CN109645589B - Moisture wicking and cold prevention basketball uniform and preparation method thereof - Google Patents
Moisture wicking and cold prevention basketball uniform and preparation method thereof Download PDFInfo
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- CN109645589B CN109645589B CN201910001867.1A CN201910001867A CN109645589B CN 109645589 B CN109645589 B CN 109645589B CN 201910001867 A CN201910001867 A CN 201910001867A CN 109645589 B CN109645589 B CN 109645589B
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- polyamide
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- 238000002360 preparation method Methods 0.000 title claims description 59
- 230000002265 prevention Effects 0.000 title claims description 19
- 239000004744 fabric Substances 0.000 claims abstract description 186
- 239000000835 fiber Substances 0.000 claims abstract description 134
- -1 polyethylene Polymers 0.000 claims abstract description 87
- 239000004952 Polyamide Substances 0.000 claims abstract description 77
- 229920002647 polyamide Polymers 0.000 claims abstract description 77
- 238000003475 lamination Methods 0.000 claims abstract description 68
- 239000004698 Polyethylene Substances 0.000 claims abstract description 67
- 229920000573 polyethylene Polymers 0.000 claims abstract description 67
- 239000002131 composite material Substances 0.000 claims abstract description 59
- 238000000034 method Methods 0.000 claims abstract description 53
- 239000000853 adhesive Substances 0.000 claims abstract description 35
- 230000001070 adhesive effect Effects 0.000 claims abstract description 35
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- 238000009413 insulation Methods 0.000 claims abstract description 30
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 60
- 239000007788 liquid Substances 0.000 claims description 55
- 229920000742 Cotton Polymers 0.000 claims description 38
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- 239000003112 inhibitor Substances 0.000 claims description 31
- 238000006116 polymerization reaction Methods 0.000 claims description 31
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 30
- 235000019253 formic acid Nutrition 0.000 claims description 30
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims description 25
- 229910052979 sodium sulfide Inorganic materials 0.000 claims description 24
- 239000004831 Hot glue Substances 0.000 claims description 20
- 239000007864 aqueous solution Substances 0.000 claims description 20
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 20
- 239000003292 glue Substances 0.000 claims description 19
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- 238000001523 electrospinning Methods 0.000 claims description 18
- 238000007654 immersion Methods 0.000 claims description 17
- 239000003054 catalyst Substances 0.000 claims description 15
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- 150000002484 inorganic compounds Chemical class 0.000 claims description 12
- 229910010272 inorganic material Inorganic materials 0.000 claims description 12
- 238000010521 absorption reaction Methods 0.000 claims description 11
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 11
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 10
- WSXIMVDZMNWNRF-UHFFFAOYSA-N antimony;ethane-1,2-diol Chemical compound [Sb].OCCO WSXIMVDZMNWNRF-UHFFFAOYSA-N 0.000 claims description 10
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 10
- 229920006395 saturated elastomer Polymers 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000009941 weaving Methods 0.000 claims description 10
- 238000009835 boiling Methods 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 9
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- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 claims description 8
- 239000003999 initiator Substances 0.000 claims description 8
- 239000003085 diluting agent Substances 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 239000001384 succinic acid Substances 0.000 claims description 6
- 210000002268 wool Anatomy 0.000 claims description 6
- 150000002009 diols Chemical class 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 241000282836 Camelus dromedarius Species 0.000 claims description 4
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 4
- ZWWQRMFIZFPUAA-UHFFFAOYSA-N dimethyl 2-methylidenebutanedioate Chemical compound COC(=O)CC(=C)C(=O)OC ZWWQRMFIZFPUAA-UHFFFAOYSA-N 0.000 claims description 4
- 210000004209 hair Anatomy 0.000 claims description 4
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 claims description 4
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- UPYPTOCXMIWHSG-UHFFFAOYSA-N 1-dodecylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCCCCCCCCC UPYPTOCXMIWHSG-UHFFFAOYSA-N 0.000 claims description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 2
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 claims description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical group CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 2
- DKRNQQHUMHYWSA-UHFFFAOYSA-L cobalt(2+);2-methylprop-2-enoate Chemical compound [Co+2].CC(=C)C([O-])=O.CC(=C)C([O-])=O DKRNQQHUMHYWSA-UHFFFAOYSA-L 0.000 claims description 2
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 2
- IXPUJMULXNNEHS-UHFFFAOYSA-L copper;n,n-dibutylcarbamodithioate Chemical compound [Cu+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC IXPUJMULXNNEHS-UHFFFAOYSA-L 0.000 claims description 2
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims description 2
- 229940112669 cuprous oxide Drugs 0.000 claims description 2
- JVLRYPRBKSMEBF-UHFFFAOYSA-K diacetyloxystibanyl acetate Chemical compound [Sb+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JVLRYPRBKSMEBF-UHFFFAOYSA-K 0.000 claims description 2
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 claims description 2
- 239000012975 dibutyltin dilaurate Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical group Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 2
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 2
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 claims description 2
- 238000013329 compounding Methods 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 238000005470 impregnation Methods 0.000 claims 1
- 230000035699 permeability Effects 0.000 abstract description 9
- GYXGAEAOIFNGAE-UHFFFAOYSA-N 2-propan-2-ylidenebutanedioic acid Chemical compound CC(C)=C(C(O)=O)CC(O)=O GYXGAEAOIFNGAE-UHFFFAOYSA-N 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 239000007787 solid Substances 0.000 description 14
- 239000000463 material Substances 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 238000012986 modification Methods 0.000 description 8
- 230000004048 modification Effects 0.000 description 8
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 239000012985 polymerization agent Substances 0.000 description 7
- 238000001035 drying Methods 0.000 description 6
- 238000011161 development Methods 0.000 description 5
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 4
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 238000003490 calendering Methods 0.000 description 3
- 238000007719 peel strength test Methods 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000012943 hotmelt Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 1
- 238000000563 Verneuil process Methods 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000037081 physical activity Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/002—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches with controlled internal environment
- A41D13/005—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches with controlled internal environment with controlled temperature
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/59—Polyamides; Polyimides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/16—Processes for the non-uniform application of treating agents, e.g. one-sided treatment; Differential treatment
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2400/00—Functions or special features of garments
- A41D2400/10—Heat retention or warming
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Manufacturing Of Multi-Layer Textile Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Woven Fabrics (AREA)
Abstract
本发明提供了一种吸湿排汗防感冒篮球服，属于服装领域。本发明提供的吸湿排汗防感冒篮球服由双层面料制备而成，其中双层面料包括外层面料和贴身面料，外层面料由保暖纤维制备而成，贴身面料为单面沉积有聚酰胺的聚乙烯纤维布，外层面料和贴身面料通过层压复合工艺粘接。本发明提供了一种性能优异的保暖纤维，能够和单面沉积有聚酰胺的聚乙烯纤维布在粘合剂的作用下形成性能优异的复合面料。用于生产吸湿排汗防感冒篮球服的复合面料的剥离强度最高可达920N/mm，透气率最佳最达130.48mm/s。The invention provides a moisture-absorbing, sweat-wicking and cold-proof basketball uniform, which belongs to the field of clothing. The moisture-absorbing, sweat-wicking and cold-proof basketball uniform provided by the present invention is prepared from double-layer fabrics, wherein the double-layer fabrics include outer layer fabrics and body-fitting fabrics, the outer-layer fabrics are prepared from thermal fibers, and the body-fitting fabrics are made of polyamide deposited on one side. The polyethylene fiber cloth, the outer fabric and the body fabric are bonded by a lamination lamination process. The invention provides a thermal insulation fiber with excellent performance, which can form a composite fabric with excellent performance with a polyethylene fiber cloth with polyamide deposited on one side under the action of an adhesive. The peel strength of the composite fabric used to produce moisture-wicking, sweat-proof, and cold-proof basketball uniforms can reach up to 920N/mm, and the best air permeability is up to 130.48mm/s.
Description
技术领域technical field
本发明属于服装领域，尤其是一种吸湿排汗防感冒篮球服及其制备方法。The invention belongs to the field of clothing, in particular to a moisture-absorbing, sweat-wicking and cold-proof basketball uniform and a preparation method thereof.
背景技术Background technique
篮球服指的就是专为篮球运动员设计的运动服装，为运动员进行篮球运动时穿着的服装，一般包括上身的背心和下身的短裤，两者颜色一致，有吸汗功能。材料一般使用具有良好透气疏水性的布料，不会影响运动员的身体活动，不易产生静电，重量轻。好的球衣有助于运动员提高成绩。Basketball uniforms refer to sports clothing specially designed for basketball players. The clothing worn by athletes during basketball sports generally includes a vest on the upper body and shorts on the lower body. The colors of the two are the same and have the function of absorbing sweat. The material is generally made of cloth with good air permeability and hydrophobicity, which will not affect the physical activity of athletes, is not easy to generate static electricity, and is light in weight. A good jersey helps athletes improve their performance.
在材料学中，复合材料由于其独特的性能和风格，在国民经济发展中扮演着越来越重要的角色。对复合材料的研究、开发与应用也成为材料学的研究趋势。究其原因，是因为复合材料既保持了原组分材料的性能特点，又可以通过材料设计使各组分的性能相互补充、彼此关联，形成复合效应，获得原组分材料所不具备的性能。就某种意义而讲，层压织物和涂层织物可称为复合材料，即属于柔性复合材料。它们没有既定的形状规格，类似于匹布一样卷绕成卷，用来制成服装及盖、铺、垫等服用性的产品。In materials science, composite materials are playing an increasingly important role in the development of the national economy due to their unique properties and styles. The research, development and application of composite materials have also become the research trend of materials science. The reason is that the composite material not only maintains the performance characteristics of the original component material, but also can make the performance of each component complement and correlate with each other through material design to form a composite effect and obtain the performance that the original component material does not have. . In a sense, laminated fabrics and coated fabrics can be called composite materials, that is, flexible composite materials. They have no predetermined shape and specifications, and are wound into rolls like a piece of cloth, and are used to make clothing and consumable products such as covers, bedding, and pads.
层压复合织物面料和里料的选择，需要根据最终的用途，一般从机织物、针织物和非织造布三种编织结构中进行选择。所需织物的材料可以是棉和毛等天然纤维，也可以是涤纶、锦纶等化学纤维。The choice of laminated composite fabric fabric and lining needs to be based on the end use, and generally choose from three woven structures of woven fabrics, knitted fabrics and non-woven fabrics. The required fabric material can be natural fibers such as cotton and wool, or chemical fibers such as polyester and nylon.
现有技术中，保暖透气层压复合织物的制备常采用干式复合工艺，复合功能膜由于其加工工艺的不同可分为：无孔薄膜、微孔薄膜。有三种制备方法：压延成膜法、流延成膜法和吹塑成膜法。压延和流延法均可用来生产无孔薄膜和微孔薄膜，吹塑成膜法仅能来 生产无孔膜。In the prior art, the preparation of the thermal insulation and breathable laminated composite fabric often adopts a dry composite process, and the composite functional film can be divided into: non-porous film and microporous film due to the difference of its processing technology. There are three preparation methods: calendering film forming method, casting film forming method and blowing film forming method. Both calendering and casting methods can be used to produce non-porous and microporous films, while blown film-forming methods can only be used to produce non-porous films.
现有技术中，为到达环境保护的要求，水溶性粘合剂替代了溶剂型粘合剂。水溶性粘合剂是一种新型的天然的物质，分为单 组分和双组分两大系列的产品，其单组分系列产品的特点是工艺操作简单、生产成本低、粘合速度快且能改善本身的粘合性能。然而双组分系列产品在剥离强度、耐化学和耐热性能有很大优势。由于水分散型粘合剂是以水作为溶剂，不存在污染环境的问题，有很好的发展前景。然而不足之处是表面润湿性差、固化时间长、溶液中粘合剂组成物分散不均匀、适用材料少。In the prior art, in order to meet the requirements of environmental protection, water-soluble adhesives have replaced solvent-based adhesives. Water-soluble adhesive is a new type of natural substance, which is divided into two series of one-component and two-component products. The one-component series products are characterized by simple process operation, low production cost and fast bonding speed. And can improve its own adhesion properties. However, two-component series products have great advantages in peel strength, chemical resistance and thermal resistance. Since the water-dispersed adhesive uses water as a solvent, there is no problem of polluting the environment, and it has a good development prospect. However, the disadvantages are poor surface wettability, long curing time, uneven dispersion of the adhesive composition in the solution, and few suitable materials.
在传统工艺中，两种不同材质的面料复合一直是一大难题，通常通过层压的方式制备复合织物，层压方法主要由粘合剂法、压延法、焰熔法和热熔层压法。In the traditional process, the composite fabric of two different materials has always been a big problem. The composite fabric is usually prepared by lamination. The lamination method mainly includes adhesive method, calendering method, flame fusion method and hot melt lamination method. .
现有技术中也有一些技术尝试对篮球服之类用于运动服装的面料进行改进，如申请公布号为CN 108677319 A的中国专利，但是这些专利更加注重的是织造方法的改进和发展而是不是面料的改进与发展。In the prior art, there are also some technical attempts to improve the fabrics used for sportswear such as basketball clothes, such as the Chinese patent with the application publication number CN 108677319 A, but these patents pay more attention to the improvement and development of the weaving method rather than the Improvement and development of fabrics.
发明内容SUMMARY OF THE INVENTION
由于现有技术中存在上述不足，本发明开发了一种吸湿排汗防感冒篮球服，使用了新型的双层面料，打造了一款透气性和保暖性兼具的篮球服。Due to the above deficiencies in the prior art, the present invention develops a moisture-absorbing, sweat-wicking and cold-proof basketball uniform, using a new type of double-layer fabric to create a basketball uniform with both breathability and warmth retention.
具体地，本发明是通过下述技术方案实现的：Specifically, the present invention is achieved through the following technical solutions:
一种吸湿排汗防感冒的篮球服，其特征在于，由双层面料制备而成；A moisture-absorbing, sweat-wicking and cold-proof basketball uniform is characterized in that it is prepared from double-layer fabrics;
所述的双层面料包括外层面料和贴身面料；The double-layer fabric includes an outer layer fabric and a close-fitting fabric;
外层面料由保暖纤维制备而成，贴身面料为单面沉积有聚酰胺的聚乙烯纤维布；The outer fabric is made of thermal insulation fibers, and the body-fitting fabric is a polyethylene fiber cloth with polyamide deposited on one side;
外层面料和贴身面料通过层压复合工艺粘接。The outer fabric and the body fabric are bonded by a lamination lamination process.
优选地，所述保暖纤维为天然纤维或改性纤维；Preferably, the thermal insulation fiber is a natural fiber or a modified fiber;
所述天然纤维为棉纤维或羊毛纤维或驼绒纤维；Described natural fiber is cotton fiber or wool fiber or camel hair fiber;
所述改性纤维为改性棉纤维或改性羊毛纤维或改性驼绒纤维。The modified fibers are modified cotton fibers or modified wool fibers or modified camel hair fibers.
优选地，所述改性纤维的制备方法为将天然纤维在改性液中浸渍2-5小时，浸渍温度为90-110℃，浸渍压力为10-20MPa；Preferably, the preparation method of the modified fiber is to immerse the natural fiber in the modification solution for 2-5 hours, the immersion temperature is 90-110°C, and the immersion pressure is 10-20MPa;
所述天然纤维与改性液的质量比为(2-3)：1；The mass ratio of the natural fiber to the modified liquid is (2-3): 1;
所述改性液由高分子引发剂、稀释剂和不饱和聚酯预聚物制备而成。The modified liquid is prepared from a polymer initiator, a diluent and an unsaturated polyester prepolymer.
优选地，所述不饱和聚酯预聚物制备方法如下：将饱和二元醇、二元酸加入到反应容器中，随后依次加入催化剂和阻聚剂，在惰性气体的保护下，将体系加热至140-200℃，并保持2-5小时，随后在140-180℃/0.05-0.08MPa 的条件下蒸除低沸点物质，剩余液体用80-90℃的水洗涤1-3次，取有机相，烘干至恒重，即得不饱和聚酯预聚物；Preferably, the preparation method of the unsaturated polyester prepolymer is as follows: adding saturated diol and dibasic acid into the reaction vessel, then adding catalyst and polymerization inhibitor in sequence, and heating the system under the protection of inert gas to 140-200°C and kept for 2-5 hours, then the low-boiling substances were distilled off under the conditions of 140-180°C/0.05-0.08MPa, the remaining liquid was washed with water at 80-90°C for 1-3 times, and the organic phase, and dried to constant weight to obtain unsaturated polyester prepolymer;
所述阻聚剂为醌类化合物阻聚剂或醌类化合物/无机化合物复合阻聚剂；The polymerization inhibitor is a quinone compound polymerization inhibitor or a quinone compound/inorganic compound composite polymerization inhibitor;
所述的醌类化合物阻聚剂选自对苯二醌、四氯苯醌、1,4-萘醌中的任意一种；The quinone compound polymerization inhibitor is selected from any one of terephthaloquinone, tetrachlorobenzoquinone and 1,4-naphthoquinone;
所述醌类化合物/无机化合物复合阻聚剂中的醌类化合物选自对苯二醌、四氯苯醌、1,4-萘醌中的任意一种；The quinone compound in the quinone compound/inorganic compound composite polymerization inhibitor is selected from any one of terephthaloquinone, tetrachlorobenzoquinone, and 1,4-naphthoquinone;
所述醌类化合物/无机化合物复合阻聚剂中的无机化合物选自氯化铁、氧化亚铜、硫化钠、甲基丙烯钴、N,N-二正丁基二硫代氨基甲酸铜中的任意一种。The inorganic compound in the quinone compound/inorganic compound composite polymerization inhibitor is selected from ferric chloride, cuprous oxide, sodium sulfide, cobalt methacrylate, and N,N-di-n-butyldithiocarbamate copper. any kind.
当阻聚剂为醌类化合物阻聚剂时，所述饱和二元醇：二元酸：催化剂：阻聚剂的摩尔比为1：(0.9-1.0)：(0.008-0.01)：(0.015-0.02)；When the polymerization inhibitor is a quinone compound polymerization inhibitor, the molar ratio of the saturated diol:dibasic acid:catalyst:polymerization inhibitor is 1:(0.9-1.0):(0.008-0.01):(0.015- 0.02);
当阻聚剂为醌类化合物/无机化合物复合阻聚剂时，所述饱和二元醇：二元酸：催化剂：醌类化合物：无机化合物的摩尔比为1：(0.9-1.0)：(0.008-0.01)： (0.013-0.016)：(0.002-0.008)；When the polymerization inhibitor is a quinone compound/inorganic compound composite polymerization inhibitor, the molar ratio of the saturated diol:dibasic acid:catalyst:quinone compound:inorganic compound is 1:(0.9-1.0):(0.008 -0.01): (0.013-0.016): (0.002-0.008);
所述饱和二元醇选自乙二醇、丙二醇、一缩二乙二醇和一缩二丙二醇中的任意一种；Described saturated dihydric alcohol is selected from any one in ethylene glycol, propylene glycol, diethylene glycol and dipropylene glycol;
所述二元酸由不饱和二元酸和饱和二元酸组成；Described dibasic acid is made up of unsaturated dibasic acid and saturated dibasic acid;
所述不饱和二元酸为衣康酸或丁烯二酸；Described unsaturated dibasic acid is itaconic acid or butenedioic acid;
所述的饱和二元酸选自邻苯二甲酸、间苯二甲酸、乙二酸、丙二酸、丁二酸、戊二酸、己二酸中的任意一种；Described saturated dibasic acid is selected from any one in phthalic acid, isophthalic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid;
所述催化剂选自二丁基锡二月桂酸酯、辛酸亚锡、二(十二烷基硫)二丁基锡、二醋酸二丁基锡、对甲苯磺酸、三氧化二锑、醋酸锑、乙二醇锑中的任意一种；The catalyst is selected from dibutyltin dilaurate, stannous octoate, bis(dodecyl sulfide) dibutyltin, dibutyltin diacetate, p-toluenesulfonic acid, antimony trioxide, antimony acetate, and ethylene glycol antimony. any of the
优选地，所述改性液的制备方法为将不饱和聚酯预聚物、稀释剂和高分子引发剂加入到索氏提取器中，在110-120℃条件下提取3-5小时，所得液体即为改性液；Preferably, the preparation method of the modified liquid is as follows: adding unsaturated polyester prepolymer, diluent and polymer initiator into a Soxhlet extractor, and extracting at 110-120° C. for 3-5 hours. The liquid is the modified liquid;
所述稀释剂选自苯乙烯、衣康酸二甲酯、甲基丙烯酸甲酯中的任意一种或任意两种的任意比例混合物；Described diluent is selected from styrene, dimethyl itaconate, methyl methacrylate any one or the mixture of any ratio of any two;
所述高分子引发剂选自过氧叔丁醇、过苯甲酸特丁酯、过氧化二叔丁基、 1,1-双(叔丁基过氧基)-3,3,5-三甲基环己烷中的任意一种；The polymer initiator is selected from tert-butyl peroxy, tert-butyl perbenzoate, di-tert-butyl peroxide, 1,1-bis(tert-butylperoxy)-3,3,5-trimethyl any one of cyclohexane;
所述不饱和聚酯预聚物：稀释剂：高分子引发剂的质量比为(2-3)：1： (0.01-0.05)。The mass ratio of the unsaturated polyester prepolymer: diluent: polymer initiator is (2-3): 1: (0.01-0.05).
优选地，所述单面沉积有聚酰胺的聚乙烯纤维布的制备方法如下：将聚酰胺溶解于甲酸水溶液中，以聚乙烯纤维布为衬底，使用静电纺丝法将聚酰胺的甲酸溶液制得的纤维沉积于聚乙烯纤维布上，使沉积层厚度为 0.020-0.050mm，即得单面沉积有聚酰胺的聚乙烯纤维布；Preferably, the preparation method of the polyethylene fiber cloth with polyamide deposited on one side is as follows: the polyamide is dissolved in an aqueous solution of formic acid, the polyethylene fiber cloth is used as a substrate, and the formic acid solution of the polyamide is prepared by electrospinning. The obtained fibers are deposited on the polyethylene fiber cloth, so that the thickness of the deposited layer is 0.020-0.050 mm, that is, the polyethylene fiber cloth with polyamide deposited on one side is obtained;
所述聚酰胺的质量为甲酸水溶液质量的30-60％；The mass of the polyamide is 30-60% of the mass of the formic acid aqueous solution;
所述甲酸水溶液的浓度为15-30wt％。The concentration of the formic acid aqueous solution is 15-30 wt%.
优选地，所述静电纺丝工艺条件为喷丝头到接收屏垂直距离为10-15cm，电压15-35kV，20-30℃，相对湿度60-65％。Preferably, the electrospinning process conditions are that the vertical distance from the spinneret to the receiving screen is 10-15cm, the voltage is 15-35kV, the temperature is 20-30°C, and the relative humidity is 60-65%.
优选地，所述聚乙烯纤维布克重为180-500g/m2。Preferably, the polyethylene fiber has a gram weight of 180-500 g/m 2 .
制备上述吸湿排汗防感冒的篮球服方法，其特征在于，制备步骤如下：The method for preparing the above-mentioned moisture-absorbing, sweat-wicking and cold-proof basketball uniform is characterized in that the preparation steps are as follows:
(1)将保暖纤维通过常规方法编织成克重为150-250g/m2的外层面料；( 1 ) Weaving the thermal insulation fiber into an outer layer fabric with a gram weight of 150-250g/m by conventional methods;
(2)在外层面料的任意一面涂抹粘合剂，上胶量为15-30g/m2；(2) Apply adhesive on any side of the outer fabric, and the amount of glue is 15-30g/m 2 ;
(3)将外层面料涂有粘合胶的一面单面沉积有聚酰胺的聚乙烯纤维布的未沉积聚酰胺的一面贴合，通过常规的层压复合工艺制得双层面料；(3) one side of the outer layer fabric coated with adhesive glue is deposited with one side of the un-deposited polyamide of the polyethylene fiber cloth of polyamide, and the double-layer fabric is obtained by conventional lamination and composite technology;
所述层压复合工艺参数如下：层压温度100-130℃，层压压力2.0-4.0 kgf/cm2，层压时间5-15s；The lamination and composite process parameters are as follows: lamination temperature 100-130°C, lamination pressure 2.0-4.0 kgf/cm 2 , lamination time 5-15s;
(4)将双层面料剪裁缝制，得到吸湿排汗防感冒篮球服。(4) The double-layer fabric is cut and sewn to obtain a moisture-wicking, sweat-proof and cold-proof basketball uniform.
优选地，所述粘合剂为EVA和/或TPR热熔胶。Preferably, the adhesive is EVA and/or TPR hot melt adhesive.
优选地，当粘合剂为EVA/TPR复合热熔胶时，制备方法如下：Preferably, when the adhesive is EVA/TPR composite hot melt adhesive, the preparation method is as follows:
将EVA热熔胶加热至170-180℃，加入TPR热熔胶，混合均匀，自然降至室温，即得。Heat the EVA hot-melt adhesive to 170-180°C, add the TPR hot-melt adhesive, mix evenly, and naturally drop to room temperature.
本发明的有益之处在于：提供了一种同时具有排汗和保暖功效的篮球服，外层使用保暖性能好的保暖纤维，诸如棉纤维、羊毛纤维等，贴身面使用一些透气性排水性较好的纤维，有助于快速排出汗水，这样的设置有利于在较低温度下保证人的体温，不至于忽冷忽热导致感冒发烧。本发明使用了热熔法制备复合材料，由于使用了单面沉积有聚酰胺的聚乙烯纤维布，无需再使用中间复合膜，即可制得透气性和保暖性兼具的面料。The present invention has the advantages of providing a basketball uniform with the functions of perspiration and keeping warm at the same time, the outer layer uses thermal insulation fibers with good thermal insulation properties, such as cotton fibers, wool fibers, etc. Good fibers help to quickly expel sweat. This setting is conducive to keeping people's body temperature at a lower temperature, so as not to cause colds and fevers due to hot and cold. The present invention uses the hot-melt method to prepare the composite material, and because the polyethylene fiber cloth with polyamide deposited on one side is used, the fabric with both air permeability and heat preservation can be obtained without using an intermediate composite film.
具体实施方式Detailed ways
下面结合具体实施方式来对本发明进行进一步详细阐述，下述实施例仅用来解释本发明，不能视为对本发明的进一步限制。The present invention will be further elaborated below in conjunction with the specific embodiments. The following examples are only used to explain the present invention and should not be regarded as a further limitation of the present invention.
具体地，下述实施例中使用的原料来源或CAS号如下：Specifically, the raw material sources or CAS numbers used in the following examples are as follows:
棉纤维，为细绒棉，平均长度29mm，线密度1.84dtex，安平县威业棉油有限公司生产。Cotton fiber is fine-staple cotton, with an average length of 29mm and a linear density of 1.84dtex, produced by Anping Weiye Cotton Oil Co., Ltd.
聚乙烯纤维布，均为超高分子量聚乙烯布，三种不同克重的纤维布均为浙江蒙泰特种材料科技有限公司生产。Polyethylene fiber cloths are all ultra-high molecular weight polyethylene cloths, and three kinds of fiber cloths with different gram weights are produced by Zhejiang Mengtai Special Material Technology Co., Ltd.
聚酰胺，为聚酰胺6，即尼龙6，纤维通用级，德国巴斯夫生产。Polyamide is polyamide 6, namely nylon 6, general-purpose fiber, produced by BASF, Germany.
一缩二丙二醇，CAS号：110-98-5。Dipropylene glycol, CAS number: 110-98-5.
丙二酸，CAS号：141-82-2。Malonic acid, CAS number: 141-82-2.
丁二酸，CAS号：110-15-6。Succinic acid, CAS number: 110-15-6.
戊二酸，CAS号：110-94-1。Glutaric acid, CAS number: 110-94-1.
过氧化二叔丁基，CAS号：110-05-4。Di-tert-butyl peroxide, CAS number: 110-05-4.
衣康酸二甲酯，CAS号：617-52-7。Dimethyl itaconate, CAS number: 617-52-7.
衣康酸，CAS号：97-65-4。Itaconic acid, CAS number: 97-65-4.
乙二醇锑，CAS号：29736-75-2。Ethylene glycol antimony, CAS number: 29736-75-2.
对苯二醌，CAS号：106-51-4。Paraquinone, CAS number: 106-51-4.
硫化钠，CAS号：1313-82-2。Sodium sulfide, CAS number: 1313-82-2.
EVA热熔胶，型号为3150M，由广东舜天新材料有限公司生产。EVA hot melt adhesive, model 3150M, produced by Guangdong Shuntian New Material Co., Ltd.
TPR热熔胶，型号为8180M，由广东舜天新材料有限公司生产。TPR hot melt adhesive, model 8180M, is produced by Guangdong Shuntian New Material Co., Ltd.
下述实施例中使用的织机为青岛万华机械有限公司生产的Z88-230CM型剑杆织机。The loom used in the following examples is the Z88-230CM type rapier loom produced by Qingdao Wanhua Machinery Co., Ltd.
实施例1Example 1
一种吸湿排汗防感冒的篮球服，由双层面料制备而成；A moisture-absorbing, sweat-wicking and cold-proof basketball uniform is prepared from double-layer fabrics;
外层面料由保暖纤维制备而成，贴身面料为单面沉积有聚酰胺的聚乙烯纤维布；The outer fabric is made of thermal insulation fibers, and the body-fitting fabric is a polyethylene fiber cloth with polyamide deposited on one side;
外层面料和贴身面料通过层压复合工艺粘接。The outer fabric and the body fabric are bonded by a lamination lamination process.
所述保暖纤维为改性棉纤维，改性棉纤维的制备方法为将棉纤维在3倍棉纤维质量的改性液中浸渍3小时，浸渍温度为100℃，浸渍压力为12MPa；The thermal insulation fiber is a modified cotton fiber, and the preparation method of the modified cotton fiber is to immerse the cotton fiber in a modification liquid with a mass of 3 times the cotton fiber for 3 hours, the immersion temperature is 100° C., and the immersion pressure is 12 MPa;
所述改性液由过氧化二叔丁基、衣康酸二甲酯和不饱和聚酯预聚物制备而成。The modified liquid is prepared from di-tert-butyl peroxide, dimethyl itaconic acid and unsaturated polyester prepolymer.
所述不饱和聚酯预聚物制备方法如下：将134g一缩二丙二醇、52g丙二酸和65g衣康酸加入到反应容器中，随后依次加入催化剂4.2g乙二醇锑和 2.04g复合阻聚剂对苯二醌/硫化钠，在氮气的保护下，将体系加热至140℃，并保持3小时，随后在140℃/0.05MPa的条件下蒸除低沸点物质，剩余液体用50g 85℃的水洗涤1次，取有机相，120℃烘干至恒重，即得不饱和聚酯预聚物；The preparation method of the unsaturated polyester prepolymer is as follows: 134g of dipropylene glycol, 52g of malonic acid and 65g of itaconic acid are added to the reaction vessel, and then 4.2g of catalysts 4.2g of ethylene glycol antimony and 2.04g of composite resistance are added in sequence. For the polymerization agent terephthaloquinone/sodium sulfide, under the protection of nitrogen, the system was heated to 140 ° C and kept for 3 hours, then the low boiling point substances were distilled off under the condition of 140 ° C / 0.05MPa, and the remaining liquid was 50 g of 85 ° C Washing with water once, taking the organic phase and drying at 120°C to constant weight to obtain unsaturated polyester prepolymer;
所述复合阻聚剂对苯二醌/硫化钠的制备方法为将对苯二醌固体和硫化钠固体按摩尔比4:1混合即得。The preparation method of the composite polymerization inhibitor terephthaloquinone/sodium sulfide is obtained by mixing terephthaloquinone solid and sodium sulfide solid in a molar ratio of 4:1.
所述改性液的制备方法为将100g不饱和聚酯预聚物、0.6g过氧化二叔丁基、40g衣康酸二甲酯加入到索氏提取器中，在110℃条件下提取3小时，所得液体即为改性液。The preparation method of the modified liquid is to add 100 g of unsaturated polyester prepolymer, 0.6 g of di-tert-butyl peroxide and 40 g of dimethyl itaconic acid into a Soxhlet extractor, and extract 3 hours, the resulting liquid is the modified liquid.
所述单面沉积有聚酰胺的聚乙烯纤维布的制备方法如下：将聚酰胺溶解于20wt％甲酸水溶液中，以聚乙烯纤维布为衬底，使用静电纺丝法将聚酰胺的甲酸溶液制得的纤维沉积于聚乙烯纤维布上，使沉积层厚度为0.030mm，即得单面沉积有聚酰胺的聚乙烯纤维布；The preparation method of the polyethylene fiber cloth with polyamide deposited on one side is as follows: the polyamide is dissolved in a 20wt% formic acid aqueous solution, the polyethylene fiber cloth is used as a substrate, and the formic acid solution of the polyamide is prepared by an electrospinning method. The obtained fiber is deposited on the polyethylene fiber cloth, so that the thickness of the deposited layer is 0.030mm, that is, the polyethylene fiber cloth with polyamide deposited on one side is obtained;
所述聚酰胺的质量为甲酸水溶液质量的50％。The mass of the polyamide is 50% of the mass of the formic acid aqueous solution.
所述静电纺丝工艺条件为喷丝头到接收屏垂直距离为15cm，电压35kV， 25℃，相对湿度65％。The electrospinning process conditions are that the vertical distance from the spinneret to the receiving screen is 15cm, the voltage is 35kV, the temperature is 25°C, and the relative humidity is 65%.
所述聚乙烯纤维布克重180g/m2。The polyethylene fiber has a book weight of 180 g/m 2 .
一种吸湿排汗防感冒的篮球服，制备方法如下：A kind of basketball uniform for moisture absorption and perspiration prevention and cold prevention, the preparation method is as follows:
(1)将保暖纤维通过常规方法编织成克重为220g/m2的外层面料；( 1 ) Weaving the thermal insulation fiber into an outer layer fabric with a gram weight of 220g/m by conventional methods;
(2)在外层面料的任意一面涂抹粘合剂，上胶量为20g/m2；(2) Apply adhesive on any side of the outer fabric, and the amount of glue is 20g/m 2 ;
(3)将外层面料涂有粘合胶的一面单面沉积有聚酰胺的聚乙烯纤维布的未沉积聚酰胺的一面贴合，通过常规的层压复合工艺制得双层面料；(3) one side of the outer layer fabric coated with adhesive glue is deposited with one side of the un-deposited polyamide of the polyethylene fiber cloth of polyamide, and the double-layer fabric is obtained by conventional lamination and composite technology;
所述层压复合工艺参数如下：层压温度120℃，层压压力2.5kgf/cm2，层压时间8s；The lamination and composite process parameters are as follows: lamination temperature 120°C, lamination pressure 2.5kgf/cm 2 , lamination time 8s;
所述粘合胶为EVA热熔胶；The adhesive is EVA hot melt adhesive;
(4)将双层面料剪裁缝制，得到吸湿排汗防感冒篮球服。(4) The double-layer fabric is cut and sewn to obtain a moisture-wicking, sweat-proof and cold-proof basketball uniform.
实施例2Example 2
一种吸湿排汗防感冒的篮球服，由双层面料制备而成；A moisture-absorbing, sweat-wicking and cold-proof basketball uniform is prepared from double-layer fabrics;
外层面料由保暖纤维制备而成，贴身面料为单面沉积有聚酰胺的聚乙烯纤维布；The outer fabric is made of thermal insulation fibers, and the body-fitting fabric is a polyethylene fiber cloth with polyamide deposited on one side;
外层面料和贴身面料通过层压复合工艺粘接。The outer fabric and the body fabric are bonded by a lamination lamination process.
所述保暖纤维为改性棉纤维，改性棉纤维的制备方法为将棉纤维在3倍棉纤维质量的改性液中浸渍3小时，浸渍温度为100℃，浸渍压力为12MPa；The thermal insulation fiber is a modified cotton fiber, and the preparation method of the modified cotton fiber is to immerse the cotton fiber in a modification liquid with a mass of 3 times the cotton fiber for 3 hours, the immersion temperature is 100° C., and the immersion pressure is 12 MPa;
所述改性液由过氧化二叔丁基、衣康酸二甲酯和不饱和聚酯预聚物制备而成。The modified liquid is prepared from di-tert-butyl peroxide, dimethyl itaconic acid and unsaturated polyester prepolymer.
所述不饱和聚酯预聚物制备方法如下：将134g一缩二丙二醇、59g丁二酸和65g衣康酸加入到反应容器中，随后依次加入催化剂4.2g乙二醇锑和 2.04g复合阻聚剂对苯二醌/硫化钠，在氮气的保护下，将体系加热至175℃，并保持3小时，随后在175℃/0.05MPa的条件下蒸除低沸点物质，剩余液体用50g 85℃的水洗涤1次，取有机相，120℃烘干至恒重，即得不饱和聚酯预聚物；The preparation method of the unsaturated polyester prepolymer is as follows: 134g of dipropylene glycol, 59g of succinic acid and 65g of itaconic acid are added into the reaction vessel, and then 4.2g of catalysts 4.2g of ethylene glycol antimony and 2.04g of composite resistance are added in sequence. The polymerization agent terephthaloquinone/sodium sulfide, under the protection of nitrogen, the system was heated to 175 ° C and kept for 3 hours, then the low boiling point substances were distilled off under the condition of 175 ° C / 0.05 MPa, and the remaining liquid was 50 g of 85 ° C Wash once with water, take the organic phase, and dry at 120°C to constant weight to obtain unsaturated polyester prepolymer;
所述复合阻聚剂对苯二醌/硫化钠的制备方法为将对苯二醌固体和硫化钠固体按摩尔比4:1混合即得。The preparation method of the composite polymerization inhibitor terephthaloquinone/sodium sulfide is obtained by mixing terephthaloquinone solid and sodium sulfide solid in a molar ratio of 4:1.
所述改性液的制备方法为将100g不饱和聚酯预聚物、0.6g过氧化二叔丁基、40g衣康酸二甲酯加入到索氏提取器中，在110℃条件下提取3小时，所得液体即为改性液。The preparation method of the modified liquid is to add 100 g of unsaturated polyester prepolymer, 0.6 g of di-tert-butyl peroxide and 40 g of dimethyl itaconic acid into a Soxhlet extractor, and extract 3 hours, the resulting liquid is the modified liquid.
所述单面沉积有聚酰胺的聚乙烯纤维布的制备方法如下：将聚酰胺溶解于20wt％甲酸水溶液中，以聚乙烯纤维布为衬底，使用静电纺丝法将聚酰胺的甲酸溶液制得的纤维沉积于聚乙烯纤维布上，使沉积层厚度为0.030mm，即得单面沉积有聚酰胺的聚乙烯纤维布；The preparation method of the polyethylene fiber cloth with polyamide deposited on one side is as follows: the polyamide is dissolved in a 20wt% formic acid aqueous solution, the polyethylene fiber cloth is used as a substrate, and the formic acid solution of the polyamide is prepared by an electrospinning method. The obtained fiber is deposited on the polyethylene fiber cloth, so that the thickness of the deposited layer is 0.030mm, that is, the polyethylene fiber cloth with polyamide deposited on one side is obtained;
所述聚酰胺的质量为甲酸水溶液质量的50％。The mass of the polyamide is 50% of the mass of the formic acid aqueous solution.
所述静电纺丝工艺条件为喷丝头到接收屏垂直距离为15cm，电压35kV， 25℃，相对湿度65％。The electrospinning process conditions are that the vertical distance from the spinneret to the receiving screen is 15cm, the voltage is 35kV, the temperature is 25°C, and the relative humidity is 65%.
所述聚乙烯纤维布克重180g/m2。The polyethylene fiber has a book weight of 180 g/m 2 .
一种吸湿排汗防感冒的篮球服，制备方法如下：A kind of basketball uniform for moisture absorption and perspiration prevention and cold prevention, the preparation method is as follows:
(1)将保暖纤维通过常规方法编织成克重为220g/m2的外层面料；( 1 ) Weaving the thermal insulation fiber into an outer layer fabric with a gram weight of 220g/m by conventional methods;
(2)在外层面料的任意一面涂抹粘合剂，上胶量为20g/m2；(2) Apply adhesive on any side of the outer fabric, and the amount of glue is 20g/m 2 ;
(3)将外层面料涂有粘合胶的一面单面沉积有聚酰胺的聚乙烯纤维布的未沉积聚酰胺的一面贴合，通过常规的层压复合工艺制得双层面料；(3) one side of the outer layer fabric coated with adhesive glue is deposited with one side of the un-deposited polyamide of the polyethylene fiber cloth of polyamide, and the double-layer fabric is obtained by conventional lamination and composite technology;
所述层压复合工艺参数如下：层压温度120℃，层压压力2.5kgf/cm2，层压时间8s；The lamination and composite process parameters are as follows: lamination temperature 120°C, lamination pressure 2.5kgf/cm 2 , lamination time 8s;
所述粘合胶为EVA热熔胶；The adhesive is EVA hot melt adhesive;
(4)将双层面料剪裁缝制，得到吸湿排汗防感冒篮球服。(4) The double-layer fabric is cut and sewn to obtain a moisture-wicking, sweat-proof and cold-proof basketball uniform.
实施例3Example 3
一种吸湿排汗防感冒的篮球服，由双层面料制备而成；A moisture-absorbing, sweat-wicking and cold-proof basketball uniform is prepared from double-layer fabrics;
外层面料由保暖纤维制备而成，贴身面料为单面沉积有聚酰胺的聚乙烯纤维布；The outer fabric is made of thermal insulation fibers, and the body-fitting fabric is a polyethylene fiber cloth with polyamide deposited on one side;
外层面料和贴身面料通过层压复合工艺粘接。The outer fabric and the body fabric are bonded by a lamination lamination process.
所述保暖纤维为改性棉纤维，改性棉纤维的制备方法为将棉纤维在3倍棉纤维质量的改性液中浸渍3小时，浸渍温度为100℃，浸渍压力为12MPa；The thermal insulation fiber is a modified cotton fiber, and the preparation method of the modified cotton fiber is to immerse the cotton fiber in a modification liquid with a mass of 3 times the cotton fiber for 3 hours, the immersion temperature is 100° C., and the immersion pressure is 12 MPa;
所述改性液由过氧化二叔丁基、衣康酸二甲酯和不饱和聚酯预聚物制备而成。The modified liquid is prepared from di-tert-butyl peroxide, dimethyl itaconic acid and unsaturated polyester prepolymer.
所述不饱和聚酯预聚物制备方法如下：将134g一缩二丙二醇、66g戊二酸和65g衣康酸加入到反应容器中，随后依次加入催化剂4.2g乙二醇锑和 2.04g复合阻聚剂对苯二醌/硫化钠，在氮气的保护下，将体系加热至175℃，并保持3小时，随后在175℃/0.05MPa的条件下蒸除低沸点物质，剩余液体用50g 85℃的水洗涤1次，取有机相，120℃烘干至恒重，即得不饱和聚酯预聚物；The preparation method of the unsaturated polyester prepolymer is as follows: 134g of dipropylene glycol, 66g of glutaric acid and 65g of itaconic acid are added to the reaction vessel, and then 4.2g of catalysts 4.2g of ethylene glycol antimony and 2.04g of composite resistance are added in sequence. The polymerization agent terephthaloquinone/sodium sulfide, under the protection of nitrogen, the system was heated to 175 ° C and kept for 3 hours, then the low boiling point substances were distilled off under the condition of 175 ° C / 0.05 MPa, and the remaining liquid was 50 g of 85 ° C Washing with water once, taking the organic phase and drying at 120°C to constant weight to obtain unsaturated polyester prepolymer;
所述复合阻聚剂对苯二醌/硫化钠的制备方法为将对苯二醌固体和硫化钠固体按摩尔比4:1混合即得。The preparation method of the composite polymerization inhibitor terephthaloquinone/sodium sulfide is obtained by mixing terephthaloquinone solid and sodium sulfide solid in a molar ratio of 4:1.
所述改性液的制备方法为将100g不饱和聚酯预聚物、0.6g过氧化二叔丁基、40g衣康酸二甲酯加入到索氏提取器中，在110℃条件下提取3小时，所得液体即为改性液。The preparation method of the modified liquid is to add 100 g of unsaturated polyester prepolymer, 0.6 g of di-tert-butyl peroxide and 40 g of dimethyl itaconic acid into a Soxhlet extractor, and extract 3 hours, the resulting liquid is the modified liquid.
所述单面沉积有聚酰胺的聚乙烯纤维布的制备方法如下：将聚酰胺溶解于20wt％甲酸水溶液中，以聚乙烯纤维布为衬底，使用静电纺丝法将聚酰胺的甲酸溶液制得的纤维沉积于聚乙烯纤维布上，使沉积层厚度为0.030mm，即得单面沉积有聚酰胺的聚乙烯纤维布；The preparation method of the polyethylene fiber cloth with polyamide deposited on one side is as follows: the polyamide is dissolved in a 20wt% formic acid aqueous solution, the polyethylene fiber cloth is used as a substrate, and the formic acid solution of the polyamide is prepared by an electrospinning method. The obtained fiber is deposited on the polyethylene fiber cloth, so that the thickness of the deposited layer is 0.030mm, that is, the polyethylene fiber cloth with polyamide deposited on one side is obtained;
所述聚酰胺的质量为甲酸水溶液质量的50％。The mass of the polyamide is 50% of the mass of the formic acid aqueous solution.
所述静电纺丝工艺条件为喷丝头到接收屏垂直距离为15cm，电压35kV， 25℃，相对湿度65％。The electrospinning process conditions are that the vertical distance from the spinneret to the receiving screen is 15cm, the voltage is 35kV, the temperature is 25°C, and the relative humidity is 65%.
所述聚乙烯纤维布克重180g/m2。The polyethylene fiber has a book weight of 180 g/m 2 .
一种吸湿排汗防感冒的篮球服，制备方法如下：A kind of basketball uniform for moisture absorption and perspiration prevention and cold prevention, the preparation method is as follows:
(1)将保暖纤维通过常规方法编织成克重为220g/m2的外层面料；( 1 ) Weaving the thermal insulation fiber into an outer layer fabric with a gram weight of 220g/m by conventional methods;
(2)在外层面料的任意一面涂抹粘合剂，上胶量为20g/m2；(2) Apply adhesive on any side of the outer fabric, and the amount of glue is 20g/m 2 ;
(3)将外层面料涂有粘合胶的一面单面沉积有聚酰胺的聚乙烯纤维布的未沉积聚酰胺的一面贴合，通过常规的层压复合工艺制得双层面料；(3) one side of the outer layer fabric coated with adhesive glue is deposited with one side of the un-deposited polyamide of the polyethylene fiber cloth of polyamide, and the double-layer fabric is obtained by conventional lamination and composite technology;
所述层压复合工艺参数如下：层压温度120℃，层压压力2.5kgf/cm2，层压时间8s；The lamination and composite process parameters are as follows: lamination temperature 120°C, lamination pressure 2.5kgf/cm 2 , lamination time 8s;
所述粘合胶为EVA热熔胶；The adhesive is EVA hot melt adhesive;
(4)将双层面料剪裁缝制，得到吸湿排汗防感冒篮球服。(4) The double-layer fabric is cut and sewn to obtain a moisture-wicking, sweat-proof and cold-proof basketball uniform.
实施例4Example 4
一种吸湿排汗防感冒的篮球服，由双层面料制备而成；A moisture-absorbing, sweat-wicking and cold-proof basketball uniform is prepared from double-layer fabrics;
外层面料由保暖纤维制备而成，贴身面料为单面沉积有聚酰胺的聚乙烯纤维布；The outer fabric is made of thermal insulation fibers, and the body-fitting fabric is a polyethylene fiber cloth with polyamide deposited on one side;
外层面料和贴身面料通过层压复合工艺粘接。The outer fabric and the body fabric are bonded by a lamination lamination process.
所述保暖纤维为改性棉纤维，改性棉纤维的制备方法为将棉纤维在3倍棉纤维质量的改性液中浸渍3小时，浸渍温度为100℃，浸渍压力为12MPa；The thermal insulation fiber is a modified cotton fiber, and the preparation method of the modified cotton fiber is to immerse the cotton fiber in a modification liquid with a mass of 3 times the cotton fiber for 3 hours, the immersion temperature is 100° C., and the immersion pressure is 12 MPa;
所述改性液由过氧化二叔丁基、衣康酸二甲酯和不饱和聚酯预聚物制备而成。The modified liquid is prepared from di-tert-butyl peroxide, dimethyl itaconic acid and unsaturated polyester prepolymer.
所述不饱和聚酯预聚物制备方法如下：将134g一缩二丙二醇、59g丁二酸和65g衣康酸加入到反应容器中，随后依次加入催化剂4.2g乙二醇锑和 2.04g复合阻聚剂对苯二醌/硫化钠，在氮气的保护下，将体系加热至175℃，并保持3小时，随后在175℃/0.05MPa的条件下蒸除低沸点物质，剩余液体用50g 85℃的水洗涤1次，取有机相，120℃烘干至恒重，即得不饱和聚酯预聚物；The preparation method of the unsaturated polyester prepolymer is as follows: 134g of dipropylene glycol, 59g of succinic acid and 65g of itaconic acid are added into the reaction vessel, and then 4.2g of catalysts 4.2g of ethylene glycol antimony and 2.04g of composite resistance are added in sequence. The polymerization agent terephthaloquinone/sodium sulfide, under the protection of nitrogen, the system was heated to 175 ° C and kept for 3 hours, then the low boiling point substances were distilled off under the condition of 175 ° C / 0.05 MPa, and the remaining liquid was 50 g of 85 ° C Washing with water once, taking the organic phase and drying at 120°C to constant weight to obtain unsaturated polyester prepolymer;
所述复合阻聚剂对苯二醌/硫化钠的制备方法为将对苯二醌固体和硫化钠固体按摩尔比4:1混合即得。The preparation method of the composite polymerization inhibitor terephthaloquinone/sodium sulfide is obtained by mixing terephthaloquinone solid and sodium sulfide solid in a molar ratio of 4:1.
所述改性液的制备方法为将100g不饱和聚酯预聚物、0.6g过氧化二叔丁基、40g衣康酸二甲酯加入到索氏提取器中，在110℃条件下提取3小时，所得液体即为改性液。The preparation method of the modified liquid is to add 100 g of unsaturated polyester prepolymer, 0.6 g of di-tert-butyl peroxide and 40 g of dimethyl itaconic acid into a Soxhlet extractor, and extract 3 hours, the resulting liquid is the modified liquid.
所述单面沉积有聚酰胺的聚乙烯纤维布的制备方法如下：将聚酰胺溶解于20wt％甲酸水溶液中，以聚乙烯纤维布为衬底，使用静电纺丝法将聚酰胺的甲酸溶液制得的纤维沉积于聚乙烯纤维布上，使沉积层厚度为0.030mm，即得单面沉积有聚酰胺的聚乙烯纤维布；The preparation method of the polyethylene fiber cloth with polyamide deposited on one side is as follows: the polyamide is dissolved in a 20wt% formic acid aqueous solution, the polyethylene fiber cloth is used as a substrate, and the formic acid solution of the polyamide is prepared by an electrospinning method. The obtained fiber is deposited on the polyethylene fiber cloth, so that the thickness of the deposited layer is 0.030mm, that is, the polyethylene fiber cloth with polyamide deposited on one side is obtained;
所述聚酰胺的质量为甲酸水溶液质量的50％。The mass of the polyamide is 50% of the mass of the formic acid aqueous solution.
所述静电纺丝工艺条件为喷丝头到接收屏垂直距离为15cm，电压35kV， 25℃，相对湿度65％。The electrospinning process conditions are that the vertical distance from the spinneret to the receiving screen is 15cm, the voltage is 35kV, the temperature is 25°C, and the relative humidity is 65%.
所述聚乙烯纤维布克重300g/m2。The polyethylene fiber has a book weight of 300 g/m 2 .
一种吸湿排汗防感冒的篮球服，制备方法如下：A kind of basketball uniform for moisture absorption and perspiration prevention and cold prevention, the preparation method is as follows:
(1)将保暖纤维通过常规方法编织成克重为220g/m2的外层面料；( 1 ) Weaving the thermal insulation fiber into an outer layer fabric with a gram weight of 220g/m by conventional methods;
(2)在外层面料的任意一面涂抹粘合剂，上胶量为20g/m2；(2) Apply adhesive on any side of the outer fabric, and the amount of glue is 20g/m 2 ;
(3)将外层面料涂有粘合胶的一面单面沉积有聚酰胺的聚乙烯纤维布的未沉积聚酰胺的一面贴合，通过常规的层压复合工艺制得双层面料；(3) one side of the outer layer fabric coated with adhesive glue is deposited with one side of the un-deposited polyamide of the polyethylene fiber cloth of polyamide, and the double-layer fabric is obtained by conventional lamination and composite technology;
所述层压复合工艺参数如下：层压温度120℃，层压压力2.5kgf/cm2，层压时间8s；The lamination and composite process parameters are as follows: lamination temperature 120°C, lamination pressure 2.5kgf/cm 2 , lamination time 8s;
所述粘合胶为EVA热熔胶；The adhesive is EVA hot melt adhesive;
(4)将双层面料剪裁缝制，得到吸湿排汗防感冒篮球服。(4) The double-layer fabric is cut and sewn to obtain a moisture-wicking, sweat-proof and cold-proof basketball uniform.
实施例5Example 5
一种吸湿排汗防感冒的篮球服，由双层面料制备而成；A moisture-absorbing, sweat-wicking and cold-proof basketball uniform is prepared from double-layer fabrics;
外层面料由保暖纤维制备而成，贴身面料为单面沉积有聚酰胺的聚乙烯纤维布；The outer fabric is made of thermal insulation fibers, and the body-fitting fabric is a polyethylene fiber cloth with polyamide deposited on one side;
外层面料和贴身面料通过层压复合工艺粘接。The outer fabric and the body fabric are bonded by a lamination lamination process.
所述保暖纤维为改性棉纤维，改性棉纤维的制备方法为将棉纤维在3倍棉纤维质量的改性液中浸渍3小时，浸渍温度为100℃，浸渍压力为12MPa；The thermal insulation fiber is a modified cotton fiber, and the preparation method of the modified cotton fiber is to immerse the cotton fiber in a modification liquid with a mass of 3 times the cotton fiber for 3 hours, the immersion temperature is 100° C., and the immersion pressure is 12 MPa;
所述改性液由过氧化二叔丁基、衣康酸二甲酯和不饱和聚酯预聚物制备而成。The modified liquid is prepared from di-tert-butyl peroxide, dimethyl itaconic acid and unsaturated polyester prepolymer.
所述不饱和聚酯预聚物制备方法如下：将134g一缩二丙二醇、59g丁二酸和65g衣康酸加入到反应容器中，随后依次加入催化剂4.2g乙二醇锑和 2.04g复合阻聚剂对苯二醌/硫化钠，在氮气的保护下，将体系加热至175℃，并保持3小时，随后在175℃/0.05MPa的条件下蒸除低沸点物质，剩余液体用50g 85℃的水洗涤1次，取有机相，120℃烘干至恒重，即得不饱和聚酯预聚物；The preparation method of the unsaturated polyester prepolymer is as follows: 134g of dipropylene glycol, 59g of succinic acid and 65g of itaconic acid are added into the reaction vessel, and then 4.2g of catalysts 4.2g of ethylene glycol antimony and 2.04g of composite resistance are added in sequence. The polymerization agent terephthaloquinone/sodium sulfide, under the protection of nitrogen, the system was heated to 175 ° C and kept for 3 hours, then the low boiling point substances were distilled off under the condition of 175 ° C / 0.05 MPa, and the remaining liquid was 50 g of 85 ° C Washing with water once, taking the organic phase and drying at 120°C to constant weight to obtain unsaturated polyester prepolymer;
所述复合阻聚剂对苯二醌/硫化钠的制备方法为将对苯二醌固体和硫化钠固体按摩尔比4:1混合即得。The preparation method of the composite polymerization inhibitor terephthaloquinone/sodium sulfide is obtained by mixing terephthaloquinone solid and sodium sulfide solid in a molar ratio of 4:1.
所述改性液的制备方法为将100g不饱和聚酯预聚物、0.6g过氧化二叔丁基、40g衣康酸二甲酯加入到索氏提取器中，在110℃条件下提取3小时，所得液体即为改性液。The preparation method of the modified liquid is to add 100 g of unsaturated polyester prepolymer, 0.6 g of di-tert-butyl peroxide and 40 g of dimethyl itaconic acid into a Soxhlet extractor, and extract 3 hours, the resulting liquid is the modified liquid.
所述单面沉积有聚酰胺的聚乙烯纤维布的制备方法如下：将聚酰胺溶解于20wt％甲酸水溶液中，以聚乙烯纤维布为衬底，使用静电纺丝法将聚酰胺的甲酸溶液制得的纤维沉积于聚乙烯纤维布上，使沉积层厚度为0.030mm，即得单面沉积有聚酰胺的聚乙烯纤维布；The preparation method of the polyethylene fiber cloth with polyamide deposited on one side is as follows: the polyamide is dissolved in a 20wt% formic acid aqueous solution, the polyethylene fiber cloth is used as a substrate, and the formic acid solution of the polyamide is prepared by an electrospinning method. The obtained fiber is deposited on the polyethylene fiber cloth, so that the thickness of the deposited layer is 0.030mm, that is, the polyethylene fiber cloth with polyamide deposited on one side is obtained;
所述聚酰胺的质量为甲酸水溶液质量的50％。The mass of the polyamide is 50% of the mass of the formic acid aqueous solution.
所述静电纺丝工艺条件为喷丝头到接收屏垂直距离为15cm，电压35kV， 25℃，相对湿度65％。The electrospinning process conditions are that the vertical distance from the spinneret to the receiving screen is 15cm, the voltage is 35kV, the temperature is 25°C, and the relative humidity is 65%.
所述聚乙烯纤维布克重500g/m2。The polyethylene fiber has a book weight of 500 g/m 2 .
一种吸湿排汗防感冒的篮球服，制备方法如下：A kind of basketball uniform for moisture absorption and perspiration prevention and cold prevention, the preparation method is as follows:
(1)将保暖纤维通过常规方法编织成克重为220g/m2的外层面料；( 1 ) Weaving the thermal insulation fiber into an outer layer fabric with a gram weight of 220g/m by conventional methods;
(2)在外层面料的任意一面涂抹粘合剂，上胶量为20g/m2；(2) Apply adhesive on any side of the outer fabric, and the amount of glue is 20g/m 2 ;
(3)将外层面料涂有粘合胶的一面单面沉积有聚酰胺的聚乙烯纤维布的未沉积聚酰胺的一面贴合，通过常规的层压复合工艺制得双层面料；(3) one side of the outer layer fabric coated with adhesive glue is deposited with one side of the un-deposited polyamide of the polyethylene fiber cloth of polyamide, and the double-layer fabric is obtained by conventional lamination and composite technology;
所述层压复合工艺参数如下：层压温度120℃，层压压力2.5kgf/cm2，层压时间8s；The lamination and composite process parameters are as follows: lamination temperature 120°C, lamination pressure 2.5kgf/cm 2 , lamination time 8s;
所述粘合胶为EVA热熔胶；The adhesive is EVA hot melt adhesive;
(4)将双层面料剪裁缝制，得到吸湿排汗防感冒篮球服。(4) The double-layer fabric is cut and sewn to obtain a moisture-wicking, sweat-proof and cold-proof basketball uniform.
实施例6Example 6
一种吸湿排汗防感冒的篮球服，由双层面料制备而成；A moisture-absorbing, sweat-wicking and cold-proof basketball uniform is prepared from double-layer fabrics;
外层面料由保暖纤维制备而成，贴身面料为单面沉积有聚酰胺的聚乙烯纤维布；The outer fabric is made of thermal insulation fibers, and the body-fitting fabric is a polyethylene fiber cloth with polyamide deposited on one side;
外层面料和贴身面料通过层压复合工艺粘接。The outer fabric and the body fabric are bonded by a lamination lamination process.
所述保暖纤维为改性棉纤维，改性棉纤维的制备方法为将棉纤维在3倍棉纤维质量的改性液中浸渍3小时，浸渍温度为100℃，浸渍压力为12MPa；The thermal insulation fiber is a modified cotton fiber, and the preparation method of the modified cotton fiber is to immerse the cotton fiber in a modification liquid with a mass of 3 times the cotton fiber for 3 hours, the immersion temperature is 100° C., and the immersion pressure is 12 MPa;
所述改性液由过氧化二叔丁基、衣康酸二甲酯和不饱和聚酯预聚物制备而成。The modified liquid is prepared from di-tert-butyl peroxide, dimethyl itaconic acid and unsaturated polyester prepolymer.
所述不饱和聚酯预聚物制备方法如下：将134g一缩二丙二醇、59g丁二酸和65g衣康酸加入到反应容器中，随后依次加入催化剂4.2g乙二醇锑和 2.04g复合阻聚剂对苯二醌/硫化钠，在氮气的保护下，将体系加热至175℃，并保持3小时，随后在175℃/0.05MPa的条件下蒸除低沸点物质，剩余液体用50g 85℃的水洗涤1次，取有机相，120℃烘干至恒重，即得不饱和聚酯预聚物；The preparation method of the unsaturated polyester prepolymer is as follows: 134g of dipropylene glycol, 59g of succinic acid and 65g of itaconic acid are added into the reaction vessel, and then 4.2g of catalysts 4.2g of ethylene glycol antimony and 2.04g of composite resistance are added in sequence. The polymerization agent terephthaloquinone/sodium sulfide, under the protection of nitrogen, the system was heated to 175 ° C and kept for 3 hours, then the low boiling point substances were distilled off under the condition of 175 ° C / 0.05 MPa, and the remaining liquid was 50 g of 85 ° C Washing with water once, taking the organic phase and drying at 120°C to constant weight to obtain unsaturated polyester prepolymer;
所述复合阻聚剂对苯二醌/硫化钠的制备方法为将对苯二醌固体和硫化钠固体按摩尔比4:1混合即得。The preparation method of the composite polymerization inhibitor terephthaloquinone/sodium sulfide is obtained by mixing terephthaloquinone solid and sodium sulfide solid in a molar ratio of 4:1.
所述改性液的制备方法为将100g不饱和聚酯预聚物、0.6g过氧化二叔丁基、40g衣康酸二甲酯加入到索氏提取器中，在110℃条件下提取3小时，所得液体即为改性液。The preparation method of the modified liquid is to add 100 g of unsaturated polyester prepolymer, 0.6 g of di-tert-butyl peroxide and 40 g of dimethyl itaconic acid into a Soxhlet extractor, and extract 3 hours, the resulting liquid is the modified liquid.
所述单面沉积有聚酰胺的聚乙烯纤维布的制备方法如下：将聚酰胺溶解于20wt％甲酸水溶液中，以聚乙烯纤维布为衬底，使用静电纺丝法将聚酰胺的甲酸溶液制得的纤维沉积于聚乙烯纤维布上，使沉积层厚度为0.030mm，即得单面沉积有聚酰胺的聚乙烯纤维布；The preparation method of the polyethylene fiber cloth with polyamide deposited on one side is as follows: the polyamide is dissolved in a 20wt% formic acid aqueous solution, the polyethylene fiber cloth is used as a substrate, and the formic acid solution of the polyamide is prepared by an electrospinning method. The obtained fiber is deposited on the polyethylene fiber cloth, so that the thickness of the deposited layer is 0.030mm, that is, the polyethylene fiber cloth with polyamide deposited on one side is obtained;
所述聚酰胺的质量为甲酸水溶液质量的50％。The mass of the polyamide is 50% of the mass of the formic acid aqueous solution.
所述静电纺丝工艺条件为喷丝头到接收屏垂直距离为15cm，电压35kV， 25℃，相对湿度65％。The electrospinning process conditions are that the vertical distance from the spinneret to the receiving screen is 15cm, the voltage is 35kV, the temperature is 25°C, and the relative humidity is 65%.
所述聚乙烯纤维布克重300g/m2。The polyethylene fiber has a book weight of 300 g/m 2 .
一种吸湿排汗防感冒的篮球服，制备方法如下：A kind of basketball uniform for moisture absorption and perspiration prevention and cold prevention, the preparation method is as follows:
(1)将保暖纤维通过常规方法编织成克重为220g/m2的外层面料；( 1 ) Weaving the thermal insulation fiber into an outer layer fabric with a gram weight of 220g/m by conventional methods;
(2)在外层面料的任意一面涂抹粘合剂，上胶量为20g/m2；(2) Apply adhesive on any side of the outer fabric, and the amount of glue is 20g/m 2 ;
(3)将外层面料涂有粘合胶的一面单面沉积有聚酰胺的聚乙烯纤维布的未沉积聚酰胺的一面贴合，通过常规的层压复合工艺制得双层面料；(3) one side of the outer layer fabric coated with adhesive glue is deposited with one side of the un-deposited polyamide of the polyethylene fiber cloth of polyamide, and the double-layer fabric is obtained by conventional lamination and composite technology;
所述层压复合工艺参数如下：层压温度120℃，层压压力2.5kgf/cm2，层压时间8s；The lamination and composite process parameters are as follows: lamination temperature 120°C, lamination pressure 2.5kgf/cm 2 , lamination time 8s;
所述粘合胶为TPR热熔胶；The adhesive is TPR hot melt adhesive;
(4)将双层面料剪裁缝制，得到吸湿排汗防感冒篮球服。(4) The double-layer fabric is cut and sewn to obtain a moisture-wicking, sweat-proof and cold-proof basketball uniform.
实施例7Example 7
一种吸湿排汗防感冒的篮球服，由双层面料制备而成；A moisture-absorbing, sweat-wicking and cold-proof basketball uniform is prepared from double-layer fabrics;
外层面料由保暖纤维制备而成，贴身面料为单面沉积有聚酰胺的聚乙烯纤维布；The outer fabric is made of thermal insulation fibers, and the body-fitting fabric is a polyethylene fiber cloth with polyamide deposited on one side;
外层面料和贴身面料通过层压复合工艺粘接。The outer fabric and the body fabric are bonded by a lamination lamination process.
所述保暖纤维为改性棉纤维，改性棉纤维的制备方法为将棉纤维在3倍棉纤维质量的改性液中浸渍3小时，浸渍温度为100℃，浸渍压力为12MPa；The thermal insulation fiber is a modified cotton fiber, and the preparation method of the modified cotton fiber is to immerse the cotton fiber in a modification liquid with a mass of 3 times the cotton fiber for 3 hours, the immersion temperature is 100° C., and the immersion pressure is 12 MPa;
所述改性液由过氧化二叔丁基、衣康酸二甲酯和不饱和聚酯预聚物制备而成。The modified liquid is prepared from di-tert-butyl peroxide, dimethyl itaconic acid and unsaturated polyester prepolymer.
所述不饱和聚酯预聚物制备方法如下：将134g一缩二丙二醇、59g丁二酸和65g衣康酸加入到反应容器中，随后依次加入催化剂4.2g乙二醇锑和 2.04g复合阻聚剂对苯二醌/硫化钠，在氮气的保护下，将体系加热至175℃，并保持3小时，随后在175℃/0.05MPa的条件下蒸除低沸点物质，剩余液体用50g 85℃的水洗涤1次，取有机相，120℃烘干至恒重，即得不饱和聚酯预聚物；The preparation method of the unsaturated polyester prepolymer is as follows: 134g of dipropylene glycol, 59g of succinic acid and 65g of itaconic acid are added into the reaction vessel, and then 4.2g of catalysts 4.2g of ethylene glycol antimony and 2.04g of composite resistance are added in sequence. The polymerization agent terephthaloquinone/sodium sulfide, under the protection of nitrogen, the system was heated to 175 ° C and kept for 3 hours, then the low boiling point substances were distilled off under the condition of 175 ° C / 0.05 MPa, and the remaining liquid was 50 g of 85 ° C Washing with water once, taking the organic phase and drying at 120°C to constant weight to obtain unsaturated polyester prepolymer;
所述复合阻聚剂对苯二醌/硫化钠的制备方法为将对苯二醌固体和硫化钠固体按摩尔比4:1混合即得。The preparation method of the composite polymerization inhibitor terephthaloquinone/sodium sulfide is obtained by mixing terephthaloquinone solid and sodium sulfide solid in a molar ratio of 4:1.
所述改性液的制备方法为将100g不饱和聚酯预聚物、0.6g过氧化二叔丁基、40g衣康酸二甲酯加入到索氏提取器中，在110℃条件下提取3小时，所得液体即为改性液。The preparation method of the modified liquid is to add 100 g of unsaturated polyester prepolymer, 0.6 g of di-tert-butyl peroxide and 40 g of dimethyl itaconic acid into a Soxhlet extractor, and extract 3 hours, the resulting liquid is the modified liquid.
所述单面沉积有聚酰胺的聚乙烯纤维布的制备方法如下：将聚酰胺溶解于20wt％甲酸水溶液中，以聚乙烯纤维布为衬底，使用静电纺丝法将聚酰胺的甲酸溶液制得的纤维沉积于聚乙烯纤维布上，使沉积层厚度为0.030mm，即得单面沉积有聚酰胺的聚乙烯纤维布；The preparation method of the polyethylene fiber cloth with polyamide deposited on one side is as follows: the polyamide is dissolved in a 20wt% formic acid aqueous solution, the polyethylene fiber cloth is used as a substrate, and the formic acid solution of the polyamide is prepared by an electrospinning method. The obtained fiber is deposited on the polyethylene fiber cloth, so that the thickness of the deposited layer is 0.030mm, that is, the polyethylene fiber cloth with polyamide deposited on one side is obtained;
所述聚酰胺的质量为甲酸水溶液质量的50％。The mass of the polyamide is 50% of the mass of the formic acid aqueous solution.
所述静电纺丝工艺条件为喷丝头到接收屏垂直距离为15cm，电压35kV， 25℃，相对湿度65％。The electrospinning process conditions are that the vertical distance from the spinneret to the receiving screen is 15cm, the voltage is 35kV, the temperature is 25°C, and the relative humidity is 65%.
所述聚乙烯纤维布克重300g/m2。The polyethylene fiber has a book weight of 300 g/m 2 .
一种吸湿排汗防感冒的篮球服，制备方法如下：A kind of basketball uniform for moisture absorption and perspiration prevention and cold prevention, the preparation method is as follows:
(1)将保暖纤维通过常规方法编织成克重为220g/m2的外层面料；( 1 ) Weaving the thermal insulation fiber into an outer layer fabric with a gram weight of 220g/m by conventional methods;
(2)在外层面料的任意一面涂抹粘合剂，上胶量为20g/m2；(2) Apply adhesive on any side of the outer fabric, and the amount of glue is 20g/m 2 ;
(3)将外层面料涂有粘合胶的一面单面沉积有聚酰胺的聚乙烯纤维布的未沉积聚酰胺的一面贴合，通过常规的层压复合工艺制得双层面料；(3) one side of the outer layer fabric coated with adhesive glue is deposited with one side of the un-deposited polyamide of the polyethylene fiber cloth of polyamide, and the double-layer fabric is obtained by conventional lamination and composite technology;
所述层压复合工艺参数如下：层压温度120℃，层压压力2.5kgf/cm2，层压时间8s；The lamination and composite process parameters are as follows: lamination temperature 120°C, lamination pressure 2.5kgf/cm 2 , lamination time 8s;
所述粘合胶为EVA/TPR热熔胶；The adhesive is EVA/TPR hot melt adhesive;
所述的EVA/TPR复合热熔胶，制备方法如下：Described EVA/TPR composite hot melt adhesive, preparation method is as follows:
将EVA热熔胶加热至175℃，加入EVA热熔胶质量5％的TPR热熔胶，混合均匀，自然降至室温，即得。Heat the EVA hot-melt adhesive to 175° C., add TPR hot-melt adhesive with 5% of the mass of the EVA hot-melt adhesive, mix evenly, and naturally drop to room temperature.
(4)将双层面料剪裁缝制，得到吸湿排汗防感冒篮球服。(4) The double-layer fabric is cut and sewn to obtain a moisture-wicking, sweat-proof and cold-proof basketball uniform.
测试例1Test Example 1
剥离强度测试Peel Strength Test
将按实施例1-7制得的用于制得吸湿排汗防感冒篮球服的双层面料进行剥离强度测试，测试方法参考FZ/T01010-91涂层织物粘结强度测试方法。使用织物强力机，采用等速牵引型强力测试，每种试样测试三次，取平均值，试样大小为5cm×15cm。The peel strength test was carried out on the double-layer fabrics prepared according to Examples 1-7 for making the moisture-wicking, sweat-proof, and cold-proof basketball uniforms. Using a fabric strength machine, a constant velocity traction type strength test was used, each sample was tested three times, and the average value was taken, and the size of the sample was 5cm × 15cm.
测试结果如表1所示。The test results are shown in Table 1.
表1剥离强度测试Table 1 Peel Strength Test
由上表可知，本发明提供的用于制备吸湿排汗防感冒的篮球服的面料均具有良好的剥离强度，其中以实施例7为最佳，因为该织物表面能敲到好处，复合压力适当，不出现渗胶现象，因此体现出了较高的剥离强度。It can be seen from the above table that the fabrics for preparing the moisture-wicking and anti-cold basketball uniforms provided by the present invention all have good peel strength, among which Example 7 is the best, because the surface of the fabric can be knocked out, and the compound pressure is appropriate. , there is no glue leakage phenomenon, so it shows a higher peel strength.
测试例2Test case 2
透气性测试Air permeability test
将按实施例1-7制得的用于制得吸湿排汗防感冒篮球服的双层面料进行透气性测试。测试方法参照GB/T 5453-1997。The air permeability test was carried out on the double-layer fabrics prepared according to Examples 1-7 for making the moisture-wicking and anti-cold basketball uniforms. The test method refers to GB/T 5453-1997.
测试条件为压力差100Pa/mm H2O，测试面积为50cm2，温度20℃，相对湿度65％，试样大小为5cm×15cm。The test conditions were a pressure difference of 100 Pa/mm H 2 O, a test area of 50 cm 2 , a temperature of 20° C., a relative humidity of 65%, and a sample size of 5 cm×15 cm.
测试结果如表2所示。The test results are shown in Table 2.
表2织物透气率Table 2 Fabric air permeability
由上表可知，本发明提供的用于制备吸湿排汗防感冒的篮球服的面料均具有良好的透气率，通过上述研究发现聚乙烯纤维布和粘合剂的性质对透气率有较大的影响，其主要原因归结于复合织物的空隙覆盖率，空隙越多透气率越差。It can be seen from the above table that the fabrics for preparing the moisture-wicking and anti-cold basketball uniforms provided by the present invention all have good air permeability. The main reason is due to the void coverage of the composite fabric. The more voids, the worse the air permeability.
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| CN2343184Y (en) * | 1998-08-12 | 1999-10-13 | 康那香企业股份有限公司 | Multi-layer composite non-woven fabric |
| CN102276856A (en) * | 2010-06-12 | 2011-12-14 | 武汉科技学院 | Preparation method of textile reinforced composite material |
| CN102380988A (en) * | 2011-10-29 | 2012-03-21 | 常熟市福嘉丽织造有限公司 | Novel warm keeping fabric |
| CN206085872U (en) * | 2016-08-05 | 2017-04-12 | 陈楚元 | Fast -drying plus material |
| CN207803482U (en) * | 2018-01-30 | 2018-09-04 | 泉州宇晨服饰有限公司 | A kind of one-way wet-guide gym suit |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2343184Y (en) * | 1998-08-12 | 1999-10-13 | 康那香企业股份有限公司 | Multi-layer composite non-woven fabric |
| CN102276856A (en) * | 2010-06-12 | 2011-12-14 | 武汉科技学院 | Preparation method of textile reinforced composite material |
| CN102380988A (en) * | 2011-10-29 | 2012-03-21 | 常熟市福嘉丽织造有限公司 | Novel warm keeping fabric |
| CN206085872U (en) * | 2016-08-05 | 2017-04-12 | 陈楚元 | Fast -drying plus material |
| CN207803482U (en) * | 2018-01-30 | 2018-09-04 | 泉州宇晨服饰有限公司 | A kind of one-way wet-guide gym suit |
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