CN109722884A - A kind of preparation method of wear-resisting high resiliency linen-cotton fabric - Google Patents
A kind of preparation method of wear-resisting high resiliency linen-cotton fabric Download PDFInfo
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- CN109722884A CN109722884A CN201811582741.XA CN201811582741A CN109722884A CN 109722884 A CN109722884 A CN 109722884A CN 201811582741 A CN201811582741 A CN 201811582741A CN 109722884 A CN109722884 A CN 109722884A
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- 229920000742 Cotton Polymers 0.000 title claims abstract description 76
- 239000004744 fabric Substances 0.000 title claims abstract description 70
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000000975 dye Substances 0.000 claims abstract description 43
- 229920000180 alkyd Polymers 0.000 claims abstract description 40
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 24
- 241000208202 Linaceae Species 0.000 claims abstract description 20
- 235000004431 Linum usitatissimum Nutrition 0.000 claims abstract description 20
- 239000000835 fiber Substances 0.000 claims abstract description 20
- 210000004177 elastic tissue Anatomy 0.000 claims abstract description 19
- 239000004005 microsphere Substances 0.000 claims abstract description 18
- 229920003180 amino resin Polymers 0.000 claims abstract description 16
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000007822 coupling agent Substances 0.000 claims abstract description 13
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229960002415 trichloroethylene Drugs 0.000 claims abstract description 8
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- 238000003756 stirring Methods 0.000 claims description 24
- 238000013019 agitation Methods 0.000 claims description 15
- 239000000049 pigment Substances 0.000 claims description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 9
- 239000002383 tung oil Substances 0.000 claims description 8
- 238000000498 ball milling Methods 0.000 claims description 7
- 238000001354 calcination Methods 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 238000000703 high-speed centrifugation Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000007873 sieving Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 4
- 235000019394 potassium persulphate Nutrition 0.000 claims description 4
- DMBHHRLKUKUOEG-UHFFFAOYSA-N N-phenyl aniline Natural products C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 3
- 235000019482 Palm oil Nutrition 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 238000006136 alcoholysis reaction Methods 0.000 claims description 3
- -1 alkyl diphenylamine Chemical compound 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- LGRLWUINFJPLSH-UHFFFAOYSA-N methanide Chemical compound [CH3-] LGRLWUINFJPLSH-UHFFFAOYSA-N 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000002540 palm oil Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 239000004753 textile Substances 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- 244000299507 Gossypium hirsutum Species 0.000 claims 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 239000008236 heating water Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims 1
- 150000004968 peroxymonosulfuric acids Chemical class 0.000 claims 1
- 241000219146 Gossypium Species 0.000 abstract description 19
- 239000003973 paint Substances 0.000 abstract description 6
- 238000004140 cleaning Methods 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 13
- 241000209094 Oryza Species 0.000 description 7
- 235000007164 Oryza sativa Nutrition 0.000 description 7
- 235000009566 rice Nutrition 0.000 description 7
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 5
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 5
- 239000000908 ammonium hydroxide Substances 0.000 description 5
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- 230000002159 abnormal effect Effects 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910000754 Wrought iron Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- CUXYLFPMQMFGPL-SUTYWZMXSA-N all-trans-octadeca-9,11,13-trienoic acid Chemical class CCCC\C=C\C=C\C=C\CCCCCCCC(O)=O CUXYLFPMQMFGPL-SUTYWZMXSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention discloses a kind of preparation method of wear-resisting high resiliency linen-cotton fabric, include the following steps: to weigh following raw material: 35-50 parts of amino resins, 55-70 parts of modified alkyd resins, 15-35 parts of nano dyes, 10-15 parts of coupling agents, 75-90 parts of mercerized cottons, 75-90 parts of flax fibers, 25-30 parts of butadiene-styrene rubber, the 120-150 parts of trichloro ethylene present invention pass through mercerized cotton, highly elastic fiber and flax fiber carry out blended, form a kind of wear-resisting high resiliency linen-cotton fabric, mercerized cotton has ensured that fabric has good comfort, pass through amino resins, the highly elastic fiber and flax fiber of modified alkyd resin and butadiene-styrene rubber preparation have ensured that fabric has certain wear-resisting property and higher elasticity, nano paint is prepared by preparing nano silica microsphere later, Nano paint is coated in linen-cotton web surface, make fabric that there is certain self-cleaning property and further enhances the wear-resisting property of fabric.
Description
Technical field
The invention belongs to fabric production technical field, specially a kind of preparation method of wear-resisting high resiliency linen-cotton fabric.
Background technique
Linen-cotton fabric is a kind of blended yarn weaved fabric for being most commonly encountered in people's life, and linen-cotton fabric be used to some often be related to again
To friction environment in when, such as mop, rag.It is more demanding for the wear-resisting property of linen-cotton fabric.Untreated cotton
Flax fabric, after long-time rubs, linen-cotton fabric can generate certain abrasion, and fiber will receive damage, influence linen-cotton face
The performance of material.
As the improvement of people's living standards, outdoor sports are more and more, everybody requirement to clothes is also higher and higher, no
Only there is good permeability, also there is preferable wearability and higher elasticity.
Summary of the invention
In order to overcome above-mentioned technical problem, the present invention provides a kind of preparation method of wear-resisting high resiliency linen-cotton fabric.It is logical
It is blended to cross mercerized cotton, highly elastic fiber and flax fiber progress, forms a kind of wear-resisting high resiliency linen-cotton fabric, mercerized cotton ensures
Fabric has good comfort, the highly elastic fiber prepared by amino resins, modified alkyd resin and butadiene-styrene rubber and Asia
Flaxen fiber has ensured that fabric has certain wear-resisting property and higher elasticity, is made later by preparing nano silica microsphere
Nano paint is coated in linen-cotton web surface by standby nano paint, and fabric is made to have certain self-cleaning property and further
Enhance the wear-resisting property of fabric.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of preparation method of wear-resisting high resiliency linen-cotton fabric, includes the following steps:
Step S1, following raw material: 35-50 parts of amino resins is weighed, 55-70 parts of modified alkyd resins, 15-35 parts
Nano dye, 10-15 parts of coupling agents, 75-90 parts of mercerized cottons, 75-90 parts of flax fibers, 25-30 parts of butadiene-styrene rubber, 120-150
Part trichloro ethylene；
Step S2, prepared by nano dye: (a) 20mL ethyl orthosilicate being added in 50mL dehydrated alcohol, 1mL25% is added
1.5gPVB is added in ammonium hydroxide, and at the uniform velocity stirring is until solution is clarified；(b) by after clear solution magnetic agitation 30min, 60 DEG C of water-baths add
Heat and ultrasonic disperse 2h carry out high speed centrifugation with the revolving speed of 10000r/min, after be centrifuged object 3 times with washes of absolute alcohol,
Being put into vacuum degree is -0.10MPa, and nano silica microsphere is made after dry 10h in the vacuum oven that temperature is 120 DEG C；
(C) nano silica microsphere and pigment are uniformly mixed and are placed in Muffle furnace, taken out after calcining 20min at 450 DEG C, stood
It is added in ball mill after 5h, ball milling is carried out with the revolving speed of 1300r/min, crushed, partial size is made after sieving is 9-60 μm and receive
The weight ratio of rice dyestuff, nano silica and pigment is 3: 2；
Step S3, amino resins, modified alkyd resin and butadiene-styrene rubber are added in the three-necked flask equipped with trichloro ethylene,
It is heated to molten condition, coupling agent is added after stirring 30min, after reacting 5h at this temperature, molten mixture is made, from spinneret
It is squeezed out in plate, forms highly elastic fiber；
Step S4, by mercerized cotton, highly elastic fiber and flax fiber according to through to spacing 0.8cm, broadwise spacing 1.0cm into
Row is blended, and it is 75/cm that warp count, which is made, and weft count is the high resiliency linen-cotton fabric of 80/cm；
Step S5, nano dye is added in 100mL deionized water, by wear-resisting high resiliency linen-cotton fabric after stirring 30min
It is immersed in dyestuff, at the uniform velocity stirs, form the nano dye coating of 1mm-2mm, be placed in 80 DEG C of baking ovens dry 2h, be made described
Wear-resisting high resiliency linen-cotton fabric.
Further, the modified alkyd resin is made by the following method:
(1) 100mL tung oil, 80mL palm oil and 5g stannous methide are added in four-hole boiling flask, are passed through nitrogen, are heated to
100 DEG C, magnetic agitation 1h, 3mL alkyl diphenylamine is added, is continuously heating to 150 DEG C, 50mL ethyl acetate is added after alcoholysis 2h,
4h is reacted at this temperature, and alkyd resin is made；
(2) alkyd resin is added in the beaker equipped with dehydrated alcohol, is heated to 120 DEG C, magnetic agitation 45min, be added
Ethyl methacrylate and potassium peroxydisulfate are warming up to 130 DEG C, clear solution are made after magnetic agitation 3h, is transferred to 150 DEG C of baking ovens
In, it is dry to solvent evaporating completely, modified alkyd resin, alkyd resin, dehydrated alcohol, ethyl methacrylate and over cure is made
The weight ratio of sour potassium is 15: 10: 5: 3.
Tung oil is drying oil, and there are three conjugated double bonds in tung oil molecule, during preparing alkyd resin, tung oil molecule
Hydrolysis becomes the unsaturated eleostearic acid containing three conjugated double bonds, and being total in tung oil molecule is introduced on alkyd resin molecular backbone
Yoke double bond, using conjugated double bond as the grafting site of ethyl methacrylate in reaction process, conjugated double bond is neighbouring in tung oil molecule
In air under the action of oxygen, hydrogen abstraction reaction occurs for the hydrogen on carbon atom, and the hydroperoxides of generation, which decompose, to be generated freely
Base, initiated polymerization form modified alkyd resin.
Further, the coupling agent is one or more of KH550, KH560, KH570.
Further, the orifice diameter of spinneret is 0.05-0.10mm in step S2.
Further, controlling air humidity in step S3 when mixed textile is 60%.
Beneficial effects of the present invention:
(1) present invention is carried out blended by mercerized cotton, highly elastic fiber and flax fiber, forms a kind of wear-resisting high resiliency cotton
Flax fabric, mercerized cotton have ensured that fabric has good comfort, have passed through amino resins, modified alkyd resin and butadiene-styrene rubber system
Standby highly elastic fiber and flax fiber has ensured that fabric has certain wear-resisting property and higher elasticity, is received later by preparation
Rice silicon dioxide microsphere prepares nano paint, and nano paint is coated in linen-cotton web surface, make fabric have it is certain from
Clean performance and further enhance the wear-resisting property of fabric.
(2) alkyd resin has good wettability, and adhesive force is strong, and manufactured coating is plentiful, but its stability is poor,
Weatherability is weaker, and the present invention is modified alkyd resin by ethyl methacrylate using potassium peroxydisulfate as initiator,
Carbon-carbon double bond fracture on alkyd backbone, ethyl methacrylate is grafted on carbon atom, branch is formed, preparation changes
Property alkyd resin not only had the advantages that alkyd resin, but also there is good weatherability and higher heat-and corrosion-resistant performance, so
The highly elastic fiber of preparation had both had good elasticity, and stability is good, had preferable rapid-drying properties.
(3) nano dye prepared by the present invention, using nano silica microsphere as matrix, dyestuff is coated on by calcining and is received
Rice silicon dioxide microsphere surface, carries out ball milling later, and the nano dye finally prepared had both had the characteristic of nano material, has one
Fixed hydrophobicity and self-cleaning property, and make nano dye that there is preferable wear-resisting property by matrix of silicon dioxide microsphere,
So improving its wearability when nano dye is coated in web surface and also increasing the waterproof of wear-resisting high resiliency linen-cotton fabric
Performance.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, all other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of preparation method of wear-resisting high resiliency linen-cotton fabric, includes the following steps:
Step S1, following raw material: 35 parts of amino resins is weighed, 55 parts of modified alkyd resins, 15 parts of nano dyes,
10 parts of KH550,75 parts of mercerized cottons, 75 parts of flax fibers, 25 parts of butadiene-styrene rubber, 120 parts of trichloro ethylenes；
Step S2, prepared by nano dye: (a) 20mL ethyl orthosilicate being added in 50mL dehydrated alcohol, 1mL25% is added
1.5gPVB is added in ammonium hydroxide, and at the uniform velocity stirring is until solution is clarified；(b) by after clear solution magnetic agitation 30min, 60 DEG C of water-baths add
Heat and ultrasonic disperse 2h carry out high speed centrifugation with the revolving speed of 10000r/min, after be centrifuged object 3 times with washes of absolute alcohol,
Being put into vacuum degree is -0.10MPa, and nano silica microsphere is made after dry 10h in the vacuum oven that temperature is 120 DEG C；
(C) nano silica microsphere and pigment are uniformly mixed and are placed in Muffle furnace, taken out after calcining 20min at 450 DEG C, stood
It is added in ball mill after 5h, ball milling is carried out with the revolving speed of 1300r/min, crushed, partial size is made after sieving is 9-60 μm and receive
The weight ratio of rice dyestuff, nano silica and pigment is 3: 2；
Step S3, amino resins, modified alkyd resin and butadiene-styrene rubber are added in the three-necked flask equipped with trichloro ethylene,
It is heated to molten condition, coupling agent is added after stirring 30min, after reacting 5h at this temperature, molten mixture is made, from spinneret
It is squeezed out in plate, forms highly elastic fiber；
Step S4, by mercerized cotton, highly elastic fiber and flax fiber according to through to spacing 0.8cm, broadwise spacing 1.0cm into
Row is blended, and it is 75/cm that warp count, which is made, and weft count is the high resiliency linen-cotton fabric of 80/cm；
Step S5, nano dye is added in 100mL deionized water, by wear-resisting high resiliency linen-cotton fabric after stirring 30min
It is immersed in dyestuff, at the uniform velocity stirs, form the nano dye coating of 1mm-2mm, be placed in 80 DEG C of baking ovens dry 2h, be made described
Wear-resisting high resiliency linen-cotton fabric.
The modified alkyd resin is made by the following method:
(1) 100mL tung oil, 80mL palm oil and 5g stannous methide are added in four-hole boiling flask, are passed through nitrogen, are heated to
100 DEG C, magnetic agitation 1h, 3mL alkyl diphenylamine is added, is continuously heating to 150 DEG C, 50mL ethyl acetate is added after alcoholysis 2h,
4h is reacted at this temperature, and alkyd resin is made；
(2) alkyd resin is added in the beaker equipped with dehydrated alcohol, is heated to 120 DEG C, magnetic agitation 45min, be added
Ethyl methacrylate and potassium peroxydisulfate are warming up to 130 DEG C, clear solution are made after magnetic agitation 3h, is transferred to 150 DEG C of baking ovens
In, it is dry to solvent evaporating completely, modified alkyd resin, alkyd resin, dehydrated alcohol, ethyl methacrylate and over cure is made
The weight ratio of sour potassium is 15: 10: 5: 3.
Embodiment 2
A kind of preparation method of wear-resisting high resiliency linen-cotton fabric, includes the following steps:
Step S1, following raw material: 38 parts of amino resins is weighed, 58 parts of modified alkyd resins, 28 parts of nano dyes,
12 parts of KH550,80 parts of mercerized cottons, 80 parts of flax fibers, 28 parts of butadiene-styrene rubber, 130 parts of trichloro ethylenes；
Step S2, prepared by nano dye: (a) 20mL ethyl orthosilicate being added in 50mL dehydrated alcohol, 1mL25% is added
1.5gPVB is added in ammonium hydroxide, and at the uniform velocity stirring is until solution is clarified；(b) by after clear solution magnetic agitation 30min, 60 DEG C of water-baths add
Heat and ultrasonic disperse 2h carry out high speed centrifugation with the revolving speed of 10000r/min, after be centrifuged object 3 times with washes of absolute alcohol,
Being put into vacuum degree is -0.10MPa, and nano silica microsphere is made after dry 10h in the vacuum oven that temperature is 120 DEG C；
(C) nano silica microsphere and pigment are uniformly mixed and are placed in Muffle furnace, taken out after calcining 20min at 450 DEG C, stood
It is added in ball mill after 5h, ball milling is carried out with the revolving speed of 1300r/min, crushed, partial size is made after sieving is 9-60 μm and receive
The weight ratio of rice dyestuff, nano silica and pigment is 3: 2；
Step S3, amino resins, modified alkyd resin and butadiene-styrene rubber are added in the three-necked flask equipped with trichloro ethylene,
It is heated to molten condition, coupling agent is added after stirring 30min, after reacting 5h at this temperature, molten mixture is made, from spinneret
It is squeezed out in plate, forms highly elastic fiber；
Step S4, by mercerized cotton, highly elastic fiber and flax fiber according to through to spacing 0.8cm, broadwise spacing 1.0cm into
Row is blended, and it is 75/cm that warp count, which is made, and weft count is the high resiliency linen-cotton fabric of 80/cm；
Step S5, nano dye is added in 100mL deionized water, by wear-resisting high resiliency linen-cotton fabric after stirring 30min
It is immersed in dyestuff, at the uniform velocity stirs, form the nano dye coating of 1mm-2mm, be placed in 80 DEG C of baking ovens dry 2h, be made described
Wear-resisting high resiliency linen-cotton fabric.
Embodiment 3
A kind of preparation method of wear-resisting high resiliency linen-cotton fabric, includes the following steps:
Step S1, following raw material: 45 parts of amino resins is weighed, 65 parts of modified alkyd resins, 30 parts of nano dyes,
13 parts of coupling agents, 85 parts of mercerized cottons, 85 parts of flax fibers, 28 parts of butadiene-styrene rubber, 140 parts of trichloro ethylenes；
Step S2, prepared by nano dye: (a) 20mL ethyl orthosilicate being added in 50mL dehydrated alcohol, 1mL25% is added
1.5gPVB is added in ammonium hydroxide, and at the uniform velocity stirring is until solution is clarified；(b) by after clear solution magnetic agitation 30min, 60 DEG C of water-baths add
Heat and ultrasonic disperse 2h carry out high speed centrifugation with the revolving speed of 10000r/min, after be centrifuged object 3 times with washes of absolute alcohol,
Being put into vacuum degree is -0.10MPa, and nano silica microsphere is made after dry 10h in the vacuum oven that temperature is 120 DEG C；
(C) nano silica microsphere and pigment are uniformly mixed and are placed in Muffle furnace, taken out after calcining 20min at 450 DEG C, stood
It is added in ball mill after 5h, ball milling is carried out with the revolving speed of 1300r/min, crushed, partial size is made after sieving is 9-60 μm and receive
The weight ratio of rice dyestuff, nano silica and pigment is 3: 2；
Step S3, amino resins, modified alkyd resin and butadiene-styrene rubber are added in the three-necked flask equipped with trichloro ethylene,
It is heated to molten condition, coupling agent is added after stirring 30min, after reacting 5h at this temperature, molten mixture is made, from spinneret
It is squeezed out in plate, forms highly elastic fiber；
Step S4, by mercerized cotton, highly elastic fiber and flax fiber according to through to spacing 0.8cm, broadwise spacing 1.0cm into
Row is blended, and it is 75/cm that warp count, which is made, and weft count is the high resiliency linen-cotton fabric of 80/cm；
Step S5, nano dye is added in 100mL deionized water, by wear-resisting high resiliency linen-cotton fabric after stirring 30min
It is immersed in dyestuff, at the uniform velocity stirs, form the nano dye coating of 1mm-2mm, be placed in 80 DEG C of baking ovens dry 2h, be made described
Wear-resisting high resiliency linen-cotton fabric.
Embodiment 4
A kind of preparation method of wear-resisting high resiliency linen-cotton fabric, includes the following steps:
Step S1, following raw material: 50 parts of amino resins is weighed, 70 parts of modified alkyd resins, 35 parts of nano dyes,
15 parts of coupling agents, 90 parts of mercerized cottons, 90 parts of flax fibers, 30 parts of butadiene-styrene rubber, 150 parts of trichloro ethylenes；
Step S2, prepared by nano dye: (a) 20mL ethyl orthosilicate being added in 50mL dehydrated alcohol, 1mL25% is added
1.5gPVB is added in ammonium hydroxide, and at the uniform velocity stirring is until solution is clarified；(b) by after clear solution magnetic agitation 30min, 60 DEG C of water-baths add
Heat and ultrasonic disperse 2h carry out high speed centrifugation with the revolving speed of 10000r/min, after be centrifuged object 3 times with washes of absolute alcohol,
Being put into vacuum degree is -0.10MPa, and nano silica microsphere is made after dry 10h in the vacuum oven that temperature is 120 DEG C；
(C) nano silica microsphere and pigment are uniformly mixed and are placed in Muffle furnace, taken out after calcining 20min at 450 DEG C, stood
It is added in ball mill after 5h, ball milling is carried out with the revolving speed of 1300r/min, crushed, partial size is made after sieving is 9-60 μm and receive
The weight ratio of rice dyestuff, nano silica and pigment is 3: 2；
Step S3, amino resins, modified alkyd resin and butadiene-styrene rubber are added in the three-necked flask equipped with trichloro ethylene,
It is heated to molten condition, coupling agent is added after stirring 30min, after reacting 5h at this temperature, molten mixture is made, from spinneret
It is squeezed out in plate, forms highly elastic fiber；
Step S4, by mercerized cotton, highly elastic fiber and flax fiber according to through to spacing 0.8cm, broadwise spacing 1.0cm into
Row is blended, and it is 75/cm that warp count, which is made, and weft count is the high resiliency linen-cotton fabric of 80/cm；
Step S5, nano dye is added in 100mL deionized water, by wear-resisting high resiliency linen-cotton fabric after stirring 30min
It is immersed in dyestuff, at the uniform velocity stirs, form the nano dye coating of 1mm-2mm, be placed in 80 DEG C of baking ovens dry 2h, be made described
Wear-resisting high resiliency linen-cotton fabric.
Comparative example 1
This comparative example lacks step (2) compared with Example 1, is not modified alkyd resin.
Comparative example 2
This comparative example lacks step S1 compared with Example 1, does not prepare nano dye.
Comparative example 3
This comparative example is a kind of wear-resisting high resiliency linen-cotton fabric in market.
To the wear-resisting property of the embodiment 1-4 and comparative example 1-3 wear-resisting high resiliency linen-cotton fabric prepared, ultimate strength, break
It splits elongation and corrosion resistance is detected, as a result as shown in table 1 below.
Wear-resisting property: diameter, which is made, in the embodiment 1-4 and comparative example 1-3 wear-resisting high resiliency linen-cotton fabric prepared is
The round fabric of 100cm carries out frictional experiment, weight quality 500g, measurement friction 500 using disk fabric plain grinding experiment instrument
Rate of weight loss after turning.
Corrosion resistance: the embodiment 1-4 and comparative example 1-3 wear-resisting high resiliency linen-cotton fabric prepared is made 3cm × 2cm's
Rectangle fabric is coated on common low carbon rod iron surface, 2/3 area of coupon is immersed in 10% dilute hydrochloric acid, in (25 ± 1) DEG C temperature
Degree is lower to be impregnated 5 days, observation whether there is or not discoloration, loss of gloss, vesicle, spot, fall off phenomena such as appearance.
1 embodiment of table and comparative example the performance test results
As can be seen from Table 1 by the rate of weight loss of the embodiment 1-4 wear-resisting high resiliency linen-cotton fabric prepared in 0.30-
In 0.35% range, the wear-resisting high resiliency linen-cotton fabric rate of weight loss of comparative example 1-3 preparation is within the scope of 0.34-0.41%；
The ultimate strength of the wear-resisting high resiliency linen-cotton fabric of embodiment 1-4 preparation is between 8512-871N, and elongation at break is in 33-
Between 38%, the ultimate strength of the wear-resisting high resiliency linen-cotton fabric of comparative example 1-3 preparation is between 821-854N, elongation at break
Between 29-33%；Wear-resisting high resiliency linen-cotton fabric prepared by embodiment 1-4 and comparative example 2 is immersed in 10% dilute hydrochloric acid 5 days
There is not abnormal phenomenon, it is abnormal that wear-resisting high resiliency linen-cotton fabric prepared by embodiment 1,3 is immersed in appearance in 5 days in 10% dilute hydrochloric acid
Phenomenon.Described wear-resisting high resiliency linen-cotton fabric prepared by the present invention not only has good wear-resisting property and higher elasticity, and
And there is good corrosion resistance.
In the description of this specification, the description of reference term " one embodiment ", " example ", " specific example " etc. means
Particular features, structures, materials, or characteristics described in conjunction with this embodiment or example are contained at least one implementation of the invention
In example or example.In the present specification, schematic expression of the above terms may not refer to the same embodiment or example.
Moreover, particular features, structures, materials, or characteristics described can be in any one or more of the embodiments or examples to close
Suitable mode combines.
Above content is only citing made for the present invention and explanation, affiliated those skilled in the art are to being retouched
The specific embodiment stated does various modifications or additions or is substituted in a similar manner, and without departing from invention or surpasses
More range defined in the claims, is within the scope of protection of the invention.
Claims (5)
1. a kind of preparation method of wear-resisting high resiliency linen-cotton fabric, which comprises the steps of:
Step S1, following raw material: 35-50 parts of amino resins, 55-70 parts of modified alkyd resins, 15-35 parts of nanometers are weighed
Dyestuff, 10-15 parts of coupling agents, 75-90 parts of mercerized cottons, 75-90 parts of flax fibers, 25-30 parts of butadiene-styrene rubber, 120-150 part three
Vinyl chloride；
Step S2, prepared by nano dye: (a) 20mL ethyl orthosilicate being added in 50mL dehydrated alcohol, 1mL25% ammonia is added
1.5gPVB is added in water, and at the uniform velocity stirring is until solution is clarified；(b) by after clear solution magnetic agitation 30min, 60 DEG C of heating water baths
And ultrasonic disperse 2h, high speed centrifugation is carried out with the revolving speed of 10000r/min, after be centrifuged object 3 times with washes of absolute alcohol, put
Entering vacuum degree is -0.10MPa, and nano silica microsphere is made after dry 10h in the vacuum oven that temperature is 120 DEG C；(C)
Nano silica microsphere and pigment are uniformly mixed and are placed in Muffle furnace, is taken out after calcining 20min at 450 DEG C, 5h is stood
After be added in ball mill, ball milling is carried out with the revolving speed of 1300r/min, crushes, the nanometer that partial size is 9-60 μm is made after sieving
The weight ratio of dyestuff, nano silica and pigment is 3: 2；
Step S3, amino resins, modified alkyd resin and butadiene-styrene rubber are added in the three-necked flask equipped with trichloro ethylene, heating
To molten condition, coupling agent is added after stirring 30min, after reacting 5h at this temperature, molten mixture is made, from spinneret
It squeezes out, forms highly elastic fiber；
Step S4, by mercerized cotton, highly elastic fiber and flax fiber according to through being mixed to spacing 0.8cm, broadwise spacing 1.0cm
It spins, it is 75/cm that warp count, which is made, and weft count is the high resiliency linen-cotton fabric of 80/cm；
Step S5, nano dye is added in 100mL deionized water, impregnates wear-resisting high resiliency linen-cotton fabric after stirring 30min
It in dyestuff, at the uniform velocity stirs, forms the nano dye coating of 1mm-2mm, be placed in 80 DEG C of baking ovens dry 2h, be made described wear-resisting
High resiliency linen-cotton fabric.
2. a kind of preparation method of wear-resisting high resiliency linen-cotton fabric according to claim 1, which is characterized in that the modification
Alkyd resin is made by the following method:
(1) 100mL tung oil, 80mL palm oil and 5g stannous methide are added in four-hole boiling flask, are passed through nitrogen, are heated to 100 DEG C,
3mL alkyl diphenylamine is added in magnetic agitation 1h, is continuously heating to 150 DEG C, 50mL ethyl acetate is added after alcoholysis 2h, warm herein
Degree is lower to react 4h, and alkyd resin is made；
(2) alkyd resin is added in the beaker equipped with dehydrated alcohol, is heated to 120 DEG C, magnetic agitation 45min, methyl is added
Ethyl acrylate and potassium peroxydisulfate are warming up to 130 DEG C, clear solution are made after magnetic agitation 3h, is transferred in 150 DEG C of baking ovens,
Modified alkyd resin, alkyd resin, dehydrated alcohol, ethyl methacrylate and persulfuric acid is made to solvent evaporating completely in drying
The weight ratio of potassium is 15: 10: 5: 3.
3. a kind of preparation method of wear-resisting high resiliency linen-cotton fabric according to claim 1, which is characterized in that the coupling
Agent is one or more of KH550, KH560, KH570.
4. a kind of preparation method of wear-resisting high resiliency linen-cotton fabric according to claim 1, which is characterized in that in step S2
The orifice diameter of spinneret is 0.05-0.10mm.
5. a kind of preparation method of wear-resisting high resiliency linen-cotton fabric according to claim 1, which is characterized in that in step S3
It is 60% that air humidity is controlled when mixed textile.
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