-made clothes generates；
I is arranged: the ready-made clothes after removal the end of a thread being immersed in the waterborne organic silicon polyurethane finishing agent aqueous solution of 40g/L, bath
Than 1:30, stirred 100 minutes in 40 DEG C；After the completion of stirring, ready-made clothes is taken out, with 200 times of water washing of its weight, after obtaining arrangement
Fabric；
J steam shaping: by the fabric after arrangement in 120 DEG C steam ironing 4 minutes.
The preparation process of the modified woolen fiber are as follows:
(1) dioxygen water pretreatment: after wool fiber is washed with 30 times of its weight of 50 DEG C of hot water, in 50 DEG C of hydrogen peroxide
With bath raio 1:25 dipping 40 minutes in pretreatment fluid, then pulls wool fiber out, washed with 70 times of cold water of its weight, 50 DEG C of bakings
It is dry stand-by；The wherein composition of hydrogen peroxide pretreatment fluid are as follows: hydrogen peroxide 30mL/L, sodium carbonate 0.02g/L, sodium metasilicate 4g/L, surplus
For water, pH8.5；The raw material of hydrogen peroxide pretreatment fluid is uniformly mixed, is adjusted using the sodium hydrate aqueous solution of mass fraction 3%
PH to 8.5 is up to hydrogen peroxide pretreatment fluid；
(2) pretreated wool fiber is impregnated in polylysine treatment fluid with bath raio 1:20, stirs 12 at 40 DEG C
Hour, it then pulls wool fiber out, is washed with 70 times of cold water of its weight, 50 DEG C of drying are stand-by；The polylysine treatment fluid
The preparation method is as follows: adding the epsilon-polylysine and 0.03 of 0.02 times of its weight in the phosphate buffer for being 6.5 to pH value
Glutamy transaminase again, mixes well to obtain the final product.
Embodiment 3
Antistatic light luxurious worsted fabric, the vinegar blueness fiber after modified woolen fiber, creeping chill dyeing after being dyed with creeping chill
The yarn obtained with the Supercool fiber blend after creeping chill dyeing is prepared as raw material using the technique included the following steps
It obtains:
The dyeing of A wool fiber creeping chill: it by modified woolen fiber and water with weight ratio 1:15 mixing, is warming up to 2 DEG C/min
40℃；It is subsequently added into 1%owf defoaming agent FFA, 5%owf anhydrous sodium sulphate, and adjusting pH value using glacial acetic acid is 4.2, stirs 10 points
Clock；The cold black dyes of 7.5%owf are then added, stir 10 minutes；98 DEG C are warming up to 0.8 DEG C/min, keeps the temperature 50 minutes；
After heat preservation, dye liquor is released, water is added with modified woolen fiber and water weight ratio 1:15, the wool for adding 3%owf is soft
Soft dose of CS-82D-73, stirring is after five minutes；80 DEG C then are warming up to 2 DEG C/min, 30 minutes is kept the temperature, water is released, is drained,
Modified woolen fiber after being dyed；The composition of the cold black dyes are as follows: curcumin 6.4wt%, orchid are taken in the fresh green F-BL
4.6wt%, levelling agent SET 1wt%, sulphur ammonium 17wt%, surplus is the dark blue S-3G in nylon mountain；
The dyeing of B vinegar blueness fiber creeping chill: it is woolen dyed identical in staining procedure and step A, wool fiber is only replaced with into vinegar
Green fiber；
C Supercool fiber creeping chill dyeing: by Supercool fiber and water with mass ratio 1:15 mixing, with 2 DEG C/minute
Clock is warming up to 45 DEG C；It is subsequently added into the nonionic penetrant JFC of 3%owf, and adjusts pH value to 5.5 using glacial acetic acid；Then plus
Enter the creeping chill auxiliary agent LT-JLG01 of 3%owf, stirs 10 minutes；The Foron ruby dye of 5%owf is then added, stirs 10 points
Clock；110 DEG C are warming up to 1.2 DEG C/min, is stirred 5 minutes；After terminating stirring, 130 DEG C are warming up to 1 DEG C/min, heat preservation 50
Minute；After heat preservation, dye liquor is released, is drained, the Supercool fiber after being dyed；
D is blended: after wool fiber after creeping chill is dyed, the vinegar blueness fiber after creeping chill dyeing and creeping chill dyeing
Supercool fiber is blended according to mass ratio 2.5:1:1, obtains scribbled；
E winder: removing the flaw of scribbled, by scribbled winder；
F woolens: according to the version type of computer data inputting by the scribbled knitting forming after winder, obtain front and rear panel, collar and
Sleeve；
G hair disc: front and rear panel, collar and sleeve are sutured, and obtain ready-made clothes；
H is repaired: the end of a thread that the suture of artificial removal's ready-made clothes generates；
I is arranged: the ready-made clothes after removal the end of a thread being immersed in the waterborne organic silicon polyurethane finishing agent aqueous solution of 40g/L, bath
Than 1:30, stirred 100 minutes in 40 DEG C；After the completion of stirring, ready-made clothes is taken out, with 200 times of water washing of its weight, after obtaining arrangement
Fabric；
J steam shaping: by the fabric after arrangement in 120 DEG C steam ironing 4 minutes.
The preparation process of the modified woolen fiber are as follows:
(1) permanganate pretreatment: after wool fiber is washed with 30 times of its weight of 50 DEG C of hot water, in 40 DEG C of Gao Meng
With bath raio 1:20 dipping 30 minutes in sour potassium pretreatment fluid；It after pulling out, is first washed 20 minutes with 40 DEG C of liquid of soaping, then with 45 DEG C
The aqueous sodium carbonate of mass fraction 2% wash 15 minutes, then use salt acid elution 40 minutes of volume fraction 2%；Finally
Wool fiber after pulling salt acid elution out is washed with 70 times of cold water of its weight, and 50 DEG C of drying are stand-by；Wherein potassium permanganate is located in advance
Manage the composition of liquid are as follows: potassium permanganate 0.04g/L, nonionic penetrant JFC 1g/L, sodium metasilicate 4g/L, surplus is water, pH4.0；
The raw material of permanganate pretreatment liquid is uniformly mixed, using the salt acid for adjusting pH of mass fraction 3% to 4.0 up to potassium permanganate
Pretreatment fluid；
(2) pretreated wool fiber is impregnated in polylysine treatment fluid with bath raio 1:20, stirs 12 at 40 DEG C
Hour, it then pulls wool fiber out, is washed with 70 times of cold water of its weight, 50 DEG C of drying are stand-by；The polylysine treatment fluid
The preparation method is as follows: adding the epsilon-polylysine and 0.03 of 0.02 times of its weight in the phosphate buffer for being 6.5 to pH value
Glutamy transaminase again, mixes well to obtain the final product.
Embodiment 4
Antistatic light luxurious worsted fabric, the vinegar blueness fiber after modified woolen fiber, creeping chill dyeing after being dyed with creeping chill
The yarn obtained with the Supercool fiber blend after creeping chill dyeing is prepared as raw material using the technique included the following steps
It obtains:
The dyeing of A wool fiber creeping chill: it by modified woolen fiber and water with weight ratio 1:15 mixing, is warming up to 2 DEG C/min
40℃；It is subsequently added into 1%owf defoaming agent FFA, 5%owf anhydrous sodium sulphate, and adjusting pH value using glacial acetic acid is 4.2, stirs 10 points
Clock；The cold black dyes of 7.5%owf are then added, stir 10 minutes；98 DEG C are warming up to 0.8 DEG C/min, keeps the temperature 50 minutes；
After heat preservation, dye liquor is released, water is added with modified woolen fiber and water weight ratio 1:15, the wool for adding 3%owf is soft
Soft dose of CS-82D-73, stirring is after five minutes；80 DEG C then are warming up to 2 DEG C/min, 30 minutes is kept the temperature, water is released, is drained,
Modified woolen fiber after being dyed；The composition of the cold black dyes are as follows: curcumin 6.4wt%, orchid are taken in the fresh green F-BL
4.6wt%, levelling agent SET 1wt%, sulphur ammonium 17wt%, surplus is the dark blue S-3G in nylon mountain；
The dyeing of B vinegar blueness fiber creeping chill: it is woolen dyed identical in staining procedure and step A, wool fiber is only replaced with into vinegar
Green fiber；
C Supercool fiber creeping chill dyeing: by Supercool fiber and water with mass ratio 1:15 mixing, with 2 DEG C/minute
Clock is warming up to 45 DEG C；It is subsequently added into the nonionic penetrant JFC of 3%owf, and adjusts pH value to 5.5 using glacial acetic acid；Then plus
Enter the creeping chill auxiliary agent LT-JLG01 of 3%owf, stirs 10 minutes；The Foron ruby dye of 5%owf is then added, stirs 10 points
Clock；110 DEG C are warming up to 1.2 DEG C/min, is stirred 5 minutes；After terminating stirring, 130 DEG C are warming up to 1 DEG C/min, heat preservation 50
Minute；After heat preservation, dye liquor is released, is drained, the Supercool fiber after being dyed；
D is blended: after wool fiber after creeping chill is dyed, the vinegar blueness fiber after creeping chill dyeing and creeping chill dyeing
Supercool fiber is blended according to mass ratio 2.5:1:1, obtains scribbled；
E winder: removing the flaw of scribbled, by scribbled winder；
F woolens: according to the version type of computer data inputting by the scribbled knitting forming after winder, obtain front and rear panel, collar and
Sleeve；
G hair disc: front and rear panel, collar and sleeve are sutured, and obtain ready-made clothes；
H is repaired: the end of a thread that the suture of artificial removal's ready-made clothes generates；
I is arranged: the ready-made clothes after removal the end of a thread being immersed in the waterborne organic silicon polyurethane finishing agent aqueous solution of 40g/L, bath
Than 1:30, stirred 100 minutes in 40 DEG C；After the completion of stirring, ready-made clothes is taken out, with 200 times of water washing of its weight, after obtaining arrangement
Fabric；
J steam shaping: by the fabric after arrangement in 120 DEG C steam ironing 4 minutes.
The preparation process of the modified woolen fiber are as follows:
(1) dichloroisocyanuric acid salt pre-processes: after wool fiber is washed with 30 times of its weight of 50 DEG C of hot water, at 25 DEG C
Dichloroisocyanuric acid salt pretreatment fluid in bath raio 1:25 dipping 30 minutes；After pulling out, in the sulfurous acid of mass fraction 3.6%
In hydrogen sodium solution after twenty minutes with bath raio 1:25 dipping, with bath raio 1:20 dipping 20 in the phosphate buffer of 40 DEG C of pH8
Minute；Finally pull out phosphate buffer dipping after wool fiber, wash with 70 times of cold water of its weight, 50 DEG C dry to
With；The composition of the dichloroisocyanuric acid salt pretreatment fluid are as follows: dichloroisocyanuric acid salt 0.03g/L, nonionic penetrant JFC
1g/L, surplus are water, pH4.0；The raw material of dichloroisocyanuric acid salt pretreatment fluid is uniformly mixed, mass fraction 3% is used
Salt acid for adjusting pH is to 4.0 up to dichloroisocyanuric acid salt pretreatment fluid；
(2) pretreated wool fiber is impregnated in polylysine treatment fluid with bath raio 1:20, stirs 12 at 40 DEG C
Hour, it then pulls wool fiber out, is washed with 70 times of cold water of its weight, 50 DEG C of drying are stand-by；The polylysine treatment fluid
The preparation method is as follows: adding the epsilon-polylysine and 0.03 of 0.02 times of its weight in the phosphate buffer for being 6.5 to pH value
Glutamy transaminase again, mixes well to obtain the final product.
The amino nitrogen content of Examples 1 to 4 dyeing wool fiber is detected, is measured using ammonia-nitrogen, specifically
Steps are as follows: the ammonium sulfate that ammonia nitrogen concentration is 1~5 μ g/mL difference gradient concentration is accurately prepared with phosphate buffer,
It is used as ammoniacal nitrogen standard solution；It is accurate to prepare solution A and solution B, the sodium nitroprusside that solution A is 50mg/L with
The phenol of 10g/L；Solution B is trisodium citrate, the sodium hydroxide of 5g/L and the sodium hypochlorite of 7mL/L of 4g/L；Take 5mL solution
A, the prepare liquid of 5mL solution B and 1mL containing ammonia is made into developing solution and carries out chromogenic reaction；Take the ammoniacal nitrogen titer of known concentration with
Developing solution is sufficiently mixed, and is placed in 37 DEG C of water-baths oscillating reactions 20 minutes, is taken in appropriate chromogenic reaction liquid and cuvette, is used
UV-2802S type ultraviolet-uisible spectrophotometer surveys its absorbing wavelength, obtains a length of 640nm of its maximum absorption wave；Respectively in wavelength
For measured under 640nm different gradient concentrations ammoniacal nitrogen standard solution chromogenic reaction liquid absorbance value, draw out ammoniacal nitrogen
Amount-absorbance standard curve；The fit equation of the curve are as follows: A=0.0884C+0.004, R2=0.99295；In formula: A- extinction
Degree；C- ammoniacal nitrogen amount (μ g/mL)
The dyeability of light luxurious worsted fabric antistatic to Examples 1 to 4 is tested: by antistatic light luxurious Worsted
Fabric, which is placed on the Premier8400 colour photometer of Shanghai Tu Xin Electronic Science and Technology Co., Ltd. offer, measures K/S value, and every piece of sample exists
Different parts are surveyed three times, its average value is taken.
The anti-microbial property of light luxurious worsted fabric antistatic to Examples 1 to 4 is tested, and oscillation flask method reference is used
" evaluation of antibiotic fabric and its anti-microbial property " (He Minzhu, Shanghai Textile science and technology, 2005,33 (3): 62-64) carries out.
The wettability of light luxurious worsted fabric antistatic to Examples 1 to 4 is tested, referring to AATCC79-2010 into
Row, using wetting time as index, specific steps are as follows: appropriately sized antistatic light luxurious worsted fabric is taken to be laid in glass plate
On, drip a drop distilled water at the same height of bullet fabric surface, starts timing to the water droplet and is completely absorbed, records number
According to.The different zones for choosing wool fabric to be measured measure 5 times, its average value is taken to be used to measure the wettability of wool fabric.
Specific test result is shown in Table 1.
1 Examples 1 to 4 ammoniacal nitrogen amount of table, K/S value, bacteriostasis rate and wetting time test table
As can be drawn from Table 1 to draw a conclusion:
1. ammoniacal nitrogen amount significantly improves, and illustrates sheep by modified wool fiber compared to unmodified wool fiber
Wool fibre is after pretreatment, and grafting epsilon-polylysine, which is released, to be conducive to discharge ammoniacal nitrogen amount, wherein 4 dichloroisocyanuric acid of embodiment
The pretreated ammoniacal nitrogen burst size highest of salt, 2 permanganate pretreatment of embodiment take second place, and 1 dioxygen water pretreatment of embodiment is minimum.
This is because the disulfide bond in wool scale layer is oxidized to-SO when potassium permanganate and dioxygen water pretreatment3H, and dichloro isocyanide urea
Hydrochlorate is pre-processed in addition to the disulfide bond in wool scale layer is oxidized to-SO3Outside H, there is also hypochlorous acid to tyrosine residue portion
The hydrolysis of position makes protein be converted into polypeptide even amino acid.Therefore, the pretreatment of dichloroisocyanuric acid salt is destroying wool scale
While layer, moreover it is possible to which the degree of exposure for increasing wool glutamine residue increases the transaminase-catalyzed wool grafting of glutamy
The graft site of epsilon-polylysine improves the degree of graft reaction, increases the ammonia nitrogen content released.
2. the colouring power of the wool fiber Jing Guo graft modification is apparently higher than the wool fiber of non-grafted modification, wherein double
The K/S value of the wool fabric of oxygen water pretreatment changes less compared with untreated wool fabric, and the woolens of other pretreatment modes
The reason of object K/S value all significantly improves, and reason is discharged with ammoniacal nitrogen amount is identical.
3. unmodified wool fiber is almost without antibiotic property, and the wool fiber antibiotic property Jing Guo graft modification obviously mentions
It is high.
4. wetting time is shortened, and wherein dichloro is different after pretreated wool fabric is grafted epsilon-polylysine
The pretreated wool fabric wetting time of cyanurate is most short.The pretreatment of dichloroisocyanuric acid salt significantly improves the profit of wool fabric
Wet performance, this may be that the pretreatment of dichloroisocyanuric acid salt is pre- higher than other to the extent of the destruction of wool surfaces hydrophobic lipid layer
Processing mode, water droplet are easier to permeate, and wetting time shortening is embodied in test case；This is because one side dichloro is different
Woolen wetability obtains a degree of raising after cyanurate pretreatment, on the other hand, due to epsilon-polylysine molecule
Containing a large amount of hydrophilic carboxyls and amino group in structure, it is grafted epsilon-polylysine by the transaminase-catalyzed wool of glutamy,
Significantly improve woolen wettability of the surface.
Embodiment 5
Antistatic light luxurious worsted fabric, the vinegar blueness fiber after modified woolen fiber, creeping chill dyeing after being dyed with creeping chill
The yarn obtained with the Supercool fiber blend after creeping chill dyeing is prepared as raw material using the technique included the following steps
It obtains:
The dyeing of A wool fiber creeping chill: it by modified woolen fiber and water with weight ratio 1:15 mixing, is warming up to 2 DEG C/min
40℃；It is subsequently added into 1%owf defoaming agent FFA, 5%owf anhydrous sodium sulphate, and adjusting pH value using glacial acetic acid is 4.2, stirs 10 points
Clock；The cold black dyes of 7.5%owf are then added, stir 10 minutes；98 DEG C are warming up to 0.8 DEG C/min, keeps the temperature 50 minutes；
After heat preservation, dye liquor is released, water is added with modified woolen fiber and water weight ratio 1:15, the wool for adding 3%owf is soft
Soft dose of CS-82D-73, stirring is after five minutes；80 DEG C then are warming up to 2 DEG C/min, 30 minutes is kept the temperature, water is released, is drained,
Modified woolen fiber after being dyed；The composition of the cold black dyes are as follows: ethyl esterified curcumin 6.4wt%, Lan Naxin
Green F-BL 4.6wt%, levelling agent SET 1wt%, sulphur ammonium 17wt%, surplus is the dark blue S-3G in nylon mountain；
The dyeing of B vinegar blueness fiber creeping chill: it is woolen dyed identical in staining procedure and step A, wool fiber is only replaced with into vinegar
Green fiber；
C Supercool fiber creeping chill dyeing: by Supercool fiber and water with mass ratio 1:15 mixing, with 2 DEG C/minute
Clock is warming up to 45 DEG C；It is subsequently added into the nonionic penetrant JFC of 3%owf, and adjusts pH value to 5.5 using glacial acetic acid；Then plus
Enter the creeping chill auxiliary agent LT-JLG01 of 3%owf, stirs 10 minutes；The Foron ruby dye of 5%owf is then added, stirs 10 points
Clock；110 DEG C are warming up to 1.2 DEG C/min, is stirred 5 minutes；After terminating stirring, 130 DEG C are warming up to 1 DEG C/min, heat preservation 50
Minute；After heat preservation, dye liquor is released, is drained, the Supercool fiber after being dyed；
D is blended: after wool fiber after creeping chill is dyed, the vinegar blueness fiber after creeping chill dyeing and creeping chill dyeing
Supercool fiber is blended according to mass ratio 2.5:1:1, obtains scribbled；
E winder: removing the flaw of scribbled, by scribbled winder；
F woolens: according to the version type of computer data inputting by the scribbled knitting forming after winder, obtain front and rear panel, collar and
Sleeve；
G hair disc: front and rear panel, collar and sleeve are sutured, and obtain ready-made clothes；
H is repaired: the end of a thread that the suture of artificial removal's ready-made clothes generates；
I is arranged: the ready-made clothes after removal the end of a thread being immersed in the waterborne organic silicon polyurethane finishing agent aqueous solution of 40g/L, bath
Than 1:30, stirred 100 minutes in 40 DEG C；After the completion of stirring, ready-made clothes is taken out, with 200 times of water washing of its weight, after obtaining arrangement
Fabric；
J steam shaping: by the fabric after arrangement in 120 DEG C steam ironing 4 minutes.
The preparation of the modified woolen fiber is the same as embodiment 4.
Embodiment 6
Antistatic light luxurious worsted fabric, the vinegar blueness fiber after modified woolen fiber, creeping chill dyeing after being dyed with creeping chill
The yarn obtained with the Supercool fiber blend after creeping chill dyeing is prepared as raw material using the technique included the following steps
It obtains:
The dyeing of A wool fiber creeping chill: it by modified woolen fiber and water with weight ratio 1:15 mixing, is warming up to 2 DEG C/min
40℃；It is subsequently added into 1%owf defoaming agent FFA, 5%owf anhydrous sodium sulphate, and adjusting pH value using glacial acetic acid is 4.2, stirs 10 points
Clock；The cold black dyes of 7.5%owf are then added, stir 10 minutes；98 DEG C are warming up to 0.8 DEG C/min, keeps the temperature 50 minutes；
After heat preservation, dye liquor is released, water is added with modified woolen fiber and water weight ratio 1:15, the wool for adding 3%owf is soft
Soft dose of CS-82D-73, stirring is after five minutes；80 DEG C then are warming up to 2 DEG C/min, 30 minutes is kept the temperature, water is released, is drained,
Modified woolen fiber after being dyed；The composition of the cold black dyes are as follows: butyl ester curcumin 6.4wt%, Lan Naxin
Green F-BL 4.6wt%, levelling agent SET 1wt%, sulphur ammonium 17wt%, surplus is the dark blue S-3G in nylon mountain；
The dyeing of B vinegar blueness fiber creeping chill: it is woolen dyed identical in staining procedure and step A, wool fiber is only replaced with into vinegar
Green fiber；
C Supercool fiber creeping chill dyeing: by Supercool fiber and water with mass ratio 1:15 mixing, with 2 DEG C/minute
Clock is warming up to 45 DEG C；It is subsequently added into the nonionic penetrant JFC of 3%owf, and adjusts pH value to 5.5 using glacial acetic acid；Then plus
Enter the creeping chill auxiliary agent LT-JLG01 of 3%owf, stirs 10 minutes；The Foron ruby dye of 5%owf is then added, stirs 10 points
Clock；110 DEG C are warming up to 1.2 DEG C/min, is stirred 5 minutes；After terminating stirring, 130 DEG C are warming up to 1 DEG C/min, heat preservation 50
Minute；After heat preservation, dye liquor is released, is drained, the Supercool fiber after being dyed；
D is blended: after wool fiber after creeping chill is dyed, the vinegar blueness fiber after creeping chill dyeing and creeping chill dyeing
Supercool fiber is blended according to mass ratio 2.5:1:1, obtains scribbled；
E winder: removing the flaw of scribbled, by scribbled winder；
F woolens: according to the version type of computer data inputting by the scribbled knitting forming after winder, obtain front and rear panel, collar and
Sleeve；
G hair disc: front and rear panel, collar and sleeve are sutured, and obtain ready-made clothes；
H is repaired: the end of a thread that the suture of artificial removal's ready-made clothes generates；
I is arranged: the ready-made clothes after removal the end of a thread being immersed in the waterborne organic silicon polyurethane finishing agent aqueous solution of 40g/L, bath
Than 1:30, stirred 100 minutes in 40 DEG C；After the completion of stirring, ready-made clothes is taken out, with 200 times of water washing of its weight, after obtaining arrangement
Fabric；
J steam shaping: by the fabric after arrangement in 120 DEG C steam ironing 4 minutes.
The preparation of the modified woolen fiber is the same as embodiment 4.
Embodiment 7
Antistatic light luxurious worsted fabric, the vinegar blueness fiber after modified woolen fiber, creeping chill dyeing after being dyed with creeping chill
The yarn obtained with the Supercool fiber blend after creeping chill dyeing is prepared as raw material using the technique included the following steps
It obtains:
The dyeing of A wool fiber creeping chill: it by modified woolen fiber and water with weight ratio 1:15 mixing, is warming up to 2 DEG C/min
40℃；It is subsequently added into 1%owf defoaming agent FFA, 5%owf anhydrous sodium sulphate, and adjusting pH value using glacial acetic acid is 4.2, stirs 10 points
Clock；The cold black dyes of 7.5%owf are then added, stir 10 minutes；98 DEG C are warming up to 0.8 DEG C/min, keeps the temperature 50 minutes；
After heat preservation, dye liquor is released, water is added with modified woolen fiber and water weight ratio 1:15, the wool for adding 3%owf is soft
Soft dose of CS-82D-73, stirring is after five minutes；80 DEG C then are warming up to 2 DEG C/min, 30 minutes is kept the temperature, water is released, is drained,
Modified woolen fiber after being dyed；The composition of the cold black dyes are as follows: ethyl esterified curcumin 6.4wt%, Lan Naxin
Green F-BL 4.6wt%, levelling agent SET 1wt%, sulphur ammonium 17wt%, n -Propyl gallate 0.3wt%, surplus are nylon mountain
Dark blue S-3G；
The dyeing of B vinegar blueness fiber creeping chill: it is woolen dyed identical in staining procedure and step A, wool fiber is only replaced with into vinegar
Green fiber；
C Supercool fiber creeping chill dyeing: by Supercool fiber and water with mass ratio 1:15 mixing, with 2 DEG C/minute
Clock is warming up to 45 DEG C；It is subsequently added into the nonionic penetrant JFC of 3%owf, and adjusts pH value to 5.5 using glacial acetic acid；Then plus
Enter the creeping chill auxiliary agent LT-JLG01 of 3%owf, stirs 10 minutes；The Foron ruby dye of 5%owf is then added, stirs 10 points
Clock；110 DEG C are warming up to 1.2 DEG C/min, is stirred 5 minutes；After terminating stirring, 130 DEG C are warming up to 1 DEG C/min, heat preservation 50
Minute；After heat preservation, dye liquor is released, is drained, the Supercool fiber after being dyed；
D is blended: after wool fiber after creeping chill is dyed, the vinegar blueness fiber after creeping chill dyeing and creeping chill dyeing
Supercool fiber is blended according to mass ratio 2.5:1:1, obtains scribbled；
E winder: removing the flaw of scribbled, by scribbled winder；
F woolens: according to the version type of computer data inputting by the scribbled knitting forming after winder, obtain front and rear panel, collar and
Sleeve；
G hair disc: front and rear panel, collar and sleeve are sutured, and obtain ready-made clothes；
H is repaired: the end of a thread that the suture of artificial removal's ready-made clothes generates；
I is arranged: the ready-made clothes after removal the end of a thread being immersed in the waterborne organic silicon polyurethane finishing agent aqueous solution of 40g/L, bath
Than 1:30, stirred 100 minutes in 40 DEG C；After the completion of stirring, ready-made clothes is taken out, with 200 times of water washing of its weight, after obtaining arrangement
Fabric；
J steam shaping: by the fabric after arrangement in 120 DEG C steam ironing 4 minutes.
The preparation of the modified woolen fiber is the same as embodiment 4.
Embodiment 8
Antistatic light luxurious worsted fabric, the vinegar blueness fiber after modified woolen fiber, creeping chill dyeing after being dyed with creeping chill
The yarn obtained with the Supercool fiber blend after creeping chill dyeing is prepared as raw material using the technique included the following steps
It obtains:
The dyeing of A wool fiber creeping chill: it by modified woolen fiber and water with weight ratio 1:15 mixing, is warming up to 2 DEG C/min
40℃；It is subsequently added into 1%owf defoaming agent FFA, 5%owf anhydrous sodium sulphate, and adjusting pH value using glacial acetic acid is 4.2, stirs 10 points
Clock；The cold black dyes of 7.5%owf are then added, stir 10 minutes；98 DEG C are warming up to 0.8 DEG C/min, keeps the temperature 50 minutes；
After heat preservation, dye liquor is released, water is added with modified woolen fiber and water weight ratio 1:15, the wool for adding 3%owf is soft
Soft dose of CS-82D-73, stirring is after five minutes；80 DEG C then are warming up to 2 DEG C/min, 30 minutes is kept the temperature, water is released, is drained,
Modified woolen fiber after being dyed；The composition of the cold black dyes are as follows: ethyl esterified curcumin 6.4wt%, Lan Naxin
Green F-BL 4.6wt%, levelling agent SET 1wt%, sulphur ammonium 17wt%, Quercetin 0.3wt%, surplus are the dark blue S-3G in nylon mountain；
The dyeing of B vinegar blueness fiber creeping chill: it is woolen dyed identical in staining procedure and step A, wool fiber is only replaced with into vinegar
Green fiber；
C Supercool fiber creeping chill dyeing: by Supercool fiber and water with mass ratio 1:15 mixing, with 2 DEG C/minute
Clock is warming up to 45 DEG C；It is subsequently added into the nonionic penetrant JFC of 3%owf, and adjusts pH value to 5.5 using glacial acetic acid；Then plus
Enter the creeping chill auxiliary agent LT-JLG01 of 3%owf, stirs 10 minutes；The Foron ruby dye of 5%owf is then added, stirs 10 points
Clock；110 DEG C are warming up to 1.2 DEG C/min, is stirred 5 minutes；After terminating stirring, 130 DEG C are warming up to 1 DEG C/min, heat preservation 50
Minute；After heat preservation, dye liquor is released, is drained, the Supercool fiber after being dyed；
D is blended: after wool fiber after creeping chill is dyed, the vinegar blueness fiber after creeping chill dyeing and creeping chill dyeing
Supercool fiber is blended according to mass ratio 2.5:1:1, obtains scribbled；
E winder: removing the flaw of scribbled, by scribbled winder；
F woolens: according to the version type of computer data inputting by the scribbled knitting forming after winder, obtain front and rear panel, collar and
Sleeve；
G hair disc: front and rear panel, collar and sleeve are sutured, and obtain ready-made clothes；
H is repaired: the end of a thread that the suture of artificial removal's ready-made clothes generates；
I is arranged: the ready-made clothes after removal the end of a thread being immersed in the waterborne organic silicon polyurethane finishing agent aqueous solution of 40g/L, bath
Than 1:30, stirred 100 minutes in 40 DEG C；After the completion of stirring, ready-made clothes is taken out, with 200 times of water washing of its weight, after obtaining arrangement
Fabric；
J steam shaping: by the fabric after arrangement in 120 DEG C steam ironing 4 minutes.
The preparation of the modified woolen fiber is the same as embodiment 4.
Embodiment 9
Antistatic light luxurious worsted fabric, the vinegar blueness fiber after modified woolen fiber, creeping chill dyeing after being dyed with creeping chill
The yarn obtained with the Supercool fiber blend after creeping chill dyeing is prepared as raw material using the technique included the following steps
It obtains:
The dyeing of A wool fiber creeping chill: it by modified woolen fiber and water with weight ratio 1:15 mixing, is warming up to 2 DEG C/min
40℃；It is subsequently added into 1%owf defoaming agent FFA, 5%owf anhydrous sodium sulphate, and adjusting pH value using glacial acetic acid is 4.2, stirs 10 points
Clock；The cold black dyes of 7.5%owf are then added, stir 10 minutes；98 DEG C are warming up to 0.8 DEG C/min, keeps the temperature 50 minutes；
After heat preservation, dye liquor is released, water is added with modified woolen fiber and water weight ratio 1:15, the wool for adding 3%owf is soft
Soft dose of CS-82D-73, stirring is after five minutes；80 DEG C then are warming up to 2 DEG C/min, 30 minutes is kept the temperature, water is released, is drained,
Modified woolen fiber after being dyed；The composition of the cold black dyes are as follows: ethyl esterified curcumin 6.4wt%, Lan Naxin
Green F-BL 4.6wt%, levelling agent SET 1wt%, sulphur ammonium 17wt%, n -Propyl gallate Quercetin 0.15wt%, Quercetin
0.15wt%, surplus are the dark blue S-3G in nylon mountain；
The dyeing of B vinegar blueness fiber creeping chill: it is woolen dyed identical in staining procedure and step A, wool fiber is only replaced with into vinegar
Green fiber；
C Supercool fiber creeping chill dyeing: by Supercool fiber and water with mass ratio 1:15 mixing, with 2 DEG C/minute
Clock is warming up to 45 DEG C；It is subsequently added into the nonionic penetrant JFC of 3%owf, and adjusts pH value to 5.5 using glacial acetic acid；Then plus
Enter the creeping chill auxiliary agent LT-JLG01 of 3%owf, stirs 10 minutes；The Foron ruby dye of 5%owf is then added, stirs 10 points
Clock；110 DEG C are warming up to 1.2 DEG C/min, is stirred 5 minutes；After terminating stirring, 130 DEG C are warming up to 1 DEG C/min, heat preservation 50
Minute；After heat preservation, dye liquor is released, is drained, the Supercool fiber after being dyed；
D is blended: after wool fiber after creeping chill is dyed, the vinegar blueness fiber after creeping chill dyeing and creeping chill dyeing
Supercool fiber is blended according to mass ratio 2.5:1:1, obtains scribbled；
E winder: removing the flaw of scribbled, by scribbled winder；
F woolens: according to the version type of computer data inputting by the scribbled knitting forming after winder, obtain front and rear panel, collar and
Sleeve；
G hair disc: front and rear panel, collar and sleeve are sutured, and obtain ready-made clothes；
H is repaired: the end of a thread that the suture of artificial removal's ready-made clothes generates；
I is arranged: the ready-made clothes after removal the end of a thread being immersed in the waterborne organic silicon polyurethane finishing agent aqueous solution of 40g/L, bath
Than 1:30, stirred 100 minutes in 40 DEG C；After the completion of stirring, ready-made clothes is taken out, with 200 times of water washing of its weight, after obtaining arrangement
Fabric；
J steam shaping: by the fabric after arrangement in 120 DEG C steam ironing 4 minutes.
The preparation of the modified woolen fiber is the same as embodiment 4.
Embodiment 10
Antistatic light luxurious worsted fabric, the vinegar blueness fiber after modified woolen fiber, creeping chill dyeing after being dyed with creeping chill
The yarn obtained with the Supercool fiber blend after creeping chill dyeing is prepared as raw material using the technique included the following steps
It obtains:
The dyeing of A wool fiber creeping chill: it by modified woolen fiber and water with weight ratio 1:15 mixing, is warming up to 2 DEG C/min
40℃；It is subsequently added into 1%owf defoaming agent FFA, 5%owf anhydrous sodium sulphate, and adjusting pH value using glacial acetic acid is 4.2, stirs 10 points
Clock；The cold black dyes of 7.5%owf are then added, stir 10 minutes；98 DEG C are warming up to 0.8 DEG C/min, keeps the temperature 50 minutes；
After heat preservation, dye liquor is released, water is added with modified woolen fiber and water weight ratio 1:15, the wool for adding 3%owf is soft
Soft dose of CS-82D-73, stirring is after five minutes；80 DEG C then are warming up to 2 DEG C/min, 30 minutes is kept the temperature, water is released, is drained,
Modified woolen fiber after being dyed；The composition of the cold black dyes are as follows: ethyl esterified curcumin 6.4wt%, Lan Naxin
Green F-BL 4.6wt%, cardanol polyoxyethylene ether sodium sulfovinate 1wt%, sulphur ammonium 17wt%, n -Propyl gallate Quercetin
0.15wt%, Quercetin 0.15wt%, surplus are the dark blue S-3G in nylon mountain；
The dyeing of B vinegar blueness fiber creeping chill: it is woolen dyed identical in staining procedure and step A, wool fiber is only replaced with into vinegar
Green fiber；
C Supercool fiber creeping chill dyeing: by Supercool fiber and water with mass ratio 1:15 mixing, with 2 DEG C/minute
Clock is warming up to 45 DEG C；It is subsequently added into the nonionic penetrant JFC of 3%owf, and adjusts pH value to 5.5 using glacial acetic acid；Then plus
Enter the creeping chill auxiliary agent LT-JLG01 of 3%owf, stirs 10 minutes；The Foron ruby dye of 5%owf is then added, stirs 10 points
Clock；110 DEG C are warming up to 1.2 DEG C/min, is stirred 5 minutes；After terminating stirring, 130 DEG C are warming up to 1 DEG C/min, heat preservation 50
Minute；After heat preservation, dye liquor is released, is drained, the Supercool fiber after being dyed；
D is blended: after wool fiber after creeping chill is dyed, the vinegar blueness fiber after creeping chill dyeing and creeping chill dyeing
Supercool fiber is blended according to mass ratio 2.5:1:1, obtains scribbled；
E winder: removing the flaw of scribbled, by scribbled winder；
F woolens: according to the version type of computer data inputting by the scribbled knitting forming after winder, obtain front and rear panel, collar and
Sleeve；
G hair disc: front and rear panel, collar and sleeve are sutured, and obtain ready-made clothes；
H is repaired: the end of a thread that the suture of artificial removal's ready-made clothes generates；
I is arranged: the ready-made clothes after removal the end of a thread being immersed in the waterborne organic silicon polyurethane finishing agent aqueous solution of 40g/L, bath
Than 1:30, stirred 100 minutes in 40 DEG C；After the completion of stirring, ready-made clothes is taken out, with 200 times of water washing of its weight, after obtaining arrangement
Fabric；
J steam shaping: by the fabric after arrangement in 120 DEG C steam ironing 4 minutes.
The preparation of the modified woolen fiber is the same as embodiment 4.
The color fastness to light of light luxurious worsted fabric antistatic to embodiment 4~10, colorfastness to rubbing, WASHING COLOR FASTNESS and
Homogenized diet is tested.
Color fastness to light is referring to ISO 105-B02:1994 textile color fastness reality color fastness to light standard.
Colorfastness to rubbing tests colour fastness to rubbing standard referring to GB/T 3920-2008 textile color stability.
WASHING COLOR FASTNESS tests fastness to soaping standard referring to GB/T 3921-2008 textile color stability.
Level-dyeing property test: an optional datum mark on the fabric appoints and takes measure itself and datum mark on color measuring and matching system at 8 points
Between color difference Δ Ei, sample canonical variance S is calculated according to the following formula, and level-dyeing property of fabric is evaluated with the size of S.S value is got over
Small, level-dyeing property is better.
Concrete outcome is shown in Table 2.
As can be drawn from Table 2 to draw a conclusion:
1. being esterified curcumin compared with curcumin, the ester group of molecule two sides participates in conjugation after esterification, while its electrophilic is imitated
Conjugated system cloud density should be reduced, the total often higher problem of system electronic cloud density of curcumin molecule, structure are avoided
It is oxidized reduced performance, light fastness is improved.Wherein due to the electron supplying capacity of ethyl esterified two pending methyl group of curcumin molecule
It is weaker than the propyl of butyl ester curcumin two sides, therefore ethyl esterified curcumin molecular conjugation system electronic cloud density is smaller, light fastness
It is higher.
2. esterification curcumin increases than the level-dyeing property of curcumin, antioxidant is more obvious to level-dyeing property raising, wherein
Ethyl esterified curcumin is more excellent than butyl ester curcumin level-dyeing property.9 Quercetin of embodiment and n -Propyl gallate composite usage exist
In dyestuff, either woolen color fastness or level-dyeing property all increases, this may be since curcumin contains long alkene
Hydrocarbon structure, while having diketone structure on alkene chain, it is volatile to go hydrogen ion as free radical with extremely strong reactivity, then into
One step is oxidized into peroxidating free radical, constantly carries out with oxidation reaction, can be continuously generated new free radical, make reaction automatically into
Row goes down, and Quercetin was compounded in structure compared to other antioxidants with n -Propyl gallate with more allocation generations living
Base prevents curcumin oxidative degradation, while there are also synergistic functions for Quercetin and n -Propyl gallate, can more be promoted by compounding
Its inoxidizability.
It should be appreciated that although this specification is described in terms of embodiments, but not each embodiment only includes one
A independent technical solution, for the sake of this narrating mode of specification is used for the purpose of clearly, those skilled in the art should be incited somebody to action
As a whole, the technical solutions in the various embodiments may also be suitably combined for specification, and forming those skilled in the art can
With the other embodiments of understanding.
Claims (10)
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| CN111005123A (en) * | 2019-12-27 | 2020-04-14 | 海澜之家股份有限公司 | Cashmere-like fabric with electromagnetic shielding function and preparation method thereof |
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Effective date of registration: 20250402 Address after: 024000 No. 1, Dongrong Road, Hongshan Economic Development Zone, Chifeng City, Inner Mongolia Autonomous Region Patentee after: Chifeng Dongli cashmere Co.,Ltd. Country or region after: China Address before: 301, Huatong building, 18 yuetanfang South Lane, pailouji community, Wanjiang street, Dongguan City, Guangdong Province, 523000 Patentee before: DONGGUAN YIDA GARMENT TECHNOLOGY Co.,Ltd. Country or region before: China |